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This final article on the outlook for U.S. future natural gas supplies expands on the concept of the natural gas resource pyramid. A series of poorly understood but potentially significant emerging gas plays is introduced. These plays reside at various levels within the resource pyramid. These emerging resources include sub-volcanic gas, shale gas, deep coalbed methane, and unrecognized tight gas sands.
The heat capacities of synthetic coesite and jadeite were measured between about 15 and 850 K by adiabatic and differential scanning calorimetry. The experimental data were smoothed and estimates were made of heat capacities to 1800 K. The following equations represent our estimate of the heat capacities of coesite and jadeite between 298.15 and 1800 K: [see original article for formula]. Tables of thermodynamic values for coesite and jadeite to 1800 K are presented. The entropies of coesite and jadeite are 40.38 ?? 0.12 and 136.5 ?? 0.32 J/(mol.K), respectively, at 298.15 K. The entropy for coesite derived here confirms the value published earlier by Holm et al. (1967). We have derived an equation to describe the quartz-coesite boundary over the temperature range of 600 to 1500 K, P(GPa) = 1.76 + 0.001T(K). Our results are in agreement with the enthalpy of transition reported by Akaogi and Navrotsky (1984) and yield -907.6 ?? 1.4 kJ/mol for the enthalpy of formation of coesite from the elements at 298.15 K and 1 bar, in agreement with the value recommended by CODATA (Khodakovsky et al. 1995). Several sources of uncertainty remain unacceptably high, including: the heat capacities of coesite at temperatures above about 1000 K; the heat capacities and volumetric properties of ?? quartz at higher pressures and at temperatures above 844 K; the pressure corrections for the piston cylinder apparatus used to determine the quartz-coesite equilibrium boundary.
This article is a summary of Arizona geological survey circular 29, which addresses the petroleum geology of Arizona, USA. Eight areas have been identified with fair to excellent oil and gas potential, and some Tertiary basins have evidence of source or reservoir rocks. The following are considered here: production history, lands status and services, regulation and permitting, petroleum geology, hydrocarbon indications, and areas with hydrocarbon potential and their petroleum geology and characteristics. The full report contains detailed figures of each of these basin areas, a descriptive tabulation of seeps and petroliferous rocks and extensive references.
Woody plants are an important component of rangeland habitat, providing food and shelter for animals that range in size from moose to warblers to insects. Because of this importance, land managers are paying increased attention to browse trends. In this two-part article, we describe how browse trend is assessed at the Mt. Haggin Wildlife Management Area in southwestern Montana. Willows are currently heavily browsed, but there is evidence that browsing pressure was lower in the past. Heavily-browsed 14-inch-tall plants grow in close proximity to 16-foot-tall plants, the tallest stems of which are unbrowsed. The 16-foot-tall stems are older than the 14-inch-tall stems, and apparently grew through the browse zone when browsing pressure was lower than its current level. An increase in browsing pressure would be consistent with the increase in the moose population that occurred over the past 3 decades.
The significance of power-law tail probabilities of drainage areas in river basins was discussed. The convergence to a power law was not observed for all underlying distributions, but for a large class of statistical distributions with specific limiting properties. The article also discussed about the scaling properties of topologic and geometric network properties in river basins.
This article discusses image, topographic, and spectral data from the Mars Global Surveyor (MGS) mission that provide new information concerning the surface age, geomorphology, and topography of the Juventae Chasma/Maja Valles system. Our study utilizes data from two instruments on board MGS: images from the Mars Orbiter Camera (MOC) and topography from the Mars Orbiter Laser Altimeter (MOLA). Within Maja Valles we can now observe depositional bars with megaripples that unequivocally show catastrophic floods occurred in the channel. Viking impact crater densities indicated the chasma and channel floor areas were all one age (late Hesperian to Amazonian); however, MOC data indicate a marked difference in densities of small craters between Juventae Chasma, Maja Valles, and the channel debouchment area in Chryse Planitia basin. Although other processes may contribute to crater variability, young resurfacing events in the chasma and episodes of recent erosion at Maja Valles channel head may possibly account for the disparate crater densities along the chasma/channel system. Relatively young volcanic eruptions may have contributed to resurfacing; as in Juventae Chasma, a small possible volcanic cone of young dark material is observed. MOC data also indicate previously unknown interior layered deposit mounds in the chasma that indicate at least two periods of mound formation. Finally, MOLA topography shows that the entire floor of the chasma lies at the same elevation as the channel debouchment area in Chryse basin, resulting in a 3-km-high barrier to water flow out of the chasma. Blocked ponded water would rapidly freeze in the current (and likely past) climate of Mars. For catastrophic flow to occur in Maja Valles, some process is required to melt ice and induce floods out of the chasma. We suggest subice volcanic eruption and calculate estimates of water discharges and volumes that these eruptions might have produced.
This article summarizes allelochemicals' active variety, its potential causes and function mechanisms. Allelochemicals' activity varies with temperature, photoperiod, water and soils during natural processes, with its initial concentration, compound structure and mixed degree during functional processes, with plant accessions, tissues and maturity within-species, and with research techniques and operation processes. The prospective developmental aspects of allelopathy studies in the future are discussed. Future research should focus on: (1) to identify and purify allelochemicals more effectively, especially for agriculture, (2) the functions of allelopathy at the molecular structure level, (3) using allelopathy to explain plant species interactions, (4) allelopathy as a driving force of succession, and (5) the significance of allelopathy in the evolutionary processes.
The US Geological Survey has developed an innovative tethered platform that supports an Acoustic Current Profiler (ACP) in making stream-flow measurements (use of the term ACP in this article refers to a class of instruments and not a specific brand name or model). The tethered platform reduces the hazards involved in conventional methods of stream-flow measurement. The use of the platform reduces or eliminates time spent by personnel in streams and boats or on bridges and cableway and stream-flow measurement accuracy is increased.
The USDA Annualized Agricultural Non-Point Source Pollution model (AnnAGNPS) has been developed to aid in evaluation of watershed response to agricultural management practices. Previous studies have demonstrated the capability of the model to simulate runoff and sediment, but not phosphorus (P). The main purpose of this article is to evaluate the performance of AnnAGNPS on P simulation using comparisons with measurements from the Deep Hollow watershed of the Mississippi Delta Management Systems Evaluation Area (MDMSEA) project. A sensitivity analysis was performed to identify input parameters whose impact is the greatest on P yields. Sensitivity analysis results indicate that the most sensitive variables of those selected are initial soil P contents, P application rate, and plant P uptake. AnnAGNPS simulations of dissolved P yield do not agree well with observed dissolved P yield (Nash-Sutcliffe coefficient of efficiency of 0.34, R2 of 0.51, and slope of 0.24); however, AnnAGNPS simulations of total P yield agree well with observed total P yield (Nash-Sutcliffe coefficient of efficiency of 0.85, R2 of 0.88, and slope of 0.83). The difference in dissolved P yield may be attributed to limitations in model simulation of P processes. Uncertainties in input parameter selections also affect the model's performance.
This article is a summary of a panel session at the 2005 Offshore Technology Conference. Oil and gas reserves estimates are further complicated with the expanding importance of the worldwide deepwater arena. These deepwater reserves can be analyzed, interpreted, and conveyed in a consistent, reliable way to investors and other stakeholders. Continually improving technologies can lead to improved estimates of production and reserves, but the estimates are not necessarily recognized by regulatory authorities as an indicator of "reasonable certainty," a term used since 1964 to describe proved reserves in several venues. Solutions are being debated in the industry to arrive at a reporting mechanism that generates consistency and at the same time leads to useful parameters in assessing a company's value without compromising confidentiality. Copyright 2005 Offshore Technology Conference.
Although the precise course of volcanic activity is difficult to predict, volcanologists are pretty adept at interpreting volcanic signals from well-monitored volcanoes in order to make short-term forecasts. Various monitoring tools record effects to give us warning before eruptions, changes in eruptive behavior during eruptions, or signals that an eruption is ending. Foremost among these tools is seismic monitoring. The character, size, depth and rate of earthquakes are all important to the interpretation of what is happening belowground. The first inkling of renewed activity at Mount St. Helens began in the early hours of Sept. 23, when a seismic swarm - tens to hundreds of earthquakes over days to a week - began beneath the volcano. This article details the obervations made during the eruptive sequence.
Copper production through smelting generates large volumes of material flows. As copper contained in ore becomes copper contained in concentrate to be fed into the smelting process, it leaves behind an altered landscape, sometimes mine waste, and always mill tailings. Copper concentrate, fluxing materials, fuels, oxygen, recyclables, scrap and water are inputs to the process. Dust (recycled), gases - containing carbon dioxide (CO2) (dissipated) and sulfur dioxide (SO2) (mostly collected, transformed and sold) and slag (discarded or sold) - are among the significant process outputs. This article reports estimates of the flows of these input/output materials for a particular set of smelters studied in some countries.
Maps of the wildland-urban interface (WUI) are both policy tools and powerful visual images. Although the growing number of WUI maps serve similar purposes, this article indicates that WUI maps derived from the same data sets can differ in important ways related to their original intended application. We discuss the use of ancillary data in modifying census data to improve WUI maps and offer a cautionary note about this practice. A comparison of two WUI mapping approaches suggests that no single map is "best" because users' needs vary. The analysts who create maps are responsible for ensuring that users understand their purpose, data, and methods; map users are responsible for paying attention to these features and using each map accordingly. These considerations should apply to any analysis but are especially important to analyses of the WUI on which policy decisions will be made.
The national Integrated Ocean Observing System (IOOS??) is responsible for coordinating a network of people, resources, and technology to disseminate continuous data, information, models, products, and services made throughout our coastal waters, Great Lakes, and the oceans. There are many components of the IOOS-including government, academic, and private entities. This article will focus on some of the federal contributions to IOOS and describe the capabilities of several agency partners.
Anthropogenic effects including river regulation, watershed development, contamination, and fish introductions have substantially affected the majority of freshwater habitats in Europe and North America. This pattern of resource development and degradation is widespread in the tropics, and often little is known about the resources before they are lost. This article describes the freshwater resources of Puerto Rico and identifies factors that threaten conservation of native fishes. The fishes found in freshwater habitats of Puerto Rico represent a moderately diverse assemblage composed of 14 orders, 29 families, and 82 species. There are fewer than 10 species of native peripherally-freshwater fish that require a link to marine systems. Introductions of nonindigenous species have greatly expanded fish diversity in freshwater systems, and native estuarine and marine species (18 families) also commonly enter lowland rivers and brackish lagoons. Environmental alterations, including land use and development, stream channelization, pollution, and the impoundment of rivers, combined with nonnative species introductions threaten the health and sustainability of aquatic resources in Puerto Rico. Six principal areas for attention that are important influences on the current and future status of the freshwater fish resources of Puerto Rico are identified and discussed.
This article is a follow-up on a previous piece in the National Wetlands Newsletter in which we outlined problems associated with a static, local approach to wetland management versus an alternative that proposes a temporal and geomorphic approach (Euliss et al. 2009). We extend that concept by drawing on companion papers recently published in the journal Wetlands (Euliss et al. 2008, Smith et al. 2008). Here we highlight reasons for the failure of many managed wetlands to provide a suite of ecosystem services (e.g., carbon storage, diodiversity, ground-water recharge, contaminant filtering, floodwater storage). Our principal theme is that wetland management is best approached by giving consideration to the hydrogeomorphic processes that maintain productive ecosystems and by removing physical and social impediments to those processes. Traditional management actions are often oriented toward maintaining static conditions in wetlands without considering the temporal cycles that wetlands need to undergo or achieve productivity for specific groups of wildlife, such as waterfowl. Possibly more often, a manager's ability to influence hydrogeomorphic processes is restricted by activities in surrounding watersheds. These could be dams, for example, which do not allow management of flood-pulse processes essential to productivity of riparian systems. In most cases, sediments and nutrients associated with land use in contributing watersheds complicate management of wetlands for a suite of services, including wildlife. Economic or policy forces far-removed from a wetland often interact to prevent occurrence of basic ecosystem processes. Our message is consistent with recommendation of supply-side sustainability of Allen et al. (2002) in which ecosystems are managed "for the system that produces outputs rather than the outputs themselves."
By 2080 the effects of climate change—on heat waves, floods, sea level rise, and drought—could push an additional 600 million people into malnutrition and increase the number of people facing water scarcity by 1.8 billion. The precise impacts will, however, strongly depend on socioeconomic conditions such as local markets and food import dependence. In the near term, two factors are also changing the nature of food security: (1) rapid urbanization, with the proportion of the global population living in urban areas expanding from 13 percent in 1975 to greater than 50 percent at present, and (2) trade and domestic market liberalization since 1993, which has promoted removal of import controls, deregulation of prices, and the loss of preferential markets for many small economies. Over the last two years, the worst drought in decades has devastated eastern Africa. The resulting food-security crisis has affected roughly 13 million people and has reminded us that there is still a long way to go in addressing current climate-related risks. In the face of such profound changes and uncertainties, our approaches to food security must evolve. In this article, we describe four key elements that, in our view, will be essential to the success of efforts to address the linked challenges of food security and climate change.
The article discusses the latest developments in the barite or baryte industry, particularly in the U.S., as of June 2011. It claims that the bulk of barites production in the country comes from four mines in Nevada, including the Big Ledge Mine, the Rossi Mine and the Greystone Mine. It cites that barite is mainly used as a weighting agent in natural gas and oil field drilling muds. Barite is also utilized as filler, extender or weighting agent in such products as paints, plastics and rubber.