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Results for “groundwater aquifer”

Search indexed USGS publications on groundwater, aquifers, geologic maps, mineral resources and earthquakes. Explore source records by subject and place.

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At least 1,027 records · Page 57Linked to original sources
USGS1989

Potentiometric surface of the lower Cape Fear aquifer in the central coastal plain of North Carolina, December 1986

Water level measurements were made in four wells open to the lower Cape Fear aquifer at the end of 1986 to determine the configuration of its potentiometric surface over an area of approximately 4,100 sq mi. Because of the scarcity of data, five earlier measurements were also used to help estimate the position of the potentiometric contours. These were one-time measurements in temporary observation wells. A broad cone of depression has formed in the area between Kinston and New Bern where the potentiometric surface is below sea level and seems likely related to large groundwater withdrawals from the aquifers overlying the lower Cape Fear in that area.

North Carolina↗
USGS2015

The quality of our Nation's waters: Water quality in the Upper Floridan aquifer and overlying surficial aquifers, southeastern United States, 1993-2010

About 10 million people rely on groundwater from the Upper Floridan and surficial aquifers for drinking water. The Upper Floridan aquifer also is of primary importance to the region as a source of water for irrigation and as a source of crystal clear water that discharges to springs and streams providing recreational and tourist destinations and unique aquatic habitats. The reliance of the region on the Upper Floridan aquifer for drinking water and for the tourism and agricultural economies highlights the importance of long-term management to sustain the availability and quality of these resources.

Florida↗
USGS2011

Three-dimensional geologic model of the southeastern Espanola Basin, Santa Fe County, New Mexico

This multimedia model and report show and describe digital three-dimensional faulted surfaces and volumes of lithologic units that confine and constrain the basin-fill aquifers within the Espanola Basin of north-central New Mexico. These aquifers are the primary groundwater resource for the cities of Santa Fe and Espanola, six Pueblo nations, and the surrounding areas. The model presented in this report is a synthesis of geologic information that includes (1) aeromagnetic and gravity data and seismic cross sections; (2) lithologic descriptions, interpretations, and geophysical logs from selected drill holes; (3) geologic maps, geologic cross sections, and interpretations; and (4) mapped faults and interpreted faults from geophysical data. Modeled faults individually or collectively affect the continuity of the rocks that contain the basin aquifers; they also help define the form of this rift basin. Structure, trend, and dip data not previously published were added; these structures are derived from interpretations of geophysical information and recent field observations. Where possible, data were compared and validated and reflect the complex relations of structures in this part of the Rio Grande rift. This interactive geologic framework model can be used as a tool to visually explore and study geologic structures within the Espanola Basin, to show the connectivity of geologic units of high and low permeability between and across faults, and to show approximate dips of the lithologic units. The viewing software can be used to display other data and information, such as drill-hole data, within this geologic framework model in three-dimensional space.

Scientific Investigations Report↗
USGS2016

Groundwater quality data from the National Water-Quality Assessment Project, May 2012 through December 2013

Groundwater-quality data were collected from 748 wells as part of the National Water-Quality Assessment Project of the U.S. Geological Survey National Water-Quality Program from May 2012 through December 2013. The data were collected from four types of well networks: principal aquifer study networks, which assess the quality of groundwater used for public water supply; land-use study networks, which assess land-use effects on shallow groundwater quality; major aquifer study networks, which assess the quality of groundwater used for domestic supply; and enhanced trends networks, which evaluate the time scales during which groundwater quality changes. Groundwater samples were analyzed for a large number of water-quality indicators and constituents, including major ions, nutrients, trace elements, volatile organic compounds, pesticides, and radionuclides. These groundwater quality data are tabulated in this report. Quality-control samples also were collected; data from blank and replicate quality-control samples are included in this report.

Data Series↗
USGS1982

Water resources of Rockland Basin, southeastern Idaho

Rockland basin comprises about 320 sq mi of the Snake River drainage in southeastern Idaho. Mountain ranges bordering the basin are composed predominantly of limestone and are complexly faulted. Major aquifers include Holocene alluvium, Quaternary-Tertiary volcanic rocks, and Tertiary sedimentary rocks. Groundwater occurs under water table conditions except where it is locally confined. Groundwater discharges to springs in the Deep Creek Mountains and maintains perennial streamflow. Near the mouth of Rock Creek, groundwater movement is northward toward the Snake River. Underflow is estimated to be 51,000 acre-ft/yr. Total water yield available to Rockland basin is estimated to be 5.0 in. (85,000 acre-ft) of the estimated 17.3 in. of annual precipitation. Evapotranspiration ranges from 9.9 to 17 in./yr, depending, in part, on altitude of the land surface. An estimated 12,000 acre-ft of surface water and 3,500 acre-ft of groundwater are used annually for irrigation. Less than 100 acre-ft of water is used for public supply, domestic, and stock supplies. East Fork Rock Creek supplies the most surface water for irrigation of agricultural lands. At the present (1980) state of groundwater development in Rockland basin, streams and aquifers are hydraulically connected. Pumping of groundwater in increased quantities from wells near streams will affect groundwater movement and may diminish streamflow. There are no long-term regional water table declines at present. Continued water level monitoring of selected wells may aid in documenting effects of future management practices on the groundwater system.

idaho↗
USGS2013

Hydrogeology and water quality in the Snake River alluvial aquifer at Jackson Hole Airport, Jackson, Wyoming, water years 2011 and 2012

The hydrogeology and water quality of the Snake River alluvial aquifer at the Jackson Hole Airport in northwest Wyoming was studied by the U.S. Geological Survey, in cooperation with the Jackson Hole Airport Board, during water years 2011 and 2012 as part of a followup to a previous baseline study during September 2008 through June 2009. Hydrogeologic conditions were characterized using data collected from 19 Jackson Hole Airport wells. Groundwater levels are summarized in this report and the direction of groundwater flow, hydraulic gradients, and estimated groundwater velocity rates in the Snake River alluvial aquifer underlying the study area are presented. Analytical results of groundwater samples collected from 10 wells during water years 2011 and 2012 are presented and summarized. The water table at Jackson Hole Airport was lowest in early spring and reached its peak in July or August, with an increase of 12.5 to 15.5 feet between April and July 2011. Groundwater flow was predominantly horizontal but generally had the hydraulic potential for downward flow. Groundwater flow within the Snake River alluvial aquifer at the airport was from the northeast to the west-southwest, with horizontal velocities estimated to be about 25 to 68 feet per day. This range of velocities slightly is broader than the range determined in the previous study and likely is due to variability in the local climate. The travel time from the farthest upgradient well to the farthest downgradient well was approximately 52 to 142 days. This estimate only describes the average movement of groundwater, and some solutes may move at a different rate than groundwater through the aquifer. The quality of the water in the alluvial aquifer generally was considered good. Water from the alluvial aquifer was fresh, hard to very hard, and dominated by calcium carbonate. No constituents were detected at concentrations exceeding U.S. Environmental Protection Agency maximum contaminant levels or health advisories; however, reduction and oxidation (redox) measurements indicate oxygen-poor water in many of the wells. Gasoline-range organics, three volatile organic compounds, and triazoles were detected in some groundwater samples. The quality of groundwater in the alluvial aquifer generally was suitable for domestic and other uses; however, dissolved iron and manganese were detected in samples from many of the monitor wells at concentrations exceeding U.S. Environmental Protection Agency secondary maximum contaminant levels. Iron and manganese likely are both natural components of the geologic materials in the area and may have become mobilized in the aquifer because of redox processes. Additionally, measurements of dissolved-oxygen concentrations and analyses of major ions and nutrients indicate reducing conditions exist at 7 of the 10 wells sampled. Measurements of dissolved-oxygen concentrations (less than 0.1 to 9 milligrams per liter) indicated some variability in the oxygen content of the aquifer. Dissolved-oxygen concentrations in samples from 3 of the 10 wells indicated oxic conditions in the aquifer, whereas low dissolved-oxygen concentrations (less than 1 milligram per liter) in samples from 7 wells indicated anoxic conditions. Nutrients were present in low concentrations in all samples collected. Nitrate plus nitrite was detected in samples from 6 of the 10 monitored wells, whereas dissolved ammonia was detected in small concentrations in 8 of the 10 monitored wells. Dissolved organic carbon concentrations generally were low. At least one dissolved organic carbon concentration was quantified by the laboratory in samples from all 10 wells; one of the concentrations was an order of magnitude higher than other detected dissolved organic carbon concentrations, and slightly exceeded the estimated range for natural groundwater. Samples were collected for analyses of dissolved gases, and field analyses of ferrous iron, hydrogen sulfide, and low-level dissolved oxygen were completed to better understand the redox conditions of the alluvial aquifer. Dissolved gas analyses confirmed low concentrations of dissolved oxygen in samples from wells where reducing conditions exist and indicated the presence of methane gas in samples from several wells. Redox processes in the alluvial aquifer were identified using a model designed to use a multiple-lines-of-evidence approach to distinguish reduction processes. Results of redox analyses indicate iron reduction was the dominant redox process; however, the model indicated manganese reduction and methanogenesis also were taking place in the aquifer. Each set of samples collected during this study included analysis of at least two, but often many anthropogenic compounds. During the previous 2008–09 study at Jackson Hole Airport, diesel-range organics were measured in small (estimated) concentrations in several samples. Samples collected from all 10 wells sampled during the 2011–12 study were analyzed for diesel-range organics, and there were no detections; however, several other anthropogenic compounds were detected in groundwater samples during water years 2011—12 that were not detected during the previous 2008–09 study. Gasoline-range organics, benzene, ethylbenzene, and total xylene were each detected (but reported as estimated concentrations) in at least one groundwater sample. These compounds were not detected during the previous study or consistently during this study. Several possible reasons these compounds were not detected consistently include (1) these compounds are present in the aquifer at concentrations near the analytical method detection limit and are difficult to detect, (2) these compounds were not from a persistent source during this study, and (3) these compounds were detected because of contamination introduced during sampling or analysis. During water years 2011–2012, groundwater samples were analyzed for triazoles, specifically benzotriazole, 4-methyl-1H-benzotriazole, and 5-methyl-1H-benzotriazole. Triazoles are anthropogenic compounds often used as an additive in deicing and anti-icing fluids as a corrosion inhibitor, and can be detected at lower laboratory reporting levels than glycols, which previously had not been detected. Two of the three triazoles measured, 4-methyl-1H-benzotriazole and 5-methyl-1H-benzotriazole, were detected at low concentrations in groundwater at 7 of the 10 wells sampled. The detection of triazole compounds in groundwater downgradient from airport operations makes it unlikely there is a natural cause for the high rates of reduction present in many airport monitor wells. It is more likely that aircraft deicers, anti-icers, or pavement deicers have seeped into the groundwater system and caused the reducing conditions.

Wyoming↗
USGS2019

Guidelines and standard procedures for high-frequency groundwater-quality monitoring stations—Design, operation, and record computation

High-frequency water-quality monitoring stations measure and transmit data, often in near real-time, from a wide range of aquatic environments to assess the quality of the Nation’s water resources. Common instrumentation for high-frequency water-quality data collection uses a multi-parameter sonde, which typically has sensors that measure and record water temperature, specific conductance, pH, and dissolved oxygen. Nitrate, turbidity, and fluorescent dissolved organic matter can also be monitored at high frequency. High-frequency groundwater-quality monitoring stations provide high-resolution time-series data to improve understanding of the timing of water-quality changes in the subsurface, especially for aquifer systems with short groundwater-residence times. High-frequency time-series data are used to monitor surface-water to groundwater interaction, quantify contaminant transport rates, and study water-quality variability in relation to variability of precipitation and groundwater pumping rates. High-frequency monitoring for contaminants or their surrogates have the added benefit of providing an early warning to protect valuable or sensitive aquifer resources. High-frequency time-series data also reveal short-term trends in groundwater quality, which may not be identifiable from monthly or annual sampling programs which facilitate the interpretation of decadal conditions. Systematic application of water-quality sonde operational procedures and a standard record-computation process are part of the required quality assurance for producing and documenting complete and accurate high-frequency groundwater-quality monitoring records. To collect quality high-frequency groundwater times-series data, water-quality sondes and sensors require careful field operation, cleaning, and calibration, as well as specific procedures for data computation, evaluation, review, and publication of final records. This report provides guidelines for the use of water-quality sondes and sensors for high-frequency groundwater-quality monitoring and updates the guidance pertaining to standardized records computation procedures for a wide range of groundwater environments. This report builds on previous continuous surface-water-quality monitoring guidance documentation for water temperature, specific conductance, pH, dissolved oxygen, and nitrate. The specific groundwater-quality monitoring guidelines presented in this report address station selection, design, installation, and operations; sonde and sensor inspections and cleaning and calibration methods; troubleshooting procedures; data evaluations, data corrections, and record computations; and record review, approval, and auditing procedures for the groundwater environment.

Techniques and Methods↗
USGS2018

Delineation of the hydrogeologic framework of the Big Sioux aquifer near Sioux Falls, South Dakota, using airborne electromagnetic data

The U.S. Geological Survey, in cooperation with the City of Sioux Falls, South Dakota, began developing a groundwater-flow model of the Big Sioux aquifer in 2014 that will enable the City to make more informed water management decisions, such as delineation of areas of the greatest specific yield, which is crucial for locating municipal wells. Innovative tools are being evaluated as part of this study that can improve the delineation of the hydrogeologic framework of the aquifer for use in development of a groundwater-flow model, and the approach could have transfer value for similar hydrogeologic settings. The first step in developing a groundwater-flow model is determining the hydrogeologic framework (vertical and horizontal extents of the aquifer), which typically is determined by interpreting geologic information from drillers’ logs and surficial geology maps. However, well and borehole data only provide hydrogeologic information for a single location; conversely, nearly continuous geophysical data are collected along flight lines using airborne electromagnetic (AEM) surveys. These electromagnetic data are collected every 3 meters along a flight line (on average) and subsequently can be related to hydrogeologic properties. AEM data, coupled with and constrained by well and borehole data, can substantially improve the accuracy of aquifer hydrogeologic framework delineations and result in better groundwater-flow models. AEM data were acquired using the Resolve frequency-domain AEM system to map the Big Sioux aquifer in the region of the city of Sioux Falls. The survey acquired more than 870 line-kilometers of AEM data over a total area of about 145 square kilometers, primarily over the flood plain of the Big Sioux River between the cities of Dell Rapids and Sioux Falls. The U.S. Geological Survey inverted the survey data to generate resistivity-depth sections that were used in two-dimensional maps and in three-dimensional volumetric visualizations of the Earth resistivity distribution. Contact lines were drawn using a geographic information system to delineate interpreted geologic stratigraphy. The contact lines were converted to points and then interpolated into a raster surface. The methods used to develop elevation and depth maps of the hydrogeologic framework of the Big Sioux aquifer are described herein. The final AEM interpreted aquifer thickness ranged from 0 to 31 meters with an average thickness of 12.8 meters. The estimated total volume of the aquifer was 1,060,000,000 cubic meters based on the assumption that the top of the aquifer is the land-surface elevation. A simple calculation of the volume (length times width times height) of a previous delineation of the aquifer estimated the aquifer volume at 378,000,000 cubic meters; thus, the estimation based on AEM data is more than twice the previous estimate. The depth to top of Sioux Quartzite, which ranged in depth from 0 to 90 meters, also was delineated from the AEM data.

South Dakota↗
USGS2007

Impact of hurricanes storm surges on the groundwater resources

Ocean surges onto coastal lowlands caused by tropical and extra tropical storms, tsunamis, and sea level rise affect all coastal lowlands and present a threat to drinking water resources of many coastal residents. In 2005, two such storms, Hurricanes Katrina and Rita struck the Gulf Coast of the US. Since September 2005, water samples have been collected from water wells impacted by the hurricanes' storm surges along the north shore of Lake Pontchartrain in southeastern Louisiana. The private and public water wells tested were submerged by 0.6-4.5 m of surging saltwater for several hours. The wells' casing and/or the associated plumbing were severely damaged. Water samples were collected to determine if storm surge water inundated the well casing and, if so, its effect on water quality within the shallow aquifers of the Southern Hills Aquifer System. In addition, the samples were used to determine if the impact on water quality may have long-term implication for public health. Laboratory testing for several indicator parameters (Ca/Mg, Cl/Si, chloride, boron, specific conductance and bacteria) indicates that surge water entered water wells' casing and the screened aquifer. Analysis of the groundwater shows a decrease in the Ca/Mg ratio right after the storm and then a return toward pre-Katrina values. Chloride concentrations were elevated right after Katrina and Rita, and then decreased downward toward pre-Katrina values. From September 2005 to June 2006, the wells showed improvement in all the saltwater intrusion indicators. ?? 2007 Springer-Verlag.

Environmental Geology↗
USGS2006

Kinetics of sorption and abiotic oxidation of arsenic(III) by aquifer materials

The fate of arsenic in groundwater depends largely on its interaction with mineral surfaces. We investigated the kinetics of As(III) oxidation by aquifer materials collected from the USGS research site at Cape Cod, MA, USA, by conducting laboratory experiments. Five different solid samples with similar specific surface areas (0.6–0.9 m 2 g −1 ) and reductively extractable iron contents (18–26 μmol m −2 ), but with varying total manganese contents (0.5–3.5 μmol m −2 ) were used. Both dissolved and adsorbed As(III) and As(V) concentrations were measured with time up to 250 h. The As(III) removal rate from solution increased with increasing solid manganese content, suggesting that manganese oxide is responsible for the oxidation of As(III). Under all conditions, dissolved As(V) concentrations were very low. A quantitative model was developed to simulate the extent and kinetics of arsenic transformation by aquifer materials. The model included: (1) reversible rate-limited adsorption of As(III) onto both oxidative and non-oxidative (adsorptive) sites, (2) irreversible rate-limited oxidation of As(III), and (3) equilibrium adsorption of As(V) onto adsorptive sites. Rate constants for these processes, as well as the total oxidative site densities were used as the fitting parameters. The total adsorptive site densities were estimated based on the measured specific surface area of each material. The best fit was provided by considering one fast and one slow site for each adsorptive and oxidative site. The fitting parameters were obtained using the kinetic data for the most reactive aquifer material at different initial As(III) concentrations. Using the same parameters to simulate As(III) and As(V) surface reactions, the model predictions were compared to observations for aquifer materials with different manganese contents. The model simulated the experimental data very well for all materials at all initial As(III) concentrations. The As(V) production rate was related to the concentrations of the free oxidative surface sites and dissolved As(III), as r As ( V ) = k ox ′ [ Mn ( IV ) OH ] [ H 3 AsO 3 ] "> rAs(V)=kox′[Mn(IV)OH][H3AsO3] with apparent second-order rate constants of k ox f ′ = 6.28 × 10 - 1 "> koxf′=6.28×10-1 and k ox s ′ = 1.25 × 10 - 2 M - 1 s - 1 "> koxs′=1.25×10-2M-1s-1 for the fast and the slow oxidative sites, respectively. The As(III) removal rate decreased approximately by half for a pH increase from 4 to 7. The pH dependence was explained using the acid–base behavior of the surface oxidative sites by considering a surface p K a = 6.2 ( I = 0). In the presence of excess surface adsorptive and oxidative sites, phosphate diminished the rate of As(III) removal and As(V) production only slightly due to its interaction with the oxidative sites. The observed As(III) oxidation rate here is consistent with previous observations of As(III) oxidation over short transport distances during field-scale transport experiments. The model developed here may be incorporated into groundwater transport models to predict arsenic speciation and transport in chemically heterogeneous systems.

Geochimica et Cosmochimica Acta↗
USGS2022

Conceptual models of groundwater flow in the Grand Canyon region, Arizona

The conceptual models of groundwater flow outlined herein synthesize what is known and hypothesized about the groundwater-flow systems that discharge to the Grand Canyon of Arizona. These models interpret the hydrogeologic characteristics and hydrologic dynamics of the physical systems into a framework for understanding key aspects of the physical systems as they relate to groundwater flow and contaminant transport. This report describes five individual groundwater-flow systems draining to the Grand Canyon: Kaibab, Uinkaret-Kanab, Marble-Shinumo, Cataract, and Blue Spring. These systems are present in the saturated parts of the lower Paleozoic carbonate section exposed on the walls of the Grand Canyon; specifically, the Mississippian Redwall Limestone down through the Cambrian Muav Limestone of Tonto Group. Together, the systems described in this report compose the regional groundwater-flow system. Local to subregional flow systems in the sedimentary units of the overlying Permian section could provide transport pathways from the land surface to the regional flow system. Despite the potential importance of the local systems, the focus of this report is on the systems present in the lower Paleozoic section because all major springs in the Grand Canyon discharge from those units. The most important hydrogeologic characteristics include system boundaries imposed by major tectonic structures, and the degree to which karstification influences the magnitude and direction of flow in each system. Important hydrologic dynamics include locations and rates of potential groundwater recharge, vertical pathways to the regional aquifer, and the locations, magnitude, geochemical signature, and hydrostratigraphic setting of groundwater discharge from springs. Unknown properties or conditions that represent the greatest uncertainties in our current understanding of the regional groundwater-flow system are identified for additional consideration. Groundwater data are sparse owing to geographic remoteness and extreme depth to water throughout much of the study area. This paucity of information was diminished with the development of a structural contour map of the top and bottom surfaces of the regional aquifer, and a Soil-Water-Balance model that produces spatial distributions of rates of potential recharge. Investigation of the five groundwater-flow systems reveals important, though mostly qualitative, characteristics controlling the rates and directions of groundwater flow. Karstification has produced dissolution-enhanced conduit flow pathways to various degrees in each of the systems. Parts of each system exhibit relative structural uplift or downdropping of the hydrostratigraphic units of the regional aquifer, with some uplifted sections dipping inward toward the Grand Canyon and others dipping outward. The Kaibab groundwater system is archetypical of an uplifted, inward-dipping karst system, whereas the Blue Spring groundwater system and most of the Cataract groundwater system are representative instances of a downdropped or basin karst system. The Uinkaret-Kanab groundwater-flow system is structurally similar to the basin karst systems but karstification has not progressed to nearly the same degree. The Marble-Shinumo groundwater system does not fall cleanly into either category and its boundaries are the most uncertain of all the groundwater systems.

Arizona↗
USGS2021

The occurrence and distribution of strontium in U.S. groundwater

Groundwater samples from 32 principal aquifers across the United States (U.S.) provide a broad spatial scope of the occurrence and distribution of strontium (Sr) and are used to assess environments and factors that influence Sr concentration. Strontium is a common trace element in soils, rocks, and water and is ubiquitous in groundwater with detectable concentrations in 99.8% of samples (n=4,824; median = 225 μg/L). Concentrations in 2.3% of samples exceeded the 4,000 μg/L health-based screening level. The relative importance of controlling factors on Sr concentration are spatially variable and partly dependent on the type of groundwater well. Three case settings illustrate controls on Sr concentration. For drinking-water supply wells, most high concentrations (>4,000 μg/L) were measured in samples from carbonate aquifers that resulted from water-rock interaction with Sr-bearing rocks and minerals. High Sr concentrations from monitoring wells were more common in unconsolidated sand and gravel aquifers in arid or semi-arid setting where shallow groundwater is affected by irrigation and evaporative concentration of dissolved constituents in combination with lithologic or applied Sr sources. Upwelling saline groundwater is also a source of Sr source in some locations. Total dissolved solids concentration is an indicator of high Sr in all settings. An estimated 2.2 million people in the conterminous U.S. are potentially supplied water from public-supply wells with high Sr concentration, ∼86% of whom use carbonate aquifers (with > half supplied by the Floridan aquifer system). An additional 120,000 people are potentially supplied high-Sr-concentration water from domestic wells, >half of whom (∼58%) are in Texas. This study markedly expands the coverage of previous surveys of Sr in groundwater and is of interest given potential adverse human-health effects related to elevated concentrations of Sr and consideration of Sr for drinking-water regulation. Case settings with elevated Sr described for U.S. groundwater are likely indicative of settings and processes affecting Sr concentration in groundwater globally.

Continemtal United States↗
USGS1999

Geochemical heterogeneity of a gasoline-contaminated aquifer

The scale of biogeochemical reactions was studied in a physically and chemically heterogeneous surficial Coastal Plain aquifer contaminated by a gasoline spill. The physical heterogeneity of the aquifer is manifested in two hydrologic units, a shallow local aquifer of perched water and a regional sandy aquifer. Over the studied vertical interval of 21.3 ft (6.5 m), concentrations of reactive species varied by orders of magnitude, and the impact of biodegradation was expressed to widely varying degrees. A thin (3 ft thick) section of the perched-water zone was the most contaminated; total aromatic hydrocarbons were as high as 19.4 mg/l. Hydrocarbons were degraded by microbially mediated reactions that varied over short vertical distances and time. Anaerobic processes dominated within the low-permeability clay unit, whereas in the more permeable sandy layers nitrate reduction and aerobic degradation occurred. Hydrocarbons were more persistent over time in the low-permeability layer due to the limited availability of electron acceptors for degradation. The microbial degradation of hydrocarbons was linked to sulfate and iron reduction in the clay unit and led to alterations in the aquifer solids; electron microscopy revealed the presence of FeS minerals encrusting primary aquifer grains. High concentrations of Fe 2+ in groundwater, up to 34.5 mg/l, persist in kinetic disequilibrium in the presence of elevated H 2 S levels of 1.0 mg/l. Assessment of aquifer heterogeneities and groundwater contamination was possible due to sample discrimination at a scale of approximately 2 ft (∼0.6 m), a much finer resolution than is attempted in many remedial investigations of polluted aquifers. The information obtained in this type of study is essential to the development of models capable of estimating the fate of hydrocarbons at a site scale.

Journal of Contaminant Hydrology↗
USGS2020

Using boosted regression tree models to predict salinity in Mississippi embayment aquifers, central United States

High salinity limits groundwater use in parts of the Mississippi embayment. Machine learning was used to create spatially continuous and three‐dimensional predictions of salinity across drinking‐water aquifers in the embayment. Boosted regression tree (BRT) models, a type of machine learning, were used to predict specific conductance (SC) and chloride (Cl), and total dissolved solids (TDS) was calculated from a correlation with SC. Explanatory variables for BRT models included well location and construction, surficial variables (e.g., soils and land use), and variables extracted from a groundwater‐flow model, including simulated groundwater ages. BRT model fits ( r 2 ) were 0.74 (SC and Cl) and 0.62 (TDS). BRT models provided spatially continuous salinity predictions across surficial and deeper aquifers where discrete water‐quality samples were missing. Uncertainty was smaller where salinity was lower, and models tended to underpredict in areas of highest salinity. Despite this, BRT models were able to capture areas of documented high salinity that exceed the TDS secondary maximum contaminant level for drinking water of 500 mg/L. Variables that served as surrogates for position along groundwater flowpaths were the most important predictors, indicating that much of the control on dissolved solids is related to rock‐water interaction as residence time increases. BRT models additionally support hypotheses of both surficial and deep sources of salinity.

Alabama, Arkansas, Kentucky, Louisiana, Mississipp↗
USGS1996

The combined use of 87Sr/86Sr and carbon and water isotopes to study the hydrochemical interaction between groundwater and lakewater in mantled karst

The hydrochemical interaction between groundwater and lakewater influences the composition of water that percolates downward from the surficial aquifer system through the underlying intermediate confining unit and recharges the Upper Floridan aquifer along highlands in Florida. The 87 Sr/ 86 Sr ratio along with the stable isotopes, D, 18 O, and 13 C were used as tracers to study the interaction between groundwater, lakewater, and aquifer minerals near Lake Barco, a seepage lake in the mantled karst terrane of northern Florida. Upgradient from the lake, the 87 Sr/ 86 Sr ratio of groundwater decreases with depth (mean values of 0.71004, 0.70890, and 0.70852 for water from the surficial aquifer system, intermediate confining unit, and Upper Floridan aquifer, respectively), resulting from the interaction of dilute oxygenated recharge water with aquifer minerals that are less radiogenic with depth. The concentrations of Sr 2+ generally increase with depth, and higher concentrations of Sr 2+ in water from the Upper Floridan aquifer (20–35 μg/L), relative to water from the surficial aquifer system and the intermediate confining unit, result from the dissolution of Sr-bearing calcite and dolomite in the Eocene limestone. Dissolution of calcite [δ 13 C= −1.6permil(‰)] is also indicated by an enriched δ 13 C DIC (-8.8 to -11.4 ‰) in water from the Upper Floridan aquifer, relative to the overlying hydrogeologic units (δ 13 C DIC < -16‰). Groundwater downgradient from Lake Barco was enriched in 18 O and D relative to groundwater upgradient from the lake, indicating mixing of lakewater leakage and groundwater. Downgradient from the lake, the 87 Sr/ 86 Sr ratio of groundwater and aquifer material become less radiogenic and the Sr 2+ concentrations generally increase with depth. However, Sr 2+ concentrations are substantially less than in upgradient groundwaters at similar depths. The lower Sr 2+ concentrations result from the influence of anoxic lakewater leakage on the mobility of Sr 2+ from clays. Based on results from mass-balance modeling, it is probable that cation exchange plays the dominant role in controlling the 87 Sr/ 86 Sr ratio of groundwater, both upgradient and downgradient from Lake Barco. Even though groundwater from the three distinct hydrogeologic units displays considerable variability in Sr concentration and isotopic composition, the dominant processes associated with the mixing of lakewater leakage with groundwater, as well as the effects of mineral-water interaction, can be ascertained by integrating the use of stable and radiogenic isotopic measurements of groundwater, lakewater, and aquifer minerals.

Geochimica et Cosmochimica Acta↗
USGS2010

Use of induced polarization to characterize the hydrogeologic framework of the zone of surface‐water/groundwater exchange at the Hanford 300 Area, WA

An extensive continuous waterborne electrical imaging (CWEI) survey was conducted along the Columbia River corridor adjacent to the U.S. Department of Energy (DOE) Hanford 300 Area, WA, in order to improve the conceptual model for exchange between surface water and U ‐contaminated groundwater. The primary objective was to determine spatial variability in the depth to the Hanford‐Ringold (H‐R) contact, an important lithologic boundary that limits vertical transport of groundwater along the river corridor. Resistivity and induced polarization (IP) measurements were performed along six survey lines parallel to the shore (each greater than 2.5 km in length), with a measurement recorded every 0.5–3.0 m depending on survey speed, resulting in approximately 65,000 measurements. The H‐R contact was clearly resolved in images of the normalized chargeability along the river corridor due to the large contrast in surface area (hence polarizability) of the granular material between the two lithologic units. Cross sections of the lithologic structure along the river corridor reveal a large variation in the thickness of the overlying Hanford unit (the aquifer through which contaminated groundwater discharges to the river) and clearly identify locations along the river corridor where the underlying Ringold unit is exposed to the riverbed. Knowing the distribution of the Hanford and Ringold units along the river corridor substantially improves the conceptual model for the hydrogeologic framework regulating U exchange between groundwater and Columbia River water relative to current models based on projections of data from boreholes on land into the river.

Washington↗
USGS1982

Hydrologic maps of the High Plains aquifer, January 1981, southwestern Kansas

The U.S. Geological Survey furnishes maps depicting saturated thickness of the High Plains aquifer to the Southwest Kansas Groundwater Management District No. 3 through a continuing cooperative agreement. The Groundwater Management District uses the maps to calculated a planned depletion rate of 40 percent of the saturated thickness of the aquifer in 25 years for a 13-county area. Because the information contained on the maps is used in management decisions, the Groundwater Management District is concerned with the accuracy, reliability, and consistency of the hydrologic information that the maps show. A mathematical technique, called kriging, has been used in the form of a computer program to interpolate hydrologic data based on a network of measured values (Karlinger and Skrivan, 1980). The technique has been applied to geohydrologic data in west-central Kansas with good results (Dunlap and Spinazola, 1981). The program calculates the values at the center of each 1-mile section in a predefined region and facilitates contouring of selected values. The kriging technique was used to produce the hydrologic maps in this report.

Kansas↗
USGS1999

Evaluation of prediction intervals for expressing uncertainties in groundwater flow model predictions

We tested the accuracy of 95% individual prediction intervals for hydraulic heads, streamflow gains, and effective transmissivities computed by groundwater models of two Danish aquifers. To compute the intervals, we assumed that each predicted value can be written as the sum of a computed dependent variable and a random error. Testing was accomplished by using a cross‐validation method and by using new field measurements of hydraulic heads and transmissivities that were not used to develop or calibrate the models. The tested null hypotheses are that the coverage probability of the prediction intervals is not significantly smaller than the assumed probability (95%) and that each tail probability is not significantly different from the assumed probability (2.5%). In all cases tested, these hypotheses were accepted at the 5% level of significance. We therefore conclude that for the groundwater models of two real aquifers the individual prediction intervals appear to be accurate.

Water Resources Research↗