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USGS2025

Examining the compositional selectivity of hydrocarbon oxidation products using liquid–liquid extraction and solid-phase extraction techniques

The effect of extraction methods on detecting hydrocarbon oxidation products (HOPs) in groundwater remains unclear. HOPs are polar, water-soluble byproducts of petroleum biodegradation. Our previous work showed that liquid–liquid extraction (LLE), a method commonly used in regulatory monitoring, has a significantly lower extraction efficiency for HOPs compared to solid-phase extraction (SPE). In this study, we evaluate the analytical limitations and compositional selectivity of LLE and SPE using groundwater samples from the Bemidji, MN, crude oil spill site. Optical properties were characterized using excitation–emission matrix spectroscopy (EEMs), and a three-component PARAFAC model was validated, showing consistent trends across both extracts and whole water samples. Ultrahigh-resolution mass spectrometry (UHR-MS) revealed that LLE selectively recovered aliphatic-like compounds but underrepresented more polar oxygenated HOPs. In contrast, SPE methods were more effective at isolating highly oxidized compound classes. These differences were consistent across a gradient of contamination. Overall, the LLE was less precise and less representative of polar HOPs, introducing bias in the characterization of HOPs. This study is the first to quantitatively demonstrate the compositional selectivity and analytical bias of LLE versus SPE for HOPs using combined EEM-PARAFAC and UHR-MS techniques, with implications for long-term monitoring and site assessment protocols.

Environmental Science and Technology↗
USGS1976

Hydrogeology of stratified drift in Farmington, Connecticut: Available data and future needs

The purpose of this report is twofold. The first is to update hydrogeologic information on the major stratified-drift deposits that underlie much of Farmington. The second is to outline data requirements for future ground-water evaluation and management. The scope of the report is limited to the stratified drift, as it is the only aquifer capable of sustaining large withdrawals for public or industrial supply. This aquifer is composed of interbedded layers of gravel, sand, silt and clay. Most of this material was deposited by glacial meltwaters, but locally the aquifer contains some unconsolidated deposits of nonglacial origin. The most extensive stratified-drift deposits are in the valleys of the Farmington and Pequabuck Rivers.(See plate B.) A few small areas of stratified drift near East Farmington Heights and Oakland Gardens are not discussed in this report as their potential for large-scale development is slight.

Connecticut↗
USGS2025

The δ13C signature of dissolved organic and inorganic carbon reveals complex carbon transformations within a salt marsh

Coastal wetlands have high rates of atmospheric CO 2 uptake, which is subsequently respired back to the atmosphere, stored as organic matter within flooded, anoxic soils, or exported to the coastal ocean. Transformation of fixed carbon occurs through a variety of subsurface aerobic and anaerobic microbial processes, and results in a large inventory of dissolved carbon. Carbon source and the roles of aerobic respiration, sulfate reduction, and methane cycling were evaluated within salt marsh peat and the underlying sandy subterranean estuary. There is a large increase in dissolved inorganic carbon (DIC, 7,350 ± 3,900 μmol L −1 ), dissolved organic carbon (DOC, 1,040 ± 1,480 μmol L −1 ) and CH 4 (14.5 ± 33.3 μmol L −1 ) within the marsh porewaters compared to creek waters. Alkalinity production (5,730 ± 2,170 μeq L −1 ) and sulfate removal (1,810 ± 1,970 μmol L −1 ) indicate anaerobic respiration, however, relative contributions from the various decomposition pathways cannot be identified due to overlapping geochemical signatures. The δ 13 C of the DOC (−29.0 ± 3.7‰) and DIC (−11.2 ± 1.1‰) produced within the marsh differed from the bulk soil organic matter δ 13 C (−14.5 ± 0.2‰). We explore a variety of mechanisms that could result in co-occurring depleted δ 13 C-DOC and enriched δ 13 C-DIC compared to the bulk soil organic carbon pool and salt marsh vegetation, including selective mineralization, production of δ 13 C-depleted bacterial biomass, and methane-derived DOC. While important questions remain about carbon cycling pathways, we found evidence of a cryptic methane cycle. Alteration of the δ 13 C of carbon species complicates source attribution in solid and dissolved phases and careful consideration should be used when carbon is partitioned between in situ salt marsh production and external marine and terrestrial sources.

Massachusetts↗
USGS2000

Assessment of potential for natural attenuation of chlorinated ethenes and ethanes in ground water at a petrochemical reclamation site, Harris County, Texas

Redox conditions in the Numerous Sand Channels Zone beneath a petrochemical reclamation site in Harris County, Texas, range from sulfate reducing to methanogenic as indicated by the presence of methane in ground water and the range of molecular hydrogen concentrations. Assessment of the potential for reductive dechlorination using BIOCHLOR as a screening tool indicated conditions favoring anaerobic degradation of chlorinated organic compounds in the Numerous Sand Channels Zone. Evidence supporting reductive dechlorination includes apparently biogenic cis -1,2-dichloroethene; an increased ratio of 1,2-dichloroethane to 1,1,2-trichloroethane downgradient from the assumed contaminant source area; ethene and methane concentrations greater than background concentrations within the area of the contaminant plume; and a positive correlation of the ratio of ethene to vinyl chloride as a function of methane concentrations. The body of evidence presented in this report argues for hydrogenolysis of trichloroethene to cis -1,2-dichloroethene; of 1,1,2-trichloroethane to 1,2-dichloroethane; and of vinyl chloride to ethene within the Numerous Sand Channels Zone. Simulations using BIOCHLOR yielded apparent first-order decay constants for reductive dechlorination in the sequence tetrachloroethene trichloroethene cis -1,2-dichloroethene vinyl chloride ethene within the range of literature values reported for each compound and apparent first-order decay constants for reductive dechlorination in the sequence 1,1,2-trichloroethane 1,2-dichloroethane slightly greater than literature values reported for each compound along the upgradient segment of a simulated ground-water flowpath. Except for vinyl chloride, apparent rates of reductive dechlorination for all simulated species show a marked decrease along the downgradient segment of the simulated ground-water flowpath. Evidence for reductive dechlorination of chlorinated ethenes within the Numerous Sand Channels Zone indicates potential for natural attenuation of chlorinated ethenes. Reductive dechlorination of chlorinated ethanes apparently occurs to a lesser extent, indicating relatively less potential for natural attenuation of chlorinated ethanes. Additional data are needed on the concentrations and distribution of chlorinated ethenes and ethanes in individual fine sand intervals of the Numerous Sand Channels Zone. This information, combined with lower minimum reporting levels for future chloroethane analyses, might enable a more complete and quantitative assessment of the potential for natural attenuation at the site.

Texas↗
USGS2025

Broadband stochastic simulation of earthquake ground motions with multiple strong phases with an application to the 2023 Kahramanmaraş, Turkey (Türkiye), earthquake

Stochastic ground motion simulation models are often less accurate at lower frequencies than at higher frequencies when fitting recorded data unless supplemented by a deterministic forward directivity velocity pulse model. Moreover, time-modulated stochastic models, which adjust ground motion amplitudes over time, typically use functions that fail to capture multiple strong-motion phases. The February 2023 Turkey (Türkiye) earthquake exhibited diverse recordings, including near-fault and far-field motions with pulse-like and non-pulse-like characteristics, along with single and multiple strong-motion phases. To better represent such a diverse set of recordings, this study enhances a fully non-stationary site-based stochastic model without combining it with a deterministic model. Improvements include a new band-pass filter with upper- and lower-frequency limits, which refines the representation of the low-frequency content. Moreover, a time-modulating function that can represent energy arrival in multiple strong phases is introduced. The reference model’s parameters are identified by fitting to the energy content, zero-level crossings, and cumulative counts of positive-minima and negative-maxima of a target accelerogram. This fitting procedure is modified to address the increased number of parameters. These improvements broaden the reference model’s applicability while preserving its simplicity, a key aspect appealing to engineering practitioners. The improved model’s applicability is demonstrated by simulating a dataset from the February 2023 Türkiye earthquake, and the accuracy is tested using a pulse-like Next Generation Attenuation Relationships for Western United States dataset. Validations are performed based on total energy, zero-level crossings, Fourier amplitude spectrum, elastic response spectra, and peak ground motion parameters. Validations are performed schematically in the time and frequency domains and quantitatively using goodness-of-fit scores, various validation-metrics errors, and inter-period correlations. Overall, the improved stochastic model can effectively simulate a set of diverse ground motion recordings, including near-fault pulse-like records, records with multiple strong phases, and far-field motions across a broad frequency range.

Kahramanmaraş↗
USGS2017

Field-trip guide to Mount Hood, Oregon, highlighting eruptive history and hazards

This guidebook describes stops of interest for a geological field trip around Mount Hood volcano. It was developed for the 2017 International Association of Volcanology and Chemistry of the Earth’s Interior (IAVCEI) Scientific Assembly in Portland, Oregon. The intent of this guidebook and accompanying contributions is to provide an overview of Mount Hood, including its chief geologic processes, magmatic system, eruptive history, local tectonics, and hazards, by visiting a variety of readily accessible localities. We also describe coeval, largely monogenetic, volcanoes in the region. Accompanying the field-trip guidebook are separately authored contributions that discuss in detail the Mount Hood magmatic system and its products and behavior (Kent and Koleszar, this volume); Mount Hood earthquakes and their relation to regional tectonics and the volcanic system (Thelen and Moran, this volume); and young surface faults cutting the broader Mount Hood area whose extent has come to light after acquisition of regional light detection and ranging coverage (Madin and others, this volume). The trip makes an approximately 175-mile (280-kilometer) clockwise loop around Mount Hood, starting and ending in Portland. The route heads east on Interstate 84 through the Columbia River Gorge National Scenic Area. The guidebook points out only a few conspicuous features of note in the gorge, but many other guides to the gorge are available. The route continues south on the Mount Hood National Scenic Byway on Oregon Route 35 following Hood River, and returns to Portland on U.S. Highway 26 following Sandy River. The route traverses rocks as old as the early Miocene Eagle Creek Formation and overlying Columbia River Basalt Group of middle Miocene age, but chiefly lava flows and clastic products of arc volcanism of late Miocene to Holocene age.

Oregon↗
USGS2025

High-precision earthquake catalog for Minto Flats fault zone, central Alaska, reveals complex and conjugate faulting

The Minto Flats fault zone (MFFZ) in central Alaska is a left‐lateral strike‐slip fault system situated between the continental‐scale right‐lateral Denali and Kaltag‐Tintina faults. The MFFZ has the potential to generate magnitude 7 earthquakes, and it hosted a magnitude 6 earthquake in 1995. It has also produced exotic events, such as very‐low‐frequency earthquakes and nucleation signals. We use network‐matched filtering and relative earthquake relocation techniques to derive a detailed catalog of earthquake locations for the MFFZ. The catalog spans from August 2014 to December 2019, a time period including 13 temporary seismic stations in the region. Our results provide the most complete catalog for the MFFZ and include deeper events, clusters of shallow seismicity, and a complex and segmented fault structure not observed in the original regional catalog. We document right‐lateral strike‐slip faulting, conjugate to the main northeast‐striking left‐lateral faults of the MFFZ. Below Nenana basin, the relocated seismicity reveals northwest‐dipping left‐lateral faults, supporting the inference that deep crustal active faulting is associated with recent basin deformation.

Alaska↗
USGS2026

Tectonic controls on volcanism and associated hydrothermal activity in a sediment-dominated mid-ocean ridge; Escanaba Trough

Mid-ocean ridges, the Earth's most extensive volcanic system, exhibit unique characteristics in sediment-dominant environments. Thick sediment cover insulates the crust and channels fluid along pathways that can lead to the formation of distinct crustal alteration patterns, exceptionally large mineral deposits, and specialized chemosynthetic ecosystems. This study presents an interdisciplinary investigation into the tectonics of the Escanaba Trough, a heavily sedimented axial valley at the southern Gorda Ridge in the Northeast Pacific Ocean. A primary challenge in such environments is overcoming the masking effect of thick sediments on basement structures that control magmatic and hydrothermal activity. We address this by employing three-dimensional (3D) magnetic modeling of high-resolution near-seafloor magnetic data collected by an autonomous underwater vehicle (AUV). The 2022 surveys with AUV Sentry provided data for 3D magnetic susceptibility models, refining our understanding of the geometry of sub-sediment laccoliths/saucer-shaped sills and hydrothermal alteration. In conjunction with a new 1:100,000 scale lithostratigraphic map, we outline the tectonic controls on the emplacement of Escanaba Trough's three main volcanic centers, characterize the geometry of its spreading segments, and provide volumetric data on the distribution of sub-sediment volcanism in the southern Gorda Ridge.

Escanaba Trough, Pacific Ocean↗
USGS2024

Quantitative risk of earthquake disruption to global copper and rhenium supply

Earthquakes have the potential to substantially affect mining operations, potentially leading to supply chain disruptions and adversely affecting the global economy. This study explores the quantification of earthquake risk to copper and rhenium commodity supply by examining the spatial concentration of high earthquake hazard areas and the commodity-specific mining, smelting, and refining operations across the globe. Because many of the largest facilities are concentrated geographically near the highly seismic regions of South America, East Asia, and the Pacific, there is a potential for cascading effects on the entire supply chain. The analysis indicates that the expected annual disruption of global production is 0.3–1.1 percent for copper mines, 1.8–4.0 percent for smelters, and 1.5–3.3 percent for refineries. Expected annual disruption of global rhenium production capacity is 0.32–1.32 percent. The research highlights that the potential lost revenue from earthquake disruptions is from $315 million to $1.29 billion for copper mining, $1.92 billion to $4.33 billion for copper smelting, $2.06 billion to $4.52 billion for copper refining, and $337,000 to $1.40 million for rhenium production capacity.

Open-File Report↗
USGS2025

U.S. Geological Survey Groundwater Climate Response Network, 2024

As of October 2024, the U.S. Geological Survey (USGS) operated 588 sites across the United States and its territories as part of the Groundwater Climate Response Network (CRN). The CRN is comprised of wells selected to monitor the effects of climate variability, such as droughts, on groundwater levels nationwide. The CRN includes nearly 500 locations with real-time data and more than 100 sites with non-real-time data available to the public on the CRN web mapper and the USGS National Water Dashboard.

General Information Product↗
USGS2025

Estimating the probability of export restrictions to inform mineral criticality

To assess risks associated with advanced technologies’ supply chain disruptions, governmental agencies and others have developed mineral “criticality” assessments, with criticality described using the economic impact and probability of supply chain disruptions. Previous work developed subjective supply risk indicators to approximate this probability, typically combining several factors such as supply diversity and trading partners’ political stability, where indicator weightings can substantially impact results. This work explicitly quantifies export barrier probability using an ensemble of machine learning classifiers, with probability estimates informed by exogenous variables, including prior barrier implementation and global export dominance. Major differences in high-probability countries and commodities are observed across models, but the ensemble method highlights Indonesia, China, Tanzania, and the United States as particularly high risk. The Supplementary Data File provides export barrier probability estimates for each analyzed country-commodity pair, enabling a direct, quantitative, objective contribution to assessing mineral criticality, enhancing risk identification and prioritization for policymakers.

Resources, Conservation, and Recycling↗
USGS2025

AAPG Energy and Minerals Division Tight Oil and Gas Committee Activities and Commodity Report for 2021-2022: Tuscaloosa Marine Shale, Gulf Coast basin, Louisiana and Mississippi

The Upper Cretaceous Tuscaloosa marine shale (TMS) potential production area encompasses 20.4 million acres across central Louisiana (LA), southern Mississippi (MS), southwestern Alabama (AL), and a small southwestern section of the Florida panhandle (Hackley et al., 2018). It remains a minor and largely undeveloped unconventional shale oil play with production from the TMS confined along the east-west LA-MS State boundary (Fig. 1). The mean undiscovered, technically recoverable resources in the TMS are estimated at 1.5 billion barrels of oil and 4.6 trillion cubic feet of gas (Hackley et al., 2018). Geochemical analyses of source rock solvent extracts and oil samples indicate that, in the play area, the TMS is the primary source of shale oil produced from the TMS as well as of accumulated oils in the underlying conventional reservoirs of the lower Tuscaloosa (Hackley et al., 2020). The API gravity of TMS oils ranges from approximately 34 to 46 degrees (Hackley et al., 2020; Croke et al., 2020).

AAPG Wiki↗
USGS1977

Summary of results from electromagnetic and galvanic soundings on Kilauea Iki lava lake, Hawaii

The purpose of this report is to summarize various electrical sounding studies made on the Kilauea Iki lava lake and to present some of the preliminary interpretations that resulted from the measurements. The following discussion is not intended as a complete interpretation, but is intended to summarize the major points made in an invited oral presentation at the American Geophysical Union fall meeting held in San Francisco, Calif. on December 6, 1976. This paper was part of a group of papers dealing with various geophysical studies recently made on the Kilauea Iki lava lake. A general plan map of Kilauea Iki lava lake is shown in figure 1. Electromagnetic (EM) loop-loop soundings, D.C. resistivity soundings, and VLF apparent resistivity measurements were made on the lave lake surface. All of these surveys were made to determine the geoelectric structure of the lava lake and to determine parameters of the molten basaltic lens that exist in the partially solidified lava lake.

Hawaii↗
USGS2024

Utilization of stochastic ground motion simulations for scenario-based performance assessment of geo-structures

Probabilistic seismic performance assessments of engineered structures can be highly sensitive to the seismic input excitation and its variability. In the present study, the scenario-based performance assessment recommended by Federal Emergency Management Agency (FEMA) P-58 guidelines is adopted to estimate seismic fragility of concrete dams for various seismic hazard scenarios. Due to the scarcity of recorded ground motions and thereby their poor representation of uncertainties, stochastic ground motion simulation methods are utilized to obtain the required input excitations. Moreover, to understand the uncertainty in ground motion simulation models, two broadband stochastic simulation models are used to generate input excitations representing six seismic hazard scenarios defined by earthquake magnitude, source-to-site distance, and soil conditions. Optimal intensity measure parameters for each scenario are identified using a systematic procedure that considers criteria such as efficiency, practicality, proficiency, sufficiency, and hazard compatibility. Fragility curves and surfaces are derived using the cloud analysis technique, taking into account various damage measures and limit state functions. The study finds that the derived fragility curves are particularly sensitive to the selection of earthquake scenarios, the choice of records, and the methods used to calculate fragility curves, with less sensitivity observed to different engineering demand parameters. Given this sensitivity, particularly to ground motion selection, the study highlights the necessity of incorporating both model-to-model variability (epistemic uncertainty) and record-to-record variability (aleatory uncertainty), alongside the established material and modeling uncertainties, in the probabilistic seismic assessment.

Reliability Engineering and System Safety (RESS)↗
USGS2025

Estimating the probability of export restrictions to inform mineral criticality

As demand for advanced technologies rises, mineral commodities will increase in geopolitical importance. To assess risks associated with mineral commodity supply chain disruptions, governmental agencies and others have developed "criticality" assessments, with criticality described using the economic impact and probability of supply chain disruptions. In previous work, subjective supply risk indicators were developed to approximate this probability, typically combining several factors such as supply diversity and political stability of trading partners, where indicator weightings can substantially impact results. This work explicitly quantifies trade barrier probability using an ensemble of several machine learning classifiers, with probability estimates informed by exogenous variables such as prior trade barrier implementation and global export dominance. Major differences in the high-probability countries and commodities are observed across models, but the ensemble method highlights Indonesia, China, Tanzania, and the United States as particularly high risk. This approach enables a direct, quantitative, objective approach to assessing trade barrier probability, enhancing risk identification and prioritization for policymakers.

SSRN↗
USGS2026

A geographic dataset of rocky reefs habitat areas of particular concern for the United States West Coast

The United States National Marine Fisheries Service determines “essential fish habitat (EFH)” for federally managed species in coordination with regional fishery management councils, considers adverse effects to those habitats, and provides information to further habitat conservation and enhancement. Identifying discrete subsets of EFH as “habitat areas of particular concern (HAPC)” can help focus conservation, management, and research efforts. In 2006, the Pacific Fishery Management Council designated rocky reefs along the United States (U.S.) West Coast as HAPCs for groundfishes because of their ecological significance, sensitivity to human impacts, and relative rarity. To better understand where rocky reefs occur, we (1) located rocky reef areas that were not included in the 2006 rocky reef dataset, and (2) incorporated best available data into a refined geographic dataset that enables visualization. Our update shows that rocky reefs are distributed throughout the U.S. West Coast continental margin, are patchier than previously known, and comprise 8% of the extent of all data inputs. This updated dataset will inform resource management decisions in coastal and marine environments.

California, Oregon, Washington↗
USGS2025

Over, under, and through: Hydrologic connectivity and the future of coastal landscape salinization

Seawater intrusion (SWI) affects coastal landscapes worldwide. Here we describe the hydrologic pathways through which SWI occurs - over land via storm surge or tidal flooding, under land via groundwater transport, and through watersheds via natural and artificial surface water channels—and how human modifications to those pathways alter patterns of SWI. We present an approach to advance understanding of spatiotemporal patterns of salinization that integrates these hydrologic pathways, their interactions, and how humans modify them. We use examples across the East Coast of the United States that exemplify mechanisms of salinization that have been reported around the planet to illustrate how hydrologic connectivity and human modifications alter patterns of SWI. Finally, we suggest a path for advancing SWI science that includes (a) deploying standardized and well-distributed sensor networks at local to global scales that intentionally track SWI fronts, (b) employing remote sensing and geospatial imaging techniques targeted at integrating above and belowground patterns of SWI, and (c) continuing to develop data analysis and model-data fusion techniques to measure the extent, understand the effects, and predict the future of coastal salinization.

Water Resources Research↗
USGS2026

Earthquake-hazard exposure of residents with potential access and functional needs in the United States

Earthquake response plans and earthquake early warning (EEW) systems designed for general populations may not consider potential access and functional needs (AFN) of individuals with physical, sensory, cognitive, or social limitations. Previous efforts to map the distribution of these populations have focused on social-vulnerability indices that ignore or oversimply these limitations. The descriptive and exploratory analysis summarized in this United States (U.S.) case study addresses this gap by identifying and integrating spatially explicit data for AFN-related residential populations, earthquake hazards, and county and county equivalents for the conterminous U.S., Alaska, Puerto Rico, and Hawaii. We focus on 13 AFN-related attributes that relate to an individual's ability to access information contained in an EEW alert, to understand and process earthquake information or observed ground shaking, and to take self-protective actions based on this information and physical cues of an earthquake. Depending on the demographic attribute, there are millions to tens of millions of U.S. residents with AFN-related attributes in areas considered to have varying likelihoods (2%, 10%, and 50%) of exceedance of a damaging earthquake in the next 50 years. Although these amounts represent low percentages at the national level, the percentage of individuals with AFN-related attributes in many counties and county equivalents substantially exceeds national percentages. No one county, county equivalent, U.S. state, or U.S. territory has the highest percentage of individuals in all AFN-related attributes; therefore, future efforts to increase individual resilience to earthquakes may benefit from understanding the local context of individuals with potential access and functional needs.

International Journal of Disaster Risk Reduction↗