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Reconnaissance for radioactive deposits in the Hyder district, southeastern Alaska, 1949

Radioactivity reconnaissance during 1949 in the Hyder district, southeastern Alaska, revealed that radioactive material is widely distributed on the Mountain View property. However, no uranium deposits of commercial value were found in the restricted parts of the district covered by this investigation. Anomalous radioactivity was detected at a number of localities on the Mountain View property, but the source could not be determined at all sites. The most highly radioactive unconcentrated vein sample collected Sn 1949 contained 0.049 percent equivalent uranium, and the most Intensely radioactive vein-material concentrate (specific gravity greater than 2.89) contained 0.398 percent equivalent uranium. Both samples are from the Skookum tunnel on the Mountain View property. The radioactive material on the properties Investigated in the Hyder district appears to be chiefly uranium which occurs In an unidentified, highly radioactive, opaque mineral and, also, in trace amounts in the sulfides of the vein deposits. Some of the radioactive material, however, occurs as disseminated deposits In the Igneous rocks of the district and, also, to a minor extent as thin secondary coatings on fracture surfaces in veins and rocks.

Alaska↗

Distribution, speciation, and transport of mercury in stream-sediment, stream-water, and fish collected near abandoned mercury mines in southwestern Alaska, USA

Concentrations of total Hg, Hg (II), and methylmercury were measured in stream-sediment, stream-water, and fish collected downstream from abandoned mercury mines in south-western Alaska to evaluate environmental effects to surrounding ecosystems. These mines are found in a broad belt covering several tens of thousands of square kilometers, primarily in the Kuskokwim River basin. Mercury ore is dominantly cinnabar (HgS), but elemental mercury (Hg(o)) is present in ore at one mine and near retorts and in streams at several mine sites. Approximately 1400 t of mercury have been produced from the region, which is approximately 99% of all mercury produced from Alaska. These mines are not presently operating because of low prices and low demand for mercury. Stream-sediment samples collected downstream from the mines contain as much as 5500 ??g/g Hg. Such high Hg concentrations are related to the abundance of cinnabar, which is highly resistant to physical and chemical weathering, and is visible in streams below mine sites. Although total Hg concentrations in the stream-sediment samples collected near mines are high, Hg speciation data indicate that concentrations of Hg (II) are generally less than 5%, and methylmercury concentrations are less than 1% of the total Hg. Stream waters below the mines are neutral to slightly alkaline (pH 6.8-8.4), which is a result of the insolubility of cinnabar and the lack of acid- generating minerals such as pyrite in the deposits. Unfiltered stream-water samples collected below the mines generally contain 500-2500 ng/l Hg; whereas, corresponding stream-water samples filtered through a 0.45-??m membrane contain less than 50 ng/l Hg. These stream-water results indicate that most of the Hg transported downstream from the mines is as finely- suspended material rather than dissolved Hg. Mercury speciation data show that concentrations of Hg (II) and methylmercury in stream-water samples are typically less than 22 ng/l, and generally less than 5% of the total Hg. Muscle samples of fish collected downstream from mines contain as much as 620 ng/g Hg (wet wt.), of which 90-100% is methylmercury. Although these Hg concentrations are several times higher than that in fish collected from regional baseline sites, the concentration of Hg in fish is below the 1000 ng/g action level for edible fish established by the US Food and Drug Administration (FDA). Salmon contain less than 100 ng/g Hg, which are among the lowest Hg contents observed for fish in the study, and well below the FDA action level. (C) 2000 Elsevier Science B.V.

Science of the Total Environment↗

Planning and operations of the Hydrate 01 Stratigraphic Test Well, Prudhoe Bay Unit, Alaska North Slope

The National Energy Technology Laboratory, the Japan Oil, Gas and Metals National Corporation, and the U.S. Geological Survey are leading an effort to conduct an extended gas hydrate production test in northern Alaska. The proposed production test required the drilling of an initial stratigraphic test well (STW) to confirm the geologic conditions of the proposed test site. This well was completed in January 2019 in cooperation with the Prudhoe Bay Unit Working Interest Owners. The Prudhoe Bay Unit Hydrate-01 STW was spudded on 10-December-2018. Downhole data acquisition was completed on 25-December-2018, and the rig was released on 01-January-2019. The Hydrate-01 STW was drilled in two sections, including the surface hole that was drilled to a depth of 2248 ft measured depth (MD) (685 m MD) and cased, and the production hole section that was drilled to a depth of 3558 ft MD (1084 m MD) and also cased. A thermally chilled mineral-oil-based mud was used in the main (production) hole section of the well to maintain wellbore stability and quality of the wellbore acquired data. The primary wellbore data were acquired using logging-while-drilling tools. A sidewall pressure core system was also deployed to gather grain size and other data needed for the design of the future production test wells. In addition to confirming the geologic conditions at the test site, the Hydrate-01 STW was designed to serve as a monitoring well during future field operations. Therefore, two sets of fiber-optic cables, each including a bundled distributed acoustic sensor (DAS) and a distributed temperature sensor (DTS), were clamped to the outside of the production casing and cemented in place. In March 2019, the project team acquired three-dimensional (3D) DAS vertical seismic profiling data in the Hydrate-01 STW. Temperature surveys were also acquired with the DTS as deployed in the Hydrate-01 STW during the completion of the well and nearly continuously since March-2019.

Alaska↗

Geologic interpretation of the gravity anomaly map of the Seward and Blying Sound quadrangles, Alaska

For more than 20 years, gravity surveys have been conducted in the vicinity of Prince William Sound, the epicentral region of the great Alaska earthquake of March 27, 1964. Some of the major regional gravity anomalies were outlined by Thiel, Ostenso, Bonini (1960), and additional anomalies were defined by pre- and post-earthquake gravity studies reported by Barnes and Allen (1965) and Case, Barnes, Plafker, and Robbins (1966). Another gravity anomaly map was prepared by personnel of the U.S. Coast and Geodetic Survey (now the National Oceanic and Atmospheric Administration) (Wood, 1966, p. 131; Rice, 1969, p. 5-20). Anomalies shown by Rice (1969) are broadly similar to those shown by Case, Barnes, Plafker, and Robbins (1966); Rice's interpretations concerned mainly gravity changed related to the earthquake, and the data were not interpreted in terms of regional geology. New gravity stations were established in 1976 as part of the mineral resource appraisal of the Seward and Blying Sound quadrangles. This report incorporates the new data obtained in 1976, reinterprets some anomalies previously discussed by Case, Barnes, Plafker, and Robbins (1966), and interprets other anomalies not previously discussed. Descriptions of the major rock units and structural features are found in the companion report by Tysdal and Case (in press). An interpretation of the aeromagnetic map of the region has been prepared by Case, Tysdal, Hillhouse, and Gromme (1979).

Alaska↗

Petrology and geochemistry of three early Holocene eruptions from Makushin volcano, Alaska

Makushin stratovolcano, Alaska, produced three, highly explosive, andesitic eruptions between ~ 9292 and 6215 yBP. Those eruptions are informally named the CFE (“crater-forming eruption”), Nateekin, and Driftwood Pumice, and they deposited significant tephra fallout in the present-day port of Dutch Harbor and City of Unalaska area. The focus of this study is to examine the geochemistry and petrology of those eruptions to better understand Makushin volcano hazards, andesite petrogenesis and eruption triggering by mafic recharge processes. The CFE, Nateekin, and Driftwood Pumice samples range from basaltic andesite to dacite but are predominantly andesitic (SiO 2 = 55.6 to 63.5 wt%). The CFE deposits are slightly compositionally stratified, with the top CFE samples slightly more mafic (55 to 60 wt% SiO 2 ) than the basal deposits (58 to 60 wt% SiO 2 ). Disequilibrium mineral compositions and textures in the CFE, Nateekin, and Driftwood Pumice samples, combined with two pyroxene thermometry and An-rich plagioclase microlites (An 80 ) found only in the top of the CFE deposits, provide evidence for repetitive mafic recharge triggering those eruptions, consistent with prior studies. We compare the Makushin geochemical data with data from select satellite vents and cones in the Makushin Volcanic Field (MVF) from prior studies, to examine possible genetic relationships. The geochemical data and Rhyolite-MELTS models run at crustal storage conditions (2 kbar, fO 2 = Ni-NiO, and 1.5 and 3.5 wt% H 2 O) indicate that no single parental magma supplies the MVF satellite cones and Makushin volcano. Instead, two component mixing models better fit the MVF geochemical array. Our Makushin results compare well with models of predominantly andesitic volcanoes that require mafic recharge to mobilize the andesites and trigger eruptions.

Alaska↗

Paleolimnology of Lake Tubutulik, an iron-meromictic Eocene Lake, eastern Seward Peninsula, Alaska

Sideritic lacustrine mudstone was found in drill core from a uranium deposit in the Death Valley area in the eastern part of the Seward Peninsula, Alaska. The precursor sediments for this rock were deposited in an unusual “iron-meromictic” Eocene lake, herein named Lake Tubutulik, which occupied part of the Boulder Creek basin, a structural graben that is probably a southern extension of the larger Death Valley basin. The Boulder Creek basin is bounded on the west by granite of the Late Cretaceous Darby Pluton, on the east by Precambrian to Paleozoic metasedimentary rocks. The lake basin was formed by basaltic flows that dammed the river valley of the ancestral Tubutulik River in early Eocene time. Lake Tubutulik contained a nearshore facies of fine-grained organic mud and an offshore facies of laminated sideritic mud. The offshore (profundal) laminated mudstone consists of alternating layers of authigenic siderite and detrital layers containing mostly quartz and clay minerals. Both lacustrine facies contain turbidities. The lacustrine sediments graded laterally into an onshore facies of colluvial and fluvial sandstone, paludal mudstone, and coal. The ancient lake apparently occupied a small deep basin in a tectonically active area of high relief. Meromixus was probably stabilized by reduced iron and bicarbonate dissolved in the monimolimnion. The intensity of meromixus decreased as the lake became shallower from sediment filling. The source of the iron, abundant in the monimolimnion of Lake Tubutulik, was probably the Eocene basalt. Based on carbon isotope analysis of the siderite, the dissolved bicarbonate in the profundal facies was largely inorganic. Sideritic carbon in one sample from the onshore paludal facies has an isotopic signature ( δ 13 C = +16.9) consistent with residual carbon formed during methanogenic fermentation.

Alaska↗

Sulfur and oxygen isotopes in barite deposits of the western Brooks Range, Alaska, and implications for the origin of the Red Dog massive sulfide deposits

Sulfur and oxygen isotope analyses have been obtained for barite samples from the giant stratiform sulfide barite deposits at Red Dog in the western Brooks Range of Alaska, from stratiform barite deposits elsewhere in the Red Dog district, and from stratiform and vein and breccia barite occurrences in the central Brooks Range. Twelve of the 15 deposits studied lie within middle to Upper Mississippian black shale and chert units. The data reveal two different patterns on ?? 34S versus ??18O plots. The first, which is best illustrated by the barite deposit at Anarraaq, shows linear trends with slopes that vary with barite texture. For most samples, ??34S and ??18O values are both higher than the values characteristic of Mississippian marine sulfate. The second pattern, which is evident at the Red Dog deposits, shows no correlation between ??34S and ??18. In most samples, ??18O is below the value for Mississippian marine sulfate. Comparisons with sulfate in modern marine environments suggest a possible model for the mineralizing process. Anarraaq-type barite formed at sea-floor vents where ascending fluids carrying barium and methane encountered sulfate-bearing pore waters or bottom waters. Barite deposition was accompanied by the reduction of sulfate to H2S by means of microbially mediated anaerobic methane oxidation. Red Dog-type barite was formed in a manner similar to Anarraaq-type barite but was over-printed by a massive sulfide-forming event. Red Dog sulfides precipitated where metal-bearing hydrothermal fluids encountered pore waters that had been charged with H2S by anaerobic methane oxidation. Textural and isotopic evidence indicates that the sulfide bodies grew by consuming the available H2S and then by reductively dissolving barite. Dissolution of barite caused barium to be released to higher stratigraphic levels where it was reprecipitated on encountering sulfate. Isotopic evidence is pre sented for a link between methane venting and barite formation and raises the possibility that the coexistence of barite and sulfide at Red Dog, and the occurrence elsewhere in the district of barite-only and sulfide-only deposits, can be explained by a spectrum of vent types in the Mississippian basin analogous to the spectrum that is observed today along the modern continental margins. Authigenic barite formed at some but not all methane seeps, perhaps owing to differences in the barium content of vent fluids, differences in the relative proportion of aqueous fluid and gas emanating from vents, or differences in sulfate availability in local bottom waters. Some barite-forming seeps were later replaced by sulfides (Red Dog deposits) whereas others were not (e.g., Anarraaq barite horizon, Gull Creek, Moil). At sulfide occurrences where there is little evidence of preexisting barite (e.g., Anarraaq, Wulik, Suds), methane venting is indicated by fossils suggestive of chemosynthetic fauna. Mammiform sedimentary structures that are widespread in black chert at the top of the Kuna Formation may represent seeps that supported neither authigenic mineral formation nor chemosynthetic megafauna. ?? 2004 by Economic Geology.

Economic Geology↗

Composition and sources of atmospheric dusts in snow at 3200 meters in the St. Elias Range, southeastern Alaska, USA

Dusts in snow from the accumulation zone in the St. Elias Range appear from their chemical compositions to have come from terranes of rocks of ferromagnesian composition. These dusts, with respect to their composition and to the moderate degree of variation that occurs through a depositional year, are similar those deposited in Greenland. The high portion of the St. Elias Range is isolated from dominance by any local dust source terranes, because of altitude and the extent of the surrounding glacierized and snow-covered region. In Greenland the altitude is typically lower, but local sources are even less likely to dominate the character of the dusts deposited into the ice record there. The similar compositions and moderate compositional variations of dusts from these two places bear on the question of whether the dusts that are transported over long distances by the atmosphere under modern and glacial-period conditions are uniform and representative of a broad regional or even hemispheric background dust. The dusts in the snow were measured by means of a suite of major, minor, and trace rock-forming metals chosen to give information about rock types, their constituent minerals, degree of degradation (weathering), and energies of atmospheric uptake from source. The variations in amounts of rock dust through the year in the St. Elias Range snowpack have no time-stratigraphic correspondence to the also large variations in concentrations of other species that are not constituents of rock-derived dusts, such the anions chloride, sulfate, and nitrate; the highs and lows of the two types of materials are apparently completely independent. The structure revealed by the moderately fine-scale sampling of the present study (≈ 10 increments/y) serves as a background for the interpretation of analysis of ice core samples, in which annual layers may be too compressed to permit analysis of sub-annual samples.

Alaska↗

Seasonal ice and hydrologic controls on dissolved organic carbon and nitrogen concentrations in a boreal-rich fen

[1] Boreal wetland carbon cycling is vulnerable to climate change in part because hydrology and the extent of frozen ground have strong influences on plant and microbial functions. We examined the response of dissolved organic carbon (DOC) and total dissolved nitrogen (TDN) across an experimental manipulation of water table position (both raised and lowered water table treatments) in a boreal-rich fen in interior Alaska. DOC and TDN responses to water table manipulation exhibited an interaction with seasonal ice dynamics. We observed consistently higher DOC and TDN concentrations in the lowered water table treatment (71.7 ± 6.5 and 3.0 ± 0.3 mg−L) than in both the control (55.6 ± 5.1 and 2.3 ± 0.2 mg−L) and raised (49.1 ± 4.3 and 1.9 ± 0.1 mg L−1, respectively) water table treatments. Across all plots, pore water DOC concentrations at 20 cm increased as the depth to water table increased (R2 = 0.43, p < 0.001). DOC concentrations also increased as the seasonal thaw depth increased, with solutes increasing most rapidly in the drained plot (R2 = 0.62, p < 0.001). About half of the TDN pool was composed of dissolved organic N (DON). Inorganic N and DON were both highly correlated with changes in DOC, and their respective constraints to mineralization are discussed. These results demonstrate that a declining water table position and dryer conditions affect thaw depth and peat temperatures, and interactions among these ecosystem properties will likely increase DOC and TDN loading and potential for export in these systems.

Alaska↗

Assessment of marine-derived nutrients in the Copper River Delta, Alaska, using natural abundance of the stable isotopes of nitrogen, sulfur, and carbon

We performed nitrogen, sulfur, and carbon stable isotope analysis (SIA) on maturing and juvenile anadromous sockeye and coho salmon, and periphyton in two Copper River delta watersheds of Alaska to trace salmonderived nutrients during 2003&ndash;2004. Maturing salmon were isotopically enriched relative to alternate freshwater N, S, and C sources as expected, with differences consistent with species trophic level differences, and minor system, sex, and year-to-year differences, enabling use of SIA to trace these salmon-derived nutrients. Periphyton naturally colonized, incubated, and collected using Wildco Periphtyon Samplers in and near spawning sites was 34 S- and 15 N-enriched, as expected, and at all freshwater sites was 13 C-depleted. At nonspawning and coho-only sites, periphyton 34 S and 15 N was generally low. However, 34 S was low enough at some sites to be suggestive of sulfate reduction, complicating the use of S isotopes. Juvenile salmon SIA ranged in values consistent with using production derived from re-mineralization as well as direct utilization, but only by a minority fraction of coho salmon. Dependency on salmon-derived nutrients ranged from relatively high to relatively low, suggesting a space-limited system. No one particular isotope was found to be superior for determining the relative importance of salmon-derived nutrients.

American Fisheries Society Symposium↗

Sulfur- and oxygen-isotopes in sediment-hosted stratiform barite deposits

Sulfur- and oxygen-isotope analyses have been obtained for sediment-hosted stratiform barite deposits in Alaska, Nevada, Mexico, and China to examine the environment of formation of this deposit type. The barite is contained in sedimentary sequences as old as Late Neoproterozoic and as young as Mississippian. If previously published data for other localities are considered, sulfur- and oxygen-isotope data are now available for deposits spanning a host-rock age range of Late Neoproterozoic to Triassic. On a ??34S versus ??18O diagram, many deposits show linear or concave-upward trends that project down toward the isotopic composition of seawater sulfate. The trends suggest that barite formed from seawater sulfate that had been isotopically modified to varying degrees. The ??34S versus ??18O patterns resemble patterns that have been observed in the modern oceans in pore water sulfate and water column sulfate in some anoxic basins. However, the closest isotopic analog is barite mineralization that occurs at fluid seeps on modern continental margins. Thus the data favor genetic models for the deposits in which barium was delivered by seafloor seeps over models in which barium was delivered by sedimentation of pelagic organisms. The isotopic variations within the deposits appear to reflect bacterial sulfate reduction operating at different rates and possibly with different electron donors, oxygen isotope exchange between reduction intermediates and H2O, and sulfate availability. Because they are isotopically heterogeneous, sediment-hosted stratiform barite deposits are of limited value in reconstructing the isotopic composition of ancient seawater sulfate.

Geochimica et Cosmochimica Acta↗

Geologic and Geochronologic Studies of the Early Proterozoic Kanektok Metamorphic Complex of Southwestern Alaska

The Kanektok complex of southwestern Alaska appears to be a rootless terrane of early Proterozoic sedimentary, volcanic, and intrusive rocks which were metamorphosed to amphibolite and granulite facies and later underwent a pervasive late Mesozoic thermal event accompanied by granitic plutonism and greenschist facies metamorphism of overlying sediments. The terrane is structurally complex and exhibits characteristics generally attributed to mantled gneiss domes. U-Th-Pb analyses of zircon and sphene from a core zone granitic orthogneiss indicate that the orthogneiss protolith crystallized about 2.05 b.y. ago and that the protolithic sedimentary, volcanic and granitic intrusive rocks of the core zone were metamorphosed to granulite and amphibolite facies about 1.77 b.y. ago. A Rb-Sr study of 13 whole-rock samples also suggests metamorphism of an early Proterozoic [Paleoproterozoic] protolith at 1.77 Ga, although the data are scattered and difficult to interpret. Seventy-seven conventional 40K/40Ar mineral ages were determined for 58 rocks distributed throughout the outcrop area of the complex. Analysis of the K-Ar data indicate that nearly all of these ages have been totally or partially reset by a pervasive late Mesozoic thermal event accompanied by granitic plutonism and greenschist facies metamorphism. Several biotites gave apparent K-Ar ages over 2 Ga. These ages appear to be controlled by excess radiogenic 40Ar produced by the degassing protolith during the 1.77 Ga metamorphism and incorporated by the biotites when they were at temperatures at which Ar could diffuse through the lattice. Five amphibolites yielded apparent Precambrian 40K/40Ar hornblende ages. There is no evidence that these hornblende ages have been increased by excess argon. The oldest 40K/40Ar hornblende age of 1.77 Ga is identical to the sphene 207Pb/206Pb orthogneiss age and to the Rb-Sr 'isochron' age for six of the 13 whole-rock samples. The younger hornblende ages are interpreted as having been partially reset during the late Mesozoic thermal event. 40Ar/39Ar incremental heating experiments suggest metamorphism occurred at least 1.2 b.y. ago but do not exhibit high temperature plateau ages significantly older than the 40Ar/39Ar total fusion ages of these samples. The age spectra are much more uniform than expected from a terrane with such a complex thermal history, perhaps caused by the small grain size of the samples which may possibly be less than the effective Ar diffusion radii of the analyzed hornblendes.

Open-File Report↗

Controls on methane released through ebullition in peatlands affected by permafrost degradation

Permafrost thaw in peat plateaus leads to the flooding of surface soils and the formation of collapse scar bogs, which have the potential to be large emitters of methane (CH 4 ) from surface peat as well as deeper, previously frozen, permafrost carbon (C). We used a network of bubble traps, permanently installed 20&thinsp;cm and 60&thinsp;cm beneath the moss surface, to examine controls on ebullition from three collapse bogs in interior Alaska. Overall, ebullition was dominated by episodic events that were associated with changes in atmospheric pressure, and ebullition was mainly a surface process regulated by both seasonal ice dynamics and plant phenology. The majority (>90%) of ebullition occurred in surface peat layers, with little bubble production in deeper peat. During periods of peak plant biomass, bubbles contained acetate-derived CH 4 dominated (>90%) by modern C fixed from the atmosphere following permafrost thaw. Post-senescence, the contribution of CH 4 derived from thawing permafrost C was more variable and accounted for up to 22% (on average 7%), in the most recently thawed site. Thus, the formation of thermokarst features resulting from permafrost thaw in peatlands stimulates ebullition and CH 4 release both by creating flooded surface conditions conducive to CH 4 production and bubbling as well as by exposing thawing permafrost C to mineralization.

Alaska↗

The Kanuti ophiolite, Alaska

The Kanuti ophiolite is a mafic-ultramafic thrust sheet of probable Jurassic age, formerly considered to be the upper part of the Yukon-Koyukuk ophiolite belt (Angayucham terrane). It is here called the Kanuti ophiolite after the Kanuti River region on the southeastern flank of the Yukon-Koyukuk Basin. The thrust sheet crops out discontinuously for a distance of more than 900 km along the northern and southeastern margins of the basin. It is probably correlative with similar ophiolite thrust sheets to the north in the western Brooks Range and to the south in the Ruby geanticline. Technically, the ophiolite is considered to be the Kanuti thrust panel of the Angayucham-Totzitna terrane. The Kanuti consistently overlies another extensive thrust sheet, consisting mostly of pillow basalt and radiolarian chert of Devonian to Jurassic age (Narvak thrust panel). This sheet is thrust over a third sheet consisting of probable Devonian phyllite and metagraywacke, which is in turn thrust over older metamorphic rocks (Slate Creek thrust panel). The Kanuti ophiolite is a partial ophiolite that consists of a lower residual mantle suite and an upper magmatic suite, but dikes, extrusives, and sediments are absent. The residual mantle suite is composed of harzburgite and dunite with refractory mineral compositions. The harzburgite is attributed to partial melting and extraction of basaltic magma; residual dunite is attributed to partial melting or to reaction of orthopyroxene out of harzburgite in contact with ascending melt diapirs. The magmatic suite consists of layered ultramafic and gabbroic rocks, containing minerals having limited iron enrichment. The absence of large volumes of magmatic rocks intermediate in composition between cumulus ultramafics and evolved gabbros favors periodic introduction of magma, rather than closed system fractional crystallization. The ultramafic rocks of both the residual mantle and magmatic suites are tectonites, which have undergone high-temperature deformation involving isoclinal folding on all scales and related syntectonic recrystallization. The olivine fabric is consistent with the glide system {0kl} [100], which has been produced experimentally at 800°–1190°C at 20 kbar. Olivine Z axes and subparallel isoclinal fold axes have consistent, northeast trends throughout the Kanuti region (>100 km NE-SW) and may be close to the original upper mantle flow direction, despite later low-angle thrust faulting. The order of crystallization in the cumulus ultramafic rocks of the magmatic suite is olivine, clinopyroxene, plagioclase, and orthopyroxene. The high Mg numbers of clinopyroxene (0.85–0.93) coexisting with olivine suggest that the cumulus ultramafic rocks crystallized at relatively high pressures (>10 kbar). The effects of parental magma composition cannot be evaluated, but the small difference in Mg numbers of coexisting olivine and clinopyroxene in the cumulus ultramafic rocks and in residual harzburgite suggests that regardless of absolute pressures, the pressure difference between the melting that produced the basalt magma and the initial fractional crystallization of the magma is small. Because of the limited range in rock types in the ophiolite, the tectonic environment cannot be interpreted unambiguously. However, the structural and petrological data are best reconciled with an origin in a volcanic arc tectonic setting.

Journal of Geophysical Research Solid Earth↗

High-alumina kaolinitic clay in the United States, exclusive of Alaska and Hawaii

The general distribution of high-alumina kaolinitic clay deposits in the United States (exclusive of Alaska and Hawaii) is shown on the accompanying map. The locations of mines, pits, and prospects are shown by appropriate symbols. Certain clay-bearing areas are shown by patterns that designate the geologic age of the deposits. The locations are numbered consecutively by states and are keyed to an index which lists the name of the deposit, county, and principal references. Only significant references on the size, quality, and geologic occurrence of deposits are listed. Some of the data for the map and index were compiled by John W. Hosterman and the late Leona Boardman.

Mineral Investigations Resource Map↗

Genesis of a zoned granite stock, Seward Peninsula, Alaska

A composite epizonal stock of biotite granite has intruded a diverse assemblage of metamorphic rocks in the Serpentine Hot Springs area of north-central Seward Peninsula, Alaska. The metamorphic rocks include amphibolite-facies orthogneiss and paragneiss, greenschist-facies fine-grained siliceous and graphitic metasediments, and a variety of carbonate rocks. Lithologic units within the metamorphic terrane trend generally north-northeast and dip moderately toward the southeast. Thrust faults locally juxtapose lithologic units in the metamorphic assemblage, and normal faults displace both the metamorphic rocks and some parts of the granite stock. The gneisses and graphitic metasediments are believed to be late Precambrian in age, but the carbonate rocks are in part Paleozoic. Dating by the potassium-argon method indicates that the granite stock is Late Cretaceous. The stock has sharp discordant contacts, beyond which is a well-developed thermal aureole with rocks of hornblende hornfels facies. The average mode of the granite is 29 percent plagioclase, 31 percent quartz, 36 percent K-feldspar, and 4 percent biotite. Accessory minerals include apatite, magnetite, sphene, allanite, and zircon. Late-stage or deuteric minerals include muscovite, fluorite, tourmaline, quartz, and albite. The stock is a zoned complex containing rocks with several textural facies that are present in four partly concentric zones. Zone 1 is a discontinuous border unit, containing fine- to coarse-grained biotite granite, that grades inward into zone 2. Zone 2 consists of porphyritic biotite granite with oriented phenocrysts of pinkish-gray microcline in a coarse-grained equigranular groundmass of plagioclase, quartz, and biotite. It is in sharp, concordant to discordant contact with rocks of zone 3. Zone 3 consists of seriate-textured biotite granite that has been intruded by bodies of porphyritic biotite granite containing phenocrysts of plagioclase, K-feldspar, quartz, and biotite in an aplitic groundmass. Flow structures, pegmatite and aplite segregations, and miarolitic cavities are common in the seriate-textured granite. Zone 4, which forms the central part of the complex, consists of fine- to medium-grained biotite granite and locally developed leucogranite. Small miarolitic cavities are common within it. Eight textural facies have been defined within the complex, and mineralogic, petrographic, modal, and chemical variations are broadly systematic within the facies sequence. Study of these variations shows that the gradational facies of zones l and 2 systematically shift toward more mafic compositions inward within the complex. Seriate-textured rocks of zone 3 are similar in composition to those of zone 2, but porphyritic rocks of zone 3 and rocks of zone 4 mark shifts to more felsic compositions. These late-crystallizing felsic rocks are products of an interior residual magma system. This system was enriched in water and certain trace elements including tin, lithium, niobium, lead, and zinc. The complex as a whole has higher concentrations of these elements than many other granites. The nature of this geochemical specialization is particularly well demonstrated by the trace-element composition of biotite. The crystallization history of the pluton was complex. The available data suggest that this history could have included: (1) chilling and metasomatic alteration adjacent to the contact, (2) in-situ crystallization in several marginal facies accompanied by some transfer of residual constituents toward interior parts of the pluton, (3) slight upward displacement of magma that was subjacent to the crystallized walls, accompanied by disequilibrium crystallization and local vapor saturation, (4) upward displacement of part of the residual water-rich interior magma, accompanied by rapid loss of a separated vapor phase, and (5) displacement of the margins of the pluton by normal faults, accompanied by loss of an exsolved vapor phase from th

Open-File Report↗

Geology and ore deposits of the central York Mountains, western Seward Peninsula, Alaska

In the central York Mountains, carbonate rocks of Lower and Middle Ordovician age and aggregating at least 8,000 feet thick are thrust northward over slate and argillaceous limestone of pre-Ordovician age which were intruded by gabbro in pre-Ordovician time. Normal faults of four distinct systems cut the thrust plates, and in Late Cretaceous time, stocks of biotite granite, abnormally rich in beryllium, tin, boron and certain other trace elements, pierced the thrust plates. In part following the intrusion of the granites, a strong set of normal faults developed striking N. 60°-85° E. through the central York Mountains and locally these faults cut the granites. Dikes of granite, rhyolite porphyry, and lamprophyre were injected into some of these faults, the lamprophyres being younger. Trace elements in the lamprophyres prove they are mafic rocks probably derived from the lama, and that they cannot be related genetically to granite. Shortly after the intrusion of lamprophyre dikes, ore deposits of tin, beryllium, and fluorite were formed from solutions probably derived from deeply-buried hot granite where the granite was ruptured by normal faults. Ore shoots were localized beneath thrust faults where the faults are intruded by dikes, and a major ore-bearing structure, the Rapid River fault, is mineralized for half its length for a distance of eight miles. The tin deposits contain cassiterite and stannite in topaz greisen with abundant sulfides of copper, lead, zinc, and iron, as well as wolframite. The beryllium deposits contain fluorite, chrysoberyl, diaspore, muscovite, and tourmaline, with trace to small amounts of euclase, bertrandite, helvite, phenikite(?), todorokite and hematite. Beryl occurs sparingly in late veins of quartz and fluorite. Chrysoberyl is the earliest and commonest beryllium mineral, followed by euclase and bertrandite, and then phenakite(?) and beryl. Helvite is restricted to banded skarns near granite, and which consist of magnetite and fluorite. Throughout the district, a strong zonation is displayed from tin deposits in greisen through transitional veins of sulfide minerals with fluorite and chrysoberyl to fluorite-beryllium deposits and thence to barren veins of silica and fluorite with trace amounts of beryllium. This zonal arrangement of deposits probably will be found elsewhere in the world where greisen tin deposits occur in carbonate rocks. The geochemical cycle of the trace elements Be, Sn, W, B, Li, Cu, Pb, Zn and Nb shows that these elements were enriched in the biotite granites and were strongly fractionated among the minerals of granites. Fran the granites, these rare elements moved outward into contact rocks and ore deposits. During the supergene cycle, clear geochemical anomalies were formed in stream sediments, soils and plants near ore deposits, and geochemical prospecting led to the discovery of the beryllium lodes. With the possible exception of zinc and niobium, the rare elements that are associated in the rocks and ores remain associated in the supergene processes. Fixation of zinc in clay soil and tundra plants may account for the relatively small amount of zinc in strew sediments. Datable Pleistocene events in the York Mountains begin with the Yarmouth Interglaciation when the York Terrace, a wide marine platform, was cut. In Illinoian time, the York Terrace was uplifted almost 400 feet, and during the Sangamon Interglaciation a second marine platform (Lost River Terrace) was cut and is not deformed. During Wisconsin time the widespread York Glaciation was followed by the more restricted Mint River Glaciation. Because uplift of the York Terrace extended into the Bering Strait, it is probable that prior to the uplift in Illinoian time the Bering Strait was a seaway and a barrier to land migration rather than a land bridge.

Alaska↗

Geology of the Alaska-Juneau lode system, Alaska

The Alaska-Juneau lode system for many years was one of the worlds leading gold-producing areas. Total production from the years 1893 to 1946 has amounted to about 94 million dollars, with principal values in contained gold but with some silver and lead values. The principal mine is the Alaska-Juneau mine, from which the lode system takes its name. The lode system is a part of a larger gold-bearing belt, generally referred to as the Juneau gold belt, along the western border of the Coast Range batholith. The rocks of the Alaska-Juneau lode system consist of a monoclinal sequence of steeply northeasterly dipping volcanic, state, and schist rocks, all of which have been metamorphosed by dynamic and thermal processes attendant with the intrusion of the Coast Range batholith. The rocks form a series of belts that trend northwest parallel to the Coast Range. In addition to the Coast Range batholith lying a mile to the east of the lode system, there are numerous smaller intrusives, all of which are sill-like in form and are thus conformable to the regional structure. The bedded rocks are Mesozoic in age; the Coast Range batholith is Upper Jurassic and Lower Cretaceous in age. Some of the smaller intrusives pre-date the batholith, others post-date it. All of the rocks are cut by steeply dipping faults. The Alaska-Juneau lode system is confined exclusively to the footwall portion of the Perseverance slate band. The slate band is composed of black slate and black phyllite with lesser amounts of thin-bedded quartzite. Intrusive into the slate band are many sill-like bodies of rocks generally referred to as meta-gabbro. The gold deposits of the lode system are found both within the slate rocks and the meta-gabbro rocks, and particularly in those places where meta-gabbro bodies interfinger with slate. Thus the ore bodies are found in and near the terminations of meta-gabbro bodies. The ore bodies are quartz stringer-lodes composed of a great number of quartz veins from 6 inches to 3 feet wide and extending along their strike and dip for several tens to hundreds of feet. In addition to quartz, the only other vein gangue mineral is ankerite. It occurs in small amounts along the borders of the quartz veins. Metallic vein minerals, in addition to native gold, are, in order of decreasing abundance, pyrrhotite, galena, sphalerite, and arsenopyrite. In the aggregate the metallic minerals comprise only 1 to 2 percent of the total amount of vein material. The wall rock, particularly the meta-gabbro, was profoundly altered by the vein-forming processes. The principal effects on the meta-gabbro were the addition of large amounts of soda, potash, titanium, carbon dioxide, and phosphorous, and the removal of considerable quantities of iron, magnesia, lime, and combined water. Silica also may have been decreased. The mineralogical changes involved in the alteration were the development of biotite and ankerite at the expense of original hornblende and feldspar, resulting in a brown-colored biotite- and ankerite-rich rock. The slates are relatively unaffected by the vein-forming processes. Because of their small size, relatively low grade, and discontinuity, no attempt has been made to mine any individual vein. The prevailing practice has been to mine large blocks of ground by a system of modified block-caving, followed by hand sorting to remove the barren country rock from the gold-bearing quartz prior to milling.

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