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Radiogenic strontium- and uranium-isotope tracers of water-rock interactions and hydrothermal flow in the Upper Geyser Basin, Yellowstone Plateau Volcanic Field, USA

Natural radiogenic isotopes (primarily 87 Sr/ 86 Sr) from hot springs in the Upper Geyser Basin of the Yellowstone Plateau volcanic field and associated rocks were used to evaluate groundwater flow patterns, water-rock reactions, and the extent of mixing between various groundwater sources. Thermal waters have very low uranium concentrations and 234 U/ 238 U activity ratios near 1.0, which limit their utility as tracers in this reducing setting. Thermal waters have higher Sr concentrations (<22 ng/g) and a wide range of 87 Sr/ 86 Sr values that vary both temporally at individual discharge sites and between adjacent springs, indicating that conduits tap different subsurface reservoirs to varying degrees. Sr from local rhyolites have 87 Sr/ 86 Sr compositions that bound the range of values observed in groundwater throughout the basin. Non-boiling springs on the west flank of the basin discharge water with low 87 Sr/ 86 Sr consistent with flow through young volcanic rocks exposed at the surface. Boiling springs in the central basin have higher 87 Sr/ 86 Sr values reflecting interactions with older, more radiogenic volcanic rocks. Variability in upwelling thermal waters requires mixing with a low 87 Sr/ 86 Sr component derived from young lava or glacial sediments, or more likely, from deeper sources of hot groundwater circulating through buried Lava Creek Tuff having intermediate 87 Sr/ 86 Sr. Isotope data constrain basin-wide output of thermal water to 110–140 kg·s −1 . Results underscore the utility of radiogenic Sr isotopes as valuable tracers of hydrothermal flow patterns and improve the understanding of temperature-dependent water-rock reactions in one of the largest continental hydrothermal systems on Earth.

Wyoming

Computing flow-field distortion coefficients from well-construction and formation properties

Direct measurements of groundwater velocity made with borehole flowmeters in screened wells must be compensated for the effects of flow-field distortion (also known as borehole acceleration). A theoretical equation developed by Drost et al. (1968) and simple inputs describing hydraulic properties of well construction and geologic formation were programmed into an Excel workbook to facilitate computation by groundwater-flowmeter users. Tables describing the physical and hydraulic properties for well constructions and gravel pack media are provided with an example to facilitate use of the workbook. Groundwater flowlines converge or diverge as they pass from a geologic formation, through a gravel pack and well screen. The extent of flowline convergence or divergence and the value of the flow-field distortion coefficient is related to the relative changes in hydraulic conductivity of the well screen, gravel pack, and geologic formation. Convergence or divergence is accompanied by acceleration or deceleration of groundwater. Direct measurements of groundwater velocity at the center of the monitoring well can be adjusted to provide a more accurate estimate of velocity in the formation by applying a correction for flow-field distortion. Variables required to compute the flow-field distortion coefficient include the hydraulic conductivity of the gravel pack, well screen, and the geologic formation surrounding the well screen; the borehole radius, and the inside radius and outside radius of the well screen.

Groundwater

Streamflow, water quality, and constituent loads and yields, Scituate Reservoir drainage area, Rhode Island, water year 2023

As part of a long-term cooperative program to monitor water quality within the Scituate Reservoir drainage area, the U.S. Geological Survey, in cooperation with Providence Water (formerly the Providence Water Supply Board), collected streamflow and water-quality data in tributaries to the Scituate Reservoir, Rhode Island. Streamflow and concentrations of chloride and sodium estimated from records of specific conductance for 16 tributaries were used to calculate loads of chloride and sodium during water year 2023 (October 1, 2022, through September 30, 2023). Water-quality samples were collected by Providence Water at 38 sampling stations on tributaries to the Scituate Reservoir during water year 2023. These water-quality data are summarized by using values of central tendency and are used, in combination with measured (or estimated) streamflows, to calculate loads and yields of selected water-quality constituents for water year 2023. Annual mean streamflows for monitoring stations in this study ranged from 0.47 to 34.4 cubic feet per second during water year 2023. At the 16 continuous-record streamgages, tributaries transported about 3,000 metric tons of chloride and 1,900 metric tons of sodium to the Scituate Reservoir; annual chloride yields for the tributaries ranged from 19 to 200 metric tons per square mile, and annual sodium yields ranged from 13 to 120 metric tons per square mile. At the stations where water-quality samples were collected by Providence Water, the medians of the median daily loads were 65,000 million colony forming units per day for coliform bacteria, 870 million colony forming units per day for Escherichia coli , 200 kilograms per day for chloride, 8.2 grams per day as nitrogen for nitrite, 520 grams per day as nitrogen for nitrate, and 300 grams per day as orthophosphate for phosphate. The medians of the median yields were 25,000 million colony forming units per day per square mile for coliform bacteria, 600 million colony forming units per day per square mile for Escherichia coli , 65 kilograms per day per square mile for chloride, 4.6 grams per day per square mile as nitrogen for nitrite, 180 grams per day per square mile as nitrogen for nitrate, and 180 grams per day per square mile as orthophosphate for phosphate.

Rhode Island

Tracking diagenetic alteration of magnetic susceptibility in thrust ridge and slope basin sediments of the Cascadia margin (ODP Sites 1249 and 1252; IODP Site U1325)

We investigated sediment core records from the Cascadia Margin (Ocean Drilling Program Sites 1249 and 1252 at Hydrate Ridge; Integrated Ocean Drilling Program Site U1325 offshore Vancouver Island) using a Zr/Rb heavy mineral proxy from X-ray fluorescence (XRF) core scanning to identify intervals of primary detrital magnetic susceptibility (κ) and predict intervals where diagenesis caused magnetite dissolution by hydrogen sulfide. We also measured total sulfur (TS) content, grain size distributions, total organic carbon (TOC) content, and the magnetic mineral assemblage to further constrain the role of diagenesis on κ. Understanding how κ can be used to better characterize the varied effects of detrital and diagenetic signals in marine settings is important for understanding biogeochemical cycling and records of paleoenvironmental change. The upper 100 m of slope basin Site 1252 contains multiple intervals (> 90 m total) of decreased κ correlated with elevated TS content, consistent with dissolution of magnetite and precipitation of pyrite, iron monosulfides, and/or elemental sulfur. Similarly at the other slope basin site, Site U1325, κ is lower and TS is elevated in the interval between 24 and 51 mbsf, due to sulfide formation. At both slope basin sites, these low κ intervals correspond with high TOC, suggesting the possibility that organoclastic sulfate reduction (OSR) is likely a major driver of diagenetic alteration of κ at these sites. High TS:TOC ratios at Site U1325 suggests anaerobic oxidation of methane (AOM) during sulfate-methane transition zone (SMTZ) migration may have contributed to alteration of κ. In contrast, within the upper 90 m of Site 1249, a methane seep site at the summit of Hydrate Ridge, κ is almost entirely altered by diagenetic processes, with much of the low κ explained by a high degree of iron sulfide formation, while some intervals are affected by precipitation of magnetic iron sulfides that maintain or even increase κ. The presence of abundant methane seepage and gas hydrate as well as chemosynthetic seafloor fauna at this site, suggests that sulfide is released to the water column and AOM, rather than OSR, drives diagenetic alteration of κ at this site. Overall, the slope basin sites show episodic variation of κ that is influenced by TOC content, likely driven by changes in marine primary productivity and sedimentation rate, while the seep site shows consistently altered κ with lower TS content and no correlation with TOC. Methane seep environments likely experience loss of hydrogen sulfide to the water column and oxidation of hydrogen sulfide by seafloor seep fauna, which limits the amount of solid phase sulfur (pyrite, iron monosulfides, elemental sulfur) that can be precipitated within the sediments. In contrast, the migration of a buried SMTZ at slope basin sites results in enhanced sulfur precipitation within the sediments. This integrated magnetic and geochemical approach reveals the diagenetic production pathway and residence time of sulfide with the sediment column ultimately controls the style and degree of diagenetic loss of κ in marine sediments. This approach works best in environments with unaltered reference intervals/sites, consistent magnetic mineralogy, and clay-to-silt grain sizes.

Cascadia margin, Pacific Ocean

Hydrogeology, water budget, and simulated groundwater availability in the Salt Fork Arkansas River and Chikaskia River alluvial aquifers, northern Oklahoma, 1980–2020

The 1973 Oklahoma Groundwater Law (Oklahoma Statute §82–1020.5) requires that the Oklahoma Water Resources Board conduct hydrologic investigations of the State’s aquifers to determine the maximum annual yield for each groundwater basin. The U.S. Geological Survey, in cooperation with the Oklahoma Water Resources Board, conducted an updated hydrologic investigation of the Salt Fork Arkansas River and Chikaskia River alluvial aquifers in northern Oklahoma for the study period spanning 1980–2020 and evaluated the simulated effects of potential groundwater withdrawals on groundwater flow and availability in the Salt Fork Arkansas River alluvial aquifer. A hydrogeologic framework and conceptual model were developed to guide the development of a numerical model. Three groundwater-availability scenarios were evaluated by using the calibrated numerical model, which was focused on the Salt Fork Arkansas River alluvial aquifer. These scenarios were used to (1) estimate equal-proportionate-share groundwater withdrawal rates, (2) quantify the potential effects of projected well withdrawals on groundwater storage over a 50-year period, and (3) simulate the potential effects of a hypothetical 10-year drought. The 20-, 40-, and 50-year equal-proportionate-share groundwater withdrawal rates for the Salt Fork Arkansas River alluvial aquifer under normal recharge conditions were about 0.63, 0.58, and 0.57 acre-foot per acre per year, respectively. Projected 50-year groundwater withdrawal scenarios were used to simulate the effects of modified well withdrawal rates. Because well withdrawals were less than 2 percent of the calibrated numerical-model water budget, changes to the well groundwater withdrawal rates had little effect on simulated Salt Fork Arkansas River base flows and groundwater storage in the Salt Fork Arkansas River alluvial aquifer. A hypothetical 10-year drought scenario was used to simulate the potential effects of a prolonged period of reduced recharge on groundwater storage. Groundwater storage at the end of the hypothetical drought period was 14.5 percent less than the groundwater storage of the calibrated numerical model without the simulated drought.

Oklahoma

Geology and geochemistry of Jurassic plutonic rocks, Baboquivari Mountains, south-central Arizona

Among the plutons of the Jurassic magmatic arc segment in southern Arizona, northern Sonora, and southern California, two distinctive rock types dominate, occurring together in numerous mountain ranges: porphyritic, titanite-bearing hornblende-biotite granodiorite; and biotite leucogranite. These characteristic rocks are particularly well preserved and well exposed around Kitt Peak, in the Baboquivari Mountains, southern Arizona. The Middle to early Late Jurassic Kitt Peak Plutonic Suite (KPPS) comprises three units: Aguirre Peak Quartz Diorite (APQD;<170 Ma, >=165 Ma, U-Pb), chiefly hornblende mesodiorite; Kitt Peak Granodiorite (KPGD; 165 Ma), hornblende-biotite granodiorite and monzogranite; and Pavo Kug Granite (PKG; 159 Ma), equigranular biotite leucogranite. This range also hosts a fourth, regionally unusual, Jurassic plutonic unit: the Baboquivari Peak Perthite Granite, related to post-arc, Late Jurassic crustal extension. Binary variation diagrams, incompatible element patterns, and REE spectra indicate APQD and KPGD are consanguineous. APQD basaltic mesodiorite evidently approximates the parental magma for the APQD–KPGD series. More evolved rocks of this series evidently formed by combinations of fractional crystallization and mixing with or assimilation of crustal material. PKG is less directly related to APQD and KPGD than these two are to one another.

Arizona, Sonora

Chemostratigraphy of the Cretaceous Hue Shale in Arctic Alaska: Exploring paleoceanographic controls on trace element enrichment, organic matter accumulation, and source-rock evolution

We document chemostratigraphy in an outcrop of late Albian to early Campanian (∼103–82 Ma) marine source rocks to better understand paleoenvironmental controls on trace element (TE) enrichment and organic matter accumulation in the distal Colville foreland basin of Arctic Alaska and how those drivers are linked to arc volcanism and successions of Cretaceous oceanographic and climatic biogeochemical events. This unique, 113-m-thick section of Cretaceous Hue Shale deposited during a series of previously undocumented Arctic Cretaceous oceanic anoxic events (Lease et al., 2024) is the only known exposure of thermally immature (0.48–0.52% R o , random vitrinite reflectance) Hue Shale in Arctic Alaska. Strata comprise mainly clay-rich mudstone with elevated total organic carbon (TOC) and hydrogen index values reaching 26.3 wt% (mean = 7.5 wt%) and 689 mg hydrocarbon (HC)/g TOC (mean = 385 mg HC/g TOC), respectively. Maceral composition consists predominantly of fluorescent amorphous organic matter, with abundant brightly fluorescent alginite, including Tasmanites , acritarchs, and Leiosphaeridia . Discrete layers of volcanic ash (preserved as bentonite) are present throughout the section and provide quantitative age control based on U–Pb dates. Chemostratigraphic trends are investigated to advance our understanding of local oceanographic conditions and controls on stratigraphic and temporal heterogeneity of Brookian source rocks. Concurrent sedimentary enrichment in Mo, U, V, Pb, and Cu across the Albian–Cenomanian boundary of the exposed basal gamma-ray zone, may reflect anoxic to euxinic benthic redox conditions favoring organic matter accumulation and preservation. Fluctuating degrees of anoxia-euxinia are inferred throughout the overlying Hue Shale succession, reflected by varying patterns of TE enrichment and TE–TOC covariation. Elevated C org /P molar ratios (>250) across most of the section, with several values exceeding 690, signify that enhanced biological productivity is sustained throughout deposition. Enhanced productivity, recorded by both C org /P and excess Ba, also parallels increases in source rock richness (elevated TOC and S 2 values) during the late Albian–early Cenomanian and late Cenomanian – Turonian. Enhanced productivity and variations in oceanic circulation/stratification likely both drove changes in benthic redox conditions that favored organic carbon accumulation and preservation. Increased continental arc volcanism (e.g., Okhotsk–Chukotka volcanic belt) and High Arctic Large Igneous Province magmatic eruptions throughout the Cretaceous, inferred to have influenced nutrient cycling and local aqueous nutrient availability, also have been invoked as potential drivers of organic carbon burial and source-rock development across the sedimentary sequence. Results presented here document the organic-rich and oil-prone source-rock quality of the Hue Shale in the distal part of the Colville foreland basin and bolster the potential for a Cretaceous petroleum system beneath the eastern North Slope.

Alaska

Trends and environmental impacts of virtual water trade

Virtual water describes water embedded in the production of goods and offers meaningful insights about the complex interplay between water, trade and sustainability. In this Review, we examine the trends, major players, traded products and key drivers of virtual water trade (VWT). Roughly 20% of water used in global food production is traded virtually rather than domestically consumed. As such, agriculture dominates VWT, with livestock products, wheat, maize, soybean, oil palm, coffee and cocoa contributing over 70% of total VWT. These products are also driving VWT growth, the volume of which has increased 2.9 times from 1986 to 2022. However, the countries leading VWT contributions (with China, the United States, the Netherlands, Germany and India accounting for 34% of the global VWT in 2022) have remained relatively stable over time, albeit with China becoming an increasingly important importer. VWT can mitigate the effects of water scarcity and food insecurity, although there are concerns about the disconnect between consumers and the environmental impacts of their choices, and unsustainable resource exploitation. Indeed, approximately 16% of unsustainable water use and 11% of global groundwater depletion are virtually traded. Future VWT analyses must consider factors such as water renewability, water quality, climate change impacts and socioeconomic implications.

Nature Reviews Earth & Environment

Seabed maps showing topography, ruggedness, backscatter intensity, sediment mobility, and the distribution of geologic substrates in quadrangle 3 of the Stellwagen Bank National Marine Sanctuary region offshore of Boston, Massachusetts

The U.S. Geological Survey, in cooperation with the National Marine Sanctuary Program of the National Oceanic and Atmospheric Administration, has conducted seabed mapping and related research in the Stellwagen Bank National Marine Sanctuary (SBNMS) region since 1993. The area being mapped using geophysical and geological data includes the SBNMS and the surrounding region, which totals approximately 3,700 square kilometers (km 2 ) and is subdivided into 18 quadrangles. The seabed is a glaciated terrain that is topographically and texturally diverse. Quadrangle 3, the subject of this scientific investigations map, has a mapped area of 185 km 2 and has water depths that range from about 30 meters (m) on the Stellwagen Bank crest to about 135 m in a basin east of South Ninety Bank, which lies off the eastern margin of Stellwagen Bank. Seven map types, each at a scale of 1:25,000, depict seabed topography, ruggedness, backscatter intensity, distribution of geologic substrates, sediment mobility, distribution of fine- and coarse-grained sand, and substrate mud content. These maps show the distribution of geologic substrates on the southeastern part of Stellwagen Bank, on adjacent banks and basins in deeper water to the east, in the eastern part of Race Point Channel to the south of the bank, and on the northern slope of Cape Cod. Interpretations of multibeam sonar bathymetric and seabed backscatter imagery, photographs, video imagery, and grain-size analyses were used to create the geology-based maps. Data from 309 stations were analyzed, including 279 sediment samples. The geologic substrate maps of quadrangle 3 show the distribution of 21 geologic substrates that represent a wide range of textures, such as rippled sand, immobile sand, immobile muddy sand, sand that partially veneers gravel, and boulder ridges. Mapped substrates are characterized by sediment grain-size composition, surface morphology, substrate layering, the mobility or immobility of substrate surfaces, and water depth range. This scientific investigations map portrays the major geological elements (substrates, topographic features, and processes) of environments in quadrangle 3. It is intended to provide a foundation for research into present and past sediment transport processes in a complex terrain, provide insights into the ecological requirements of invertebrate and vertebrate species that use the various substrates, and support seabed management in the region.

Quadrangle 3 of the Stellwagen Bank National Marin

Bathymetric and velocimetric surveys at highway bridges crossing the Missouri and Mississippi Rivers on the periphery of Missouri, June 13–22, 2022

Bathymetric and velocimetric data were collected by the U.S. Geological Survey, in cooperation with the Missouri Department of Transportation, near seven bridges at six highway crossings of the Missouri and Mississippi Rivers on the periphery of Missouri from June 13–22, 2022. A multibeam echosounder mapping system was used to obtain channel-bed elevations for river reaches about 1,640 feet longitudinally and generally extending laterally across the active channel from bank to bank during minor flood-flow conditions. These surveys provided channel geometry and hydraulic conditions at the time of the surveys and provided characteristics of scour holes that may be useful in developing or verifying predictive guidelines or equations for computing potential scour depth. These data also may be useful to the Missouri Department of Transportation as a minor flood-flow assessment of the bridges for stability and integrity issues with respect to bridge scour during floods. Bathymetric data were collected around every in-channel pier. Scour holes were present at most piers for which bathymetry could be obtained, except those on banks or surrounded by riprap. Occasionally, scour holes were minor and difficult to discern from nearby dunes and ripples. All bridge sites in this study were surveyed and documented in previous studies. Although partial exposure of substructural support elements was observed at several piers, at most sites the exposure most likely is minimal compared to the overall substructure that remains buried in bed material at these piers. The notable exceptions are piers 12 and 13 at structure L0135 on State Highway 51 at Chester, Illinois, where the bedrock material was fully exposed around the piers. The average difference between the bathymetric surfaces between 2022 and 2018 varied from 0.41 foot higher to 1.86 feet lower. Between 2022 and 2014, the average difference between the bathymetric surfaces varied from 1.02 feet higher to 4.69 feet lower. Only the two sites on the Missouri River and the Caruthersville site were surveyed in 2011; for those sites, the average difference between the bathymetric surfaces varied from 5.83 feet higher to 1.34 feet lower. The most substantial overall net gain of sediment in a reach was between 2011 and 2022 at structure A1700 near Caruthersville, Mo. (site 38). This result was expected because structure A1700 is downstream from the confluences of the Missouri and Ohio Rivers, and therefore subject to the largest streamflows, the largest streamflow fluctuations, and the most substantial sediment flux, as has historically been observed at this site. The presence of riprap blankets, pier size and nose shape, and alignment to flow had a substantial effect on the size of the scour hole observed for a given pier. Piers that were surrounded by riprap blankets had scour holes that were substantially smaller (to nonexistent) compared to piers at which no rock or riprap were present. New riprap blankets were surveyed at pier 3 of structure L0098 at Brownville, Nebraska, and at piers 15–18 of structure A1700 near Caruthersville, Mo., that effectively mitigated the scour holes historically observed at these piers. Narrow piers having round or sharp noses that were aligned with flow often had scour holes that were difficult to discern from nearby bed features, whereas piers having wide or blunt noses resulted in larger, deeper scour holes. Several of the structures had piers that were skewed to primary approach flow. Scour holes near these piers consistently displayed greater depth on the side of the pier with impinging flow and deposition on the leeward side of the pier.

Missouri

Evaluation of ground-water flow and hydrologic budget for Lake Five-O, a seepage lake in northwestern Florida

Temporal and spatial distributions of ground-water inflow to, and leakage from Lake Five-O, a softwater, seepage lake in northwestern Florida, were evaluated using hydrologic data and simulation models of the shallow ground-water system adjacent to the lake. The simulation models indicate that ground-water inflow to the lake and leakage from the lake to the ground-water system are the dominant components in the total inflow (precipitation plus ground-water inflow) and total outflow (evaporation plus leakage) budgets of Lake Five-O. Simlulated ground-water inflow and leakage were approximately 4 and 5 times larger than precipitation inputs and evaporative losses, respectively, during calendar years 1989-90. Exchanges of water between Lake Five-O and the ground-water system were consistently larger than atmospheric-lake exchanges. A consistent pattern of shallow ground-water inflow and deep leakage was also evident throughout the study period. The mean time of travel from ground-water that discharges at Lake Five-O (time from recharge at the water table to discharge at the lake) was estimated to be within a range of 3 to 6 years. Flow-path evaluations indicated that the intermediate confining unit probably has a negligible influence on the geochemistry of ground-water inflow to Lake Five-O. The hydrologic budgets and flow-path evaluations provide critical information for developing geochemical budgets for Lake Five-O and for improving the understanding of the relative importance of various processes that regulate the acid-neutralizing capacity of softwater seepage lakes in Florida.

Florida

Summary of results from monitoring the Geysers with continuous passive seismic and repeat magnetotelluric measurements (2021-2023)

Understanding temporal variations in a geothermal field can support operators in decision making that pertains to optimizing production and mitigating hazards. Between 2021 and 2023, The Geysers geothermal field in northern California was monitored with an array of continuous passive seismic sensors and annual repeat magnetotelluric (MT) measurements. Each of these data sets were analyzed and modelled separately to understand the data, sensitivity, and any observable changes. Then, the data were inverted jointly using a crossgradient method to further constrain temporal changes in geophysical properties within the geothermal field. Multiple permutations of annual datasets were used as inputs to the joint inversion. Results demonstrate seismic data constrain smooth inversion of the MT data, and the MT data provide supplementary information about the location of temporal fluid changes. Estimating relative changes in steam saturation for various time intervals of the joint models shows compartmentalized changes in the field, and good spatial correlation with the location of injection wells. These results demonstrate that collecting both passive seismic and MT measurements then modeling them jointly provide complementary information and a relatively inexpensive method for monitoring temporal changes in an active geothermal field that provides results to support operators.

California

Design, revisions, and considerations for continued use of a ground-water-flow model of the coastal plain aquifer system in Virginia

A digital numerical model of the ground-water-flow system in the Virginia Coastal Plain was constructed as part of the Regional Aquifer System Analysis program of the U.S. Geological Survey and subsequently revised based on reinterpretations of the hydrogeologic framework. The revised model has been incorporated by the Virginia Department of Environmental Quality as a means to evaluate the effects of existing and proposed ground-water withdrawals. The revised model, which is documented here, includes many design features of the original model. Principal modifications are (1) reassignment of some model layers to represent different aquifers, (2) replacement of applied recharge and the uppermost surface-water layer by constant-head cells to represent the unconfined aquifer, and (3) revision of the lateral extents and transmissivity and vertical leakance values assigned to model layers. Ground-water levels simulated by the revised model under steady-state conditions, using withdrawal rates representing the period 1978-80, generally are similar to the water levels simulated by the original model under transient conditions using the same withdrawal rates. Differences probably result largely from changes in transmissivity and vertical leakance values. T he revised model enables the continued evaluation of development of the large and complex aquifer system. Improved information on parts of some aquifers has been incorporated. Only large, regional-scale trends in ground-water water levels, flow directions, and flow rates are simulated, however, and not local trends and (or) short-term changes in water level and flow. Changing hydraulic stresses, knowledge of hydrogeologic conditions, and resource-management needs require periodic revision of the model to maintain its usefulness for the management of ground-water resources in the Virginia Coastal Plain.

Virginia

Development of a hydrologic flow model of the Zuñi Salt Lake and surrounding areas, west-central New Mexico

The terminal Zuñi Salt Lake is in a maar in west-​central New Mexico and contains hypersaline water that has long been used by Native Americans for religious purposes and the collection of salt. The U.S. Geological Survey (USGS), in cooperation with the Zuni Tribe of the Zuni Reservation, New Mexico, and Bureau of Reclamation, developed the Zuñi Salt Lake hydrologic flow model to simulate the steady-state conditions of the lake and surrounding groundwater-flow system. The model is a tool that can be used to analyze the potential hydrologic responses to resource development in the region under different water-use scenarios, which can support negotiations that could help protect future use of the lake. The USGS modular hydrologic model, MODFLOW 6, was used to simulate the hydrologic system of the lake and surrounding areas. To define the layering of the model, a three-dimensional hydrogeologic framework was constructed, which included seven informal hydrogeologic units and the locations of faults that truncate and offset the units. Calibration of the model was performed using the iterative ensemble smoother included in a parameter estimation software suite (PEST++). The iterative ensemble smoother approach resulted in a posterior parameter ensemble of model realizations with parameter and simulated values that show similar success in matching observations. Groundwater flux to the Zuñi Salt Lake simulated by using the posterior parameter distribution ranged from 26 to 730 acre-feet per year with a mean, median, and standard deviation of 530, 570, and 170 acre-feet per year, respectively. The relative contribution of groundwater discharge to the lake was simulated using a particle-tracking model for MODFLOW (MODPATH) to be from, in order of decreasing contribution, the Mesaverde, Cenozoic, Mancos, and Dakota hydrogeologic units. Simulations of future conditions using the ensemble of models can provide an empirical estimate of forecast uncertainty without substantial additional analysis.

New Mexico

Water quality of the Boca Raton canal system and effects of the Hillsboro Canal inflow, southeastern Florida, 1990-91

The City of Boca Raton in southeastern Palm Beach County, Florida, is an urban residential area that has sustained a constant population growth with subsequent increase in water use. The Boca Raton network of canals is controlled to provide for drainage of excess water, to maintain proper coastal ground-water levels to prevent saltwater intrusion, and to recharge the surficial aquifer system from which the city withdraws potable water. Most of the water supplied to the Boca Raton canal system and the surficial aquifer system, other than rainfall and runoff, is pumped from the Hillsboro Canal. The Biscayne aquifer, principal hydrogeologic unit of the surficial aquifer system, is highly permeable and there is a close relation between water levels in the canals and the aquifer. The amount of water supplied by seepage from the conservation areas is unknown. Because the Hillsboro Canal flows from Lake Okeechobee and Water Conservation Areas 1 and 2, which are places of more highly mineralized ground water and surface water, the canal is a possible source of contamination. Water samples were collected at 10 canal sites during wet and dry seasons and analyzed for major inorganic ions and related characteristics, nutrients, and trace elements. All concentrations were generally within or less than the drinking-water standards established by the Florida Department of Environmental Protection. The high concentrations of sodium and chloride that were detected in samples from the Boca Raton canal system are probably from the more mineralized water of the Hillsboro Canal. Other water-quality data, gathered from various sources from 1982 through 1991, did not indicate any significant changes nor trends. The data include pesticide and metal analyses of water samples and bottom sediments collected at four canal sites in the Boca Raton study area by the U.S. Geological Survey during 1982-84. The effects of the Hillsboro Canal on the water quality of the Boca Raton canal system are indicated by increased concentrations of sodium, chloride, dissolved solids, and total organic carbon. Concentrations of the constituents in the canal water generally decrease with distance from the Hillsboro Canal pumping station and are the result of dilution by receiving canal waters.

Florida

Peak-discharge frequency and potential extreme peak discharge for natural streams in the Brazos River basin, Texas

The 2-, 5-, 10-, 25-, 50-, and 100-year peak discharges were estimated for 186 streamflow-gaging stations with at least 8 years of data for natural streams in and near the Brazos River Basin, Texas. Multiple regression equations were developed to estimate peak-discharge frequency for the 2-, 5-, 10-, 25-, 50-, and 100-year recurrence intervals for each of three hydrologic regions that compose the Brazos River Basin. The equations for each region are a function of significant basin characteristics (explanatory variables). The significant explanatory variables among six that were tested are the contributing drainage area and stream slope for regions 1 and 2 and the contributing drainage area for region 3. For the three sets of equations, the coefficient of determination ranges from 0.59 to 0.93, and the standard error ranges from 0.184 to 0.391 log units. A larger coefficient of determination and a lower standard error generally are associated with the equations for hydrologic regions 2 and 3. Statistics from the regression analysis allow computation of the prediction interval associated with a given significance level for a peak-discharge frequency estimate. The regression equations can be used to estimate peak discharges for sites at, near, or away from sites with streamflow-gaging stations. The potential extreme peak-discharge curves as related to contributing drainage area were estimated for each of the three hydrologic regions from measured extreme peaks of record at 186 sites with streamflow-gaging stations and from measured extreme peaks at 37 sites without streamflow-gaging stations in and near the Brazos River Basin. The potential extreme peak-discharge curves generally are similar for hydrologic regions 1 and 2, and the curve for region 3 consistently is below the curves for regions 1 and 2, which indicates smaller peak discharges.

Texas

Depth of magma crystallization and fluid exsolution beneath the porphyry-skarn Cu deposits at Santa Rita and Hanover-Fierro, New Mexico, USA

The depth level at which porphyry Cu–forming magmas fractionated and exsolved mineralizing fluids is actively debated. In the classic model, extensive magma fractionation occurs in large, upper crustal magma chambers, and concomitant fluid exsolution leads to forceful expulsion of residual magmas in the form of porphyry dikes, stocks, and breccia pipes, which subsequently serve as pathways for the mineralizing fluids. In contrast, some recent studies highlighting the role of deep crustal magma fractionation in the production of fertile magmas essentially deny the existence of upper crustal magma chambers at the time of mineralization. To address this, we conducted a detailed thermobarometric investigation of 13 intermediate to felsic, porphyritic intrusive rocks related to porphyry-skarn Cu mineralization at Santa Rita and Hanover-Fierro, New Mexico, United States, representing two premineralization magmas (61–60 Ma), seven synmineralization magmas (60–58 Ma), and four late- to postmineralization magmas (58–57 Ma). For each sample, the pressure of last magma crystallization before final magma ascent to the current exposure level was reconstructed based on Al-in-hornblende barometry of small hornblende inclusions trapped within quartz phenocrysts and through titanium-in-quartz (TitaniQ) thermobarometry of the host quartz phenocrysts themselves. Since quartz is one of the last crystallizing magmatic minerals, and no significant phenocryst growth could have occurred in small dikes and stocks after final magma emplacement, quartz phenocrysts and their contained hornblende inclusions record the depth of last magma crystallization before final magma ascent. When present, hornblende phenocrysts and hornblende inclusions within other major phenocrysts were also analyzed. Both quartz and hornblende barometers return consistent average pressures of 3.2 ± 0.4 kbar for the entire suite of pre- to postmineralization magmas, corresponding to depths of 11 to 14 km. The synmineralization magmas return even more consistent average pressures of 3.1 ± 0.2 kbar, corresponding to a depth of 12 ± 1 km. The volume of the mineralizing porphyry dikes and stocks at the emplacement level is far too small to have provided all the fluids and metals required to form the observed ore deposits. Therefore, the majority of the ore-forming fluids must have originated from the magmas that crystallized at 12 ± 1 km depth. The ore deposits, conversely, formed at ~5-km paleodepth. This implies that most of the mineralizing fluids traveled an average vertical distance of ~7 km from their magmatic source to the eventual site of ore precipitation. The relatively unaltered nature and low veining degree of deeper parts of mineralized porphyry dikes and stocks suggest that the fluid transport through these intrusive bodies occurred mostly at near-solidus conditions by means of fluid percolation along grain boundaries. In summary, our results suggest that (1) a large, upper crustal pluton exists ~7 km beneath the Santa Rita and Hanover-Fierro deposits; (2) abundant phenocryst crystallization occurred at this depth level; and (3) this pluton was the main source for the exsolution of ore-forming fluids. However, the investigated rocks have elevated whole-rock Sr/Y ratios, indicating magma fractionation at deep crustal levels. As a result, our preferred model is a combination of the two end-member models introduced above, with most magma fractionation having occurred in the deep crust and with residual, intermediate to felsic melts having ascended and accumulated at 11 to 14 km paleodepth, where they continued to crystallize with comparatively little crystal-liquid separation, before some of these magmas ascended further to shallow levels and quenched to porphyries.

New Mexico