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Ground-motion aleatory-variability models for Puerto Rico and the U.S. Virgin Islands

I develop independent logic trees for aleatory variability for crustal and subduction-zone (interface and intraslab) earthquakes for seismic hazards analyses in Puerto Rico and the U.S. Virgin Islands (PRVI) from existing suites of ground-motion models (GMMs) and from ground-motion datasets, including a regional PRVI dataset. The aleatory variability models are parameterized using a partially nonergodic partitioning of standard deviation that consists of independently developed between-event ( ), site-to-site ( ), and event-corrected single-station ( ) standard deviation components. The effects of nonlinear site response on aleatory variability are incorporated through additional terms that modify the standard deviation components. Because one goal of this work is to develop independent logic trees for aleatory variability that synthesize the aleatory variability models from GMMs, I make use of the functional forms of the input GMMs. The PRVI dataset contains a limited number of stations with high-quality site metadata and does not contain records from earthquakes with magnitudes greater than 6.1, so I choose not to develop the aleatory variability models from the regional dataset alone. Instead, the standard deviation components from regional ground-motion data are evaluated against the components derived from GMMs and from available global datasets, and regionalized standard deviation components are incorporated where there is evidence that regional effects exhibit substantial differences. The resulting logic trees for aleatory variability consist of models of and that are consistent with semiempirical GMMs for active crustal and subduction-zone regimes, and two alternative models of , including one model that exhibits site-to-site variability informed by PRVI data, with values that exceed global models. The aleatory variability models may be considered in future hazards assessments in PRVI to simplify the hazard calculations, to incorporate regional ground-motion variability effects, and to enable direct logic-tree weighs of aleatory variability.

Puerto Rico, U.S. Virgin Islands

Color-Shaded Relief Bathymetry of Lake Chelan, Washington

In 2023, the U.S. Geological Survey (USGS) completed a 3-week field operation in Lake Chelan, Washington, the third deepest lake in the conterminous United States, to acquire sediment cores, high-resolution bathymetry data, and chirp sub-bottom profiles. The high-resolution bathymetry displayed in this map publication was collected using a Norbit Winghead i67-curved array multibeam system; raw data were cleaned and gridded (3 by 3 meters [m]) in the Teledyne CARIS software. In some locations where the slopes of Lake Chelan are near-vertical, multibeam returns were sparse, resulting in artifacts resembling holes that appear as grey dots within the color-shaded bathymetric relief. Although the 2023 bathymetric mapping of Lake Chelan resulted in similar morphometric characteristics to previous hydrographic campaigns (table 1; Kendra and Singleton, 1987; Pelletier and others, 1989), these new data provide a much more detailed understanding of the two physiographic basins that comprise Lake Chelan: the deeper (as deep as 445.8 m [fig. 1]; previously reported as 453 m) and narrower (1–2 kilometers [km] wide) Lucerne Basin to the north, and the shallower (as deep as 127.8 m [fig. 1]), and wider (2–3 km wide) Wapato Basin to the south. With this detailed imaging of Lake Chelan, we find pervasive morphological evidence of slope failure and mass-transport deposits (MTDs) in at least 89 locations within the lake and 63 subaqueous deltas (fig. 2). The deeper Lucerne Basin is dominated by steep slopes and numerous subaqueous deltas fed by steep fluvial catchments, whereas the Wapato Basin contains numerous landslide scarps, scars, and debris aprons along the more gently sloping lake margins, and abundant relict kettle structures from the Pleistocene deglaciation. Lake Chelan’s geomorphic, geophysical, and sediment data contain important records of glacial retreat and advance, regional volcanic eruptions, and earthquakes that generate ground motions severe enough to induce landslides recorded in the sediment as MTDs. The epicenter of the 1872 Washington State Earthquake (M 6.5–7.2; Bakun and others, 2002; Brocher and others, 2017; Sherrod and others, 2021) is along the Spencer Canyon Fault, near the southern end of Lake Chelan. Shaking from this earthquake was strong enough to affect local aquifers, induce liquefaction of unconsolidated sediments, produce large seiches (Brocher and others, 2018), and likely cause landslides within Lake Chelan.

Washington

Estimation of parental abundance using hierarchical Bayesian modeling with data augmentation

Pedigree-based estimation methods leverage the fact that each offspring in a cohort is genotypically “marked” by its parents and represent a recent and promising toolset for estimating population dynamics. This includes pedigree accumulation estimators that model the “accumulation” of inferred unique parents within a given cohort to estimate parental abundance. Unlike close-kin mark-recapture approaches, which rely on intercohort comparisons, pedigree accumulation modeling can be completed solely using intracohort samples. This is particularly advantageous for semelparous species, where intercohort pairs are impossible and adult life stages can be difficult to sample without affecting their likelihood of successfully reproducing. Previous work has evaluated a range of estimators for such datasets, concluding that the non-parametric Chao estimator provides the most accurate and precise estimates for feasible levels of sampling effort. We used simulated data to evaluate an alternative estimator based on hierarchical modeling and data augmentation in a Bayesian framework. Results indicate that estimates from the hierarchical Bayesian estimator had comparable accuracy and better precision than both the previously tested Chao1 estimator and the improved iChao formulation across a range of sample sizes and sex ratios. Furthermore, the Bayesian estimator was far more robust to simulated errors in pedigree reconstruction, especially the presence of false negatives. Hierarchical Bayesian pedigree accumulation models can also provide additional insight into underlying reproductive ecology through their use of an explicit observation process, allowing for the incorporation or estimation of species- and population-specific reproductive dynamics. More broadly, the parametric nature of these models offers opportunities to efficiently pool information among datasets as well as to propagate uncertainty within more complex models.

Ecology and Evolution

The 3D Elevation Program—Supporting New Hampshire’s economy

Introduction The topography of New Hampshire ranges from the Coastal Lowlands to the Eastern New England Upland to the White Mountains region. High-quality statewide elevation data are useful in managing this very diverse landscape. For example, the short coastline, including the Great Bay estuary and the Hampton-Seabrook marshes, is of disproportionately high value to New Hampshire’s tourist economy. The vulnerability of the coast to the effects of sea-level rise underscores the need for accurate, high-quality nearshore topographic elevation data and offshore bathymetric data to effectively manage the coast’s valuable resources, which include important fisheries, habitat, and infrastructure. Another important use for accurate elevation data in New Hampshire is in the evaluation of flood hazards and their potential environmental and infrastructure effects. This evaluation includes mapping of inundation and sediment transport, and assessing the associated costs of flooding. Addressing this challenge requires detailed knowledge of both surface topography and inland bathymetry. Other important activities having a substantial economic element and needing accurate elevation data include geologic resource assessment and hazard mitigation, urban and regional planning, infrastructure and construction management, and cultural resources preservation and management. Critical applications that meet the State’s management needs depend on light detection and ranging (lidar) data that provide a highly detailed three-dimensional model of the Earth’s surface and aboveground features.

New Hampshire

Fault displacement model for surface principal rupture of strike-slip faults

The probability distribution model for principal displacement accommodated on the surface main trace is a critical input to the fault displacement hazard analysis. This article presents a new model for strike-slip ruptures in the moment magnitude ( M ) range of 6 to 8.3. The new model is the outcome of a multi-year research effort to update the widely used model developed by Petersen and others in 2011. Updates include the adoption of the Fault Displacement Hazard Initiative database and enhancements to rupture and displacement data preparation. Statistical formulation and estimation have also been updated substantially. A three-parameter modified normal distribution that we refer to as the negative Exponentially Modified Gaussian distribution is adopted to model the probability distribution of the natural logarithm of principal displacement. Formulation for the mean parameter of the modified normal includes a random earthquake term, a nonlinear scaling relation with M , and an ellipse function for along-main-trace variation. The aleatory variability of the updated model now depends on M as well as site’s along-main-trace position. These updates not only significantly improve the fit to the distribution of the observed displacements but also yield reasonable 95th percentile predictions for M > 7.5 events. Alternative models representing the estimation uncertainty of the M -scaling relation are also developed. These new models are compared to the previous model in terms of percentile predictions and the calculated hazard curves. The steeper hazard curves from the new models yield a lower exceedance rate than the normal-distribution based model developed previously by Petersen and others.

Earthquake Spectra

Comparative assessment of STIC sensors, streamflow and rain gauges for quantifying river connectivity in intermittent systems

In intermittent stream systems, including those occurring in Texas, USA, the severity of low-flow conditions, duration of seasonal disconnection, and frequency of no-flow events have been amplified by drought. Documentation of these no-flow events is necessary to evaluate ecosystem health. However, many intermittent reaches remain un-gauged given that perennial river sec-tions are often prioritized for gauge placement. Our objectives were to 1) document stream flow using Stream Temperature, Intermittency, and Conductivity (STIC) loggers to determine the frequency and duration of no-flow events in intermittent tributaries of the Colorado River, Texas and 2) compare logger data to publicly available data from streamflow discharge and precipitation gauge networks to understand differences among these data types for drying event characterization. We use these comparisons to summarize benefits and limitations of the application of in-stream data loggers. STIC loggers were deployed at 19 sites, one in each pool and riffle habitat of a stream reach. STIC loggers recorded a measurement of relative conductance every six hours from June 2022 to March 2024, which was used to determine the presence or absence of flow connectivity in a reach. No-flow duration among intermittent reaches varied between 37 and 270 days across tributaries during an ongoing drought in the study area. Overall, logger data was more precise than discharge data for characterizing no-flow events or precipitation data when documenting presence of water in the stream channel due to runoff. Lack of discharge gauges in intermittent tributaries left large sections of stream reaches undocumented and resulted in mischaracterization of flow patterns. Drought severity across the tributaries did not follow longitudinal patterns that would be expected by the climatic precipitation gradient of the study area. More research is needed to determine if factors such as population size affect severity. Likewise, precipitation data did not correlate well with logger water presence data, lacking consideration for groundwater recharge, soil hydrophobicity, and surface compaction. This study shows that to monitor no-flow events, detailed spatial datasets are necessary and that STIC loggers are useful tools that provide data to fill spatial information gaps and facilitate more accurate flow characterization and water presence data in intermittent systems.

Texas

Diamond drilling at the Ma'milah Mine, Kingdom of Saudi Arabia

The Ma'millah gold mine is about 90 km southeast of At Ta'if at lat 21°03'N., long 41°18'E., in southwestern Saudi Arabia. The deposit, which was worked extensively by ancient miners, consists of several veins and massive lenses of quartz along a regional fault. The extensive ancient mine workings, large size of some quartz outcrops, and significant gold content of several samples indicated that subsurface exploration was warranted. Accordingly, two holes were drilled into the deposit during the interval December 1972 to February 1973. The drill findings were disappointing; the grade of vein material was found to be too low to be of economic interest and the quartz bodies were found to pinch out both along strike and downdip. The drilling program therefore was terminated. The deposit is not worth further exploration

Ma'milah Mine

Reassessing water availability in the Nile River Basin using satellite-based irrigation water use accounting

Existing estimates of irrigation areas and water use in the Nile River Basin vary widely and are based on inconsistent data and methodologies. This study leverages advances in remote sensing to provide an up-to-date and consistent basin-wide reassessment of water use in the Nile River Basin. Land cover and actual evapotranspiration data from 2013 to 2022 were used to quantify irrigated areas, irrigation water use, and the average naturalized water yield. Across the basin, 7.1 million hectares of irrigated land consume an average of 72.5 ± 2.6 billion cubic meters (BCM) of blue water annually. Egypt and Sudan together account for 92% of the irrigated area and 97% of the irrigation water use. The basin’s average naturalized yield, evaluated at Dongola station, is determined to be between 108 and 114.4 ± 3.2 BCM. Although conservative, this updated analysis indicates the basin’s average naturalized yield is 14%–20% higher than the previous naturalized yield estimate (95 BCM) and 29%–36% higher than the commonly cited observed flow of 84 BCM, which is frequently treated as the total basin-wide available water. Importantly, the study underscores that the 84 BCM represents flow at the Aswan gauging station after upstream consumptive uses, not the total water available in the basin under naturalized conditions. This distinction is critical for accurate water accounting, planning, and governance in this water-scarce basin. This study demonstrates the value of open-source remote sensing resources in data-scarce regions while emphasizing the need for region specific validation and bias correction for improved accuracy.

Nile River Basin

Low-frequency earthquakes track the motion of a captured slab fragment

Accurate tectonic models are essential for assessing seismic hazard and fault interactions. However, the plate configuration at the complex Mendocino triple junction, where the San Andreas Fault and the Cascadia subduction zone meet, remains uncertain. We analyzed fault slip associated with a recently identified zone of tectonic tremor and low-frequency earthquakes (LFEs) near the southern edge of the subducting Gorda slab. Based on tidal sensitivity and P-wave first motions, we show that the LFEs are generated by dipping, strike-slip motion. This suggests that a former Farallon slab fragment, now captured by the Pacific plate, is translating northward beneath westernmost North America. This geometry effectively extends the slab interface fault, challenging prevailing interpretations of slab window formation and creating a potential unaccounted earthquake hazard in this region.

Science

Uranium analysis of single drops of natural waters using the fission-track technique

The fission-track technique has been applied to uranium analysis of natural waters using a single drop of water. Samples may be collected in the field by evaporating a drop of water on a detector, and samples may then be analyzed by returning the detector to the laboratory. A sample collecting kit has been assembled, which facilitates the designed sampling method. Some unique advantages of this technique are picogram sensitivity (10 -12 g) for uranium on single drops of water, maintenance of sample integrity during transport and storage, and the ability to discern whether the uranium is in solution or in the suspended material. Counting the tracks is the most time-consuming part of the analysis, but it can be reduced by using automatic counting systems. The analytical error is generally ± 10 percent over the entire range of concentrations.

Open-File Report

Development of vegetation based soil quality indices for mineralized terrane in arid and semi-arid regions

Soil quality indices (SQIs) are often management driven and attempt to describe key relationships between above- and below-ground parameters. In terrestrial systems, indices that were initially developed and modified for agroecosystems have been applied to non-agricultural systems in increasing number. We develop an SQI in arid and semi-arid ecosystems of the Western US impacted by different types of geologic mineralization using the relationship between vegetation community parameters and soil abiotic and biotic properties. We analyze these relations in soils associated with three different mineralization types: podiform chromite, Cu/Mo porphyry, and acid-sulfate gold vein systems at four different sites in California and Nevada. Soil samples were collected from undisturbed soils in both mineralized and nearby unmineralized substrates as well as from waste rock and tailings. Aboveground net primary productivity (ANPP), canopy cover and shrub density were measured for the vegetative communities. Minimum data sets were developed based on correlations between the soil and vegetation parameters, refined using principal components analysis, scored using non-linear functions, and combined into an overall SQI. The indices are comprised of one or two microbial parameters and three to six abiotic parameters, the latter consisting of nutrients and metals. Given the preliminary development of this approach, the parameters and combinations to arrive at an SQI for a given site cannot at this time be correlated or compared with that of another site. This SQI approach provides a means of quantifying disturbed ecosystem recovery resulting from mining, and could be applied to other disturbances in a way that readily distills the information for potential use by land managers. However, severely disturbed areas with little to no aboveground biomass, such as unreclaimed tailings, have likely crossed an ecological threshold that precludes the use of this type of monitoring tool.

California

Determination of per- and polyfluoroalkyl substances in water by direct injection of matrix-modified centrifuge supernatant and liquid chromatography/tandem mass spectrometry with isotope dilution

A direct-injection liquid chromatography/tandem mass spectrometry method was developed to determine 34 per- and polyfluoroalkyl substances (PFAS), including selected branched isomers, in centrifuge supernatant of matrix-modified (amended with approximately 50 percent methanol) water samples. The method has been validated in reagent water, surface water, groundwater, and wastewater effluent. Other water types (for example, drinking water, untreated wastewater, and landfill leachate) have been analyzed by the method but not systematically validated. Recovery of isotope-dilution standards, added to each sample, may be used to assess method performance in nonvalidated matrices on a sample-by-sample basis. Using this method, PFAS concentrations were determined in the range of 2–2,000 nanograms per liter in water samples. This range can be extended by diluting concentrated samples. At circumneutral pH, most compounds are present in the environment in their ionized form, and data are reported as such (for example, perfluorooctanoic acid is referred to as “perfluorooctanoate” [PFOA], perfluorooctane sulfonic acid is referred to as “perfluorooctane sulfonate” [PFOS]). Sample preparation procedures were designed without the use of filtration and with minimum sample handling steps to mitigate procedural losses of target compounds due to sorption to surfaces. Further, isotope-dilution quantification allowed for the correction of bias that may result from procedural losses, matrix-induced signal suppression or enhancement, and other factors. Validation experiments to characterize bias and variability, method detection level, and holding time were done in four distinct water matrices—reagent water, surface water, treated wastewater effluent, and groundwater—at multiple concentration levels. Mean PFAS recoveries met data quality objectives of bias and variability studies in all four validation matrices except for two compounds with low and variable recovery in the reagent water matrix only. Isotope-dilution standards, treated as surrogate compounds, were analyzed in more than 1,500 customer-submitted environmental samples with aggregate recovery of 102.5±6.5 percent (mean±standard deviation). Maximum holding times for all target compounds in the four validation matrices were 28 days for refrigerated samples and 90 days for frozen samples.

Techniques and Methods

James Buttle review: The characteristics of baseflow resilience across diverse ecohydrological terrains

The dynamic storage of aquifers is the portion of groundwater that can potentially drain to any given point along a stream to create baseflow. Baseflow typically occurs year-round in perennial streams, though the characteristics and stability of dynamic storage are often most important to instream processes during extended dry periods (without precipitation and snowmelt) when runoff and quickflows are minimised. The term ‘baseflow resilience’ is defined for this review as the tendency of baseflow in streams to maintain a consistent volume and water quality year to year while under stress from climate variability and extremes, along with anthropogenic stressors such as water withdrawals, land use change, and water quality degradation. ‘Baseflow resilience’ has, in part, a user-defined meaning spanning water supply and water quality variables of primary interest. Watershed characteristics that directly impact resilience can often produce non-intuitive feedbacks that enhance some attributes of baseflow while simultaneously impairing others. For example, permeable stream corridor geology creates strong stream-groundwater hydrologic connectivity, yet fast groundwater drainage via preferential high-permeability flowpaths can lead to streamflow not being sustained during extended dry periods. Also, shallow groundwater sources are generally more immediately vulnerable to extreme events, warming, salinization, transpiration, and precipitation drought, compared to deeper groundwater. Yet baseflow drought in streams influenced by deeper groundwater can lag precipitation drought by years, and contaminant legacies may propagate through deep groundwater flowpaths to receiving waters for decades to centuries. Finally, irrigation withdrawals can intercept groundwater that would have drained to streams, and the application of irrigation may leach contaminants from the soil zone by unnaturally raising water tables, yet irrigation return flows can sustain baseflow and groundwater-dependent habitats in semiarid areas. This review covers the concept of hydrologic resilience in the context of stream baseflow processes and summarises the common hydrogeological controls on, and multiscale stressors of, dynamic groundwater storage. Further, we present several quantitative metrics to assess a range of water supply to water quality baseflow characteristics using both broadly available and boutique data types, a subset of which are demonstrated using data from the Delaware River Basin, USA.

Delaware River Basin

Continental-scale prediction of hydrologic signatures and processes

Understanding how dominant hydrologic processes and their drivers vary across diverse continental-scale landscapes is critical for hydrologic modeling and water management applications. Our research addresses this question by synthesizing large-sample watershed datasets, Caravan and GAGES-II, and developing random forest models to identify patterns in hydrologic function. We assessed dominant processes by examining hydrologic signatures – summary indicators of watershed function derived from hydroclimatic time series and random forest models across 14 146 gauged United States watersheds. The results reveal clear continental-scale gradients in hydrologic processes, including baseflow, overland flow, storage, and water balance losses. Our map of dominant processes highlights, for example, the transition from baseflow to fast responses and back to baseflow along the elevation gradient from the Appalachian spine, through the Piedmont, to the Eastern Coastal Plain; a distinct outer ring around the Great Lakes region; and sharp contrasts between coastal and inland processes in the West. Variable importance analysis from random forest models show that processes in the western U.S. are primarily controlled by climate, whereas in the eastern U.S., soil, geology, and topography play larger roles, with distinct human influences apparent in urban areas. Our approach of estimating dominant processes and their drivers facilitates extending process knowledge from research watersheds to the continental scale, assessing current hydrological understanding, and evaluating hydrological model structures.

conterminous United States

Seismic tomography 2023

Seismic tomography is the most abundant source of information about the internal structure of the Earth at scales ranging from a few meters to thousands of kilometers. It constrains the properties of active volcanoes, earthquake fault zones, deep reservoirs and storage sites, glaciers and ice sheets, or the entire globe. It contributes to outstanding societal problems related to natural hazards, resource exploration, underground storage, and many more. The recent advances in seismic tomography are being translated to nondestructive testing, medical ultrasound, and helioseismology. Nearly 50 yr after its first successful applications, this article offers a snapshot of modern seismic tomography. Focused on major challenges and particularly promising research directions, it is intended to guide both Earth science professionals and early‐career scientists. The individual contributions by the coauthors provide diverse perspectives on topics that may at first seem disconnected but are closely tied together by a few coherent threads: multiparameter inversion for properties related to dynamic processes, data quality, and geographic coverage, uncertainty quantification that is useful for geologic interpretation, new formulations of tomographic inverse problems that address concrete geologic questions more directly, and the presentation and quantitative comparison of tomographic models. It remains to be seen which of these problems will be considered solved, solved to some extent, or practically unsolvable over the next decade.

Bulletin of the Seismological Society of America

Geochemistry of quartz and fluid inclusions associated with gold, tungsten, and antimony in the Stibnite-Yellow Pine district, Idaho

Deposits in the historic Stibnite-Yellow Pine district in east-central Idaho were mined for Ag, Au, Hg, Sb, and W. Ore is hosted in breccia and fault zones along NE-striking faults that transect the Atlanta lobe of the Late Cretaceous Idaho batholith and metamorphosed Neoproterozoic to lower Paleozoic rocks. Geochronological studies have delineated five superimposed and zoned hydrothermal events in the mining district which range in age from Late Cretaceous to the Eocene. They formed the following consecutive assemblages: (1) vein and disseminated pre-ore milky quartz (± calcite), muscovite, and brassy pyrite with minor molybdenite and base metal sulfides; (2) vein and disseminated quartz, calcite, sericite, auriferous-pyrite, and arsenopyrite; (3) potassium feldspar, quartz, dolomite, and calcite with vein and disseminated scheelite ± pyrite and arsenopyrite; (4) Au-Ag veins that contain adularia; and (5) breccia, vein, and disseminated quartz, calcite, and stibnite with minor Ag sulfosalts and distal zones of cinnabar and realgar at Fern and Hermes mines. In this study, the pressure, temperature, and composition of ore-forming fluids were measured in Au-, W-, and Sb-bearing samples collected from drill core and surface exposures. Using optical petrography, scanning electron microscopy cathodoluminescence (SEM-CL) and electron microprobe cathodoluminescence (EMPA-CL) imaging, as well as electron microprobe (EMP) and laser ablation-inductively coupled plasma-mass spectrometry trace element analyses, four major overprinting generations of hydrothermal quartz are defined. Fluid inclusion assemblages (FIAs) in each generation of quartz were characterized by microthermometry and laser Raman spectroscopy. Quartz and fluid inclusion paragenesis are as follows: (Qi) altered and overprinted Qi with no coeval FIAs that formed before or during event 1; (Q1) early veins as well as disseminated quartz with dull gray SEM-CL and H 2 O-NaCl-CO 2 FIAs that formed at minimum temperatures and pressures of 281° to 358°C and 1346 to 1789 bar during event 2 (Au); (Q2) vein and disseminated quartz, often euhedral, with H 2 O-NaCl ± CO 2 ± CH 4 FIAs that formed at minimum temperatures and pressures of 183° to 213°C and 72 to 602 bar during event 3 (W); and (Q3) euhedral and disseminated quartz with H 2 O-NaCl FIAs that formed at minimum temperature and pressures of 156° to 161°C and 5 to 6 bar during event 5 (Sb). Stibnite hosts H 2 O-NaCl FIAs trapped at minimum temperatures and pressures of 150° to 189°C and 5 to 12 bar that are similar to those of Q3-hosted FIAs. The quartz paragenetic history in the district follows a progressive temporal path from Tienriched quartz deposited by a relatively deep and higher temperature aqueous-carbonic fluid to a Li, Al, and Sb enriched quartz precipitated from a lower temperature aqueous fluid. Gases in fluid inclusion extracts from ore and gangue minerals were analyzed by mass spectrometry. Noble gas isotope analysis of fluid inclusion extracts revealed three signatures. Pre-ore Qi has R/R A (the isotopic ratio of the sample 3 He/ 4 He to atmospheric 3 He/ 4 He (1.384 × 10 −6 )) values that reflect the composition of the crustal melt-derived Atlanta lobe of the Idaho batholith. Quartz (Q1) and auriferous arsenian pyrite of hydrothermal event 2 have 20 Ne/ 4 He and R/R A values that plot along the air-crust mixing line, and these gases were likely introduced by metamorphic fluids derived from metasedimentary rocks. Stibnite with associated quartz (Q3 ± Q2) have 20 Ne/ 4 He and R/R A values that extend from the air-crust mixing line to the air-mantle mixing line, showing a shift from a crustal signature to an overprinting mantle signature. Late calcite has 20 Ne/ 4 He and R/R A values that extend from air toward the mantle end member, which suggests that magmatic volatiles condensed into meteoric groundwater late in the paragenesis. A mantle volatile source is also supported by high 20 Ne/ 22 Ne ratios. The Stibnite-Yellow Pine district is similar to other Au-W-Sb districts around the world in ore fluid chemistries, with late-stage stibnite being a product of cooling. The fluid pressure-temperature-composition (P-T-X) estimates and the crustal source of He during hydrothermal event 2 gold mineralization are characteristic of orogenic Au deposits, and the observed inclusion reequilibration textures indicate that trapped fluid inclusions were deformed during transitions between the brittle-ductile environment. Scheelite was deposited during event 3 with Q2 quartz and is overgrown by Q3 quartz and stibnite. Our interpretation of the quartz texture, chemistry, and fluid inclusion P-T-X data suggest that Au, W, and Sb mineralization occurred as hydrothermal fluids evolved from H 2 O-NaCl-CO 2 at >300°C and depths of ~4 to 6 km near the ductile to brittle transition to H 2 O-NaCl at ~150°C and epithermal depths as the Idaho batholith was exhumed. Geochronology indicates that from the Late Cretaceous to early Eocene, overprinting hydrothermal events formed deep orogenic Au, intermediate W, and shallow epithermal Au-Ag and Sb. Without comprehensive geochronologic constraints, our fluid inclusion data and textural observations could be interpreted as a single evolving hydrothermal system, as has been done in many other mining districts with similar mineralization.

Idaho

Groundwater and surface-water interactions in the Lower Duwamish Waterway, Seattle, Washington

The U.S. Geological Survey (USGS), in cooperation with the Washington State Department of Ecology (Ecology), conducted a study to describe the current understanding of the regional groundwater system of the lower Duwamish River valley and groundwater and surface-water interactions in the lower Duwamish Waterway. The lower Duwamish Waterway is the final 5-mile (mi) reach of the Duwamish River before it empties into Elliott Bay in Puget Sound near Seattle, Washington. A nearshore site (hereinafter referred to as “Nearshore Site” to distinguish the particular site from general discussions of nearshore areas) along the western shoreline of the Duwamish River, about 1.5 mi upstream from the river mouth, was selected for focused groundwater data collection by USGS. Data loggers were deployed in seven groundwater wells and one stilling well in the Duwamish River to measure specific conductance, temperature, and depth at 15-minute intervals for a period of about 2 years. At the Nearshore Site during 2020–22, water levels in the shallow wells were 3–8 feet (ft) higher than water levels in the deep wells, providing evidence for a low-permeability layer between the shallow and deep aquifers in this area. The shallow wells had a pronounced seasonal variability, with high water levels in winter and low water levels in summer. Data from the deep wells showed far less seasonal variability, with slight increases in winter and a near-constant water level from spring to autumn. The deep wells had a strong hydraulic connection to the Duwamish River, as evidenced by the synchronous water-level variability during the tidal cycle, whereas the shallow wells had minimal to no tidal response. The potentiometric maps developed for the Nearshore Site and surrounding areas indicate large differences in groundwater-flow directions for the shallow and deep aquifers at low and high tides. For the shallow aquifer, flow is toward the lower Duwamish Waterway near the Nearshore Site, regardless of the tidal condition. For the deep aquifer, a potentiometric trough forms parallel to the shoreline during high tide, indicating that groundwater flow converges from the uplands to the west and the Duwamish River to the east. The geometry of the potentiometric surfaces between the nearshore-most well and the shoreline is complex and is further confounded by intermittent shoreline armoring and other buried infrastructure, which could serve as either a barrier or a conduit to flow. Groundwater and surface-water interactions in the lower Duwamish Waterway are inherently complex as a result of three overarching factors. First, water levels in the lower reaches of the Duwamish River vary daily by 11–16 ft because of tides from Puget Sound, which create large swings in the hydraulic gradient in the nearshore groundwater system. Second, the density and chemical composition of water in the Duwamish River change daily with the tides and seasonally, which constrains how river water entering the nearshore sediments interacts with discharging groundwater. Third, the nearshore subsurface and shoreline conditions are heterogenous because of extensive shoreline armoring over the past century, which governs the flow of groundwater and infiltrating river water. These unique features of groundwater and surface-water interactions in the lower Duwamish Waterway thus govern the transport of terrestrial contaminants to the lower Duwamish Waterway. Furthermore, the heterogenous aquifer properties in the lower Duwamish Waterway contribute to spatially and temporally dynamic contaminant-transport processes.

Washington

On-orbit calibration and performance of the EMIT imaging spectrometer

The Earth surface Mineral dust source InvesTigation (EMIT) is a remote visible to shortwave infrared (VSWIR) imaging spectrometer that has been operating onboard the International Space Station since July 2022. This article describes EMIT's on-orbit spectroradiometric calibration and validation. Accurate spectroscopy is vital to achieve consistent mapping results with orbital imaging spectrometers. EMIT takes a unique approach to this challenge, with just six optical elements, no shutter, and no onboard calibration systems. Its simple design focuses on uniformity and stability to enable vicarious spectroradiometric calibration. Our experiments demonstrate that this approach is successful, approaching the fidelity of manual field spectroscopy in some cases, and enabling new and more accurate products across diverse Earth science disciplines. EMIT achieves several notable firsts for an instrument of its class. It demonstrates successful on-orbit adjustments of Focal Plane Array (FPA) alignment with sub-micron precision. It offers spectral uniformity better than 98%. Optical artifacts in the measurement channels are at least three orders of magnitude below the primary solar-reflected surface signals. Its noise performance enables percent-level discrimination in the depths of mineral absorption features. In these aspects, EMIT satisfies the stringent performance needs for the next generation of VSWIR imaging spectrometers to observe the Earth's ecosystems, geology , and water resources.

Remote Sensing of Environment