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1,687 records · Page 57Linked to original sources

Detailed investigation of a coastal plain-Piedmont fault contact in northeastern Virginia

A trench across the Dumfries fault of the Stafford fault zone near Stafford, Virginia (see Mixon and Newell, 1976) exposed a high-angle reverse fault juxtaposing Paleozoic Quantico Slate and Cretaceous Potomac Group rocks. A system of subsidiary reverse faults and small scale normal faults disrupt the Coastal Plain strata adjacent to the main fault. Cross-cutting relations and stratigraphic details indicate that the subsidiary faults in the Cretaceous rocks document a history of episodic deformation, in part active during accumulation of the Coastal Plain strata. Slickensides and stereo net analysis of theorientation of subsidiary reverse faults, normal faults, and bedding indicate that, through time, faulting consistently included right lateral separation.

Virginia

Constraining mean landslide occurrence rates for non-temporal landslide inventories using high-resolution elevation data

Constraining landslide occurrence rates can help to generate landslide hazard models that predict the spatial and temporal occurrence of landslides. However, most landslide inventories do not include any temporal data due to the difficulties of dating landslide deposits. Here we introduce a method for estimating the mean landslide occurrence rate of deep-seated rotational and translational slides derived solely from high-resolution (≤3 m) elevation data and globally available estimates of the diffusion coefficient for sediment flux. The method applies a linear diffusion model to the roughest landslide deposits until they reach a representative non-landslide roughness distribution. This estimates the time for a landslide deposit to be unrecognizable in high-resolution digital elevation data, which we term the mean lifetime of the landslide. Using the mean lifetime and number of landslides within an area of interest, we can estimate the mean occurrence rate of landslides over that domain. We validate this approach using a comprehensive temporal inventory of landslides in western Oregon created using age-roughness curves that are calibrated with high-resolution elevation data and radiocarbon data. We find good agreement between our diffusion method and the existing age-roughness-derived estimates, producing mean lifetimes of 4500 and 5200 years (4% difference), respectively. Hazard maps produced using the two methodologies generally agree, with the maximum differences in landslide probability reaching 0.1. Due to the relative abundance of high-resolution elevation data compared with age-dated landslides, our method could help constrain landslide occurrence rates in areas previously considered unfeasible.

Oregon

Application of non-stationary shear-wave velocity randomization approach to predict 1D seismic site response and its variability at two downhole array recordings

Accounting for uncertainties in seismic site response is crucial to improving the performance of one-dimensional (1D) ground response analyses (GRAs) at downhole array recording sites. In addition to site effects, uncertainties in 1D-GRAs can also be contributed from the seismic source and/or path. Though often representing not more than one percent of the distance (path) from the source, site conditions are known to have an enormous influence on ground shaking. In this study, we focus on the site shear-wave velocity ( V S ) structure, which is the main ingredient for estimating the variability of site response. As such, V S can manifest aleatory uncertainties related to the effects of small-scale spatial heterogeneities within the near surface, thus V S can substantially modify ground shaking during earthquakes. We apply a novel V S randomization approach to propagate the small-scale heterogeneities of V S to estimate seismic site response within a non-stationary probabilistic framework. The randomization approach generates samples of V S profiles that are used to perform several 1D-GRAs and obtain an averaged site response and related variability. The proposed method is implemented on data recorded at two downhole array sites with different subsurface soil conditions: a soft soil site on Treasure Island (California, United States of America) and a rock outcrop site in Cadarache (South-East France). We show that synthetic surface-to-borehole transfer functions from 1D-GRAs provide an acceptable fit to the empirical transfer functions from low-motion earthquake records and succeed in reproducing most of the site-specific seismic response variability. The remaining mismatch between transfer functions is likely due to insufficient precision on the seismic bedrock and the impedance contrast. The variability in site response is discussed with emphasis on the role of V S small-scale heterogeneities, attenuation, and input motion incidence angle in ground motion variability for the site and soil conditions at both locations.

California

Digitizer Suite: The Albuquerque Seismological Laboratory Digitizer Testing Suite

Laboratory testing of digitizers and seismometers helps ensure that prior to deployment the instrumentation can produce high quality data and is operating within specifications. In this work we detail the software package called: the Albuquerque Seismological Laboratory (ASL) Digitizer Test Suite. This Java software package provides several algorithms to verify various performance parameters of digitizers commonly used for recording analog seismic instruments. The goal of these tests is not to be exhaustive, but to identify common failures that could compromise the integrity of seismic data being recorded on the digitizer. For example, Sandia National Laboratories (e.g., Slad and Merchant, 2018) routinely do comprehensive testing of digitizers for various monitoring missions. While these tests reports are valuable for comprehensively characterizing a recording system, it would be resource intensive to conduct such tests on every seismic recorder used in a network. We focus on tests that include ways to estimate the sensitivity, timing, self-noise, and clip-level of the digitizer, as well as the fidelity of the signal being recorded. The software is publicly available and provides a way for the community to verify the integrity of a digitizer using a minimum amount of outside equipment.

Seismological Research Letters

Evaluating the U.S. Geological Survey’s earthquake shaking hazard forecasts and their implications on seismic risk

We analyze the last six update cycles of the long-term probabilistic earthquake shaking hazard forecast from the U.S. Geological Survey (USGS) and discuss the changes in hazard estimates from the 1996 to the latest 2023 update of the National Seismic Hazard Model (NSHM) for the conterminous U.S. We summarize how our understanding of earthquake hazards has evolved over the last two decades and quantify the implications of changing hazards on people, buildings, and lifeline infrastructure. The net effect of changes in hazard estimates, with reference to the mean hazard from the 2023 NSHM update that has 2% probability of exceedance in 50 years, suggests an overall increase in total geographic areas facing very strong shaking levels (modified Mercalli Intensity (MMI) of VII or more) when compared with any of the previous cycles. This increase puts ~159.2 million people (an increase from 111.8 million when using the 2018 NSHM), ~47.3 million residential buildings (an increase from 32.5 million with the 2018 NSHM), and ~$25.6 trillion of economic exposure of all buildings (an increase from $17.4 trillion when using the 2018 NSHM) at risk from earthquakes. We demonstrate that small changes in hazard estimates do not necessarily imply small changes in risk estimates. Therefore, changes in risk estimates can be used to highlight key USGS NSHM updates for improving risk mitigation efforts.

Earthquake Spectra Journal

High-resolution transboundary vegetation community maps of the Sonoran and Mojave Desert ecoregion to support critical landscape conservation planning and habitat management needs

We produced a 30-m resolution binational land cover map of Bird Conservation Region 33 (BCR 33) for the U.S. North American Bird Conservation Initiative. The region covers large portions of the Sonoran and Mojave Deserts. The map can support the U.S. Fish and Wildlife Service (FWS) Migratory Bird Program’s recovery planning efforts and constitutes the first known binational land cover dataset spanning sections of the United States–Mexico border and using a consistent classification system for both countries. The mapped region includes 152 distinct land cover classes, covering a total area of 38,421,453 ha (148,345 mi 2 ), of which 13,148,345 ha (52,706 mi 2 ) are located in Mexico and 24,770,640 ha (95,639 mi 2 ) in the United States. We primarily used Landsat 8 (OLI) imagery, supplemented by limited ground surveys from two field campaigns, drone-based aerial data, and existing vegetation classification frameworks from both countries. The classification applied a data-fusion approach integrating 30-m Landsat 8 imagery, decadal phenology metrics from vegetation indices, and a random forest model trained mainly with datasets from a comprehensive national mapping project from the U.S. Geological Survey (USGS) GAP Analysis Project (GAP) and federal wildland fire agencies’ Landscape Fire and Resource Management Planning Tools (LANDFIRE) (GAP/LANDFIRE) [United States side] and the National Institute of Statistics and Geography (INEGI) [Mexico side] as well as land cover maps and opportunistic open-access and field observations. Mapping of the full BCR 33 region was carried out in two phases: 1) Phase I, the prototype map, covered a smaller portion of the transboundary area and identified 31 land cover classes, and 2) Phase II, the full BCR 33 map (refer to Figure 1), which resulted in 152 land cover classes. Using a Random Forest classifier, we achieved an overall prediction accuracy of 92% for the Phase I map and 87% for the Phase II full region map. This slight decrease can be attributed to working on a larger, more complex area with a greater number of land cover classes. No formal validation was conducted, aside from using a subset of the collected field observations and training data to assess model performance during and after training. The training sites were further verified using Google Earth (Google, 2026) imagery. Two undergraduate students who worked for over a year visually inspected imagery and open access public images to confirm each training site during model training using in-house developed, online, visual tools. A portion of this field training data was reserved for model validation, and the corresponding results are to be presented in later sections. The project developed an end-to-end, medium- and fine-resolution remote sensing–based data fusion mapping approach. This effort produced a map (Nagler et al., 2025) and the online tools to support a dynamic, live, online map for visualizing the transboundary vegetation communities in BCR 33. The toolset is currently hosted by the University of Arizona (UofA) Vegetation Index and Phenology (VIP) Lab to support FWS partners (https://vip.arizona.edu/viplab_data_explorer?LCM_BCR33). The online map is designed to allow rapid updates using new training, validation, or correction data, making it dynamic and maintainable. The approach we took established a framework for rapid updating and correction of land cover maps, as the model can be quickly retrained with new field observations, updated training data, or other sources. This enables dynamic mapping and change detection of the region’s vegetation. This framework is an advance in data fusion and crowdsourced mapping of complex, vulnerable regions, providing support to regional stakeholders and the wider user community. This transboundary map can inform the protection, conservation, and restoration of vegetation, habitat, and ecosystems, particularly for threatened and endangered species across the two nations using consistent and harmonized binational mapping systems. Beyond supporting land management decisions and stakeholders in the transboundary desert ecoregions, this BCR 33 mapping effort establishes a foundation for future rapid, low-cost, cross-border land cover mapping that can benefit and advance ecosystem management.

Arizona, Baja California, California, Nevada, Sina

Water use across the conterminous United States, water years 2010–20

Withdrawals of water for human use are fundamental to the evaluation of the Nation’s water availability. This chapter provides an analysis of public supply, crop irrigation, and thermoelectric power water use for the conterminous United States (CONUS) during water years 2010–20. These three categories account for about 90 percent of water withdrawals in the Nation. The values presented here are based on modeling approaches that estimate water use at temporal (monthly) and spatial scales (12-digit hydrologic unit code—small watersheds sized 50–100 square kilometers) compatible for integration into a broader national assessment of water availability. Models also provide an understanding of factors that influence water use. An estimated 244,817 million gallons per day (Mgal/d; 28,677 million cubic meters per month [Mm 3 /mo]) were withdrawn on average within the CONUS during water years 2010–20 from fresh water and saline water for crop irrigation, public supply, and thermoelectric power, with shares of 43, 14.5, and 42.5 percent for each of these categories, respectively. In the same period, estimated withdrawals and consumptive use (1) for public supply were 35,400 and 4,219 Mgal/d (4,081 and 486 Mm 3 /mo), respectively; (2) for crop irrigation were 105,497 and 75,698 Mgal/d (12,147 and 8,716 Mm 3 /mo), respectively; and (3) for thermoelectric power from fresh water were 82,656 and 2,904 Mgal/d (9,952 and 345 Mm 3 /mo), respectively. Withdrawals for these categories of water use are highly spatially variable, with western States dominated by crop irrigation and eastern States dominated by thermoelectric-power water use. Public supply accounts for the largest percentage of water use in several heavily populated northeastern States. Reliance on groundwater compared to surface water depends on the availability of water sources and the type of water use. For public supply, withdrawals from groundwater are greater than withdrawals from surface water in the Western aggregated hydrologic regions, whereas the balance shifts to more surface water for the rest of the CONUS. In all aggregated hydrologic regions, the predominant source of water for crop irrigation is groundwater. Most thermoelectric power facilities in the eastern half of the CONUS use surface water from freshwater and saline sources; most thermoelectric power facilities in the western half of the CONUS use groundwater.

conterminous United States

Effects of stochastically-simulated near-fault ground motions on soil liquefaction

The scarcity of historically recorded near-fault ground motions poses a challenge to systematically understanding the influence of near-fault effects on various types of seismic demands for engineering purposes. In particular, the current state of knowledge of the influence of ground-shaking intensity on soil liquefaction and its consequences does not specifically account for the effects of near-fault ground motion characteristics. In this study, the influence of near-fault ground motions on liquefaction triggering and lateral spreading are investigated using non-linear modeling of a hypothetical liquefiable soil column in the finite-element computational platform OpenSees subjected to simulated ground motion time series that represent strong earthquake shaking in the near field. The simulated ground motion time series and resulting datasets are based on a parametric stochastic model and are developed for a range of source and path parameters to represent a realistic variability of ground motion characteristics. Dependencies between ground motion intensity measures (IMs) and liquefaction demand parameters are investigated for near-fault pulse and nonpulse-like ground motion sets. Evolutionary IMs, such as cumulative absolute velocity (CAV) and the time-varying magnitude-adjusted peak ground acceleration (PGAM), are considered in developing liquefaction triggering probability density functions. Post-liquefaction triggering responses such as lateral spreading displacements are examined in relation to PGA M and CAV. The ground motion simulations are validated by comparing their liquefaction-capacity PGA M fragilities and post-triggering CAV vulnerability relationships to historical records from the 1994 Northridge earthquake in California, USA. Finally, a path forward for future studies that includes finding systematic differences in the IM-liquefaction demand relationships between near-fault and far-field stochastic ground motion sets is outlined.

Conference Paper

Insights on gas hydrate formation and growth within an interbedded sand reservoir from well logging at the Qiongdongnan Basin, South China Sea

Although variable well log resolution and its control on saturation estimation has been studied, it has not been directly applied to a specific location to explore the nature of gas hydrate within a sand reservoir. We applied in-situ measurements of resistivities, neutron porosity, and gamma ray at two sites in the Qiongdongnan Basin, South China Sea (QDN-W05–2021 and QDN-W08–2021) to investigate the reservoir parameters of a hydrate-bearing sand reservoir. Our results show that gas hydrate is distributed in 5 zones with a total thickness of 10.7 m and an average saturation of 69% at the QDN-W05–2021 site, while they are distributed in 2 zones with a total thickness of 4.3 m and an average saturation of 49% at the QDN-W08–2021 site. We found that variances in saturations estimated from lateral-extra deep button (RX), phase shift (P40H-P40L), and attenuation (A40H-A40L) resistivities within the laterally mapped continuous sand body were affected by the nature of gas hydrate occurrences. Results indicate gas hydrate forms and accumulates at the center of the sand layer and tends to be less or not present toward the top and base. Integrated with seismic data, the in-situ measurements provide insights in the evolution of a mushroom-shaped, hydrate-gas reservoir system. In the system, free gas is likely horizontally transported from the top-center of the gas chimney to the surrounding areas in the early stage dominated by a warm-gas environment, whereas hydrate forms in the opposite pathway starting from the surrounding areas in the following stage with temperature reducing. Our study suggests that high-resolution in-situ measurements not only are a tool to identify the physical properties, but also can be used to help explain the physical process of hydrate growth and accumulation.

Marine Geology

A comparison of electronic particle counting and pipette techniques in routine mud analysis

Electronic particle counting and pipette size-analysis techniques are compared for their relative effectiveness in large-scale routine mud analysis. Optimum laboratory procedures for conducting electronic analyses with a Model TA Coulter Counter are presented. Comparative electronic and pipette analyses conducted on the same samples resulted in equivalent precision for both techniques. Results of electronic analyses consistently showed size distributions significantly coarser than those obtained by pipette analyses. The laboratory efficiency of the relatively rapid electronic technique is far superior to that of the pipette technique, although more extensive precautionary measures are required to maintain a high level of analytical accuracy and precision. The quality of electronic analyses largely depends upon the effectiveness of standardized operational procedures established within the laboratory.

Open-File Report

Event classification, seismicity, and eruption forecasting at Great Sitkin Volcano, Alaska: 1999–2023

The frequency content of volcanogenic seismicity is often used to classify events and their spatial and temporal progression is then used to map subsurface volcanic processes. The progression of volcano-seismic events and associated source processes also plays a critical role in eruption forecasting. Here we develop and evaluate a computerized methodology for characterizing volcano-seismic event types using Frequency Index and Average Peak Frequency. We apply and test this technique at Great Sitkin Volcano, Alaska, classifying over 9000 hypocenters between 1999 and 2023. This 24-year time span covers periods of seismic quiescence, earthquake activity on nearby tectonic (bookshelf) faults, precursory unrest from 2016 to 2021, and the explosive onset in May 2021 of the ongoing effusive eruption. We use the spatial and temporal evolution of classified event types to map the active volcanic and tectonic processes, develop a conceptual model of the subsurface magmatic system, and perform a retrospective analysis of eruption forecasts at Great Sitkin Volcano between 2016 and the present. The classification and progression of hypocenters suggests the subsurface Great Sitkin Volcano magmatic system consists of a mid- to lower- crustal source zone between 10 and 40 km depth and an upper crustal magma storage area between −1 and 10 km depth (hypocenter depth is referenced to sea level and negative depths reflect height above sea level). The earliest precursors occurred in July 2016 and consisted of deep long-period and volcano-tectonic earthquakes at mid-crustal depths suggesting the subsequent unrest and eruption were triggered by a deeper intrusion of magma. This mid-crustal seismic activity was immediately followed by the onset upper-crustal long-period events and volcano-tectonic earthquakes VTs suggesting a strong linkage between the shallow and deeper portions of the magmatic system. The upper crustal area was likely capped by the 1974 lava dome until the magmatic explosion on May 26, 2021.

Alaska

Temperature

The “National Field Manual for the Collection of Water-Quality Data” (NFM) provides guidelines and procedures for U.S. Geological Survey (USGS) personnel who collect data used to assess the quality of the Nation’s surface-water and groundwater resources. This chapter, NFM A6.1, provides guidance and protocols for the measurement of temperature of air, of a surface-water body or in groundwater, which include the scientific basis of the measurement, selection and maintenance of equipment, calibration verification, troubleshooting, and procedures for measurement and reporting. It updates and supersedes USGS Techniques of Water-Resources Investigations, book 9, chapter A6.1, version 2.0, by Franceska D. Wilde. Temperature of air and water is routinely measured when water samples are collected, is often measured continually at USGS streamgages, and is a parameter regularly measured during laboratory and field experiments. The field method for measuring temperature described in this chapter is applicable to air and most natural waters. Before 2017, the NFM chapters were released in the USGS Techniques of Water-Resources Investigations series. Effective in 2018, new and revised NFM chapters are being released in the USGS Techniques and Methods series; this series change does not affect the content and format of the NFM. More information is in the general introduction to the NFM (USGS Techniques and Methods, book 9, chapter A0) at https://doi.org/10.3133/tm9A0 . The authoritative current versions of NFM chapters are available in the USGS Publications Warehouse at https://pubs.usgs.gov/ . Comments, questions, and suggestions related to the NFM can be addressed to nfm@usgs.gov .

Techniques and Methods

Long‐period ground motions from dynamic rupture simulations of large earthquakes on the creeping Hayward–Calaveras–Rodgers Creek fault system

he Hayward, Calaveras, and Rodgers Creek faults in the San Francisco Bay region of California have a high probability of producing a large earthquake in the next decades. Although these faults creep, the creep is insufficient to keep up with their relatively rapid slip rates on their deepest sections, so they have been storing tectonic strain since their last large earthquakes, with the Hayward’s and Rodgers Creek’s more than 150 yr ago. We do not know what the next large Hayward–Calaveras–Rodgers Creek earthquakes will look like or how strongly they will shake the San Francisco Bay region. Harris et al. (2021) used the 3D dynamic (spontaneous) rupture method to simulate large earthquakes on these creeping faults. In this article, we examine the resulting simulated long‐period ( T > 1 s) ground shaking from 0 to 50 km distance, for earthquakes nucleating on the Hayward fault and earthquakes nucleating on the Rodgers Creek fault. We compare these simulated long‐period ground motions with the Boore et al. (2014) well‐established empirically based ground‐motion model suitable for the slowest material velocity in our 3D velocity structure. We find that the simulated long‐period ground motions from the creeping‐fault earthquake scenarios produce a reasonable agreement with the empirical expectations if frictional cohesion is included only where it is appropriate.

California

High-precision earthquake catalog for Minto Flats fault zone, central Alaska, reveals complex and conjugate faulting

The Minto Flats fault zone (MFFZ) in central Alaska is a left‐lateral strike‐slip fault system situated between the continental‐scale right‐lateral Denali and Kaltag‐Tintina faults. The MFFZ has the potential to generate magnitude 7 earthquakes, and it hosted a magnitude 6 earthquake in 1995. It has also produced exotic events, such as very‐low‐frequency earthquakes and nucleation signals. We use network‐matched filtering and relative earthquake relocation techniques to derive a detailed catalog of earthquake locations for the MFFZ. The catalog spans from August 2014 to December 2019, a time period including 13 temporary seismic stations in the region. Our results provide the most complete catalog for the MFFZ and include deeper events, clusters of shallow seismicity, and a complex and segmented fault structure not observed in the original regional catalog. We document right‐lateral strike‐slip faulting, conjugate to the main northeast‐striking left‐lateral faults of the MFFZ. Below Nenana basin, the relocated seismicity reveals northwest‐dipping left‐lateral faults, supporting the inference that deep crustal active faulting is associated with recent basin deformation.

Alaska

The addition of 144Nd atomic mass to routine ICP-MS analysis as a Quick Screening Tool for Approximating Rare Earth Elements (Q-STAR) in natural waters

Rare earth elements (REEs) are a class of critical minerals, all of which can have supply chain vulnerability that impacts economic security. These elements are widely measured in environmental matrices via inductively coupled plasma mass spectrometry (ICP-MS); however, successful quantification can require time-consuming, sample-specific optimization. While a sample-by-sample approach is appropriate for targeted quantification studies, this approach is not suitable for mineral exploration efforts where rapidly screening thousands of samples for the presence of REEs is desired. Here, we demonstrated the use of a Quick Screening Tool for Approximating REEs (Q-STAR) to detect REEs in surface water and groundwater matrices, collected as part of existing environmental studies. A mass-to-charge ratio of 144 ( m / z = 144) was added to an ICP-MS method to screen for REEs in filtered water samples submitted for metals analyses to the U.S. Geological Survey (USGS) National Water Quality Laboratory. We detected the presence of REEs above a reference threshold of 1200 counts per second in 18 % of pre-selected 6626 samples. Using this screened dataset, we mapped estimated dissolved REE concentrations across the United States in relation to ecoregions and underlying geology. Data are constrained to where sample collection took place but nevertheless show estimated aqueous dissolved REE concentrations on a geographic scale that has not yet been studied. To validate Q-STAR, REEs were measured in a USGS standard reference sample, a subset of 88 archived filtered water samples, and in fresh filtered surface water samples. Our targeted analyses demonstrated a strong linear relationship between Q-STAR predicted and measured values in all archived samples for Nd (r 2 = 0.94), and light REEs (LREEs) such as lanthanum (La) (r 2 = 0.93), praseodymium (Pr) (r 2 = 0.94) and samarium (Sm) (r 2 = 0.94). Using Q-STAR screen values, nine field sites were identified and surface water samples recollected to confirm the continued presence of Nd and LREEs. Q-STAR can be used to screen an unlimited number of water samples for the presence of REEs prior to time-intensive and costly quantitative analyses and to generate large REE datasets for further investigation.

Journal of Geochemical Exploration

Developing, testing, and communicating earthquake forecasts: Current practices and future directions

While deterministically predicting the time and location of earthquakes remains impossible, earthquake forecasting models can provide estimates of the probabilities of earthquakes occurring within some region over time. To enable informed decision-making of civil protection, governmental agencies, or the public, Operational Earthquake Forecasting (OEF) systems aim to provide authoritative earthquake forecasts based on current earthquake activity in near-real time. Establishing OEF systems involves several nontrivial choices. This review captures the current state of OEF worldwide and analyzes expert recommendations on the development, testing, and communication of earthquake forecasts. An introductory summary of OEF-related research is followed by a description of OEF systems in Italy, New Zealand, and the United States. Combined, these two parts provide an informative and transparent snapshot of today's OEF landscape. In Section 4, we analyze the results of an expert elicitation that was conducted to seek guidance for the establishment of OEF systems. The elicitation identifies consensus and dissent on OEF issues among a non-representative group of 20 international earthquake forecasting experts. While the experts agree that communication products should be developed in collaboration with the forecast user groups, they disagree on whether forecasting models and testing methods should be user-dependent. No recommendations of strict model requirements could be elicited, but benchmark comparisons, prospective testing, reproducibility, and transparency are encouraged. Section 5 gives an outlook on the future of OEF. Besides covering recent research on earthquake forecasting model development and testing, upcoming OEF initiatives are described in the context of the expert elicitation findings.

Reviews of Geophysics

Per- and polyfluoroalkyl substances in waters associated with oil and gas development in the Denver Basin

Use of per- and polyfluoroalkyl substances (PFAS) in the petroleum industry could be a cause for concern due to the large volumes of produced water (PW) generated during oil and gas extraction, the reuse of these wastes in water-stressed regions, and adverse health outcomes related to PFAS exposures. However, PW PFAS characterization is nearly absent in the literature, and hydraulic fracturing (HF) chemical disclosures often omit the identities of additives as proprietary. Here we evaluate PFAS in PW samples from three petroleum wells in the Denver Basin during their first year of production. Total concentrations of targeted PFAS (Σ 40 PFAS) were < 35 ng/L in PW samples, with short-chain PFAS like perfluorobutanoic acid persisting throughout the sampled duration. Analysis of freshwater inputs for hydraulic fracturing (Σ 40 PFAS ~ 113 ng/L) and mixed fracture fluid (Σ 40 PFAS ~ 69 ng/L) indicated much of the targeted PFAS content was derived from the input water, and not from HF additives, however samples subjected to oxidation indicated the presence of PFAS precursors that would not be detected by targeted analysis. This study highlights that while PFAS content is low in the studied PWs, the potential for redistribution of PFAS in the environment may be a consideration for reuse applications.

Colorado, Nebraska, Wyoming

A review of post-wildfire adaptations of surface-water-quality models: Synthesis, gaps, and opportunities

As wildfires increasingly affect water-supply watersheds, the demand for models to predict water-quality responses is increasing. This work reviews and synthesizes existing post-wildfire applications of water-quality models in the context of geographic and ecohydrological distribution, hydrologic and water-quality response process representation, model parameterization, model and input data scales, model calibration data availability, as well as calibration and performance evaluation approaches. Emphasis is placed on models that simulate water-quality output, rather than sediment and erosional response as the primary focus. Here, identified gaps and opportunities to advance the post-wildfire application of water-quality models include: 1. applying models in under-represented geographic and ecohydrologic regions, 2. simulating multiple streamflow generation mechanisms, including groundwater, with an emphasis on shifting dominant flow pathways as the landscape recovers following wildfire, 3. adding studies that include the simulation of metals, 4. incorporating more biogeochemical and in-stream processes to model applications, 5. applying finer spatial and temporal resolution of precipitation data input as well as finer spatial resolution hydrologic response units, 6. implementing fully distributed grid or element models or finer resolution response units to capture burn severity heterogeneity, 7. collecting enhanced water-quality data for model calibration and validation, 8. conducting model-intercomparison studies, and 9. developing model parameter value guidance in post-wildfire applications. These identified gaps and opportunities may assist users in deciding on key processes and approaches to consider in modeling post-wildfire water-quality conditions.

Science of the Total Environment