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Geology of the Stegall Mountain 7.5-minute quadrangle, Shannon and Carter Counties, south-central Missouri

The bedrock exposed in the Stegall Mountain Quadrangle, Missouri, comprises Mesoproterozoic aged volcanic rocks overlain by Late Cambrian and Early Ordovician aged dolomite, sandstone, and chert. The sedimentary rocks are nearly flat-lying except where they drape around knobs of the volcanic rocks or where they are adjacent to faults. The carbonates are karstified and the area contains numerous sinkholes, springs, caves, and losing-streams. This map is one of several being produced under the U.S. Geological Survey National Cooperative Geologic Mapping Program to provide geologic data applicable to land-use problems in the Ozarks of south-central Missouri. Ongoing and potential industrial and agricultural development in the Ozarks region has presented issues of ground-water quality in karst areas. A National Park in this region (Ozark National Scenic Riverways, Missouri ) is concerned about the effects of activities in areas outside of their stewardship on the water resources that define the heart of this Park. This task applies geologic mapping and karst investigations to address issues surrounding competing land use in south-central Missouri. This task keeps geologists from the USGS associated with the park and allows the Parks to utilize USGS expertise and aid the NPS on how to effectively use geologic maps for Park management. For more information see: http://geology.er.usgs.gov/eespteam/Karst/index.html

IMAP↗

Geologic map of the Van Buren South quadrangle, Carter County, Missouri

The bedrock exposed in the Van Buren South quadrangle, Missouri, comprises Late Cambrian and Early Ordovician aged dolomite, sandstone, and chert. The sedimentary rocks are nearly flat-lying except where they are adjacent to faults. The carbonate rocks are karstified and the area contains numerous sinkholes, springs, caves, and losing-streams. This map is one of several being produced under the U.S. Geological Survey National Cooperative Geologic Mapping Program to provide geologic data applicable to land-use problems in the Ozarks of south-central Missouri. Ongoing and potential industrial and agricultural development in the Ozarks region has presented issues of ground-water quality in karst areas. A National Park in this region (Ozark National Scenic Riverways, Missouri ) is concerned about the effects of activities in areas outside of their stewardship on the water resources that define the heart of this Park. This task applies geologic mapping and karst investigations to address issues surrounding competing land use in south-central Missouri. This task keeps geologists from the USGS associated with the park and allows the Parks to utilize USGS expertise and aid the NPS on how to effectively use geologic maps for Park management. For more information see: http://geology.er.usgs.gov/eespteam/Karst/index.html

Missouri↗

Geologic Map of the Big Spring Quadrangle, Carter County, Missouri

The bedrock exposed in the Big Spring quadrangle of Missouri comprises Late Cambrian and Early Ordovician aged dolomite, sandstone, and chert. The sedimentary rocks are nearly flat lying except where they are adjacent to faults. The carbonate rocks are karstified, and the area contains numerous sinkholes, springs, caves, and losing streams. This map is one of several being produced under the U.S. Geological Survey (USGS) National Cooperative Geologic Mapping Program to provide geologic data applicable to land-use problems in the Ozarks of south-central Missouri. Ongoing and potential industrial and agricultural development in the Ozarks region has presented issues of ground-water quality in karst areas. A national park in this region (Ozark National Scenic Riverways, Missouri) is concerned about the effects of activities in areas outside of their stewardship on the water resources that define the heart of this park. This task applies geologic mapping and karst investigations to address issues surrounding competing land use in south-central Missouri. This task keeps geologists from the USGS associated with the park and allows the park to utilize USGS expertise and aid the NPS on how to effectively use geologic maps for park management. For more information, see: http://geology.er.usgs.gov/eespteam/Karst/index.html

IMAP↗

Gulf of Mexico integrated science - Tampa Bay study, the impact of groundwater and contaminants on Tampa Bay

Despite the recreational and economic value of coastal bays and estuaries, these ecosystems are often among our most 'troubled' natural environments. Urbanization, agriculture, mining, and shipping are just a few activities that can have a profound and lasting impact on the coastal zone. In order to maintain a healthy coastal ecosystem, it is crucial to develop reasonable management practices around expert scientific information. We still have much to learn about the quantity and quality of groundwater being discharged into Tampa Bay, Florida. We also need to improve our knowledge of a wide range of contaminants entering the bay and must be able to determine where they accumulate in seafloor sediments. Such buried contaminants can potentially be harmful to biota if they are released to the water column. U.S. Geological Survey (USGS) scientists and research partners from the University of South Florida (USF), the University of Florida (UF), and the Florida Marine Research Institute (FMRI) are mapping sources of groundwater, measuring groundwater flow into Tampa Bay, and assessing the impact of contaminants and sediments on bay water quality and ecosystem health.

Open-File Report↗

Geologic Map of the Big Spring Quadrangle, Carter County, Missouri

The bedrock exposed in the Big Spring quadrangle of Missouri comprises Late Cambrian and Early Ordovician aged dolomite, sandstone, and chert. The sedimentary rocks are nearly flat lying except where they are adjacent to faults. The carbonate rocks are karstified, and the area contains numerous sinkholes, springs, caves, and losing streams. This map is one of several being produced under the U.S. Geological Survey (USGS) National Cooperative Geologic Mapping Program to provide geologic data applicable to land-use problems in the Ozarks of south-central Missouri. Ongoing and potential industrial and agricultural development in the Ozarks region has presented issues of ground-water quality in karst areas. A national park in this region (Ozark National Scenic Riverways, Missouri) is concerned about the effects of activities in areas outside of their stewardship on the water resources that define the heart of this park. This task applies geologic mapping and karst investigations to address issues surrounding competing land use in south-central Missouri. This task keeps geologists from the USGS associated with the park and allows the park to utilize USGS expertise and aid the NPS on how to effectively use geologic maps for park management. For more information, see: http://geology.er.usgs.gov/eespteam/Karst/index.html

Scientific Investigations Map↗

Water Withdrawals, Use, and Wastewater Return Flows in the Concord River Basin, Eastern Massachusetts, 1996-2000

Water withdrawals, use, and wastewater return flows for the Concord River Basin were estimated for the period 1996-2000. The study area in eastern Massachusetts is 400 square miles in area and includes the basins of two major tributaries, the Assabet and Sudbury Rivers, along with the Concord River, which starts at the confluence of the two tributaries. About 400,000 people lived in the basin during the study period, on the basis of an analysis of census data, land use, and population density. Public water systems served an estimated 87 percent of the people in the basin, and public wastewater systems served an estimated 65 percent of the basin population. The estimates of water withdrawals, use, wastewater return flows, and imports and exports for the Concord River Basin and 25 subbasins provide information that can be used in hydrologic analyses such as water budgets and can guide water-resources allocations for human and environmental needs. Withdrawals in the basin were estimated at 12,700 million gallons per year (Mgal/yr) during the study period, of which 10,100 Mgal/yr (about 80 percent) were withdrawn by public water-supply systems and 2,650 Mgal/yr were self-supplied by individual users. Water use in the basin and subbasins was estimated by using water withdrawals, average per capita use rates (about 72 gallons per day per person), land-use data, estimated population densities, and other information. Total water use in the basin, which included imports, was 19,200 Mgal/yr and was provided mostly (86.2 percent) by public supply. Domestic use (11,300 Mgal/yr) was the largest component, accounting for about 60 percent of total water use in the basin. Commercial use (3,770 Mgal/yr), industrial use (1,330 Mgal/yr), and agricultural use (including golf-course irrigation; 562 Mgal/yr) accounted for 19.6, 6.9, and 2.9 percent, respectively, of total use. Water that was unaccounted for in public-supply systems was estimated at 2,260 Mgal/yr, or 11.8 percent of total water use in the basin. Wastewater return flows discharged in the basin were estimated at 11,800 Mgal/yr, of which 6,620 Mgal/yr were discharged from municipal wastewater-treatment facilities to surface waters and 5,190 Mgal/yr were self-disposed through septic systems to ground water; wastewater disposed through septic systems was generated by both public- and self-supply use. Water use and management in the Concord River Basin resulted in an estimated import of 6,460 Mgal/yr of potable water for public supply and an estimated export of 6,590 Mgal/yr of wastewater. Water was imported into the Assabet, Sudbury, and Lower Concord (the area draining directly to the Concord River) River Basins for public supply. Wastewater was imported into the Assabet River Basin, but exported from the Sudbury and Lower Concord River Basins. Of the 25 subbasins in the Concord River Basin for which water use was analyzed, 20 subbasins imported potable water, 4 subbasins exported potable water (Fort Meadow Brook, Indian Brook, Lower Sudbury River, and Whitehall Brook), and potable water was neither imported nor exported in one subbasin (Elizabeth Brook). Wastewater was imported into the Assabet Headwaters, Assabet Main Stem, and Hop Brook subbasins; wastewater was neither imported to nor exported from the Elizabeth Brook, Nashoba Brook, and Pine Brook subbasins; and wastewater was exported from all other subbasins. Water use and management in the basin also resulted in a net transfer of water from ground water to surface water, discharged as wastewater, of about 4,000 Mgal/yr.

Scientific Investigations Report↗

National water summary 1986: Hydrologic events and ground-water quality

Ground water is one of the most important natural resources of the United States and degradation of its quality could have a major effect on the welfare of the Nation. Currently (1985), ground water is the source of drinking water for 53 percent of the Nation's population and for more than 97 percent of its rural population. It is the source of about 40 percent of the Nation's public water supply, 33 percent of water for irrigation, and 17 percent of freshwater for selfsupplied industries. Ground water also is the source of about 40 percent of the average annual streamflow in the United States, although during long periods of little or no precipitation, ground-water discharges provide nearly all of the base streamflow. This hydraulic connection between aquifers and streams implies that if a persistent pollutant gets into an aquifer, it eventually could discharge into a stream. Information presented in the 1986 National Water Summary clearly shows that the United States has very large amounts of potable ground water available for use. Although naturally occurring constituents, such as nitrate, and human-induced substances, such as synthetic organic chemicals, frequently are detected in ground water, their concentrations usually do not exceed existing Federal or State standards or guidelines for maximum concentrations in drinking water. Troublesome contamination of ground water falls into two basic categories related to the source or sources of the contamination. Locally, high concentrations of a variety of toxic metals, organic chemicals, and petroleum products have been detected in ground water associated with point sources such as wastedisposal sites, storage-tank leaks, and hazardous chemical spills. These types of local problems commonly occur in densely populated urban areas and industrialized areas. Larger, multicounty areas also have been identified where contamination frequently is found in shallow wells. These areas generally are associated with broad-scale, or nonpoint, sources of contamination such as agricultural activities or highdensity domestic waste disposal (septic systems) in urban centers. At present, only a very small percentage of the total volume of potable ground water in the United States is contaminated from both point and nonpoint sources; however, available data, especially data about the occurrence of synthetic organic and toxic substances, generally are inadequate to determine the full extent of ground-water contamination in the Nation's aquifers or to define trends in groundwater quality. Most information about the occurrence of these substances has come from the study of individual sites or areas where contamination had already been detected or suspected. Management and protection of ground water present a major challenge to the Nation. Current and projected costs of detection and cleanup of existing ground-water contamination are staggering and, even so, complete removal of pollutants from ground water in the vicinity of some waste sites might not be technically feasible. At all levels of government, the task of protecting the resource for its most beneficial uses is difficult and controversial. Despite increasing awareness that some of the Nation's ground water is contaminated with a variety of toxic metals, synthetic organic chemicals, radionuclides, pesticides, and other contaminants that might present a long-term risk to human health, public policy towards ground-water protection is still in the formative stages. Despite increasing efforts devoted to ground-water protection by State and Federal regulatory and resource-management agencies, the extent of ground-water contamination is likely to appear to increase over the next few years because more agencies will be searching for evidence of contamination, and they will be using increasingly sensitive analytical procedures. Increased technology and expanded monitoring activities probably will detect the effects of past contamination and land uses on water quality. The significant time lag between a waterquality change in one part of an aquifer system and the effects of that change at a downgradient site, such as a well, results from the generally slow movement of ground water. This lag between cause and observed effect needs to be considered in evaluating the effectiveness of current and future ground-water policies and remedial measures. Conclusive answers to questions about the location, extent, and severity of ground-water contamination, and about trends in ground-water quality, must await further collection and analysis of data from the Nation's aquifers. Generalizations, however, can be made, and the 1986 National Water Summary, which describes the natural quality of ground-water resources in each State and the major contamination problems that have been identified as of 1986, provides a national perspective of the ground-water-quality situation. The 1986 National Water Summary follows the format of previous volumes. It contains three parts, and the contents of each of these parts are highlighted below.

Water Supply Paper↗

Sagebrush ecosystems: current status and trends.

The sagebrush ( Artemisia spp .) biome has changed since settlement by Europeans. The current distribution, composition and dynamics, and disturbance regimes of sagebrush ecosystems have been altered by interactions among disturbance, land use, and invasion of exotic plants. In this chapter, we present the dominant factors that have influenced habitats across the sagebrush biome. Using a large-scale analysis, we identified regional changes and patterns in “natural disturbance”, invasive exotic species, and influences of land use in sagebrush systems. Number of fires and total area burned has increased since 1980 across much of the sagebrush biome. Juniper ( Juniperus spp. ) and pinyon (Pinus spp.) woodlands have expanded into sagebrush habitats at higher elevations. Cheatgrass ( Bromus tectorum ), an exotic annual grass, has invaded much of lower elevation, more xeric sagebrush landscapes across the western portion of the biome. Consequently, synergistic feedbacks between habitats and disturbance (natural and human-caused) have altered disturbance regimes, plant community dynamics and contributed to loss of sagebrush habitats and change in plant communities. Habitat conversion to agriculture has occurred in the highly productive regions of the sagebrush biome and influenced up to 56% of the Conservation Assessment area. Similarly, urban areas, and road, railroad, and powerline networks fragment habitats, facilitate predator movements, and provide corridors for spread of exotic species across the entire sagebrush biome. Livestock grazing has altered sagebrush habitats; the effects of overgrazing combined with drought on plant communities in the late 1880s and early 1900s still influences current habitats. Management of livestock grazing has influenced sagebrush ecosystems by habitat treatments to increase forage and reduce sagebrush and other plant species unpalatable to livestock. Fences, roads, and water developments to manage livestock movements have further influenced the landscape and increased access into sagebrush habitats. Energy development also influenced sagebrush landscapes by construction of wells, access roads, and pipelines. Treatments to restore sagebrush are becoming a major emphasis of land management agencies. However, revegetation and rehabilitation treatments are limited by the financial, biological, and technological resources needed to restore sagebrush landscapes that function at the spatial and temporal scales used by sage-grouse ( Centrocercus urophasianus )

Book chapter↗

Integrating sea level rise scenarios into Everglades restoration planning

One of the largest and most expensive restoration efforts in the world is occurring in the Everglades, a sub-tropical freshwater wetland system located in southern Florida. This unique ecosystem supports several endangered species, provides flood control for Florida’s large urban population, and provides water for both agriculture and drinking supply within the state. The Comprehensive Everglades Restoration Plan (CERP), authorized by Congress in 2000, guides federal, state, and local efforts to build the infrastructure necessary to bring more water into the Everglades and restore its ecological integrity, while balancing other water-related needs such as water supply and flood protection in the human environment. The Everglades encompasses the southern coast of Florida and restoration efforts are likely to be impacted by climate-induced sea level rise. However, currently, many project planning studies do not formally incorporate the potential impacts of sea level rise when evaluating restoration plan outcomes. Resource managers and project planners require methods and tools to confidently incorporate scenarios of sea level rise into their evaluations. The U.S. Geological Survey (USGS) and partners from the University of Florida worked with project planners from multiple agencies to identify restoration questions for consideration when addressing sea level rise. In addition, our project team sought to understand the types of sea level rise decision-support tools that would be of interest, and then worked with Everglades restoration managers and project planners to develop those tools. The tools developed by this project can be used by project planners to inform their decision-making abilities when considering multiple restoration plans across the Everglades landscape. Specifically, the novel ways to visualize output information from ecological models that came of this project can help project planners compare alternative restoration plans that include potential sea level rise impacts. This effort demonstrates how incorporating sea level rise scenarios into Everglades restoration project planning can help managers decide whether projects will maintain or improve ecological integrity and evaluate water availability for wildlife and humans.

Final Report↗

Bird community response to field-level integration of prairie strips

Grassland birds are under threat worldwide due to loss of habitat to agriculture. Prairie strips are a new agricultural conservation practice composed of linear strips of reconstructed diverse, native, herbaceous, perennial vegetation designed to promote land sharing among agriculture and biodiversity, while also addressing soil and water conservation goals. We evaluated bird community response to establishment of prairie strips on commercial row-crop fields (corn [( Zea mays ] and soybean [ Glycine max ]) in Iowa, USA compared to controls fields without prairie strips, from 2015 to 2020. We found a 2.94-fold higher density of grassland birds on fields with prairie strips compared to control fields, and a 1.87-fold higher density of birds overall. Time since prairie strip establishment was a significant predictor of grassland bird density, with significant increases between years 1 and 2 and years 3 and 4. Species with the strongest positive response to prairie strips were Red-winged Blackbird ( Agelaius phoeniceus ), Common Yellowthroat ( Geothlypis trichas ), Western Meadowlark ( Sturnella neglecta ) and two species of greatest conservation need: Dickcissel ( Spiza americana ) and Eastern Meadowlark ( Sturnella magna ). Diversity measures (e.g., Shannon’s and Simpson’s indices) did not differ between fields with prairie strips versus those without. Prairie strips provide quality breeding habitat for a suite of species, including grassland species and those of conservation concern. While improving several bird community measures, prairie strips do not provide habitat for area-sensitive grassland birds. Larger grassland patches are needed, potentially managed as land-sparing reserves, to achieve overall biodiversity goals in agricultural landscapes.

Iowa↗

Environmental impacts of petroleum production--Initial results from the Osage-Skiatook Petroleum Environmental Research Sites, Osage County, Oklahoma

Exploration for and production of petroleum have caused major detrimental impacts to soils, surface and ground waters, and the local ecosystems in the United States. These impacts arise primarily from the improper disposal of large volumes of saline water produced with oil and gas, from accidental hydrocarbon and produced water releases, and from abandoned oil wells that were not correctly sealed. It is important to understand the long-term and short-term effects of produced water and hydrocarbon releases from these sites in order to develop risk-based remediation plans. Remediation is particularly needed in aging and depleted fields where land use is changing from petroleum production to residential, agricultural or recreational uses. About 20 scientists from the USGS and other governmental agencies and academia are involved in a multidisciplinary investigation to study the transport, fate, and natural attenuation of inorganic salts, trace metals, organic compounds and radionuclides present in produced water, and their impacts at the Osage-Skiatook Petroleum Environmental Research (OSPER) "A" and "B" sites, located on the Osage Reservation in Osage County, Oklahoma. Stakeholders in the project include the Osage Nation, which holds the mineral rights, the Bureau of Indian Affairs with trust responsibility, and the Army Corps of Engineers, which owns the surface rights at these sites and manages adjacent Skiatook Lake. The 4250-hectare Skiatook Lake provides drinking water to local Tulsa suburban communities and a rural water district, and offers recreational fishing and boating opportunities to tens of thousands of visitors each year. Approximately 1.5 and 1.0 hectare of land at the OSPER "A" (depleted Lester lease) and "B" (active Branstetter lease) sites, respectively, are affected by salt scarring, tree kills, soil salinization and brine and petroleum contamination due to the leakage of produced water and associated hydrocarbons from brine pits and accidental releases from active and inactive pipes and tank batteries. The leases are typical of many depleted and aging petroleum fields in Osage County, which ranks among the top oil and gas producing counties in Oklahoma with about 39,000 wells. Oil and gas production has occurred in Osage county for over one hundred years, but current production is mainly from stripper wells (averaging ~2.8 bbl/d oil and >30 bbl/d brine) that are shallow, mostly 300-700 m in depth, and produce from several sandstones of Pennsylvanian age. Results to date show that the produced water source is a Na-Ca-Cl brine (~150,000 mg/L total dissolved solids), with relatively high concentrations of Mg, Sr, and NH4, but low SO4 and H2S. With the exception of Fe and Mn, the concentrations of trace metals are low. Results also show that some and, eventually, the bulk, of inorganic salts and some dissolved organic species in the released brine from both sites will reach Skiatook Lake. Results at the "A" site show that the salts have essentially been removed from the sandy soil which formed in a surficial layer of eolian sand, but degraded and weathered oil persists on the surface of old oil and brine pits, close to sites of old tanks, on old channels that carried oil from tanks to the oil pits and other impacted areas. Results also show a plume of high salinity water (5,000-30,600 mg/L TDS) is present at intermediate depths that extend from below the old oil and brine pits to Skiatook Lake. No liquid petroleum was found in the contaminated groundwater, but soluble petroleum byproducts, including organic acid anions and other volatile organic compounds (VOCs) are present. Results to date clearly show that significant amounts of salts from produced-water releases and petroleum hydrocarbons still remain in the soils and rocks of the impacted area after more than 60 years of natural attenuation. At the "B" site significant amounts of produced water from the two active brine pits percolate into the surficial rocks and flow towards the Skiatook Reservoir; but only minor amounts of liquid petroleum leave the brine pits and reach the Skiatook Reservoir. At both sites, results show that the chemical composition of released brines is modified further by sorption, mineral precipitation/dissolution, transpiration, volatilization and bacterially mediated oxidation/reduction reactions.

Oklahoma↗

U.S. Geological Survey Toxic Substances Hydrology Program: Proceedings of the technical meeting, Charleston, South Carolina, March 8-12, 1999: Volume 1 (Part A)

This report contains papers presented at the seventh Technical Meeting of the U.S. Geological Survey (USGS), Toxic Substances Hydrology (Toxics) Program. The meeting was held March 8-12, 1999, in Charleston, South Carolina. Toxics Program Technical Meetings are held periodically to provide a forum for presentation and discussion of results of recent research activities. The objectives of these meetings are to: Present recent research results to essential stakeholders, Encourage synthesis and integrated interpretations among scientists with different expertise who are working on a contamination issue, and Promote exchange of ideas among scientists working on different projects and issues within the Toxics Program. The Proceedings is published in three volumes. Volume 1 contains papers that report on results of research on contamination from hard-rock mining. Results include research on contamination from hard rock mining in arid southwest alluvial basins, research on hard rock mining in mountainous terrain, and progress from the USGS Abandoned Mine Lands Initiative. This Initiative is designed to develop a watershed-based approach to characterize and remediate contamination from abandoned mine lands and transfer technologies to Federal land management agencies and stakeholders. Volume 2 contains papers on contamination of hydrologic systems and related ecosystems. The papers discuss research on the response of estuarine ecosystems to contamination from human activities. They include research on San Francisco Bay; mercury contamination of aquatic ecosystems; and investigation of the occurrence, distribution, and fate of agricultural chemicals in the Mississippi River Basin. This volume also contains results on development and reconnaissance testing of new methods to detect emerging contaminants in environmental samples. Volume 3 contains papers on subsurface contamination from point sources. The papers discuss research on: hydrocarbons and fuel oxygenates at gasoline release sites; ground-water contamination by crude oil; complex contaminant mixtures from treated wastewater discharges; waste disposal and subsurface transport of contaminants in arid environments; ground water and surface water affected by municipal landfill leachate; natural attenuation of chlorinated solvents; and characterizing flow and transport in fractured rock aquifers. In all, the more than 175 papers contained in this proceedings reflect the contributions of more than 350 scientists who are co-authors. These scientists are from across the USGS, as well as from universities, other Federal and State agencies, and industry.

Water-Resources Investigations Report↗

U.S. Geological Survey Toxic Substances Hydrology Program: Proceedings of the technical meeting, Charleston, South Carolina, March 8-12, 1999: Volume 2 (Part B)

This report contains papers presented at the seventh Technical Meeting of the U.S. Geological Survey (USGS), Toxic Substances Hydrology (Toxics) Program. The meeting was held March 8-12, 1999, in Charleston, South Carolina. Toxics Program Technical Meetings are held periodically to provide a forum for presentation and discussion of results of recent research activities. The objectives of these meetings are to: Present recent research results to essential stakeholders, Encourage synthesis and integrated interpretations among scientists with different expertise who are working on a contamination issue, and Promote exchange of ideas among scientists working on different projects and issues within the Toxics Program. The Proceedings is published in three volumes. Volume 1 contains papers that report on results of research on contamination from hard-rock mining. Results include research on contamination from hard rock mining in arid southwest alluvial basins, research on hard rock mining in mountainous terrain, and progress from the USGS Abandoned Mine Lands Initiative. This Initiative is designed to develop a watershed-based approach to characterize and remediate contamination from abandoned mine lands and transfer technologies to Federal land management agencies and stakeholders. Volume 2 contains papers on contamination of hydrologic systems and related ecosystems. The papers discuss research on the response of estuarine ecosystems to contamination from human activities. They include research on San Francisco Bay; mercury contamination of aquatic ecosystems; and investigation of the occurrence, distribution, and fate of agricultural chemicals in the Mississippi River Basin. This volume also contains results on development and reconnaissance testing of new methods to detect emerging contaminants in environmental samples. Volume 3 contains papers on subsurface contamination from point sources. The papers discuss research on: hydrocarbons and fuel oxygenates at gasoline release sites; ground-water contamination by crude oil; complex contaminant mixtures from treated wastewater discharges; waste disposal and subsurface transport of contaminants in arid environments; ground water and surface water affected by municipal landfill leachate; natural attenuation of chlorinated solvents; and characterizing flow and transport in fractured rock aquifers. In all, the more than 175 papers contained in this proceedings reflect the contributions of more than 350 scientists who are co-authors. These scientists are from across the USGS, as well as from universities, other Federal and State agencies, and industry.

Water-Resources Investigations Report↗

U.S. Geological Survey Toxic Substances Hydrology Program: Proceedings of the technical meeting, Charleston, South Carolina, March 8-12, 1999: Volume 3 (Part C)

This report contains papers presented at the seventh Technical Meeting of the U.S. Geological Survey (USGS), Toxic Substances Hydrology (Toxics) Program. The meeting was held March 8-12, 1999, in Charleston, South Carolina. Toxics Program Technical Meetings are held periodically to provide a forum for presentation and discussion of results of recent research activities. The objectives of these meetings are to: Present recent research results to essential stakeholders, Encourage synthesis and integrated interpretations among scientists with different expertise who are working on a contamination issue, and Promote exchange of ideas among scientists working on different projects and issues within the Toxics Program. The Proceedings is published in three volumes. Volume 1 contains papers that report on results of research on contamination from hard-rock mining. Results include research on contamination from hard rock mining in arid southwest alluvial basins, research on hard rock mining in mountainous terrain, and progress from the USGS Abandoned Mine Lands Initiative. This Initiative is designed to develop a watershed-based approach to characterize and remediate contamination from abandoned mine lands and transfer technologies to Federal land management agencies and stakeholders. Volume 2 contains papers on contamination of hydrologic systems and related ecosystems. The papers discuss research on the response of estuarine ecosystems to contamination from human activities. They include research on San Francisco Bay; mercury contamination of aquatic ecosystems; and investigation of the occurrence, distribution, and fate of agricultural chemicals in the Mississippi River Basin. This volume also contains results on development and reconnaissance testing of new methods to detect emerging contaminants in environmental samples. Volume 3 contains papers on subsurface contamination from point sources. The papers discuss research on: hydrocarbons and fuel oxygenates at gasoline release sites; ground-water contamination by crude oil; complex contaminant mixtures from treated wastewater discharges; waste disposal and subsurface transport of contaminants in arid environments; ground water and surface water affected by municipal landfill leachate; natural attenuation of chlorinated solvents; and characterizing flow and transport in fractured rock aquifers. In all, the more than 175 papers contained in this proceedings reflect the contributions of more than 350 scientists who are co-authors. These scientists are from across the USGS, as well as from universities, other Federal and State agencies, and industry.

Water-Resources Investigations Report↗

Trends in nutrients

The roles of nitrogen (N) and phosphorus (P) as key nutrients determining the trophic status of water bodies are examined, and evidence reviewed for trends in concentrations of N and P species which occur in freshwaters, primarily in northern temperate environments. Data are reported for water bodies undergoing eutrophication and acidification, especially water bodies receiving increased nitrogen inputs through the atmospheric deposition of nitrogen oxides (NO x ). Nutrient loading on groundwaters and surface freshwaters is assessed with respect to causes and rates of change, relative rates of change for N and P, and implications of change for the future management of lakes, rivers and groundwaters. In particular, the nature and emphasis of studies for N species and P fractions in lakes versus rivers and groundwaters are contrasted. This review paper primarily focuses on results from North America and Europe, particularly for the UK where a wide range of data sets exists. Few nutrient loading data have been published on water bodies in less developed countries; however, some of the available data are presented to provide a global perspective. In general, N and P concentrations have increased dramatically (>20 times background concentrations) in many areas and causes vary considerably, ranging from urbanization to changes in agricultural practices.

Hydrological Processes↗

Loads and yields of selected constituents in streams and rivers of Monroe County, New York, 1984-2001

Hydrologic data collected in Monroe County since the 1980s and earlier, including long-term records of streamflow and chemical loads, provide a basis for assessment of water-management practices. All monitored streams except Northrup Creek showed a slight (nonsignificant) overall decrease in annual streamflow over their period of record; Northrup Creek showed a slight increase. The highest yields of all constituents except chloride and sulfate were at Northrup Creek; these values exceeded those of the seven Irondequoit Creek basin sites and the Genesee River site. The highest yields of dissolved chloride were at the most highly urbanized site (Allen Creek), whereas the highest yields of dissolved sulfate were at the most upstream Irondequoit Creek sites -- Railroad Mills (active) and Pittsford (inactive). Yields of all constituents in the Genesee River at the Charlotte Pump Station were within the range of those at the Irondequoit Creek basin sites. The four active Irondequoit Creek basin sites showed significant downward trends in flow-adjusted loads of ammonia + organic nitrogen, possibly from the conversion of agricultural land to suburban land. Two active sites (Allen Creek and Blossom Road) and one inactive site (Thomas Creek) showed downward trends in loads of ammonia. All active sites showed significant upward trends in dissolved chloride loads. Northrup Creek showed a significant downward trend in total phosphorus load since the improvement in phosphorus removal at the Spencerport wastewater-treatment plant, and upward trends in dissolved chloride and sulfate loads. The Genesee River at the Charlotte Pump Station showed significant downward trends in loads of ammonia + organic nitrogen and chloride, and an upward trend in loads of orthophosphate. The improved treatment or diversion of sewage-treatment-plant-effluent has produced decreased yields of some constituents throughout the county, particularly in the Irondequoit Creek basin, where the loads of nutrients delivered to Irondequoit Bay have been decreased.

New York↗

Long-term impacts of impervious surface cover change and roadway deicing agent application on chloride concentrations in exurban and suburban watersheds

Roadway deicing agents, including rock salt and brine containing NaCl, have had a profound impact on the water quality and aquatic health of rivers and streams in urbanized areas with temperate climates. Yet, few studies evaluate impacts to watersheds characterized by relatively low impervious surface cover (ISC; < 15 %). Here, we use long-term (1997-2019), monthly streamwater quality data combined with daily streamflow for six exurban and suburban watersheds in southeastern Pennsylvania to examine the relations among chloride (Cl − ) concentrations and ISC. Both flow-normalized Cl − concentrations and ISC increased over time in each of the six watersheds, consistent with changes in watershed management (e.g., ISC, road salt application, etc.). The watersheds that experienced the greatest changes in percent ISC (e.g., agriculture replaced by residential and commercial development) experienced the greatest changes in flow-normalized Cl − concentrations. We also utilized a comprehensive mass-balance model (2011–2018) that indicated Cl − inputs exceeded the outputs for the study watersheds. Road salt applied to state roads, non-state roads, and other impervious surfaces accounted for the majority of Cl − inputs to the six watersheds. Furthermore, increasing Cl − concentrations during baseflow conditions confirm impacts to shallow groundwater. Although flow-normalized Cl − concentrations are below the U.S. Environmental Protection Agency's chronic threshold value for impacts to aquatic organisms, year-round exceedances may result before the end of this century based on current trends. Though reduced Cl − loading to streams may be achieved by limiting the expansion of impervious surfaces in exurban and suburban watersheds, changes in baseflow concentrations are likely to be gradual because of the accumulated Cl − in groundwater.

Pennsylvania↗

The Ozark Highlands

The Ozark Highlands include diverse topographic, geologic, soil, and hydrologic conditions that support a broad range of habitat types. The landscape features rugged uplands - some peaks higher than 2,500 feet above sea level - with exposed rock and varying soil depths and includes extensive areas of karst terrain. The Highlands are characterized by extreme biological diversity and high endemism (uniqueness of species). Vegetation communities are dominated by open oak-hickory and shortleaf pine woodlands and forests. Included in this vegetation matrix is an assemblage of various types of fens, forests, wetlands, fluvial features, and carbonate and siliceous glades. An ever-growing human population in the Ozark Highlands has become very dependent on reservoirs constructed on major rivers in the region and, in some cases, groundwater for household and public water supply. Because of human population growth in the Highlands and increases in industrial and agricultural activities, not only is adequate water quantity an issue, but maintaining good water quality is also a challenge. Point and nonpoint sources of excessive nutrients are an issue. U.S. Geological Survey (USGS) partnership programs to monitor water quality and develop simulation tools to help stakeholders better understand strategies to protect the quality of water and the environment are extremely important. The USGS collects relevant data, conducts interpretive studies, and develops simulation tools to help stakeholders understand resource availability and sustainability issues. Stakeholders dependent on these resources are interested in and benefit greatly from evolving these simulation tools (models) into decision support systems that can be used for adaptive management of water and ecological resources. The interaction of unique and high-quality biological and hydrologic resources and the effects of stresses from human activities can be evaluated best by using a multidisciplinary approach that the USGS can provide. Information varying from defining baseline resource conditions to developing simulation models will help resource managers and users understand the human impact on resource sustainability. Varied expertise and experience in biological and water-resources activities across the entire Highlands make the USGS a valued collaborator in studies of Ozark ecosystems, streams, reservoirs, and groundwater. A large part of future success will depend on the involvement and active participation of key partners.

Fact Sheet↗