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River enhancement in the Upper Mississippi River basin: Approaches based on river uses, alterations, and management agencies

The Upper Mississippi River is characterized by a series of locks and dams, shallow impoundments, and thousands of river channelization structures that facilitate commercial navigation between Minneapolis, Minnesota, and Cairo, Illinois. Agriculture and urban development over the past 200 years have degraded water quality and increased the rate of sediment and nutrient delivery to surface waters. River enhancement has become an important management tool employed to address causes and effects of surface water degradation and river modification in the Upper Mississippi River Basin. We report information on individual river enhancement projects and contrast project densities, goals, activities, monitoring, and cost between commercially non-navigated and navigated rivers (Non-navigated and Navigated Rivers, respectively). The total number of river enhancement projects collected during this effort was 62,108. Cost of all projects reporting spending between 1972 and 2006 was about US$1.6 billion. Water quality management was the most cited project goal within the basin. Other important goals in Navigated Rivers included in-stream habitat improvement and flow modification. Most projects collected for Non-navigated Rivers and their watersheds originated from the U.S. Department of Agriculture (USDA). The U.S. Army Corps of Engineers and the USDA were important sources for projects in Navigated Rivers. Collaborative efforts between agencies that implement projects in Non-navigated and Navigated Rivers may be needed to more effectively address river impairment. However, the current state of data sources tracking river enhancement projects deters efficient and broad-scale integration. ?? Journal compilation ?? 2007 Society for Ecological Restoration International.

Restoration Ecology↗

Influence of reactive sulfide (AVS) and supplementary food on Ag, Cd and Zn bioaccumulation in the marine polychaete Neanthes arenaceodentata

A laboratory bioassay determined the relative contribution of various pathways of Ag, Cd and Zn bioaccumulation in the marine polychaete Neanthes arenaceodentata exposed to moderately contaminated sediments. Juvenile worms were exposed for 25 d to experimental sediments containing 5 different reactive sulfide (acid volatile sulfides, AVS) concentrations (1 to 30 ??mol g-1), but with constant Ag, Cd, and Zn concentrations of 0.1, 0.1 and 7 ??mol g-1, respectively. The sediments were supplemented with contaminated food (TetraMin??) containing 3 levels of Ag-Cd-Zn (uncontaminated, 1?? or 5??1 metal concentrations in the contaminated sediment). The results suggest that bioaccumulation of Ag, Cd and Zn in the worms occurred predominantly from ingestion of contaminated sediments and contaminated supplementary food. AVS or dissolved metals (in porewater and overlying water) had a minor effect on bioaccumulation of the 3 metals in most of the treatments. The contribution to uptake from the dissolved source was most important in the most oxic sediments, with maximum contributions of 8% for Ag, 30% for Cd and 20% for Zn bioaccumulation. Sediment bioassays where uncontaminated supplemental food is added could seriously underestimate metal exposures in an equilibrated system; N. arenaceodentata feeding on uncontaminated food would be exposed to 40-60% less metal than if the food source was equilibrated (as occurs in nature). Overall, the results show that pathways of metal exposure are dynamically linked in contaminated sediments and shift as external geochemical characteristics and internal biological attributes vary.

Marine Ecology Progress Series↗

February 2012 workshop jumpstarts the Mekong Fish Monitoring Network

The Mekong River in Southeast Asia travels through a basin rich in natural resources. The river originates on the northern slope of the world's tallest mountains, the Himalaya Range, and then drops elevation quickly through steep mountain gorges, tumbling out of China into Myanmar (Burma) and the Lao People's Democratic Republic (Lao PDR). The precipitous terrain of Lao PDR and Thailand generates interest in the river and its tributaries for hydropower development. The terrain, soils, water, and climate make it one of the world's most biologically rich regions. The Mekong's bounty is again on display in the Mekong River Delta, where rice production has successfully been increased to high levels making Vietnam second only to Thailand as the world's largest rice exporters. At least 800 fish species contribute to the natural resource bounty of the Mekong River and are the basis for one of the world's most productive fisheries that provide the primary protein source to more than 50 million people. Against this backdrop of rich natural resources, the U.S. Geological Survey (USGS) is working with the consulting firm FISHBIO, colleagues from the international Delta Research and Global Observation Network (DRAGON) Institute, and a broad contingent of Southeast Asian representatives and partners from abroad to increase knowledge of the Mekong River fisheries and to develop the capacity of permanent residents to investigate and understand these fisheries resources. With the Lower Mekong Basin (LMB) region facing the likelihood of significant environmental changes as a result of both human activities and global climate change, enhancing environmental understanding is critical. To encourage cooperation among the LMB scientists and managers in the study of the Mekong River's fisheries, FISHBIO and the USGS, with generous support from the U.S. State Department, hosted a workshop in Phnom Penh, Cambodia, in February 2012. Workshop participants were from Lao PDR, Thailand, Cambodia, and Vietnam. Representatives from the governments, universities, nongovernmental organizations, and the Mekong River Commission discussed current and potential methods and mechanisms of the Mekong Fish Monitoring Network. The goals of the workshop were to determine if the Network and associated databases were of interest and value to the LMB nations, to determine if future fisheries monitoring data would be comparable among the nations, and to establish methods and an organizational structure for collaborating on future monitoring and research. The participants in this international workshop agreed that the Network would be useful but would require additional funding to secure their full participation. The USGS and FISHBIO are collaboratively seeking additional funding to expand research participation and projects in all four LMB nations. If the Network can facilitate cooperation among many fisheries researchers in the LMB, the basin would become a model of cooperative international fishery studies and would increase the understanding of a river basin rich in natural resources.

Phnom Penh↗

Method of analysis at the U.S. Geological Survey California Water Science Center, Sacramento Laboratory - determination of haloacetic acid formation potential, method validation, and quality-control practices

An analytical method for the determination of haloacetic acid formation potential of water samples has been developed by the U.S. Geological Survey California Water Science Center Sacramento Laboratory. The haloacetic acid formation potential is measured by dosing water samples with chlorine under specified conditions of pH, temperature, incubation time, darkness, and residual-free chlorine. The haloacetic acids formed are bromochloroacetic acid, bromodichloroacetic acid, dibromochloroacetic acid, dibromoacetic acid, dichloroacetic acid, monobromoacetic acid, monochloroacetic acid, tribromoacetic acid, and trichloroacetic acid. They are extracted, methylated, and then analyzed using a gas chromatograph equipped with an electron capture detector. Method validation experiments were performed to determine the method accuracy, precision, and detection limit for each of the compounds. Method detection limits for these nine haloacetic acids ranged from 0.11 to 0.45 microgram per liter. Quality-control practices include the use of blanks, quality-control samples, calibration verification standards, surrogate recovery, internal standard, matrix spikes, and duplicates.

Scientific Investigations Report↗

Documentation of a Conduit Flow Process (CFP) for MODFLOW-2005

This report documents the Conduit Flow Process (CFP) for the modular finite-difference ground-water flow model, MODFLOW-2005. The CFP has the ability to simulate turbulent ground-water flow conditions by: (1) coupling the traditional ground-water flow equation with formulations for a discrete network of cylindrical pipes (Mode 1), (2) inserting a high-conductivity flow layer that can switch between laminar and turbulent flow (Mode 2), or (3) simultaneously coupling a discrete pipe network while inserting a high-conductivity flow layer that can switch between laminar and turbulent flow (Mode 3). Conduit flow pipes (Mode 1) may represent dissolution or biological burrowing features in carbonate aquifers, voids in fractured rock, and (or) lava tubes in basaltic aquifers and can be fully or partially saturated under laminar or turbulent flow conditions. Preferential flow layers (Mode 2) may represent: (1) a porous media where turbulent flow is suspected to occur under the observed hydraulic gradients; (2) a single secondary porosity subsurface feature, such as a well-defined laterally extensive underground cave; or (3) a horizontal preferential flow layer consisting of many interconnected voids. In this second case, the input data are effective parameters, such as a very high hydraulic conductivity, representing multiple features. Data preparation is more complex for CFP Mode 1 (CFPM1) than for CFP Mode 2 (CFPM2). Specifically for CFPM1, conduit pipe locations, lengths, diameters, tortuosity, internal roughness, critical Reynolds numbers (NRe), and exchange conductances are required. CFPM1, however, solves the pipe network equations in a matrix that is independent of the porous media equation matrix, which may mitigate numerical instability associated with solution of dual flow components within the same matrix. CFPM2 requires less hydraulic information and knowledge about the specific location and hydraulic properties of conduits, and turbulent flow is approximated by modifying horizontal conductances assembled by the Block-Centered Flow (BCF), Layer-Property Flow (LPF), or Hydrogeologic-Unit Flow Packages (HUF) of MODFLOW-2005. For both conduit flow pipes (CFPM1) and preferential flow layers (CFPM2), critical Reynolds numbers are used to determine if flow is laminar or turbulent. Due to conservation of momentum, flow in a laminar state tends to remain laminar and flow in a turbulent state tends to remain turbulent. This delayed transition between laminar and turbulent flow is introduced in the CFP, which provides an additional benefit of facilitating convergence of the computer algorithm during iterations of transient simulations. Specifically, the user can specify a higher critical Reynolds number to determine when laminar flow within a pipe converts to turbulent flow, and a lower critical Reynolds number for determining when a pipe with turbulent flow switches to laminar flow. With CFPM1, the Hagen-Poiseuille equation is used for laminar flow conditions and the Darcy-Weisbach equation is applied to turbulent flow conditions. With CFPM2, turbulent flow is approximated by reducing the laminar hydraulic conductivity by a nonlinear function of the Reynolds number, once the critical head difference is exceeded. This adjustment approximates the reductions in mean velocity under turbulent ground-water flow conditions.

Techniques and Methods↗

Observations on the geology and geohydrology of the Chernobyl' nuclear accident site, Ukraine

The most higly contaminated surface areas from cesium-137 fallout from the April 1986 accident at the Chernobyl' nuclear power station in Ukraine occur within the 30-km radius evacuation zone set up around the station, and an 80-km lobe extending to the west-southwest. Lower levels of contamination extend 300 km to the west of the power station. The deposition of this radioactive dust on the surface and the subsequent entombment of the damaged reactor effectively result in the de facto establishment of an above-ground nuclear waste storage site. This site is located on a thick sedimentary sequence of loose, mostly clastic deposits, with a shallow (generally 3-5 m) water table. The geology, the presence of surface water, a shallow water table, and leaky aquifers at depth make this an unfavorable environment for the long-term containment and storage of the radioactive debris. An understanding of the general geology and hydrology of the area is important to assess the environmental impact of this unintended waste storage site, and to evaluate the potential for radionuclide migration through the soil and rock and into subsurface aquifers and nearby rivers.

International Geology Review↗

Tertiary volcanic rocks from the southern Pannonian Basin, Croatia

The Tertiary volcanic rocks of the southern part of the Pannonian Basin are related to a sequence of tectonic events that occurred along the northern margin of the Dinarides when subduction ceased and after uplift of the region in middle Eocene time. The oldest rocks are andesites and dacites erupted during an Egerian to Eggenburgian marine transpression phase. In early Miocene time (about 17 Ma), rifting started, probably caused by the rise of the mantle, resulting in E-W extension and strike-slip faulting leading to formation of the Pannonian Basin. The initial rifting was accompanied by trachyandesitic volcanism of Karpathian age, followed by Badenian-age (15 to 13 Ma) volcanic activity producing basalts, andesites, and dacites. During these volcanic phases the Pannonian Basin, or the Paratethys, probably was periodically connected with the Mediterranean Sea. The final period of volcanism (about 9 to 7 Ma) produced alkalic basalts and basalts and occurred in fresh-water environments. These volcanic rocks have had a complex petrological evolution, related to an active continental margin. Egerian-Eggenburgian andesites and dacites can be explained by upper crustal assimilation with fractional crystallization (ACF) of primary basalt magma. The three younger associations originated by partial melting of rocks from both the upper mantle and the lower crust. Their evolution was accompanied by crustal contamination.

Carpathian Basin, Pannonian Basin↗

Characterizing the interface between wild ducks and poultry to evaluate the potential of transmission of avian pathogens

Background Characterizing the interface between wild and domestic animal populations is increasingly recognized as essential in the context of emerging infectious diseases (EIDs) that are transmitted by wildlife. More specifically, the spatial and temporal distribution of contact rates between wild and domestic hosts is a key parameter for modeling EIDs transmission dynamics. We integrated satellite telemetry, remote sensing and ground-based surveys to evaluate the spatio-temporal dynamics of indirect contacts between wild and domestic birds to estimate the risk that avian pathogens such as avian influenza and Newcastle viruses will be transmitted between wildlife to poultry. We monitored comb ducks ( Sarkidiornis melanotos melanotos ) with satellite transmitters for seven months in an extensive Afro-tropical wetland (the Inner Niger Delta) in Mali and characterise the spatial distribution of backyard poultry in villages. We modelled the spatial distribution of wild ducks using 250-meter spatial resolution and 8-days temporal resolution remotely-sensed environmental indicators based on a Maxent niche modelling method. Results Our results show a strong seasonal variation in potential contact rate between wild ducks and poultry. We found that the exposure of poultry to wild birds was greatest at the end of the dry season and the beginning of the rainy season, when comb ducks disperse from natural water bodies to irrigated areas near villages. Conclusions Our study provides at a local scale a quantitative evidence of the seasonal variability of contact rate between wild and domestic bird populations. It illustrates a GIS-based methodology for estimating epidemiological contact rates at the wildlife and livestock interface integrating high-resolution satellite telemetry and remote sensing data.

Inner Niger Delta↗

Status of a broadly distributed endangered species: Results and implications of the second International Piping Plover Census

Methods for monitoring progress toward recovery goals are highly variable and may be problematic for endangered species that are mobile and widely distributed. Recovery objectives for Piping Plovers ( Charadrius melodus ) include attainment of minimum population sizes within specified recovery units, as determined by two U.S. and two Canadian recovery teams. To assess progress toward these goals, complete surveys of the species' winter and breeding ranges in Canada, the United States, Mexico, the Bahamas, and the Greater Antilles are conducted every 5 years. In 1996, 1200 biologists and volunteers participated in the second International Piping Plover Census, tallying 2515 wintering birds and 5913 adults (2668 breeding pairs) during the breeding census. Winter numbers were 27% lower than those of the first international census conducted in 1991, with substantially fewer wintering birds along the Gulf of Mexico and an overall increase in numbers along the Atlantic Coast. Large numbers of wintering plovers remain undetected. In 1996, the total number of breeding adults was 7.7% higher than in 1991. Regionally, breeding numbers were 31% higher along the Atlantic Coast and 20% higher in the small Great Lakes population, but declined by 5% in the U.S. Great Plains and the Canadian Prairie. Target recovery numbers were met only for Saskatchewan but were approached in Alberta and New England. The results suggest that Piping Plover distribution and habitat use in the U.S. Great Plains/Canadian Prairie region may shift dramatically with water conditions.

Greater Antilles↗

High-resolution paleoclimatology of the Santa Barbara Basin during the Medieval Climate Anomaly and early Little Ice Age based on diatom and silicoflagellate assemblages in Kasten core SPR0901-02KC

Diatom and silicoflagellate assemblages documented in a high-resolution time series spanning 800 to 1600 AD in varved sediment recovered in Kasten core SPR0901-02KC (34°16.845’ N, 120°02.332’ W, water depth 588 m) from the Santa Barbara Basin (SBB) reveal that SBB surface water conditions during the Medieval Climate Anomaly (MCA) and the early part of the Little Ice Age (LIA) were not extreme by modern standards, mostly falling within one standard deviation of mean conditions during the pre anthropogenic interval of 1748 to 1900. No clear differences between the character of MCA and the early LIA conditions are apparent. During intervals of extreme droughts identified by terrigenous proxy scanning XRF analyses, diatom and silicoflagellate proxies for coastal upwelling typically exceed one standard deviation above mean values for 1748-1900, supporting the hypothesis that droughts in southern California are associated with cooler (or La Niña-like) sea surface temperatures (SSTs). Increased percentages of diatoms transported downslope generally coincide with intervals of increased siliciclastic flux to the SBB identified by scanning XRF analyses. Diatom assemblages suggest only two intervals of the MCA (at ~897 to 922 and ~1151 to 1167) when proxy SSTs exceeded one standard deviation above mean values for 1748 to 1900. Conversely, silicoflagellates imply extreme warm water events only at ~830 to 860 (early MCA) and ~1360 to 1370 (early LIA) that are not supported by the diatom data. Silicoflagellates appear to be more suitable for characterizing average climate during the 5 to 11 year-long sample intervals studied in the SPR0901-02KC core than diatoms, probably because diatom relative abundances may be dominated by seasonal blooms of a particular year.

California↗

Hydraulic and Geomorphic Assessment of the Merced River and Historic Bridges in Eastern Yosemite Valley, Yosemite National Park, California: Sacramento, California

The Merced River in the popular and picturesque eastern-most part of Yosemite Valley in Yosemite National Park, California, USA, has been extensively altered since the park was first conceived in 1864. Historical human trampling of streambanks has been suggested as the cause of substantial increases in stream width, and the construction of undersized stone bridges in the 1920s has been suggested as the major factor leading to an increase in overbank flooding due to deposition of bars and islands between the bridges. In response, the National Park Service at Yosemite National Park (YNP) requested a study of the hydraulic and geomorphic conditions affecting the most-heavily influenced part of the river, a 2.4-km reach in eastern Yosemite Valley extending from above the Tenaya Creek and Merced River confluence to below Housekeeping Bridge. As part of the study, present-day conditions were compared to historical conditions and several possible planning scenarios were investigated, including the removal of an elevated road berm and the removal of three undersized historic stone bridges identified by YNP as potential problems: Sugar Pine, Ahwahnee and Stoneman Bridges. This Open-File Report will be superseded at a later date by a Scientific Investigations Report. A two-dimensional hydrodynamic model, the USGS FaSTMECH (Flow and Sediment Transport with Morphological Evolution of Channels) model, within the USGS International River Interface Cooperative (iRIC) model framework, was used to compare the scenarios over a range of discharges with annual exceedance probabilities of 50-, 20-, 10-, and 5- percent. A variety of topographic and hydraulic data sources were used to create the input conditions to the hydrodynamic model, including aerial LiDAR (Light Detection And Ranging), ground-based LiDAR, total station survey data, and grain size data from pebble counts. A digitized version of a historical topographic map created by the USGS in 1919, combined with estimates of grain size, was used to simulate historical conditions, and the planning scenarios were developed by altering the present-day topography. Roughness was estimated independently of measured water-surface elevations by using the mapped grain-size data and the Keulegan relation of grain size to drag coefficient. The FaSTMECH hydrodynamic model was evaluated against measured water levels by using a 130.9 m 3 s -1 flow (approximately a 33-percent annual exceedance probability flood) with 36 water-surface elevations measured by YNP personnel on June 8, 2010. This evaluation run had a root mean square error of 0.21 m between the simulated- and observed water-surface elevations (less than 10 percent of depth), though the observed water-surface elevations had relatively high variation due to the strong diurnal stage changes over the course of the 4.4-hour collection period, during which discharge varied by about 15 percent. There are presently no velocity data with which to test the model. A geomorphic assessment was performed that consisted of an estimate of the magnitude and frequency of bedload and suspended-sediment transport at “Tenaya Bar”, an important gravel-cobble bar located near the upstream end of the study site that determines the amount of flow across the floodplain at the Sugar Pine – Ahwahnee bend. An analysis of select repeat cross-sections collected by YNP since the late 1980s was done to investigate changes in channel cross-sectional area near the Tenaya Bar site. The results of the FaSTMECH models indicate that the maximum velocities in the present-day channel within the study reach are associated with Stoneman and Sugar Pine Bridges, at close to 3.0 m s -1 for the 5-percent annual exceedance probability flood. The modeled maximum velocities at Ahwahnee Bridge are comparatively low, at between 1.5 and 2.0 m s -1 , most likely due to the bridge's orientation parallel to down-valley floodplain flows. The results of the FaSTMECH models for the bridge removal scenarios indicate a reduction in average velocity at the bridge sites for the range of flows by approximately 23-38 percent (Sugar Pine Bridge), 32-42 percent (Ahwahnee Bridge), and 33-39 percent (Stoneman Bridge), though a side channel of concern to YNP management did not appear to be substantially affected by the removal scenarios. In comparison to the historical data, the FaSTMECH results suggest that flows for present-day conditions do not inundate the floodplain until between the 50- and 20-percent annual exceedance probability flood, whereas historically, a large portion of the floodplain was inundated during the 50-percent annual exceedance probability flood. Modeled maximum velocities in the present-day channel commonly exceed 2.0 m s -1 , whereas with the historical scenario, modeled maximum in-channel velocities rarely exceeded 2.0 m s -1 . The geomorphic analysis of the magnitude-frequency of bedload and suspended-sediment transport suggests that at the important Tenaya Bar site, the majority of bed sediment is mobile during most snowmelt-dominated floods. In contrast to sediment transport capacity, the analysis of repeat cross-sections suggests that bedload sediment supply into the eastern Yosemite Valley may be quite different between rain-on-snow floods and snowmelt-dominated floods, potentially with most sediment supply occurring during rain-on-snow floods, such as the 1997 flood. In contrast, the magnitude-frequency analysis of bedload and suspended-sediment transport suggests that long-term bedload sediment transport is likely dominated by snowmelt floods, and suspended-sediment transport is relatively low compared to bedload transport. Obtaining measured velocity data throughout the study reach would aid in model calibration, and thus would improve confidence in model results. Improved confidence in the model velocity results would allow additional substantial analyses of reach-scale effects of the planning scenarios and would enable the development of geomorphic models to evaluate the long-term geomorphic responses of the site. In addition, the collection of watershed sediment-supply data, about which little is presently known, would give planners helpful tools to plan restoration scenarios for this nationally important river.

California↗

Electrogeochemical sampling with NEOCHIM - results of tests over buried gold deposits

Electrogeochemical extraction methods are based on the migration of ions in an electric field. Ions present in soil moisture are transported by an applied current into fluids contained in special electrodes placed on the soil. The fluids are then collected and analyzed. Extractions are governed by Faraday's and Ohm's laws and are modeled by the operation of a simple Hittord transference apparatus. Calculations show that the volume of soil sampled in an ideal electrogeochemical extraction can be orders of magnitude greater than the volumes used in more popular geochemical extraction methods, although this has not been verified experimentally. CHIM is a method of in-situ electrogeochemical extraction that was developed in the former Soviet Union and has been tested and applied internationally to exploration for buried mineral deposits. Tests carried out at the US Geological Survey (USGS) indicated that there were problems inherent in the use of CHIM technology. The cause of the problems was determined to be the diffusion of acid from the conventional electrode into the soil. The NEOCHIM electrode incorporates two compartments and a salt bridge in a design that inhibits diffusion of acid and enables the collection of anions or cations. Tests over a gold-enriched vein in Colorado and over buried, Carlin-type, disseminated gold deposits in northern Nevada show that there are similarities and differences between NEOCHIM results and those by partial extractions of soils which include simple extractions with water, dilute acids and solutions of salts used as collector fluids in the electrodes. Results of both differ from the results obtained by total chemical digestion. The results indicate that NEOCHIM responds to mineralized faults associated with disseminated gold deposits whereas partial and total chemical extraction methods do not. This suggests that faults are favored channels for the upward migration of metals and that NEOCHIM may be more effective in exploration for the deposits. It defines anomalies that are often narrow and intense, an observation previously made by CHIM researchers. The field tests show that NEOCHIM is less affected by surface contamination. A test over the Mike disseminated gold deposit indicates that the method may not be effective for locating deposits with impermeable cover. Faradaic extraction efficiencies of 20-30%, or more, are frequently achieved with NEOCHIM and the method generally shows good reproducibility, especially in extraction of major cations. However, ions of other metals that are useful in exploration, including Au and As, may be collected in low and temporally variable concentrations. The reason for this variability is unclear and requires further investigation.CHIM is a method of in-situ electrogeochemical extraction developed for the exploration of buried mineral deposits. However, electrode problems like diffusion of acid into the soil were encountered during the use of CHIM. The NEOCHIM electrode was developed to inhibit the diffusion of acid and enable collection of anions or cations. Tests over buried gold deposits showed that NEOCHIM responds to mineralized faults associated with disseminated gold deposits whereas partial and total chemical extraction methods do not. This suggests that faults are favored channels for the upward migration of metals and NEOCHIM may be effective in exploration for the deposits. But ions of metals may be collected in low and variable concentration.

Journal of Geochemical Exploration↗

Legacy of the California Gold Rush: Environmental geochemistry of arsenic in the southern Mother Lode Gold District

Gold mining activity in the Sierra Nevada foothills, both recently and during the California Gold Rush, has exposed arsenic-rich pyritic rocks to weathering and erosion. This study describes arsenic concentration and speciation in three hydrogeologic settings in the southern Mother Lode Gold District: mineralized outcrops and mine waste rock (overburden); mill tailings submerged in a water reservoir; and lake waters in this monomictic reservoir and in a monomictic lake developing within a recent open-pit mine. These environments are characterized by distinct modes of rock-water interaction that influence the local transport and fate of arsenic. Arsenic in outcrops and waste rock occurs in arsenian pyrite containing an average of 2 wt% arsenic. Arsenic is concentrated up to 1300 ppm in fine-grained, friable, iron-rich weathering products of the arsenian pyrite (goethite, jarosite, copiapite), which develop as efflorescences and crusts on weathering outcrops. Arsenic is sorbed as a bidentate complex on goethite, and substitutes for sulfate in jarosite. Submerged mill tailings obtained by gravity core at Don Pedro Reservoir contain arsenic up to 300 ppm in coarse sand layers. Overlying surface muds have less arsenic in the solid fraction but higher concentrations in porewaters (up to 500 μg/L) than the sands. Fine quartz tailings also contain up to 3.5 ppm mercury related to the ore processing. The pH values in sediment porewaters range from 3.7 in buried gypsum-bearing sands and tailings to 7 in the overlying lake sediments. Reservoir waters immediately above the cores contain up to 3.5 μg/L arsenic; lake waters away from the submerged tailings typically contain less than 1 μg/L arsenic. Dewatering during excavation of the Harvard open-pit mine produced a hydrologic cone of depression that has been recovering toward the pre-mining groundwater configuration since mining ended in 1994. Aqueous arsenic concentrations in the 80 m deep pit lake are up to 1000 μg/L. Redistribution of the arsenic occurs during summer stratification, with highest concentrations at middle depths. The total mass of arsenic in the pit lake increases coinciding with early winter rains that erode, partially dissolve, and transport arsenic-bearing salts into the pit lake. Arsenic concentration, speciation, and distribution in the Sierra Nevada foothills depend on many factors, including the lithologic sources of arsenic, climatic influences on weathering of host minerals, and geochemical characteristics of waters with which source and secondary minerals react. Oxidation of arsenian pyrite to goethite, jarosite, and copiapite causes temporary attenuation of arsenic during summer, when these secondary minerals accumulate; subsequent rapid dissemination of arsenic into the aqueous environment is caused by annual winter storms. As the population of the Mother Lode area grows, it is increasingly important to consider these effects during planning and development of land and groundwater resources.

California↗

Age, geochemical composition, and distribution of Oligocene ignimbrites in the northern Sierra Nevada, California: Implications for landscape morphology, elevation, and drainage divide geography of the Nevadaplano

To gain a better understanding of the topographic and landscape evolution of the Cenozoic Sierra Nevada and Basin and Range, we combine geochemical and isotopic age correlations with palaeoaltimetry data from widely distributed ignimbrites in the northern Sierra Nevada, California. A sequence of Oligocene rhyolitic ignimbrites is preserved across the modern crest of the range and into the western foothills. Using trace and rare earth element geochemical analyses of volcanic glass, these deposits have been correlated to ignimbrites described and isotopically dated in the Walker Lane fault zone and in central Nevada (Henry et al. , 2004, Geologic map of the Dogskin mountain quadrangle; Washoe County, Nevada; Faulds et al. , 2005, Geology, v. 33, p. 505–508). Ignimbrite deposits were sampled within the northern Sierra Nevada and western Nevada, and four distinct geochemical compositions were identified. The majority of samples from within the northern Sierra Nevada have compositions similar to the tuffs of Axehandle Canyon or Rattlesnake Canyon, both likely sourced from the same caldera complex in either the Clan Alpine Mountains or the Stillwater Range, or to the tuff of Campbell Creek, sourced from the Desatoya Mountains caldera. New 40 Ar/ 39 Ar age determinations from these samples of 31.2, 30.9, and 28.7 Ma, respectively, support these correlations. Based on an Oligocene palinspastic reconstruction of the region, our results show that ignimbrites travelled over 200 km from their source calderas across what is now the crest of the Sierra Nevada, and that during that time, no drainage divide existed between the ignimbrite source calderas in central Nevada and sample locations 200 km to the west. Palaeoaltimetry data from Sierra Nevada ignimbrites, based on the hydrogen isotopic composition of hydration water in glass, reflect the effect of a steep western slope on precipitation and indicate that the area had elevations similar to the present-day range. These combined results suggest that source calderas were likely located in a region of high elevation to the east of the Oligocene Sierra Nevada, which had a steep western slope that allowed for the large extent and broad distribution of the ignimbrites.

International Geology Review↗

Landscape ecology of the Upper Mississippi River System: Lessons learned, challenges and opportunities

The Upper Mississippi River System (UMRS) is a mosaic of river channels, backwater lakes, floodplain forests, and emergent marshes. This complex mosaic supports diverse aquatic and terrestrial plant communities, over 150 fish species; 40 freshwater mussel species; 50 amphibian and reptile species; and over 360 bird species, many of which use the UMRS as a critical migratory route. The river and floodplain are also hotspots for biogeochemical activity as the river-floodplain collects and processes nutrients derived from the UMR basin. These features qualify the UMRS as a Ramsar wetland of international significance. Two centuries of land-use change, including construction for navigation and conversion of large areas to agriculture, has altered the broad-scale structure of the river and changed local environmental conditions in many areas. Such changes have affected rates of nutrient processing and transport, as well as the abundance of various fish, mussel, plant, and bird species. However, the magnitude and spatial scale of these effects are not well quantified, especially in regards to the best methods and locations for restoring various aspects of the river ecosystem. The U.S. Congress declared the navigable portions of the Upper Mississippi River System (UMRS) a “nationally significant ecosystem and nationally significant commercial navigation system” in the Water Resources Development Act of 1986 (Public Law 99-662) and launched the Upper Mississippi River Restoration (UMRR) Program, the first comprehensive program for ecosystem restoration, monitoring, and research on a large river system. This fact sheet focuses on landscape ecological studies conducted by the U.S. Geological Survey to support decision making by the UMRR with respect to ecosystem restoration.

Upper Mississippi River System↗

Bedload-surrogate monitoring technologies

Advances in technologies for quantifying bedload fluxes and in some cases bedload size distributions in rivers show promise toward supplanting traditional physical samplers and sampling methods predicated on the collection and analysis of physical bedload samples. Four workshops held from 2002 to 2007 directly or peripherally addressed bedload-surrogate technologies, and results from these workshops have been compiled to evaluate the state-of-the-art in bedload monitoring. Papers from the 2007 workshop are published for the first time with this report. Selected research and publications since the 2007 workshop also are presented. Traditional samplers used for some or all of the last eight decades include box or basket samplers, pan or tray samplers, pressure-difference samplers, and trough or pit samplers. Although still useful, the future niche of these devices may be as a means for calibrating bedload-surrogate technologies operating with active- and passive-type sensors, in many cases continuously and automatically at a river site. Active sensors include acoustic Doppler current profilers (ADCPs), sonar, radar, and smart sensors. Passive sensors include geophones (pipes or plates) in direct contact with the streambed, hydrophones deployed in the water column, impact columns, and magnetic detection. The ADCP for sand and geophones for gravel are currently the most developed techniques, several of which have been calibrated under both laboratory and field conditions. Although none of the bedload-surrogate technologies described herein are broadly accepted for use in large-scale monitoring programs, several are under evaluation. The benefits of verifying and operationally deploying selected bedload-surrogate monitoring technologies could be considerable, providing for more frequent and consistent, less expensive, and arguably more accurate bedload data obtained with reduced personal risk for use in managing the world's sedimentary resources. Twenty-six papers are published for the first time as part of the 2007 International Bedload-Surrogate Monitoring Workshop (listed in table 2 in alphabetical order by name of first author). Sequential page numbering of the papers begins on page 38, after the last page of the report. The report plus the 26 papers comprise 430 pages.

Scientific Investigations Report↗

Identifying salt marsh shorelines from remotely sensed elevation data and imagery

Salt marshes are valuable ecosystems that are vulnerable to lateral erosion, submergence, and internal disintegration due to sea-level rise, storms, and sediment deficits. Because many salt marshes are losing area in response to these factors, it is important to monitor their lateral extent at high resolution over multiple timescales. In this study we describe two methods to calculate the location of the salt marsh shoreline. The Marsh Edge from Elevation Data (MEED) method uses remotely sensed elevation data to calculate an objective proxy for the shoreline of a salt marsh. This proxy is the abrupt change in elevation that usually characterizes the seaward edge of a salt marsh, designated the “marsh scarp.” It is detected as the maximum slope along a cross-shore transect between Mean High Water and Mean Tide Level. The method was tested using lidar topobathymetric and photogrammetric elevation data from Massachusetts, USA. The other method to calculate the salt marsh shoreline is the Marsh Edge by Image Processing (MEIP) method which finds the unvegetated/vegetated line. This method applies image classification techniques to multispectral imagery and elevation datasets for edge detection. The method was tested using aerial imagery and coastal elevation data from the Plum Island Estuary in Massachusetts, USA. Both methods calculate a line that closely follows the edge of vegetation seen in imagery. The root-mean-square deviation between the two methods within the test area is 0.6 meter. The two methods were compared to each other using high resolution Unmanned Aircraft Systems (UAS) data and to a heads-up digitized shoreline. The root-mean-square deviation was 0.6 meters between the two methods and less than 0.43 meters from the digitized shoreline. MEIP method was also applied to a lower resolution dataset to investigate the effect of horizontal resolution on the results. Both methods provide an accurate, efficient, and objective way to track salt marsh shorelines with spatially intensive data over large spatial scales, which is necessary to evaluate geomorphic change and wetland vulnerability

Massachusetts↗

Presence and potential significance of aromatic-ketone groups in aquatic humic substances

Aquatic humic- and fulvic-acid standards of the International Humic Substances Society were characterized, with emphasis on carbonyl-group nature and content, by carbon-13 nuclear-magnetic-resonance spectroscopy, proton nuclear-magnetic-resonance spectroscopy, and infrared spectroscopy. After comparing spectral results of underivatized humic and fulvic acids with spectral results of chemically modified derivatives, that allow improved observation of the carbonyl group, the data clearly indicated that aromatic ketone groups comprised the majority of the carbonyl-group content. About one ketone group per monocyclic aromatic ring was determined for both humic and fulvic acids. Aromatic-ketone groups were hypothesized to form by photolytic rearrangements and oxidation of phenolic ester and hydrocarbon precursors; these groups have potential significance regarding haloform formation in water, reactivity resulting from active hydrogen of the methyl and methylene adjacent to the ketone groups, and formation of hemiketal and lactol structures. Aromatic-ketone groups also may be the point of attachment between aliphatic and aromatic moieties of aquatic humic-substance structure.

Georgia↗