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Cenozoic tectonic reorganizations of the Death Valley region, southeast California and southwest Nevada

The Death Valley region, of southeast California and southwest Nevada, is distinct relative to adjacent regions in its structural style and resulting topography, as well as in the timing of basin-range extension. Cenozoic basin-fill strata, ranging in age from greater than or equal to 40 to approximately 2 million years are common within mountain-range uplifts in this region. The tectonic fragmentation and local uplift of these abandoned basin-fills indicate a multistage history of basin-range tectonism. Additionally, the oldest of these strata record an earlier, pre-basin-range interval of weak extension that formed broad shallow basins that trapped sediments, without forming basin-range topography. The Cenozoic basin-fill strata record distinct stratigraphic breaks that regionally cluster into tight age ranges, constrained by well-dated interbedded volcanic units. Many of these stratigraphic breaks are long recognized formation boundaries. Most are angular unconformities that coincide with abrupt changes in depositional environment. Deposits that bound these unconformities indicate they are weakly diachronous; they span about 1 to 2 million years and generally decrease in age to the west within individual basins and regionally, across basin boundaries. Across these unconformities, major changes are found in the distribution and provenance of basin-fill strata, and in patterns of internal facies. These features indicate rapid, regionally coordinated changes in strain patterns defined by major active basin-bounding faults, coincident with step-wise migrations of the belt of active basin-range tectonism. The regionally correlative unconformities thus record short intervals of radical tectonic change, here termed "tectonic reorganizations." The intervening, longer (about 3- to 5-million-year) interval of gradual, monotonic evolution in the locus and style of tectonism are called "tectonic stages." The belt of active tectonism in the Death Valley region has abruptly stepped westward during three successive tectonic reorganizations that intervened between four stages of basin-range tectonism, the youngest of which is ongoing. These three tectonic reorganizations also intervened between four stages of volcanic activity, each of which has been distinct in the compositions of magmas erupted, in eruption rates, and in the locus of volcanic activity—which has stepped progressively westward, in close coordination with the step-wise migrations in the locus of basin-range extension. The timing of the Cenozoic tectonic reorganizations in the Death Valley region correlates closely with the documented timing of episodic reorganizations of the boundary between the Pacific and North American plates, to the west and southwest. This supports models that explain the widely distributed transtensional tectonism in southwestern North America since approximately 40 million years ago as resulting from traction imposed by the adjacent, divergent Pacific plate.

California;Nevada↗

An improved proximal tephrochronology for Redoubt Volcano, Alaska

Sediment cores from lakes in volcanically active regions can be used to reconstruct the frequency of tephra-fall events. We studied sediment cores from two lakes within 25 km of the summit of Redoubt Volcano, western Cook Inlet, to develop a robust age model for the Holocene tephrochronology, and to assess the extent to which the tephrostratigraphies were correlative between the two nearby lakes. Visually distinct tephra layers were correlated among cores from Bear and Cub lakes, located within 17 km of each other, to construct a composite age model, which incorporates two Pu-activity profiles and 27 radiocarbon ages, and extends the record back to 11,540 cal a BP. The age model was used to interpolate the ages and quantify the uncertainties of ages for all tephras at least 1 mm thick. Between − 55 and 3850 a BP, 31 tephras were deposited in Bear Lake and 41 tephras in Cub Lake. Bear Lake contains an additional 38 tephras deposited between 11,540 and 3850 a BP. During the period of overlap, (− 55 to 3850 a BP), 24 tephras are of significantly different ages, including nine from Bear Lake and 17 from Cub Lake. The presence of these unique tephras indicates that ejecta plumes erupted from Redoubt Volcano can be highly directional, and that sediment cores from more than one lake are needed for a comprehensive reconstruction of tephra-fall events. Unlike distal lakes in south Alaska, where geomorphic and limnological factors dominate the quality of the tephrostratigraphic record, the variability in tephra-fall trajectory near a Redoubt Volcano appears to be a major control on the number of tephras contained in the sediment of proximal lakes.

Alaska↗

Varve calibrated records of carbonate and organic carbon accumulation over the last 2000 years in the Black Sea

Sedimentologic and geochemical studies of box and gravity cores recovered from the Black Sea during the first leg of a multileg international Black Sea expedition in 1988 allow reconstruction of the basinwide Holocene environmental history of the Black Sea. In the deeper parts of the basin, box cores typically recovered a flocculent surface layer (“fluff”), laminated coccolith marls of Unit I (25–45 cm thick), and the upper 5–10 cm of finely laminated, dark‐colored sapropels of Unit II. Fine‐grained, homogeneous mud turbidites are interbedded with Units I and II over much of the basin, but the stratigraphie position of these turbidites differs, from site to site. The deposition of individual turbidites up to 15 cm thick does not appear to have significantly disturbed underlying laminae. Sediment trap deployments in the Black Sea suggest that light and dark laminae couplets represent annual increments of sedimentation (i.e., varves); we have therefore constructed a varve chronology for the sequence in order to correlate and date distinctive sedimentation and paleoenvironmental events. Distinctive groups of laminae in Unit I can be correlated across the entire deeper basin (a distance of more than 1000 km). This implies a remarkable homogeneity in production, accumulation, and preservation of biogenic material over much of the Black Sea during deposition of Unit I. The change from deposition of finely laminated, organic carbon‐rich sapropels (Unit II) to laminated, more calcareous, coccolith‐rich marls (Unit I) is thought to represent the crossing of a salinity threshold for Emiliania huxleyi. The varve chronology sets this change at about 1.63 ka (1633±100 yr B.P.), but the record of magnetic secular variation measured in several cores produces an age estimate of about 2.0 ka for the base of Unit I, or about 1.2 times the varve age. The average of six calibrated accelerator mass spectrometry radiocarbon ages for the base of Unit I is 2.7 ka, or about 1.7 times the varve age. Following the initial change to coccolith‐dominated sedimentation, deposition of sapropel resumed for at least one significant period, 1.56–1.25 ka. Since 1.25 ka, cycles of carbonate deposition with quasi‐decadal periodicities have produced characteristic darker and lighter assemblages of laminae. These cycles may have been climatically driven. Geochemical analyses coupled with the varve ages adopted herein indicate that accumulation rates of carbonate are nearly an order of magnitude higher in Unit I (averaging 35–45 g m −2 yr −1 ) than in sapropelic Unit II. which contains primarily detrital carbonate. The accumulation of lithogenic components in parts of Unit I is only 1.5 times the rate in Unit II. Deepwater organic carbon accumulation rates are somewhat higher in Unit I (3.5–4.5 g m −2 yr −1 ) than in the upper part of Unit II. Organic carbon accumulation rates in Unit I are somewhat antithetic to those of carbonate, and on the basis of this and additional constraints placed by pyrolysis and carbon isotopic analyses of organic material, it appears that terrestrial organic matter is an important component (perhaps >25%) of total organic carbon burial in the basin. Unit I in the western part of the Black Sea has a higher terrestrial organic component and higher accumulation rates of terrigenous clastic material than Unit I in the eastern part. This difference between eastern and western Black Sea is to be expected because of the major rivers that empty into the western Black Sea from eastern Europe, Ukraine, and Russia. Shallow slope sites, but still within euxinic bottom waters, have lower organic carbon accumulation rates and lower pyrolysis hydrogen indices than deepwater basinal sites, suggesting selective resuspension and oxidation of organic matter at basin margins and focusing of organic matter deposition toward the basin center. A comparison of the Black Sea data with those from several open ocean sites with similar water depths showed no significant difference between organic carbon accumulation rates under oxic and anoxic conditions. For a given bulk accumulation rate the organic carbon accumulation rates, normalized to primary productivity, are about the same in both settings.

Global Biogeochemical Cycles↗

Late Pliocene paleoeco­logic reconstructions based on ostracode assemblages from the Sagavanirktok and Gubik formations, Alaskan North Slope

Shallow-marine ostracode assemblages from upper Pliocene sediments of the upper part of the Sagavanirktok Formation and lower part of the Gubik Formation record the last warm period that occurred before the onset of significant cooling of the Arctic Ocean and the initiation of Northern Hemisphere continental glaciation. The informally named Colvillian and Bigbendian transgressions represent the oldest deposits of the Gubik Formation and are dated, based on various lines of evidence, between 2.48 and 3 Ma. Ostracode faunas from the lower part of the Gubik Formation indicate a cold-temperate to subfrigid marine climate with summer bottom temperatures 1-4 C warmer than today. Deposits of the upper part of the Sagavanirktok Formation at Manning Point and Barter Island are older than Colvillian sediments but are believed to be late Pliocene in age and contain an ostracode fauna that has many species in common with the lower part of the Gubik Formation. The Sagavanirktok ostracode faunas indicate a cold-temperature to subfrigid marine climate, similar to that inferred for the lower part of the Gubik Formation, with summer bottom temperatures 1-3 C warmer than today. The opening of Bering Strait at about 3 Ma altered Arctic Ocean assemblage composition as Pacific species migrated into the Arctic and North Atlantic oceans. The admixture of evolutionarily distinct faunas from the Atlantic and Pacific oceans identifies Colvillian (and younger) faunas and provides a convenient reference horizon in the Alaskan fossil record. The marine climatic deterioration that followed the Bigbendian appears to have been abrupt and is documented by biotic turnover, with large numbers of species extinctions and first appearances of new species. The change in species composition can be attributed to the cooling of the Arctic Ocean during the late Pliocene.

Alaska↗

U.S. Geological Survey external quality-assurance project report for the National Atmospheric Deposition Program / National Trends Network and Mercury Deposition Network, 2011-2012

The U.S. Geological Survey operated six distinct programs to provide external quality-assurance monitoring for the National Atmospheric Deposition Program (NADP) / National Trends Network (NTN) and Mercury Deposition Network (MDN) during 2011–2012. The field-audit program assessed the effects of onsite exposure, sample handling, and shipping on the chemistry of NTN samples; a system-blank program assessed the same effects for MDN. Two interlaboratory-comparison programs assessed the bias and variability of the chemical analysis data from the Central Analytical Laboratory and Mercury Analytical Laboratory (HAL). A blind-audit program was implemented for the MDN during 2011 to evaluate analytical bias in HAL total mercury concentration data. The co-located–sampler program was used to identify and quantify potential shifts in NADP data resulting from the replacement of original network instrumentation with new electronic recording rain gages and precipitation collectors that use optical precipitation sensors. The results indicate that NADP data continue to be of sufficient quality for the analysis of spatial distributions and time trends of chemical constituents in wet deposition across the United States. Co-located rain gage results indicate -3.7 to +6.5 percent bias in NADP precipitation-depth measurements. Co-located collector results suggest that the retrofit of the NADP networks with the new precipitation collectors could cause +10 to +36 percent shifts in NADP annual deposition values for ammonium, nitrate, and sulfate; -7.5 to +41 percent shifts for hydrogen-ion deposition; and larger shifts (-51 to +52 percent) for calcium, magnesium, sodium, potassium, and chloride. The prototype N-CON Systems bucket collector typically catches more precipitation than the NADP-approved Aerochem Metrics Model 301 collector.

Report↗

Sedimentary geochemistry of deepwater slope deposits in southern Lake Tanganyika (East Africa): Effects of upwelling and minor lake level oscillations

Lake Tanganyika ranks among the most valuable modern analogs for understanding depositional processes of carbonaceous sediments in ancient tropical rifts. Prior research on Lake Tanganyika has emphasized the importance of bottom-water anoxia, depositional processes (hemipelagic settling versus gravity flows), and large-scale (100s of meters) lake level change on the quality of sedimentary organic matter content. Here, facies analysis and numerous organic geochemical tools (elemental, carbon isotope, and programmed pyrolysis) were applied to a radiocarbon-dated core from southern Lake Tanganyika to investigate the accumulation of carbonaceous sediments in a deepwater slope environment influenced by high-frequency climatic fluctuations accompanied by only minor (10s of meters) lake level changes. Considerable variability in lithofacies and geochemistry characterizes the ∼ 1030-year-long core record, chiefly driven by climate-mediated changes to the lake's upwelling system. Laminated diatom oozes and sapropels with mean total organic carbon (TOC) concentrations and hydrogen indices of 6.9 wt.% and 385 mg hydrocarbon/g TOC, respectively, characterize sediments deposited during periods of strong upwelling and variable water levels. Silty sediments deposited via gravity-flow processes were likewise rich in organic matter, likely due to preservation-enhancing bottom-water anoxia. Dilution by reworked tephra was the chief constraint on organic enrichment at the study site. Data from this study reveal that oscillations in atmospheric and limnological processes in the absence of major shoreline movements can result in geochemically diverse deepwater slope sediments, which have implications for improving depositional models of petroliferous continental rift basins.

Journal of Sedimentary Research↗

Eruptive history of the Ubehebe Crater Cluster, Death Valley, California

A sequence of late Holocene eruptions from the Ubehebe Crater cluster in Death Valley was short-lived, emplacing several phreatomagmatic and magmatic deposits. Seven craters form the main group, which erupted along a north-south alignment 1.5 km long. At least five more make a 500-m east-west alignment west of the main crater group. One more is an isolated shallow crater ~ 400 m south of that alignment. All erupted through Miocene fanglomerate and sandstone, which are now distributed as comminuted matrix and lithic clasts in all Ubehebe deposits. Stratigraphic evidence showing that all Ubehebe strata were emplaced within a short time interval includes: (1) deposits from the many Ubehebe vents make a multi-package sequence that conformably drapes paleo-basement topography with no erosive gullying between emplacement units; (2) several crater rims that formed early in the eruptive sequence are draped smoothly by subsequent deposits; and (3) tack-welded to agglutinated spatter and bombs that erupted at various times through the sequence remained hot enough to oxidize the overlying youngest emplacement package. In addition, all deposits sufficiently consolidated to be drilled yield reliable paleomagnetic directions, with site mean directions showing no evidence of geomagnetic secular variation. Chemical analyses of juvenile components representing every eruptive package yield a narrow range in major elements [SiO 2 (48.65–50.11); MgO (4.98–6.23); K 2 O (2.24–2.39)] and trace elements [Rb (28–33); Sr (1513–1588); Zr (373–404)]. Despite lithologic similarities, individual fall units can be traced outward from vent by recording layer thicknesses, maximum scoria and lithic sizes, and juvenile clast textural variations. This permits reconstruction of the eruptive sequence, which produced a variety of eruptive styles. The largest and northernmost of the craters, Ubehebe Crater, is the youngest of the group. Its largely phreatomagmatic deposits drape all of the others, thicken in paleogullies and thin over several newly created crater rims. Evidence in-hand virtually requires that the Ubehebe cluster of craters erupted over a brief time interval, not protracted over centuries.

California↗

"Sour gas" hydrothermal jarosite: Ancient to modern acid-sulfate mineralization in the southern Rio Grande Rift

As many as 29 mining districts along the Rio Grande Rift in southern New Mexico contain Rio Grande Rift-type (RGR) deposits consisting of fluorite-barite??sulfide-jarosite, and additional RGR deposits occur to the south in the Basin and Range province near Chihuahua, Mexico. Jarosite occurs in many of these deposits as a late-stage hydrothermal mineral coprecipitated with fluorite, or in veinlets that crosscut barite. In these deposits, many of which are limestone-hosted, jarosite is followed by natrojarosite and is nested within silicified or argillized wallrock and a sequence of fluorite-barite??sulfide and late hematite-gypsum. These deposits range in age from ???10 to 0.4 Ma on the basis of 40Ar/39Ar dating of jarosite. There is a crude north-south distribution of ages, with older deposits concentrated toward the south. Recent deposits also occur in the south, but are confined to the central axis of the rift and are associated with modern geothermal systems. The duration of hydrothermal jarosite mineralization in one of the deposits was approximately 1.0 my. Most ??18OSO4-OH values indicate that jarosite precipitated between 80 and 240 ??C, which is consistent with the range of filling temperatures of fluid inclusions in late fluorite throughout the rift, and in jarosite (180 ??C) from Pen??a Blanca, Chihuahua, Mexico. These temperatures, along with mineral occurrence, require that the jarosite have had a hydrothermal origin in a shallow steam-heated environment wherein the low pH necessary for the precipitation of jarosite was achieved by the oxidation of H2S derived from deeper hydrothermal fluids. The jarosite also has high trace-element contents (notably As and F), and the jarosite parental fluids have calculated isotopic signatures similar to those of modern geothermal waters along the southern rift; isotopic values range from those typical of meteoric water to those of deep brine that has been shown to form from the dissolution of Permian evaporite by deeply circulating meteoric water. Jarosite ??34S values range from -24??? to 5???, overlapping the values for barite and gypsum at the high end of the range and for sulfides at the low end. Most ??34S values for barite are 10.6??? to 13.1???, and many ??34S values for gypsum range from 13.1??? to 13.9??? indicating that a component of aqueous sulfate was derived from Permian evaporites (??34 S=12??2???). The requisite H2SO4 for jarosite formation was derived from oxidation of H2S which was likely largely sour gas derived from the thermochemical reduction of Permian sulfate. The low ??34S values for the precursor H2S probably resulted from exchange deeper in the basin with the more abundant Permian SO42- at ???150 to 200 ??C. Jarosite formed at shallow levels after the pH buffering capacity of the host rock (typically limestone) was neutralized by precipitation of earlier minerals. Some limestone-hosted deposits contain caves that may have been caused by the low pH of the deep basin fluids due to the addition of deep-seated HF and other magmatic gases during periods of renewed rifting. Caves in other deposits may be due to sulfuric acid speleogenesis as a result of H2S incursion into oxygenated groundwaters. The isotopic data in these "sour gas" jarosite occurrences encode a record of episodic tectonic or hydrologic processes that have operated in the rift over the last 10 my. ?? 2004 Elsevier B.V. All rights reserved.

Chemical Geology↗

Mineralogical, magnetic and geochemical data constrain the pathways and extent of weathering of mineralized sedimentary rocks

The oxidative weathering of sulfidic rock can profoundly impact watersheds through the resulting export of acidity and metals. Weathering leaves a record of mineral transformation, particularly involving minor redox-sensitive phases, that can inform the development of conceptual and quantitative models. In sulfidic sedimentary rocks, however, variations in depositional history, diagenesis and mineralization can change or overprint the distributions of these trace minerals, complicating the interpretation of weathering signatures. Here we show that a combination of bulk mineralogical and geochemical techniques, micrometer-resolution X-ray fluorescence microprobe analysis and rock magnetic measurements, applied to drill core samples and single weathered fractures, can provide data that enable the development of a geochemically consistent weathering model. This work focused on one watershed in the Upper Colorado River Basin sitting within the Mesaverde Formation, a sedimentary sandstone bedrock with disseminated sulfide minerals, including pyrite and sphalerite, that were introduced during diagenesis and subsequent magmatic-hydrothermal mineralization. Combined analytical methods revealed the pathways of iron (Fe), carbonate and silicate mineral weathering and showed how pH controls element retention or release from the actively weathering fractured sandstone. Drill core logging, whole rock X-ray diffraction, and geochemical measurements document the progression from unweathered rock at depth to weathered rock at the surface. X-ray microprobe analyses of a 1-cm size weathering profile along a fracture surface are consistent with the mobilization of Fe(II) and Fe(III) into acidic pore water from the dissolution of primary pyrite, Fe-sphalerite, chlorite, and minor siderite and pyrrhotite. These reactions are followed by the precipitation of secondary minerals such as of goethite and jarosite, a Fe-(oxyhydr)oxide and hydrous Fe(III) sulfate, respectively. Microscale analyses also helped explain the weathering reactions responsible for the mineralogical transformations observed in the top and most weathered section of the drill core. For example, dissolution of feldspar and chlorite neutralizes the acidity generated by Fe and sulfide mineral oxidation, oversaturating the solution in both Fe-oxides. The combination of X-ray spectromicroscopy and magnetic measurements show that the Fe(III) product is goethite, mainly present either as a coatings on fracture surfaces in the actively weathering region of the core or more homogeneously contained within the unconsolidated regolith at the top of the core. Low-temperature magnetic data reveal the presence of ferromagnetic Fe-sulfide pyrrhotite that, although it occurs at trace concentrations, could provide a qualitative proxy for unweathered sulfide minerals because the loss of pyrrhotite is associated with the onset of oxidative weathering. Pyrrhotite loss and goethite formation are detectable through room-temperature magnetic coercivity changes, suggesting that rock magnetic measurements can determine weathering intensity in rock samples at many scales. This work contributes evidence that the weathering of sulfidic sedimentary rocks follows a geochemical pattern in which the abundance of sulfide minerals controls the generation of acidity and dissolved elements, and the pH-dependent mobility of these elements controls their export to the ground- and surface-water.

Colorado↗

Syn-eruptive hydration of volcanic ash records pyroclast-water interaction in explosive eruptions

Magma-water interaction can dramatically influence the explosivity of volcanic eruptions. However, syn- and post-eruptive diffusion of external (non-magmatic) water into volcanic glass remains poorly constrained and may bias interpretation of water in juvenile products. Hydrogen isotopes in ash from the 2009 eruption of Redoubt Volcano, Alaska, record syn-eruptive hydration by vaporized glacial meltwater. Both ash aggregation and hydration occurred in the wettest regions of the plume, which resulted in the removal and deposition of the most hydrated ash in proximal areas <50 km from the vent. Diffusion models show that the high temperatures of pyroclast-water interactions (>400°C) are more important than the cooling rate in facilitating hydration. These observations suggest that syn-eruptive glass hydration occurred where meltwater was entrained at high temperature, in the plume margins near the vent. Ash in the drier plume interior remained insulated from entrained meltwater until it cooled sufficiently to avoid significant hydration.

Geophysical Research Letters↗

Site characterization and site response in Port-au-Prince, Haiti

Waveform analysis of aftershocks of the M w 7.0 Haiti earthquake of 12 January 2010 reveals amplification of ground motions at sites within the Cul de Sac valley in which Port-au-Prince is situated. Relative to ground motions recorded at a hard-rock reference site, peak acceleration values are amplified by a factor of approximately 1.8 at sites on low-lying Mio-Pliocene deposits in central Port-au-Prince and by a factor of approximately 2.5–3 on a steep foothill ridge in the southern Port-au-Prince metropolitan region. The observed amplitude, predominant periods, variability, and polarization of amplification are consistent with predicted topographic amplification by a steep, narrow ridge. A swath of unusually high damage in this region corresponds with the extent of the ridge where high weak-motion amplifications are observed. We use ASTER (Advanced Spaceborne Thermal Emission and Reflection Radiometer) imagery to map local geomorphology, including characterization of both near-surface and of small-scale topographic structures that correspond to zones of inferred amplification.

Port-au-prince↗

Notes on some winter birds of north central New Mexico

The observations recorded below were made in Santa Fe, Sandoval and Rio Arriba counties during the winter of 1939-1940. Occasional specimens, 54 in all, collected for racial identification, are deposited in the Museum of Zoology, University of Michigan.

New Mexico↗

Determination of pre-mining geochemical conditions and paleoecology in the Animas River Watershed, Colorado

Determination of the pre-mining geochemical baseline in bed sediments and the paleoecology in a watershed impacted by historical mining activity is of utmost importance in establishing watershed restoration goals. We have approached this problem in the Animas River watershed using geomorphologic mapping methods to identify old pre-mining sediments. A systematic evaluation of possible sites resulted in collection of a large number of samples of pre-mining sediments, overbank sediments, and fluvial tailings deposits from more than 50 sites throughout the watershed. Chemical analysis of individual stratigraphic layers has resulted in a chemical stratigraphy that can be tied to the historical record through geochronological and dendochronological studies at these sites. Preliminary analysis of geochemical data from more than 500 samples from this study, when coupled with both the historical and geochronological record, clearly show that there has been a major impact by historical mining activities on the geochemical record preserved in these fluvial bed sediments. Historical mining activity has resulted in a substantial increase in metals in the very fine sand to clay sized component of the bed sediment of the upper Animas River, and Cement and Mineral Creeks. Enrichment factors for metals in modern bed sediments, relative to the pre-mining sediments, range from a factor of 2 to 6 for arsenic, 4 to more than 10 for cadmium, 2 to more than 10 for lead, 2 to 5 for silver, and 2 to more than 15 for zinc. However, the pre-mining bed sediment geochemical baseline is high relative to crustal abundance levels of many orerelated metals and the watershed would readily be identified as a highly mineralized area suitable for mineral exploration if it had not been disturbed by historical mining activity. We infer from these data that the water chemistry in the streams was less acidic prior to historical mining activity in the watershed. Paleoentologic evidence does not indicate a healthy aquatic habitat in any of the stream reaches investigated above the confluence of the Animas River with Mineral Creek (fig. 1) prior to the impact of historical mining activity. The absence of paleoentologic remains is interpreted to reflect the poor preservation regime of the bed sediment materials sampled. The fluvial sediments sampled in this study represent higher energy environments than are conducive to the preservation of most aquatic organisms including fish remains. We interpret the sedimentological data to indicate that there has been substantial loss of riparian habitat in the upper Animas River above Howardsville as a result of historical mining activity.

Colorado↗

Catastrophic debris flows transformed from landslides in volcanic terrains : mobility, hazard assessment and mitigation strategies

Communities in lowlands near volcanoes are vulnerable to significant volcanic flow hazards in addition to those associated directly with eruptions. The largest such risk is from debris flows beginning as volcanic landslides, with the potential to travel over 100 kilometers. Stratovolcanic edifices commonly are hydrothermal aquifers composed of unstable, altered rock forming steep slopes at high altitudes, and the terrain surrounding them is commonly mantled by readily mobilized, weathered airfall and ashflow deposits. We propose that volcano hazard assessments integrate the potential for unanticipated debris flows with, at active volcanoes, the greater but more predictable potential of magmatically triggered flows. This proposal reinforces the already powerful arguments for minimizing populations in potential flow pathways below both active and selected inactive volcanoes. It also addresses the potential for volcano flank collapse to occur with instability early in a magmatic episode, as well as the 'false-alarm problem'-the difficulty in evacuating the potential paths of these large mobile flows. Debris flows that transform from volcanic landslides, characterized by cohesive (muddy) deposits, create risk comparable to that of their syneruptive counterparts of snow and ice-melt origin, which yield noncohesive (granular) deposits, because: (1) Volcano collapses and the failures of airfall- and ashflow-mantled slopes commonly yield highly mobile debris flows as well as debris avalanches with limited runout potential. Runout potential of debris flows may increase several fold as their volumes enlarge beyond volcanoes through bulking (entrainment) of sediment. Through this mechanism, the runouts of even relatively small collapses at Cascade Range volcanoes, in the range of 0.1 to 0.2 cubic kilometers, can extend to populated lowlands. (2) Collapse is caused by a variety of triggers: tectonic and volcanic earthquakes, gravitational failure, hydrovolcanism, and precipitation, as well as magmatic activity and eruptions. (3) Risk of collapse begins with initial magmatic activity and increases as intrusion proceeds. An archetypal debris flow from volcanic terrain occurred in Colombia with a tectonic earthquake (M 6.4) in 1994. The Rio Piez conveyed a catastrophic wave of debris flow over 100 kilometers, coalesced from multiple slides of surflcial material weakened both by weathering and by hydrothermal alteration in a large strato- volcano. Similar seismogenic flows occurred in Mexico in 1920 (M -6.5), Chile in 1960 (M 9.2), and Ecuador in 1987 (M 6.1 and 6.9). Velocities of wave fronts in two examples were 60 to 90 km/hr (17-25 meters per second) over the initial 30 kilometers. Volcano flank and sector collapses may produce untransformed debris avalanches, as occurred initially at Mount St. Helens in 1980. However, at least as common is direct transformation of the failed mass to a debris flow. At two other volcanoes in the Cascade Range-- Mount Rainier and Mount Baker--rapid transformation and high mobility were typical of most of at least 15 Holocene flows. This danger exists downstream from many stratovolcanoes worldwide; the population at risk is near 150,000 and increasing at Mount Rainier. The first step in preventing future catastrophes is documenting past flows. Deposits of some debris flows, however, can be mistaken for those of less-mobile debris avalanches on the basis of mounds formed by buoyed megaclasts. Megaclasts may record only the proximal phase of a debris flow that began as a debris avalanche. Runout may have extended much farther, and thus furore flow mobility may be underestimated. Processes and behaviors of megaclast-bearing paleoflows are best inferred from the intermegaclast matrix. Mitigation strategy can respond to volcanic flows regardless of type and trigger by: (1) Avoidance: Limit settlement in flow pathways to numbers that can be evacuated after event warnings (flow is occurring). (2) Instrumental even

Professional Paper↗

Uranium in the Copper King Mine, Black Hawk No. 1 Claim, Larimer County, Colorado

Radioactive rock was discovered on the dump of the Copper King mine, sec. 8, T. 10 N., R. 72 W., Larirrier County, Colo., in the summer of 1949. The mine had been prospected intermittently for copper and zinc since 1,916, but there is no record that ore was produced. The country rock is pre-Cambrian granite containing many schist inclusions and narrow pegmatite dikes. Pitchblende disseminated in chlorite and sulfides was deposited in an obscure vein system during an intermediate stage of mineralization. This stage was preceded by biotitic alteration of amphiboles and sulfide deposition. The latest stage of mineralization is represented-by the limonitic dense quartz vein followed during mining. The uranium-bearing vein is about 2-3 feet wide and the dense quartz vein is less than 6 inches wide. Both veins are bordered by 1-3 feet of biotite- and sulfide-bearing granite and arriphibole schist. The uranium content of 26 samples taken in the mine and on the dump ranges from 0.002 to 1.40 percent. These samples contained as much as 2.97 percent copper and 5.96 percent zinc. The general outlook for further prospecting near the Copper King shaft is not favorable, because much of the 'immediately surrounding area has been thoroughly investigated without finding abnormal radioactivity. The most favorable environment for concentration of uranium minerals appears to have been in or near schist inclusions in granite, and further exploration in nearby prospects may result in the discovery of other uranium-bearing deposits. In the Copper King mine, additional exploration would aid in determining the extent of the uranium-bearing material.

Colorado↗

New plant records from Hawai'i Island

The following plant records from the island of Hawai'i include 2 new state records, 6 new island records, 3 new records of naturalized species previously known to be present on the island, and 1 range extension of an orchid recently reported as naturalized. All cited voucher specimens are deposited at BISH.

Hawai'i↗

Remobilization of old permafrost carbon to Chukchi Sea sediments during the end of the last deglaciation

Climate warming is expected to destabilize permafrost carbon (PF‐C) by thaw‐erosion and deepening of the seasonally thawed active layer and thereby promote PF‐C mineralization to CO 2 and CH 4 . A similar PF‐C remobilization might have contributed to the increase in atmospheric CO 2 during deglacial warming after the last glacial maximum. Using carbon isotopes and terrestrial biomarkers (Δ 14 C, δ 13 C, and lignin phenols), this study quantifies deposition of terrestrial carbon originating from permafrost in sediments from the Chukchi Sea (core SWERUS‐L2‐4‐PC1). The sediment core reconstructs remobilization of permafrost carbon during the late Allerød warm period starting at 13,000 cal years before present (BP), the Younger Dryas, and the early Holocene warming until 11,000 cal years BP and compares this period with the late Holocene, from 3,650 years BP until present. Dual‐carbon‐isotope‐based source apportionment demonstrates that Ice Complex Deposit—ice‐ and carbon‐rich permafrost from the late Pleistocene (also referred to as Yedoma)—was the dominant source of organic carbon (66 ± 8%; mean ± standard deviation) to sediments during the end of the deglaciation, with fluxes more than twice as high (8.0 ± 4.6 g·m −2 ·year −1 ) as in the late Holocene (3.1 ± 1.0 g·m −2 ·year −1 ). These results are consistent with late deglacial PF‐C remobilization observed in a Laptev Sea record, yet in contrast with PF‐C sources, which at that location were dominated by active layer material from the Lena River watershed. Release of dormant PF‐C from erosion of coastal permafrost during the end of the last deglaciation indicates vulnerability of Ice Complex Deposit in response to future warming and sea level changes.

Global Biogeochemical Cycles↗

Neogene paleoceanographic events recorded in an active-margin setting: Humboldt basin, California

Recognition of North Pacific paleoceanographic events in the marginal Humboldt (Eel River) basin of northern California enables correlation of stratigraphic sections and development of a chronostratigraphy. Paleoclimatically related coiling shifts in Neogloboquadrina pachyderma (Ehrenberg) and benthic foraminiferal datums form the basis of the chronostratigraphy. Benthic foraminiferal datums are defined by the occurrence of selected benthic species and abundance maxima of benthic biofacies. The compiled chronostratigraphy is used to refine reconstructions of the depositional history of Humboldt basin. Paleoceanographic events, recognized by the distribution of benthic foraminiferal biofacies, are used to infer paleoceanographic history along the northeastern Pacific margin. The similarity in coiling curves of N. pachyderma from the marine sequence at DSDP Site 173 and the coastal Centerville Beach section of Humboldt basin and at other independently dated sites along the northeastern Pacific margin demonstrates that matching records of climatic oscillations is a reliable method of correlating marine sequences. Benthic fauna from the Centerville Beach section vary in phase with climatically related coiling shifts in N. pachyderma . In particular these data show an increase in displaced neritic fauna during inferred warm intervals and resurgence of deeper bathyal fauna during inferred cool events. Similar data are observed from the inland Eel River section, demonstrating that benthic foraminiferal trends recognized at Centerville Beach can be identified elsewhere in Humboldt basin. This in-phase benthic response to climatic fluctuations probably results from changes in vertical depth range of many benthic species in response to paleoclimatically related vertical changes in water-mass position. Depositional histories reconstructed for two key sites in southern Humboldt basin indicate low rates of sediment accumulation during early basin filling with hemipelagic sediments. Initiation of turbidite sedimentation in the early Pliocene resulted in a sharp increase in rate of sediment accumulation. This increase in rate of sediment accumulation is partially a response to tectonic uplift in the northern Coast Ranges and may be an effect of realignment of motion between the Pacific and North American plates at about this time. The inland site shoaled more rapidly during turbidite sedimentation as a result of a higher rate of sediment accumulation. The rate of sediment accumulation increased again at this site in the late Pliocene during deposition of shelf and nearshore facies. The Eel River region subsided concurrent with deposition of these shallow-water deposits.

Palaeogeography, Palaeoclimatology, Palaeoecology↗