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Isotopic study of galenas from the upper Mississippi Valley, the Illinois-Kentucky, and some Appalachian Valley mineral districts

Analyses of lead isotopes in galena in carbonate rock ore deposits collected from several mineralized districts in the Central and Eastern Interior of the United States support previous studies in establishing that the galena is anomalously radiogenic ("J"type")- This study , using care-fully selected samples to test some géologie relationships, shows region-wide and distrietwide systematic variations in isotope ratios. The genetic implications of thèse variations are discussed. Two mechanisms of origin are considered to explain thèse variations in isotopic ratios. One involves mixing of leads from multiple sources, the other calls for variable lead-isotope ratios originating from a single source. Several source materials for the lead ores have been suggested; whether a single source has predominated, or two or more main sources have predominated is still unresolved. Slopes from Pb206/Pb204 versus Pb207/Pb204 plot are compatible with a contribution of lead by the 1300 ± 300 m.y. basement rocks that underlie the deposits. The spatial relationships of alkaline igneous rocks to several of the minerai districts in the Mississippi Valley région suggest a possible mag-matic source for the lead. Isotopic analyses of galenas closely associated with several of the intrusive rocks are similar in isotopic composition to adjacent ore leads, but genetic implications are ambiguous. Galena oc-curring in shales in the Mississippi Valley région outside mineralized districts contains ordinary lead. Théories that call upon such shales to be the major source of the lead in the depoaits of the Mississippi Valley type must explain this distinct différence in isotopic compositions. Galena collected from districts within the Appalachian Ridge and Valley Province contains notably less radiogenic lead than that from the Mississippi Valley minerai districts , and the lead is of the ordinary type.

Illinois, Kentucky↗

Geology and quality of water in the Modesto-Merced area, San Joaquin Valley, California, with a brief section on hydrology

The Modesto-Merced area includes about 1,800 square miles on the northeast side of the San Joaquin Valley. The physiographic units in the area are (1) Sierra Nevada, (2) dissected uplands, (3) low alluvial plains and fans, (4) river flood plains and channels, and (5) overflow lands. Geologic units consist of consolidated rocks and unconsolidated deposits. The dominant structure of the geologic units is that of a homocline, which reflects the southwestward-tilted fault block of the Sierra Nevada. The consolidated rocks include: (1) basement complex (pre-Tertiary), (2) marine sandstone and shale (Cretaceous), (3) Ione Formation and other sedimentary rocks (Eocene), (4) Valley Springs Formation (late? Miocene), and (5) the Mehrten Formation (Miocene and Pliocene). In the eastern part of the area, the consolidated rocks generally yield small quantities of water to wells except for the Mehrten Formation which is an important aquifer. The unconsolidated deposits include: (1) continental deposits (Pliocene and Pleistocene?), (2) lacustrine and marsh deposits (Pleistocene), (3) older alluvium (Pleistocene and Holocene?), (4) younger alluvium (Holocene), and (5) flood-basin deposits (Holocene). The continental deposits and older alluvium are the main water-yielding units in the unconsolidated deposits. The lacustrine and marsh deposits (E-clay) and the flood-basin deposits yield little water to wells, and the younger alluvium in most places probably yields only moderate quantities of water to wells. There are three ground-water bodies in the Modesto-Merced area: (1) the unconfined water body, (2) the confined water body, and (3) the water body in consolidated rocks. The unconfined water body occurs in the unconsolidated deposits above and east of the E-clay, except in the western and southern parts of the area where clay lenses occur and semiconfined conditions exist. The confined water body occurs in the unconsolidated deposits below the E-clay and extends downward to the base of fresh water. The water body in consolidated rocks occurs under both perched and confined conditions. Ground-water movement in the unconfined and the confined water bodies is generally westward toward the valley trough. In the unconfined water body, the water also moves toward the major rivers, and toward pumping depressions at Modesto and near El Nido. Because of the higher head in the unconfined water body, water slowly moves from it through the E-clay to the underlying confined water body. Surface water is used extensively for irrigation in most of the study area; consequently, shallow water in the unconfined water body has to be controlled by pumping. Nevertheless, water levels near Modesto declined about 6 feet between 1958 and 1962, for the most part during the dry years 1959-61. Near El Nido, water levels declined about 70 feet between 1942 and 1967. In the confined water body, water levels were high in the winter and spring and low in the summer and fall, reflecting irrigation practices. In the southwestern part of the area, water levels in the confined water body declined about 14 feet from 1962 to 1968 and rose slightly after 1968, whereas in the northwestern part water levels remained fairly constant. Water from the upper reaches of the Stanislaus, Tuolumne, Merced, and Chowchilla Rivers is calcium bicarbonate in chemical type and is of excellent quality. As those rivers cross the valley floor, their water quality is generally degraded by return flows from irrigated land, and in the Tuolumne River by saline water discharged from abandoned gas wells. Average dissolvedsolids content in the major rivers, as indicated by chemical analyses, do not exceed 400 mg/1 (milligrams per liter) except in the San Joaquin River where average dissolved-solids content has not exceeded 1,050 mg/l. Water from minor streams in the area is bicarbonate in chemical type with dissolved-solids content ranging from 56 mg/1 to about 350 mg/l. Although chloride-type fresh ground water occurs in the unconfined and confined water bodies and in the water body in consolidated rocks, most of the fresh ground water is a bicarbonate type that has a dissolved-solids content of less than 500 mg/l. Water having dissolved solids in excess of about 2,000 mg/1 is considered to be saline. Saline water extends below the base of fresh water to the basement complex and, except in the extreme eastern part, underlies most of the study area. Saline water also occurs as lenses above the base of fresh water in the unconfined and confined water bodies.

California↗

Seismic methods for determining earthquake source parameters and lithospheric structure

The seismologic methods most commonly used in studies of earthquakes and the structure of the continental lithosphere are reviewed in three main sections: earthquake source parameter determinations, the determination of earth structure using natural sources, and controlled-source seismology. The emphasis in each section is on a description of data, the principles behind the analysis techniques, and the assumptions and uncertainties in interpretation. Rather than focusing on future directions in seismology, the goal here is to summarize past and current practice as a companion to the review papers in this volume. Reliable earthquake hypocenters and focal mechanisms require seismograph locations with a broad distribution in azimuth and distance from the earthquakes; a recording within one focal depth of the epicenter provides excellent hypocentral depth control. For earthquakes of magnitude greater than 4.5, waveform modeling methods may be used to determine source parameters. The seismic moment tensor provides the most complete and accurate measure of earthquake source parameters, and offers a dynamic picture of the faulting process. Methods for determining the Earth’s structure from natural sources exist for local, regional, and teleseismic sources. One-dimensional models of structure are obtained from body and surface waves using both forward and inverse modeling. Forward-modeling methods include consideration of seismic amplitudes and waveforms, but lack the formal resolution estimates obtained with inverse methods. Two- and three-dimensional lithospheric models are derived using various inverse methods, but at present most of these methods consider only traveltimes of body waves. Controlled-source studies of the Earth’s structure are generally divided by method into seismic refraction/wide-angle reflection and seismic reflection studies. Seismic refraction profiles are usually interpreted in terms of two-dimensional structure by forward modeling of traveltimes and amplitudes. The refraction method gives excellent estimates of seismic velocities, but relatively low resolution of structure. Formal resolution estimates are not possible for models derived from forward modeling, but informal estimates can be obtained by perturbing the best-fitting model. Inversion methods for seismic refraction data for one-dimensional models are well established, and two- and three-dimensional methods, including tomography, have recently been developed. Seismic reflection data provide the highest resolution of crustal structure, and have provided many important geological insights in the past decade. The acquisition and processing of these data have been greatly advanced by the hydrocarbon exploration industry. However, reliable crustal velocity control is generally lacking, and the origin of deep crustal reflections remains unclear, resulting in nonunique interpretations. A new form of lithospheric seismology has recently emerged that combines the advantages of seismic refraction and seismic reflection profiles, and the distinction between the two methods is steadily diminishing. Major challenges for future work will be the collection of data that are more densely sampled in space, and the development of interpretation methods that provide quantitative estimates of the uncertainties in the calculated models.

GSA Memoirs↗

Genesis of ore deposits in the San Juan Volcanic Field, Southwestern Colorado-lead isotope evidence

In the San Juan volcanic area of southwestern Colorado, the isotopic composition of lead in ores and ore prospects of Cenozoic age ranges widely: 17.72 to 21.13 for 206 Pb/ 204 Pb; 15.50 to 15.81 for 207 Pb/ 204 Pb; and 37.21 to 38 for 208 Pb/ 204 Pb. Examination of the lead isotope data indicates that once deposition of lead minerals begins, further exchange of lead between fluid and wall rock is insignificant. This conclusion is supported by the relatively constant isotopic composition of the lead in these ores, which is not affected by the grade of ore mineralization or type of wall rock. The values of 206 Pb/ 204 Pb in some vein-type deposits exceed the maximum value known for all Mesozoic and Cenozoic igneous rocks of the Rocky Mountain region. These isotopic relations show that if ore-forming solutions are composed of meteoric water, as indicated in studies of light stable isotopes, they must have penetrated deep enough to acquire lead from Pre-cambrian rocks or sediments derived from them. The fact that some of these vein ores are now in Cenozoic igneous rocks indicates the ore fluid had an upward vertical component to its movement. The lead isotope data therefore support a circulating cell hypothesis for these kinds of ores, as suggested by many recent studies of light stable isotopes as related to mineralization. Some other deposits (Summitville, Jasper, Red Mountain district) have values of 206 Pb/ 204 Pb similar to those of the large volumes of altered rock that enclose them ( 206 Pb/ 204 Pb ∼ 18.5), suggesting that in places the lead may have been locally derived by leaching of the adjacent rocks or from magmatogenic fluids. When the lead isotope data are treated in detail, the rocks and galenas of the Platoro caldera complex, of the central San Juan caklera complex, and of the Baughman Creek center appear to contain significant components derived from 1,400- to l,500-m.y.-old and 1,700- to 1,800 m.y.-old source materials. These also are the ages of the two main groups of rocks that comprise the Precambrian basement under the San Juan volcanic area. Although the data from the western San Juan caldera complex scatter considerably, the only obvious source for the lead seems to be the 1,700- to l,800-m.y.-old rocks or detritus of such age in Phanerozoic sediments. Where the involvement of 1,400- to l,500-m.y.-old sources is greatest, the Th/U ratio in the source material is small (calculated to be about 0.7), whereas the Th/U ratio of the 1,700- to l,800-m.y.-old source material appears to be 2.3 to 3.3. The largest Th/U values are from the western San Juan caldera complex. © 1979 Society of Economic Geologists, Inc.

Colorado↗

Source of lead and mineralizing brines for rossie-type Pb-Zn veins in the Frontenac axis area, New York ( USA).

Veins composed mainly of calcite and some galena, sphalerite, fluorite, and other minerals are widespread in the Frontenac axis area of New York and Ontario. In New York, the veins (Fig. 1) occur mainly west and northwest of Gouverneur (Brown, 1983). The veins, mined in the 1800s for lead, were first described by Emmons (1838). Smyth (1903) called these the "Rossie lead veins," a name now used locally for all veins of this type. Similar veins in southeastern Ontario were described by Uglow (1916) and Sangster (1970). The steeply dipping veins are aligned along extensional fractures in metamorphic rocks of the Grenville Complex and in Paleozoic sedimentary rocks, including the Potsdam Sandstone of Late Cambrian age, and limestones as young as Middle Ordovician. However, the age of emplacement of Rossie veins is unknown. The veins are mineralogically simple, consisting of calcite (~95%) with minor and approximately equal amounts of sphalerite and galena, and sparse fluorite, barite, celestite, and chalcopyrite (Brown, 1983). Paragenetically early minerals are crushed and granulated; later undeformed minerals fill open spaces (Fig. 2). Sandstone dikes that originated from either the overlying Potsdam Sandstone or stratigraphically higher arenaceous rocks cut into the Rossie veins and occupy all available space. Their unstratified nature suggests that sand was intruded under high hydraulic pressure during tectonic events that reopened the veins. Most veins are vertical and narrow (1-3 cm wide) and those that were mined are as much as 1.7 m wide. The veins trend mainly northwest-southeast but have a local east-west orientation. The fractures and veins show evidence of strike-slip faulting with a right-lateral offset due to late reactivation of north-east-trending faults that originally formed during the Proterozoic Grenville orogeny. Relatively rare inclined veins, termed gash veins (Brown, 1983), occur in proximity to some of the regional northeast-trending faults. These veins contain open spaces lined with large, undeformed crystals of calcite (~90%) and green fluorite (~5%). The minerals of the northeast-trending gash veins, which dip to the northwest, are believed to be paragenetically late results of the same mineralization and tectonic event that produced the Rossie veins. For example, the green fluorite in the gash veins is similar in color and occurrence to small fluorite crystals in vugs in the vertical Rossie veins. Associated with the fluorite in both occurrences is coarse crystalline calcite containing tiny tetrahedra of chalcopyrite aligned along crystallographic planes. The present study of fluid inclusions and lead isotopes was done to understand better the nature and possible source of the mineralizing solutions for both vertical and gash veins and the possible origin of the lead and zinc mineralization. Large deposits of essentially syngenetic sphalerite with minor to trace galena occur in the Proterozoic rocks of this region (e.g., Balmat-Edwards, New York). Although none of these deposits are known in the immediate vicinity of Rossie veins, the possibility that Rossie veins contain remobilized metals from these older deposits was considered.

New York↗

Geology, Water, and Wind in the Lower Helmand Basin, Southern Afghanistan

This report presents an overview of the geology, hydrology, and climate of the lower Helmand Basin, a large, closed, arid basin in southern Afghanistan. The basin is drained by the Helmand River, the only perennial desert stream between the Indus and Tigris-Euphrates Rivers. The Helmand River is the lifeblood of southern Afghanistan and has supported desert civilizations in the Sistan depression for over 6,000 years. The Helmand Basin is a structurally closed basin that began to form during the middle Tertiary as a consequence of the collision of several Gondwanaland fragments. Aeromagnetic studies indicate the basin is 3-5 kilometers deep over basement rocks. Continued subsidence along basin-bounding faults in Iran and Pakistan throughout the Neogene has formed the Sistan depression in the southwest corner of the basin. Lacustrine, eolian, and fluvial deposits are commonly exposed in the basin and were intruded by latest Miocene-middle Quaternary volcanoes, which indicates that depositional environments in the lower Helmand Basin have not substantially changed for nearly 10 million years. Lakes expanded in the Sistan depression during the Quaternary; however, the size and extent of these pluvial lakes are unknown. Climate conditions in the lower Helmand Basin likely mirrored climate changes in the Rajasthan Desert to the east and in Middle Eastern deserts to the west: greater aridity during global episodes of colder temperatures and increased available moisture during episodes of warmer temperatures. Eolian processes are unusually dominant in shaping the landscape in the basin. A strong wind blows for 120 days each summer, scouring dry lakebeds and creating dune fields from annual flood deposits. Nearly one-third of the basin is mantled with active or stabilized dunes. Blowing winds combined with summer temperatures over 50? Celsius and voluminous insect populations hatched from the deltaic wetlands create an environment referred to as the 'most odious place on earth' by 19th century visitors. During dry years, large plumes of dust originating from Sistan are recorded by weather satellites. The Helmand River drains about 40 percent of Afghanistan and receives most of its moisture from melting snow and spring storms. Similar to many desert streams, the Helmand and its main tributary, the Arghandab River, are characterized by large fluctuations in monthly and annual discharges. Water from the Helmand accumulates in several hamuns (shallow lakes) in the Sistan depression. The wetlands surrounding these hamuns are the largest in western Asia and are directly affected by droughts and floods on the Helmand. Average annual discharge on the Helmand is about 6.12 million megaliters (million cubic meters), and the annual discharge varies by a factor of five. In 2005, the region was just beginning to recover from the longest drought (1998-2005) of record back to 1830. Annual peak discharges range from less than 80 cubic meters per second in 1971 to nearly 19,000 cubic meters per second in 1885. Large floods fill each hamun to overflowing to create one large lake that overflows into the normally dry Gaud-i Zirreh basin. The interaction of flooding, active subsidence, and wind erosion causes frequent channel changes on the Helmand delta. A major development effort on the Helmand River was initiated after World War II with substantial aid from the United States. Two dams and several major canals were completed in the 1950s; however, poor drainage conditions on the newly prepared agricultural fields caused extensive waterlogging and salinization. New drains were installed and improved agricultural methods were implemented in the 1970s, and some lands became more productive. Since 1980, Afghanistan has endured almost constant war and civil and political strife. In 2005, the country was on a path to rebuild much of its technical infrastructure. Revitalization of agricultural lands in the lower Helmand Basin and improved managem

Scientific Investigations Report↗

Hydrology and water quality in the Green River and surrounding agricultural areas near Green River in Emery and Grand Counties, Utah, 2004-05

Water from the Colorado River and its tributaries is used for municipal and industrial purposes by about 27 million people and irrigates nearly 4 million acres of land in the Western United States. Water users in the Upper Colorado River Basin consume water from the Colorado River and its tributaries, reducing the amount of water in the river. In addition, application of water to agricultural land within the basin in excess of crop needs can increase the transport of dissolved solids to the river. As a result, dissolved-solids concentrations in the Colorado River have increased, affecting downstream water users. During 2004-05, the U.S. Geological Survey, in cooperation with the Natural Resources Conservation Service, investigated the occurrence and distribution of dissolved solids in water from the agricultural areas near Green River, Utah, and in the adjacent reach of the Green River, a principle tributary of the Colorado River. The flow-weighted concentration of dissolved solids diverted from the Green River for irrigation during 2004 and 2005 was 357 milligrams per liter and the mean concentration of water collected from seeps and drains where water was returning to the river during low-flow conditions was 4,170 milligrams per liter. The dissolved-solids concentration in water from the shallow part of the ground-water system ranged from 687 to 55,900 milligrams per liter. Measurable amounts of dissolved solids discharging to the Green River are present almost exclusively along the river banks or near the mouths of dry washes that bisect the agricultural areas. The median dissolved-solids load in discharge from the 17 drains and seeps visited during the study was 0.35 ton per day. Seasonal estimates of the dissolved-solids load discharging from the study area ranged from 2,800 tons in the winter to 6,400 tons in the spring. The estimate of dissolved solids discharging from the study area annually is 15,700 tons. Water samples collected from selected sites within the Green River agricultural areas were analyzed for naturally occurring isotopes of strontium and boron, which can be useful for differentiating dissolved-solids sources. Substantial variations in the delta strontium-87 and delta boron-11 values among the sites were measured. Canal and river samples had relatively low concentrations of strontium and the most positive (heavier) isotopic ratios, while drains and seeps had a wide range of strontium concentrations and isotopic ratios that generally were less positive (lighter). Further study of the variation in strontium and boron concentrations and isotope ratios may provide a means to distinguish end members and discern processes affecting dissolved solids within the Green River study area; however, the results from isotope data collected during this study are inconclusive. Flow and seepage losses were estimated for the three main canals in the study area for May 2 to October 4 in any given year. This period coincides with the frost-free period in the Green River area. Estimated diversion from the Green River into the Thayn, East Side, and Green River Canals is 6,600, 6,070, and 19,900 acre-feet, respectively. The estimated seepage loss to ground water from the Thayn, East Side, and Green River Canals during the same period is 1,550, 1,460, and 4,710 acre-feet, respectively.

Utah↗

Predicting ground-water movement in large mine spoil areas in the Appalachian Plateau

Spoil created by surface mining can accumulate large quantities of ground-water, which can create geotechnical or regulatory problems, as well as flood active mine pits. A current study at a large (4.1 km2), thick, (up to 90 m) spoil body in eastern Kentucky reveals important factors that control the storage and movement of water. Ground-water recharge occurs along the periphery of the spoil body where surface-water drainage is blocked, as well as from infiltration along the spoil-bedrock contact, recharge from adjacent bedrock, and to a minor extent, through macropores at the spoil's surface. Based on an average saturated thickness of 6.4 m for all spoil wells, and assuming an estimated porosity of 20%, approximately 5.2 x 106 m3 of water is stored within the existing 4.1 km2 of reclaimed spoil. A conceptual model of ground-water flow, based on data from monitoring wells, dye-tracing data, discharge from springs and ponds, hydraulic gradients, chemical data, field reconnaissance, and aerial photographs indicate that three distinct but interconnected saturated zones have been established: one in the spoil's interior, and others in the valley fills that surround the main spoil body at lower elevations. Ground-water movement is sluggish in the spoil's interior, but moves quickly through the valley fills. The conceptual model shows that a prediction of ground-water occurrence, movement, and quality can be made for active or abandoned spoil areas if all or some of the following data are available: structural contour of the base of the lowest coal seam being mined, pre-mining topography, documentation of mining methods employed throughout the mine, overburden characteristics, and aerial photographs of mine progression.Spoil created by surface mining can accumulate large quantities of ground-water, which can create geotechnical or regulatory problems, as well as flood active mine pits. A current study at a large (4.1 km2), thick, (up to 90 m) spoil body in eastern Kentucky reveals important factors that control the storage and movement of water. Ground-water recharge occurs along the periphery of the spoil body where surface-water drainage is blocked, as well as from infiltration along the spoil-bedrock contact, recharge from adjacent bedrock, and to a minor extent, through macropores at the spoil's surface. Based on an average saturated thickness of 6.4 m for all spoil wells, and assuming an estimated porosity of 20%, approximately 5.2 ?? 106 m3 of water is stored within the existing 4.1 km2 of reclaimed spoil. A conceptual model of ground-water flow, based on data from monitoring wells, dye-tracing data, discharge from springs and ponds, hydraulic gradients, chemical data, field reconnaissance, and aerial photographs indicate that three distinct but interconnected saturated zones have been established: one in the spoil's interior, and others in the valley fills that surround the main spoil body at lower elevations. Ground-water movement is sluggish in the spoil's interior, but moves quickly through the valley fills. The conceptual model shows that a prediction of ground-water occurrence, movement, and quality can be made for active or abandoned spoil areas if all or some of the following data are available: structural contour of the base of the lowest coal seam being mined, pre-mining topography, documentation of mining methods employed throughout the mine, overburden characteristics, and aerial photographs of mine progression.

International Journal of Coal Geology↗

Surficial geologic map of the greater Omaha area, Nebraska and Iowa

Geologic mapping, in support of the USGS Omaha-Kansas City Geologic Mapping Project, shows the spatial distribution of artificial-fill, alluvial, eolian, and glacial deposits and bedrock in and near Omaha, Nebraska. Artificial fill deposits are mapped chiefly beneath commercial structures, segments of interstate highways and other major highways, railroad tracks, airport runways, and military facilities, and in landfills and earth fills. Alluvial deposits are mapped beneath flood plains, in stream terraces, and on hill slopes. They include flood-plain and stream-channel alluvium, sheetwash alluvium, and undivided sheetwash alluvium and stream alluvium. Wind-deposited loess forms sheets that mantle inter-stream areas and late Wisconsin terrace alluvium. Peoria Loess is younger of the two loess sheets and covers much of the inter-stream area in the map area. Loveland Loess is older and is exposed in a few small areas in the eastern part of the map area. Glacial deposits are chiefly heterogeneous, ice-deposited, clayey material (till) and minor interstratified stream-deposited sand and gravel. Except for small outcrops, glacial deposits are covered by eolian and alluvial deposits throughout most of the map area. Bedrock is locally exposed in natural exposures along the major streams and in quarries. It consists of Dakota Sandstone and chiefly limestone and shale of the Lansing and Kansas City Groups. Sand and gravel in flood plain and stream-channel alluvium in the Platte River valley are used mainly for concrete aggregate. Limestone of the Lansing and Kansas City Groups is used for road-surfacing material, rip rap, and fill material.

Iowa, Nebraska↗

Combining sediment fingerprinting with age-dating sediment using fallout radionuclides for an agricultural stream, Walnut Creek, Iowa, USA

Purpose The main purpose of this study was to demonstrate the utility of the sediment fingerprinting approach to apportion surface-derived sediment, and then age date that portion using short-lived fallout radionuclides. In systems where a large mass of mobile sediment is in channel storage, age dating provides an understanding of the transfer of sediment through the watershed and the time scales over which management actions to reduce sediment loadings may be effective. Materials and methods In the agricultural Walnut Creek watershed, Iowa, the sediment-fingerprinting approach with elemental analysis was used to apportion the sources of fine-grained sediment (croplands, prairie, unpaved roads, and channel banks). Fallout radionuclides ( 7 Be, 210 Pb ex ) were used to age the portion of suspended sediment that was derived from agricultural topsoil. Age dating was performed at two different scales: 210 Pb ex which can date sediment to ~ 85 years and 7 Be to ~ 1 year. Results and discussion Sediment fingerprinting results indicated that the majority of suspended sediment is derived from cropland (62%) with streambanks contributing 36%, and prairie, pasture, and unpaved roads each contributing ≤ 1%. The topsoil–derived portion of sediment (primarily agriculture) dated using 210 Pb ex has ages ranging from 1 to 58 years, and using 7 Be, a component of much younger sediment that yields ages ranging from 44 to 205 days. The occurrence of 7 Be indicates that some portion of the sediment is young, on the order of months, whereas the dating based on 210 Pb ex indicates that some of the surface-derived sediment has been in channel storage for decades. Published studies in Walnut Creek indicate that a large component of sediment is stored in the channel bed. Conclusions We conclude that the 210 Pb ex -based ages are a reasonable estimate for the mean age of the surface-derived fraction and that 7 Be activities are evidence that there is a smaller fraction of very young sediment in the stream. We propose a geomorphic model where agricultural soil is delivered to the channel and conveyed to the watershed outlet at three time scales: a geologic-millennial time scale, decades, and a young time scale (< 1 year).

Iowa↗

Well installation, single-well testing, and particle-size analysis for selected sites in and near the Lost Creek Designated Ground Water Basin, north-central Colorado, 2003-2004

This report describes results from a groundwater data-collection program completed in 2003-2004 by the U.S. Geological Survey in support of the South Platte Decision Support System and in cooperation with the Colorado Water Conservation Board. Two monitoring wells were installed adjacent to existing water-table monitoring wells. These wells were installed as well pairs with existing wells to characterize the hydraulic properties of the alluvial aquifer and shallow Denver Formation sandstone aquifer in and near the Lost Creek Designated Ground Water Basin. Single-well tests were performed in the 2 newly installed wells and 12 selected existing monitoring wells. Sediment particle size was analyzed for samples collected from the screened interval depths of each of the 14 wells. Hydraulic-conductivity and transmissivity values were calculated after the completion of single-well tests on each of the selected wells. Recovering water-level data from the single-well tests were analyzed using the Bouwer and Rice method because test data most closely resembled those obtained from traditional slug tests. Results from the single-well test analyses for the alluvial aquifer indicate a median hydraulic-conductivity value of 3.8 x 10-5 feet per second and geometric mean hydraulic-conductivity value of 3.4 x 10-5 feet per second. Median and geometric mean transmissivity values in the alluvial aquifer were 8.6 x 10-4 feet squared per second and 4.9 x 10-4 feet squared per second, respectively. Single-well test results for the shallow Denver Formation sandstone aquifer indicate a median hydraulic-conductivity value of 5.4 x 10-6 feet per second and geometric mean value of 4.9 x 10-6 feet per second. Median and geometric mean transmissivity values for the shallow Denver Formation sandstone aquifer were 4.0 x 10-5 feet squared per second and 5.9 x 10-5 feet squared per second, respectively. Hydraulic-conductivity values for the alluvial aquifer in and near the Lost Creek Designated Ground Water Basin generally were greater than hydraulic-conductivity values for the Denver Formation sandstone aquifer and less than hydraulic-conductivity values for the alluvial aquifer along the main stem of the South Platte River Basin reported by previous studies. Particle sizes were analyzed for a total of 14 samples of material representative of the screened interval in each of the 14 wells tested in this study. Of the 14 samples collected, 8 samples represent the alluvial aquifer and 6 samples represent the Denver Formation sandstone aquifer in and near the Lost Creek Designated Ground Water Basin. The sampled alluvial aquifer material generally contained a greater percentage of large particles (larger than 0.5 mm) than the sampled sandstone aquifer material. Alternatively, the sampled sandstone aquifer material generally contained a greater percentage of fine particles (smaller than 0.5 mm) than the sampled alluvial aquifer material consistent with the finding that the alluvial aquifer is more conductive than the sandstone aquifer in the vicinity of the Lost Creek Designated Ground Water Basin.

Open-File Report↗

Selenium in the upper Blackfoot River watershed, southeastern Idaho, 2001-12

The upper Blackfoot River in southeastern Idaho receives runoff from 12 large phosphate mines. Waste shales that are removed to access the phosphate ore are highly enriched with selenium, resulting in elevated selenium in runoff from the mine waste dumps. In 2001, in cooperation with the Bureau of Land Management, the U.S. Geological Survey (USGS) began monitoring streamflow, selenium, and other water-quality parameters at a single location near the outlet of the upper Blackfoot River to the Blackfoot Reservoir. Water samples primarily were collected by a flow triggered, automated pump sampler, supplemented by manual point and equal-width integrated manual samples. The approach to monitoring concentrations and streamflow over time at a fixed location is ideal for evaluating temporal trends, but provides no information about the relative source contributions from the mine waste dumps draining into various tributaries. In 2001, the Idaho Department of Environmental Quality (IDEQ) began an annual, mid-May, synoptic survey of selenium concentrations and streamflow at 21 locations along the main stem Blackfoot River and its tributaries. Individually, neither the intensive USGS sampling at the outlet nor the IDEQ annual synoptic sampling provides a comprehensive view of selenium runoff in the Blackfoot River watershed. Together, the efforts are complementary; therefore, in this report, results are presented from both sampling efforts. The USGS collected time-series data from 2001 to 2012 at a fixed location, the Blackfoot River near the outlet of the reservoir, near Henry, Idaho (USGS streamgage 13063000). Dissolved selenium concentrations from 450 filtered samples collected at this site ranged from 0.5 to 11.4 micrograms per liter (&mu;g/L). The State of Idaho chronic aquatic life criterion concentration of 5 &mu;g/L was exceeded in 31 percent of the samples, with most exceedances occurring during May of each year. No exceedances of the selenium criterion were recorded in months other than April, May, or June. Concentrations of selenium in unfiltered and filtered samples were similar, and concentrations from samples collected by depth and width integrated methods were similar to those collected by grab (point) samples, indicating that the grab samples adequately represent selenium concentrations across the entire river cross section. In speciation analyses made during 2003 and 2004, the median percentage of total selenium as selenate was 81 percent, ranging from 17 to 98 percent, and the median percentage of total selenium as selenite was 19 percent, ranging from 2 to 83 percent of the total selenium. During the period of study, selenium concentrations had an upward trend during the lowflow season of August&ndash;October. Time trends were not obvious during other seasons. Selenium daily loads varied by more than a factor of 900 during the study period and ranged from 0.03 kilograms per day (kg/d) to more than 24 kg/d. Annual maximum daily loads of selenium varied over nearly a factor of 12, ranging from about 2 to 24 kg/d. For the annual spring synoptic samples collected by the IDEQ along the main stem Blackfoot River and major tributaries, selenium concentrations ranged from less than 2 to 870 &mu;g/L in 176 samples. In most years, the synoptic sampling showed that the majority of the selenium loads passing the USGS streamgage at the outlet of the watershed could be attributed to a single tributary, East Mill Creek, which enters the Blackfoot River through Spring Creek. Selenium loads decreased by about half from East Mill Creek before reaching the Blackfoot River, suggesting that much selenium is at least temporarily removed from the water column by uptake by aquatic vegetation or by losses to sediment. Similar decreases in selenium loads occurred through the main stem Blackfoot River before reaching the outlet in low flow years, but not in high flow years.

Idaho↗

Species diversity: Patterns in modern and Miocene foraminifera of the eastern margin of North America

Patterns of foraminiferal species diversity were examined along the eastern margin of North America by utilizing the number of species, S, the information function, H(S), and species equitability, E. The 350 modern samples we studied extended from the Arctic to the Gulf of Mexico at depths ranging from a few meters to more than 5,000 m. In addition, 29 samples from Miocene strata of the Atlantic Coastal Plain and continental shelf were studied. Modern species diversity as measured by S and H(S) generally increases as depth increases and latitude decreases. Some notable exceptions occur, however, which are difficult to explain. For example, species diversity in the Arctic depth interval of 0 to 100 m is as high or higher than that found immediately south of Nova Scotia, in the Gulf of Maine, on Browns and Georges Banks, and even off the Gulf of Mexico deltas. At the moderate depth interval of 100 to 1,000 m, however, the entire margin north of Browns and Georges Banks has lower diversities than that to the south. The highest diversity by far in this depth interval occurs in the northeastern Gulf of Mexico. At the depth interval greater than 1,000 m, the more southern areas studied generally have a higher species diversity than the more northern Cape Cod to Maryland area. An exception to this is the northwestern Gulf of Mexico; this area is also an exception in that species diversity is significantly lower in the deeper waters than in the shallower waters in the same area. The measure of species equitability, E, showed no clear pattern with depth or latitude. This may be so because no simple pattern of species proportions exists or because the sampling was inadequate to measure it. Samples from the Miocene strata show a striking resemblance in species diversity to modern samples at similar depths and latitudes. Our observations indicate that species diversity and equitability have not increased during the last 15 × 10 6 yrs. The fossil and modern data indicate that each environment has its own carrying capacity and that this capacity is reached rather quickly. Although time and environmental stability are undoubtedly important in determining species diversity, as presently defined they are inadequate to explain all observed patterns. Long-term observations in various environments will be required to determine the relative importance of variables that affect species diversity.

Geological Society of America Bulletin↗

Micromineralogy of silver-bearing sphalerite from Flat River, Missouri

Detailed mineralogical and chemical study of sphalerite-rich lead ores from Flat River, Mo., confirms the presence of anomalous amounts of silver in the sphalerite. Although silver is closely associated with chlorine and no silver sulfide minerals were identified, geochemical considerations indicate the silver may be in the form of discrete submicron-size grains of sulfide rather than chloride. However, the close correlation between abundance variations in silver, chlorine, cadmium, iron, and minor lead suggests the possible existence of submicron-size grains of a complex chloride or oxychloride. Results from detailed chemical study of sphalerite show: (1) chlorine is present in areas containing silver and changes in abundance of both elements are similar; (2) the mole ratio of chlorine to silver varies from approximately 3:1 to 6:1 with an approximate average of 5:1 and the total content of each element varies widely between grains and within the same grain; (3) taking total silver in any analysis and calculating the amount of chlorine required for silver chloride leaves an excess of chlorine; (4) in chlorine-deficient areas the amounts of iron and cadmium substituting for zinc in the sphalerite structure vary widely; and (5) in areas containing chlorine, changes in abundance of iron and cadmium vary directly with that of chlorine. The fine-grained dusty opaque inclusions characterize sphalerite from this area; they were identified as mainly galena with lesser amounts of pyrite and cassiterite. Galena is silver-free (<0.02 weight percent Ag) and is essentially pure lead sulfide. Other sulfides identified include pyrite, a cobalt-nickel-iron sulfide of composition Co (sub 0.55) Ni (sub 0.25) Fe (sub 0.20) S (sub 2.00), and an iron-cobalt-nickel sulfide containing 22-28 weight percent Fe, 10-15 weight percent Co, and 3-5 weight percent Ni. Anomalous amounts of tin present as cassiterite are associated with the gangue minerals quartz, potash feldspar, a kaolinite-type clay, and trace amounts of cuprite. Carbonate gangue minerals include calcite, dolomite, ankerite, magnesite, and minor amounts of cerussite. Chemical analyses were made of many minerals and physical and textural relationships examined.

Missouri↗

Noble gas data from Goldfield and Tonopah epithermal Au-Ag deposits, ancestral Cascades Arc, USA: Evidence for a primitive mantle volatile source

The He, Ne, and Ar isotopic composition of fluid inclusions in ore and gangue minerals were analyzed to determine the source of volatiles in the high-grade Goldfield and Tonopah epithermal Au-Ag deposits in southwestern Nevada, USA. Ar and Ne are mainly atmospheric, whereas He has only a minor atmospheric component. Corrected 3 He/ 4 He ratios (with atmospheric He removed) range widely from 0.05 to 35.8 times the air 3 He/ 4 He ratio (R A ), with a median of 1.43 R A . Forty-one percent of measured 3 He/ 4 He ratios are ≥4 R A , corresponding to ≥50% mantle He assuming a mantle ratio of 8 R A . These results suggest that mafic magmas were part of the magmatic-hydrothermal system underlying Goldfield and Tonopah, and that associated mantle-sourced volatiles may have played a role in ore formation. The three highest corrected 3 He/ 4 He ratios of 17.0, 23.7, and 35.8 R A indicate a primitive mantle He source and are the highest yet reported for any epithermal-porphyry system and for the Cascades arc region. Compiled 3 He/ 4 He measurements from epithermal-porphyry systems in subduction-related magmatic arcs around the world (n = 209) display a statistically significant correlation between 3 He/ 4 He and Au-Ag grade. The correlation suggests that conditions which promote higher fluid inclusion 3 He/ 4 He ratios (abundance of mantle volatiles and focused upward volatile transport) have some relation to conditions that promote higher Au-Ag grades (focused flow of metal-bearing fluids and efficient chemical traps). Results of this and previous investigations of He isotopes in epithermal-porphyry systems are consistent with the hypothesis posed in recent studies that mafic magmas serve an important function in the formation of these deposits.

Cascades Arc↗

Biological water-quality assessment of selected streams in the Milwaukee Metropolitan Sewerage District Planning Area of Wisconsin, 2007

Changes in the water quality of stream ecosystems in an urban area may manifest in conspicuous ways, such as in murky or smelly streamwater, or in less conspicuous ways, such as fewer native or pollution-sensitive organisms. In 2004, and again in 2007, the U.S. Geological Survey sampled stream organisms—algae, invertebrates, and fish—in 14 Milwaukee area streams to assess water quality as part of the ongoing Milwaukee Metropolitan Sewerage District (MMSD) Corridor Study. In addition, passive-sampling devices (SPMDs, “semipermeable membrane devices”) were deployed at a subset of sites in order to evaluate the potential exposure of stream organisms to certain toxic chemicals. Results of the 2007 sampling effort are the focus of this report. Results of sampling from 2007 are compared with results from 2004. The water quality of sampled streams was assessed by evaluating biological-assemblage data, metrics computed from assemblage data, and an aggregate bioassessment ranking method that combined data for algae, invertebrates, and fish. These data contain information about the abundance (number) of different species in each group of stream organisms and the balance between species that can or cannot tolerate polluted or disturbed conditions. In 2007, the highest numbers of algal, invertebrate, and fish species were found at the Milwaukee River at Milwaukee, the largest sampled site. Algal results indicated water quality concerns at 10 of the 14 sampled sites due to the occurrence of nuisance algae or low percentages of pollution-sensitive algae. When compared to 2004, total algal biovolume was higher in 2007 at 12 of 14 sites, due mostly to more nuisance green algae from unknown causes. Results of several metrics, including the Hilsenhoff Biotic Index (HBI-10), suggest that invertebrate assemblages in the Little Menomonee River, Underwood Creek, and Honey Creek were poorer quality in 2007 compared to 2004. Six sites received “very poor” quality ratings for fish in 2007, mostly because inadequate numbers of fish were collected at five sites to allow computation of an Index of Biotic Integrity (IBI); this resulted in three additional sites receiving “very poor” ratings compared to 2004. Some signs of potential improvement in the fish assemblage were evident at Lincoln Creek, possibly reflecting delayed effects of the restoration of stream habitat, completed in 2002; however, algae and invertebrates did not show signs of improvement. Aggregate bioassessment rankings across all groups of organisms for 2004 and 2007 indicated that water quality at the two Milwaukee River main stem sites (at Milwaukee and near Cedarburg), Jewel Creek, and the Menomonee River at Menomonee Falls was the least-degraded among all sampled sites. Rankings for Oak Creek and Little Menomonee suggested water quality was worse in 2007 compared to 2004 and placed these two sites together with Kinnickinnic River and Underwood Creek, two concrete-line sites, indicating the most-degraded water quality among all sampled sites. The aggregate ranking for Lincoln Creek in 2007 would have placed it in the most-degraded category but for the positive influence of the fish ranking when compared to poor algal and invertebrate rankings. Potential toxicity due to certain manmade chemicals, such as polycyclic aromatic hydrocarbons (PAHs), was found at all six sites where SPMDs were deployed. As was found in 2004, the highest potential toxicity in 2007 was observed at Lincoln Creek where chemical screening in 2007 also showed the highest total PAHs of all six sites; however, potential toxicity at Little Menomonee River, Honey Creek, and Kinnickinnic River was relatively high compared to Milwaukee River near Cedarburg. Although toxicity and chemical results in 2007 did not agree with aggregate rankings for Lincoln Creek because of fish, nor for Honey Creek, the results did agree with aggregate rankings at four of the six sites. In addition to toxicological and chemical influences, the more urbanized sites have high percentages of impervious surface area, resulting in frequent high stream flows that can adversely affect algal, invertebrate, and fish assemblages. Assessments of the ecological status of different groups of organisms and of potential chemical and physical stressors to organisms are important tools in evaluating streamwater quality.

Wisconsin↗

Oceanographic controls on sedimentary and geochemical facies on the Peru outer shelf and upper slope

Concentrations and characteristics of organic matter in surface sediments deposited under an intense oxygen-minimum zone (OMZ) on the Peru margin were mapped and studied in samples from deck-deployed box cores and push cores acquired by submersible on two east-west transects spanning depths of 75 to 1,000 meters (m) at 12°S and 13.5°S. On the basis of sampling and analyses of the top 1–2 centimeters (cm) of available cores, three main belts of sediments were identified on each transect with increasing depth: (1) muds rich in organic carbon (OC); (2) authigenic phosphatic mineral crusts and pavements; and (3) glaucony facies. Sediments rich in OC on the 12°S transect were mainly located on the outer shelf and upper slope (150–350 m), but they occurred in much shallower water (approximately 100 m) on the 13.5°S transect. The organic matter is almost entirely marine as confirmed by Rock-Eval pyrolysis and isotopic composition of OC. Concentrations of OC are highest (up to 18 percent) in sediments within the OMZ where dissolved oxygen (DO) concentrations are <5 micromoles per kilogram (μM). Even at these low concentrations of DO, however, the surface sediments from within the OMZ are dominantly unlaminated. Concentrations of DO may have the dominant effect on organic matter characteristics, but reworking of fine-grained sediment and organic matter by strong bottom currents with velocities as high as 30 centimeters per second (cm/s) on the slope between 150 and 300 m and redeposition on the seafloor in areas of lower energy and higher DO concentration also exert important controls on OC concentration and degree of oxidation in this region. Phosphate-rich sediments and crusts occurred at depths of about 300 to 550 m on both transects. Nodular crusts of sediment cemented by carbonate-fluorapatite (CFA; phosphorite) or dolomite form within the OMZ. These phosphorite crusts evolve through cementation from light olive-green, stiff but friable, phosphatized claystone “protocrusts” through dense, dark phosphorite crusts, cemented breccias, and pavements. The degree of phosphatization and thickness of the crusts depend on the rates of sediment supply and on the strength and frequency of currents that re-expose crusts on the seafloor. Phosphorite crusts and pavements on the Peru margin can only become buried and incorporated into the geologic record once bottom currents slacken sufficiently to allow fine-grained sediment to accumulate. Glaucony-rich surface sediments, relatively undiluted by other components, were found mainly in deeper water on the 13.5°S transect (750 m to at least 1,067 m). These sediments consist almost entirely of sand-size glaucony pellets. These widespread glaucony sands formed in place and were then concentrated and reworked by strong currents that winnowed away the fine-grained matrix. Although the glaucony occurs in sand-size pellets, the pellets are made up of aggregates of authigenic, platy, micaceous clay minerals. Glaucony is predominantly a potassium (K), sodium (Na), iron (Fe), magnesium (Mg) aluminosilicate with an approximate formula of (K,Na)(Fe 3+ ,Al,Mg) 2 (Si,Al) 4 O 10 (OH) 2 . The glaucony on the 13.5°S transect forms by alteration of one or more original “framework” minerals (carbonate and [or] aluminosilicates) to form pellital aggregates of Fe-, K-, and Mg-rich clay minerals. Because Fe, K, and Mg are derived from seawater, sedimentation rates must be extremely slow in order for the original framework minerals to remain in contact with seawater. The close association of glaucony and phosphorite indicates a delicate balance between the slightly oxidizing conditions at the base of the OMZ that form glaucony and the slightly reducing conditions that mobilize iron and phosphate to form phosphorite.

Open-File Report↗

Palila Restoration: Lessons from Long-term Research

BACKGROUND The palila (Loxioides bailleui) is a member of the Hawaiian honeycreeper family of birds (Drepanidinae), which is renowned for the profusion of species - many with bizarre bills and specialized feeding habits - that radiated from a single ancestral type. Most of the 57 or so honeycreeper species are extinct, and the palila is endangered because of its high degree of dependence on the mamane tree (Sophora chrysophylla) (Figure 1) and its restricted distribution on the upper slopes of Mauna Kea (Figure 2). Three decades of research have revealed many important facts about palila, providing the foundation and impetus for conservation programs in the wild and captivity. Additionally, an ambitious public conservation campaign arose due to the land-use conflicts on Mauna Kea. Here we summarize progress in palila conservation biology and outline steps that might overcome the remaining major challenges to its recovery. We also highlight lessons learned from palila research that may help the recovery of other Hawaiian forest birds. Palila and two closely-related species on the tiny islands of Nihoa and Laysan are the last of the seed-eating honeycreeper species in the Hawaiian Islands. About a quarter of the honeycreeper species known from living and fossil specimens had finch-like bills suited mainly for eating seeds and fruits. Because of their dietary specialization, palila are vulnerable to changes in forest size and quality, as was also likely the case for extinct species of seed specialists. Palila and many other forest bird species were once distributed in dry, lowland forests. Fossil records indicate that palila also occurred in the lowlands of O`ahu and Kaua`i until human settlement of those islands. However, because lowland habitats have been highly modified by humans and because mamane occurs today primarily at high elevation, palila are the only native bird species found exclusively in dry, subalpine habitat (2000?2850 m). Similar to other feeding specialists, palila lay few eggs, raise few young each year, and take a relatively long time to complete the nesting cycle. Low rates of reproduction result in low rates of population growth and low potential for recovery from disturbances. Long-term studies of palila offer important insights into the conservation biology of all Hawaiian forest bird species, particularly feeding specialists like the palila. Palila face many challenges common to both generalist and specialist Hawaiian honeycreeper species. Habitat loss and degradation, as well as introduced avian diseases, have reduced their numbers and limited their distribution to a very small portion of their historic range. Introduced mammals prey on palila, while alien insects reduce caterpillars that are particularly important in the diet of nestlings. Securing legal protection and funding for palila restoration has been challenging. Understanding how the palila has avoided extinction can help managers plan its recovery, and better design recovery plans for species with different feeding strategies in other habitats.

Fact Sheet↗