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At least 1,009 records · Page 56Linked to original sources

Measurement and modeling of polychlorinated biphenyl bioaccumulation from sediment for the marine polychaete neanthes arenaceodentata and response to sorbent amendment

Bioaccumulation rates of polychlorinated biphenyls (PCBs) for the marine polychaete Neanthes arenaceodentata were characterized, including PCB uptake rates from water and sediment, and the effect of sorbent amendment to the sediment on PCB bioavailability, organism growth, and lipid content. Physiological parameters were incorporated into a biodynamic model to predict contaminant uptake. The results indicate rapid PCB uptake from contaminated sediment and significant organism growth dilution during time-series exposure studies. PCB uptake from the aqueous phase accounted for less than 3% of the total uptake for this deposit-feeder. Proportional increase of gut residence time and assimilation efficiency as a consequence of the organism's growth was assessed by PCB uptake and a reactor theory model of gut architecture. Pulse-chase feeding and multilabeled stable isotope tracing techniques proved high sediment ingestion rates (i.e., 6?10 times of dry body weight per day) indicating that such deposit-feeders are promising biological indicators for sediment risk assessment. Activated carbon amendment reduced PCB uptake by 95% in laboratory experiments with no observed adverse growth effects on the marine polychaete. Biodynamic modeling explained the observed PCB body burdens for N. arenaceodentata, with and without sorbent amendment.

Environmental Science & Technology↗

Measuring contemporary crustal motions; NASA’s Crustal Dynamics Project

In the early and middle 1970's, two new space-based geodetic techniques became available that offered unprecedented accuracy in the measurement of distances over long baselines. As described below, Satellite Laser Ranging (SLR) and Very Long Baseline Interferometry (VLBI) provided a capability to determine in relatively short periods of time the inter-site distance between two observing stations to a level of several centimeters, even if they were separated by thousands or tens of thousands of kilometers. During the 1980's the two techniques have evolved to the point where baselines can now be routinely measured to a level below one centimeter. This is a tenfold improvement in about ten years. Perhaps more important than providing the measurement capability are the consequences of this capability when applied over a few years: the motion of any one site with respect to another can be monitored at the level of better than a cm/yr. This has made possible, for the first time, direct measurement of the motion of the Earth's tectonic plates and of the deformation of its crust in active plate boundary regions. Because such measurements have the potential for providing important information on the mechanisms that drive plates and cause them to slip during earthquakes, a coordinated federal program for the application of this space technology to crustal dynamics and earthquake research was established in 1979. The participating agencies were the National Aeronautics and Space Administration (NASA), the National Oceanic and Atmospheric Administration (NOAA), the United States Geological Survey (USGS), the National Science Foundation (NSF), and the Defense Mapping Agency. NASA formed the Crustal Dynamics Project to further develop the SLR and VLBI techniques, to implement global networks of stations with the cooperation of many different countries, and to conduct measurements of plate motions and regional deformations. this project has grown into an international effort to collect information directly relevant to understanding the threat of the earthquake hazard as well as fundamental research about the crust and upper mantle. In this article we describe briefly the two space geodetic techniques and how they are used by the Crustal Dynamics Project, show some of the very exciting results that have emerged at the halfway point in the project's life, describe the availability and utilization of the data being collected, and consider what the future may hold when measurement accuracies eventually exceed even those now available and when other international groups become more heavily involved.

Earthquakes & Volcanoes (USGS)↗

Arsenic in benthic bivalves of San Francisco Bay and the Sacramento/San Joaquin River Delta

Arsenic concentrations were determined in fine-grained, oxidized, surface sediments and in two benthic bivalves, Corbicula sp. and Macoma balthica , within San Francisco Bay, the Sacramento/San Joaquin River Delta, and selected rivers not influenced by urban or industrial activity. Arsenic concentrations in all samples were characteristic of values reported for uncontaminated estuaries. Small temporal fluctuations and low arsenic concentrations in bivalves and sediments suggest that most inputs of arsenic are likely to be minor and arsenic contamination is not widespread in the Bay.

California↗

Nearshore survey and cleanup of benthic marine debris using citizen science divers along the Mediterranean coast of Israel

Information on marine debris along the Mediterranean coast of Israel, especially on the seafloor, is limited. Many recreational divers are enthusiasts of marine conservation and can thus contribute to data collection which does not require highly specialized training. The Society for the Protection of Nature in Israel together with The Israeli Diving Federation established the diver volunteer program “Sea Guard” (“Mishmar Hayam” in Hebrew), which supports marine conservation through citizen science. The divers were trained in marine ecology and survey methods to conduct independent surveys and lead underwater cleanups. For the first time, we have described the patterns of benthic debris density and composition in the nearshore environment of the southeastern part of the Mediterranean Sea. We found that benthic marine debris in the nearshore along the Israeli Mediterranean coast is primarily plastic, likely originating from the use of local beaches. Fishing, boating and domestic activities also play an important role as sources for marine debris. The currents' regime prevented the debris from accumulating on the seafloor in the nearshore environment, with the exception of several “debris traps”. Our findings will be useful for the development of programs to improve coastal waste management.

Ocean and Coastal Management↗

Lacustrine responses to decreasing wet mercury deposition rates: results from a case study in northern Minnesota

We present a case study comparing metrics of methylmercury (MeHg) contamination for four undeveloped lakes in Voyageurs National Park to wet atmospheric deposition of mercury (Hg), sulfate (SO 4 –2 ), and hydrogen ion (H + ) in northern Minnesota. Annual wet Hg, SO 4 –2 , and H + deposition rates at two nearby precipitation monitoring sites indicate considerable decreases from 1998 to 2012 (mean decreases of 32, 48, and 66%, respectively). Consistent with decreases in the atmospheric pollutants, epilimnetic aqueous methylmercury (MeHg aq ) and mercury in small yellow perch (Hg fish ) decreased in two of four lakes (mean decreases of 46.5% and 34.5%, respectively, between 2001 and 2012). Counter to decreases in the atmospheric pollutants, MeHg aq increased by 85% in a third lake, whereas Hg fish increased by 80%. The fourth lake had two disturbances in its watershed during the study period (forest fire; changes in shoreline inundation due to beaver activity); this lake lacked overall trends in MeHg aq and Hg fish . The diverging responses among the study lakes exemplify the complexity of ecosystem responses to decreased loads of atmospheric pollutants.

Minnesota↗

Report of the committee on underground‐water, 1933–34

The by‐laws adopted at the meeting of the Section of Hydrology in 1933 provided that the membership of research committees should be reconstituted every three years. There have, accordingly, been some changes in the membership of the Committee on Underground ‐ Water . Certain members have retired because of pressure of other duties or because they are no longer actively engaged in ground‐ water work. Dr. O. E. Meinzer, who retired as Chairman of the Section of Hydrology, has agreed to serve on the Committee , and probably two or three other men will be appointed to make contact with special phases of the field covered by the Committee . It is with regret that the Chairman reports the loss to the Committee by the death of A. F. Melcher, who had contributed much to the science of ground‐ water hydrology by his studies on permeability and absorption of sedimentary formations for water , oil, and gas. ©19 34

Eos, Transactions, American Geophysical Union↗

A regional spatio-temporal analysis of large magnitude snow avalanches using tree rings

Snow avalanches affect transportation corridors and settlements worldwide. In many mountainous regions, robust records of avalanche frequency and magnitude are sparse or non-existent. However, dendrochronological methods can be used to fill this gap and infer historical avalanche patterns. In this study, we developed a tree-ring-based avalanche chronology for large magnitude avalanche events (size ≥ ∼ D 3 "> ≥ ∼ D 3 ) using dendrochronological techniques for a portion of the US northern Rocky Mountains. We used a strategic sampling design to examine avalanche activity through time and across nested spatial scales (i.e., from individual paths, four distinct subregions, and the region). We analyzed 673 samples in total from 647 suitable trees collected from 12 avalanche paths from which 2134 growth disturbances were identified over the years 1636 to 2017 CE. Using existing indexing approaches, we developed a regional avalanche activity index to discriminate avalanche events from noise in the tree-ring record. Large magnitude avalanches, common across the region, occurred in 30 individual years and exhibited a median return interval of approximately 3 years (mean = 5.21 years). The median large magnitude avalanche return interval (3–8 years) and the total number of avalanche years (12–18) varies throughout the four subregions, suggesting the important influence of local terrain and weather factors. We tested subsampling routines for regional representation, finding that sampling 8 random paths out of a total of 12 avalanche paths in the region captures up to 83 % of the regional chronology, whereas four paths capture only 43 % to 73 %. The greatest value probability of detection for any given path in our dataset is 40 %, suggesting that sampling a single path would capture no more than 40 % of the regional avalanche activity. Results emphasize the importance of sample size, scale, and spatial extent when attempting to derive a regional large magnitude avalanche event chronology from tree-ring records.

Montana↗

Toward fisheries sustainability in North America: Issues, challenges, and strategies for action

Many fisheries in North America are severely depleted and trending downwards. In an effort to find ways of reversing this disturbing situation, the American Fisheries Society and the Sustainable Fisheries Foundation invited leading experts in fisheries science and aquatic resource management to share their thoughts and insights in this book. These experts were asked to identify the factors that are currently impairing our ability to effectively manage fisheries resources and propose creative solutions for addressing the most challenging issues affecting fisheries sustainability. Based on the information that was provided by the experts (i.e., as presented in the earlier chapters of this book), it is apparent that a wide range of human activities are adversely affecting our shared fisheries resources and the aquatic habitats upon which they depend. The most challenging problems stem from causes that are largely beyond the scope of traditional fisheries management (e.g., human population growth, resource consumption patterns, global climate change, broad land-use patterns). It is also apparent that resolution of these challenges will require a new approach to fisheries management - one that effectively integrates economic, social, and environmental interests into a decision-making framework that supports fisheries sustainability. The key strategies for supporting such a transition toward a more holistic and comprehensive approach to managing the human activities that influence fisheries and aquatic resources are summarized in this chapter. ?? 2004 by the American Fisheries Society.

American Fisheries Society Symposium↗

Landsat Science Team: 2016 winter meeting summary

The winter meeting of the joint U.S. Geological Survey (USGS)–NASA Landsat Science Team (LST) was held January 12-14, 2016, at Virginia Tech University in Blacksburg, VA. LST co-chairs Tom Loveland [USGS’s Earth Resources Observation and Science Data Center (EROS)—Senior Scientist] and Jim Irons [NASA’s Goddard Space Flight Center (GSFC)—Landsat 8 Project Scientist] welcomed more than 50 participants to the three-day meeting. The main objectives of this meeting focused on identifying priorities and approaches to improve the global moderate-resolution satellite record. Overall, the meeting was geared more towards soliciting team member recommendations on several rapidly evolving issues, than on providing updates on individual research activities. All the presentations given at the meeting are available at landsat.usgs. gov//science_LST_january2016.php.

The Earth Observer↗

Science summary in support of Manatee Protection Area (MPA) design in Puerto Rico

The Antillean manatee (Trichechus manatus manatus), a subspecies of the West Indian manatee, is listed as endangered by the US Department of Interior. In accordance with its listing, the U.S. Fish and Wildlife Service’s Caribbean Field Office (USFWS) is mandated to create one or more Manatee Protection Areas (MPAs) for Puerto Rico. Designation of these areas must comply with the legal definition of an MPA’s purpose: to prevent or reduce take of manatees (CFR 50: 44 FR 60964, Oct. 22, 1979). To meet this goal, we pursued two objectives: 1) identify areas which include the specific ecological attributes necessary to support manatee populations, and 2) identify areas where take can be reduced through approved MPA regulatory frameworks. We achieved these objectives through literature review, expert elicitation, and geospatial modeling. This report delivers to USFWS a set of nine potential MPA regions. These regions represent the spatial realization of experts’ hypotheses regarding manatee requirements and threats, and the potential to implement MPA strategies (e.g. watercraft access, speed regulations, signage and boater education). The nine regions are compared based on a number of factors, including their potential to reduce take, quality of the habitat encompassed, and total area. These maps and statistics serve as suitable starting points to select one or more MPA sites, but we recommend that the mapped attributes and threats (i.e., boating activity) of MPAs be ground-truthed to visually confirm the local presence of resources, threats, and manatees before any area is selected. Once established, the effectiveness of MPAs can be monitored and updated through processes of adaptive monitoring and management. Aerial surveys, radio tracking studies, and public surveys are all valuable tools to assess the success of an MPA. Establishing MPAs is a management action that, integrated within the species Recovery Plan, should enhance the conservation of manatees.

Cooperator Science Series↗

A look ahead to the next decade at US volcano observatories

Volcano monitoring, eruption response, and hazard assessment at volcanoes in the United States of America (US) fall under the mandate of five regional volcano observatories covering 161 active volcanoes. Working in a wide range of volcanic and geographic settings, US observatories must learn from and apply new knowledge and techniques to a great variety of scientific and hazard communication problems in volcanology. Over the past decade, experience during volcanic crises, such as the landmark 2018 eruption of Kīlauea, Hawaiʻi, has combined with investments and advances in research and technology, and the changing needs of partner agencies and the public, to transform the operations, science, and communication programs of US volcano observatories. Scientific and operational lessons from the past decade now guide new research and growing inter-observatory and external communication networks to meet new challenges and improve detection, forecasting, and response to volcanic eruptions in the US and around the world.

Bulletin of Volcanology↗

Stratigraphy, geochemistry and tectonic significance of the Oligocene magmatic rocks of western Oaxaca, southern Mexico

In Western Oaxaca, Tertiary magmatic activity is represented by extensive plutons along the continental margin and volcanic sequences in the inland region. K-Ar age determinations reported previously and in the present work indicate that these rocks correspond to a relatively broad arc in this region that was active mainly during the Oligocene (~ 35 to ~ 25 Ma). In the northern sector of western Oaxaca (Huajuapan-Monte Verde-Yanhuitlan), the volcanic suite comprises principally basaltic andesite to andesitic lavas, overlying minor silicic to intermediate volcaniclastic rocks (epiclastic deposits, ash fall tuffs, ignimbrites) that were deposited in the lacustrine-fluvial environment. The southern sector of the volcanic zone includes the Tlaxiaco-Laguna de Guadalupe region and consists of intermediate to silicic pyroclastic and epiclastic deposits, with silicic ash fall tuffs and ignimbrites. In both sectors, numerous andesitic to dacitic hypabyssal intrusions (stocks and dikes) were emplaced at different levels of the sequence. The granitoids of the coastal plutonic belt are generally more differentiated than the volcanic rocks that predominate in the northern sector and vary in composition from granite to granodiorite. The studied rocks show large-ion lithophile element (LILE) enrichment (K, Rb, Ba, Th) relative to high-field-strength (HFS) elements (Nb, Ti, Zr) that is characteristic of subduction-related magmatic rocks. On chondrite-normalized rare earth element diagrams, these samples display light rare earth element enrichment (LREE) and a flat pattern for the heavy rare earth elements (HREE). In spite of the contrasting degree of differentiation between the coastal plutons and inland volcanic rocks, there is a relatively small variation in the isotopic composition of these two suites. Initial 87Sr/86Sr ratios obtained and reported previously for Tertiary plutonic rocks of western Oaxaca range from 0.7042 to 0.7054 and ??Nd values, from -3.0 to +2.4, and for the volcanic rocks, from 0.7042 to 0.7046 and 0 +2.6. The range of these isotope ratios and those reported for the basement rocks in this region suggest a relatively low degree of old crustal involvement for most of the studied rocks. The Pb isotopic compositions of the Tertiary magmatic rocks also show a narrow range [(206Pb/204Pb) = 18.67-18.75; (207Pb/204Pb) = 15.59-15.62; (208Pb/204Pb) = 38.44-38.59], suggesting a similar source region for the volcanic and plutonic rocks. Trace elements and isotopic compositions suggest a mantle source in the subcontinental lithosphere that has been enriched by a subduction component. General tectonic features in this region indicate a more active rate of transtensional deformation for the inland volcanic region than along the coastal margin during the main events of Oligocene magmatism. The lower degree of differentiation of the inland volcanic sequences, particularly the upper unit of the northern sector, compared to the plutons of the coastal margin, suggests that the differentiation of the Tertiary magmas in southern Mexico was controlled to a great extent by the characteristics of the different strain domains. (C) 2000 Elsevier Science B.V. All rights reserved.

Conference Paper↗

USGS Tampa Bay Pilot Study

Many of the nation's estuaries have been environmentally stressed since the turn of the 20th century and will continue to be impacted in the future. Tampa Bay, one the Gulf of Mexico's largest estuaries, exemplifies the threats that our estuaries face (EPA Report 2001, Tampa Bay Estuary Program-Comprehensive Conservation and Management Plan (TBEP-CCMP)). More than 2 million people live in the Tampa Bay watershed, and the population constitutes to grow. Demand for freshwater resources, conversion of undeveloped areas to resident and industrial uses, increases in storm-water runoff, and increased air pollution from urban and industrial sources are some of the known human activities that impact Tampa Bay. Beginning on 2001, additional anthropogenic modifications began in Tampa Bat including construction of an underwater gas pipeline and a desalinization plant, expansion of existing ports, and increased freshwater withdrawal from three major tributaries to the bay. In January of 2001, the Tampa Bay Estuary Program (TBEP) and its partners identifies a critical need for participation from the U.S. Geological Survey (USGS) in providing multidisciplinary expertise and a regional-scale, integrated science approach to address complex scientific research issue and critical scientific information gaps that are necessary for continued restoration and preservation of Tampa Bay. Tampa Bay stakeholders identified several critical science gaps for which USGS expertise was needed (Yates et al. 2001). These critical science gaps fall under four topical categories (or system components): 1) water and sediment quality, 2) hydrodynamics, 3) geology and geomorphology, and 4) ecosystem structure and function. Scientists and resource managers participating in Tampa Bay studies recognize that it is no longer sufficient to simply examine each of these estuarine system components individually, Rather, the interrelation among system components must be understood to develop conceptual and predictive modeling tools for effective ecosystem adaptive management. As a multidisciplinary organization, the USGS possesses the capability of developing and coordinating an integrated science strategy for estuarine research founded on partnerships and collaborative efforts, multidisciplinary teams of scientists, and integrated field work, data analysis and interpretation, and product development. The primary role of the USGS in Tamps Bay research was defined with our partners based upon this capability to address estuarine issues using an integrated science approach with a regional perspective and within a national context to complement the numerous ongoing scien efforts by state and local agencies that address local issues within Tamp Bay. Six primary components of the USGS Tamp Bay Study address critical gaps within each of the the four estuarine system components and focus on: 1.) Examining how natural and man-made physical changes affect ecosystem health through mapping and modeling. 2.) Identifying sources and quality of groundwater, surface water, and sediment, 3.) Identifying sources and quality of groundwater, surface water, and sediment, 4.) Assessing the natural and man-made changes affecting wetland health and restoration, 5.) Identifying and measuring the impact of urbanization on seafloor habitats, Providing a web-based digital information management system of information for scientists and the public, including a system that supports the work of those officials who must make decisions that affect the state of the bay. The Tampa Bay Study is in its sixth year and will continue through September 2007. This paper presents a non-inclusive summary of key findings associated with the six primary project components listed above. Component 4 (above) is described in detail in the following chapter 13. More information on the Tampa Bay Study is available from our on-line digital information system for the Tampa Bay Study at http://gulfsci.usgs.gov.

Florida↗

North Cascades National Park Service Complex

Natural Resource Condition Assessments (NRCAs) evaluate current conditions for a subset of natural resources and resource indicators in national parks. NRCAs also report on trends in resource condition (when possible), identify critical data gaps, and characterize a general level of confidence for study findings. The resources and indicators emphasized in a given project depend on the park’s resource setting, status of resource stewardship planning and science in identifying high-priority indicators, and availability of data and expertise to assess current conditions for a variety of potential study resources and indicators. Although the primary objective of NRCAs is to report on current conditions relative to logical forms of reference conditions and values, NRCAs also report on trends, when appropriate (i.e., when the underlying data and methods support such reporting), as well as influences on resource conditions. These influences may include past activities or conditions that provide a helpful context for understanding current conditions and present-day threats and stressors that are best interpreted at park, watershed, or landscape scales (though NRCAs do not report on condition status for land areas and natural resources beyond park boundaries). Intensive cause-andeffect analyses of threats and stressors, and development of detailed treatment options, are outside the scope of NRCAs.

Washington↗

Mount Rainier National Park

Natural Resource Condition Assessments (NRCAs) evaluate current conditions for a subset of natural resources and resource indicators in national parks. NRCAs also report on trends in resource condition (when possible), identify critical data gaps, and characterize a general level of confidence for study findings. The resources and indicators emphasized in a given project depend on the park’s resource setting, status of resource stewardship planning and science in identifying high-priority indicators, and availability of data and expertise to assess current conditions for a variety of potential study resources and indicators. Although the primary objective of NRCAs is to report on current conditions relative to logical forms of reference conditions and values, NRCAs also report on trends, when appropriate (i.e., when the underlying data and methods support such reporting), as well as influences on resource conditions. These influences may include past activities or conditions that provide a helpful context for understanding current conditions and present-day threats and stressors that are best interpreted at park, watershed, or landscape scales (though NRCAs do not report on condition status for land areas and natural resources beyond park boundaries). Intensive cause-andeffect analyses of threats and stressors, and development of detailed treatment options, are outside the scope of NRCAs. It is also important to note that NRCAs do not address resources that lack sufficient data for assessment. For Mount Rainier National Park, this includes most invertebrate species and many other animal species that are subject to significant stressors from climate change and other anthropogenic sources such as air pollutants and recreational use. In addition, we did not include an analysis of the physical hydrology associated with streams (such as riverine landforms, erosion and aggradation which is significant in MORA streams), due to a loss of staff expertise from the USGS-BRD staff conducting the work, and human disturbance landcover issues such as the effects of roads, trails, and other anthropogenic developments due to lack of funds.

Report↗

Volcanoes in outer space and inner space

AS a teenager, I spent many long, bone-chilling hours studying the Moon and the planets with a rickety, homemade telescope. After 30 years, I still recall the pain and pleasure of creeping illicitly out of the house in the small hours of the morning for the few moments of satisfaction when the boiling, bouncing image of Jupiter would come to rest momentarily in sharp focus, the Galilean satellites strung out like brilliant beads on either side of the flattened disc. For me, then, the most remarkable piece of volcanology in the last twenty years was the discovery of active volcanism on Io, one of those tiny points of light I grew to know so well, though I was never really sure which satellite was which. To be sure, flying in a helicopter over the wasteland surrounding Mount St. Helens shortly after the 1980 eruption left an indelible, visceral impression on me, as it must have done to a great many others. But the discovery of volcanism on Io was a stunning piece of pure science.

Earthquakes & Volcanoes (USGS)↗

Spatial and temporal patterns of late Quaternary eolian deposition, eastern Colorado, USA

Eolian sediment covers about 60% of Colorado east of the Rocky Mountains; about 30% of the sediment is sand and 70% is loess. Initially, flood plains were the principal sources of eolian sediment, but during the Holocene, dunes formed from older eolian sand and alluvium on uplands. Since latest Pleistocene time, dominant dune-forming winds have been northwesterly in the northern part of the region and southwesterly in the southern part. At present, sand sheets and dunes, mainly parabolic types, are stable and covered with vegetation. In dunes, sand is commonly 20–30 m thick but elsewhere averages < 10 m. Three sand units are recognized on the basis of bedforms, topographic expression, and soil development. Preliminary age limits for the three units, based on 26 numerical ages, are 22.5–9 ka, 8−1 ka, and l.0−0. 15 ka. The middle unit is the product of multiple episodes of eolian activity that are not yet accurately dated. Loess is widespread but thin (generally < 2.4 m). Three units — middle Pleistocene, late Pleistocene. and Holocene — are recognized on the basis of differences in soil-profile development and stratigraphic position; late Pleistocene loess is by far the most common loess.

Colorado↗

Concentration, distribution, and translocation of mercury and methylmercury in mine-waste, sediment, soil, water, and fish collected near the Abbadia San Salvatore mercury mine, Monte Amiata district, Italy

The distribution and translocation of mercury (Hg) was studied in the Paglia River ecosystem, located downstream from the inactive Abbadia San Salvatore mine (ASSM). The ASSM is part of the Monte Amiata Hg district, Southern Tuscany, Italy, which was one of the world’s largest Hg districts. Concentrations of Hg and methyl-Hg were determined in mine-waste calcine (retorted ore), sediment, water, soil, and freshwater fish collected from the ASSM and the downstream Paglia River. Concentrations of Hg in calcine samples ranged from 25 to 1500 μg/g, all of which exceeded the industrial soil contamination level for Hg of 5 μg/g used in Italy. Stream and lake sediment samples collected downstream from the ASSM ranged in Hg concentration from 0.26 to 15 μg/g, of which more than 50% exceeded the probable effect concentration for Hg of 1.06 μg/g, the concentration above which harmful effects are likely to be observed in sediment-dwelling organisms. Stream and lake sediment methyl-Hg concentrations showed a significant correlation with TOC indicating considerable methylation and potential bioavailability of Hg. Stream water contained Hg as high as 1400 ng/L, but only one water sample exceeded the 1000 ng/L drinking water Hg standard used in Italy. Concentrations of Hg were elevated in freshwater fish muscle samples and ranged from 0.16 to 1.2 μg/g (wet weight), averaged 0.84 μg/g, and 96% of these exceeded the 0.3 μg/g (methyl-Hg, wet weight) USEPA fish muscle standard recommended to protect human health. Analysis of fish muscle for methyl-Hg confirmed that > 90% of the Hg in these fish is methyl-Hg. Such highly elevated Hg concentrations in fish indicated active methylation, significant bioavailability, and uptake of Hg by fish in the Paglia River ecosystem. Methyl-Hg is highly toxic and the high Hg concentrations in these fish represent a potential pathway of Hg to the human food chain.

Monte Amiata↗