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Patterns and drivers of cliff erosion in Big Sur, California, USA using repeat photogrammetry, 2017–2023

Seacliff erosion in steep terrain poses major risks to transportation and critical infrastructure. In Big Sur, California, USA, seacliff erosion threatens the sustainability of the central coast stretch of California State Route 1, a transportation corridor that is critical to the region's economy. Published cliff retreat rates for the region range from 1 to 40 cm yr −1 , highlighting that high-resolution, process-based studies could enhance understanding of the causes of spatial and temporal variability. We quantified cliff erosion and investigated its drivers along ∼13 km of the Big Sur coastline at week–month timescales during the late fall to early spring wet seasons between January 2017 and June 2023 by analyzing 3D point clouds developed from aerial imagery using four-dimensional structure-from-motion (4D SfM) photogrammetry techniques. We calculated cliff face retreat rates of 2.23 ± 3.06 cm yr −1 (mean ±1 σ ), an order of magnitude lower than long-term estimated rates for the region (which included large deep-seated landslides), but in line with short-term rates reported across California. Change detection imagery comparison, cliff profiles through time, and statistical analysis reveal a cyclical cliff evolution process in which erosion by wave action at the cliff base destabilizes the cliff and primes it for subsequent failure during precipitation events. Although more erosion by volume could be attributed to precipitation-induced increases in soil moisture (784 m 3 km −1 yr −1 ) compared with erosion attributed to wave power (282 m 3 km −1 yr −1 ), our observations underscore the coupled nature of these processes in driving cliff evolution, consistent with established theory and observations.

California

Assessment of extreme subsurface hydrologic conditions captured during atmospheric river storms in the San Francisco Bay area (California, USA) with applications to shallow landslide early warning

An increase in soil pore water pressure is the typical trigger for the majority of landslides caused by rainfall. Atmospheric river storms, common to the west coast of North America during the winter season, can deliver landslide triggering rainfall resulting in severe impacts to coastal communities. Using a network of hydrologic monitoring stations situated within landslide-prone terrain in the San Francisco Bay area of California (USA), we assess the meteorologic conditions and resulting hydrologic and landslide response resulting from eight consecutive storm events that caused thousands of shallow landslides during the winter of 2022–2023. We find disparate hydrological responses and resultant degrees of observed landsliding ranging from < 1 landslide/km2 to 18 landslides/km2 at the monitoring sites that reflect the interplay and differences between rainfall delivery, subsurface hydrological characteristics, and geotechnical properties at each site. Antecedent soil moisture from both early season rainfall and the first storm in the sequence played a critical role in setting up some hillslopes for failure. Subsequent storms then generated elevated pore water pressures for several hours with associated landsliding. However, we find that the occurrence of widespread landsliding required not only sufficient pore water pressure magnitude in susceptible hillslopes, but also full and prolonged effective soil saturation throughout hillslope profiles. Landslides may still occur at lower values and durations of effective saturation but are likely to be less extensive regionally. We present these findings within the context of research directions and improvements to landslide early warning systems first suggested by researchers 40 years ago.

California

Rebuilding a volcano one lava flow at a time—Visualizing the lava dome-building eruption in the crater of Mount St. Helens, 1982–1986

Between 1980 and 1986, the U.S. Geological Survey made a series of 1:2,000-scale topographic contour maps from aerial photographic surveys to monitor the eruption. These maps were made for operational purposes and were not intended for publication. Since then, advances in technology made it possible to digitize the original, highly detailed hardcopy maps and derive new digital data elevation models of the surface of the lava dome. These digital elevation models allow for the visualization of the progression of the eruption and reveal the rubbly, chaotic surface of the lava flows and dome. Additionally, these new data help fill gaps in the long-term record of topographic changes that have occurred at the volcano since the May 18, 1980, eruption.

Washington

Detailed investigation of a coastal plain-Piedmont fault contact in northeastern Virginia

A trench across the Dumfries fault of the Stafford fault zone near Stafford, Virginia (see Mixon and Newell, 1976) exposed a high-angle reverse fault juxtaposing Paleozoic Quantico Slate and Cretaceous Potomac Group rocks. A system of subsidiary reverse faults and small scale normal faults disrupt the Coastal Plain strata adjacent to the main fault. Cross-cutting relations and stratigraphic details indicate that the subsidiary faults in the Cretaceous rocks document a history of episodic deformation, in part active during accumulation of the Coastal Plain strata. Slickensides and stereo net analysis of theorientation of subsidiary reverse faults, normal faults, and bedding indicate that, through time, faulting consistently included right lateral separation.

Virginia

Foundational uncertainties in terminal Ediacaran chronostratigraphy revealed by high-precision zircon U-Pb geochronology of the Nama Group, Namibia

The Nama Group of southern Namibia and northwestern South Africa hosts the best-dated mixed carbonate-siliciclastic foreland basin succession of the terminal Ediacaran [ca. 551 million years (Ma) ago to <538 Ma] and is key for resolving the chronology of early metazoan evolution. Numerous silicified volcanic tuff interbeds are present, but differing interpretations regarding the fidelity of their ages lead to different regional stratigraphic correlations, especially for the Urusis Formation of the Schwarzrand Subgroup. An expanded record of the Urusis Formation is found in the Swartpunt area of southern Namibia, which has yielded an important metazoan biota. But the succession in this area is preserved as a series of thrusts at the leading edge of the Gariep orogenic belt and zircon U-Pb data show systematic age repetition. We use regional stratigraphic and structural mapping, integrated with carbonate carbon isotope (δ 13 C carb ) chemostratigraphy and high-precision radioisotope U-Pb zircon geochronology from outcrop and recently acquired drill core to develop a temporally calibrated basin-wide depositional model. This integrated dataset either reflects complex zircon reworking, inheritance, or potential analytical biases (Scenario 1) or the presence of a Gariep-related cryptic décollement within the Spitskop Member that has resulted in stratigraphic repetition (Scenario 2). We investigate the evidence for and against both scenarios and consider their implications for stratigraphic and δ 13 C carb correlations between the Swartpunt area and coeval exposures along the Orange River border with South Africa. Given that these issues are in an area that hosts numerous silicified ash beds and extensive exposure, an inability to confidently discount either scenario highlights a level of compounding uncertainty in zircon U-Pb geochronology that must be considered when attempting to build global chronostratigraphic frameworks. Scenario 1 implies that some of the weighted mean ages and Bayesian eruption ages from the Swartpunt area may be >1 Myr older than the depositional age of their respective ash beds when assuming existing stratigraphic correlations. If this scenario is preferred, then a cautious approach would be to consider all weighted mean zircon U-Pb ages from ash beds to reflect maximum depositional ages. Both scenarios support deposition of the Huns Member >540 Ma in the Swartpunt area if the oldest weighted mean age reported here represents a near-depositional age, which has significant implications for the temporal calibration of important terminal Ediacaran ichnofossil assemblages and future cyclostratigraphic studies. Stratigraphic correlations common to both scenarios allow us to temporally calibrate a basin evolution model for the Nama Group. Temporal trends in initial hafnium isotope (εHf) compositions of zircon grains from ash beds throughout the succession may support progressive crustal thickening associated with underplating of the Damara orogenic belt along the northern periphery of the Kalahari craton from ca. 547 Ma to ca. 538 Ma. The compilation of new and published zircon U-Pb ages may also imply that the locus of carbonate platform development migrated from north to south (present co-ordinates), tracking the migration of foredeep subsidence.

Earth-Science Reviews

Estimating habitat availability for Chinook salmon (Oncorhynchus tshawytscha) and steelhead (O. mykiss) to inform reintroduction planning in the middle Snake River basin, USA

Anadromous fishes have been blocked from the middle Snake River basin since the construction of flood control, irrigation, and hydroelectric projects during the 19 th and 20 th centuries, culminating with the construction of Hells Canyon Dam (river kilometer [rkm] 398) in 1967. Seven large watersheds in the blocked area of the basin are under consideration for Pacific salmon reintroduction. The primary objective of this study was to identify and characterize potential reintroduction sites with high-quality rearing and spawning habitat for Chinook salmon ( Oncorhynchus tshawytscha ) and steelhead ( O. mykiss ) upstream of the Hells Canyon Complex in Idaho, Oregon, and Nevada, USA. We created and tested habitat models to predict rearing presence/absence, rearing abundance, and spawning presence/absence using channel morphology, hydrology, and stream temperature variables obtained from regional peer-reviewed datasets. Habitat models were trained with salmonid presence and abundance records collected in the lower Snake River basin (downstream of Hells Canyon Dam), where anadromous fish can currently access, from 1993 to 2011. Model performance was tested with set-aside data comprised of randomly selected reaches and independent environmental DNA data. An index model was created in the middle Snake River basin for each species by combining results from the habitat models. Modeling covariates differed by species and life stage and included different combinations of August stream temperature, summer flow, channel slope, and quadratic terms for temperature and slope. The habitat models predicted high versus low Chinook salmon and steelhead probability and abundance with 66% to 85% accuracy depending on species and life stage. The index models predicted a total of 2,887 km of Chinook salmon habitat and 2,434 km of steelhead habitat in the blocked area. The three basins in the blocked area with the greatest amount of predicted habitat were the Powder River, South Fork Payette River, and North Fork Payette River for Chinook salmon, and the Powder River, South Fork Boise River, and South Fork Payette River for steelhead. The modeling approach presented here is complementary to other planning efforts for Chinook salmon and steelhead reintroduction in the blocked area of the Snake River basin, and similar approaches may be useful for reintroduction planning in other systems.

Idaho, Nevada, Oregon, Utah, Washington, Wyoming

Utilizing downhole datasets for modelling the aeromagnetic signature of the Iron Creek Co-Cu deposit in the Idaho Cobalt Belt

The Idaho Cobalt Belt in east-central Idaho is host to some of the largest domestic Co resources, including the informal Iron Creek deposit. The two main ore zones of this deposit, the Iron Creek and the Ruby, are hosted in greenschist-grade interbedded argillite/siltstone and quartz-rich units of the Mesoproterozoic Apple Creek Formation of Lemhi Group. The primary ore mineral is cobalt-bearing pyrite, which occurs with pyrrhotite, chalcopyrite, and magnetite. This study integrates mineralogical and core-scale geophysical measurements with regional-scale aeromagnetic surveys. The high magnetite content within the Ruby zone produces elevated magnetic susceptibility, but the relatively limited spatial footprint of the ore zone would produce a small-scale anomaly that may be overlooked in regional surveys. The low magnetite content in the Iron Creek zone results in low magnetic susceptibility, creating a relatively low amplitude geophysical response. By characterizing the magnetic properties and mineralogy of these ore zones, this study enhances the interpretation of aeromagnetic data, enabling the identification of small or faint anomalies as potential Co targets. These findings improve can improve exploration strategies, both within the Idaho Cobalt Belt as well as for similar deposit types globally.

Idaho

Quantitative mineral resource assessment of lithium pegmatite deposits in the southern Appalachian orogen

The first quantitative mineral resource assessment for undiscovered lithium pegmatite deposits in the southern Appalachian region of the United States was conducted. Permissive tracts for lithium pegmatite deposits were delineated by integrating lithological, tectonic, geochemical, geophysical and mineral occurrence data. Lithium pegmatite prospectivity of the tracts was ranked with simplified mappable criteria, including proximity to Paleozoic felsic intrusions and major lithotectonic structures, stream sediment geochemical anomalies, and pegmatite occurrence data. The geospatial data and permissive tracts were used to estimate the number of undiscovered lithium pegmatite deposits. These estimates were integrated into probabilistic simulations along with a new global lithium pegmatite grade and tonnage dataset to quantify potential contained undiscovered lithium resources. An economic filter was applied to convert the probabilistic estimates of contained lithium into recoverable material. The identified lithium pegmatite resources for the Carolina Lithium and Kings Mountain deposits, North Carolina, contain 1589 thousand tons (kt) of Li 2 O. The median contained undiscovered resource for the southern Appalachian orogen was estimated to be 2240 kt Li 2 O. At 90% confidence, the region contains at least 130 kt Li 2 O, and 10,700 kt at 10% confidence. After applying economic filters, the median recoverable contained resource was 1430 kt Li 2 O, corresponding to approximately 201 years of current lithium imports for consumption in the United States. North and South Carolina are likely to contain most of these resources. Coarse data resolution and intra-state variations in the geological data contribute to uncertainty of undiscovered lithium pegmatite resources. Continued efforts to harmonize disparate geospatial datasets with updated or new information can improve the accuracy and precision of estimated undiscovered lithium pegmatite resources in the study area and at broader scales.

Alabama, Georgia, Maryland, North Carolina, South

Sources and risk factors for nitrate, pathogens, and fecal contamination of private wells in rural southwestern Wisconsin, USA

Household well water can be degraded by contaminants from the land's surface, but private well owners lack means to protect the source water from neighboring disturbances. Rural residents of southwestern Wisconsin, USA, rely on private well water, and the combination of land use and fractured carbonate bedrock makes groundwater vulnerable to contamination. To identify the extent, sources, and risk factors of private well contamination, randomly selected wells sampled during two-day periods in fall (n = 301) and spring (n = 529) were analyzed for nitrate and indicator bacteria, and a subset (n = 138) was sampled across four seasonal events for analysis of pathogens and microbial source tracking markers by quantitative polymerase chain reaction. Risk factors representing land use, hydrology, geology, and well construction were analyzed for associations with contamination in multivariable models. The importance of risk factors varied by contaminant, illustrating the multifaceted nature of rural groundwater quality. Nitrate contamination was associated with agricultural land use, and wells with casings that extended below a shale aquitard accessed less contaminated water than those drawing water from above it. Human fecal microbes were detected in 64 wells (46%), and rainfall was the key risk factor for contamination, indicating that wastewater from septic systems was available to contaminate wells when transport conditions were favorable. Manure microbes from cattle/ruminants and pigs were detected in 33 and 13 wells, respectively, and concentrations increased with the hectarage of cultivated land near wells. Pathogen genes for viruses, bacteria, and protozoa were detected in 66 wells (48%), including more detections of zoonotic than human-specific pathogens, and human Bacteroides , an indicator of wastewater, was an equivocal predictor of pathogen presence in private wells. Characterizing important elements of the setting, like geology, and identifying sources and risk factors for contaminants can inform landscape-level policies to protect groundwater quality.

Wisconsin

Effects of stochastically-simulated near-fault ground motions on soil liquefaction

The scarcity of historically recorded near-fault ground motions poses a challenge to systematically understanding the influence of near-fault effects on various types of seismic demands for engineering purposes. In particular, the current state of knowledge of the influence of ground-shaking intensity on soil liquefaction and its consequences does not specifically account for the effects of near-fault ground motion characteristics. In this study, the influence of near-fault ground motions on liquefaction triggering and lateral spreading are investigated using non-linear modeling of a hypothetical liquefiable soil column in the finite-element computational platform OpenSees subjected to simulated ground motion time series that represent strong earthquake shaking in the near field. The simulated ground motion time series and resulting datasets are based on a parametric stochastic model and are developed for a range of source and path parameters to represent a realistic variability of ground motion characteristics. Dependencies between ground motion intensity measures (IMs) and liquefaction demand parameters are investigated for near-fault pulse and nonpulse-like ground motion sets. Evolutionary IMs, such as cumulative absolute velocity (CAV) and the time-varying magnitude-adjusted peak ground acceleration (PGAM), are considered in developing liquefaction triggering probability density functions. Post-liquefaction triggering responses such as lateral spreading displacements are examined in relation to PGA M and CAV. The ground motion simulations are validated by comparing their liquefaction-capacity PGA M fragilities and post-triggering CAV vulnerability relationships to historical records from the 1994 Northridge earthquake in California, USA. Finally, a path forward for future studies that includes finding systematic differences in the IM-liquefaction demand relationships between near-fault and far-field stochastic ground motion sets is outlined.

Conference Paper

Environmental setting and water-quality issues in the lower Tennessee River basin

The goals of the National Water-Quality Assessment Program are to describe current water-quality conditions for a large part of the Nation's water resources, identify water-quality changes over time, and identify the primary natural and human factors that affect water quality. The lower Tennessee River Basin is one of 59 river basins selected for study. The water-quality assessment of the lower Tennessee River Basin study unit began in 1997. The lower Tennessee River Basin study unit encompasses an area of about 19,500 square miles and extends from Chattanooga, Tennessee, to Paducah, Kentucky. The study unit had a population of about 1.5 million people in 1995. The study unit was subdivided into subunits with relatively homogeneous geology and physiography. Subdivision of the study unit creates a framework to assess the effects of natural and cultural settings on water quality. Nine subunits were delineated in the study unit; their boundaries generally coincide with level III and level IV ecoregion boundaries. The nine subunits are the Coastal Plain, Transition, Western Highland Rim, Outer Nashville Basin, Inner Nashville Basin, Eastern Highland Rim, Plateau Escarpment and Valleys, Cumberland Plateau, and Valley and Ridge.The lower Tennessee River Basin consists of predominantly forest (51 percent) and agricultural land (40 percent). Activities related to agricultural land use, therefore, are the primary cultural factors likely to have a widespread effect on surface- and ground-water quality in the study unit. Inputs of total nitrogen and phosphorus from agricultural activities in 1992 were about 161,000 and 37,900 tons, respectively. About 3.7 million pounds (active ingredient) of pesticides was applied to crops in the lower Tennessee River Basin in 1992. State water-quality agencies identified nutrient enrichment and pathogens as water-quality issues affecting both surface and ground water in the lower Tennessee River Basin. Water-quality data collected by State and Federal agencies between 1980 and 1996 were summarized to characterize surface- and ground-water quality of the subunits with respect to these issues. Median concentrations of nitrogen species generally were less than 1 milligram per liter in surface and ground water in all subunits, and were highest throughout the subunits that had the largest percentages of agricultural land use. Median phosphorus concentrations also were less than 1 milligram per liter in all subunits. Phosphatic limestones present in two subunits had a larger effect on phosphorus concentrations in surface and ground water than did the amount of agricultural land use in these subunits. Median counts of fecal coliform were higher in surface water than in ground water in all subunits. The highest median counts in surface water were in the Valley and Ridge (7,500 colonies per 100 milliliters) and the Outer Nashville Basin subunits (5,000 colonies per 100 milliliters). Highest median counts in ground water were in the Inner and Outer Nashville Basin subunit. Natural setting likely has an important effect with respect to fecal contamination of surface and ground water in the lower Tennessee River Basin.

Alabama, Georgia, Kentucky, Mississippi, Tennessee

Analysis of the potential effects of Uzbekistan’s mineral endowment on the critical mineral supply of tungsten

Tungsten appears on the 2018 and 2022 U.S. Geological Survey critical mineral lists in part because of a very high global production concentration in China, which produces almost 83 percent of the world’s mined tungsten. Using known parameters and values from other tungsten mining operations, we created hypothetical scenarios in which three tungsten deposits in Uzbekistan are considered for development. Our results show that all three deposits are likely to be economically viable to develop under 2024 market conditions. If the three studied tungsten deposits were put into production, Uzbekistan could become the third-leading tungsten-producing country in the world and increase world output of tungsten by 2.7 percent. Putting these tungsten deposits in Uzbekistan into production could slightly reduce the tungsten global market concentration, therefore reducing the supply disruption potential for tungsten.

Open-File Report

The feasibility of using lidar-derived digital elevation models for gravity data reduction

Gravity data require submeter elevation accuracy for data processing, and differential global navigation satellite system (dGNSS) equipment is commonly used to acquire three-dimensional positional data to achieve such accuracy. However, lidar (light detection and ranging) data are commonly used to develop digital elevation models (DEMs) of Earth’s surface. Therefore, using elevations from lidar-derived DEMs for gravity-data acquisition and reduction may improve field efficiency and reduce cost. This study examines the feasibility of using DEMs for gravity-data reduction by comparing dGNSS elevation data from 435 gravity stations in Michigan, Wyoming, and Colorado with their respective DEM elevations. The results show that the average difference between DEM and dGNSS elevations is 13 centimeters (cm) and that 93 percent of those differences are less than 50 cm, even in areas with steep terrain. Because an elevation discrepancy of 50 cm corresponds to an error of roughly 0.1 milligals (mGal) in the simple Bouguer gravity anomaly, the results suggest that lidar-derived DEMs are a viable source for acquiring the elevation data needed to process gravity data, thus improving both the cost and efficiency of data collection for regional surveys where an accuracy of less than 1.0 mGal is desired.

Open-File Report

Preliminary geology of the North Meadow Creek Area, Tobacco Root Mountains, southwest Montana: The North Meadow Creek Fault

This report documents a previously unmapped fault, informally referred to herein as the North Meadow Creek fault, on the east flank of the Tobacco Mountains of southwestern Montana. This fault has an apparently long and complex history, including Quaternary offset of an older alluvial terrace, offset of a debris flow of presumed Pleistocene age, offset of rhyolite lava flows of presumed Tertiary age from their presumed source several kilometers east, on the opposite side of the fault, and offset and possible rotation of blocks of Archean gneiss on northeast side of the fault. The western part of the fault is covered by glacial moraines of two apparent ages, both Pleistocene.

Montana

Complex carbonate ore mineralogy in the Mountain Pass carbonatite rare earth element deposit, USA

Economic concentrations of rare earth element (REE) minerals are uncommon in the Earth’s crust, with most occurring in carbonatites. Unlike most igneous rocks composed of silicate minerals, carbonatites are dominated by carbonate minerals, some of which can incorporate significant light REEs (LREEs; La, Ce, Pr, Nd). Technological applications of REEs are numerous and they have been identified as some of the most critical mineral commodities to the global economy. The Mountain Pass carbonatite stock in the Mojave Desert of California is the most economically significant REE deposit in the USA and contains a few to tens of percent (by volume) of the carbonate REE ore mineral bastnäsite. Despite the economic significance of the Mountain Pass deposit, studies of its ore mineralogy are limited. Here we present new carbonate ore mineralogy data for a compositionally diverse suite of carbonatitic rocks from the Mountain Pass stock and related dikes. Whole-rock geochemical data are integrated with mineral-scale textural and chemical data obtained by scanning electron microscopy (SEM), electron probe microanalysis (EPMA), and microRaman spectroscopy. Our results document a complex spectrum of REE-bearing carbonate minerals and intermediate mixed-layer structures. Mineral species include bastnäsite [REE(CO 3 )F], hydroxylbastnäsite [REE(CO 3 )OH], parisite [Ca(REE) 2 (CO 3 ) 3 F 2 ], synchysite [Ca(REE)(CO 3 ) 2 F], röntgenite [Ca 2 (Ce,La) 3 (CO 3 ) 5 F 3 ], and sahamalite [(Mg,Fe 2+ )(REE) 2 (CO 3 ) 4 ]. Carbonate ore mineralogy is heterogeneous within and between samples, including at the intracrystal scale. Complexly zoned crystals exhibit as many as five to six different compositional domains and syntaxial intergrowths, commonly with the more Ca-rich varieties (parisite, synchysite) forming crystal rims that surround relict bastnäsite cores. We attribute the phenocryst variability to changes in the chemistry and temperature of primary carbonatite magmas and evolved/exsolved fluids. Cross-cutting vein textures of calcite, celestine and various REE carbonate minerals, interstitial bastnäsite crystallization, breccia blocks lined by fine-grained bastnäsite, and the presence of hydroxylbastnäsite and partially hydroxylated bastnäsite point to the role of secondary hydrothermal processes in REE mineralization. Fluorcarbonate mineral compositions demonstrate that La and Ce are more structurally abundant in bastnäsite, whereas the more Ca-rich species (parisite, synchysite) contain a greater proportion of REE heavier than Pr (Nd, Sm, Eu, Gd) and Y. Atomic ratios of Pr/(Nd + Pr) are likewise variable, with the highest average value for bastnäsite (0.25) compared to parisite (0.22) and sychysite (0.21). This finding has geometallurgical implications, given that current mining operations are focused on recovery of Nd and Pr for high field strength permanent magnets and the Nd/Pr ratios are a critical factor in ore processing and magnet manufacture.

California

Physicochemical properties and bioreactivity of sub-10 µm geogenic particles: Comparison of volcanic ash and desert dust

Exposure to ambient particulate matter (PM) with an aerodynamic diameter of <10 μm (PM 10 ) is a well-established health hazard. There is increasing evidence that geogenic (Earth-derived) particles can induce adverse biological effects upon inhalation, though there is high variability in particle bioreactivity that is associated with particle source and physicochemical properties. In this study, we investigated physicochemical properties and biological reactivity of volcanic ash from the April 2021 eruption of La Soufrière volcano, St. Vincent, and two desert dust samples: a standardized test dust from Arizona and an aeolian Gobi Desert dust sampled in China. We determined particle size, morphology, mineralogy, surface texture and chemistry in sub-10 μm material to investigate associations between particle physicochemical properties and observed bioreactivity. We assessed cellular responses (cytotoxic and pro-inflammatory effects) to acute particle exposures (24 hr) in monocultures at the air-liquid interface using two types of cells of the human airways: BEAS-2B bronchial epithelial cells and A549 alveolar type II epithelial cells. In acellular assays, we also assessed particle oxidative potential and the presence of microorganisms. The results showed that volcanic ash and desert dust exhibit intrinsically different particle morphology, surface textures and chemistry, and variable mineralogical content. We found that Gobi Desert dust is more bioreactive than freshly erupted volcanic ash and Arizona test dust, which is possibly linked to the presence of microorganisms (bacteria) and/or nanoscale elongated silicate minerals (potentially clay such as illite or vermiculite) on particle surfaces.

GeoHealth

Grammar to graph—An approach for semantic transformation of annotations to triples

Data annotation is the process of labeling data to show the outcome that a related data model should predict. In this study, annotation data were transformed into semantic graph triples, mainly for use with the Resource Description Framework (RDF), a type of entity-relationship-attribute data model for graph databases. The transformation of annotation data to semantic graph triples provides complex linguistic meaning with data handling advantages such as reduced data storage needs, improved logical specification of relations between objects, and reusable classes and properties that support logic and inference. A grammar-based framework in graph form supports user questions and queries. The words defining approximately 334 topographic feature types compiled by the U.S. Geological Survey were tokenized as units of analysis and grouped by part of speech. Their dependency relations were identified for this study using natural language processing libraries. Dependency concepts are used as structured semantic relations among part-of-speech classes. Tokens, units equivalent to words, form instances of classes and were quantified within a tabular output format using PostgreSQL data storage software. Table data were logically aligned as triples following a mapping file and stored with an ontology file using Ontop virtual triplestore software. A grammar ontology schema for the data was synchronized to match queries whose results validated the graph’s structure. The text analysis produced 8 part-of-speech classes of content words for object representations and 4 classes of function words for operational applications. Dependency relations formed 27 ontology properties for topographic subgraph structures. Token occurrences shaped overall ontology salience and formed a lexicon of syntactic terms for subgraph objects and properties. The schema ontology of class and property population shapes formed the lexicon of English terms. SPARQL Protocol and RDF Query Language (SPARQL) was used with the lexicon to conform data to RDF guidelines. This study confirms the hypothesis that although linguistic logic varies from description logic, its approximation applies to ontology design. Property and query use case patterns extracted from the analysis support queries concerning complex topographic relations and patterns normally embedded within text definitions. The method used in this study could be applied to text forms in other domains, such as survey notes.

Scientific Investigations Report

Streamflow, base flow, and ground-water recharge in the Housatonic River basin, western Massachusetts and parts of eastern New York and northwestern Connecticut

Streamflows for selected flow durations from 1 to 99 percent and the August median streamflows were estimated for 11 long-term streamflow-gaging stations in and near the study area. Estimates of streamflow and associated standard errors were determined for selected flow durations from 50 to 99 percent and the August median streamflows for 21 low-flow partial-record stations and for selected flow durations from 1 to 99 percent and the August median streamflows for two partial-record stations and seven short-term discontinued streamflow-gaging stations. Median streamflows per square mile for the 10-, 50-, and 90-percent flow durations and the August median streamflows were 3.90, 1.01, 0.185, and 0.248 cubic feet per second per square mile. Streamflows per square mile at selected flow-duration discharges between 1 and 99 percent at the 41 stations were related to basin characteristics to explain differences in streamflow characteristics. Basin characteristics included basin elevations, extent of stratified-drift deposits, land use, aspect, and underlying bedrock geology types. Most streamflow differences were positively correlated to basin elevation differences, most likely because precipitation increases with elevation, and to stratified-drift deposits, which allow more precipitation to recharge the ground water and to discharge later than do till and bedrock deposits. Mean base flow was computed from continuous records of daily mean discharge at 11 long-term streamflow-gaging stations in and near the study area. Mean annual base flow ranged from 13.4 to 24.5 inches per year. Minimum annual base flow ranged from 45 to 72 percent of mean annual rates at the 11 long-term stations, and the ratio of base flow to streamflow (base-flow index) ranged from 0.55 to 0.80. Base-flow durations between 1 and 99 percent were calculated from streamflow records at the 11 long-term streamflow-gaging stations. Base flow accounted for 45.5 to 85.0 percent of total annual streamflow at the 1- and 99-percent flow durations. Ground-water-recharge rates were computed from continuous records of daily mean discharge at 11 long-term streamflow-gaging stations in and near the study area. Mean annual ground-water-recharge rates ranged from 17.5 to 22.4 inches per year at 10 of the 11 long-term stations. Mean annual ground-water-recharge rates ranged from 2 to 7 inches per year higher than base flow. Minimum annual ground-water-recharge rates ranged from 48 to 72 percent of mean annual ground-water-recharge rates. Mean annual potential ground-water recharge was estimated from monthly climatological data collected at six climatological stations in and near the study area. Mean potential ground-water recharge ranged from about 17.9 to 28.9 inches per year, with a median value of 22.6 inches per year. This median value compares well to that calculated by use of streamflow records at the 11 streamflow-gaging stations (20.0 inches per year). Streamflows per square mile for the 10-, 50-, and 90-percent flow durations at stations in and near the study area were similar to those computed for other unregulated long-term continuous streamflow-gaging stations in central and eastern Massachusetts. Base-flow and ground-water-recharge rates in the study area compared closely to results from other studies in southeastern Massachusetts and Rhode Island, which were based on the same computational methods.

Connecticut, Massachusetts, New York