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Using a temporary emigration model to estimate abundance of stream fishes from hybrid removal surveys with and without block nets

Monitoring programs are often faced with a decision to allocate resources into either robust spatiotemporal coverage to estimate a population index (e.g., not true abundance) or confirming closed sampling conditions (e.g., with block nets) for an unbiased population estimate at the cost of spatiotemporal coverage. However, making accurate and precise abundance estimates at robust spatiotemporal scales is possible when combining open and closed sampling designs with integrated modeling techniques. We used simulations and a case study of backpack electrofishing surveys in the Santa Ana River, California to test the efficacy of an integrated abundance model (temporary emigration model, TE) to estimate abundance of fishes using removal sampling methods with a hybrid sampling design (sampling with and without block nets during removal sampling). We found that the TE model performed well under most modeling scenarios (sample size, amount of closure violation, number of samples collected during closure), although at least a few samples with block nets were necessary for all parameters to be estimable. When applied to fish surveys in the Santa Ana River, we found that catch of the fishes fit to the TE model (Santa Ana Sucker, Arroyo Chub, Channel Catfish, Largemouth Bass, Yellow Bullhead) showed little evidence that the closure assumption was violated when block nets were not used. Additionally, we found that the abundance of non-native fishes negatively affected the abundance of the native Santa Ana Sucker, which was also found to adversely affect the native fish’s access to critical habitat consisting of gravel and cobble substrate. Our results indicate that the TE model presents a viable solution to common sampling problems that impact many monitoring programs, where precise and accurate population estimates can be made at large spatiotemporal scales even when most samples violate the closure assumption.

California

Multi-scale geophysical imaging of a hydrothermal system in Yellowstone National Park, USA

Little is known about the local plumbing systems that fuel Yellowstone’s famous hot springs, geysers and mud pots. A multi-method, multi-scale geophysical investigation was carried out in the Obsidian Pool Thermal Area (OPTA) to: (i) delineate the lateral extent of the hydrothermal area and associated surface features; (ii) estimate the dimensions of the upflow zone and identify its main controlling structures; (iii) assess fluids circulation pathways from depth to surface. Ground and airborne geophysical data were acquired to connect local and regional scales, from shallow to large depths. Maps of surface electrical resistivity show a strong correlation with hydrothermal features. At in-termediate depths, electrical resistivity permits delineating the upper limit of the upflow zone, while Poisson’s ratio highlights differences in subsurface fluid content. Combining these results with surface observations and topographic information, we speculate that differential mixing of hydrothermal and fresh water could explain the wide diversity of features observed at OPTA. Low electrical resistivity observed at large depths also suggest that a vast upflow zone, controlled by rhyolite flows and conjugate faults, underlies the OPTA. We speculate that hydrothermal fluids rise along fractures and reach the surface in topographic lows to form hydrothermal features. Our results show that synoptic, multi-scale geophysical measurements provide a roadmap for understanding where and how geologic heterogeneity, topography, fluid-gas separation, and the mixing of thermal and meteoric waters conspire to produce the wide variety of Yellowstone’s renowned hydrothermal features.

Wyoming

Bottom-up characterization of geologic methane emissions in the San Juan Basin in the southwestern USA

Methane is a potent greenhouse gas that plays an important role in atmospheric chemistry and global warming. The current global methane budget has large uncertainties, and a better understanding of the budget would help to guide strategies for reducing anthropogenic emissions to fight climate change. Natural geologic methane emissions are a particularly poorly constrained source, with top-down estimates from 14 C in ice cores suggesting much lower geologic emissions than bottom-up scaling of direct flux measurements. Our study aims to contribute to resolving this discrepancy through improved bottom-up characterization of geologic methane seepage in the San Juan Basin in southwestern Colorado and northwestern New Mexico, USA. We performed 983 new flux chamber measurements in this basin during summer 2022 and winter 2023 field campaigns. Our results, in combination with prior measurements, suggest that natural seepage in the San Juan Basin only occurs on or near the Fruitland coal outcrop. Specifically, our new measurements confirm previous measurements of seepage along the northwestern exposure of the Fruitland outcrop in Colorado (a known hydrodynamic overpressure region) and for the first time, identified seepage locations along the southernmost Fruitland outcrop exposure in New Mexico, in association with a coal cleat and a fault. Overall, seepage along the Fruitland coal outcrop is heterogeneously distributed, with both positive and negative (interpreted as microbial soil sink) methane fluxes. Features that are hypothesized to be predictive of seepage (e.g., faults) were not associated with positive methane fluxes in areas outside of the Fruitland outcrop. Our best estimate for total geologic methane seepage in the San Juan Basin from spatial interpolation and statistical upscaling is approximately 0.14 Tg CH 4 /yr, with a range from 0.029 to 0.48 Tg CH 4 /yr. This best-estimate value is lower than a previous bottom-up estimate from a gridded seepage inventory, but higher than a previous top-down estimate.

Colorado, New Mexico

Development of a hydrogeologic visualization model for western Sarpy County, Nebraska

Population in western Sarpy County, Nebraska, has steadily increased over the last several decades and has led to increased groundwater use for domestic purposes. To meet the increase in demand, the Papio-Missouri River Natural Resources District is seeking to use all available sources of groundwater in western Sarpy County. Additionally, elevated groundwater nitrate plus nitrite as nitrogen concentrations were detected, indicating the need to better understand the groundwater quality of the area. Although the general geology of the area is understood, the area does not have detailed information on the extent of the various aquifers, particularly the Dakota aquifer. To characterize these aquifers, the Papio-Missouri River Natural Resources District invested in airborne electromagnetic surveys of the area to better understand the subsurface geology. Although these surveys improved understanding of the groundwater systems in the area, the Papio-Missouri River Natural Resources District wanted to integrate the subsurface information with available water-quality and groundwater-level data. In response, the U.S. Geological Survey, in cooperation with the Papio-Missouri River Natural Resources District, the Nebraska Natural Resources Commission, and the Nebraska Department of Natural Resources, assembled geologic, hydrogeologic and nitrate plus nitrite as nitrogen information for the selected area into a three-dimensional visualization computer software package called GeoScene3D. The completed GeoScene3D project was assembled to provide a visualization of the groundwater systems and associated water-quality results in Sarpy County and to provide the Papio-Missouri River Natural Resources District managers with information that can be used to make more informed groundwater resource-planning decisions in the future. This report details the development of a three-dimensional model created within GeoScene3D to visualize the subsurface, particularly the Dakota Sandstone in western Sarpy County.

Nebraska

Evidence of nitrate attenuation in intertidal and subtidal groundwater in a subterranean estuary at a Cape Cod embayment, East Falmouth, Massachusetts, 2015–16

Nitrogen dynamics in intertidal and nearshore subtidal groundwater (subterranean estuary) adjacent to the Seacoast Shores peninsula, Falmouth, Massachusetts, were investigated during 2015–16 by the U.S. Geological Survey. The peninsula is a densely populated residential area with septic systems and cesspools that are substantial sources of nitrogen to groundwater. The study area is in the Eel River, an estuarine saltwater embayment connected to the ocean adjacent to the western shore of the peninsula, that was the subject of an earlier study by Colman and others (2018, https://doi.org/10.3133/sir20185095 ) on nitrogen transport and transformations in groundwater between onshore and offshore locations. The previous study documented the distribution of nitrate concentrations and nitrate attenuation reactions in fresh groundwater beneath the peninsula and the estuary. The current study extended those observations with more detailed sampling and analysis of shallow groundwater from wells near discharge sites beneath the estuary. The current field investigation included sampling of existing wells and installation and sampling of clusters of wells and temporary sampling points in the subterranean estuary, including (1) shallow transects 0.3 to 1.2 meters (m) deep extending from 1 to 13.5 m offshore and (2) deeper wells (from 1.83 to 4.88 m deep) extending from 4.3 to 14.3 m offshore. Measurements of hydraulic-head gradients 2–5 m below the sediment/water interface in the intertidal and nearshore subtidal zones indicated that groundwater flow generally was upwards (towards the estuary) under all tide conditions in October 2016. The magnitude of the gradient was greatest during low tide conditions, indicating that groundwater discharge likely decreased during high tides. Measurements of specific conductance in shallow groundwater in the subterranean estuary in three transects perpendicular to shore were consistent with the existence of saltwater flow cells (infiltration of overlying saline water, mixing with fresh groundwater, and discharge to the overlying saline water) in the intertidal and nearshore subtidal regions. The size of these flow cells was variable in space and time and dependent on the elevation of the tide (spring or neap). At this location in the Eel River subterranean estuary, and offshore to at least 13.5 m, offshore flow of fresh groundwater apparently prevented a deeper saltwater wedge from discharging to the surface. Nitrate concentrations in shallow groundwater (30 to 122 centimeters [cm] depth) were variable in space and time, ranging from not detectable to 600 micromoles per liter (μmol/L) (8.4 milligrams per liter as N), and were highest in June 2016 at depths from 61 to 122 cm below the sediment/water interface and from 4 to 9 m offshore. Nitrate generally was not detectable in saline shallow groundwater at 30-cm depth or at any depth from 30 to 122 cm from 10 to 13.5 m offshore. Dissolved oxygen concentrations were suboxic (less than 16 μmol/L) in 60 percent of the sampled subterranean groundwater beneath the intertidal and subtidal zones. In the remaining sites, the range of dissolved oxygen concentrations was from 18 to 272 μmol/L and the median concentration was 43 μmol/L. Evidence for microbial nitrate reduction (denitrification and possibly anammox) was provided by the distribution of the reaction product nitrogen gas (excess N 2 , or N 2MIC ), as determined from analysis of the dissolved nitrogen gas and argon gas (Ar) concentrations in groundwater samples. Excess nitrogen gas provided evidence for nitrate reduction in shallow groundwater below the subtidal and, to a lesser extent, intertidal zones adjacent to the Seacoast Shores peninsula. These zones, where evidence for nitrate reduction was detected, were in fresh and brackish groundwater near subtidal or intertidal saltwater cells where discharging fresh groundwater mixed with infiltrating saline water. Infiltrating seawater may have supplied organic carbon, one of several potential electron donors that are required for denitrification. Other potential electron donors, such as organic carbon, iron, manganese, hydrogen, methane, ammonium, elemental sulfur, or sulfide phases, may have been supplied by the estuarine sediments. Drainage from surface runoff near the shore also may have supplied organic carbon to fresh groundwater near the intertidal saltwater cell. The highest amounts of nitrate converted to excess nitrogen gas were estimated to be in the range of 230 to 430 μmol/L in nearly fresh groundwater near the subtidal saltwater cell at depths of 61 to 122 cm below the sediment/water interface and from 10 to 13.5 m offshore. Evidence of denitrification within 10 m of the shore was sparse (generally limited to less than 50 μmol/L of N 2 -N) despite the presence of high nitrate concentrations. The spatial distribution of estimated nitrate reduction in the intertidal and nearshore subtidal fresh and brackish groundwater may be related to local variability in the distribution of reactive electron donors in those zones. Variations in the amount of nitrate reduction to nitrogen gas were not clearly related to potential aqueous electron donors such as dissolved organic carbon, nor to potential reaction products such as alkalinity, but may have been controlled by combinations of aqueous and solid-phase reactants. The distribution of relatively shallow fresh groundwater containing nitrate could indicate potential nitrate discharge areas in the lower intertidal zone and uncertain locations farther offshore; however, the data did not extend all the way to the sediment/water interface or to the offshore freshwater limit. This study confirmed substantial loss of nitrate from some of the fresh and brackish groundwater in shallow subestuarine sediments prior to discharge but did not quantify how much nitrate eventually discharged to the estuary.

Massachusetts

Geomorphic map of the Umatilla River corridor, Oregon

This map portrays the distribution of landforms along the Umatilla River in northeastern Oregon and covers a corridor 127 kilometers long from the confluence of the Umatilla River with the Columbia River upstream to Meacham Creek. The map encompasses the valley bottom and extends about 1 kilometer up the adjoining hillslopes. Map data are intended to support water quality and fisheries enhancement efforts pursuant to the First Foods, a resource-management approach that focuses on traditionally gathered foods including water, fish, big game, roots, and berries and calls attention to the reciprocity between people and the foods upon which humans depend. The Umatilla River drains about 6,300 square kilometers on the northwest slope of the Blue Mountains in northeast Oregon. Most of the drainage basin is underlain by Miocene basalt flows of the Columbia River Basalt Group. Younger, weakly lithified, late Miocene and early Pliocene gravel deposits of local origin (for example, McKay Formation) are mapped in a few places. Upland surfaces are mantled with windborne silt (loess) correlative with deposits elsewhere known as the Palouse Formation. Surfaces below an elevation of about 340 meters were inundated repeatedly by large Pleistocene glacial outburst floods, most emanating from glacial Lake Missoula in western Montana. In backflooded areas such as the lower Umatilla River valley, Missoula floods deposited extensive slack-water silt. Areas mapped as open water, active channel and tie channel, flood basin, valley bottom, and modified land constitute the geomorphic floodplain: the area subject to occasional inundation by the Umatilla River. Deposits and landforms within the floodplain are inset into Missoula flood deposits and hence postdate the 20–15-kilo-annum Missoula floods. Some floodplain deposits are no more than a few centuries old, as indicated by substantial erosion and deposition during the Umatilla River flood of February 2020, the largest since systematic measurements began in October 1903. Deposits and landforms of the floodplain are transient features within the longer-term incision of the Umatilla River into mid-Miocene flood basalts and younger gravel of the McKay Formation.

Oregon

A great tsunami earthquake component of the 1957 Aleutian Islands earthquake

The great 1957 Aleutian Islands earthquake ruptured ∼1200 km of the plate boundary along the Aleutian subduction zone and produced a destructive tsunami across Hawaiʻi. Early seismic and tsunami analyses indicated that large megathrust fault slip was concentrated in the western Aleutian Islands, but tsunami waves generated by slip in the west cannot explain the large observed runup in Hawaiʻi far to the southeast. Recently mapped 1957 geologic deposits on eastern Aleutian Islands suggest occurrence of very large nearby slip. Jointly modeling tsunami runup along the eastern Aleutian and Hawaiian Islands together with tide gauge recordings across the Pacific resolves 12-26 m shallow slip along 600 km of the eastern Aleutian Islands in addition to modest, deeper western slip inferred from seismic records. The eastern near-trench slip results in an M W 8.3-8.6 tsunami earthquake component of the M W 8.6-8.8 rupture, comparable in size to the adjacent 1946 Aleutian tsunami earthquake to the east. The reexamination of the 1957 rupture confirms the tsunami hazards posed by the eastern Aleutian subduction zone to Hawaiʻi and lays the groundwork for investigation of large prehistoric earthquakes through modeling tsunami runup inferred from stratigraphic observations to constrain their rupture processes.

Alaska

Microclimate mediates the strength and direction of avian biotic interactions

Theory predicts that that the strength and direction of species interactions can shift from being competitive in benign environments toward being facilitative in stressful environments. However, the environmental context dependency of species interactions has rarely been tested in animal communities. We capitalized on a 15-year, landscape-scale dataset, collected annually in a relatively stable old-growth forest environment to test the long-held hypothesis that the strength and direction of species interactions might be mediated by climatic conditions. It is generally accepted that competitive and facilitative interactions drive the distributions of many species. Using multi-species dynamic occupancy models applied to long-term data, we tested whether annual settlement by bird species could affect either the persistence or settlement by other phylogenetically related species, and whether these interactions are mediated by microclimate. We found that species interactions were influenced by microclimate for some, but not all avian species pairs. Related species pairs more often showed settlement dynamics that were indicative of attraction rather than repulsion. In some cases, competitive interactions at warmer microclimates flipped to become facilitative in colder ones. However, the reverse was also true: facilitative interactions amplified for some species under warm conditions. Furthermore, species pairs that were closely related were more likely to exhibit competitive relationships along at least part of the microclimatic gradient. Our results highlight the importance of using long-term data to incorporate competitive and facilitative interactions into species distribution models and support the notion that the strength and direction of species interactions can be dependent on microclimatic environmental conditions.

Oregon

Repeated coseismic uplift of coastal lagoons above the Patton Bay Splay Fault System, Montague Island, Alaska, USA

Coseismic slip on the Patton Bay splay fault system during the 1964 M w 9.2 Great Alaska Earthquake contributed to local tsunami generation and vertically uplifted shorelines as much as 11 m on Montague Island in Prince William Sound (PWS). Sudden uplift of 3.7–4.3 m caused coastal lagoons along the island's northwestern coast to gradually drain. The resulting change in depositional environment from marine lagoon to freshwater muskeg created a sharp, laterally continuous stratigraphic contact between silt and overlying peat. Here, we characterize the geomorphology, sedimentology, and diatom ecology across the 1964 earthquake contact and three similar prehistoric contacts within the stratigraphy of the Hidden Lagoons locality. We find that the contacts signal instances of abrupt coastal uplift that, within error, overlap the timing of independently constrained megathrust earthquakes in PWS—1964 Common Era, 760–870 yr BP, 2500–2700 yr BP, and 4120–4500 yr BP. Changes in fossil diatom assemblages across the inferred prehistoric earthquake contacts reflect ecological shifts consistent with repeated draining of a lagoon system caused by >3 m of coseismic uplift. Our observations provide evidence for four instances of combined megathrust-splay fault ruptures that have occurred in the past ∼4,200 years in PWS. The possibility that 1964-style combined megathrust-splay fault ruptures may have repeated in the past warrants their consideration in future seismic and tsunami hazards assessments.

Alaska

Near-surface material and topography generate anomalous high-frequency ground motion amplification in Chugiak, Alaska

An ∼3 km long nodal array oriented approximately east–west was deployed in Chugiak, Alaska, by the U.S. Geological Survey during 2021. The array intersects with the permanent NetQuakes station NP.ARTY, where peak ground acceleration (PGA) value of 1.98 g was recorded during the 2018 M w 7.1 Anchorage, Alaska, earthquake, in sharp contrast to the PGA of ∼0.3 g at a site just 4 km to the west. Seismic data for M w 1.8–4.3 aftershocks from the M w 7.1 event recorded by the nodal array confirm the anomalously large ground motions obtained at NP.ARTY as well as similar amplifications at nodes within ∼1 km to the east. Here, we performed 0–10 Hz 3D finite‐difference simulations, including high‐resolution surface topography, to explore the cause of the unexpectedly large amplification. As expected, the simulations computed with a regional 3D tomography velocity model severely underpredict the 0–10 Hz acceleration records at almost all sites. Adding a near‐surface low‐velocity taper to 300 m depth amplifies the accelerations by up to a factor of 5 and enables a reasonable match between the nodal data and simulations at sites to the west of NP.ARTY. However, this model still underpredicts the spectral energy in the area covered by glacial sediments by up to an order of magnitude. The addition of a till layer using a depth‐dependent shear‐wave velocity ( ⁠⁠ V s ) profile along with a homogeneous, 8 m thick low‐velocity layer with V s = 250 m/s representing the kame terraces improves the fit to data to within a factor of 2 at nodes located on top of the glacial sediments. Our study shows that the anomalously large high‐frequency amplification recorded at and near NP.ARTY can be explained by a combination of topographic effects and near‐surface low‐velocity material with amplification effects on the high‐frequency ground motion by up to about 40% and an order of magnitude, respectively.

Alaska

California State Waters Map Series—Benthic habitat characterization in the region offshore Humboldt Bay, California

Coastal and Marine Ecological Classification Standard (CMECS) geoform, substrate, and biotic component geographic information system (GIS) products were developed for the California State Waters of northern California in the region offshore of Humboldt Bay. The study was motivated by interest in development of offshore wind-energy capacity and infrastructure in Federal waters offshore. This project, carried out by the U.S. Geological Survey (USGS), resulted in four data releases for individual map blocks that are part of the “California State Waters Map Series”: (1) Offshore of Arcata, (2) Offshore of Eureka, (3) Offshore of the Eel River, and (4) Offshore of Cape Mendocino. The study area consists of 436 square kilometers of multibeam echo sounder (MBES) data acquired by Fugro Pelagos, Inc., in 2007. Towed camera-sled video was acquired in 2009 and 2010 to supervise the classification of the MBES data into habitats, and single channel sparker data were collected to calculate sediment thickness above the transgressive unconformity. Using video observations of habitat as ground truth, derivatives of the MBES data were classified into 3 seafloor character types (hard-rugose, hard-flat, and soft-flat), 26 induration-slope-depth groups, and 15 geoforms. The study area substrate is predominantly soft-flat sediment (mud and fine sand) covering 73.6 percent of the area. Hard-flat substrate areas, predominantly coarse sediment in scour depressions, cover 5.4 percent of the study area. The hard-rugose substrate areas are primarily outcrops of layered sedimentary bedrock and constitute 20.9 percent of the study area. Fifteen geoforms were identified in the analysis. The predominant geoforms mirror the seafloor character results, shelf geoforms, rock outcrop geoforms, and scour depression geoforms. Rock and scour areas are restricted to the southern portion of the study area off Cape Mendocino where uplift has exposed bedrock. On the flat shelf area post-transgressive sediment varies in thickness from 1.7 meters (m) nearshore to 28.1 m offshore.

California

Insights into Mountain Pass carbonatite formation from in-situ sulfur isotopes and geochemistry of sulfate and sulfide minerals

The Mountain Pass carbonatite stock hosts a world-class rare earth element deposit and may be classified as a carbonate-sulfate igneous rock, as it contains on average > 50 volume percent carbonate minerals and 20 to 30 volume percent sulfate minerals. The sulfates range in composition from barite to celestine and locally occur with sparse sulfide minerals. We investigate the origin of sulfur enrichment and the occurrence of sulfur-bearing minerals in the Mountain Pass carbonatite with in-situ sulfur isotope and mineral chemistry. Barite cores with δ 34 S of 1 to 3‰ do not coexist with sulfides, whereas celestine rims with δ 34 S of > 3‰ are associated with sulfides with δ 34 S < -10‰. We propose a model in which sulfur-bearing sediments were subducted during episodes of plate convergence in the Mojave Province that preceded Mountain Pass magmatism. Metasomatism of the overlying mantle by melts derived from the subducted sediments generated an unusually carbon- and sulfur-rich source to yield carbonatite magmas. Sulfur from primary carbonatite magmas and ~ 1 to 7% sulfur from subducted sediment melts yielded a slightly enriched δ 34 S composition (relative to depleted mantle δ 34 S of -1‰) for early crystallizing barite. Celestine rims on magmatic barite cores formed at low, hydrothermal temperatures (< 350 °C) based on S isotope thermometry for equilibrium celestine-galena and celestine-pyrite pairs. The sparse sulfides in the carbonatite stock are not in equilibrium with the primary barite cores and therefore do not permit S isotope thermometry estimates of magmatic temperatures. The S/Se ratios of sulfide minerals (> 3,400) typically exceed primitive mantle values (S/Se of 3,340), also consistent with their derivation from hydrothermal fluids. Trace occurrences of sulfide and sulfate minerals in alkaline silicate stocks related to the carbonatite stock have similar δ 34 S compositions and yield similarly low formation temperatures, suggesting regionally extensive and chemically similar sulfur-bearing hydrothermal fluids that imparted lithologically diverse rocks with a consistent sulfur isotope fingerprint.

California, Nevada

Constraining the earthquake recording threshold of intraslab earthquakes with turbidites in southcentral Alaska’s lakes and fjords

Strong ground motion from intraslab earthquakes, which do not produce primary paleoseismic evidence, may initiate gravity-driven turbidity flows in subaqueous basins. The resulting deposits (turbidites) can provide a paleoseismic proxy if the conditions that initiate these flows are known. To better constrain the initiating conditions, we use two recent intraslab earthquakes in southcentral Alaska, the M w 7.1 30 November 2018 Anchorage earthquake and the M w 7.1 24 January 2016 Iniskin earthquake, as calibration events. Through a multilake investigation, we document the occurrence, or the absence, of earthquake-generated turbidity flows from these two events. Both earthquakes are recorded by centimeter-scale turbidites that can be differentiated from climatically generated deposits, as well as other seismic sources based on deposit thickness, sedimentological properties, and deposit age. We show that a Modified Mercalli Intensity (MMI) of ∼V–V1/2 is the minimum shaking intensity required to generate localized sediment remobilization from deltaic slopes, and an MMI of ∼V1/2 is required to produce a deposit of sufficient thickness that a seismic origin can be confidently assigned. The documentation of seismically generated deposits in quick succession (∼2 years) with diagnostic features highlights the utility of using recent earthquakes as calibration events to investigate the subaqueous response to strong ground motion.

Alaska

The advantages of electric-grade heat storage in long closed-loop wells

Though long (e.g., tens of kilometers) closed-loop geothermal wells are under consideration for the extraction of subsurface heat, these wells might also serve as an efficient energy storage mechanism for electricity generation. Using a semi-analytic model solution, the potential for electric-grade heat storage as a function of ambient temperature (e.g., corresponds to depth of loop), well length, well diameter, and flow rate is evaluated. The following simplified cases for comparison of standard closed loop operation with energy storage operation were considered: [1] constant flow rate and constant temperature (90 °C) injection to represent the standard closed-loop base-case; and [2] constant flow rate and annual cycle sinusoidal temperature (90-150 °C) to represent seasonal (summer) charging while solar resources are peak. Initial temperatures for all scenarios considered herein are a uniform 175 °C. Electric-grade heat is assumed to be delivered whenever temperatures at the extraction point exceed 90 °C. For calculation purposes only, if temperature falls below 100 °C, it is assumed that heat delivered is sub-economic, so no electricity would be produced. For all scenarios, temperatures at the extraction well asymptotically approach the flow-weighted average injection temperature, but energy storage scenarios exhibited a damped time-varying signal that diminishes in magnitude with length of the loop. The asymptotic approach depends on initial temperatures in the rock and the heat extraction rate (a function of well diameter and flowrate). This analysis demonstrates that shorter closed loops can produce more electricity over time than longer closed-loops previously proposed for electricity production over typical engineering design lifetimes (e.g., 30 years). Although only a high-temperature scenario is considered herein, rock that is initially below boiling temperature would not host a standard closed-loop resource, but injection of hot water seasonally would asymptotically heat this low-temperature system to temperatures capable of electricity production. In other words, regardless of initial temperatures, closed loops could be used to store electricity with no critical minerals in the geothermal battery.

Conference Paper

Apatite and monazite geochemistry record magmatic and metasomatic processes in rare earth element mineralization at Mountain Pass, California

The largest rare earth element (REE) deposit in the United States is a carbonatite intrusion at Mountain Pass in the Mojave Desert, California. Despite a clear spatiotemporal association of alkaline silicate and carbonatite intrusions at Mountain Pass, a genetic model of their mutual formation has not been resolved. The Mountain Pass carbonatite has long been upheld as an example of a primary magmatic body, but recent work has suggested it could be fluid-derived. This study investigates the geochemistry of apatite and monazite grains from the alkaline silicate and carbonatite stocks and dikes of the Mountain Pass district, to elucidate the magmatic history of the intrusive suite and identify the role of fluids in rare earth element mineralization. Three apatite populations are identified in the alkaline silicate rocks. A primary magmatic apatite group supports intrusion of the stocks as separate pulses of magma derived from a spatially extensive metasomatized mantle source region. The second group implicates the role of a regional fluid that mobilized light rare earth elements from apatite grains. A minor group of inherited apatite cores, identified by low Sr and negative Eu anomalies, supports assimilation of crustal material in the formation of the intrusive suite. Analyses of monazite and apatite grains from the carbonatite orebody also reveal a mix of primary magmatic and metasomatic (fluid-related) minerals. Compositional similarities between primary phosphates in the carbonatite and alkaline silicate rocks support a genetic link between the intrusive suites. The presence of fluids regionally and within the carbonatite orebody indicates the Mountain Pass carbonatite should not be classified as a purely magmatic REE deposit.

Arizona, California, Nevada

Ground deformation and gravity for volcano monitoring

Introduction When magma accumulates or migrates, it can cause pressurization and related ground deformation. Characterization of surface deformation provides important constraints on the potential for future volcanic activity, especially in combination with seismic activity, gas emissions, and other indicators. A wide variety of techniques and instrument types have been applied to the study of ground deformation at volcanoes (sidebar, p. 2; Dzurisin, 2000, 2003, 2007). Geodetic instruments include continuously recording Global Navigation Satellite System (GNSS; of which the United States’ Global Positioning System is one example) stations (fig. D1), borehole tiltmeters, and interferometric synthetic aperture radar (InSAR) measurements (from satellites, occupied and unoccupied aircraft systems, and ground-based sensors). Additional geodetic measurements like continuous- and survey-mode gravity (fig. D2) can contribute substantially to interpreting these data. Borehole strainmeters (see chapter K , this volume, by Hurwitz and Lowenstern, 2024) also have outstanding utility for monitoring deformation, although because of cost and permitting challenges, we do not include them as part of standard volcano monitoring networks for U.S. volcanoes. Still other techniques like light detection and ranging (lidar), structure from motion, and optical satellite data can be used to derive gross topographic changes, which can be used to map volcanic deposits, infer eruption rates, and gain insights into the source processes associated with eruptive activity (see chapter G , this volume, on tracking surface changes caused by volcanic activity; Orr and others, 2024). Experience has shown that no single geodetic monitoring technique is adequate to detect and track the entire range of ground-motion patterns that occur at volcanoes, primarily because of the temporal and spatial diversity of volcano deformation (fig. D3). Similarly, the magnitude of surface deformation varies widely. Geodetic monitoring strategies should therefore include multiple techniques and instrument types to cover a wide range of spatial and temporal scales. In identifying recommendations for geodetic instrumentation for volcano monitoring networks, we attempted to maximize the diversity of instrument types to measure the full range of deformation signals and minimize their expense and number; thus, we do not include several well-known deformation-monitoring techniques in our recommendations. Extensometers, for example, measure strains over distances of a few meters and have an excellent record of success in detecting changes in preeruptive localized ground motion across existing cracks, including at Mount St. Helens, Washington (Iwatsubo and others, 1992), and Piton de la Fournaise, Réunion Island (Peltier and others, 2006). Despite being relatively inexpensive, extensometers are best used primarily when localized ground displacements (for example, ground cracks) need to be tracked, and are not necessary at all volcanoes. In considering volcano deformation monitoring strategies, two complicating factors are deserving of special attention. First, not all deformation is driven by subsurface magmatic activity—for example, at many large stratovolcanoes (for example, Mount Rainier), flank collapses and landslides are significant geologic hazards (Reid and others, 2001) that may occur even in the absence of magmatic activity. Monitoring the stability of volcanoes is thus another critical application of geodetic monitoring networks to inform hazard assessment. One of the most famous examples of edifice instability is the large flank collapse that initiated the May 18, 1980, eruption of Mount St. Helens. Deformation monitoring had detected a bulge on the north flank of the mountain in April 1980 that was expanding by several meters per day (Lipman and others, 1981). Given that flank collapses can happen at any time during a period of volcanic unrest (or even outside a period of unrest), the capability to assess edifice stability is critical. Second, although volcanoes are commonly treated as idealized structures that erupt from single points, like centralvent stratovolcanoes, many are characterized by long rift zones from which eruptions may originate, and distributed volcanic fields are characterized by broadly spaced vents. For example, linear dikes are common at Kīlauea, Mauna Loa, and between Mount Shasta and Medicine Lake in California. At Kīlauea, one of these linear dikes emerged more than 40 kilometers (km) away from the summit of the volcano during the lower East Rift Zone eruption in 2018. Other volcanic fields, like Lassen volcanic center, California, or the San Francisco Volcanic Field, Arizona, have many small vents spread over a wide area. Although the instrumentation guidelines presented in this chapter remain phrased for central-vent volcanoes, they should be modified as needed in the context of the eruptive characteristics of each individual volcanic system. Spatial analysis of geodetic network coverage could help to ensure adequate instrumentation in areas where volcanism can occur over a broad area as opposed to a central vent. As an example, consider the adjacent volcanoes Mount Shasta and Medicine Lake. If station locations are chosen based only on the distance from the centers of the volcanoes, then any geodetic anomalies between the two volcanoes—an area of potential volcanism as indicated by the presence of volcanic features—may remain undetected by ground-based instrumentation. The spatial analysis is accomplished via a grid of pressure point sources (Mogi, 1958) evenly distributed across the map area, at a depth of 5 km in this example (fig. D4). Each source is inflated until predicted deformations exceed the GNSS white noise uncertainty estimates at one site (Langbein, 2017; Murray and Svarc, 2017). This volume of detectable magma provides a measure of the quality of the coverage (fig. D4). The results indicate that, as of 2022, there is a large area between Mount Shasta and Medicine Lake volcano with existing mapped dikes in which a substantial amount of magma could intrude without being detected geodetically. Applying this style of analysis to individual volcanic systems can provide a guide for designing network geometry given the expected locations of future eruptions.

Scientific Investigations Report

In-situ geochronology using LA-ICP-MS/MS: Application of the Lu-Hf system in carbonate, apatite and fluorite

Geochronology is a fundamental tool for reconstructing earth history and constraining the timing of ore deposit formation. Traditionally, U-rich minerals like zircon, titanite, monazite and apatite have been analysed to determine the timing of mineralization and alteration events. However, not all deposits or alteration assemblages contain these minerals, and the U-Pb system can be disturbed due to open system behaviour. We present a methodology for obtaining in-situ Lu-Hf dates from various minerals to demonstrate the potential for dating ore deposits that lack U-rich minerals. Carbonate, apatite and fluorite minerals from different tectonic settings and geological environments were analysed. We acquired Lu-Hf and REE (rare earth element) data from carbonate minerals from a carbonatite orebody and dike samples from the Mountain Pass REE carbonatite deposit in California, USA. We also tested a ‘double-dating’ method, where U-Th-Pb dates and Lu-Hf dates were obtained from the same analysis of apatite from rocks in the Michigan’s Great Lakes Tectonic Zone. Preliminary results for Lu-Hf dating of fluorite from carbonatite rocks in the Lemitar Mountains of New Mexico are also included. The analytical methodology shows promising results in each of these cases where there is sufficient parent Lu and U and measurable daughter Hf and Pb respectively.

Conference Paper

Upper crustal seismic velocity structure of the Hayward fault zone, San Francisco Bay, California, USA: Results from the 2016 East Bay Seismic Experiment (EBSI-16)

We developed Vp, Vs, Vp / Vs ratio, and Poisson’s ratio models of the uppermost crust (<4 km depth) from the eastern San Francisco (SF) Bay (California, USA) to near the Calaveras fault along a 15-km-long, linear profile. Upper crustal velocities are highly variable beneath, west, and well east of the Hayward fault. We observe eight notable features, from west to east: (1) Near San Francisco Bay, there is an ~2-km-wide structure with high Vp / Vs ratios (up to 5) and Poisson’s ratios (up to 0.48) extending from the surface to the base of our model, which we suggest the structure is a near-vertical fault that lies along a straight-line projection between the Silver Creek fault to the south and the Point Richmond fault to the north. The structure may be part of an ~90-km-long fault along the eastern SF Bay. (2) The western East Bay Plain, the lower lying area between the bay and the hills, includes up to 800 m of low-velocity sediments ( Vp ~1600–3000 m/s, Vs ~500 m/s to ~1000 m/s), underlain by higher velocity basement rocks ( Vp ~3000–5800 m/s; Vs ~1000–1500 m/s). (3) Between ~1 km and 3 km east of the Bay shoreline, sediments thin in a series of steps (likely faults) toward the Hayward fault. (4) Between ~3 km west and ~1 km east of the Hayward fault (at the East Chabot fault) at depths greater than 1 km, basement Vp (up to 6000 m/s) and Vs (up to 2800 m/s) are high, and Vp / Vs ratios (<2) and Poisson’s ratios (<0.3) are low, suggesting crystalline rocks. Furthermore, a near-vertical zone of low Vp / Vs ratios and Poisson’s ratios is between near-surface traces of the Hayward and East Chabot faults, likely corresponding to the San Leandro Gabbro of Ponce et al. (2003) . (5) Eastward of the East Chabot fault in the upper 1.5 km, basement Vp (~3000 m/s to ~4200 m/s) and Vs (~1200–2000 m/s) are lower than those west of the fault. (6) In the eastern Hayward/Oakland Hills, there are zones of laterally varying, high- and low-velocity ( Vp ~2500–3000 m/s) Jurassic–Cretaceous and Tertiary sediments in the shallow subsurface that likely extend much deeper than imaged. (7) Seismic energy that propagates westward from sources east of the Hayward fault (HF) appear weaker than energy that propagates eastward from sources west of the HF, suggesting that the HF acts as a partial barrier to shallow seismic energy propagation into the more populated eastern SF Bay area. (8) Unlike many fault zones, it appears that the active trace of the Hayward fault (in our study area) is not cored by a prominent, low-velocity zone relative to rocks to the east and west of the active trace. However, the active trace does mark a prominent change from relatively higher velocities to the west and lower velocities to the east.

California