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Future of coral bleaching research

Coral bleaching is the largest global threat to coral reef ecosystem persistence this century. Advancing our understanding of coral bleaching and developing solutions to protect corals and the reefs they support are critical. In the present article, we, the US National Science Foundation–funded Coral Bleaching Research Coordination Network, outline future directions for coral bleaching research. Specifically, we address the need for embedded inclusiveness, codevelopment, and capacity building as a foundation for excellence in coral bleaching research and the critical role of coral-bleaching science in shaping policy. We outline a path for research innovation and technology and propose the formation of an international coral bleaching consortium that, in coordination with existing multinational organizations, could be a hub for planning, coordinating, and integrating global-scale coral bleaching research, innovation, and mitigation strategies. This proposed strategy for future coral bleaching research could facilitate a step-function change in how we address the coral bleaching crisis.

BioScience↗

Watershed ‘chemical cocktails’: forming novel elemental combinations in Anthropocene fresh waters

In the Anthropocene, watershed chemical transport is increasingly dominated by novel combinations of elements, which are hydrologically linked together as ‘chemical cocktails.’ Chemical cocktails are novel because human activities greatly enhance elemental concentrations and their probability for biogeochemical interactions and shared transport along hydrologic flowpaths. A new chemical cocktail approach advances our ability to: trace contaminant mixtures in watersheds, develop chemical proxies with high-resolution sensor data, and manage multiple water quality problems. We explore the following questions: (1) Can we classify elemental transport in watersheds as chemical cocktails using a new approach? (2) What is the role of climate and land use in enhancing the formation and transport of chemical cocktails in watersheds? To address these questions, we first analyze trends in concentrations of carbon, nutrients, metals, and salts in fresh waters over 100 years. Next, we explore how climate and land use enhance the probability of formation of chemical cocktails of carbon, nutrients, metals, and salts. Ultimately, we classify transport of chemical cocktails based on solubility, mobility, reactivity, and dominant phases: (1) sieved chemical cocktails (e.g., particulate forms of nutrients, metals and organic matter); (2) filtered chemical cocktails (e.g., dissolved organic matter and associated metal complexes); (3) chromatographic chemical cocktails (e.g., ions eluted from soil exchange sites); and (4) reactive chemical cocktails (e.g., limiting nutrients and redox sensitive elements). Typically, contaminants are regulated and managed one element at a time, even though combinations of elements interact to influence many water quality problems such as toxicity to life, eutrophication, infrastructure corrosion, and water treatment. A chemical cocktail approach significantly expands evaluations of water quality signatures and impacts beyond single elements to mixtures. High-frequency sensor data (pH, specific conductance, turbidity, etc.) can serve as proxies for chemical cocktails and improve real-time analyses of water quality violations, identify regulatory needs, and track water quality recovery following storms and extreme climate events. Ultimately, a watershed chemical cocktail approach is necessary for effectively co-managing groups of contaminants and provides a more holistic approach for studying, monitoring, and managing water quality in the Anthropocene.

Biogeochemistry↗

Late Holocene human-environment interactions on the central California coast, USA, inferred from Morro Bay salt marsh sediments

Coastal salt marshes and estuaries provide valuable ecosystem services, yet are susceptible to alteration from human activities. Records of past environmental change in these ecosystems can elucidate relationships between human activities, such as land-use practices, and physical and ecological processes, such as sediment accretion and vegetation changes. To reconstruct the environmental history of one such site, we present inferences based on analysis of sediment cores (including magnetic susceptibility, loss-on-ignition, and pollen) from the Morro Bay salt marsh, located in California’s central coast in the USA. Chronologic control for the sediments was established using radiocarbon dates, a spike in lead (Pb) sourced from gasoline combustion exhaust, and the first identified occurrences of the non-native taxa Erodium cf. cicutarium (filaree) and Eucalyptus . We demonstrate that the Morro Bay watershed was significantly altered following Spanish settlement in the region. Environmental changes associated with livestock grazing and agriculture become evident in the data starting after 1772 CE, when the Mission San Luis Obispo de Tolosa was established nearby. The most prominent changes observed are an increase in the accumulation rate of terrigenous sediment, organic matter, and carbonates, as well as a reduction in arboreal taxa concomitant with increased abundances of shrubs, herbs, and grasses. The expansion of Salicornia (pickleweed) in the 19th century suggests the salt marsh expanded at this time due to increased sediment accumulation and a resulting increase in local elevation. The timing and character of changes recorded in the Morro Bay salt marsh sediments are similar to those documented across California in estuaries, marshes, lakes, and meadows, demonstrating the magnitude of the impacts of European settlement and associated land-use practices in this region.

Anthropocene↗

Mercury speciation and microbial transformations in mine wastes, stream sediments, and surface waters at the Almaden Mining District, Spain

Speciation of Hg and conversion to methyl-Hg were evaluated in mine wastes, sediments, and water collected from the Almade??n District, Spain, the world's largest Hg producing region. Our data for methyl-Hg, a neurotoxin hazardous to humans, are the first reported for sediment and water from the Almade??n area. Concentrations of Hg and methyl-Hg in mine waste, sediment, and water from Almade??n are among the highest found at Hg mines worldwide. Mine wastes from Almade??n contain highly elevated Hg concentrations, ranging from 160 to 34 000 ??g/g, and methyl-Hg varies from <0.20 to 3100 ng/g. Isotopic tracer methods indicate that mine wastes at one site (Almadenejos) exhibit unusually high rates of Hg-methylation, which correspond with mine wastes containing the highest methyl-Hg concentrations. Streamwater collected near the Almade??n mine is also contaminated, containing Hg as high as 13 000 ng/L and methyl-Hg as high as 30 ng/L; corresponding stream sediments contain Hg concentrations as high as 2300 ??g/g and methyl-Hg concentrations as high as 82 ng/g. Several streamwaters contain Hg concentrations in excess of the 1000 ng/L World Health Organization (WHO) drinking water standard. Methyl-Hg formation and degradation was rapid in mines wastes and stream sediments demonstrating the dynamic nature of Hg cycling. These data indicate substantial downstream transport of Hg from the Almade??n mine and significant conversion to methyl-Hg in the surface environment.

Environmental Science & Technology↗

Streamflow depletion caused by groundwater pumping: Fundamental research priorities for management-relevant science

Reductions in streamflow caused by groundwater pumping, known as “streamflow depletion,” link the hydrologic process of stream-aquifer interactions to human modifications of the water cycle. Isolating the impacts of groundwater pumping on streamflow is challenging because other climate and human activities concurrently impact streamflow, making it difficult to separate individual drivers of hydrologic change. In addition, there can be lags between when pumping occurs and when streamflow is affected. However, accurate quantification of streamflow depletion is critical to integrated groundwater and surface water management decision making. Here, we highlight research priorities to help advance fundamental hydrologic science and better serve the decision-making process. Key priorities include (a) linking streamflow depletion to decision-relevant outcomes such as ecosystem function and water users to align with partner needs; (b) enhancing partner trust and applicability of streamflow depletion methods through benchmarking and coupled model development; and (c) improving links between streamflow depletion quantification and decision-making processes. Catalyzing research efforts around the common goal of enhancing our streamflow depletion decision-support capabilities will require disciplinary advances within the water science community and a commitment to transdisciplinary collaboration with diverse water-connected disciplines, professions, governments, organizations, and communities.

Water Resource Research↗

Physical, chemical, and biological data for detailed study of irrigation drainage in the Uncompahgre Project area and in the Grand Valley, west-central Colorado, 1991-92

Because of concerns about potential effects of irrigation drainage on fish and wildlife resources and on human health, the U.S. Department of the Interior initiated a program in 1985 to assess water-quality problems associated with Federal irrigation projects in the Western United States. Physical, chemical, and biological data were collected for a detailed study of irrigation drainage in the Uncompahgre Project area and in the Grand Valley, west-central Colorado, during 1991-92. This report lists onsite measurements and concen- trations of major constituents, trace elements, and stable isotopes for surface-water- and ground-water-sampling sites. Insecticide data collected in the Grand Valley are presented. Ranges of specific-conductance measurements and dissolved- oxygen concentrations for selected wells and a daily record of water-level altitude and specific conduc- tance for a well in the Grand Valley are presented. The report presents historical water-level and dissolved-solids data for two wells in the Grand Valley. Concentrations of trace elements, major constituents, total carbon, and organic carbon in bottom-sediment, bedrock, and in aquifer-sediment samples and semiquantitative data on clay and bulk mineralogy of samples of the Mancos Shale are presented. The report contains selenium-speciation data for selected water and bottom-sediment samples and selected aquifer-test results. Biological samples collected in the Uncompahgre Project area and in the Grand Valley included aquatic plants, aquatic invertebrates, fish, birds, and bird eggs. The report lists concentrations of trace elements in biological samples collected in 1991-92. A limited number of biological samples were analyzed for pesticides, PCB's, and polycyclic aromatic hydrocarbons.

Open-File Report↗

Variations in City Exposure and Sensitivity to Tsunami Hazards in Oregon

Evidence of past events and modeling of potential future events suggest that tsunamis are significant threats to Oregon coastal communities. Although a potential tsunami-inundation zone from a Cascadia Subduction Zone earthquake has been delineated, what is in this area and how communities have chosen to develop within it have not been documented. A vulnerability assessment using geographic-information-system tools was conducted to describe tsunami-prone landscapes on the Oregon coast and to document city variations in developed land, human populations, economic assets, and critical facilities relative to the tsunami-inundation zone. Results indicate that the Oregon tsunami-inundation zone contains approximately 22,201 residents (four percent of the total population in the seven coastal counties), 14,857 employees (six percent of the total labor force), and 53,714 day-use visitors on average every day to coastal Oregon State Parks within the tsunami-inundation zone. The tsunami-inundation zone also contains 1,829 businesses that generate approximately $1.9 billion in annual sales volume (seven and five percent of study-area totals, respectively) and tax parcels with a combined total value of $8.2 billion (12 percent of the study-area total). Although occupancy values are not known for each facility, the tsunami-inundation zone also contains numerous dependent-population facilities (for example, adult-residential-care facilities, child-day-care facilities, and schools), public venues (for example, religious organizations and libraries), and critical facilities (for example, police stations). Racial diversity of residents in the tsunami-inundation zone is low, with 96 percent identifying themselves as White, either alone or in combination with one or more race. Twenty-two percent of the residents in the tsunami-inundation zone are over 65 years in age, 36 percent of the residents live on unincorporated county lands, and 37 percent of the households are renter occupied. The employee population in the tsunami-inundation zone is largely in accommodation and food services, retail trade, manufacturing, and arts and entertainment sectors. Results indicate that vulnerability, described here by exposure (the amount of assets in tsunami-prone areas) and sensitivity (the relative percentage of assets in tsunami-prone areas) varies considerably among 26 incorporated cities in Oregon. City exposure and sensitivity to tsunami hazards is highest in the northern portion of the coast. The City of Seaside in Clatsop County has the highest exposure, the highest sensitivity, and the highest combined relative exposure and sensitivity to tsunamis. Results also indicate that the amount of city assets in tsunami-prone areas is weakly related to the amount of a community's land in this zone; the percentage of a city's assets, however, is strongly related to the percentage of its land that is in the tsunami-prone areas. This report will further the dialogue on societal risk to tsunami hazards in Oregon and help identify future preparedness, mitigation, response, and recovery planning needs within coastal cities and economic sectors of the state of Oregon.

Scientific Investigations Report↗

Water-quality and algal conditions in the Clackamas River basin, Oregon, and their relations to land and water management

In 1998, the U.S. Geological Survey sampled the Clackamas River, its major tributaries, and reservoirs to characterize basic water quality (nutrients, dissolved oxygen, pH, temperature, and conductance), water quantity (water sources within the basin), and algal conditions (biomass and species composition). Sampling locations reflected the dominant land uses in the basin (forest management, agriculture, and urban development) as well as the influence of hydroelectric projects, to examine how these human influences might be affecting water quality and algal conditions. Nuisance algal growths, with accompanying negative effects on water quality, were observed at several locations in the basin during this study. Algal biomass in the lower Clackamas River reached a maximum of 300 mg/m2 chlorophyll a, producing nuisance algal conditions, including fouled stream channels and daily fluctuations in pH and dissolved oxygen concentrations to levels that did not meet water-quality standards. Algal biomass was highest at sites immediately downstream from the hydroelectric project's reservoirs and/or powerhouses. Nuisance algal conditions also were observed in some of the tributaries, including the North Fork of the Clackamas River, Clear Creek, Rock Creek, and Sieben Creek. High amounts of drifting algae increased turbidity levels in the Clackamas River during June, which coincided with a general increase in the concentration of disinfection by-products found in treated Clackamas River water used for drinking, presumably due to the greater amounts of organic matter in the river. The highest nutrient concentrations were found in the four lowermost tributaries (Deep, Richardson, Rock, and Sieben Creeks), where most of the agriculture and urban development is concentrated. Of these, the greatest load of nutrients came from Deep Creek, which had both high nutrient concentrations and relatively high streamflow. Streams draining forestland in the upper basin (upper Clackamas River and Oak Grove Fork) had the highest concentrations of phosphorus (and lowest concentrations of nitrogen), and streams draining forestland in the middle basin (Clear Creek, Eagle Creek, and the North Fork of the Clackamas River) had relatively high concentrations of nitrogen (and low concentrations of phosphorus). In contrast, relatively low concentrations of both nitrogen and phosphorus were found at the two reference streams, reflecting their pristine condition. Relatively high phosphorus levels in the upper basin are probably due to the erosion of naturally occurring phosphorus deposits in this area. Likely sources of nitrogen (mostly nitrate) in the forested watersheds include nitrogen-fixing plants, atmospheric deposition, timber harvesting, and applications of urea fertilizers.

Water-Resources Investigations Report↗

Concentrations of mineral aerosol from desert to plains across the central Rocky Mountains, western United States

Mineral dusts can have profound effects on climate, clouds, ecosystem processes, and human health. Because regional dust emission and deposition in western North America are not well understood, measurements of total suspended particulate (TSP) from 2011 to 2013 were made along a 500-km transect of five remote sites in Utah and Colorado, USA. The TSP concentrations in μg m −3 adjusted to a 24-h period were relatively high at the two westernmost, dryland sites at Canyonlands National Park (mean = 135) and at Mesa Verde National Park (mean = 99), as well as at the easternmost site on the Great Plains (mean = 143). The TSP concentrations at the two intervening montane sites were less, with more loading on the western slope of the Rocky Mountains (Telluride, mean = 68) closest to the desert sites compared with the site on the eastern slope (Niwot Ridge, mean = 58). Dust concentrations were commonly highest during late winter-late spring, when Pacific frontal storms are the dominant causes of regional wind. Low concentrations (<7 wt%) of organic matter indicated that rock-derived mineral particles composed most TSP. Most TSP mass was carried by particle sizes larger than 10 μm (PM >10 ), as revealed by relatively low average daily concentrations of fine (<5 μg m −3 ; PM 2.5 ) and coarse (<10 μg m −3 ; PM 2.5–10 ) fractions monitored at or near four sites. Standard air-quality measurements for PM 2.5 and PM 10 apparently do not capture the large majority of mineral-particulate pollution in the remote western interior U.S.

Aeolian Research↗

Science to support the understanding of Ohio's water resources

Ohio’s water resources support a complex web of human activities and nature—clean and abundant water is needed for drinking, recreation, farming, and industry, as well as for fish and wildlife needs. The distribution of rainfall can cause floods and droughts, which affects streamflow, groundwater, water availability, water quality, recreation, and aquatic habitats. Ohio is bordered by the Ohio River and Lake Erie and has over 44,000 miles of streams and more than 60,000 lakes and ponds (State of Ohio, 1994). Nearly all the rural population obtain drinking water from groundwater sources. The U.S. Geological Survey (USGS) works in cooperation with local, State, and other Federal agencies, as well as universities, to furnish decisionmakers, policymakers, USGS scientists, and the general public with reliable scientific information and tools to assist them in management, stewardship, and use of Ohio’s natural resources. The diversity of scientific expertise among USGS personnel enables them to carry out large- and small-scale multidisciplinary studies. The USGS is unique among government organizations because it has neither regulatory nor developmental authority—its sole product is reliable, impartial, credible, relevant, and timely scientific information, equally accessible and available to everyone. The USGS Ohio Water Science Center provides reliable hydrologic and water-related ecological information to aid in the understanding of use and management of the Nation’s water resources, in general, and Ohio’s water resources, in particular. This fact sheet provides an overview of current (2012) or recently completed USGS studies and data activities pertaining to water resources in Ohio. More information regarding projects of the USGS Ohio Water Science Center is available at http://oh.water.usgs.gov/.

Ohio↗

Occurrence of selected contaminants in water, fish tissue, and streambed sediments in central Nebraska, 1992-95

Surface and ground water in Nebraska may contain contaminants resulting from human activities. For purposes of this publication, a contaminant is any element or compound whose presence may affect the water's suitability for certain uses. For example, herbicide concentrations may exceeed the U.S. Environmental Protection Agency's (USEPA) Health Advisory Levels (HAL) for drinking water or trace-element concentrations may exceed guidelines for the protection of aquatic life. In general, the contaminats discussed in this report enter the aquatic system through nonpoint-source runoff from agricultural lands that dominate the Nebraska landscape. However,because this assessment was conducted as part of a larger, national program, a screening for contaminants with non-agricultural origins was included. The measurement of water quality involves a variety of steps, each contributing unique information while also aggregating to an overall assessment. One aspect of water-quality assesment is to describe the occurrence and distribution of contaminants. Some contaminants may be hundreds or thousands of times more concentrated in the tissues of aquatic organisms or in fine sediments than they are in the water. As a result, fish tissue and streambed sediments are well suited for the detection of certain contaminants. For example, pesticides used in the United States prior to the early 1970's, such as DDT, may have degraded into more stable but still toxic compounds that are highly concentrated in fish tissues. Conversely, other contaminants are not concentrated in sediments or tissues but are readily detected in water samples. Organonitrogen herbicides (such as atrazine), the most commonly used herbicides in Nebraska, are examples of water-soluble contaminants. Several sampling strategies were used to address specific questions. Some sites were sampled repeatedly through time and during all hydrologic conditions, whereas others were sampled only once to determine presence of contaminants. Because a strong relation between concentration and streamflow often exists for contaminants originating from nonpoint sources, streams typically were sampled near gaging stations that monitor streamflow.

Nebraska↗

A policy model to initiate environmental negotiations: Three hydropower workshops

How do I get started in natural resource negotiations? Natural resource managers often face difficult negotiations when they implement laws and policies regulating such resources as water, wildlife, wetlands, endangered species, and recreation. As a result of these negotiations, managers must establish rules, grant permits, or create management plans. The Legal‐Institutional Analysis Model (LIAM) was designed to assist managers in systematically analyzing the parties in natural resource negotiations and using that analysis to prepare for bargaining. The LIAM relies on the theory that organizations consistently employ behavioral roles. The model uses those roles to predict likely negotiation behavior. One practical use of the LIAM is when all parties to a negotiation conduct a workshop as a way to open the bargaining on a note of trust and mutual understanding. The process and results of three LIAM workshops designed to guide hydroelectric power licensing negotiations are presented. Our experience with these workshops led us to conclude that the LIAM can be an effective tool to begin a negotiation and that trust built through the workshops can help create a successful result.

Human Dimensions of Wildlife: An International Jou↗

Methods used for the collection and analysis of chemical and biological data for the Tapwater Exposure Study, United States, 2016–17

In 2016, the U.S. Geological Survey (USGS) Environmental Health Mission Area, initiated the Tapwater Exposure Study as part of an infrastructure project to assess human exposure to potential threats from complex mixtures of contaminants. In the pilot phase (2016), samples were collected from 11 States throughout the United States, and in the second phase (2017), the study focused on the Greater Chicago area, including North and South Chicago, Illinois, and East Chicago, Indiana. Residential tapwater samples were collected at private residences during both phases, and during the first phase, samples were collected from Federal office buildings and from one office 19-liter water-bottle source. During the second phase, raw intake and treated (pre-distributional) water samples also were collected from four drinking-water treatment facilities in the Greater Chicago area. Samples were sent to laboratories at the USGS, U.S. Environmental Protection Agency, National Institute of Environmental Health Sciences, and Colorado School of Mines Center for Environmental Risk Assessment, for potential drinking-water pathogens, chemical, and bioassay analyses. These analyses included more than 400 chemicals such as trace elements, steroid hormones, pharmaceuticals, volatile organic compounds, pesticides, per- and polyfluorinated alkyl substances, cyanotoxins, and other organic compounds. The in vitro bioassay analyses included estrogen, androgen, and glucocorticoid receptor activity.

Open-File Report↗

Variations in Community Exposure and Sensitivity to Tsunami Hazards on the Open-Ocean and Strait of Juan de Fuca Coasts of Washington

Evidence of past events and modeling of potential future events suggest that tsunamis are significant threats to communities on the open-ocean and Strait of Juan de Fuca coasts of Washington. Although potential tsunami-inundation zones from a Cascadia Subduction Zone (CSZ) earthquake have been delineated, the amount and type of human development in tsunami-prone areas have not been documented. A vulnerability assessment using geographic-information-system tools was conducted to document variations in developed land, human populations, economic assets, and critical facilities relative to CSZ-related tsunami-inundation zones among communities on the open-ocean and Strait of Juan de Fuca coasts of Washington (including Clallam, Jefferson, Grays Harbor, and Pacific Counties). The tsunami-inundation zone in these counties contains 42,972 residents (24 percent of the total study-area population), 24,934 employees (33 percent of the total labor force), and 17,029 daily visitors to coastal Washington State Parks. The tsunami-inundation zone also contains 2,908 businesses that generate $4.6 billion in annual sales volume (31 and 40 percent of study-area totals, respectively) and tax parcels with a combined total value of $4.5 billion (25 percent of the study-area total). Although occupancy values are not known for each site, the tsunami-inundation zone also contains numerous dependent-population facilities (for example, schools and child-day-care centers), public venues (for example, religious organizations), and critical facilities (for example, police stations and public-work facilities). Racial diversity of residents in tsunami-prone areas is low?89 percent of residents are White and 8 percent are American Indian or Alaska Native. Nineteen percent of the residents in the tsunami-inundation zone are over 65 years in age, 30 percent of the residents live on unincorporated county lands, and 35 percent of the households are renter occupied. Employees in the tsunami-inundation zone are largely in businesses related to health care and social assistance, accommodation and food services, and retail trade, reflecting businesses that cater to a growing retiree and tourist population. Community vulnerability, described here by exposure (the amount of assets in tsunami-prone areas) and sensitivity (the relative percentage of assets in tsunami-prone areas) varies among 13 incorporated cities, 7 Indian reservations, and 4 counties. The City of Aberdeen has the highest relative community exposure to tsunamis, whereas the City of Long Beach has the highest relative community sensitivity. Levels of community exposure and sensitivity to tsunamis are found to be related to the amount and percentage, respectively, of a community?s land that is in a tsunami-inundation zone. This report will further the dialogue on societal risk to tsunami hazards in Washington and help risk managers to determine where additional risk-reduction strategies may be needed.

Scientific Investigations Report↗

Science to support the understanding of Ohio's water resources, 2014-15

Ohio’s water resources support a complex web of human activities and nature—clean and abundant water is needed for drinking, recreation, farming, and industry, as well as for fish and wildlife needs. Although rainfall in normal years can support these activities and needs, occasional floods and droughts can disrupt streamflow, groundwater, water availability, water quality, recreation, and aquatic habitats. Ohio is bordered by the Ohio River and Lake Erie; it has over 44,000 miles of streams and more than 60,000 lakes and ponds. Nearly all the rural population obtain drinking water from groundwater sources. The U.S. Geological Survey (USGS) works in cooperation with local, State, and other Federal agencies, as well as universities, to furnish decision makers, policy makers, USGS scientists, and the general public with reliable scientific information and tools to assist them in management, stewardship, and use of Ohio’s natural resources. The diversity of scientific expertise among USGS personnel enables them to carry out large- and small-scale multidisciplinary studies. The USGS is unique among government organizations because it has neither regulatory nor developmental authority—its sole product is impartial, credible, relevant, and timely scientific information, equally accessible and available to everyone. The USGS Ohio Water Science Center provides reliable hydrologic and water-related ecological information to aid in the understanding of the use and management of the Nation’s water resources, in general, and Ohio’s water resources, in particular. This fact sheet provides an overview of current (2014) or recently completed USGS studies and data activities pertaining to water resources in Ohio. More information regarding projects of the USGS Ohio Water Science Center is available at http://oh.water.usgs.gov/ .

Ohio↗

Factors Controlling Pre-Columbian and Early Historic Maize Productivity in the American Southwest, Part 1: The Southern Colorado Plateau and Rio Grande Regions

Maize is the New World's preeminent grain crop and it provided the economic basis for human culture in many regions within the Americas. To flourish, maize needs water, sunlight (heat), and nutrients (e. g., nitrogen). In this paper, climate and soil chemistry data are used to evaluate the potential for dryland (rainon-field) agriculture in the semiarid southeastern Colorado Plateau and Rio Grande regions. Processes that impact maize agriculture such as nitrogen mineralization, infiltration of precipitation, bare soil evaporation, and transpiration are discussed and evaluated. Most of the study area, excepting high-elevation regions, receives sufficient solar radiation to grow maize. The salinities of subsurface soils in the central San Juan Basin are very high and their nitrogen concentrations are very low. In addition, soils of the central San Juan Basin are characterized by pH values that exceed 8.0, which limit the availability of both nitrogen and phosphorous. In general, the San Juan Basin, including Chaco Canyon, is the least promising part of the study area in terms of dryland farming. Calculations of field life, using values of organic nitrogen for the upper 50 cm of soil in the study area, indicate that most of the study area could not support a 10-bushel/acre crop of maize. The concepts, methods, and calculations used to quantify maize productivity in this study are applicable to maize cultivation in other environmental settings across the Americas. ?? 2010 US Government.

Journal of Archaeological Method and Theory↗

Global patterns of the isotopic composition of soil and plant nitrogen

We compiled new and published data on the natural abundance N isotope composition (δ 15 N values) of soil and plant organic matter from around the world. Across a broad range of climate and ecosystem types, we found that soil and plant δ 15 N values systematically decreased with increasing mean annual precipitation (MAP) and decreasing mean annual temperature (MAT). Because most undisturbed soils are near N steady state, the observations suggest that an increasing fraction of ecosystem N losses are 15 N-depleted forms (NO 3 , N 2 O, etc.) with decreasing MAP and increasing MAT. Wetter and colder ecosystems appear to be more efficient in conserving and recycling mineral N. Globally, plant δ 15 N values are more negative than soils, but the difference (δ 15 N plant -δ 15 N soil ) increases with decreasing MAT (and secondarily increasing MAP), suggesting a systematic change in the source of plant-available N (organic/NH 4 + versus NO 3 − ) with climate. Nitrogen isotopes reflect time integrated measures of the controls on N storage that are critical for predictions of how these ecosystems will respond to human-mediated disturbances of the global N cycle.

Global Biogeochemical Cycles↗

Diel cycles in dissolved barium, lead, iron, vanadium, and nitrite in a stream draining a former zinc smelter site near Hegeler, Illinois

Diel variations in the concentrations of a number of constituents have the potential to substantially affect the appropriate sampling regimen in acidic streams. Samples taken once during the course of the day cannot adequately reflect diel variations in water quality and may result in an inaccurate understanding of biogeochemical processes, ecological conditions, and of the threat posed by the water to human health and the associated wildlife. Surface water and groundwater affected by acid drainage were sampled every 60 to 90 min over a 48-hour period at a former zinc smelter known as the Hegeler Zinc Superfund Site, near Hegeler, Illinois. Diel variations related to water quality in the aquifer were not observed in groundwater. Diel variations were observed in the temperature, pH, and concentration of dissolved oxygen, nitrite, barium, iron, lead, vanadium, and possibly uranium in surface water. Temperature, dissolved oxygen, nitrite, barium, lead, and uranium generally attained maximum values during the afternoon and minimum values during the night. Iron, vanadium, and pH generally attained minimum values during the afternoon and maximum values during the night. Concentrations of dissolved oxygen were affected by the intensity of photosynthetic activity and respiration, which are dependent upon insolation. Nitrite, an intermediary in many nitrogen reactions, may have been formed by the oxidation of ammonium by dissolved oxygen and converted to other nitrogen species as part of the decomposition of organic matter. The timing of the pH cycles was distinctly different from the cycles found in Midwestern alkaline streams and likely was the result of the photoreduction of Fe 3+ to Fe 2+ and variations in the intensity of precipitation of hydrous ferric oxide minerals. Diel cycles of iron and vanadium also were primarily the result of variations in the intensity of precipitation of hydrous ferric oxide minerals. The diel variation in the concentrations of lead, uranium, and barium may have been affected by competition with Fe + 2 for sorption sites on hydrous ferric oxide minerals.

Illinois↗