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At least 991 records · Page 55Linked to original sources

Applicability of tetrazolium salts for the measurement of respiratory activity and viability of groundwater bacteria

A study was undertaken to measure aerobic respiration by indigenous bacteria in a sand and gravel aquifer on western Cape Cod, MA using tetrazolium salts and by direct oxygen consumption using gas chromatography (GC). In groundwater and aquifer slurries, the rate of aerobic respiration calculated from the direct GC assay was more than 600 times greater than that using the tetrazolium salt 2-(4-iodophenyl)-3-(4-nitrophenyl)-5-phenyl tetrazolium chloride (INT). To explain this discrepancy, the toxicity of INT and two additional tetrazolium salts, sodium 3′-[1-(phenylamino)-carbonyl]-3,4-tetrazolium]-bis(4-methoxy-6-nitro) benzenesulfonic acid hydrate (XTT) and 5-cyano-2,3-ditolyl tetrazolium chloride (CTC), to bacterial isolates from the aquifer was investigated. Each of the three tetrazolium salts was observed to be toxic to some of the groundwater isolates at concentrations normally used in electron transport system (ETS) and viability assays. For example, incubation of cells with XTT (3 mM) caused the density of four of the five groundwater strains tested to decline by more than four orders of magnitude. A reasonable percentage (>57%) of cells killed by CTC and INT contained visible formazan crystals (the insoluble, reduced form of the salts) after 4 h of incubation. Thus, many of the cells reduced enough CTC or INT prior to dying to be considered viable by microscopic evaluation. However, one bacterium ( Pseudomonas fluorescens ) that remained viable and culturable in the presence of INT and CTC, did not incorporate formazan crystals into more than a few percent of cells, even after 24 h of incubation. This strain would be considered nonviable based on traditional tetrazolium salt reduction assays. The data show that tetrazolium salt assays are likely to dramatically underestimate total ETS activity in groundwater and, although they may provide a reasonable overall estimate of viable cell numbers in a community of groundwater bacteria, some specific strains may be falsely considered nonviable by this assay due to poor uptake or reduction of the salts.

Massachusetts↗

Preliminary investigation of the effects of sea-level rise on groundwater levels in New Haven, Connecticut

Global sea level rose about 0.56 feet (ft) (170 millimeters (mm)) during the 20th century. Since the 1960s, sea level has risen at Bridgeport, Connecticut, about 0.38 ft (115 mm), at a rate of 0.008 ft (2.56 mm + or - 0.58 mm) per year. With regional subsidence, and with predicted global climate change, sea level is expected to continue to rise along the northeast coast of the United States through the 21st century. Increasing sea levels will cause groundwater levels in coastal areas to rise in order to adjust to the new conditions. Some regional climate models predict wetter climate in the northeastern United States under some scenarios. Scenarios for the resulting higher groundwater levels have the potential to inundate underground infrastructure in lowlying coastal cities. New Haven is a coastal city in Connecticut surrounded and bisected by tidally affected waters. Monitoring of water levels in wells in New Haven from August 2009 to July 2010 indicates the complex effects of urban influence on groundwater levels. The response of groundwater levels to recharge and season varied considerably from well to well. Groundwater temperatures varied seasonally, but were warmer than what was typical for Connecticut, and they seem to reflect the influence of the urban setting, including the effects of conduits for underground utilities. Specific conductance was elevated in many of the wells, indicating the influence of urban activities or seawater in Long Island Sound. A preliminary steady-state model of groundwater flow for part of New Haven was constructed using MODFLOW to simulate current groundwater levels (2009-2010) and future groundwater levels based on scenarios with a rise of 3 ft (0.91 meters (m)) in sea level, which is predicted for the end of the 21st century. An additional simulation was run assuming a 3-ft rise in sea level combined with a 12-percent increase in groundwater recharge. The model was constructed from existing hydrogeologic information for the New Haven area and from new information on groundwater levels collected during October 2009-June 2010. For the scenario with a 3-ft rise in sea level and no increase in recharge, simulated groundwater levels near the coast rose 3 ft; this increased water level tapered off toward a discharge area at the only nontidal stream in the study area. Simulated stream discharge increased at the nontidal stream because of the increased gradient. Although groundwater levels rose, the simulated difference between the groundwater levels in the aquifer and the increased sea level declined, indicating that the depth to the interface between freshwater and saltwater may possibly decline. Simulated water levels were affected by rise in sea level even in areas where the water table was at 17-24 ft (5.2-7.3 m) above current (2011) sea level. For the scenario with increased recharge, simulated groundwater levels were as much as an additional foot higher at some locations in the study area. The results of this preliminary investigation indicate that groundwater levels in coastal areas can be expected to rise and may rise higher if groundwater recharge also increases. This finding has implications for the disposal of stormwater through infiltration, a low-impact development practice designed to improve water quality and reduce overland peak discharge. Other implications include increased risk of basement flooding and increased groundwater seepage into underground sewer pipes and utility corridors in some areas. These implications will present engineering challenges to New Haven and Yale University. The preliminary model developed for this study can be the starting point for further simulation of future alternative scenarios for sea-level rise and recharge. Further simulations could identify those areas of New Haven where infrastructure may be at greatest risk from rising levels of groundwater. The simulations described in this report have limitations due to the preliminary scope of the work. Approaches to improve simulations include but are not limited to incorporating: * The variable density of seawater into the model in order to understand the current and future location of the interface between freshwater and saltwater; * Collection of additional data in order to better resolve temporal and spatial patterns in water levels in the aquifer; * Improved estimates of recharge through direct and indirect measurements of freshwater discharge from the study area; and * Transient simulations for greater understanding of the amount of time required for water levels and the position of the interface between freshwater and saltwater to adjust to changes in sea level and recharge.

Connecticut↗

Evaluation of sample preservation methods for analysis of selected volatile organic compounds in groundwater at the Idaho National Laboratory, Idaho

During 2020, water samples were collected from 25 wells completed in the eastern Snake River Plain aquifer and from 1 well completed in perched groundwater above the aquifer at the Idaho National Laboratory to determine the effect of different sample-preservation methods on the laboratory determinations of concentrations of volatile organic compounds. Paired-sample sets were collected at each well. One sample in each set was preserved with hydrochloric acid, and one sample without. Both samples were chilled after collection and during shipping to the laboratory for analysis. The samples were analyzed for 61 volatile organic compounds at the U.S. Geological Survey National Water Quality Laboratory in cooperation with the U.S. Department of Energy. A comparison of the reproducibility of the analyses of co-located unpreserved and preserved samples by a relative percent difference method determined that all sample pairs were statistically equivalent. Using a normalized absolute difference method, 81 percent of the analyses were found to be statistically equivalent. This study confirms that the results of analyses of historical collected samples, which were preserved by chilling only, are statistically comparable to the analyses of samples being currently collected and preserved by both hydrochloric acid and chilling, and thus are valid for use in future geochemical evaluations.

Idaho↗

Hydrogeology and water-supply potential of the water-table aquifer on Dauphin Island, Alabama

The water table aquifer on Dauphin Island, Alabama, consists of a thin veneer of Holocene sand and an underlying Pleistocene unit locally known as the Gulfport Formation. The aquifer is from 28 to 35 ft thick with a thick marine clay at its base. Water in the aquifer generally is low in chloride content except near the coast. Excessively high iron concentrations in groundwater were found locally. A two-dimensional finite-difference groundwater flow model of the water table aquifer on Dauphin Island was used in the steady-state mode to evaluate the flow system under steady-state conditions. Model input data were obtained primarily from 40 test wells, 2 aquifer tests, continuous recording of groundwater levels, and rainfall. The model was calibrated to the low water-table conditions of July 1985 and high water table conditions of April 1985. The model was also used to simulate pumpage from the aquifer under transient conditions with no rainfall. Patterns of computed head changes compared favorably to the natural recession of water levels for the periods of April to May 1985 and May to June 1985. Simulation of groundwater withdrawals in the transient model showed the feasibility of producing 0.6 million gallons/day from eight wells that tap the water table aquifer without inducing lateral seawater encroachment. (USGS)

Water-Resources Investigations Report↗

Microorganisms as tracers in groundwater injection and recovery experiments: A review

Modern day injection and recovery techniques designed to examine the transport behavior of microorganisms in groundwater have evolved from experiments conducted in the late 1800s, in which bacteria that form red or yellow pigments were used to trace flow paths through karst and fractured- rock aquifers. A number of subsequent groundwater hydrology studies employed bacteriophage that can be injected into aquifers at very high concentrations (e g., 1013 phage ml-1) and monitored through many log units of dilution to follow groundwater flow paths for great distances, particularly in karst terrain. Starting in the 1930s, microbial indicators of fecal contamination (particularly coliform bacteria and their coliphages) were employed as tracers to determine potential migration of pathogens in groundwater. Several injection and recovery experiments performed in the 1990s employed indigenous groundwater microorganisms (both cultured and uncultured) that are better able to survive under in situ conditions. Better methods for labeling native bacteria (e.g by stable isotope labeling or inserting genetic markers; such as the ability to cause ice nucleation) are being developed that will not compromise the organisms' viability during the experimental time course.

FEMS Microbiology Reviews↗

Simulation of groundwater flow and analysis of the effects of water-management options in the North Platte Natural Resources District, Nebraska

The North Platte Natural Resources District (NPNRD) has been actively collecting data and studying groundwater resources because of concerns about the future availability of the highly inter-connected surface-water and groundwater resources. This report, prepared by the U.S. Geological Survey in cooperation with the North Platte Natural Resources District, describes a groundwater-flow model of the North Platte River valley from Bridgeport, Nebraska, extending west to 6 miles into Wyoming. The model was built to improve the understanding of the interaction of surface-water and groundwater resources, and as an optimization tool, the model is able to analyze the effects of water-management options on the simulated stream base flow of the North Platte River. The groundwater system and related sources and sinks of water were simulated using a newton formulation of the U.S. Geological Survey modular three-dimensional groundwater model, referred to as MODFLOW–NWT, which provided an improved ability to solve nonlinear unconfined aquifer simulations with wetting and drying of cells. Using previously published aquifer-base-altitude contours in conjunction with newer test-hole and geophysical data, a new base-of-aquifer altitude map was generated because of the strong effect of the aquifer-base topography on groundwater-flow direction and magnitude. The largest inflow to groundwater is recharge originating from water leaking from canals, which is much larger than recharge originating from infiltration of precipitation. The largest component of groundwater discharge from the study area is to the North Platte River and its tributaries, with smaller amounts of discharge to evapotranspiration and groundwater withdrawals for irrigation. Recharge from infiltration of precipitation was estimated with a daily soil-water-balance model. Annual recharge from canal seepage was estimated using available records from the Bureau of Reclamation and then modified with canal-seepage potentials estimated using geophysical data. Groundwater withdrawals were estimated using land-cover data, precipitation data, and published crop water-use data. For fields irrigated with surface water and groundwater, surface-water deliveries were subtracted from the estimated net irrigation requirement, and groundwater withdrawal was assumed to be equal to any demand unmet by surface water. The groundwater-flow model was calibrated to measured groundwater levels and stream base flows estimated using the base-flow index method. The model was calibrated through automated adjustments using statistical techniques through parameter estimation using the parameter estimation suite of software (PEST). PEST was used to adjust 273 parameters, grouped as hydraulic conductivity of the aquifer, spatial multipliers to recharge, temporal multipliers to recharge, and two specific recharge parameters. Base flow of the North Platte River at Bridgeport, Nebraska, streamgage near the eastern, downstream end of the model was one of the primary calibration targets. Simulated base flow reasonably matched estimated base flow for this streamgage during 1950–2008, with an average difference of 15 percent. Overall, 1950–2008 simulated base flow followed the trend of the estimated base flow reasonably well, in cases with generally increasing or decreasing base flow from the start of the simulation to the end. Simulated base flow also matched estimated base flow reasonably well for most of the North Platte River tributaries with estimated base flow. Average simulated groundwater budgets during 1989–2008 were nearly three times larger for irrigation seasons than for non-irrigation seasons. The calibrated groundwater-flow model was used with the Groundwater-Management Process for the 2005 version of the U.S. Geological Survey modular three-dimensional groundwater model, MODFLOW–2005, to provide a tool for the NPNRD to better understand how water-management decisions could affect stream base flows of the North Platte River at Bridgeport, Nebr., streamgage in a future period from 2008 to 2019 under varying climatic conditions. The simulation-optimization model was constructed to analyze the maximum increase in simulated stream base flow that could be obtained with the minimum amount of reductions in groundwater withdrawals for irrigation. A second analysis extended the first to analyze the simulated base-flow benefit of groundwater withdrawals along with application of intentional recharge, that is, water from canals being released into rangeland areas with sandy soils. With optimized groundwater withdrawals and intentional recharge, the maximum simulated stream base flow was 15–23 cubic feet per second (ft 3 /s) greater than with no management at all, or 10–15 ft 3 /s larger than with managed groundwater withdrawals only. These results indicate not only the amount that simulated stream base flow can be increased by these management options, but also the locations where the management options provide the most or least benefit to the simulated stream base flow. For the analyses in this report, simulated base flow was best optimized by reductions in groundwater withdrawals north of the North Platte River and in the western half of the area. Intentional recharge sites selected by the optimization had a complex distribution but were more likely to be closer to the North Platte River or its tributaries. Future users of the simulation-optimization model will be able to modify the input files as to type, location, and timing of constraints, decision variables of groundwater withdrawals by zone, and other variables to explore other feasible management scenarios that may yield different increases in simulated future base flow of the North Platte River.

Nebraska↗

A new tool to assess groundwater resources in the Mississippi embayment

What is the Mississippi Embayment? The Mississippi embayment study area encompasses approximately 78,000 square miles in eight States and includes large parts of Arkansas, Louisiana, Mississippi, and Tennessee, and smaller areas of Alabama, Illinois, Kentucky, and Missouri (fig. 1). The Mississippi embayment is essentially a basin that slopes toward the Gulf of Mexico and is filled with sediments of alternating sand, silt, and clay layers. There are two principal aquifers in the embayment-the Mississippi River Valley alluvial aquifer (alluvial aquifer) and the middle Claiborne aquifer (fig. 1). The shallow alluvial aquifer is the primary source of groundwater for irrigation in the largely agricultural region, while the deeper middle Claiborne aquifer is a primary source of drinking water for many of the 5.2 million people living in the embayment. The U.S. Geological Survey (USGS) is conducting large-scale multidisciplinary regional studies of groundwater availability for the Nation. Studies comprise individual assessments of regional groundwater-flow systems that encompass varied terrains and document a comprehensive regional and national perspective of groundwater resources. Collectively, these studies are the foundation for the national assessment of groundwater availability and are conducted in cooperation with other Federal, State, local governments, and the private sector. Numerical groundwater-flow models are used in these studies to document effects of human activities and climate variability on groundwater levels, changes in aquifer storage, and flow between groundwater and surface-water bodies. As part of the Mississippi Embayment Regional Aquifer Study (MERAS), a numerical model was constructed of 13 layers over 78,000 square miles representing multiple aquifers and confining units for the period of 1870 to 2007. The model is a tool that was used to assess and better understand groundwater resources.

Mississippi↗

A three-dimensional ground-water-flow model modified to reduce computer-memory requirements and better simulate confining-bed and aquifer pinchouts

The Trescott computer program for modeling groundwater flow in three dimensions has been modified to (1) treat aquifer and confining bed pinchouts more realistically and (2) reduce the computer memory requirements needed for the input data. Using the original program, simulation of aquifer systems with nonrectangular external boundaries may result in a large number of nodes that are not involved in the numerical solution of the problem, but require computer storage. (USGS)

Water-Resources Investigations Report↗

Groundwater availability in the Lahaina District, west Maui, Hawai'i

Most of the public water supply in the Lahaina District, west Maui, Hawai'i, is pumped from a freshwater lens in volcanic rocks. Because of population growth, groundwater withdrawals from wells in this area are expected to increase from about 5.8 million gallons per day in 2007 to more than 11 million gallons per day by 2030. Currently (2011), the salinity of water pumped from some of the wells in the area exceeds acceptable limits for drinking water. The expected increasing demand for water in an area in which the salinity of water is already unacceptable has led to concern over the long-term sustainability of withdrawals from existing and proposed wells. A three-dimensional numerical groundwater flow and transport model was developed to simulate the effects of hypothetical withdrawal and recharge scenarios on water levels and on the transition zone between freshwater and saltwater. The model was constructed using time-varying recharge, withdrawals, and ocean levels. Hydraulic characteristics used to construct the model were initially based on published estimates but ultimately were varied to obtain better agreement between simulated and measured water levels and salinity profiles in the modeled area during 1926–2008. Scenarios included groundwater withdrawal at 2008–09 rates and locations with projected recharge (based on 2000–04 land use, no agricultural irrigation, and the rainfall record for the period 1926–2004) and withdrawal at redistributed rates and locations with several different recharge scenarios. Simulation results indicate that continuing the 2008–09 withdrawal rates and distribution (6.3 million gallons per day from 21 wells) into the future would result in decreased water levels, a thinner freshwater lens, and increased salinity of water pumped from wells. Groundwater demand projections and proposed new well sites were used to produce a projected withdrawal rate and distribution during 2010–39. Simulation results from this projected withdrawal scenario (11.2 million gallons per day from 28 wells, including 10 proposed wells) also indicate decreased water levels, a thinner freshwater lens, increased water salinity, and unacceptable salinity at several current withdrawal sites, mainly in the Honokōwai Aquifer System; however, more groundwater is available than in the previous scenario. A simulation in which injection of treated wastewater is stopped indicates that several wells will have increased salinities compared to the scenario in which injection continues. A scenario in which increased groundwater withdrawal was redistributed in an attempt to maximize withdrawal while maintaining acceptable salinities in the withdrawn water was simulated. The redistributed withdrawal simulates 20.7 million gallons per day of withdrawal from 26 wells or well fields in the Lahaina District. Simulation results indicate the following: (1) average water levels decrease by about 0.5–1 feet and the transition zone rises 20–50 feet in some areas after 30 years, mainly in the Launiupoko Aquifer System near the proposed wells, and (2), all wells produce water with salinities in the acceptable class (less than one-percent seawater salinity) after 30 years.

Hawai'i↗

Questa baseline and pre-mining ground-water quality investigation. 17. Geomorphology of the Red River Valley, Taos County, New Mexico, and influence on ground-water flow in the shallow alluvial aquifer

In April 2001, the U.S. Geological Survey (USGS) and the New Mexico Environment Department (NMED) began a cooperative study to infer the pre-mining ground-water chemistry at the Molycorp molybdenum mine site in the Red River Valley of north-central New Mexico. This report is one in a series of reports that can be used to determine pre-mining ground-water conditions at the mine site. Molycorp’s Questa molybdenum mine in the Red River Valley, northern New Mexico, is located near the margin of the Questa caldera in a highly mineralized region. The bedrock of the Taos Range surrounding the Red River is composed of Proterozoic rocks of various types, which are intruded and overlain by Oligocene volcanic rocks associated with the Questa caldera. Locally, these rocks were altered by hydrothermal activity. The alteration zones that contain sulfide minerals are particularly important because they constitute the commercial ore bodies of the region and, where exposed to weathering, form sites of rapid erosion referred to as alteration scars. Over the past thousand years, if not over the entire Holocene, erosion rates were spatially variable. Forested hillslopes eroded at about 0.04 millimeter per year, whereas alteration scars eroded at about 2.7 millimeters per year. The erosion rate of the alteration scars is unusually rapid for naturally occurring sites that have not been disturbed by humans. Watersheds containing large alteration scars delivered more sediment to the Red River Valley than the Red River could remove. Consequently, large debris fans, as much as 80 meters thick, developed within the valley. The geomorphology of the Red River Valley has had several large influences on the hydrology of the shallow alluvial aquifer, and those influences were in effect before the onset of mining within the watershed. Several reaches where alluvial ground water emerges to become Red River streamflow were observed by a tracer dilution study conducted in 2001. The aquifer narrows where erosion-resistant bedrock, which tends to form vertical cliffs, restricts the width of the valley bottom. Although the presence of a shallow bedrock sill, overlain by shallow alluvium, is a plausible cause of ground-water emergence, this cause was not demonstrated in the study area. The water-table gradient can locally decrease in the downstream direction because of changes in the hydraulic properties of the alluvium, and this may be a contributing cause of ground-water emergence. However, at one site (near Cabin Springs), ground-water emergence could not be explained by spatial changes in geometric or hydraulic properties of the aquifer. Furthermore, the available evidence demonstrates that ground water flowing through bedrock fractures or colluvium entered the north side of the alluvial aquifer, and is the cause of ground-water emergence. At that location the alluvial aquifer was already flowing full, causing the excess water to emerge into the stream. An indirect consequence of altered rock in the tributary watersheds is the rapid erosion rate of alteration scars combined with the hydraulic properties of sediments shed from those scars. Where alteration scars are large the debris fans at the mouths of the tributary watersheds substantially encroach into the Red River Valley. At such locations debris-fan materials dominate the width and thickness of the alluvium in the valley and reduce the rate of flow of ground water within the Red River alluvial aquifer. Most sites of groundwater emergence are located immediately upstream from or along the margins of debris fans. A substantial fraction of the ground water approaching a debris fan can emerge to become streamflow. This last observation has three implications. First, very little water can flow the entire length of the study area entirely within the alluvial aquifer because the ground water repeatedly contacts debris-fan sediments over that length. Second, it follows that emerging water containing unique elemental constituents must have entered the alluvial aquifer at a relatively short distance upstream. Third, a gravel aquifer downstream from a large debris fan can transmit more ground water than flows into it through the debris fan. This observation explains how the water table can be naturally, and permanently, located well beneath the level of the bed of a perennial stream.

New Mexico↗

Hydrogeology, hydraulic characteristics, and water-quality conditions in the surficial, Castle Hayne and Peedee aquifers of the greater New Hanover County area, North Carolina, 2012-13

A major issue facing the greater New Hanover County, North Carolina, area is the increased demand for drinking water resources as a result of rapid growth. The principal sources of freshwater supply in the greater New Hanover County area are withdrawals of surface water from the Cape Fear River and groundwater from the underlying Castle Hayne and Peedee aquifers. Industrial, mining, irrigation, and aquaculture groundwater withdrawals increasingly compete with public-supply utilities for freshwater resources. Future population growth and economic expansion will require increased dependence on high-quality sources of fresh groundwater. An evaluation of the hydrogeology and water-quality conditions in the surficial, Castle Hayne, and Peedee aquifers was conducted in New Hanover, eastern Brunswick, and southern Pender Counties, North Carolina. A hydrogeologic framework was delineated by using a description of the geologic and hydrogeologic units that compose aquifers and their confining units. Current and historic water-level, water-quality, and water-isotope data were used to approximate the present boundary between freshwater and brackish water in the study area. Water-level data collected during August–September 2012 and March 2013 in the Castle Hayne aquifer show that recharge areas with the highest groundwater altitudes are located in central New Hanover County, and the lowest are located in a discharge area along the Atlantic Ocean. Between 1964 and 2012, groundwater levels in the Castle Hayne aquifer in central New Hanover County have rebounded by about 10 feet, but in the Pages Creek area groundwater levels declined in excess of 20 feet. In the Peedee aquifer, the August–September 2012 groundwater levels were affected by industrial withdrawals in north-central New Hanover County. Groundwater levels in the Peedee aquifer declined more than 20 feet between 1964 and 2012 in northeastern New Hanover County because of increased withdrawals. Vertical gradients calculated between the Castle Hayne and Peedee aquifers at six well cluster sites were downward in August–September 2012 and March 2013 with the exception of one well pair that had a slight upward gradient in March 2013. Major ion chemistry results from samples collected in August–September 2012 from 97 well sites suggest that seawater is mixing with groundwater in both the Castle Hayne and Peedee aquifers in several locations in Brunswick, New Hanover, and Pender Counties. The 250 milligram per liter line of equal chloride concentration has moved inland in both aquifers since 1965, with the area between Futch and Pages Creeks in northeastern New Hanover County experiencing the greatest increase. Groundwater from the surficial, Castle Hayne, and Peedee aquifers had a stable isotope of water composition similar to that of modern precipitation. A comparison of chloride concentration data collected from public-supply wells in the 1960s with that collected in 2012 shows marked increases in chloride concentrations in the Peedee aquifer near the town of Carolina Beach at the southern end of New Hanover County.

North Carolina↗

Simulation of spring discharge from a limestone aquifer in Iowa, USA

A lumped-parameter model and least-squares method were used to simulate temporal variations of discharge from Big Spring, Iowa, USA, from 1983 to 1994. The simulated discharge rates poorly match the observed one when precipitation is taken as the sole input. The match is improved significantly when the processes of evapotranspiration and infiltration are considered. The best results are obtained when snowmelt is also included in the model. Potential evapotranspiration was estimated with Thornthwaite's formula, infiltration was calculated through a water-balance approach, and snowmelt was generated by a degree-day model. The results show that groundwater in the limestone aquifer is mainly recharged by snowmelt in early spring and by infiltration from rainfall in later spring and early summer. Simulated discharge was visually calibrated against measured discharge; the similarity between the two supports the validity of this approach. The model can be used to study the effects of climate change on groundwater resources and their quality.

Hydrogeology Journal↗

Drought and deluge: Effects of recent climate variability on groundwater levels in eastern Arkansas

Arkansas experienced wide extremes in climate variability during the period of 2005 to 2010, recording the largest annual precipitation ever recorded in the State (100.05 inches) in 2009. Many weather stations across the State reported between 80 to 90 inches of rainfall in 2009. For comparison, the average annual precipitation in Little Rock, Arkansas, for the period 1878 to 2010 was 47.1 inches. In contrast, 2005 and 2010 were the 7th and 14th driest years on record in Little Rock with 34.55 and 36.52 inches, respectively; both tied as the hottest years ever recorded in Arkansas. The wettest year on record in Little Rock (2009) was interspersed within these dry years, with a total of 81.79 inches. Fifteen weather stations within the State ranked 2009 as the wettest year on record. Extremes in annual precipitation rates may lead to greater variability in groundwater recharge rates and water use, particularly in the agricultural areas in eastern Arkansas that rely heavily on groundwater produced from the Mississippi River Valley alluvial aquifer (hereafter referred to as the alluvial aquifer). How does this variability affect the groundwater system and water use therein? Are the effects of this variability discernable in measured water levels in wells? Czarnecki and Schrader examined these questions and provided some insights, the results of which are presented here.

Arkansas↗

Geomorphic, flood, and groundwater-flow characteristics of Bayfield Peninsula streams, Wisconsin, and implications for brook-trout habitat

In 2002–03, the U.S. Geological Survey conducted a study of the geomorphic, flood, and groundwater-flow characteristics of five Bayfield Peninsula streams, Wisconsin (Cranberry River, Bark River, Raspberry River, Sioux River, and Whittlesey Creek) to determine the physical limitations for brook-trout habitat. The goals of the study were threefold: (1) to describe geomorphic characteristics and processes, (2) to determine how land-cover characteristics affect flood peaks, and (3) to determine how regional groundwater flow patterns affect base flow. The geomorphic characterization consisted of analyses of historical aerial photographs and General Land Office Survey notes, observations from helicopter video footage, surveys of valley cross sections, and coring. Sources of sediment were identified from the helicopter video and field surveys, and past erosion-control techniques were evaluated. Geomorphic processes, such as runoff sediment erosion, transport, and deposition, are driven by channel location within the drainage network, texture of glacial deposits, and proximity to postglacial lake shorelines; these processes have historically increased because of decreases in upland forest cover and channel roughness. Sources of sediment for all studied streams mainly came from bank, terrace, or bluff erosion along main stem reaches and along feeder tributaries that bisect main-stem entrenched valley sides. Bluff, terrace, and bank erosion were the major sources of sediment to Whittlesey Creek and the Sioux River. No active bluff erosion was observed on the Cranberry River or the Bark River but anecdotal information suggests that landslides occasionally happen on the Cranberry River. For the Bark River, sources of sediment were somewhat evenly divided among road crossings (bridges, culverts, and unimproved forest lanes), terrace erosion, bank erosion, and incision along upper main stems and feeder channels along valley sides. Evaluation of past erosion-control techniques indicated that bluffs were stabilized by a combination of artificial hardening and bioengineering of the bluff base and reducing mass wasting of the tops of the bluffs. Flood hydrographs for the Cranberry River were simulated for four land-cover scenarios—late 20th century (1992–93), presettlement (before 1870), peak agriculture (1928), and developed (25 percent urban). Results were compared to previous simulations of flood peaks for Whittlesey Creek and for North Fish Creek (southern adjacent basin to Whittlesey Creek). Even though most uplands are presently forested, flood peaks simulated for 1992–93 were 1.5 to 2 times larger than presettlement flood peaks. The increased flood peaks caused (1) increased incision along upper main stems and tributaries that bisect entrenched valley sides, (2) bluff and terrace erosion along reaches with entrenched valleys, (3) overbank deposition and bar formation in middle and lower main stems, and (4) aggradation in mouth areas. A base-flow survey was conducted and a groundwater-flow model was developed for the Bayfield Peninsula to delineate groundwater contributing areas. A deep aquifer system, which includes thick deposits of sand and the upper part of the bedrock, is recharged through the permeable sands in the center of the peninsula. Base flow is unevenly distributed among the Bayfield streams and depends on the amount of channel incision and the proximity of the channels to the recharge area and coarse outwash deposits. Groundwater contributing areas for the five streams do not coincide with surface-water-contributing areas. About 89 percent of total recharge to the deep aquifer system discharges to Bayfield streams; the remaining 11 percent directly discharges to Lake Superior. Historical land-cover changes have had negligible effects on groundwater-flow from the deep aquifer system. Available brook-trout habitat is dependent on the locations of groundwater upwellings, the sizes of flood peaks, and sediment loads. Management practices that focus on reducing or slowing runoff from upland areas and increasing channel roughness have potential to reduce flood peaks, erosion, and sedimentation and improve brook-trout habitat in all Bayfield Peninsula streams.

Wisconsin↗

Transmissivity of the Upper Floridan aquifer in Florida and parts of Georgia, South Carolina, and Alabama

The Floridan aquifer system (FAS) covers an area of approximately 100,000 square miles in Florida and parts of Georgia, South Carolina, Alabama, and Mississippi. Groundwater wells for water supply were first drilled in the late 1800s and by the year 2000, the FAS was the primary source of drinking water for about 10 million people. One of the methods for assessing groundwater availability is the development of regional or subregional groundwater flow models of the aquifer system that can be used to develop water budgets spatially and temporally, as well as evaluate the groundwater resource change over time. Understanding the distribution of transmissivity within the FAS is critical to the development of groundwater flow models. The map presented herein differs from previously published maps of the FAS in that it is based on interpolation of 1,487 values of transmissivity. The transmissivity values in the dataset range from 8 to 9,000,000 feet squared per day (ft 2 /d) with the majority of the values ranging from 10,000 to 100,000 ft 2 /d. The wide range in transmissivity (6 orders of magnitude) is typical of carbonate rock aquifers, which are characterized by a wide range in karstification. Commonly, the range in transmissivity is greatest in areas where groundwater flow creates conduits in facies that dissolve more readily or areas of high porosity units that have interconnected vugs, with diameters greater than 0.1 foot. These are also areas where transmissivity is largest. Additionally, first magnitude springsheds and springs are shown because in these springshed areas, the estimates of transmissivity from interpolation may underestimate the actual range in transmissivity. Also shown is an area within the Gulf Trough in Georgia where high yielding wells are unlikely to be developed in the Upper Floridan aquifer. The interpolated transmissivity ranges shown on this map reflect the geologic structure and karstified areas. Transmissivity is large in the areas where the system is unconfined, such as west-central Florida and southwest Georgia just northwest of the Gulf Trough. Transmissivity is small along the Gulf Trough and Southwest Georgia Embayment (referred to as Apalachicola Embayment in some reports). Transmissivity is also small in the thin, updip part of the system near its northern boundary. Another area of large transmissivity coincides with the Southeast Georgia Embayment.

Alabama, Florida, Georgia, South Carolina↗

Occurrence and distribution of organic chemicals and nutrients and comparison of water-quality data from public drinking-water supplies in the Columbia aquifer in Delaware, 2000-08

The U.S. Geological Survey, in cooperation with the Delaware Department of Natural Resources and Environmental Control and the Delaware Geological Survey, conducted a groundwater-quality investigation to (a) describe the occurrence and distribution of selected contaminants, and (b) document any changes in groundwater quality in the Columbia aquifer public water-supply wells in the Coastal Plain in Delaware between 2000 and 2008. Thirty public water-supply wells located throughout the Columbia aquifer of the Delaware Coastal Plain were sampled from August through November of 2008. Twenty-two of the wells in the sampling network for this project were previously sampled in 2000. Eight new wells were selected to replace wells no longer in use. Groundwater collected from the wells was analyzed for the occurrence and distribution of selected pesticides, pesticide degradates, volatile organic compounds, nutrients, and major inorganic ions. Nine of the wells were analyzed for radioactive elements (radium-226, radium-228, and radon). Groundwater-quality data were compared for sites sampled in both 2000 and 2008 to document any changes in water quality. One or more pesticides were detected in samples from 29 of the 30 wells. There were no significant differences in pesticide and pesticide degradate concentrations and similar compounds were detected when comparing sampling results from 2000 and 2008. Pesticide and pesticide degradate concentrations were generally less than 1 microgram per liter. Twenty-four compounds, 14 pesticides, and 10 pesticide degradates were detected in at least one sample; the pesticide degradates, metolachlor ethanesulfonic acid, deethylatrazine, and alachlor ethanesulfonic acid were the most frequently detected compounds, each found in more than 50 percent of samples. Almost 80 percent of the detected pesticides were agricultural herbicides, which reflects the prevalence and wide distribution of agriculture in sampled areas, as well the dominance of agricultural pesticides among the target analytes for this study. No concentration of a pesticide or pesticide degradate exceeded any regulatory standard. Dieldrin, an insecticide that has been banned for several decades, was detected at a concentration that exceeded a non-regulatory health-based screening level of 0.002 micrograms per liter at nine sites. Volatile organic compounds (VOCs) were generally detected at concentrations of less than 1 microgram per liter, although 7 of the 31 detected VOCs had concentrations greater than 1 microgram per liter. There were no significant differences in VOC concentrations from 2000 to 2008; however, among the resampled wells, the mean number of VOCs detected per well was significantly different over the 8-year period. The number of VOCs detected per well decreased in 73 percent of the resampled wells; the decrease ranged from one to eight fewer detections in 2008 than in 2000. Chloroform and methyl tert-butyl ether were the most frequently detected VOCs, at 90 percent and 63 percent, respectively, among the 30 wells. Solvents were the most frequently detected class of VOCs. All measured concentrations of VOCs in groundwater were below established standards for drinking water and below other health-based guidelines. There were no significant differences in nutrient or major-ion concentrations between 2000 and 2008, however, the medians of two field measurements, pH and dissolved oxygen, were significantly higher in 2008 than in 2000 in the resampled wells. Although pH and dissolved oxygen were higher, water was still acidic and predominantly oxic. Nitrate was the predominant nutrient species in the Columbia aquifer, with a 90-percent detection frequency. The median nitrate concentration in groundwater was 4.88 milligrams per liter, which was slightly lower than, but not significantly different from, the median of 5.23 milligrams per liter for the 2000 samples. Concentrations of nitrate exceeded the U.S. Environmental Protection Agency's Maximum Contaminant Level or Federal drinking-water standard of 10 milligrams per liter as nitrogen in samples from two wells. Eight of the 30 wells sampled had iron or manganese concentrations that exceeded the U.S. Environmental Protection Agency's Secondary Maximum Contaminant Level; nine samples exceeded the Health Advisory Limit set by the Delaware Division of Public Health of 20 milligrams per liter for sodium in drinking water. Two radiochemical isotopes, radium-226 and radon-222, were detected in all nine groundwater samples analyzed; five samples had detectable levels of radium-228 activity. None of the samples exceeded the U.S Environmental Protection Agency's Maximum Contaminant Level for radium or radon in drinking water. Although radioactive elements were more frequently detected in 2008 than in 2000, this increased detection frequency is more likely due to lower detection levels in 2008 than 2000. The average age of groundwater entering the screens of the production wells sampled in 2008 ranged from 6 to 35 years, with a median groundwater age of 22 years. Groundwater age was positively correlated with well depth and negatively correlated with dissolved oxygen. Data from the 22 resampled wells indicate a significant positive difference in the average modeled groundwater-sample-age results. The average groundwater age from samples collected in 2008 was generally 7 years older than the average groundwater age from samples collected in 2000.

Delaware↗

Simulation of Reclaimed-Water Injection and Pumping Scenarios and Particle-Tracking Analysis near Mount Pleasant, South Carolina

The effect of injecting reclaimed water into the Middendorf aquifer beneath Mount Pleasant, South Carolina, was simulated using a groundwater-flow model of the Coastal Plain Physiographic Province of South Carolina and parts of Georgia and North Carolina. Reclaimed water, also known as recycled water, is wastewater or stormwater that has been treated to an appropriate level so that the water can be reused. The scenarios were simulated to evaluate potential changes in groundwater flow and groundwater-level conditions caused by injecting reclaimed water into the Middendorf aquifer. Simulations included a Base Case and two injection scenarios. Maximum pumping rates were simulated as 6.65, 8.50, and 10.5 million gallons per day for the Base Case, Scenario 1, and Scenario 2, respectively. The Base Case simulation represents a non-injection estimate of the year 2050 groundwater levels for comparison purposes for the two injection scenarios. For Scenarios 1 and 2, the simulated injection of reclaimed water at 3 million gallons per day begins in 2012 and continues through 2050. The flow paths and time of travel for the injected reclaimed water were simulated using particle-tracking analysis. The simulations indicated a general decline of groundwater altitudes in the Middendorf aquifer in the Mount Pleasant, South Carolina, area between 2004 and 2050 for the Base Case and two injection scenarios. For the Base Case, groundwater altitudes generally declined about 90 feet from the 2004 groundwater levels. For Scenarios 1 and 2, although groundwater altitudes initially increased in the Mount Pleasant area because of the simulated injection, these higher groundwater levels declined as Mount Pleasant Waterworks pumping increased over time. When compared to the Base Case simulation, 2050 groundwater altitudes for Scenario 1 are between 15 feet lower to 23 feet higher for production wells, between 41 and 77 feet higher for the injection wells, and between 9 and 23 feet higher for observation wells in the Mount Pleasant area. When compared to the Base Case simulation, 2050 groundwater altitudes for Scenario 2 are between 2 and 106 feet lower for production wells and observation wells and between 11 and 27 feet higher for the injection wells in the Mount Pleasant area. Water budgets for the model area immediately surrounding the Mount Pleasant area were calculated for 2011 and for 2050. The largest flow component for the 2050 water budget in the Mount Pleasant area is discharge through wells at rates between 7.1 and 10.9 million gallons of water per day. This groundwater is replaced predominantly by between 6.0 and 7.8 million gallons per day of lateral groundwater flow within the Middendorf aquifer for the Base Case and two scenarios and through reclaimed-water injection of 3 million gallons per day for Scenarios 1 and 2. In addition, between 175,000 and 319,000 gallons of groundwater are removed from this area per day because of the regional hydraulic gradient. Additional sources of water to this area are groundwater storage releases at rates between 86,800 and 116,000 gallons per day and vertical flow from over- and underlying confining units at rates between 69,100 and 150,000 gallons per day. Reclaimed water injected into the Middendorf aquifer at three hypothetical injection wells moved to the Mount Pleasant Waterworks production wells in 18 to 256 years as indicated by particle-tracking simulations. Time of travel varied from 18 to 179 years for simulated conditions of 20 percent uniform aquifer porosity and between 25 to 256 years for 30 percent uniform aquifer porosity.

South Carolina↗

A novel high-frequency groundwater quality monitoring system

High-frequency, long-term monitoring of water quality has revolutionized the study of surface waters in recent years. However, application of these techniques to groundwater has been limited by the ability to remotely pump and analyze groundwater. This paper describes a novel autonomous groundwater quality monitoring system which samples multiple wells to evaluate temporal changes and identify trends in groundwater chemistry. The system, deployed near Fresno, California, USA, collects and transmits high-frequency data, including water temperature, specific conductance, pH, dissolved oxygen, and nitrate, from supply and monitoring wells, in real-time. The system consists of a water quality sonde and optical nitrate sensor, manifold, submersible three-phase pump, variable frequency drive, data collection platform, solar panels, and rechargeable battery bank. The manifold directs water from three wells to a single set of sensors, thereby reducing setup and operation costs associated with multi-sensor networks. Sampling multiple wells at high frequency for several years provided a means of monitoring the vertical distribution and transport of solutes in the aquifer. Initial results show short period variability of nitrate, specific conductivity, and dissolved oxygen in the shallow aquifer, while the deeper portion of the aquifer remains unchanged—observations that may be missed with traditional discrete sampling approaches. In this aquifer system, nitrate and specific conductance are increasing in the shallow aquifer, while invariant changes in deep groundwater chemistry likely reflect relatively slow groundwater flow. In contrast, systems with high groundwater velocity, such as karst aquifers, have been shown to exhibit higher-frequency groundwater chemistry changes. The stability of the deeper aquifer over the monitoring period was leveraged to develop estimates of measurement system uncertainty, which were typically lower than the manufacturer’s stated specifications, enabling the identification of subtle variability in water chemistry that may have otherwise been missed.

California↗