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At least 991 records · Page 55Linked to original sources

A submarine landslide source for the devastating 1964 Chenega tsunami, southern Alaska

During the 1964 Great Alaska earthquake (M w 9.2), several fjords, straits, and bays throughout southern Alaska experienced significant tsunami runup of localized, but unexplained origin. Dangerous Passage is a glacimarine fjord in western Prince William Sound, which experienced a tsunami that devastated the village of Chenega where 23 of 75 inhabitants were lost – the highest relative loss of any community during the earthquake. Previous studies suggested the source of the devastating tsunami was either from a local submarine landslide of unknown origin or from coseismic tectonic displacement. Here we present new observations from high-resolution multibeam bathymetry and seismic reflection surveys conducted in the waters adjacent to the village of Chenega. The seabed morphology and substrate architecture reveal a large submarine landslide complex in water depths of 120–360 m. Analysis of bathymetric change between 1957 and 2014 indicates the upper 20–50 m ( ∼ 0.7 km 3 ) of glacimarine sediment was destabilized and evacuated from the steep face of a submerged moraine and an adjacent ∼ 21 km 2 perched sedimentary basin. Once mobilized, landslide debris poured over the steep, 130 m-high face of a deeper moraine and then blanketed the terminal basin ( ∼ 465 m water depth) in 11 ± 5 m of sediment. These results, combined with inverse tsunami travel-time modeling, suggest that earthquake- triggered submarine landslides generated the tsunami that struck the village of Chenega roughly 4 min after shaking began. Unlike other tsunamigenic landslides observed in and around Prince William Sound in 1964, the failures in Dangerous Passage are not linked to an active submarine delta. The requisite environmental conditions needed to generate large submarine landslides in glacimarine fjords around the world may be more common than previously thought.

Alaska↗

Mobilization of lead and other trace elements following shock chlorination of wells

Many owners of domestic wells shock chlorinate their wells to treat for bacterial contamination or control bad odors from sulfides. Analysis of well water with four wells from Fallon, Nevada, showed that following recommended procedures for shock chlorinating wells can cause large, short-lasting increases in trace-element concentrations in ground water, particularly for Cu, Fe, Pb, and Zn. Lead concentrations increased up to 745 fold between samples collected just before the well was shock chlorinated and the first sample collected 22-24??h later; Zn concentrations increased up to 252 fold, Fe concentrations increased up to 114 fold, and Cu concentrations increased up to 29 fold. Lead concentrations returned to near background levels following pumping of about one casing volume, however, in one well an estimated 120??mg of excess Pb were pumped before concentrations returned to prechlorination levels. Total Pb concentrations were much greater than filtered (0.45????m) concentrations, indicating the excess Pb is principally particulate. Recommended procedures for purging treated wells following shock chlorination may be ineffective because a strong NaOCl solution can remain in the casing above the pump even following extended pumping. Only small changes in gross alpha and beta radioactivity occurred following shock chlorination. USEPA has not promulgated drinking-water standards for 210Pb, however, measured 210Pb activities in the study area typically were less than the Canadian Maximum Acceptable Concentration of 100??mBq/L. By consuming well water shortly after shock chlorination the public may inadvertently be exposed to levels of Pb, and possibly 210Pb, that exceed drinking-water standards.

Science of the Total Environment↗

Wet deposition of fission-product isotopes to North America from the Fukushima Dai-ichi incident, March 2011

Using the infrastructure of the National Atmospheric Deposition Program (NADP), numerous measurements of radionuclide wet deposition over North America were made for 167 NADP sites before and after the Fukushima Dai-ichi Nuclear Power Station incident of March 12, 2011. For the period from March 8 through April 5, 2011, wet-only precipitation samples were collected by NADP and analyzed for fission-product isotopes within whole-water and filterable solid samples by the United States Geological Survey using gamma spectrometry. Variable amounts of 131 I, 134 Cs, or 137 Cs were measured at approximately 21% of sampled NADP sites distributed widely across the contiguous United States and Alaska. Calculated 1- to 2-week individual radionuclide deposition fluxes ranged from 0.47 to 5100 Becquerels per square meter during the sampling period. Wet deposition activity was small compared to measured activity already present in U.S. soil. NADP networks responded to this complex disaster, and provided scientifically valid measurements that are comparable and complementary to other networks in North America and Europe.

Environmental Science & Technology↗

Phyllosilicate diversity and past aqueous activity revealed at Mawrth Vallis, Mars

Observations by the Mars Reconnaissance Orbiter/Compact Reconnaissance Imaging Spectrometer for Mars in the Mawrth Vallis region show several phyllosilicate species, indicating a wide range of past aqueous activity. Iron/magnesium (Fe/Mg)-smectite is observed in light-toned outcrops that probably formed via aqueous alteration of basalt of the ancient cratered terrain. This unit is overlain by rocks rich in hydrated silica, montmorillonite, and kaolinite that may have formed via subsequent leaching of Fe and Mg through extended aqueous events or a change in aqueous chemistry. A spectral feature attributed to an Fe2+ phase is present in many locations in the Mawrth Vallis region at the transition from Fe/Mg-smectite to aluminum/silicon (Al/Si)-rich units. Fe2+-bearing materials in terrestrial sediments are typically associated with microorganisms or changes in pH or cations and could be explained here by hydrothermal activity. The stratigraphy of Fe/Mg-smectite overlain by a ferrous phase, hydrated silica, and then Al-phyllosilicates implies a complex aqueous history.

Science↗

Inexpensive automated paging system for use at remote research sites

The use of a flow-activated automatic sampler at a remote research site required personnel to periodically visit the site to collect samples and reset the automatic sampler. To reduce site visits, a cellular telephone was modified for activation by a datalogger. The purpose of this study was to demonstrate the use and benefit of the modified telephone. Both the power switch and the speed-dial button on the telephone were bypassed and wired to a relay driver. The datalogger was programmed to compare values of a monitored environmental parameter with a target value. When the target value was reached or exceeded, the datalogger pulsed a relay driver, activating power to the telephone. A separate relay activated the speed dial, dialing the number of a tone-only pager. The use of this system has saved time and reduced travel costs by reducing the number of trips to the site, without the loss of any data.The use of a flow-activated automatic sampler at a remote research site required personnel to periodically visit the site to collect samples and reset the automatic sampler. To reduce site visits, a cellular telephone was modified for activation by a datalogger. The purpose of this study was to demonstrate the use and benefit of the modified telephone. Both the power switch and the speed-dial button on the telephone were bypassed and wired to a relay driver. The datalogger was programmed to compare values of a monitored environmental parameter with a target value. When the target value was reached or exceeded, the datalogger pulsed a relay driver, activating power to the telephone. A separate relay activated the speed dial, dialing the number of a tone-only pager. The use of this system has saved time and reduced travel costs by reducing the number of trips to the site, without the loss of any data.

Soil Science Society of America Journal↗

Bird populations on the Island of Tinian: persistence despite wholesale loss of native forests

Bird habitat on the island of Tinian, Mariana Islands, has been substantially altered, and only around 5% of the island has native forest today. The modern bird fauna is likely to be a subset of the original avifauna where only species tolerant to native forest loss and human disturbance have survived. Avian surveys were conducted on the island in 2008 by the U.S. Fish and Wildlife Service to provide current densities and abundances of the remaining species, and assess population trends using data collected from previous surveys. During the three surveys (1982, 1996, and 2008), 18 species were detected, and abundances and trends were assessed for 11 species. Five of the nine native species and one alien bird have increased since 1982. Three native birds—Mariana Fruit-Dove ( Ptilinopus roseicapilla ), Micronesian Honeyeater ( Myzomela rubratra ), and Tinian Monarch ( Monarcha takatsukasae )—have decreased since 1982. Trends for the remaining two birds (one native and one alien) were considered relatively stable. Only five birds, including the Tinian Monarch, showed significant differences among regions of Tinian by year. Increased development on Tinian may result in increases in habitat clearing and expansion of human-dominated habitats, and declines in some bird populations would likely continue or be exacerbated with these actions. Expanded development activities on Tinian would also mean increased cargo movement between Guam and Tinian, elevating the probability of transporting the Brown Tree Snake ( Boiga irregularis ) to Tinian, which would lead to precipitous decreases and extinctions.

Hawai'i↗

Hydrogeologic processes in saline systems: Playas, sabkhas, and saline lakes

Pans, playas, sabkhas, salinas, saline lakes, and salt flats are hydrologically similar, varying only in their boundary conditions. Thus, in evaluating geochemical processes in these systems, a generic water and solute mass-balance approach can be utilized. A conceptual model of a coastal sabkha near the Arabian Gulf is used as an example to illustrate the various water and solute fluxes. Analysis of this model suggests that upward flux of ground water from underlying formations could be a major source of solutes in the sabkha, but contribute only a small volume of the water. Local rainfall is the main source of water in the modeled sabkha system with a surprisingly large recharge-to-rainfall ratio of more than 50%. The contribution of seawater to the solute budget depends on the ratio of the width of the supratidal zone to the total width and is generally confined to a narrow zone near the shoreline of a typical coastal sabkha. Because of a short residence time of water, steady-state flow is expected within a short time (<100 years), while steady state for solutes may take much longer (>50,000 years). The solute composition of the brine in a closed saline system depends largely on the original composition of the input water. The high total ion content in the brine limits the efficiency of water-rock interaction and absorption. Because most natural systems are hydrologically open, the chemistry of the brines and the associated evaporite deposits may be significantly different than that predicted for hydrologically closed systems. Seasonal changes in temperature of the unsaturated zone cause precipitation of minerals in saline systems undergoing evaporation. Thus, during the hot dry season months, minerals exhibit retrograde solubility so that gypsum, anhydrite and calcite precipitate. Evaporation near the surface is also a major process that causes mineral precipitation in the upper portion of the unsaturated zone (e.g. halite and carnallite), provided that the relative humidity of the atmosphere is less than the activity of water. The slope of the fresh/brine-water interface in saline lake systems is shallower than in fresh/seawater interface because of the greater density difference between the fresh/brine-water bodies. The interface between sabkha brines and seawater slopes seaward, unlike normal marine-fresh water systems that slope landward. Moreover, the brine/seawater interface does not achieve steady state because it is pushed toward the sea by the sabkha's brine. ?? 2002 Elsevier Science B.V. All rights reserved.

Earth-Science Reviews↗

Highly specialized recreationists contribute the most to the citizen science project eBird

Contributory citizen science projects (hereafter “contributory projects”) are a powerful tool for avian conservation science. Large-scale projects such as eBird have produced data that have advanced science and contributed to many conservation applications. These projects also provide a means to engage the public in scientific data collection. A common challenge across contributory projects like eBird is to maintain participation, as some volunteers contribute just a few times before disengaging. To maximize contributions and manage an effective program that has broad appeal, it is useful to better understand factors that influence contribution rates. For projects capitalizing on recreation activities (e.g., birding), differences in contribution levels might be explained by the recreation specialization framework, which describes how recreationists vary in skill, behavior, and motives. We paired data from a survey of birders across the United States and Canada with data on their eBird contributions (n = 28,926) to test whether those who contributed most are more specialized birders. We assigned participants to 4 contribution groups based on eBird checklist submissions and compared groups’ specialization levels and motivations. More active contribution groups had higher specialization, yet some specialized birders were not active participants. The most distinguishing feature among groups was the behavioral dimension of specialization, with active eBird participants owning specialized equipment and taking frequent trips away from home to bird. Active participants had the strongest achievement motivations for birding (e.g., keeping a life list), whereas all groups had strong appreciation motivations (e.g., enjoying the sights and sounds of birding). Using recreation specialization to characterize eBird participants can help explain why some do not regularly contribute data. Project managers may be able to promote participation, particularly by those who are specialized but not contributing, by appealing to a broader suite of motivations that includes both appreciation and achievement motivations, and thereby increase data for conservation.

Ornithological Applications↗

Analyzing stakeholder preferences for managing elk and bison at the National Elk Refuge and Grand Teton National Park: An example of the disparate stakeholder management approach

The U.S. Fish and Wildlife Service (FWS) and the National Park Service (NPS) are preparing a management plan for bison and elk inhabiting the National Elk Refuge (NER) and Grand Teton National Park (GTNP) near Jackson Hole, Wyoming. A management plan is needed to evaluate current and possible changes to habitat management, disease management, winter feeding and hunting programs related to the NER and GTNP. In order to make good decisions, managers need to incorporate the opinions and values of the involved stakeholders as well as understand the complex institutional constraints and opportunities that influence the decision making process. Federal, state, local, private and public stakeholders have diverse values and preferences about how to use and manage resources, and underlying institutional factors give certain stakeholders more influence over the outcome. How stakeholders use their influence can greatly affect the time, effort and costs of the decision making process. The overall result will depend both on the stakeholder&rsquo;s relative power and level of conviction for their preferences. Many programs and tools have been developed by different disciplines to facilitate group negotiation and decision making. Three examples are relevant here. First, decision analysis models such as the Analytical Hierarchy Process (AHP) are commonly used to prioritize the goals and objectives of stakeholders&rsquo; preferences for resource planning by formally structuring conflicts and assisting decision makers in developing a compromised solution (Forman, 1998). Second, institutional models such as the Legal Institutional Analysis Model (LIAM) have been used to describe the organizational rules of behavior and the institutional boundaries constraining management decisions (Lamb and others, 1998). Finally, public choice models have been used to predict the potential success of rent-seeking activity (spending additional time and money to exert political pressure) to change the political rules (Becker, 1983). While these tools have been successful at addressing various pieces of the natural resource decision making process, their use in isolation is not enough to fully depict the complexities of the physical and biological systems with the rules and constraints of the underlying economic and political systems. An approach is needed that combines natural sciences, economics, and politics.

Wyoming↗

Mortality and cholinesterase inhibition in butterflies following aerial naled applications for mosquito control on the National Key Deer Refuge

Natural resource managers are concerned about the impacts of aerial ultra-low volume spray (ULV) of insecticides for mosquito control (i.e., mosquito adulticides) and seek science-driven management recommendations that reduce risk but allow vector control for nearby human populations. Managers at the National Key Deer Refuge (Florida Keys, FL) are concerned for ULV effects upon conservation efforts for imperiled butterflies (Florida leafwing [ Anaea troglodyta floridalis ] and Bartram’s hairstreak [ Strymon acis bartrami ] butterflies). No-spray zones were designated for protection of those butterflies, but their effectiveness for mitigation is unclear. To address this uncertainty, cholinesterase activity (ChE) and mortality were monitored for caged butterflies gulf fritillary [ Agraulis vanilla ] and great southern white [ Ascia monuste ]) deployed on the Refuge during three aerial ULV applications of the insecticide naled. Residue samplers also were deployed to estimate butterfly exposure. Spray efficacy against mosquitoes was assessed by deploying caged mosquitoes at the same locations as the butterflies. Average naled residue levels on filter paper samplers in the target area (1882–2898 µg/m 2 ) was significantly greater than in the no-spray zone (9–1562 µg/m 2 ). Differences between the no-spray zone and target area for butterfly mortality and ChE were inconsistent. Average mortality was significantly lower, and average ChE was significantly higher in the no-spray zone for larvae of one species but not for larvae of the other species. Mosquito mortality did not differ significantly between the two areas. Data from the present study reflect the inconsistent effectiveness of no-spray zones on the Refuge using standard methods employed at the time by the vector control agency in the Florida Keys and possibly by other vector control agencies in similar coastal environments. Furthermore, these findings helped to guide the design and to improve the conservation value of future no-spray zone delineations while allowing for treatment in areas where mosquito control is necessary for vector-borne disease reduction.

Florida↗

Radium and radon in Charlotte Harbor Estuary, Florida

Radium-226 and 222 Rn activities are greater in the estuarine waters of northern Charlotte Harbor and the lower tidal Peace and Myakka Rivers, Florida, than in either the freshwater reaches of the rivers or waters of the lower estuary and the Gulf of Mexico. The activity of 226 Ra in the tidal rivers increases with decreasing river inflow, with a maximum value of 548 dpm 1001 −1 measured in the tidal Myakka River. The source of the high activity of 226 Ra and 222 Rn is predominantly ground water inflow. Because of the large ground water input, the contribution of 226 Ra from suspended and bottom sediments is a smaller fraction of the total 226 Ra input than in many other estuaries. Although ground water 226 Ra activity in the area varies widely, we estimate that artesian ground water inflow to the tidal rivers is similar in magnitude to the flow of the rivers above the tidal reach during the dry season.

Florida↗

An astrobiological perspective on Meridiani Planum

Sedimentary rocks exposed in the Meridiani Planum region of Mars record aqueous and eolian deposition in ancient dune and interdune playa-like environments that were arid, acidic, and oxidizing. On Earth, microbial populations have repeatedly adapted to low pH and both episodic and chronic water limitation, suggesting that, to a first approximation, the Meridiani plain may have been habitable during at least part of the interval when deposition and early diagenesis took place. On the other hand, the environmental conditions inferred for Meridiani deposition would have posed a challenge for prebiotic chemical reactions thought to have played a role in the origin of life on Earth. Orbital observations suggest that the combination of sulfate minerals and hematite found in Meridiani rocks may be unusual on the martian surface; however, there is reason to believe that acidity, aridity, and oxidizing conditions were broadly distributed on ancient Mars. When these conditions were established and how much environmental heterogeneity existed on early Mars remain to be determined. Because sulfates and iron oxides can preserve detailed geochemical records of environmental history as well as chemical, textural and microfossil signatures of biological activity, Meridiani Planum is an attractive candidate for Mars sample return. ?? 2005 Elsevier B.V. All rights reserved.

Earth and Planetary Science Letters↗

Past climate variability and change in the Arctic and at high latitudes

Paleoclimate records play a key role in our understanding of Earth's past and present climate system and in our confidence in predicting future climate changes. Paleoclimate data help to elucidate past and present active mechanisms of climate change by placing the short instrumental record into a longer term context and by permitting models to be tested beyond the limited time that instrumental measurements have been available.

Synthesis and Assessment Product↗

The importance of wetland carbon dynamics to society: Insight from the Second State of the Carbon Cycle Science Report

The Second State of the Carbon Cycle Report (SOCCR2) culminated in 19 chapters that spanned all North American sectors – from Energy Systems to Agriculture and Land Use – known to be important for understanding carbon (C) cycling and accounting. Wetlands, both inland and coastal, were found to be significant components of C fluxes along the terrestrial to aquatic hydrologic continuum. In this chapter, we synthesize the role of wetlands in the overall C footprint of North America (from Canada to Mexico) as one metric of the societal values placed on these terrestrial-aquatic interfaces. We also summarize the effects of management activities and climate change on the wetland C cycle and give some perspectives on the current and future importance of wetlands to society.

Geophysical Monograph Series↗

The state of the science and practice of stream restoration in the Chesapeake: Lessons learned to inform better implementation, assessment and outcomes

The Chesapeake Bay Program’s (CBP) Science and Technical Advisory Committee (STAC) organized and led a workshop on the science and practice of stream restoration in order to summarize the state of knowledge in order to identify ways to improve stream restoration outcomes. The workshop identified a general framework for explaining the main factors leading to stream restoration outcomes: stream degradation has occurred, leading to regulatory and policy motivations that prioritize project goals, which leads to restoration approaches, assessment and monitoring efforts, and ultimately stream restoration outcomes. In the Chesapeake Bay watershed, stream restoration often occurs in response to Clean Water Act (CWA) mandates to reduce nitrogen, phosphorus, and sediment loads to the Bay. Reviews of stream restoration outcomes summarized at the workshop showed that, in general, stream restorations have led to minimal improvement to stream aquatic biota, effective ‘stabilization’ of channel form over time, moderate improvements to water quality, and short-term negative impacts to riparian vegetation. The fundamental finding of the workshop was that often the primary goal of stream restoration projects is to improve geomorphic stability in the restored reach and downstream water quality, and not to improve local ecological conditions through ‘uplift’ (improvement of one or more ecosystem functions through a restorative activity; a term defined in Appendix D), and therefore these projects often do not improve aquatic macroinvertebrate or fish communities. This conflict in goals is a shortcoming of the currently most common regulatory driver for stream restoration (reducing downstream loads of N, P, and sediment) that could be addressed directly through diversifying goals to include biotic uplift, as biological benefit is an assumed condition for the permitting and crediting of stream restoration projects. It is also likely that current understanding of stressors and drivers of stream ecosystem health is insufficient, and that reach-scale restoration focused on geomorphic restoration is not removing the actual sources of stream health impairment that may arise in the upstream watershed. More science could help to identify how to improve the ecological condition of streams through management. The outcome of stream restoration monitoring has revealed that while geomorphic and hydrodynamic functions of stream restoration projects may be achieved, biotic stream function improvements remain elusive. As such, ensuring uplift may be achieved by avoiding restoration projects that risk resources in higher-quality streams and riparian corridors. Reach-scale restoration often does not effectively mitigate the watershed-scale stressors of stream ecosystems. If a desired outcome of stream restoration includes ecological uplift, then focusing efforts on improving stream ecology could help meet that goal.

Chesapeake Bay watershed↗

Atypical pit craters on Mars: new insights from THEMIS, CTX and HiRISE observations

More than 100 pit craters in the Tharsis region of Mars exhibit morphologies, diameters and thermal behaviors that diverge from the much larger bowl-shaped pit craters that occur in most regions across Mars. These Atypical Pit Craters (APCs) generally have sharp and distinct rims, vertical or overhanging walls that extend down to their floors, surface diameters of ~50-350 m, and high depth-to-diameter (d/D) ratios that are usually greater than 0.3 (which is an upper-range value for impacts and bowl-shaped pit craters), and can exceed values of 1.8. Observations by the Mars Odyssey THermal Emission Imaging System (THEMIS) show that APC floor temperatures are warmer at night, and fluctuate with much lower diurnal amplitudes than nearby surfaces or adjacent bowl-shaped pit craters. Kīlauea volcano, Hawai'i, hosts pit craters that formed through subsurface collapse into active volcanic dikes, resulting in pits that can appear morphologically analogous to either APCs or bowl-shaped pit craters. Partially-drained dikes are sometimes exposed within the lower walls and floors of these terrestrial APC analogs and can form extensive cave systems with unique microclimates. Similar caves in martian pit craters are of great interest for astrobiology. This study uses new observations by the Mars Reconnaissance Orbiter (MRO) High Resolution Imaging Science Experiment (HiRISE) and Context Camera (CTX) to refine previous work where seven APCs were described from lower-resolution THEMIS visible-wavelength (VIS) observations. Here, we identify locations of 115 APCs, map their distribution across the Tharsis region, characterize their internal morphologies with high-resolution observations, and discuss possible formation mechanisms.

Journal of Geophysical Research↗

Catalogue of polar bear (Ursus maritimus) maternal den locations in the Beaufort Sea and neighboring regions, Alaska, 1910–2010

This report presents data on the approximate locations and methods of discovery of 392 polar bear ( Ursus maritimus ) maternal dens found in the Beaufort Sea and neighboring regions between 1910 and 2010 that are archived by the U.S. Geological Survey, Alaska Science Center, Anchorage, Alaska. A description of data collection methods, biases associated with collection method, primary time periods, and spatial resolution are provided. Polar bears in the Beaufort Sea and nearby regions den on both the sea ice and on land. Standardized VHF surveys and satellite radio telemetry data provide a general understanding of where polar bears have denned in this region over the past 3 decades. Den observations made during other research activities and anecdotal reports from other government agencies, coastal residents, and industry personnel also are reported. Data on past polar bear maternal den locations are provided to inform the public and to provide information for natural resource agencies in planning activities to avoid or minimize interference with polar bear maternity dens.

Alaska↗

De facto water reuse: Bioassay suite approach delivers depth and breadth in endocrine active compound detection

Although endocrine disrupting compounds (EDCs) have been detected in wastewater and surface waters worldwide using a variety of in vitro effects-based screening tools, e.g. bioassays, few have examined potential attenuation of environmental contaminants by both natural (sorption, degradation, etc) and anthropogenic (water treatment practices) processes. This study used several bioassays and quantitative chemical analyses to assess residence-time weighted samples at six sites along a river in the northeastern United States beginning upstream of a waste water treatment plant (WWTP) outfall and proceeding downstream along the stream reach to a drinking water treatment plant (DWTP). Known steroidal estrogens were quantified and changes in signaling pathway molecular initiating events (activation of estrogen, androgen, glucocorticoid, peroxisome proliferator-activated, pregnane X receptor, and aryl hydrocarbon receptor signaling networks) were identified in water extracts. In initial multi-endpoint assays geographic and receptor-specific endocrine activity patterns in transcription factor signatures and nuclear receptor activation were discovered. In subsequent single endpoint receptor-specific bioassays, estrogen (16 of 18 samples; 0.01 to 28 ng estradiol equivalents [E2Eqs]/L) glucocorticoid (3 of 18 samples; 1.8 to 21 ng dexamethasone equivalents [DexEqs]/L), and androgen (2 of 18 samples; 0.95 to 2.1 ng dihydrotestosterone equivalents [DHTEqs]/L) receptor transcriptional activation occurred above respective assay method detection limits (0.04 ng E2Eqs/L, 1.2 ng DexEqs/L, and 0.77 ng DHTEqs/L) in multiple sampling events. Estrogen activity, the most often detected, correlated well with measured concentrations of known steroidal estrogens (R2 = 0.890). Overall, activity indicative of multiple types of endocrine active compounds was highest in wastewater effluent samples, while activity downstream was progressively lower, and negligible in (unfinished) treated water. This multiple bioassay approach, in conjunction with targeted analytical chemistry methods, has gained acceptance among water quality screening programs. Not only was estrogenic and glucocorticoid activity confirmed in the effluent by utilizing multiple methods concurrently, but other activated signaling networks that historically received less attention (i.e. peroxisome proliferator-activated receptor) were also detected.

Science of the Total Environment↗