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At least 991 records · Page 55Linked to original sources
USGS1985

Cyclic variations in calcium carbonate and organic carbon in Miocene to Holocene sediments, Walvis Ridge, South Atlantic Ocean

The entire upper Miocene to Holocene sedimentary sequence recovered in a hydraulic piston core at DSDP Site 532 on Walvis Ridge shows distinct cycles in amount of CaCO sub(3) that correlate with dark and light cycles of sediment color. The average periodicities of the carbonate cycles for the Quaternary, upper Pliocene, and lower Pliocene are about 35, 46, and 28 ky, respectively, with an overall average of about 36 ky for the last 5 my. Most minima in carbonate abundance correspond to dark parts of the color cycles, and most maxmia in carbonate abundance correspond to dark parts of color cycles, The darker parts of the color cycle usually contain higher concentrations of organic carbon, but organic carbon does not follow the color cycles in detail. Organic carbon cycles were analyzed only for the last 2.5 my, and for this interval they have an average periodicity of about 34 ky. The carbonate and color cycles persist through more than 5my during which major changes in relative proportions of siliceous-biogenic, calcareous- biogenic and terrigenous- clastic components occurent in response to climate change and to the waxing and waning of the Benguela Current upwelling systems off southwest Africa. The cyclic nature of these sediments probably is the result of dilution by terrigrnous clastic material and not dissolution of carbonate. We believe that the forcing mechanisms that produced the cycliclity was external to the area of site 532. Because of the similarity among the periodicities of the Walvis Ridge cycles and those of carbonate cycles in the northeastern Atlantic, Caribbean and eastern equatorial Pacific, these cycles probably are responses to global events. We conclude that fluctuations om global sea level with an average period of about 36 ky during the last 5 my caused variations in influx of terrigenous clastic materials from the Africans continental margin

Book chapter↗
USGS2005

Scanning electron microscope studies of some early Miocene diatoms from the equatorial Pacific Ocean with descriptions of two new species, Actinocyclus jouseae Barron and Actinocyclus nigriniae Barron

Scanning electron microscope (SEM) and light microscope (LM) studies are used to propose and describe two new species, Actinocyclus jouseae Barron , sp. nov. and Actinocyclus nigriniae Barron , sp. nov. from lower Miocene sediments from equatorial Pacific ODP Site 1219. Parallel SEM and LM studies reveal that Thalassiosira bukryi Barron should be transferred to Azpeitia and suggest that Actinocyclus barronii Radionova is likely to be a variety of A. radionovae Barron

Proceedings of the California Academy of Sciences ↗
USGS2023

Geology of the Mount Rogers area, revisited: Evidence of Neoproterozoic continental rifting, glaciation, and the opening and closing of the Iapetus Ocean, Blue Ridge, VA–NC–TN

Recent field and geochronological studies in eight 7.5-minute quadrangles near Mount Rogers in Virginia, North Carolina and Tennessee recognize (1) important stratigraphic and structural relationships for the Neoproterozoic Mount Rogers and Konnarock Formations, and the northeast end of the Mountain City window; (2) the separation of Mesoproterozoic rocks of the Blue Ridge into three age groups; and (3) the timing and emplacement of the Blue Ridge thrust sheet. The study area includes folded and faulted Paleozoic strata of the Valley and Ridge in the northwest juxtaposed by metamorphic and igneous rocks of the Blue Ridge to the southeast. In the Valley and Ridge, Cambrian to Middle Ordovician carbonate and clastic rocks are exposed in a syncline in the Pulaski thrust sheet; these rocks are overridden by the Blue Ridge thrust sheet. The northeast end of the Mountain City window is interpreted as a simple window; the Stone Mountain fault is folded and continues as the Iron Mountain fault on the NW-side of the window. The Stone Mountain fault does not exist at the surface to the NE near the Razor Ridge volcanic center. Instead, a continuous section of Proterozoic gneisses, Mount Rogers Formation, Konnarock Formation and Chilhowee Group is now recognized. Rhyolites of the Mount Rogers Formation range from 760–749Ma, with detrital zircon age populations from associated volcaniclastic rocks indicating magmatism and rifting began by ~780 Ma. Rhyolite outliers in the Konnarock Formation and a change from rift-related clastic rocks of the Mount Rogers Formation transitioning to maroon laminites, mudstones and laminites with dropstones, suggest that the Konnarock Formation may be as old as ~751 Ma. Mesoproterozoic crystalline rocks of the Blue Ridge, previously referred to as the Cranberry Gneiss, are distinguished based on field relationships and SHRIMP U–Pb zircon geochronology: (1) ~1.33 Ga pre-Grenvillian crust; (2) 1190–1140 Ma granitoids (early magmatic suite); and (3) 1075–1030 Ma granitoids (late magmatic suite). Multiple greenschist-facies high-strain zones, including the 2–11 km wide Fries high-strain zone, occur in the Blue Ridge thrust sheet. Fabrics across the Fries and Gossan Lead faults have similar orientations and NW–directed contractional deformation. 40 Ar/ 39 Ar hornblende, muscovite, and K-feldspar ages indicate the western and eastern Blue Ridge had different thermal histories. The eastern Blue Ridge (Gossan Lead thrust sheet) experienced a 360–340 Ma amphibolite facies event prior to juxtaposition with the western Blue Ridge. 40 Ar/ 39 Ar muscovite ages in western Blue Ridge rocks document greenschist facies metamorphism and deformation and emplacement of the Blue Ridge thrust sheet at ~340 Ma; the Catface and Fries faults are tentatively interpreted to be contemporaneous. After initial emplacement of the Blue Ridge thrust sheet at ~340 Ma, shortening was accommodated by westward translation along the basal decollement, which carried the Blue Ridge thrust sheet to its current position.

North Carolina, Tennessee, Virginia↗
USGS2003

Global occurrence of tellurium-rich ferromanganese crusts and a model for the enrichment of tellurium

Hydrogenetic ferromanganese oxyhydroxide crusts (Fe-Mn crusts) precipitate out of cold ambient ocean water onto hard-rock surfaces (seamounts, plateaus, ridges) at water depths of about 400 to 4000 m throughout the ocean basins. The slow-growing (mm/Ma) Fe-Mn crusts concentrate most elements above their mean concentration in the Earth’s crust. Tellurium is enriched more than any other element (up to about 50,000 times) relative to its Earth’s crustal mean of about 1 ppb, compared with 250 times for the next most enriched element. We analyzed the Te contents for a suite of 105 bulk hydrogenetic crusts and 140 individual crust layers from the global ocean. For comparison, we analyzed 10 hydrothermal stratabound Mn-oxide samples collected from a variety of tectonic environments in the Pacific. In the Fe-Mn crust samples, Te varies from 3 to 205 ppm, with mean contents for Pacific and Atlantic samples of about 50 ppm and a mean of 39 ppm for Indian crust samples. Hydrothermal Mn samples have Te contents that range from 0.06 to 1 ppm. Continental margin Fe-Mn crusts have lower Te contents than open-ocean crusts, which is the result of dilution by detrital phases and differences in growth rates of the hydrogenetic phases. Correlation coefficient matrices show that for hydrothermal deposits, Te has positive correlations with elements characteristic of detrital minerals. In contrast, Te in open-ocean Fe-Mn crusts usually correlates with elements characteristic of the MnO 2 , carbonate fluorapatite, and residual biogenic phases. In continental margin crusts, Te also correlates with FeOOH associated elements. In addition, Te is negatively correlated with water depth of occurrence and positively correlated with crust thickness. Q-mode factor analyses support these relationships. However, sequential leaching results show that most of the Te is associated with FeOOH in Fe-Mn crusts and ≤10% is leached with the MnO 2 . Thermodynamic calculations indicate that Te occurs predominantly as H 5 TeO 6 − in ocean water. The speciation of Te in ocean water and charge balance considerations indicate that Te should be scavenged by FeOOH, which is in agreement with our leaching results. The thermodynamically more stable Te(IV) is less abundant by factors of 2 to 3.5 than Te(VI) in ocean water. This can be explained by preferential (not exclusive) scavenging of Te(IV) by FeOOH at the Fe-Mn crust surface and by Fe-Mn colloids in the water column. We propose a model in which the extreme enrichment of Te in Fe-Mn crusts is likely the result of an oxidation reaction on the surface of FeOOH. A similar oxidation process has been confirmed for Co, Ce, and Tl at the surface of MnO 2 in crusts, but has not been suggested previously to occur in association with FeOOH in Fe-Mn crusts. Mass-balance considerations indicate that ocean floor Fe-Mn deposits are the major sink for Te in the oceans. The concentration and redox chemistry of Te in the global ocean are likely controlled by scavenging on Fe-Mn colloids in the water column and Fe-Mn deposits on the ocean floor, as is also the case for Ce.

Geochimica et Cosmochimica Acta↗
USGS1969

Mesozoic California and the underflow of Pacific mantle

The Mesozoic evolution of California is interpreted as dominated by the underflow of oceanic mantle beneath the continental margin. Underflow during part of Late Cretaceous time of more than 2000 km of the eastern Pacific plate seems required by the marine magnetic data. Correspondingly, varied oceanic environments—abyssal hill, island arc, trench, oceanic crust, and upper mantle, perhaps also continental rise and abyssal plain—appear to be represented in the eugeosynclinal terranes of California. The rock juxtapositions accord with the concept that these materials were scraped off against the continent as the oceanic plate slid beneath it along Mesozoic Benioff seismic zones, which are now seen as serpentine belts separating profoundly different rock assemblages. The chaotic Franciscan Formation of coastal California consists of deep-ocean Late Jurassic to Late Cretaceous sedimentary, volcanic, crustal, and mantle materials. As open-ocean abyssal oozes and the oceanic crust beneath them were swept into the Benioff-zone trench at the continental margin, they were covered by terrigenous clastic sediments, and the entire complex was carried beneath the correlative continental-shelf and continental-slope deposits (Great Valley sequence) and the older Mesozoic complexes. The other eugeosynclinal terranes of California can be interpreted, albeit with less confidence, in similar terms of underflow of Pacific mantle. In the Klamath Mountains and northern Sierra Nevada, for example, Ordovician and Silurian ocean-floor materials, overlain by or juxtaposed against an Upper Silurian to Permian island arc, were swept in first to the continent, along with a large fragment of oceanic crust and mantle and another fragment of an old orogenic belt. This debris was followed by Permian and Triassic ocean-floor deposits. Late Triassic and Jurassic volcanic products from stocks and batholiths forming in the welded complexes lapped across both landward and oceanward sides of the region. Reversal of Cenozoic extension, strike-slip faulting, and volcanic crustal growth in the western United States reveals a Cretaceous tectonic pattern strikingly like the modern pattern of the Andes, so the paleotectonic setting of North America can be inferred from the South American present. The Mesozoic batholiths of North America, like the late Cenozoic volcanic belt of the central Andes, are products of the same rapid motion of oceanic plates that carried oceanic sediments against the continent to form eugeosynclinal terranes. Magmas generated in the Benioff zones formed the batholiths and the volcanic fields which initially capped them.

California↗
USGS2014

USGS Field Activities 12BHM01, 12BHM02, 12BHM03, 12BHM04, and 12BHM05 on the West Florida Shelf, in February, April, May, June, and August 2012

Atmospheric carbon dioxide (CO 2 ) is absorbed by the ocean’s surface where it combines with seawater to form a weak, naturally occurring acid called carbonic acid (H 2 CO 3 ). Increasing carbon dioxide in the atmosphere results in the absorption of more CO 2 by the ocean and, therefore, increases in the acidity of seawater. This process, known as ocean acidification, has the potential to elicit change in ecosystems and organisms by disrupting biological processes. For example, ocean acidification is a problem for marine organisms such as corals, foraminifera, and algae that precipitate calcium carbonate to form their skeletons and shells (Kleypas and others, 2006). The effects are related to corresponding changes in the carbonate saturation state (Ω), where Ω is the ratio of the ion concentration product (Ca 2+ x CO 3 2- ) to the stoichiometric aragonite solubility product (K*sp) (Langdon and Atkinson, 2005). Because pH and CO 3 2- are strongly interdependent through the inorganic carbon system, the decrease in pH will cause a proportionally greater decrease in CO 3 2- . Globally, ocean acidification is occurring faster than at any time in the last 300 million years (Broeker and others, 1979). Recent evidence indicates that individual oceans are responding at different rates, depending on physical and biological processes. For example in the Arctic Ocean, the rate of saturation state decrease was 2.1 percent per year between 1997 and 2010 (Robbins and others., 2013) in an area as large as Montana, largely because of increases in melt of ice, versus the average rate observed for the Pacific Ocean (0.36 percent per year) (Feely and others, 2012). Unfortunately, comparative data sets over multiyear time frames are often not available because time series baseline carbon information has not been collected in many oceans. Data are needed in subtropical latitudes where carbonate saturation states are already naturally low and fluctuate seasonally. These data will help construct a baseline for the assessment of future changes. As part of the U.S. Geological Survey (USGS) Coastal and Marine Geology Program project "R esponse of Florida Shelf Ecosystems to Climate Change " and in partnership with Kendra Daly, University of South Florida ( USF ), data on surface ocean carbonate chemistry were collected on five cruises along transects on the shallow inner west Florida shelf and northern Gulf of Mexico in 2012. Data from the 2011 cruises were also published (Robbins and others., 2013). The data collected allows the USGS, National Oceanic and Atmospheric Administration ( NOAA ), and USF scientists to map variations in ocean chemistry including carbonate saturation states along designated tracks. The USGS also partners with NOAA and the National Aeronautics and Space Administration ( NASA ) to model air-sea flux as part of a Gulf of Mexico Carbon Synthesis project led by NASA.

Florida↗
USGS2025

Isotopic compositions of modern seawater at the Mariana and Yap trenches

The isotopic composition of ocean water is crucial in studying water masses and mixing in deep oceans, isotope mass balance in ocean water regulated by high-temperature and low-temperature hydrothermal alterations, and the exchange of water among crust-ocean-mantle reservoirs. We collected 40 water samples from Challenger Deep and the water column above at the Mariana Trench (down to 10,923 m) and 12 from the Yap Trench (down to 6,300 m) in the western Pacific Ocean in three hadal cruises from 2016 to 2018. The δ 2 H values at the Mariana and Yap Trenches average 0.1 ± 0.2 ‰ (1σ error). The δ 2 H records from this study, together with existing databases, manifest that deep waters have δ 2 H values varying between −2 and +2 ‰ (except for the Weddell Sea, the Greenland, Iceland, and Norwegian Seas, and the Mediterranean Sea), with increasing values from the Southern Ocean to the Pacific and Indian Oceans, and to the Atlantic Ocean. The average δ 18 O value of water samples from both trenches is –0.04 ± 0.03 ‰ (1σ error). The correlation between δ 18 O and salinity distinguishes abyssal water masses at the study region, UCDW (Upper Circumpolar Deep Water) and LCDW (Lower Circumpolar Deep Water). These water samples from the Mariana and Yap Trenches gave an average 17 O excess value of −6 ± 1 ppm (1σ error). Our 52 data records of 17 O excess expand the 38 existing records for the deep ocean. Both δ 2 H and 17 O excess of modern ocean have rolled as anchor points to reconstruct compositions of Earth’s early ocean.

ACS Earth and Space Chemistry↗