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At least 991 records · Page 55Linked to original sources

Titanium mineral resources of the western U.S.: An update

Thirteen deposits or districts in the western U.S. have been examined in which titanium mineral resources have been reported or implied. These deposits are of the following general types (in probable order of importance): 1) Cretaceous shoreline placer deposits, 2) silica-sand deposits of California, 3) fluvial monazite placers of Idaho, 4) anorthosite related deposits, and 5) clay and bauxite deposits of the northwestern U.S. Relative to previous reports, this one shows some greater and some lesser resources (table 1). In any case, titanium-mineral resources of the western U.S. (west of 103° longitude) remain modest at world scale except as unconventional (especially perovskite) and by-product (especially porphyry) resources. Some deposits, however, have enhanced value to the titanium explorationist for the geologic relations they illustrate. Among the new conclusions are: a) Loci of Cretaceous shoreline placers form linear patterns, nested as a function of age, that can be traced for thousands of kilometers, permitting focused exploration in whole new mountain ranges. b) Medial hematite-ilmenite solid-solution, which is highly magnetic, is a major carrier of TiO 2 values in the Cretaceous deposits of Wyoming. This phase was previously thought to be relatively rare. c) Regressive shoreline placer deposits in indurated Cretaceous sequences expose intricate facies relations, such as the construction of shoreface sequences by long-shore drift over tidal-channel fill, without much loss of paleogeographic information. d) Due to deep weathering, virtually every Eocene sediment that accumulated in the Ione basin at the foot of the Sierra Nevada has economic value, permitting recovery of altered ilmenite and zircon along with silica, clay, coal, and gold. Ilmenite is most abundant in newly recognized shoreline sands. e) Upper Tertiary fluvial placers of Idaho formed in and filled fault-bounded basins and thus are far more voluminous than deposits in the modern valley system. Previously reported resources are thus far too low. f) Mafic igneous rocks of Proterozoic age near Bagdad, Arizona are of ophiolitic affinity, but contain nelsonitic ilmenite enrichments associated with anorthositic layers.

Open-File Report↗

Trace-element contents of postorogenic granites of the eastern Arabian Shield, Kingdom of Saudi Arabia

Trace-element contents for 46 postorogenic granitoids vary by as much as two orders of magnitude; most samples are strongly enriched in incompatible elements (such as the heavy rare earths, yttrium, niobium, and uranium) and depleted in the compatible elements (such as barium, strontium, scandium, europium, and cobalt). These trace-element characteristics are typical of A-type granites found in other areas of the world. In spite of the wide range in trace-element contents, no samples contained economically significant concentrations of a single element. Samples range from peralkaline to strongly peraluminous; most are weakly peraluminous or metaluminous. All three subgroups (peralkaline, metaluminous, and peraluminous) are enriched in uranium and hafnium and are depleted in compatible elements. The peralkaline granites are generally enriched in yttrium and niobium - the strongly peraluminous granites in rubidium and tantalum; both groups are also somewhat enriched in the heavy-rare-earth elements. Several of the peraluminous granites are known to be tin-bearing and, like tin-bearing granites found elsewhere in the world, their chondrite-normalized, rare-earth-element patterns are flat and have large negative europium anomalies. Samples from several plutons have very anomalous ratios for geochemically similar elements such as yttrium and holmium, niobium and tantalum, and zirconium and hafnium. These ratios may reflect differential complexing with a halogen-rich aqueous phase that may be characteristic of plutons that have been subjected to an ore-forming process. A program to test these hypotheses, through study of known mineralized areas and laboratory experiments, should be implemented. The regional trends for the chemical data and geochemical correlations over the large area sampled, suggest that the postorogenic granites were derived from a single protolith that formed by the mixing of oceanic sediments from the west, continental sediments from the east.

Open-File Report↗

Manganese content of the Shady dolomite in Bumpass Cove, Tennessee

The Shady dolomite in Bumpass Cove, Tennessee, contains deposits of hydrothermal sulphide minerals, and its residual clay contains oxidized manganese deposits. New chemical evidence bearing on the source of this manganese is presented.Chemical analyses of isolated components of sulphide-bearing dolomite show that the percentage of manganese is highest in country-rock dolomite unaffected by hydrothermal action, and that the manganese is present as carbonate. Manganese determinations on samples from a drill hole show that 43 feet of beds, about 100 feet above the base of the Shady dolomite, average 0.6 per cent manganese oxide, and that adjacent beds carry smaller amounts. Manganese carbonate, deposited with the original carbonate rock, is therefore considered to be the source of the manganese deposits of Bumpass Cove

Tennessee↗

Tectonic setting of the pebble and other copper-gold-molybdenum porphyry deposits within the evolving middle cretaceous continental margin of Northwestern North America

The Pebble Cu-Au-Mo deposit in southwestern Alaska, containing the largest gold resource of any known porphyry in the world, developed in a tectonic setting significantly different from that of the present-day. It is one of a series of metalliferous middle Cretaceous porphyritic granodiorite, quartz monzonite, and diorite bodies, evolved from lower crust and metasomatized lithospheric mantle melts, which formed along much of the length of the North American craton suture with the Peninsular-Alexander-Wrangellia arc. The porphyry deposits were emplaced within the northernmost two of a series of ca. 130 to 80 Ma flysch basins that define the suture, as well as into arc rocks immediately seaward of the two basins. Deposits include the ca. 100 to 90 Ma Pebble, Neacola, and other porphyry prospects along the Kahiltna basin-Peninsula terrane boundary, and the ca. 115 to 105 Ma Baultoff, Carl Creek, Horsfeld, Orange Hill, Bond Creek, and Chisna porphyries along the Nutzotin basin-Wrangellia terrane boundary. The porphyry deposits probably formed along the craton margin more than 1,000 km to the south of their present latitude. Palinspastic reconstructions of plate kinematics from this period are particularly difficult because magmatism overlaps the 119 to 83 Ma Cretaceous Normal Superchron, a period when sea-floor magnetic data are lacking. Our favored scenario is that ore formation broadly overlaps the cessation of sedimentation and contraction and the transition to a transpressional continental margin regime, such that the remnant ocean basins were converted to strike-slip basins. The basins and outboard Peninsular-Alexander-Wrangellia composite superterrane, which are all located seaward of the deep crustal Denali-Farewell fault system, were subjected to northerly dextral transpression for as long as perhaps 50 m.y., beginning at ca. 95 ± 10 Ma. The onset of this transpression was marked by development of the mineralized bodies along fault segments on the seaward side of the basins. Geochemical and radiogenic isotopic data for igneous rocks associated with the Pebble porphyry deposit suggest continuous melt derivation from enriched lithosphere of a recently metasomatized mantle. These geochemical characteristics, coupled with the arc-continent-related collisional setting, suggest that lithospheric thickening and postcollisional lithospheric melting are the most likely cause of the ore-related magmatism. Subsequent to translation of the Alaskan margin terranes and early Tertiary oroclinal bending of Alaska, the northernmost Kahiltna basin and the Pebble deposit, as well as the other porphyry systems, reached their present-day locations along southern Alaska.

Alaska, Yukon↗

Stratified deposits of the oxides and carbonates of manganese

Compared with the stratified deposits of iron minerals, those of manganese minerals have received little attention until recent years. Before 1930, students of the stratified deposits of manganese minerals have generally concluded that the contained manganese was derived from the decomposition of the rocks that formed the borders of the basins. Only in a few places have geologists recognized that if these rocks were the principal source of the contained manganese the basins should contain also enormous quantities of iron minerals, whereas most of the large deposits of manganese contain little iron. Even though more than 100 years ago some geologists proposed that the iron contained in some deposits of stratified iron minerals was probably derived from hydrothermal waters related to centers of volcanism, not until about 1930 was this source of manganese in similar deposits seriously proposed. This mode of origin was given the name "volcanogene sedimentaire" by French geologists working in Morocco. Since then, other names, such as "exhalative sedimentaire," have been used by geologists working in several European districts. Because of the development of new techniques for the study of the chemical and physical features of the minerals, and because close attention to the lithologic environments of the beds is being given more and more during recent years, it has seemed advisable to review the features of stratified deposits of the manganese minerals in many parts of the world and over a wide range in age. This study indicates that at least three sources may have contributed the manganese in the large deposits of iron-free oxides and carbonates : (1) the rocks that form the borders of the basins, either marine or continental; (2) the nearby underlying sediments, largely of igneous origin, decomposed by warm waters largely derived from depth; and (3) waters of hydrothermal origin derived from great depths during epochs of volcanism from which iron minerals with little manganese are deposited in deep zones, then minerals with much iron and more manganese at intermediate depths, and, finally, manganese minerals with little iron near the surface. As the hot waters of many thermal springs contain more manganese than iron, such waters could yield the pure manganese oxides and carbonates found in stratified deposits . Several kinds of evidence indicate that most of the manganese in the large stratified deposits of the oxides and carbonates of manganese in many parts of the world has been derived from hydrothermal waters from depth related to centers of volcanism. Obviously, manganese derived from decay of the rocks on the lands adjacent to large basins-marine and continental -may have been added to that derived from centers of volcanism to form the sedimentary deposits found in the basins.

Economic Geology↗

Sulfur isotope study of the "B" limestone and Galena fissure ore deposits of the U.S. mine, Bingham mining district, Utah

The delta S 34 values for 261 sulfide concentrates from the "B" limestone replacement and Galena fissure deposits of the U. S. mine range from +3.8 to --8.0 permil; the mean is +0.56 permil. The data indicate that (1) sulfides of the "B" limestone ore deposits are depleted in S 34 by 0.4 to 0.7 permil relative to those of the Galena fissure ore deposits; (2) sulfides of both deposits exhibit a primary fractionation trend characterized by increasing S 34 depletion in the sequence pyrite, sphalerite, tetrahedrite, and galena; (3) delta values for coexisting sulfide pairs of the "B" limestone deposit increase with increasing altitude; (4) sulfides of both deposits are increasingly depleted in S 34 with increasing altitude; (5) the paragenetic order of sulfide deposition is accompanied by an apparent depletion of S 34 that is independent of mineral species; and (6) pyrite disseminated in wall rocks is depleted in S 34 relative to pyrite from adjacent ore deposits. The similarity of delta S 34 values and isotopic trends to those of the central porphyry-type deposit at Bingham (Field, 1966) suggests that the hydrothermal deposits of the district were formed by fluids that originated from a common source during one episode of sequential mineralization. Gross isotopic differences between the deposits, consistent differences between coexisting sulfides, and systematic variations of delta values are attributed to temperature effects imposed upon sulfide exchange equilibria; isotopic temperatures suggest a lateral gradient between the "B" limestone and adjacent Galena fissure deposits and a possible vertical gradient within the "B" limestone deposit. The vertical zonation of delta S 34 values and trends related to pyrite physical occurrence and sulfide paragenesis are provisionally attributed to a pH-Eh control. Although the apparent trends are imperfectly resolved because of textural complexities, the marked depletion of S 34 in pyrite disseminated in country rocks warrants additional study as a potential exploration method.

Utah↗

Heavy metals in altered rock over blind ore bodies, East Tintic District, Utah

Standard chemical tests and spectroscopic analyses of altered Tertiary lavas that occur above blind ore bodies in the East Tintic district, Utah, have failed to show any evidence of the mineralization in the underlying dolomites. A new technique involving dithizone was used in the field to test ammonium acetate extracts of crushed samples of the lava for soluble heavy metals, with significant results. Concentrations of heavy metals, believed to be chiefly zinc, with some lead and rarely copper (?), were found in pyritized rhyolite above and up-rake from known blind ore bodies, and were lacking in similarly altered rhyolite underlain by barren rocks. An incompletely prospected area of pyritic alteration shows a definite pattern of positive tests and seems worthy of further exploration. The theory and practice of the dithizone method as used in the field is described briefly.

Utah↗

Paleo-channels at the Guayacan copper mine, Cabildo District, Aconcagua Province, Chile

An uneven erosion surface separates calcareous sedimentary rocks above and vesicular andesite porphyry below at the Guayacan mine of central Chile . Channel -like depressions filled with sedimentary rock flank elongate, stratiform bodies of disseminated copper ore which impregnate the vesicular crests of andesite lava flows. The " channels " lie parallel to and mark the margins of tongues of lava. Erosional features such as scour surfaces, conglomerate and crossbedding mark some of the channels . Other channels show no evidence of erosion, suggesting that some, at least, represent depressions or spaces that were not filled during extrusion of the lava. The flows strike east. Their crests are vesicular and impregnated with copper sulfide minerals, mainly bornite, to depths as much as 3 m below the contact. Bornite fills vesicles and fractures, impregnates the andesite ground mass, and replaces andesine phenocrysts, mainly along cleavage planes. Chalcopyrite is mixed with bornite in the upper, more vesicular part of the flows and occurs with fine-grained pyrite as disseminations and replacing fossils in the base of the overlying sedimentary rock. The channel axes also strike roughly east and, in most places, are underlain by barren ground. These mappable features, when recognized, are valuable in determining the size, shape, and orientation of adjacent ore bodies and, thereby, assist in the evaluation, exploration and mining of these stratiform copper deposits.

Economic Geology↗

Veins of hypogene manganese oxide minerals in the southwestern United States

Characteristic minerals are psilomelane, hollandite, cryptomelane, and coronadite, more rarely ramsdellite and pyrolusite. Host rocks are Mn-deficient; 80 percent of examples are middle to late Tertiary layered volcanics. Though deposits are shallow, mostly mined to only 100-200 feet (maximum 500 feet), a hypogene origin is indicated by their persistent association with barite and fluorite, a peripheral position in the zonal pattern of some metal-mining districts, alteration of plagioclase to K-spar, and abundance of W, Pb, Cu, Mo, Ti, As, Sb. They represent the subzone of Mn-bearing epithermal vein deposits lying nearest the surface, succeeded in depth by four other subzones: barite, fluorite, gold-silver, and base metals.

Arizona, California, Colorado, Nevada, New Mexico,↗

Structure and stratigraphy of the western Florida shelf; Part I, Multichannel reflection seismic data

This paper presents a synthesis of multichannel seismic data on the Western Florida shelf (Fig. 1). This work is part of an ongoing regional program conducted by the U.S. Geological Survey in studying the Exclusive Economic Zones of the United States. The data include 1270 km of 32-fold, common-depth-point (CDP), reflection seismic line obtained with a 3200 m, 64 channel, hydrophone streamer and a 2000 in 3 airgun array. The rationale for the line layout was to tie eight key exploration wells among the 14 existing in federal waters prior to 1980 to 4 key wells in Florida. An attempt was also made to connect our survey with that of the University of Texas Institute of Geophysics in the deep Gulf of Mexico basin. A second set of 1500 km of 24-fold CDP data were collected using a 1200 m, 24-channel streamer and a 550 in 3 airgun source. This set was intended to tie additional wells, drilled between 1979 and 1983, and to infill our original net. Gravity and magnetic measurements were also made along these lines. Our subsurface information in federal waters consists of well logs and files released to us initially by the Conservation Division of the U.S. Geological Survey and subsequently by the U.S. Minerals Management Service. Most information from wells in state waters was provided by the Florida Geological Survey. Table 1 lists wells included in our study and summarizes the types of logs and other information available from each well. Spontaneous potential or gamma ray, resistivity or conductivity, sonic and density logs were generally available. Lithologic information, paleontologic and log picks on stratigraphic units and dip-meter data were also common. Check shot surveys for velocity analysis were available in three wells.

Florida↗

Paleozoic sedimentary rocks in the Red Dog Zn-Pb-Ag district and vicinity, western Brooks Range, Alaska: provenance, deposition, and metallogenic significance

Geochemical analyses of Paleozoic sedimentary rocks in the western Brooks Range reveal a complex evolutionary history for strata surrounding the large Zn-Pb-Ag deposits of the Red Dog district. Data for major elements, trace elements, and rare earth elements (REE) were obtained on 220 samples of unaltered and unmineralized siliciclastic rocks from the Upper Devonian-Lower Mississippian Endicott Group (Hunt Fork Shale, Noatak Sandstone, Kanayut Conglomerate, Kayak Shale), the overlying Carboniferous Lisburne Group (Kuna Formation, unnamed drowned shelf facies), and the Pennsylvanian-Permian Siksikpuk Formation. Major base metal sulfide deposits of the region are present only in the Kuna Formation, which in the Red Dog district comprises siliceous black shale and black chert, minor limestone (calcareous radiolarite), and sparse lithic turbidite and bedded siliceous rock. Gray and rare black shales of the Kayak Shale and common black shales of the Kuna Formation are anomalously low in iron (avg Fe/Ti = 6.25 and 6.34, respectively) relative to other Paleozoic shales in the region (9.58-10.6) and to average shales worldwide (10.1-10.5). In contrast, the bedded siliceous rocks contain appreciable hematite (avg Fe/Ti = 35.0) and high U/Ti and REE/Ti ratios that are interpreted to reflect low amounts of detrital material and a major Fe-rich eolian component. Geochemical data (e.g., MnO <0.01 wt %; avg Cr = 317 ppm), sizes of framboidal pyrite grains, and limited bioturbation suggest anoxic and denitrifying depositional conditions for most black shales of the Kuna Formation; low Mo/Ti ratios argue against euxinic (sulfate-reducing) conditions. Organic-rich black shales of the Kuna Formation with up to 8.4 wt percent C organic and gray to black shales of the Kayak Shale with up to 4.1 wt percent C organic typically have only sparse pyrite (<1 wt % S) and very low iron-limited S/C ratios (mostly <0.2). Immobile element plots (e.g., Th-Zr/10-Sc) suggest that source terranes for all of the formations were dominated by one or more felsic-rich continental arcs; a small proportion of recycled sediments is present locally. A minor mafic igneous component also occurs in several shales of the Kuna and Siksikpuk Formations. High average values for the chemical index of alteration [Al 2 O 3 /(Al 2 O 3 + CaO + Na 2 O + K 2 O)] &infin; 100 for shales of the Endicott Group (76.4-81.5) imply moderate to intense chemical weathering in source areas of these sediments. A lower average for black shales of the Kuna Formation (73.7) does not require such weathering. Textural and geochemical data record the effects of diagenetic and/or hydrothermal fluid flow in some of the Paleozoic rocks. Mobility of P, F, U, and light REE is documented in black shales of the Kuna Formation by phosphate replacements of carbonate clasts and of matrix material surrounding the clasts. A relatively low average Ce/Ce* value of 0.73 for P-poor black shales of the Kuna Formation ( < 0.05 wt % P 2 O 5 ) and a similar Ce/Ce* value of 0.78 for a siderite concretion in Kayak Shale suggest that these diagenetic fluids were oxidizing. Many shales of the Kuna Formation have high (K 2 O &infin; 100)/(K 2 O + Al 2 O 3 ) ratios of 21.0 to 23.0, which contrast with low ratios of generally <18.0 for shales of the underlying Endicott Group. The high ratios in shales of the Kuna Formation reflect preferential reaction of smectite to illite during the Jurassic-Cretaceous Brookian orogeny, owing to high silica activities in pore fluids that were generated by the dissolution of abundant biogenic silica. The distribution and composition of Paleozoic strata in the western Brooks Range may have played a fundamental role in Zn-Pb mineralization of the Red Dog district. In our model, deposition and early lithification of biogenic chert and bedded siliceous rocks in the upper part of the Kuna Formation served as a regional hydrologic seal, acting as a cap rock to heat and hydrothermal fluids during Late Mississippian base-metal mineralization. Equally important was the iron-poor composition of black shales of the Kuna Formation (i.e., low Fe/Ti ratios), which limited synsedimentary pyrite formation in precursor sediments, resulting in significant H 2 S production in pore waters through the interaction of aqueous sulfate with abundant organic matter. This H 2 S may have been critical to the subsurface deposition of the huge quantities of Zn and Pb in the district. On the basis of this model, we propose that low Fe/Ti and S/C ratios in black shale sequences are potential basin-scale exploration guides for giant sediment-hosted, stratiform Zn-Pb-Ag deposits.

Alaska↗

Ground-water investigations of the Project Gnome area, Eddy and Lea Counties, New Mexico

The U.S. Atomic Energy Commission, through the Office of Test Operations, Albuquerque Operations Office, plans to detonate a nuclear device in a massive salt bed 1,200 feet beneath the land surface. The project, known as Project Gnome, is an element of the Plowshare program--a study of peacetime applications of nuclear fission. The location of the proposed underground shot is in a sparsely-populated area in southeastern Eddy County, N. Mex., east of the Pecos River and about 25 miles southeast of the city of Carlsbad. The area is arid to Semiarid and ground water is a vital factor in the economic utilization of the land, which is primarily used for stock raising. An investigation of the Project Gnome site and surrounding area for the purposes of evaluating the ground-water resources and the possible effect upon them from the detonation of the nuclear shot was desired by the Commission. This report describes work done by the U.S. Geological Survey on behalf of the Commission and presents results of the investigation of the ground-water resources and geology of the area. The most intensive investigations were made within a 15-mile radius of the site of Project Gnome and mainly on the east side of the Pecos River. The total area of study of over 1,200 square miles includes parts of Eddy and Lea Counties, N. Mex. The Project Gnome site is in the sedimentary Delaware Basin. It is underlain by about 18,000 feet of sedimentary rocks ranging in age from Ordovician to Recent. Upper Permian evaporitic rocks, which contain the principal source of potash available in the United States, are worked in nearby mines. The potash minerals are found in a massive salt bed about 1,400 feet thick in the Salado Formation of Permian age. The land surface of the area is covered mostly by a wind-blown sand and caliche; however, rocks of the Rustler Formation of Permian age and younger rocks of Permian, Triassic, Pleistocene(?) and Recent age crop out at several localities. Solution by ground water of salt at the top of the Salado Formation and of anhydrite within the Rustler Formation has removed thick sections of these rocks. A subsequent lowering of the land surface and differential collapse of the Rustler has formed many sinkholes and has created a karst topography over much of the western part of the area. Ground water is obtained from rocks of Permian, Triassic, Tertiary, and Quaternary age in the general region. However, the only aquifer at the Gnome site is the Culebra Dolomite Member of the Rustler Formation of Permian age. The aquifer is about 500 feet beneath the surface at the site and is about 30 feet thick. An aquifer, immediately above the top of the salt, contains a brine solution in Nash Draw, a few miles west of the Gnome site. This aquifer discharges into the Pecos River and is a major source of contamination of the river water. No potable water is known to be present in the area below the top of the salt of the Salado Formation. The ground water in the area is generally under artesian pressure. The general direction of ground-water movement is toward the Pecos River both east and west of the river. At the Gnome site the artesian head of the water in the Culebra Dolomite Member is about 7.5 feet. The water moves westward through the aquifer at a rate of about ? foot per day. The most widespread utilization of ground water east of the river is for stock use. Irrigation usage west of the Pecos River accounts for the largest withdrawal of water. Wells range in depth from a few tens of feet to nearly 800 feet. Water levels range from a few feet to about 500 feet below the surface. A test well at the Gnome site drawing water from the Culebra Dolomite Member was pumped at a rate of 100 gpm (gallons per minute); however, most wells east of the river yield only a few gpm. Irrigation wells west of the river yield as much as 3,500 gpm. Most of the water in the area is highly mineralized and is suitable only for use by livest

Open-File Report↗

Stratigraphic sections of the Phosphoria formation in Idaho, 1947-48, Part I

The Permian Phosphoria formation of the western states contains one of the world's largest reserves of phosphate. Although previous investigations (see especially Mansfield, 1927), including reconnaissance geologic mapping and sampling, established the location of most of the important deposits and their quality of scattered localities, they were not sufficiently detailed to permit a comparison of the merits of individual deposits or an appraisal of the reserves of phosphate rock that might be available under present economic conditions. Because the growing importance of the western phosphate deposits requires a better, more detailed understanding of their distribution and quality, the Geological Survey began in 1947 a comprehensive investigation, including (1) reconnaissance geologic mapping, mostly in Montana, of areas in which the Phosphoria formation could occur but where it had not previously been looked for or found; (2) geologic mapping, mostly in Montana, at a scale no smaller than 1:62,500, of several areas known to contain the Phosphoria formation but not previously mapped except in reconnaissance fashion; (3) geologic and topographic mapping, at a scale of 1:12,000, of some of the richest, thickest, and most accessible deposits; (4) measuring, describing, and sampling all beds of the phosphatic and shaly parts, and in some places the full thickness, of the Phosphoria formation and its stratigraphic equivalents at one or two localities per township over the entire field; (5) chemical and spectrographic analysis of the samples for phosphate, fluorine, minor metals, oil, and rock-forming constituents; and (6) petrologic and geochemical studies of the rocks and minerals of the formation. These studies are designed to define the regional and local geologic structures in which the phosphate bed lie, to provide a basis for the estimation of reserves of the inferred class over the entire region, and to determine the origin of the rocks and the elements contained in them. The data collected are not of the detail required to plan actual mining operations, but it is hoped they will guide industry in the selection of individual deposits worthy of further exploration. Most of the field work contemplated as a part of this investigation is now completed. Although the data will not be compiled or published in final form for some years to come, segments of the data, accompanied by little or no interpretation, will be published as preliminary maps or reports as they are assembled. The present report is the first of a series presenting in abbreviated form the description and analyses of the beds measured and sampled at various localities in southeastern Idaho (pl. 1). Companion reports presenting segments of the data from Montana, Wyoming, and Utah (Swanson and others, 1952, and McKelvey and others, 1952a and 1952b) are being released at the same time as this report, and others are in preparation.

Idaho↗

Origin of the Red Dog Zn-Pb-Ag deposits, Brooks Range, Alaska: Evidence from regional Pb and Sr isotope sources

Pb and Sr isotope data were obtained on the shale-hosted Zn-Pb-Ag Red Dog deposits (Qanaiyaq, Main, Aqqaluk, and Paalaaq), other shale-hosted deposits near Red Dog, and Zn-Pb-Ag sulfide and barite deposits in the western and central Brooks Range. The Red Dog deposits and other shale-hosted Zn-Pb-Ag deposits near Red Dog are hosted in the Mississippian Kuna Formation, which is underlain by a sequence of marine-deltaic clastic rocks of the Upper Devonian to Lower Mississippian Endicott Group. Ag-Pb-Zn vein-breccias are found in the Endicott Group. Galena formed during the main mineralization stages in the Red Dog deposits and from the Anarraaq and Wulik deposits have overlapping Pb isotope compositions in the range 206Pb/204Pb = 18.364 to 18.428, 207Pb/204Pb = 15.553 to 15.621, and 208Pb/204Pb = 38.083 to 38.323. Galena and sphalerite formed during the main ore-forming stages in the Red Dog deposits define a narrow field on standard uranogenic and thorogenic Pb isotope diagrams. Lead in sulfides of the Red Dog district is less radiogenic (238U/204Pb: ?? = 9.51-9.77) than is indicated by the average crustal lead evolution model (?? = 9.74), a difference consistent with a long history of evolution at low ratios of ?? before the Carboniferous. The homogeneous regional isotopic reservoir of Pb may indicate large-scale transport and leaching of minerals with various ?? ratios and Th/Pb ratios. Younger and genetically unrelated fluids did not significantly disturb the isotopic compositions of galena and sphalerite after the main mineralization event in the Red Dog district. Some pyrite shows evidence of minor Pb remobilization. The overall lead isotope homogeneity in the shale-hosted massive sulfide deposits is consistent with three types of control: a homogeneous regional source, mixing of lead during leaching of a thick sedimentary section and fluid transport, or mixing at the site of deposition. Isotopic variability of the hydrothermal fluids, as represented by galena in the Red Dog district, appears to be consistent with a simple mixing system. Evidence indicates that galena was deposited from largely similar hydrothermal solutions throughout the Red Dog district. A shared regional isotopic reservoir is also supported by the correspondence of Pb isotope compositions of galena in deposits of the Red Dog district and galena in clastic rocks (vein-breccias). Leaching of metals and progressive extraction of radiogenic lead from the clastic rocks in the Endicott Group may account for the trend of increasing 206Pb/204Pb in galena of the Red Dog district. Galena in the Red Dog deposits is unlikely to have been derived entirely from the same isotopic reservoir as that represented by the lead in the Kuna Formation or from the igneous rocks in the Red Dog district. Sr isotope data for barite, calcite, and witherite from the Red Dog deposits are compared with data from regional barite that is associated with sulfides and from barite in sulfide-poor occurrences. Fluids with heterogeneous Sr isotope signatures are indicated. Barite in the Main deposit extends to higher ratios of 87Sr/86Sr (0.709034-0.709899) than barite in the Anarraaq deposit (0.708615-0.709256). All barite is more radiogenic than Carboniferous seawater. Other Mississippian(?) shale-hosted deposits and mineral occurrences containing barite in the Red Dog district and barite in regional occurrences east of Red Dog in the western and central Brooks Range also have heterogeneous 87Sr/86Sr ratios. Carbonate (87Sr/86Sr = 0.710319-0.713637) and witherite (87 Sr/86 Sr = 0.710513) in the Main deposit are more radiogenic than barite. In contrast, carbonate (87Sr/86Sr = 0.708196-0.709740) intergrown with massive sulfides at Anarraaq has isotopic compositions similar to that of barite. Paragenetic and isotop ic studies suggest that early barite is similar to barite typically formed in cold seeps along continental margins. This early fine-grained barite formed before the main mineralizat

Economic Geology↗

Challenge theme 4: People in the Borderlands: Chapter 6 in United States-Mexican Borderlands: Facing tomorrow's challenges through USGS science

The management of shared resources in the United States–Mexican border region requires cooperation from the people of both countries to assess and understand their relation to the environment. Society is dependent on the long-term healthy functioning of ecosystems and their ability to supply food and raw materials. Likewise, resources and services obtained from nature could be used efficiently within the society. A more equitable distribution of costs and benefits related to goods and services can lead to fewer tensions and a higher quality of life for all the people in the Borderlands. Urban development, background contamination from mineral ore deposits, irrigation, sewage effluent, and even global climate change all have the potential to alter the stability of the fragile systems in the Borderlands (Brady and others, 2001, 2002; Norman, 2007, 2010; Gu and others, 2008; Norman, Gray, and others, 2008; Norman, Hirsch, and Ward, 2008; Norman, Callegary, and others, 2010; Norman, Huth, and others, 2010; Norman, Levick, and others, 2010; Norman, Tallent-Halsell, and others, 2010; Norman, Villarreal, and others 2012). Social efficiency means that because resources should be used where they are needed most, they should be distributed proportionally among human societies and individuals (Azar and others, 1996). Despite the critical role natural resources play in maintaining human and environmental health, current knowledge of the manner in which natural and human-caused forces interact to limit these resources—including their quality and quantity (such as through spatiotemporal changes in precipitation, evapotranspiration, pumping of groundwater, and release of contaminants)—is inadequate. The U.S. Geological Survey (USGS) is trying to understand the relation between changing landscapes, changing demographics, and a changing climate in the Borderlands while the environmental, economic, and societal issues continue to be intertwined between the two nations.

United States-Mexico Borderlands↗

Mineral resources of the Bradwell Bay Wilderness and the Sopchoppy River study area, Wakulla County, Florida

The Bradweli Bay Wilderness and Sopchoppy River Study Area comprise 23,000 acres (93 km 2 ) in the Apalachicola National Forest in the Florida panhandle. The area is a swamp-covered, almost flat surface of a terrace in which the Sopchoppy River is entrenched. Deposits directly underlying the terrace surface generally consist of as much as 30 feet (9 m) of sand, clay, muck, and peat of Pliocene to Holocene age overlying limestone and marl of Miocene age. The limestone and marl are on the east flank of the gulf trough, and are underlain by a thick sequence of older Tertiary and Cretaceous sedimentary rocks. Older formations of probable Jurassic, Triassic, Paleozoic, and Precambrian ages are known from scattered holes drilled for oil in surrounding areas. The Hawthorn Formation of middle Miocene age, from which phosphate and fuller's earth are chiefly produced in Florida, is not found in the Study Area therefore, the potential for resources of phosphate is low. Phosphate pellets, however, were found in auger holes in sand above the St. Marks and Jackson Bluff Formations of early and late Miocene age, respectively. The pellets are mostly in sands deposited in an estuary during Pliocene or early Pleistocene time; they were derived from older rocks, presumably the Hawthorn Formation. Approximately 136,000 tons (123,000 tonnes) of air-dried peat are available from bay swamps in the Study Area, but the deposits are too shallow and widespread to make mining economically feasible. Large quantities of quartz sand are available in abandoned beach ridges and in deposits of shallow nearshore marine origin, but sieve tests show that the sand is generally too fine for mortar and masonry use, and it is not suitable as moulding or glass sand because it lacks the required size grades and purity. The northern Florida, southern Alabama, and Georgia region produces oil, phosphate, fuller's earth, sand, and peat. The Study Area is about 175 miles (280 km) east-southeast of the Jay oil field in the western panhandle of Florida. Part of the production is from the Smackover Formation of Jurassic age, which is also the target formation for drilling in the vicinity of the Study Area. Four oil test wells have been drilled in the vicinity of the Study Area but all proved to be unsuccessful. Phillips Petroleum Company completed a well in Leon County at a depth of 10,466 feet (3,190 m). Placid Oil Company drilled a well in Wakulla County to 12,116 feet (3,693 m) and two in Liberty County, one to 12,131 feet (3,698 m) and the second to 12,400 feet (3,780 m). These three test wells are alined along a northeast trend immediately northwest of the Bradwell Bay area. The oil and gas potential of the Bradwell Bay-Sopchoppy area is low.

Florida↗

One hundred years of cobalt production in the Democratic Republic of the Congo

Cobalt is an indispensable element for the manufacture of strategic technologies including advanced batteries, jet engines, rare-earth permanent magnets, petroleum catalysts, and tool parts that enable construction, manufacturing, and mining. Cobalt routinely scores high in mineral supply risk assessments due to the concentration of cobalt mine production in the Democratic Republic of the Congo (DRC). This stands in contrast to the fact that DRC cobalt mine production had a 20% compound annual growth rate from 1995 through 2020—in large part due to investments by Chinese firms beginning in the mid-2000s. Given this continuous growth, one may ask why this supply is perceived to be so risky. This analysis illuminates the causes of historic disruptions to DRC cobalt mine and refinery production by analyzing country-level production, historical reports, and cobalt prices back to 1924. The results indicate that the main causes of supply disruptions were damage to transportation routes, underinvestment in maintaining nationalized mining assets, and the disintegration of the DRC economy during the early 1990s. On the other hand, cobalt mine production increased 50% from 1977 to 1979 despite two secessionist conflicts in DRC's cobalt producing region and increased seven-fold from 1996 to 2003 despite two African wars over the DRC and its resources. These results indicate that—barring another economic disintegration or mining industry nationalization—DRC mine production will likely continue to be the dominant supplier of the world's growing demand for cobalt in lithium-ion batteries. These results also indicate that sustained development of transportation (and other) infrastructure in Africa, as well as support for good governance in the DRC may prove key to the continued stability of DRC cobalt mine supplies.

Resources Policy↗

Structural controls on Carlin-type gold mineralization in the gold bar district, Eureka County, Nevada

The Gold Bar district in the southern Roberts Mountains, 48 km northwest of Eureka , Nevada , contains one main deposit ( Gold Bar ), five satellite deposits, and other resources. Approximately 0.5 Moz of gold have been recovered from a resource of 1,639,000 oz of gold in Carlin - type gold deposits in lower plate, miogeoclinal carbonate rocks below the Roberts Mountains thrust. Host rocks are unit 2 of the Upper Member of the Devonian Denay Formation and the Bartine Member of the McColley Canyon Formation. Spatial and temporal relations between structures and gold mineralization indicate that both pre-Tertiary and Tertiary structures were important controls on gold mineralization . Gold mineralization occurs primarily along high-angle Tertiary normal faults, some of which are reactivated reverse faults of Paleozoic or Mesozoic age. Most deposits are localized at the intersection of northwest- and northeast-striking faults. Alteration includes decalcification, and to a lesser extent, silicification along high-angle faults. Jasperoid (pervasive silicification), which formed along most faults and in some strata-bound zones, accounts for a small portion of the ore in every deposit. In the Gold Canyon deposit, a high-grade jasperoid pipe formed along a Tertiary normal fault which was localized along a zone of overturned fault-propagation folds and thrust faults of Paleozoic or Mesozoic age.

Nevada↗