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Decadal trends in the quality of groundwater used for public drinking-water supply in California, 2004–23, California Groundwater Ambient Monitoring and Assessment Program, Priority Basin Project

This study provides a comprehensive assessment of decadal changes in the quality of groundwater used for public drinking-water supply at 444 monitoring sites across California during 2004–23. We assessed decadal step trends in groundwater quality for 145 water-quality constituents and geochemical indicators statewide and across geographic and land-use based network groups. We evaluated the statistical significance of directional changes (predominant increase or decrease of constituent concentrations) and the magnitude of those changes across all network groups. Uranium showed the most widespread directional and high-magnitude increases of all constituents with regulatory benchmarks statewide, particularly in the agriculture-dominated Central Valley as well as urban-and desert-dominated regions of Southern California. Fluoride and perchlorate showed the most widespread directional and high-magnitude decreases of all constituents with regulatory benchmarks statewide, which were also most pronounced in Southern California. Although arsenic and nitrate did not often register significant directional changes across network groups, they showed widespread, high-magnitude changes in both directions (increase and decrease) at levels often exceeding 10 percent of respective regulatory benchmarks statewide. Triazine herbicides (atrazine and simazine) and the gasoline oxygenate methyl tert -butyl ether showed significant directional decreases statewide, but not at levels considered to be of high magnitude compared to respective regulatory benchmarks. We observed significant directional and high-magnitude increases of total dissolved solids statewide, which were most pronounced in agricultural areas. Analysis of explanatory geochemical indicators indicated that prevalent statewide increases of alkalinity and calcium were the predominant components of the observed statewide increases in total dissolved solids by mass. Widespread increases in groundwater alkalinity and calcium across agricultural and urban areas may be related, in part, to warm-season irrigation and other anthropogenic factors that have shifted soil weathering dynamics over the long term. Increasing alkalinity concentrations were related to increasing uranium concentrations, particularly in areas with aquifer materials derived from granitic rocks. Conversely, increasing calcium concentrations were related to decreasing fluoride concentrations, particularly in areas where fluoride occurred naturally at elevated concentrations. Decrease of perchlorate, triazine herbicides, and methyl tert -butyl ether are likely related to decreased anthropogenic source inputs over time and natural attenuation in aquifers.

California

Oligocene–Miocene northward growth of the Tibetan Plateau: Insights from intermontane basins in the West Qinling Belt, NW China

Growth of the Tibetan Plateau, Earth’s broadest and highest elevation collisional system, shapes orographic barriers, reorganizes drainage networks, and influences surface erosion and sediment delivery, whose changes in space and provenance feed back to intracontinental tectonic processes. Studies of interior basins within the northern Tibetan Plateau provide new sediment accumulation, provenance, paleodrainage, and deformation timing data that enable a reconstruction of the far-field tectono-geomorphic evolution of the rising Tibetan Plateau. Along the northern plateau margin, topographic growth in the West Qinling Belt is inferred to have initiated in the Eocene, nearly coeval with the India-Asia collision, as well as in the late Miocene. However, geological knowledge about the intervening period remains at present enigmatic, and the kinematics and dynamics are uncertain. This study presents a multidisciplinary data set from the intermontane Anhua-Huicheng Basin (AHB; Gansu Province, China) to fill this gap. Magnetostratigraphic dating, regional mapping, and sedimentological analysis imply that contractional deformation and thrust-top basin systems formed within the West Qinling Belt in the Oligocene (not later than ca. 24 Ma). A combination of observations including paleocurrent changes, detrital zircon U-Pb age variations, and appearance of growth strata along the Anhua-Huicheng Basin reveal the rapid uplift of the West Qinling Belt at ca. 15 Ma. Sedimentation in the intermontane basins ended after the late Miocene (ca. 8 Ma), when the region experienced intrabasinal deformation, uplift, and erosion with the establishment of an external drainage system. Since the late Miocene, the growth of the West Qinling Belt reached a climax with the lack of substantial contractional deformation in Cenozoic sequences heralding the onset of the modern kinematic regime and attainment of high elevation. Observed transitions in the tectonostratigraphy and paleodrainage define different phases of deformation and plateau-wide shifts in stress reorganization, which led to the northward growth and later lateral expansion of the Tibetan Plateau.

GSA Bulletin

Assessment of western Oregon debris-flow hazards in burned and unburned environments

In the steep and mountainous environment of western Oregon, debris flows pose a considerable threat to property, infrastructure and life. Wildfire is commonly known to increase the susceptibility of steep slopes to debris flows, but the extent of this process in the western Cascades is not well understood. The US Geological Survey (USGS) currently estimates postfire debris-flow likelihood and triggering rainfall thresholds using a model calibrated to a southern California inventory of debris flows generated by excess runoff within the first year after fire. Because of a lack of available data, this model has not been tested in western Oregon, or in locations where postfire debris flows initiate via other mechanisms (e.g., shallow landslides or in-channel failures). Using repeat field observations and aerial imagery, we developed two new debris-flow inventories within and adjacent to the perimeters of five 2020 wildfires in western Oregon: Archie Creek, Holiday Farm, Beachie Creek, Lionshead and Riverside. The first inventory focuses on postfire debris flows (2020–2022); the second focuses on debris flows prior to fires (1995–2020). Our inventories of prefire and postfire debris flows were used to document initiation mechanisms in Oregon's western Cascades and to evaluate the effects of wildfire. We found that wildfire changed the distribution of debris-flow initiation mechanisms in the western Cascades. After the wildfires, annual rates of runoff-generated debris flows increased by 22% and the number of shallow landslide-initiated debris flows decreased by 17% relative to before the wildfires. Despite this shift, shallow landsliding was the dominant debris-flow initiation mechanism in both unburned and burned environments. We found the performance of the current USGS debris-flow likelihood model was degraded relative to other previously tested locations across the intermountain western United States. Our results highlight the need for improved postfire hazard assessment in western Oregon based on regional model calibration that is tuned to the dominant debris-flow initiation mechanisms.

Oregon

Episodic sediment-discharge events in Cascade Springs, southern Black Hills, South Dakota

Cascade Springs is a group of artesian springs in the southern Black Hills, South Dakota, with collective flow of about 19.6 cubic feet per second. Beginning on February 28, 1992, a large discharge of red suspended sediment was observed from two of the six known discharge points. Similar events during 1906-07 and 1969 were documented by local residents and newspaper accounts. Mineralogic and grain-size analyses were performed to identify probable subsurface sources of the sediment. Geochemical modeling was performed to evaluate the geochemical evolution of water discharged from Cascade Springs. Interpretations of results provide a perspective on the role of artesian springs in the regional geohydrologic framework. X-ray diffraction mineralogic analyses of the clay fraction of the suspended sediment were compared to analyses of clay-fraction samples taken from nine geologic units at and stratigraphically below the spring-discharge points. Ongoing development of a subsurface breccia pipe(s) in the upper Minnelusa Formation and/or Opeche Shale was identified as a likely source of the suspended sediment; thus, exposed breccia pipes in lower Hell Canyon were examined. Upper Minnelusa Formation breccia pipes in lower Hell Canyon occur in clusters similar to the discrete discharge points of Cascade Springs. Grain-size analyses showed that breccia masses lack clay fractions and have coarser distributions than the wall rocks, which indicates that the red, fine-grained fractions have been carried out as suspended sediment. These findings support the hypothesis that many breccia pipes were formed as throats of abandoned artesian springs. Geochemical modeling was used to test whether geochemical evolution of ground water is consistent with this hypothesis. The evolution of water at Cascade Springs could not be suitably simulated using only upgradient water from the Minnelusa aquifer. A suitable model involved dissolution of anhydrite accompanied by dedolomitization in the upper Minnelusa Formation, which is caused by upward leakage of relatively fresh water from the Madison aquifer. The anhydrite dissolution and dedolomitization account for the net removal of minerals that would lead to breccia pipe formation by gravitational collapse. Breccia pipes in the lower Minnelusa Formation are uncommon; however, networks of interconnected breccia layers and breccia dikes are common. These networks, along with vertical fractures and faults, are likely pathways for transmitting upward leakage from the Madison aquifer. It is concluded that suspended sediment discharged at Cascade Springs probably results from episodic collapse brecciation that is caused by subsurface dissolution of anhydrite beds and cements of the upper Minnelusa Formation, accompanied by replacement of dolomite by calcite. It is further concluded that many breccia pipes probably are the throats of artesian springs that have been abandoned and exposed by erosion. The locations of artesian spring-discharge points probably have been shifting outwards from the center of the Black Hills uplift, essentially keeping pace with regional erosion over geologic time. Thus, artesian springflow probably is a factor in controlling water levels in the Madison and Minnelusa aquifers, with hydraulic head declining over geologic time, in response to development of new discharge points. Development of breccia pipes as throats of artesian springs would greatly enhance vertical hydraulic conductivity in the immediate vicinity of spring-discharge points. Horizontal hydraulic conductivity in the Minnelusa Formation also may be enhanced by dissolution processes related to upward leakage from the Madison aquifer. Potential processes could include dissolution resulting from leakage in the vicinity of breccia pipes that are abandoned spring throats, active spring discharge, development of subsurface breccias with no visible surface expression or spring discharge, as well as general areal leakage from the Madison aquifer into the Minnelusa Formation.

South Dakota

Noble and base metal distribution and processes affecting ore tenors in the disrupted lower stratigraphy of the Stillwater Complex, USA

Exploration continues for contact-style Ni-Cu sulfide and chromitite-associated PGE mineralization in ultramafic rocks of the Stillwater Complex. At the Iron and Chrome Mountain areas, massive sulfides occur along the complex’s footwall contact and anomalous concentrations of PGE+Au are associated with the three lowermost chromitite seams. Southeast of Chrome Mountain, magmatic layering is highly disrupted by the presence of faults, magmatic breccias, serpentinized discordant dunites, pyroxenite pegmatoids, and disaggregated chromitite seams. The bulk rock chemistry, sulfide chemistry, and noble metal mineralogy of samples from this area were examined to determine the deportment of PGE and processes that led to enrichments in PGE, Au, Cu, Co and Ni. Results show that a sulfide liquid was the principal collector of PGE. If sulfide liquid was initially deposited with chromite, it was disaggregated or redistributed by subsequent melt or fluid infiltration, which may have resulted in the offset of peak PGE(+Cu, Ni) from peak Cr 2 O 3 concentrations, and upgraded PGE tenors. Upon cooling, PGE exsolved from sulfides to form discrete bismuth tellurides, arsenides, arsenic sulfides, antimonides, and alloys, commonly along the margins of sulfide globules. Calculated metal tenors are highest in the disseminated sulfides southwest of Chrome Mountain, whereas massive and net-textured sulfides near the Iron Mountain-Camp zone represent monosulfide solid solution cumulates. At progressively shallower levels, higher metal tenors combined with lower S/Se ratios are consistent with increasing R-factors from 100 to 100,000. Serpentinization and talc-tremolite alteration resulted in S loss through partial replacement of sulfides by secondary silicate+carbonate+magnetite+sulfide assemblages, further upgrading Ni-Cu-PGE tenors. The present work shows that processes responsible for the disruption of magmatic layering and post-magmatic fluid alteration along the intrusion’s lower contact led to noble and base metal enrichments.

Montana

Evaluation of daily stream temperature predictions (1979-2021) across the contiguous United States using a spatiotemporal aware machine learning algorithm

Stream temperature controls a variety of physical and biological processes that affect ecosystems, human health, and economic activities. We used 42 years (1979–2021) of data to predict daily summary statistics of stream temperature across >50,000 stream reaches in the contiguous United States using a recurrent graph convolution network. We comprehensively documented the performance – both across all reaches and by stream type (e.g., reservoir or groundwater influence) – as a baseline for future improvement. The model showed reach-level RMSE of <2 °C with 90 % prediction intervals that contain 90.7 % of observations. We also assessed how the model captured variability in ecologically relevant metrics (e.g., R 2 for annual 7-day maximum = 0.76; R 2 for days exceeding 25 °C = 0.75). This model does not outperform state-of-the-art machine learning efforts (e.g., RMSE ≤1.5 °C) due to a limited input set but does provide the most spatially complete modeling to date to support water availability assessments.

contiguous United States

Quantitative subsurface characterization illuminates the origin of the Quaternary Mississippi River Valley alluvial aquifer

The Mississippi River Valley alluvial aquifer (MRVA) is vital to U.S. food security and global agricultural supply. However, quantitative understanding of its Quaternary origin, architecture, and hydrologic function remains incomplete. Here we develop a three-dimensional hydrostratigraphic model to characterize the deposition of clay and silt, fine-medium sands, and graveliferous sands using lithologic data from 75,000 boreholes compiled across the Lower Mississippi Valley and a geostatistical method—interval kriging. We find that cyclic glacial entrenchments, evidenced by remnants of pre-Wisconsinan postglacial sediments, alongside geodynamic activities shaped the MRVA basal configuration. Stratal weakening from faulting and salt diapirism enhanced glacial incision and thereby produced abrupt aquifer thickening. We demarcate the top of graveliferous sands as the regional marker of the Pleistocene-Holocene transition. The MRVA hydrostratigraphy reveals hydrologic function and geologic controls on groundwater storage and quality, advancing the assessment of aquifer sustainability under a changing climate, with implications for alluvial aquifers globally.

Arkansas, Illinois, Kentucky, Louisiana, Mississip

Reconnaissance basement geology and tectonics of North Zealandia

New rock dredge samples supply key information to establish the tectonic and geological framework of the northern two-thirds of the 95% submerged Zealandia continent. The R/V Investigator voyage IN2016T01 to the Fairway Ridge, Coral Sea, obtained poorly sorted poly-lithologic pebbly to cobbly sandstones, well sorted fine grained sandstones, mudstones, bioclastic limestones, and basaltic lavas. Post-cruise analytical work comprised petrography, whole rock geochemical and Sr and Nd isotopic analyses, and U-Pb zircon, Rb-Sr, and Ar-Ar geochronology. A Fairway Ridge cobbly sandstone has a ∼95 Ma (early Late Cretaceous) depositional age; two biotite granite cobbles are 111 ± 1 and 128 ± 1 Ma in age, and some volcanic pebbles are also likely Early Cretaceous. Fairway Ridge basalts have intraplate alkaline chemistry and are of Late Eocene age (∼40–36 Ma). By analogy with South Zealandia, we interpret strong positive continental magnetic anomalies of North Zealandia to mainly result from Late Cretaceous to Cenozoic intraplate basalts, many of them rift-related lavas. A new basement geological map of North Zealandia shows the position of the Mesozoic Gondwana magmatic arc axis (Median Batholith) and other major geological units. This study completes onland and offshore reconnaissance geological mapping of the entire 5 Mkm 2 Zealandia continent.

Tectonics

Over, under, and through: Hydrologic connectivity and the future of coastal landscape salinization

Seawater intrusion (SWI) affects coastal landscapes worldwide. Here we describe the hydrologic pathways through which SWI occurs - over land via storm surge or tidal flooding, under land via groundwater transport, and through watersheds via natural and artificial surface water channels—and how human modifications to those pathways alter patterns of SWI. We present an approach to advance understanding of spatiotemporal patterns of salinization that integrates these hydrologic pathways, their interactions, and how humans modify them. We use examples across the East Coast of the United States that exemplify mechanisms of salinization that have been reported around the planet to illustrate how hydrologic connectivity and human modifications alter patterns of SWI. Finally, we suggest a path for advancing SWI science that includes (a) deploying standardized and well-distributed sensor networks at local to global scales that intentionally track SWI fronts, (b) employing remote sensing and geospatial imaging techniques targeted at integrating above and belowground patterns of SWI, and (c) continuing to develop data analysis and model-data fusion techniques to measure the extent, understand the effects, and predict the future of coastal salinization.

Water Resources Research

Geologic map of the southern Stillwater Range, Nevada

The southern Stillwater Range in west-central Nevada contains the western part of the Oligocene Stillwater-Clan Alpine caldera complex, which extends about 55 kilometers (km) east from the west side of the Stillwater Range to the northwestern Desatoya Mountains. The complex consists of at least seven nested ignimbrite calderas and subjacent plutonic rocks emplaced into a complex basement composed of Mesozoic metasedimentary and metavolcanic rocks and Cretaceous granitic plutons. The calderas formed during large-volume (100s to greater than (>) 2,500 cubic kilometers [km 3 ]) eruptions of silicic ignimbrites between about 30.4 and 25.1 million years before present (Ma). The Job Canyon and Poco Canyon calderas and the western part of the much larger Elevenmile Canyon caldera, and their plutonic roots, are exposed in the southern Stillwater Range. There, the caldera complex was steeply tilted during large-magnitude crustal extension in the middle Miocene, and further exhumed during the late Miocene to Holocene Basin and Range extension that formed the modern Stillwater Range. This tilted crustal section affords an exceptional opportunity to view structural cross sections of ignimbrite calderas and their plutonic roots to paleodepths as much as 9–10 km.

Nevada

Regional characterization of coal resources in the U.S. Gulf Coast

There is increasing interest in extracting critical minerals (CM), including rare earth elements (REE), from coals in the United States to address the overreliance on imported REE. The U.S. Gulf Coast and the Williston basins are the two major lignite-bearing basins within the country. Recent REE and CM studies of the lignite in these basins have indicated that the coals may be a viable source material for REE and CM extraction. To evaluate in-place coal as a potential source of REE and CM, the coal resources need to be quantified. This study presents the results of a regional analysis of the U.S. Gulf Coast lignite and bituminous coal resources that might be available as potential sources of REE and CM. The resource analysis used kriging methods to develop isopleth maps of cumulative coal thickness throughout the region using data from 31,181 drill holes and other data points. The estimated total coal resource in the Gulf Coast is about 83 billion metric tons in the upper 90 m (~ 300 ft) of the subsurface. Texas accounted for 40 percent (32 billion metric tons) of the total resource, followed by Mississippi (24 %, 20 billion metric tons), Louisiana (14 %, 12 billion metric tons), Tennessee (10 %, 8.5 billion metric tons), and Arkansas (6 %, 5.1 billion metric tons). The remaining states each accounted for less than 5 percent of the total resource. Georgia had the smallest resource estimated at 7 million metric tons. Here we report the first known state-wide lignite resource estimates for Georgia, Kentucky (820 million metric tons), and Missouri (1,800 million metric tons). A comparison of the results of this study with those of previous Gulf Coast and Williston Basin resource studies is difficult because each study used different data sources, assessment methodologies, overburden depths, and qualifying coal thicknesses. Coal-power electric generation has sharply decreased in past decades and mining of these coals for CM and REE could provide additional co-products such as activated carbon and other uses such as fertilizer (soil enhancer).

EarthArXiv

Monitoring and assessment of urban stormwater best management practices at selected Chicago public schools in Chicago, Illinois, from September 1, 2016, to July 1, 2017

The Space to Grow program helps transform aging and neglected schoolyards of Chicago Public Schools into outdoor community spaces with the goal of promoting health and learning while addressing neighborhood flooding issues. Virgil I. Grissom Elementary School and Donald L. Morrill Math and Science School were selected in 2014 for schoolyard upgrades and the installation of various green infrastructure (GI) improvements. The U.S. Geological Survey installed sensors to measure precipitation, groundwater levels, and stormwater runoff volumes from September 1, 2016, to July 1, 2017. At Virgil I. Grissom Elementary School, about 933,000 gallons of water fell on the schoolyard during the monitoring period. No discharge was recorded coming from the GI sewer lines, but backflow indicated water was flowing from the sewer line draining the impervious running track into the combined manhole structure and backwards into the GI retention basins (as designed). This design allowed for a 100-percent capture rate. Native soil at Virgil I. Grissom Elementary School also was conducive to rapid infiltration. Soil borings at Virgil I. Grissom Elementary School indicated about 10.5 feet (ft) of fine sand overlying silty clay to a depth of at least 16 ft. At Donald L. Morrill Math and Science School, about 1,120,000 gallons of water fell on the schoolyard during the monitoring period. About 72.5 precent of this water was discharged into the sewer system, and the other 27.5 percent was captured by the GI. Unlike Virgil I. Grissom Elementary School, the soil profile at Donald L. Morrill Math and Science School consisted of about 5 ft of clay loam overlying stiff blue clay to a depth of at least 12 ft. The sewer line coming from the GI under the football field was at the bottom of the reservoir. This design seemed to allow water to flow out of the line before being absorbed by the retention basin.

Illinois

Grammar to graph—An approach for semantic transformation of annotations to triples

Data annotation is the process of labeling data to show the outcome that a related data model should predict. In this study, annotation data were transformed into semantic graph triples, mainly for use with the Resource Description Framework (RDF), a type of entity-relationship-attribute data model for graph databases. The transformation of annotation data to semantic graph triples provides complex linguistic meaning with data handling advantages such as reduced data storage needs, improved logical specification of relations between objects, and reusable classes and properties that support logic and inference. A grammar-based framework in graph form supports user questions and queries. The words defining approximately 334 topographic feature types compiled by the U.S. Geological Survey were tokenized as units of analysis and grouped by part of speech. Their dependency relations were identified for this study using natural language processing libraries. Dependency concepts are used as structured semantic relations among part-of-speech classes. Tokens, units equivalent to words, form instances of classes and were quantified within a tabular output format using PostgreSQL data storage software. Table data were logically aligned as triples following a mapping file and stored with an ontology file using Ontop virtual triplestore software. A grammar ontology schema for the data was synchronized to match queries whose results validated the graph’s structure. The text analysis produced 8 part-of-speech classes of content words for object representations and 4 classes of function words for operational applications. Dependency relations formed 27 ontology properties for topographic subgraph structures. Token occurrences shaped overall ontology salience and formed a lexicon of syntactic terms for subgraph objects and properties. The schema ontology of class and property population shapes formed the lexicon of English terms. SPARQL Protocol and RDF Query Language (SPARQL) was used with the lexicon to conform data to RDF guidelines. This study confirms the hypothesis that although linguistic logic varies from description logic, its approximation applies to ontology design. Property and query use case patterns extracted from the analysis support queries concerning complex topographic relations and patterns normally embedded within text definitions. The method used in this study could be applied to text forms in other domains, such as survey notes.

Scientific Investigations Report

Geochemical and hydrological investigations of historical data collected at the Lee Acres Landfill and Giant Bloomfield Refinery, New Mexico, 1985–2020

The Lee Acres Landfill and Giant Bloomfield Refinery are adjacent properties near the City of Farmington, New Mexico, each having undergone monitoring and remediation related to historical site activities. At the landfill, site cleanup has included the installation of a capillary barrier over former liquid waste lagoons and periodic monitoring of groundwater elevations and groundwater quality. At the refinery, remediation has focused on several petrochemical and crude oil release areas and included soil excavation, groundwater treatment, and regular monitoring of groundwater elevations and quality. Groundwater at both sites has higher concentrations of volatile organic compounds and trace metals than background aquifer concentrations. In 2022, the U.S. Geological Survey compiled the Lee Acres-Giant Bloomfield Refinery Database (LAGBRD), which contains publicly available groundwater-elevation data and organic and inorganic groundwater-quality data from both sites, spanning from 1985 to 2020. Data from the LAGBRD and precipitation data from other sources were used to better understand the cause of relatively high manganese concentrations observed in some groundwater wells at the site through comparison of groundwater chemistry to chemical end members, interpretation of spatial and temporal patterns in the groundwater chemistry, and interpretation of groundwater flow properties. In this study, elevated chloride concentrations in groundwater downgradient from the landfill have been attributed to landfill leachate based on the temporal and spatial variability of chloride concentrations and chloride-to-bromide ratios. Installation of a capillary barrier and surface-water runoff controls at the landfill in 2005 appears to have altered infiltration patterns at that site, resulting in a decrease in chloride at some wells but an increase in chloride and dissolved manganese at others. The timing and relation among groundwater elevation, chloride concentration, and manganese concentration suggest that leachate stored in the vadose zone provides a continued source of contamination to groundwater.

New Mexico

Projections of multiple climate-related coastal hazards for the US Southeast Atlantic

Faced with accelerating sea level rise and changing ocean storm conditions, coastal communities require comprehensive assessments of climate-driven hazard impacts to inform adaptation measures. Previous studies have focused on flooding but rarely on other climate-related coastal hazards, such as subsidence, beach erosion and groundwater. Here, we project societal exposure to multiple hazards along the Southeast Atlantic coast of the United States. Assuming 1 m of sea level rise, more than 70% of the coastal residents and US \ $ 1 trillion in property are in areas projected to experience shallow and emerging groundwater, 15 times higher than daily flooding. Storms increase flooding exposure by an order of magnitude over daily flooding, which could impact up to ~50% of all coastal residents and US \ $ 770 billion in property value. The loss of up to ~80% of present-day beaches and high subsidence rates that currently affect over 1 million residents will exacerbate flooding and groundwater hazard risks.

Florida, Georgia, North Carolina, South Carolina,

Metal mobilization from thawing permafrost to aquatic ecosystems is driving rusting of Arctic streams

Climate change in the Arctic is altering watershed hydrologic processes and biogeochemistry. Here, we present an emergent threat to Arctic watersheds based on observations from 75 streams in Alaska’s Brooks Range that recently turned orange, reflecting increased loading of iron and toxic metals. Using remote sensing, we constrain the timing of stream discoloration to the last 10 years, a period of rapid warming and snowfall, suggesting impairment is likely due to permafrost thaw. Thawing permafrost can foster chemical weathering of minerals, microbial reduction of soil iron, and groundwater transport of metals to streams. Compared to clear reference streams, orange streams have lower pH, higher turbidity, and higher sulfate, iron, and trace metal concentrations, supporting sulfide mineral weathering as a primary mobilization process. Stream discoloration was associated with dramatic declines in macroinvertebrate diversity and fish abundance. These findings have considerable implications for drinking water supplies and subsistence fisheries in rural Alaska.

Alaska

Biodegradation of chlorinated ethenes at a karst site in middle Tennessee

This report presents results of field and laboratory investigations examining the biodegradation of chlorinated ethenes in a karst aquifer contaminated with trichloroethylene (TCE). The study site, located in Middle Tennessee, was selected because of the presence of TCE degradation byproducts in the karst aquifer and available site hydrologic and chlorinated-ethene information. Additional chemical, biological, and hydrologic data were gathered to evaluate whether the occurrence of TCE degradation byproducts in the karst aquifer was the result of biodegradation within the aquifer or simply transport into the aquifer. Geochemical analysis established that sulfate-reducing conditions, essential for reductive dechlorination of chlorinated solvents, existed in parts of the contaminated karst aquifer. Other areas of the aquifer fluctuated between anaerobic and aerobic conditions and contained compounds associated with cometabolism, such as ethane, methane, ammonia, and dissolved oxygen. A large, diverse bacteria population inhabits the contaminated aquifer. Bacteria known to biodegrade TCE and other chlorinated solvents, such as sulfate-reducers, methanotrophs, and ammonia-oxidizers, were identified from karst-aquifer water using the RNA-hybridization technique. Results from microcosms using raw karst-aquifer water found that aerobic cometabolism and anaerobic reductive-dechlorination degradation processes were possible when appropriate conditions were established in the microcosms. These chemical and biological results provide circumstantial evidence that several biodegradation processes are active in the aquifer. Additional site hydrologic information was developed to determine if appropriate conditions persist long enough in the karst aquifer for these biodegradation processes to be significant. Continuous monitoring devices placed in four wells during the spring of 1998 indicated that pH, specific conductance, dissolved oxygen, and oxidation-reduction potentials changed very little in areas isolated from active ground-water flow paths. These stable areas in the karst aquifer had geochemical conditions and bacteria conducive to reductive dechlorination of chlorinated ethenes. Other areas of the karst aquifer were associated with active ground-water flow paths and fluctuated between anaerobic and aerobic conditions in response to rain events. Associated with this dynamic environment were bacteria and geochemical conditions conducive to cometabolism. In summary, multiple lines of evidence developed from chemical, biological, and hydrologic data demonstrate that a variety of biodegradation processes are active in this karst aquifer.

Tennessee

Status of water-quality conditions in the United States, 2010–20

Degradation of water quality can make water harmful or unusable for humans and ecosystems. Although many studies have assessed the effect of individual constituents or narrow suites of constituents on freshwater systems, no consistent, comprehensive assessment exists over the wide range of water-quality effects on water availability. Using published studies, data, and models completed at regional or national scales in the United States during 2010–20, this chapter moves towards a comprehensive assessment by summarizing how selected anthropogenic and geogenic water-quality constituents affect national-scale water availability for human and ecosystem needs. Several types of human health, agricultural, ecological, and beneficial-use standards or thresholds were used to provide context for categorizing surface-water and groundwater quality. Water availability for human and ecological use is limited by elevated concentrations of geogenic and anthropogenic constituents in surface and groundwater. Elevated concentrations of five geogenic constituents (arsenic, manganese, strontium, radium, and adjusted gross alpha) are common in groundwater and collectively affect the drinking water supply to over 30 million people. Surface water sourced drinking water supplies are impaired in about a third of assessed stream miles, most commonly because of non-mercury metals and salinity. Health-based violations at community water systems may disproportionately affect socially vulnerable communities. Ecological water uses are predominantly limited by nutrients, sediment, temperature, pathogens, salinity, and pesticides. Water availability for human and ecological use is adversely affected by human activities including human contaminant sources (for example, wastewater, agriculture), processes (for example, dredging, groundwater pumping), or permanent landscape modifications (for example, dams, urbanization). Primary contaminant sources vary spatially and include fertilizer and manure, atmospheric deposition, wastewater treatment plants, urban land, and a range of natural sources. Contaminants of emerging concern, contaminants without regulatory thresholds, and mixtures of geogenic and anthropogenic water contaminants also contribute to ecological degradation and human exposure.

conterminous United States