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A regional model comparison between MODPATH and MT3D of groundwater travel time distributions

Groundwater quality changes in wells and streams lag behind changes to land use due to groundwater travel times. Two contaminant transport methods were compared to assess differences in their simulated travel time distributions (TTDs) to streams and wells in the Wisconsin Central Sands. MODPATH simulates advective groundwater flow with particle tracking, while MT3D simulates age-mass using a finite difference solution without dispersion to allow for direct comparison of the two methods. MODPATH appropriately simulates groundwater TTDs from the water table to surface discharge but is subject to inaccuracies at weak-sink well cells due to the flow-model grid discretization and imprecise location of well discharge within well cells. MT3D better represents weak-sink well cells since it removes mass in proportion to the prescribed pumping rate, although travel time within well cells is neglected. Conversely, MT3D's treatment of surface water boundary cells is not as accurate as MODPATH because mass should be removed from the water table rather than the full cell volume. MT3D simulations of TTDs can also be confounded by the instantaneous vertical distribution of mass introduced throughout recharge cells instead of at the water table, which initiates mass along deeper flow paths. We evaluated 9 MODPATH and 13 MT3D implementations, generating differences in median travel times of up to 18 years. Both methods have strengths and weaknesses, with MT3D better representing weak-sink well cell behavior and MODPATH better representing surficial recharge and discharge. The effect of these characteristics on simulated TTDs, along with ideas for ameliorating method weaknesses, is discussed.

Wisconsin

Potential warming-induced changes in stream water sources between proglacial and non-glacial streams, south-central Alaska

Snow and ice-melt are essential for global water resources. Rising air temperatures are causing vegetation encroachment and shrubification of previously snow- and ice-covered landscapes, and precipitation regimes are changing. Collectively, these changes will likely affect the hydrology of mountain environments, although the exact ways in which the hydrology will change are poorly understood. Changing source waters (i.e., the proportion of ice-melt, snowmelt, rain and groundwater) affect the timing and magnitude of streamflow and affect stream temperature, sediment, solute and nutrient fluxes. We investigate spatial and seasonal source water contributions across sub-watersheds of the Nellie Juan River watershed on Alaska's Kenai Peninsula, which differ in glacier cover, elevation and land cover, using a space-for-time approach. To do so, we use a three-endmember mixing model to quantify the contribution of rain, snow/ice-melt and deep groundwater. We show that snow/ice-melt peak later in proglacial streams compared to non-glacial streams. Endmember contributions in non-glacial streams generally vary with elevation and season. We also found that groundwater is a major contributor to streamflow across the study area, contributing between 12% and 47% seasonally, and may become increasingly important as snowpack and ice-melt decrease. This research characterises the shift from a glacierised to a deglaciating landscape through the lens of source water contribution. Broadly, these findings could help improve understanding of how water resources in glacierised watersheds are affected by warming air temperatures.

Alaska

Prioritizing US Geological Survey science on salinization and salinity in candidate and selected priority river basins

The US Geological Survey (USGS) is selecting and prioritizing basins, known as Integrated Water Science basins, for monitoring and intensive study. Previous efforts to aid in this selection process include a scientifically defensible and quantitative assessment of basins facing human-caused water resource challenges (Van Metre et al. in Environmental Monitoring and Assessment , 192(7), 458 2020). In the present work, we explore this ranking process based on water quality considerations, specifically salinity and salinization. We selected top candidate basins to study salinity and salinization issues in 18 hydrologic regions that include 163 candidate basins. Our prioritization is based on quantitative assessment of sources of salinity, drivers of change, and receptors that must respond to those sources and drivers. Source terms represented in the prioritization include geology, depth to brackish groundwater, stream conductivity, chloride in precipitation, urban and agricultural land use, application of road salt as a deicer, and irrigation. Drivers represented in prioritization include changes in chemical weathering as a result of changes in rainwater chemistry. Receptors include measures of water stress, measurements of stream ecological health, and socioeconomic factors. In addition, we present research activities for the USGS on salinity and salinization that can be pursued in these basins including assessment of sources, pathways, and loadings; predicting and understanding changes in sources, peaks, and trends; understanding the components of salinity and mobilization of contaminants; understanding the relationship between salinization and changing ecosystems; and developing knowledge on the causes and distribution of groundwater salinity, brackish water resources, and challenges related to desalination.

Enviornmental Monitoring and Assessment

Hydrologic response of groundwater and streamflow to natural and anthropogenic drivers of change in headwaters of the upper Colorado River basin during recent wet (1982–1999) and drought (2000–2022) conditions

Study region: Headwaters of the upper Colorado River basin (UCOL), USA Study focus: Surface-water and groundwater numerical models incorporating water-use information were used to investigate changes in climate, water use, and simulated hydrologic responses of snow processes, evapotranspiration, groundwater, and streamflow during recent wet (1982–1999) and drought (2000–2022) periods in the headwater subregions of the upper Colorado River basin. New hydrologic insights for the region: Decreases in average streamflow between wet and drought periods ranged from 20 % in the Colorado River headwaters subregion to 23 % in the Gunnison River headwaters subregion. Like streamflow, average surface runoff was statistically less during the drought than the wet period, with decreases from 24–31 % in the headwaters. On a volume basis, runoff decreases were greater than streamflow decreases in both the Colorado River and Gunnison River headwaters. Although the amount of water-year groundwater discharge to streams remained nearly the same between the wet and drought periods, groundwater as a percentage of streamflow increased between the wet and drought periods, highlighting the importance of groundwater in sustaining streamflow during drought conditions. Multiple linear regression analyses revealed that snowmelt-only models were better than the best precipitation and temperature models at explaining streamflow variability from all headwater subregions for both the wet and drought periods.

Arizona, Colorado, New Mexico, Utah, Wyoming

An environmental assessment of impacts of coal development on the water resources of the Yampa River basin, Colorado and Wyoming; Phase I work plan

Coal resources of the western United States are being developed at ever-increasing rates, causing concerns of the effects of mining and associated activities on the environment. The Yampa River basin in northwestern Colorado and south-central Wyoming is undergoing economic development of its coal, oil and gas, and uranium resources. The Yampa River basin assessment is a 21-year program of the U.S. Geological Survey. It is designed primarily to assess the availability and quality of the basin's water resources. The basin assessment also will evaluate potential environmental and selected socioeconomic impacts of energy-resource development plans proposed by mining and power companies. This report serves as a project work plan for the basin assessment's first-phase work activities. Economic development in the Yampa River basin will result in higher levels of residuals (noneconomic byproducts) being discharged into the environment. Residuals-management encompasses the technological and economic interrelationships that should be considered in order to comply with Federal and State environmental-control regulations regarding air quality, water quality, and disposal of solid wastes. The basin assessment, the first phase that is described by this report, is designed to provide Federal, State, and local decision-makers with the basic environmental information needed to formulate and to evaluate policies for the development of energy resources. The techniques applied and conclusions reached in the Yampa River basin assessment should aid similar studies of other energy-rich basins in the western United States.

Colorado, Wyoming

Ecohydrological response of a forested headwater catchment to a flash drought in the Southeastern U.S.

Flash droughts differ from traditionally defined droughts in their rapidity of intensification and often associated high vapor-pressure deficit. These droughts can lead to declines in streamflow and water table depth and induce water stress to vegetation at a greater rate than droughts that manifest over longer periods. However, little is known regarding the response of forested environments to flash drought because most studies of impacts have been conducted in agricultural settings. In this study we investigated water-use patterns of riparian trees using sap flow methods and examined the role of groundwater as a source of moisture over three periods that were delimited by antecedent soil moisture conditions. For a longer-term perspective we also examine monthly streamflow over the 35-year record. We observed that trees at only one monitoring plot showed a decrease in water use relative to evaporative demand during a flash drought. Total reverse sap flow (flow toward the roots rather than the canopy) greatly increased during the flash drought period, suggesting the likely occurrence of hydraulic redistribution to the excessively dry soils. Over the drought period groundwater became a more dominant source of moisture for sustaining forest water use. Monthly mean streamflow during the flash drought approached levels observed in past multiyear droughts. This is the first study, to our knowledge, to specifically investigate the response of multiple water budget components to flash drought in a humid forest. As more studies are conducted, a better understanding of the range of expected responses are likely to emerge.

Georgia

Extremophile hotspots linked to containerized industrial waste dumping in a deep-sea basin

Decaying barrels on the seafloor linked to DDT contamination have raised concerns about the public health implications of decades old industrial waste dumped off the coast of Los Angeles. To explore their contents, we collected sediment cores perpendicular to five deep-sea barrels. The concentration of DDT and its breakdown products were highly elevated relative to control sites yet did not vary with distance from the barrels, suggesting that they were not associated with the contamination. Sediment cores collected through white halos surrounding three barrels were enriched in calcite and had elevated pH. The associated microbial communities were low diversity and dominated by alkalophilic bacteria with metagenome-assembled genomes adapted to high pH. A solid concretion sampled between a white halo and barrel was composed of brucite, a magnesium hydroxide mineral that forms at high pH. Based on these findings, we postulate that leakage of containerized alkaline waste triggered the formation of mineral concretions that are slowly dissolving and raising the pH of the surrounding sediment pore water. This selects for taxa adapted to extreme alkalinity and drives the precipitation of “anthropogenic” carbonates forming white halos, which serve as a visual identifier of barrels that contained alkaline waste. Remarkably, containerized alkaline waste discarded >50 years ago represents a persistent pollutant creating localized mineral formations and microbial communities that resemble those observed at some hydrothermal systems. These formations were observed at one-third of the visually identified barrels in the San Pedro Basin and have unforeseen, long-term consequences for benthic communities in the region.

California

How do hydrological variability and human activities control the spatiotemporal changes of riverine nitrogen export in the Upper Mississippi River Basin?

Excessive nitrogen export from agricultural watersheds remains a critical water quality challenge, with the Upper Mississippi River Basin (UMRB) significantly contributing to downstream eutrophication and hypoxia in the Gulf. This study investigates the spatiotemporal dynamics of riverine nitrate plus nitrite (NO 3 – + NO 2 – -N) export across the UMRB at high spatial resolution (12-digit Hydrologic Unit Codes or HUC12 subwatershed scale) during 2001–2020 and quantifies the effects of anthropogenic activities and hydrological variability on riverine NO 3 – + NO 2 – -N export changes in the region between 2001–2005 and 2016–2020. Our results revealed hotspots of substantial increases in NO 3 – + NO 2 – -N yields across the UMRB, with distinct regional patterns in driving factors. Over the entire UMRB, NO 3 – + NO 2 – -N yields increased by 9.7 kg/ha/yr on average from 2001–2005 to 2016–2020, with anthropogenic activities contributing 4.8 kg/ha/yr and hydrological variability contributing 4.9 kg/ha/yr. The northern and western UMRB had combined influences from both anthropogenic activities and hydrological variability, while the east-central regions had predominantly hydrologically driven changes. Agricultural sources, including fertilizer, manure, and biological nitrogen fixation, collectively contributed over 80% of NO 3 – + NO 2 – -N loading throughout the basin. This framework for disentangling human and hydrological impacts provides critical insights for developing effective and targeted watershed management strategies to reduce nutrient losses and improve water quality.

Upper Mississippi River Basin

Toward a new framework to evaluate process-based model configurations and quantify data worth prior to calibration

Model criticism, discrimination, and selection methods often rely on calibrated model outputs. Because calibration can be computationally expensive, model criticism can first be undertaken by assessing model outputs obtained from limited prior parameter ensembles. However, such prior-based methods are often heuristic and do not formalize the notion of balancing model consistency with data and model complexity (i.e., model adequacy). We present a new framework to discriminate among candidate models prior to calibration that formalizes prior-to-calibration model adequacy into a metric to implicitly balance prior model output data coverage with model complexity represented by prior output (co)variance. The prior model adequacy metric “Mahalanobis distance deviation” quantifies the deviation of (a) the set of squared Mahalanobis distances of data from a prior model output distribution from (b) the set of squared Mahalanobis distances of data from their own distribution. A new data worth metric “discernment value” is also presented which quantifies the value of data for screening less-adequate models prior to calibration. Discernment value is calculated from the change in variance of a weighted average of prior model outputs from all candidate models due to less-adequate model outputs receiving lower weight. The framework is demonstrated using a one-dimensional groundwater flow model with eight possible configurations. A synthetic data network is used to test the framework. Results show the framework identifies the candidate models most similar to the true model used to create the synthetic data. Discernment values show variation in the value of different data types and locations for screening less-adequate models.

Water Resources Research

Ground-water quality near an inactive landfill and sludge-spreading area, Tallahassee, Florida

Ground-water quality of a 120-acre area encompassing an inactive landfill southwest of Tallahassee, Florida, was assessed by installing and sampling 21 monitoring wells. Sludge from a municipal sewage-treatment plant was also applied to the land surface near the landfill site. Water samples were collected from the 21 monitoring wells from June 1987 through September 1990 and analyzed for concentrations of major ions, nitrogen species, trace metals, field measurements, and more than 140 organic constituents. Water quality in the Upper Floridan aquifer at the study site was compared to background water quality in other areas of Leon County. Ground-water quality of the study site was evaluated by the location of wells sampled in relation to the landfill and the sludge-spreading areas. Results of nonparametric statistical analysis indicated that potassium and nitrite plus nitrate as nitrogen concentrations in water samples from wells completed in the Upper Floridan aquifer at the study site were significantly different at the 5 percent probability level from those in samples from background wells completed in this aquifer in Leon County. Median potassium concentrations were 0.4 mg/L (milligrams per liter) in water from wells at the study site and 0.7 mg/L in water from background wells in Leon County. Median nitrite plus nitrate concentrations were 6.48 mg/L in water samples from wells at the study site and 0.51 mg/L in water samples from background wells. Graphical comparison of the water quality characteristics in water from six categories of wells; upgradient, landfill, adjacent to the landfill, downgradient onsite, downgradient offsite, and background Leon County, indicated that sodium, bicarbonate, sulfate, iron, manganese, and dissolved solids concentrations and specific conductance values were highest within the landfill. Upgradient and downgradient well categories include wells in areas affected by sludge spreading. Localized reducing conditions were indicated in a downgradient area by median iron concentrations of 930 and 30 ug/L (micrograms per liter) in samples from wells only 5 feet apart. Nitrite plus nitrate concentrations were lowest in water from wells in the landfill compared to water from the other categories. Concentrations of most trace elements and organic compounds were mostly below detection limits, although State maximum contaminant levels of 1 ug/L for benzene and vinyl chloride and 3 ug/L for tetrachloroethene were exceeded in 14 samples. Concentrations of sodium, potassium, chloride, sulfate, nitrite plus nitrate, total organic and ammonia nitrogen, and ammonia nitrogen in ground water were statistically analyzed in areas affected by sludge-spreading and other areas. Only nitrite plus nitrate and chloride concentrations were significantly different between the two areas. Median nitrite plus nitrate and chloride concentrations in sludge-spreading areas were 6.9 mg/L and 2.9 mg/L, respectively, compared to 1.1 mg/L and 1.8 mg/L in other areas.

Florida

Microclimate mediates the strength and direction of avian biotic interactions

Theory predicts that that the strength and direction of species interactions can shift from being competitive in benign environments toward being facilitative in stressful environments. However, the environmental context dependency of species interactions has rarely been tested in animal communities. We capitalized on a 15-year, landscape-scale dataset, collected annually in a relatively stable old-growth forest environment to test the long-held hypothesis that the strength and direction of species interactions might be mediated by climatic conditions. It is generally accepted that competitive and facilitative interactions drive the distributions of many species. Using multi-species dynamic occupancy models applied to long-term data, we tested whether annual settlement by bird species could affect either the persistence or settlement by other phylogenetically related species, and whether these interactions are mediated by microclimate. We found that species interactions were influenced by microclimate for some, but not all avian species pairs. Related species pairs more often showed settlement dynamics that were indicative of attraction rather than repulsion. In some cases, competitive interactions at warmer microclimates flipped to become facilitative in colder ones. However, the reverse was also true: facilitative interactions amplified for some species under warm conditions. Furthermore, species pairs that were closely related were more likely to exhibit competitive relationships along at least part of the microclimatic gradient. Our results highlight the importance of using long-term data to incorporate competitive and facilitative interactions into species distribution models and support the notion that the strength and direction of species interactions can be dependent on microclimatic environmental conditions.

Oregon

Submarine avalanche deposits hold clues to past earthquakes

Earthquakes and other natural events sometimes shake the seafloor near coastlines severely enough to cause underwater avalanches that rush down steep slopes, scouring the seabed and carrying sediment to greater depths. These fast-moving sediment-laden flows, called turbidity currents , have at times damaged underwater infrastructure like pipelines and communications cables, as they did, for example, in snapping transatlantic cables off the coast of Newfoundland after the 1929 Grand Banks earthquake.

EOS Transactions

ShakeAlert® and schools: Incorporating earthquake early warning in school districts in Alaska, California, Oregon, and Washington

The U.S. Geological Survey-managed ShakeAlert® earthquake early warning system is the first public alerting system in the United States to provide rapid mass notification when an earthquake is detected. Although public alert delivery via mobile phones began in California in 2019 followed by Oregon and Washington in 2021, little is known about what might drive widespread implementation in at-risk institutional settings such as schools. For example, there has been limited research on how to best integrate earthquake early warning into existing emergency plans, alert systems, and drills to keep school children and personnel safe in an earthquake. To address this gap, in the spring of 2022, every school district superintendent in Alaska, California, Oregon, and Washington was sent a 15-min online survey. The survey assessed superintendent knowledge of ShakeAlert, preferences for alert messaging, and perceived opportunities and barriers to incorporating the system in schools. The results showed that superintendents had low awareness of ShakeAlert but held positive perceptions of the system's potential to enable life-saving protective actions. A major barrier to adoption included the perceived financial cost of implementing and maintaining the system. There were some statistically significant differences in state responses, and future research could investigate the specific needs of each state based on school district size and composition, hazard exposure, and earthquake experience. Together these findings can help inform targeted strategies to increase ShakeAlert adoption in schools and ultimately improve the safety of school children and staff during earthquakes.

Alaska, California, Oregon, Washington

Modeling byproduct and coproduct mine production and mineral substitution using multidimensional supply curves: Application to the Cu-Co-Ni system and beyond

Rapid demand growth is expected for many metals used in the energy transition. Many of these metals are byproducts of other commodities. Byproduct production’s price response is tied to host mineral economics, complicating its supply dynamics. Moreover, many of these metals are used in applications where the material properties desired are difficult to substitute; effectively, limiting how quickly demand can adapt to changes in commodity price. Previous work has demonstrated the interconnectivity of jointly produced mineral commodities from the supply side, where the copper–cobalt–nickel system was used and demand was assumed independent across commodities. Studies to understand byproduct-coproduct market interconnectivity on the demand side are limited, while studies on the interconnectivity of supply and demand simultaneously are even more so. We propose a modification to the multicommodity supply curve method to enable inter-commodity effects on demand simultaneous with supply. In batteries, high cobaltprices may push consumers to transition to high-nickel chemistries, causing the nickel demand surface to decrease with nickel price but increase with cobaltprice, creating a two-dimensional demand surface. Below cross-price elasticities of 0.05, inter-commodity effects were found to be negligible, potentially permitting exclusion of these effects for many commodities. This additional demand curve complexity introduces potential computation challenges alongside the capacity to model many interrelated commodity systems such as rare earth elements, ferroalloys, country-oriented subsidies or restrictions, and bifurcated sustainable metals markets. By presenting the work done on multicommodity supply surfaces to date and potential new directions, this work aims to catalyze the next round of innovative approaches to modeling jointly produced commodities.

Conference Paper

Anaerobic biodegradation of perfluorooctane sulfonate (PFOS) and microbial community composition in soil amended with a dechlorinating culture and chlorinated solvents

Perfluorooctane sulfonate (PFOS), one of the most frequently detected per - and polyfluoroalkyl substances (PFAS) occurring in soil, surface water, and groundwater near sites contaminated with aqueous film-forming foam (AFFF), has proven to be recalcitrant to many destructive remedies, including chemical oxidation. We investigated the potential to utilize microbially mediated reduction (bioreduction) to degrade PFOS and other PFAS through addition of a known dehalogenating culture, WBC-2, to soil obtained from an AFFF-contaminated site. A substantial decrease in total mass of PFOS (soil and water) was observed in microcosms amended with WBC-2 and chlorinated volatile organic compound (cVOC) co-contaminants — 46.4 ± 11.0 % removal of PFOS over the 45-day experiment. In contrast, perfluorooctanoate (PFOA) and 6:2 fluorotelomer sulfonate (6:2 FTS) concentrations did not decrease in the same microcosms. The low or non-detectable concentrations of potential metabolites in full PFAS analyses, including after application of the total oxidizable precursor assay, indicated that defluorination occurred to non-fluorinated compounds or ultrashort-chain PFAS. Nevertheless, additional research on the metabolites and degradation pathways is needed. Population abundances of known dehalorespirers did not change with PFOS removal during the experiment, making their association with PFOS removal unclear. An increased abundance of sulfate reducers in the genus Desulfosporosinus (Firmicutes) and Sulfurospirillum (Campilobacterota) was observed with PFOS removal, most likely linked to initiation of biodegradation by desulfonation. These results have important implications for development of in situ bioremediation methods for PFAS and advancing knowledge of natural attenuation processes.

Science of the Total Environment

A 10-year continuous daily simulation of chloride flux from a suburban watershed in Fairfax County, Virginia, USA

Increasing levels of chloride in surface water are associated with detrimental effects on water quality, aquatic ecosystems, infrastructure, and human health. Numerous mass-balance studies have inferred watershed transport processes by interpreting chloride inputs and outputs, but few represent internal dynamics explicitly. We constructed a coupled water/chloride mass balance model to gain insights into storage, residence time, and transport processes in a 10-km 2 urban watershed. The model, which operates over a 10-year period at a daily time scale, represents storage in a dynamic soil-moisture reservoir, quick-flow runoff from storm events, and slow-flow runoff that sustains streamflow in dry weather. The calibrated model accurately represented (a)the observed transition from a streamflow enrichment regime in cold months to a dilution regime in warmer months, (b) the observed tendency for late-summer concentrations to be higher after winters with heavy snowfall, and (c) a period-of-record downward trend in chloride concentration likely associated with a downward trend in annual snowfall. Estimated chloride inputs averaged 195 metric tons per year, while the average output was 270 metric tons per year. In contrast, estimated storage was only 107 metric tons. The estimated mean residence time in groundwater was 1.27 years. This short residence time indicates that efforts to reduce inputs will manifest as decreased concentrations in streamflow on a management-relevant time scale of several years. The coupled mass balance model yielded insights into internal watershed dynamics that would not be possible from simple input/output analysis; such models can be useful tools for gaining insight into small watershed hydrology and pollutant transport.

Virginia

Using subducting plate motion to constrain Cascadia slab geometry and interface strength

Subduction zones are home to multiple geohazards driven by the evolution of the regional tectonics, including earthquakes, volcanic eruptions and landslides. Past evolution builds the present-day structure of the margin, while the present-day configuration of the system determines the state-of-stress in which individual hazardous events manifest. Regional simulations of subduction zones provide a tool to synthesize the tectonic history of a region and investigate how geologic features lead to variations in the state of stress across the subduction system. However, it is challenging to design regional models that provide a force-balance that is consistent with the large-scale motion of surrounding tectonic plates while also not over-constraining the solution. Here, we present new models for the Cascadia subduction zone that meet these criteria and demonstrate how the motion of the subducting Juan de Fuca plate can be used to determine the along-strike variations in the viscous (long-term) coupling across the plate boundary. All successful models require lower viscous coupling in the northern section of the trench compared to the central and southern sections. However, due to uncertainties in the geometry of the Cascadia slab, we find that there is a trade-off between along-strike variation in viscous coupling and slab shape. Better constraints on the slab shape, and/or use of other observations are needed to resolve this trade-off. The approach presented here provides a framework for further exploring how geologic features in the overriding plate and the properties of the plate boundary region affect the state-of-stress across this and other subduction zones.

Cascadia subduction zone

New constraints on location and timing of the Great Lakes tectonic zone, central Upper Peninsula, Michigan, USA

The Great Lakes tectonic zone (GLTZ) forms the boundary between the Wawa–Abitibi and Minnesota River Valley subprovinces within the Archean Superior Province. The GLTZ is concealed for all of its 1100 km length, except for a segment in the central Upper Peninsula of Michigan. There, it is exposed as a northwest-striking mylonite zone along a 11 km segment, extending to the onlap of Paleozoic rocks to the east. Farther east, its location has been unknown. Here, we use aeromagnetic and gravity data to develop interpretations of the expression of the GLTZ and to define its extent under cover. Aeromagnetic gradients over the mylonite zone are interpreted to be produced by structurally juxtaposed rocks with varying magnetizations. Gravity data show a regional gradient along the GLTZ, produced by the juxtaposition of a dense greenstone belt on the north against lower-density gneisses and granites on the south. The GLTZ is interpreted to extend ∼55 km under cover to the east. The GLTZ is terminated on the east by the buried eastern arm of the ca. 1100 Ma Midcontinent Rift. An undeformed granitic dike that cuts the mylonitic foliation produces a U–Pb apatite age of 2523 ± 33 Ma, implying no major post-Archean shearing occurred, and is at odds with previous interpretations of major Proterozoic reactivation. A granite intrusion in the Minnesota River Valley subprovince produces a Pb–Pb zircon age of 2606.9 ± 3.6/7.4 Ma. This suggests that magmatism related to the Sacred Heart orogeny, previously known in Minnesota, extended to Michigan.

Michigan