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At least 973 records · Page 54Linked to original sources

Translational and fluctuating asymmetry as tools to detect stress in stress-adapted and nonadapted plants

Plants having experienced previous exposure to a stress are expected to be more resistant to further stress than those not having been exposed. While the assessment of stress in plants is a difficult task, particularly for stress-adapted plants, developmental instability has proven a useful tool for assessing stress in organisms. We examined the effect of water availability on developmental instability (translational asymmetry and fluctuating asymmetry) and growth of Anthyllis cytisoides L. under a precipitation gradient. We compared A. cytisoides in very xeric (Almeri??a, 256 mm of average rainfall) and subhumid (Ma??laga, 613 mm of average rainfall) areas, from north- and south-facing slopes, after both a period of extreme drought (1995) and a humid period (1997). Translational symmetry varied between north- and south-exposed plants but differently for the Almeri??a and Ma??laga populations. We observed that developmental stability was enhanced in south-exposed plants in the population from the more xeric habitat (Almeri??a) after both dry and humid periods. In contrast, A. cytisoides living in a subhumid habitat did not alter their developmental stability in response to exposure after a humid period but exhibited a decline in stability in south-exposed slopes after a dry period. That is interpreted as a consequence of the adaptation of A. cytisoides to aridity. Growth patterns were also investigated. By reducing growth, plants can mitigate stress through a reduction of water and nutrient demands, allowing the maintenance of a steady supply of nutrients for developmental stability. This strategy was followed by plants acclimated to drought. But in mild weather, such as that of Montes de Ma??laga, a high growth rate cannot be supported when water is scarce. We also observed that floral fluctuating asymmetry was greatest on north-facing slopes at both the Almeri??a and Ma??laga sites. That is, southern exposure enhanced floral homeostasis during development. Additionally, comparisons between translational and fluctuating asymmetry showed that translational asymmetry is more sensitive to environmental change than fluctuating asymmetry.

International Journal of Plant Sciences↗

Comparison of stable isotope reference samples

Use of light stable isotope ratio measurements has proliferated in the past decade. The need for procuring additional stable isotope reference materials was recognized at an International Atomic Energy Agency (IAEA) consultants' meeting convened in 1976 1 . This group recommended acquisition of two carbonates, two carbon dioxide samples, a biotite, a sulphate, and other reference materials. We report here on the mass-spectrometric analysis of these and other reference samples in a single laboratory to minimize interlaboratory calibration errors. A result of this work is an improved equation for relating the PDB isotope scale (belemnite from the Peedee Formation of South Carolina adopted in the 1950s as a reference in palaeotemperature studies 2 ) to the V-SMOW (Vienna-Standard Mean Ocean Water) scale 1 .

Nature↗

Quantifying stream thermal regimes at management-pertinent scales: combining thermal infrared and stationary stream temperature data in a novel modeling framework.

Accurately quantifying stream thermal regimes can be challenging because stream temperatures are often spatially and temporally heterogeneous. In this study, we present a novel modeling framework that combines stream temperature data sets that are continuous in either space or time. Specifically, we merged the fine spatial resolution of thermal infrared (TIR) imagery with hourly data from 10 stationary temperature loggers in a 100 km portion of the Big Hole River, MT, USA. This combination allowed us to estimate summer thermal conditions at a relatively fine spatial resolution (every 100 m of stream length) over a large extent of stream (100 km of stream) during during the warmest part of the summer. Rigorous evaluation, including internal validation, external validation with spatially continuous instream temperature measurements collected from a Langrangian frame of reference, and sensitivity analyses, suggests the model was capable of accurately estimating longitudinal patterns in summer stream temperatures for this system Results revealed considerable spatial and temporal heterogeneity in summer stream temperatures and highlighted the value of assessing thermal regimes at relatively fine spatial and temporal scales. Preserving spatial and temporal variability and structure in abiotic stream data provides a critical foundation for understanding the dynamic, multiscale habitat needs of mobile stream organisms. Similarly, enhanced understanding of spatial and temporal variation in dynamic water quality attributes, including temporal sequence and spatial arrangement, can guide strategic placement of monitoring equipment that will subsequently capture variation in environmental conditions directly pertinent to research and management objectives.

Montana↗

Sodium cyanide hazards to fish and other wildlife from gold mining operations

Highly toxic sodium cyanide (NaCN) is used increasingly by the international mining community to extract gold and other precious metals through milling of high grade ores and heap leaching of low grade ores. Of the 98 million kg cyanide (CN) consumed in North America in 1989, about 80% was used in gold mining (Knudson 1990). In Canada, more than 90% of the mined gold is extracted from ores with the cyanidation process. This process consists of leaching gold from the ore as a gold-cyanide complex, and gold being recovered by precipitation (Simovic and Snodgrass 1985). Milling and heap leaching require cycling of millions of liters of alkaline water containing high concentrations of potentially toxic NaCN, free cyanide, and metal cyanide complexes that are frequently accessible to wildlife. Some milling operations result in tailings ponds of 150 ha and larger. Heap leach operations that spray or drip cyanide solution onto the flattened top of the ore heap require solution processing ponds of about 1 ha in surface area. Although not intentional or desired, puddles of various sizes may occur on the top of heaps where the highest concentrations of NaCN are found. Exposed solution recovery channels are usually constructed at the base of leach heaps. All of these cyanidecontaining water bodies are hazardous to wildlife if not properly managed (Henny et al. 1994). In this account we emphasize hazards of cyanide from mining operations to fish and wildlife species and proposed mitigation to protect them.

Book chapter↗

Examples of deformation-dependent flow simulations of conjunctive use with MF-OWHM

The dependency of surface- and groundwater flows and aquifer hydraulic properties on deformation induced by changes in aquifer head is not accounted for in the standard version of MODFLOW. A new USGS integrated hydrologic model, MODFLOW-OWHM, incorporates this dependency by linking subsidence and mesh deformation with changes in aquifer transmissivity and storage coefficient, and with flows that also depend on aquifer characteristics and land-surface geometry. This new deformation-dependent approach is being used for the further development of the integrated Central Valley hydrologic model (CVHM) in California. Preliminary results from this application and from hypothetical test cases of similar systems show that changes in canal flows, stream seepage, and evapotranspiration from groundwater (ET gw ) are sensitive to deformation. Deformation feedback has been shown to also have an indirect effect on conjunctive surface- and groundwater use components with increased stream seepage and streamflows influencing surface-water deliveries and return flows. In the Central Valley model, land subsidence may significantly degrade the ability of the major canals to deliver surface water from the Delta to the San Joaquin and Tulare basins. Subsidence can also affect irrigation demand and ET gw , which, along with altered surface-water supplies, causes a feedback response resulting in changed estimates of groundwater pumping for irrigation. This modeling feature also may improve the impact assessment of dewatering-induced land subsidence/uplift (following irrigation pumping or coal-seam gas extraction) on surface receptors, inter-basin transfers, and surface infrastructure integrity.

Proceedings of the International Association of Hy↗

Opportunities and Needs for Mobile-Computing Technology to Support U.S. Geological Survey Fieldwork

To assess the opportunities and needs for mobile-computing technology at the U.S. Geological Survey (USGS), we conducted an internal, Internet-based survey of bureau scientists whose research includes fieldwork. In summer 2005, 144 survey participants answered 65 questions about fieldwork activities and conditions, technology to support field research, and postfieldwork data processing and analysis. Results suggest that some types of mobile-computing technology are already commonplace, such as digital cameras and Global Positioning System (GPS) receivers, whereas others are not, such as personal digital assistants (PDAs) and tablet-based personal computers (tablet PCs). The potential for PDA use in the USGS is high: 97 percent of respondents record field observations (primarily environmental conditions and water-quality data), and 87 percent take field samples (primarily water-quality data, water samples, and sediment/soil samples). The potential for tablet PC use in the USGS is also high: 59 percent of respondents map environmental features in the field, primarily by sketching in field notebooks, on aerial photographs, or on topographic-map sheets. Results also suggest that efficient mobile-computing-technology solutions could benefit many USGS scientists because most respondents spend at least 1 week per year in the field, conduct field sessions that are least 1 week in duration, have field crews of one to three people, and typically travel on foot about 1 mi from their field vehicles. By allowing researchers to enter data directly into digital databases while in the field, mobile-computing technology could also minimize postfieldwork data processing: 93 percent of respondents enter collected field data into their office computers, and more than 50 percent spend at least 1 week per year on postfieldwork data processing. Reducing postfieldwork data processing could free up additional time for researchers and result in cost savings for the bureau. Generally, respondents support greater use of mobile-computing technology at the USGS and are interested in training opportunities and further discussions related to data archiving, access to additional digital data types, and technology development.

Circular↗

Plant and insect herbivore community variation across the Paleocene–Eocene boundary in the Hanna Basin, southeastern Wyoming

Ecosystem function and stability are highly affected by internal and external stressors. Utilizing paleobotanical data gives insight into the evolutionary processes an ecosystem undergoes across long periods of time, allowing for a more complete understanding of how plant and insect herbivore communities are affected by ecosystem imbalance. To study how plant and insect herbivore communities change during times of disturbance, we quantified community turnover across the Paleocene­–Eocene boundary in the Hanna Basin, southeastern Wyoming. This particular location is unlike other nearby Laramide basins because it has an abundance of late Paleocene and Eocene coal and carbonaceous shales and paucity of well-developed paleosols, suggesting perpetually high water availability. We sampled approximately 800 semi-intact dicot leaves from five stratigraphic levels, one of which occurs late in the Paleocene–Eocene thermal maximum (PETM). Field collections were supplemented with specimens at the Denver Museum of Nature & Science. Fossil leaves were classified into morphospecies and herbivore damage was documented for each leaf. We tested for changes in plant and insect herbivore damage diversity using rarefaction and community composition using non-metric multidimensional scaling ordinations. We also documented changes in depositional environment at each stratigraphic level to better contextualize the environment of the basin. Plant diversity was highest during the mid-late Paleocene and decreased into the Eocene, whereas damage diversity was highest at the sites with low plant diversity. Plant communities significantly changed during the late PETM and do not return to pre-PETM composition. Insect herbivore communities also changed during the PETM, but, unlike plant communities, rebound to their pre-PETM structure. These results suggest that insect herbivore communities responded more strongly to plant community composition than to the diversity of species present.

Wyoming↗

Carbon and oxygen isotopic composition of coal and carbon dioxide derived from laboratory coal combustion: A preliminary study

The concentration of carbon dioxide (CO 2 ) in the atmosphere has dramatically increased from the start of the industrial revolution in the mid-1700s to present levels exceeding 400 ppm. Carbon dioxide derived from fossil fuel combustion is a greenhouse gas and a major contributor to on-going climate change. Carbon and oxygen stable isotope geochemistry is a useful tool to help model and predict the contributions of anthropogenic sources of CO 2 in the global carbon cycle. Surprisingly few studies have addressed the carbon and oxygen isotopic composition of CO 2 derived from coal combustion. The goal of this study is to document the relationships between the carbon and oxygen isotope signatures of coal and signatures of the CO 2 produced from laboratory coal combustion in atmospheric conditions. Six coal samples were selected that represent various geologic ages (Carboniferous to Tertiary) and coal ranks (lignite to bituminous). Duplicate splits of the six coal samples were ignited and partially combusted in the laboratory at atmospheric conditions. The resulting coal-combustion gases were collected and the molecular composition of the collected gases and isotopic analyses of δ 13 C of CO 2 , δ 13 C of CH 4 , and δ 18 O of CO 2 were analysed by a commercial laboratory. Splits (~ 1 g) of the un-combusted dried ground coal samples were analyzed for δ 13 C and δ 18 O by the U.S. Geological Survey Reston Stable Isotope Laboratory. The major findings of this preliminary work indicate that the isotopic signatures of δ 13 C (relative to the Vienna Pee Dee Belemnite scale, VPDB) of CO 2 resulting from coal combustion are similar to the δ 13 C VPDB signature of the bulk coal (− 28.46 to − 23.86 ‰) and are not similar to atmospheric δ 13 C VPDB of CO 2 (~ − 8 ‰, see http://www.esrl.noaa.gov/gmd/outreach/isotopes/c13tellsus.html ). The δ 18 O values of bulk coal are strongly correlated to the coal dry ash yields and appear to have little or no influence on the δ 18 O values of CO 2 resulting from coal combustion in open atmospheric conditions. There is a wide range of δ 13 C values of coal reported in the literature and the δ 13 C values from this study generally follow reported ranges for higher plants over geologic time. The values of δ 18 O (relative to Vienna Standard Mean Ocean Water) of CO 2 derived from atmospheric combustion of coal and other high-carbon fuels (peat and coal) range from + 19.03 to + 27.03‰ and are similar to atmospheric oxygen δ 18 O VSMOW values which average + 23.8‰. Further work is needed on a broader set of samples to better define the relationships between coal composition and combustion-derived gases.

International Journal of Coal Geology↗

U.S. Geological Survey climate and land use change science strategy—A framework for understanding and responding to global change

Executive Summary The U.S. Geological Survey (USGS), a nonregulatory Federal science agency with national scope and responsibilities, is uniquely positioned to serve the Nation’s needs in understanding and responding to global change, including changes in climate, water availability, sea level, land use and land cover, ecosystems, and global biogeochemical cycles. Global change is among the most challenging and formidable issues confronting our Nation and society. Scientists agree that global environmental changes during this century will have far-reaching societal implications (Intergovernmental Panel on Climate Change, 2007; U.S. Global Change Research Program, 2009). In the face of these challenges, the Nation can benefit greatly by using natural science information in decisionmaking. Since the passage of the U.S. Global Change Research Act of 1990, the USGS has made substantial scientific contributions to understanding the interactive living and nonliving components of the Earth system. USGS natural science activities have led to fundamental advances in observing and understanding climate and land-cover change and the effects these changes have on ecosystems, natural-resource availability, and societal sustainability. Most of these major advances were pursued in partnership with other organizations within and outside the Department of the Interior. The inherent value of partnerships with other U.S. Global Change Research Program agencies and natural-resource managers is emphasized in all aspects of the planning and implementation of this Science Strategy for the coming decade. Over the next 10 years, the USGS will make substantial contributions to understanding how Earth systems interact, respond to, and cause global change. The USGS will work with science partners, decisionmakers, and resource managers at local to international levels (including Native American tribes) to improve understanding of past and present change; develop relevant forecasts; and identify those lands, resources, and communities most vulnerable to global change processes. Science will play an essential role in helping communities and land and resource managers understand local to global implications, anticipate effects, prepare for changes, and reduce the risks associated with decisionmaking in a changing environment. USGS partners and stakeholders will benefit from the data, predictive models, and decision-support products and services resulting from the implementation of this strategy. This Science Strategy recognizes core USGS strengths that are applied to key societal problems. It establishes seven goals for USGS global change science and strategic actions that may be implemented in the short term (1–5 years) and the longer term (5–10 years) to improve our understanding of the following areas of inquiry: Rates, causes, and impacts of past global changes; The global carbon cycle; Biogeochemical cycles and their coupled interactions; Land-use and land-cover change rates, causes, and consequences; Droughts, floods, and water availability under changing land-use and climatic conditions; Coastal response to sea-level rise, climatic change, and human development; and Biological responses to global change. In addition to the seven thematic goals, we address the central role of monitoring in accordance with the USGS Science Strategy recommendation that global change research should rely on existing “…decades of observational data and long-term records to interpret consequences of climate variability and change to the Nation’s biological populations, ecosystems, and land and water resources” (U.S. Geological Survey, 2007, p. 19). We also briefly describe specific needs and opportunities for coordinating USGS global change science among USGS Mission Areas and address the need for a comprehensive and sustained communications strategy.

Circular↗

Osmoregulation and muscle water control in vitro facing salinity stress of the Amazon fish Oscar Astronotus ocellatus (Cichlidae)

Specimens of Oscar Astronotus ocellatus from a fish farm were abruptly submitted to salt stress of 14 ppt and 20 ppt, for 3 and 8 h to determine their plasma osmolality. Muscle wet body mass change in vitro was analyzed from control freshwater animals. Fish in 14 ppt presented no osmolality distress even after 8 h. In 20 ppt, a slight increase (10%) in plasma osmolality was observed for both times of exposure when compared to control fish. Muscle slices submitted in vitro to hyper-osmotic saline displayed decreased body mass after 75 min, and slices submitted to hypo-osmotic saline displayed increased body mass after 45 min when compared to control (isosmotic saline). These results reinforce A. ocellatus ’s euryhalinity. The fish were able to regulate its internal medium and tolerate 14 ppt, but presented an intense osmotic challenge and low muscle hydration control when facing salinities of 20 ppt.

Marine and Freshwater Behaviour and Physiology↗

Enhanced Late Holocene ENSO/PDO expression along the margins of the eastern North Pacific

Pacific climate is known to have varied during the Holocene, but spatial patterns remain poorly defined. This paper compiles terrestrial and marine proxy data from sites along the northeastern Pacific margins and proposes that they indicate 1) suppressed ENSO conditions during the middle Holocene between ∼8000 and 4000 cal BP with a North Pacific that generally resembled a La Niña-like or more negative PDO phase and 2) a climate transition between ∼4200 and 3000 cal BP that appears to be the teleconnected expression to a more modern-like ENSO Pacific. Compared to modern day conditions, the compiled data suggest that during the middle Holocene, the Aleutian Low was generally weaker during the winter and/or located more to the west, while the North Pacific High was stronger during the summer and located more to the north. Coastal upwelling off California was more enhanced during the summer and fall but suppressed during the spring. Oregon and California sea surface temperatures (SSTs) were cooler. The Santa Barbara Basin had an anomalous record, suggesting warmer SSTs. Late Holocene records indicate a more variable, El Niño-like, and more positive PDO Pacific. The Aleutian Low became more intensified during the winter and/or located more to the east. The North Pacific High became weaker and/or displaced more to the south. Coastal upwelling off California intensified during the spring but decreased during the fall. Oregon and California SSTs became warmer, recording the shoreward migration of sub-tropical gyre waters during the fall, while spring upwelling (cooler SST) increased in the Santa Barbara Basin. The high-resolution proxy records indicate enhanced ENSO and PDO variability after ∼4000 cal BP off southern California, ∼3400 cal BP off northern California, and by ∼2000 cal BP in southwestern Yukon. A progressively northward migration of the ENSO teleconnection during the late Holocene is proposed.

Quaternary International↗

Final report for sea-level rise response modeling for San Francisco Bay estuary tidal marshes

The International Panel on Climate Change has identified coastal ecosystems as areas that will be disproportionally affected by climate change. Current sea-level rise projections range widely with 0.57 to 1.9 meters increase in mea sea level by 2100. The expected accelerated rate of sea-level rise through the 21 st century will put many coastal ecosystems at risk, especially those in topographically low-gradient areas. We assessed marsh accretion and plant community state changes through 2100 at 12 tidal salt marshes around San Francisco Bay estuary with a sea-level rise response model. Detailed ground elevation, vegetation, and water level data were collected at all sites between 2008 and 2011 and used as model inputs. Sediment cores (taken by Callaway and others, 2012) at four sites around San Francisco Bay estuary were used to estimate accretion rates. A modification of the Callaway and others (1996) model, the Wetland Accretion Rate Model for Ecosystem Resilience (WARMER), was utilized to run sea-level rise response models for all sites. With a mean sea level rise of 1.24 m by 2100, WARMER projected that the vast majority, 95.8 percent (1,942 hectares), of marsh area in our study will lose marsh plant communities by 2100 and to transition to a relative elevation range consistent with mudflat habitat. Three marshes were projected to maintain marsh vegetation to 2100, but they only composed 4.2 percent (85 hectares) of the total marsh area surveyed.

California↗

Geologic and geophysical models for Osage County, Oklahoma, with implications for groundwater resources

This report summarizes a three-dimensional (3-D) geologic model that was constructed to provide a framework to investigate groundwater resources of the Osage Nation in northeastern Oklahoma. This report also presents an analysis of an airborne electromagnetic (AEM) survey that assessed the spatial variation of electrical resistivity to depths as great as 300 meters in the subsurface. The report and model provide support for a countywide assessment of groundwater resources, emphasizing the Upper Pennsylvanian rock units in the shallow subsurface of central and eastern Osage County having electrical resistivity properties that may indicate aquifers. Surface outcrops and subsurface stratigraphic picks on wire-line geophysical logs of Upper Pennsylvanian–Lower Permian sedimentary rock were used to construct a 3-D model of the geologic subsurface as an aid for evaluating groundwater resources in Osage County. Quaternary alluvium and terraces along major streams and the Arkansas River are included in the geologic framework model. Data from the AEM survey were subjected to quality-control procedures, truncated at depth of investigation (DOI), and then used to build a 3-D electrical resistivity model making use of secondary and tertiary interpolation profiles between primary data profiles. The AEM data highlight westward-inclined resistivity gradients that parallel the shallow dip of bedrock strata; bodies have resistivity >30 ohm-meters, and extend as much as 10 kilometers (km) down the dip of host geologic units. Volume analysis and internal imaging of an integrated 3-D geology and electrical resistivity model give a proxy for likely aquifer units with large relative volumes of high resistivity: Quaternary alluvium, Elgin Sandstone Lentil in the upper part of the Vamoosa Group, Tallant Formation, and parts of a combined Wann-Iola-Chanute Formation. Less voluminous, high-resistivity bodies correspond to intervals in the lower part of the Vamoosa Group in the east-central part of the county and probable limestone intervals in the upper part of the Vanoss Group in the northwest part of the county. Northwestern and eastern troughs of potable water previously defined for central Osage County generally correspond to down-dip projections of high-resistivity bodies associated with the Elgin Sandstone Lentil of the Vamoosa Group and Tallant Formation, respectively.

Oklahoma↗

Groundwater data network interoperability

Water data networks are increasingly being integrated to answer complex scientific questions that often span large geographical areas and cross political borders. Data heterogeneity is a major obstacle that impedes interoperability within and between such networks. It is resolved here for groundwater data at five levels of interoperability, within a Spatial Data Infrastructure architecture. The result is a pair of distinct national groundwater data networks for the United States and Canada, and a combined data network in which they are interoperable. This combined data network enables, for the first time, transparent public access to harmonized groundwater data from both sides of the shared international border.

Journal of Hydroinformatics↗

Predicting invasiveness of freshwater fishes imported into North America: Regional differences in models and outcomes

Biological invasions driven by international trade heighten the urgency for development of invasion risk models, as the traits and parameters that consistently predict successful invasion remain unresolved. For four regions of North America that include parts of the United States and Canada (Sacramento-San Joaquin River Basins, Lower Colorado River Basin, Great Lakes Region, Mid-Atlantic Region), we construct and compare classification tree models to reveal robust predictors for the establishment and ecological impact stages of freshwater fish invasion. We subsequently apply the models to identify invasive fish species in trade and conduct pathway analyses to determine which trades (aquarium, biological supply, live bait, live food, water garden) and source continents pose the greatest risk to each region. Model results differed by invasion stage and region. Across regions, establishment models shared climate-related predictors including climate match and temperature tolerance. Three of the four impact models contained prior establishment success. The greatest number of species (548) were predicted to establish in the Sacramento-San Joaquin while the fewest (5) were predicted to establish in the Mid-Atlantic. Forty species were predicted to establish in multiple regions, five of which were also predicted to have high impact. The aquarium trade and Asia supplied the most species predicted to establish. Taken together, the results highlight region-specific models, indicating no universal model predicts invasion. Climate-related and prior establishment variables were most useful to risk assessments. The regional models, and identified high-risk pathways and potential invaders, could be applied to prevent future fish invasions in North America.

Laurentian Great Lakes Region, Lower Colorado Rive↗

Anthropogenic influences on the input and biogeochemical cycling of nutrients and mercury in Great Salt Lake, Utah, USA

Despite the ecological and economic importance of Great Salt Lake (GSL), little is known about the input and biogeochemical cycling of nutrients and trace elements in the lake. In response to increasing public concern regarding anthropogenic inputs to the GSL ecosystem, the US Geological Survey (USGS) and US Fish and Wildlife Service (USFWS) initiated coordinated studies to quantify and evaluate the significance of nutrient and Hg inputs into GSL. A 6??? decrease in ??15N observed in brine shrimp (Artemia franciscana) samples collected from GSL during summer time periods is likely due to the consumption of cyanobacteria produced in freshwater bays entering the lake. Supporting data collected from the outflow of Farmington Bay indicates decreasing trends in ??15N in particulate organic matter (POM) during the mid-summer time period, reflective of increasing proportions of cyanobacteria in algae exported to GSL on a seasonal basis. The C:N molar ratio of POM in outflow from Farmington Bay decreases during the summer period, supportive of the increased activity of N fixation indicated by decreasing ??15N in brine shrimp and POM. Although N fixation is only taking place in the relatively freshwater inflows to GSL, data indicate that influx of fresh water influences large areas of the lake. Separation of GSL into two distinct hydrologic and geochemical systems from the construction of a railroad causeway in the late 1950s has created a persistent and widespread anoxic layer in the southern part of GSL. This anoxic layer, referred to as the deep brine layer (DBL), has high rates of SO42 - reduction, likely increasing the Hg methylation capacity. High concentrations of methyl mercury (CH3Hg) (median concentration = 24 ng/L) were observed in the DBL with a significant proportion (31-60%) of total Hg in the CH3Hg form. Hydroacoustic and sediment-trap evidence indicate that turbulence introduced by internal waves generated during sustained wind events can temporarily mix the elevated CH3Hg concentrations in the DBL with the more biologically active upper brine layer (UBL). Brine shrimp collected during the summer/fall time periods contained elevated Hg concentrations (median concentration = 0.34 mg/kg, dry weight (dw)) relative to samples collected during the spring (median concentration < 0.2 mg/kg, dw). Higher Hg in brine shrimp during the summer and fall may reflect the higher proportion of adult brine shrimp during this time period, resulting in an increased time for bioaccumulation of Hg. Eared grebes (Podiceps nigricollis) consume brine shrimp from GSL during the fall molting period. Median Hg concentrations in eared grebe livers increased by almost three times during the 3-5 month fall molting period. Selected duck species utilizing GSL have consistently exceeded the US Environmental Protection Agency (USEPA) screening level for Hg (0.3 mg/kg Hg wet weight), resulting in the issuance of warnings against unlimited human consumption of breast muscle tissue.

Applied Geochemistry↗

River suspended-sand flux computation with uncertainty estimation using water samples and high-resolution ADCP measurements

Measuring suspended-sand fluxes in rivers remains a scientific challenge due to their high spatial and temporal variability. To capture the vertical and lateral gradients of concentration in the cross-section, measurements with point samples are performed. However, the uncertainty related to these measurements is rarely evaluated, as few studies of the major sources of error exist. Therefore, the aim of this study is to develop a method to determine the cross-sectional sand flux and estimate its uncertainty. This SDC (for sand discharge computing) method combines suspended-sand concentrations from point samples with ADCP (acoustic Doppler current profiler) high-resolution depth and velocity measurements. The MAP (for multitransect averaged profile) method allows obtaining an average of several ADCP transects on a regular grid, including the unmeasured areas. The suspended-sand concentrations are integrated vertically by fitting a theoretical exponential suspended-sand profile to the data using Bayesian modeling. The lateral integration is based on the water depth as a proxy for the local bed shear stress to evaluate the bed concentration and sediment diffusion along the river cross-section. The estimation of uncertainty combines ISO standards and semi-empirical methods with a Bayesian approach to estimate the uncertainty due to the vertical integration. The new method is applied to data collected in four rivers under various hydro-sedimentary conditions: the Colorado, Rhône, Isère, and Amazon rivers, with computed flux uncertainties ranging between 18 % and 32 %. The relative difference between the suspended-sand flux in 21 cases calculated with the proposed SDC method compared to the International Organization for Standardization (ISO) 4363 standard method ranges between − 40 % and + 23 %. This method that comes with a flexible, open-source code is the first to propose an applicable uncertainty estimation that could be adapted to other flux computation methods.

Earth Surface Dynamics↗

The effect of coal bed dewatering and partial oxidation on biogenic methane potential

Coal formation dewatering at a site in the Powder River Basin was associated with enhanced potential for secondary biogenic methane determined by using a bioassay. We hypothesized that dewatering can stimulate microbial activity and increase the bioavailability of coal. We analyzed one dewatered and two water-saturated coals to examine possible ways in which dewatering influences coal bed natural gas biogenesis by looking at differences with respect to the native coal microbial community, coal-methane organic intermediates, and residual coal oxidation potential. Microbial biomass did not increase in response to dewatering. Small Subunit rRNA sequences retrieved from all coals sampled represented members from genera known to be aerobic, anaerobic and facultatively anaerobic. A Bray Curtis similarity analysis indicated that the microbial communities in water-saturated coals were more similar to each other than to the dewatered coal, suggesting an effect of dewatering. There was a higher incidence of long chain and volatile fatty acid intermediates in incubations of the dewatered coal compared to the water-saturated coals, and this could either be due to differences in microbial enzymatic activities or to chemical oxidation of the coal associated with O 2 exposure. Dilute H 2 O 2 treatment of two fractions of structural coal (kerogen and bitumen + kerogen) was used as a proxy for chemical oxidation by O 2 . The dewatered coal had a low residual oxidation potential compared to the water-saturated coals. Oxidation with 5% H 2 O 2 did increase the bioavailability of structural coal, and the increase in residual oxidation potential in the water saturated coals was approximately equivalent to the higher methanogenic potential measured in the dewatered coal. Evidence from this study supports the idea that coal bed dewatering could stimulate biogenic methanogenesis through partial oxidation of the structural organics in coal once anaerobic conditions are restored.

Montana;Wyoming↗