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At least 973 records · Page 54Linked to original sources
USGS1971

Program design for San Francisco Bay Region environment and resources planning study

The "Program Design" for the San Francisco Bay Region Environment and Resources Planning Study represents a refinement, elaboration, and extension of the plans which formed the basis for the cooperative program between the Department of the Interior, Geological Survey, and the Department of Housing and Urban Development, Office of Research and Technology, formally recognized in the Letter of Agreement of October 24, 1969, and begun January 1, 1970. From the first, the study was recognized as an experimental pilot study, and new developments in the state-of-the-art in the earth sciences and in urban and regional planning were recognized as necessary. Indeed, the development of a suitable structure for such a program was considered one of the important parts of the experiment. Consequently, one of the stated goals of the Letter of Agreement was to produce a Program Design.

California↗
USGS2007

A GIS Analysis of Seagrass Resources and Condition Within Padre Island National Seashore, Texas

A survey of the seagrass resources of Padre Island National Seashore was conducted in fall 2002 and 2003, with additional sampling through 2006, to resolve distribution questions. Location coordinates were recorded to thousandths of minutes of latitude and longitude and converted to decimal degrees (minus decimal degrees for longitude) for import into ArcView (Environmental Systems Research Institute, Inc.). The seagrass core frequency data were developed as a theme in ArcView and overlaid on digital orthophoto quarter quadrangles of the U.S. Geological Survey to show sample depth with respect to mean sea level and frequency of occurrence of seagrass for five samples collected from every station sampled. These data were used to draw boundaries of area submerged at mean sea level and seagrass meadow in relation to the boundary of Padre Island National Seashore. Frequency of seagrass occurrence, mean plant height, shoot density, plant height multiplied by shoot density, live biomass, and dead biomass on a 1' latitude by 0.25' longitude grid were collected, and their distribution was plotted in space and according to depth. A User Guide for displaying data in ArcView is included at the end of this report. Seagrasses covered almost two-thirds of the regularly flooded part of Laguna Madre within the borders of Padre Island National Seashore. Comparisons with earlier surveys showed that substantial areas of seagrass cover had been lost in deep water between 1988 and 1998 as a result of a persistent phytoplankton bloom, and little recovery has occurred since. Maximum depth of seagrass occurrence responded to changes in water clarity. In contrast, much of the cover at shallow to intermediate depths lost at the south end of the study area between 1988 and 1998 was replaced by 2003. The seven stations with greatest plant height were located in this area of recent recolonization. Continuity of cover as measured by frequency of occurrence was high except near the edge of seagrass meadow. Decrease in this measure may be an indicator of meadow fragmentation, signaling deterioration of seagrass meadow before loss. The other measures of condition were so variable that they were insensitive indicators of impending change.

Open-File Report↗
USGS2006

Fate of fish production in a seasonally flooded saltmarsh

Although saltmarshes are thought to enhance the productivity of open estuarine waters, the mechanism by which energy transfer occurs has been debated for decades. One possible mechanism is the transfer of saltmarsh production to estuarine waters by vagile fishes and invertebrates. Monthly estimates of fish standing stock, net fish ingress, and predation were used to develop a biomass budget to estimate annual production of fishes and the relative yield to predatory fish, birds, and direct migration to the estuary. Annual production of saltmarsh fishes was estimated to be 31.0 g m-2 saltmarsh, which falls within the range of previously reported values for estuarine fish communities. The relative yields were 12 to 20% to piscivorous fishes, 8 to 13% to piscivorous birds, and 18 to 29% to export. Annual export of fish biomass was 5.6 g fish m-2 saltmarsh, representing about 1 to 2% of saltmarsh primary production. Saltmarsh fishes convert marsh production to high-quality vagile biomass (fishes concentrate energy, protein, and nutrients as body mass) and move this readily useable production to the estuary, providing an efficient link between saltmarshes and estuarine predators. ?? Inter-Research 2006.

Marine Ecology Progress Series↗
USGS2017

Spatial and temporal patterns in golden eagle diets in the western United States, with implications for conservation planning

Detailed information on diets and predatory ecology of Golden Eagles ( Aquila chrysaetos ) is essential to prioritize prey species management and to develop landscape-specific conservation strategies, including mitigation of the effects of energy development across the western United States. We compiled published and unpublished data on Golden Eagle diets to (1) summarize available information on Golden Eagle diets in the western U.S., (2) compare diets among biogeographic provinces, and (3) discuss implications for conservation planning and future research. We analyzed 35 studies conducted during the breeding season at 45 locations from 1940–2015. Golden Eagle diet differed among western ecosystems. Lower dietary breadth was associated with desert and shrub-steppe ecosystems and higher breadth with mountain ranges and the Columbia Plateau. Correlations suggest that percentage of leporids in the diet is the factor driving overall diversity of prey and percentage of other prey groups in the diet of Golden Eagles. Leporids were the primary prey of breeding Golden Eagles in 78% of study areas, with sciurids reported as primary prey in 18% of study areas. During the nonbreeding season, Golden Eagles were most frequently recorded feeding on leporids and carrion. Golden Eagles can be described as both generalist and opportunistic predators; they can feed on a wide range of prey species but most frequently feed on abundant medium-sized prey species in a given habitat. Spatial variations in Golden Eagle diet likely reflect regional differences in prey community, whereas temporal trends likely reflect responses to long-term change in prey populations. Evidence suggests dietary shifts from traditional (leporid) prey can have adverse effects on Golden Eagle reproductive rates. Land management practices that support or restore shrub-steppe ecosystem diversity should benefit Golden Eagles. More information is needed on nonbreeding-season diet to determine what food resources, such as carrion, are important for overwinter survival.

Journal of Raptor Research↗
USGS2000

Northeastern Gulf of Mexico Coastal and Marine Ecosystem Program: Coastal Characterization: an overview and update

The U.S. Geological Surveys Biological Resources Division (BRD) mission is to provide leadership in gathering, analyzing, and disseminating biological information as support for sound management of the Nation's natural resources. Since becoming operational in October of 1996 through the transfer of programs from various bureaus within the Department of the Interior, the BRD, in cooperation with other Federal, State, and local partners, has begun research, inventory and monitoring, information sharing, and technology transfer. Through these activities, the BRD is fostering an understanding of biological systems and their benefits to society, and providing the essential scientific support and technical assistance required for management and policy decisions. The role of BRD' s National Wetlands Research Center (NWRC) in Lafayette, Louisiana, with project offices in Baton Rouge, LA and Gulf Breeze, FL, is to provide leadership in research and development related to the Nation's natural resources for the Southeast. The research focuses on wetlands ecology, animal ecology, and the development and application of spatial analysis techniques for natural resource related studies. Current geographic information system (GIS) technologies in use at NWRC are designed to provide natural resource managers with the on-line data and computerized techniques necessary to make informed decisions. Major GIS activities at NWRC include: compilation and analysis of digital databases for monitoring of natural resources; integration and transfer of databases with existing digital databases from various sources into a comprehensive GIS; and development of multifunctional decision support systems for natural resource managers using these data. NWRC is also an active participant in the National Information Infrastructure (NIT), in particular the National Spatial Data Infrastructure (NSDI) and the National Biological Information Infrastructure (NBTI), which will facilitate the dissemination of research results and other knowledge and information gained from these efforts. This summary and the three summaries that follow provides an overview and update of a four year study entitled, Northeastern Gulf of Mexico Coastal and Marine Ecosystem Program: Coastal Characterization.

Minerals Management Service↗
USGS2019

Scientific Framework for resilience research on the Upper Mississippi River System

The goal of this research framework is to outline research that would continue to improve our understanding of ecological resilience of the Upper Mississippi River System (UMRS) and inform management of the system for health and resilience. We provide a broad overview of recently completed and ongoing work that has been funded as a part of the UMRS Ecological Resilience Assessment and related efforts to provide context for how proposed research questions build upon our current knowledge and may inform restoration planning and design. We describe two primary objectives within this research framework - the first objective is to investigate hypothesized drivers and feedbacks related to specified resilience, and the second is to expand our utility of general resilience indicators through further development and evaluation. The intended audience for this framework is the Upper Mississippi River Restoration Program (UMRR). The UMRR partnership is made up of natural resource agencies from five states (Illinois, Iowa, Minnesota, Missouri and Wisconsin) and five federal agencies (U.S. Army Corps of Engineers, U.S. Environmental Protection Agency, U.S. Fish and Wildlife Service, U.S. Geological Survey, and USDA Natural Resources Conservation Service).

Illinois, Iowa, Minnesota, Missouri, Wisconsin↗
USGS2016

Contaminants in urban waters—Science capabilities of the U.S. Geological Survey

Streams and estuaries with urban watersheds commonly exhibit increased streamflow and decreased base flow; diminished stream-channel stability; excessive amounts of contaminants such as pesticides, metals, industrial and municipal waste, and combustion products; and alterations to biotic community structure. Collectively, these detrimental effects have been termed the “urban-stream syndrome.” Water-resource managers seek to lessen the effects on receiving water bodies of new urban development and remediate the effects in areas of existing urbanization. Similarly, the scientific community has produced extensive research on these topics, with researchers from the U.S. Geological Survey (USGS) leading many studies of urban streams and the processes responsible for the urban-stream syndrome. Increasingly, USGS studies are evaluating the effects of management and restoration activities to better understand how urban waters respond to the implementation of management practices. The USGS has expertise in collecting and interpreting data for many physical, chemical, and ecological processes in urban waters and, thus, provides holistic assessments to inform managers of urban water resources.

Fact Sheet↗
USGS2013

Ocean climate indicators: A monitoring inventory and plan for tracking climate change in the north-central California coast and ocean region

The impacts of climate change, defined as increasing atmospheric and oceanic carbon dioxide and associated increases in average global temperature and oceanic acidity, have been observed both globally and on regional scales, such as in the North-central California coast and ocean, a region that extends from Point Arena to Point Año Nuevo and includes the Pacific coastline of the San Francisco Bay Area. Because of the high economic and ecological value of the region’s marine environment, the Gulf of the Farallones National Marine Sanctuary (GFNMS) and other agencies and organizations have recognized the need to evaluate and plan for climate change impacts. Climate change indicators can be developed on global, regional, and site-specific spatial scales, and they provide information about the presence and potential impacts of climate change. While indicators exist for the nation and for the state of California as a whole, no system of ocean climate indicators exist that specifically consider the unique characteristics of the California coast and ocean region. To that end, GFNMS collaborated with over 50 regional, federal, and state natural resource managers, research scientists, and other partners to develop a set of 2 ocean climate indicators specific to this region. A smaller working group of 13 regional partners developed monitoring goals, objectives, strategies, and activities for the indicators and recommended selected species for biological indicators, resulting in the Ocean Climate Indicators Monitoring Inventory and Plan. The working group considered current knowledge of ongoing monitoring, feasibility of monitoring, costs, and logistics in selecting monitoring activities and selected species.

Report↗
USGS2012

Identification of the thiamin pyrophosphokinase gene in rainbow trout: Characteristic structure and expression of seven splice variants in tissues and cell lines and during embryo development

Thiamin pyrophosphokinase (TPK) converts thiamin to its active form, thiamin diphosphate. In humans, TPK expression is down-regulated in some thiamin deficiency related syndrome, and enhanced during pregnancy. Rainbow trout are also vulnerable to thiamin deficiency in wild life and are useful models for thiamin metabolism research. We identified the tpk gene transcript including seven splice variants in the rainbow trout. Almost all cell lines and tissues examined showed co-expression of several tpk splice variants including a potentially major one at both mRNA and protein levels. However, relative to other tissues, the longest variant mRNA expression was predominant in the ovary and abundant in embryos. During embryogenesis, total tpk transcripts increased abruptly in early development, and decreased to about half of the peak shortly after hatching. In rainbow trout, the tpk transcript complex is ubiquitously expressed for all tissues and cells examined, and its increase in expression could be important in the early-middle embryonic stages. Moreover, decimated tpk expression in a hepatoma cell line relative to hepatic and gonadal cell lines appears to be consistent with previously reported down-regulation of thiamin metabolism in cancer.

Comparative Biochemistry and Physiology, Part B: B↗
USGS2014

Summary of U.S. Geological Survey reports documenting flood profiles of streams in Iowa, 1963-2012

This report is part of an ongoing program that is publishing flood profiles of streams in Iowa. The program is managed by the U.S. Geological Survey in cooperation with the Iowa Department of Transportation and the Iowa Highway Research Board (Project HR-140). Information from flood profiles is used by engineers to analyze and design bridges, culverts, and roadways. This report summarizes 47 U.S. Geological Survey flood-profile reports that were published for streams in Iowa during a 50-year period from 1963 to 2012. Flood events profiled in the reports range from 1903 to 2010. Streams in Iowa that have been selected for the preparation of flood-profile reports typically have drainage areas of 100 square miles or greater, and the documented flood events have annual exceedance probabilities of less than 2 to 4 percent. This report summarizes flood-profile measurements, changes in flood-profile report content throughout the years, streams that were profiled in the reports, the occurrence of flood events profiled, and annual exceedance-probability estimates of observed flood events. To develop flood profiles for selected flood events for selected stream reaches, the U.S. Geological Survey measured high-water marks and river miles at selected locations. A total of 94 stream reaches have been profiled in U.S. Geological Survey flood-profile reports. Three rivers in Iowa have been profiled along the same stream reach for five different flood events and six rivers in Iowa have been profiled along the same stream reach for four different flood events. Floods were profiled for June flood events for 18 different years, followed by July flood events for 13 years, May flood events for 11 years, and April flood events for 9 years. Most of the flood-profile reports include estimates of annual exceedance probabilities of observed flood events at streamgages located along profiled stream reaches. Comparisons of 179 historic and updated annual exceedance-probability estimates indicate few differences that are considered substantial between the historic and updated estimates for the observed flood events. Overall, precise comparisons for 114 observed flood events indicate that updated annual exceedance probabilities have increased for most of the observed flood events compared to the historic annual exceedance probabilities. Multiple large flood events exceeding the 2-percent annual exceedance-probability discharge estimate occurred at 37 of 98 selected streamgages during 1960–2012. Five large flood events were recorded at two streamgages in Ames during 1990–2010 and four large flood events were recorded at four other streamgages during 1973–2010. Results of Kendall’s tau trend-analysis tests for 35 of 37 selected streamgages indicate that a statistically significant trend is not evident for the 1963–2012 period of record; nor is an overall clear positive or negative trend evident for the 37 streamgages.

Iowa↗
USGS2008

Environmental contaminant hazards to wildlife at National Capital region and Mid-Atlantic National Park Service units

Pollutant data for air, water, soil and biota were compiled from databases and internet sources and by staff interviews at 23 National Park Service (NPS) units in 2005. A metric was derived describing the quality and quantity of data for each park, and in combination with known contaminant threats, the need for ecotoxicological study was identified and ranked. Over half of NP units were near Toxic Release Inventory sites discharging persistent pollutants, and fish consumption advisories were in effect at or near 22 of the units. Pesticide and herbicide use was found to be minimal, with the exception of those units with agricultural leases. Only 70 reports were found that describe terrestrial vertebrate environmental contaminant data at or near the units. Of the >75,000 compounds in commerce, empirical exposure data were limited to merely 58 halogenated compounds, insecticides, rodenticides, metals, and some contemporary compounds. Further ecotoxicological monitoring and research is warranted at several units including Shenandoah National Park, Richmond National Battlefield Park, Chesapeake & Ohio Canal National Historical Park, Valley Forge National Historical Park, Hopewell Furnace National Historic Site, Monocacy National Battlefield, and Harpers Ferry National Historical Park. The types of investigations vary according to the wildlife species present and potential contaminant threats, but should focus on contemporary use pesticides and herbicides, polychlorinated biphenyls, mercury, lead, and perhaps antibiotics, flame retardants, pharmaceuticals, and surfactants. Other management recommendations include inclusion of screening level contaminant risk assessments into the NPS Vital Signs Program, development of protocols for toxicological analysis of seemingly affected wildlife, alternative methods and compounds for pest management, and use of non-toxic fishing tackle by visitors.

Book chapter↗
USGS2011

Applying remote sensing to invasive species science—A tamarisk example

The Invasive Species Science Branch of the Fort Collins Science Center provides research and technical assistance relating to management concerns for invasive species, including understanding how these species are introduced, identifying areas vulnerable to invasion, forecasting invasions, and developing control methods. This fact sheet considers the invasive plant species tamarisk (Tamarix spp), addressing three fundamental questions: *Where is it now? *What are the potential or realized ecological impacts of invasion? *Where can it survive and thrive if introduced? It provides peer-review examples of how the U.S. Geological Survey, working with other federal agencies and university partners, are applying remote-sensing technologies to address these key questions.

Fact Sheet↗
USGS1985

Mapping and research in the exclusive economic zone

By proclamation of the President on March 10, 1983, the United States claimed sovereign rights and jurisdiction within an Exclusive Economic Zone (EEZ). The United States is responsible for wisely developing and managing the EEZ and its marine resources and for protecting its environment. The U.S. Exclusive Economic Zone is a region that extends seaward 200 nautical miles from the coast and brings within the national domain over 3 million square nautical miles of submarine lands. The EEZ contains vital natural resources, both living and nonliving, of the seabed, subsoil, and overlying water. Because most of the EEZ has not been explored, its resources and their potential remain undefined

Report↗
USGS2012

Hydrologic, vegetation, and soil data collected in selected wetlands of the Big River Management area, Rhode Island, from 2008 through 2010

The Rhode Island Water Resources Board planned to develop public water-supply wells in the Big River Management Area in Kent County, Rhode Island. Research in the United States and abroad indicates that groundwater withdrawal has the potential to affect wetland hydrology and related processes. In May 2008, the Rhode Island Water Resources Board, the U.S. Geological Survey, and the University of Rhode Island formed a partnership to establish baseline conditions at selected Big River wetland study sites and to develop an approach for monitoring potential impacts once pumping begins. In 2008 and 2009, baseline data were collected on the hydrology, vegetation, and soil characteristics at five forested wetland study sites in the Big River Management Area. Four of the sites were located in areas of potential drawdown associated with the projected withdrawals. The fifth site was located outside the area of projected drawdown and served as a control site. The data collected during this study are presented in this report.

Rhode Island↗
USGS2015

Invasive Species Science Branch: research and management tools for controlling invasive species

Invasive, nonnative species of plants, animals, and disease organisms adversely affect the ecosystems they enter. Like “biological wildfires,” they can quickly spread and affect nearly all terrestrial and aquatic ecosystems. Invasive species have become one of the greatest environmental challenges of the 21st century in economic, environmental, and human health costs, with an estimated effect in the United States of more than $120 billion per year. Managers of the Department of the Interior and other public and private lands often rank invasive species as their top resource management problem. The Invasive Species Science Branch of the Fort Collins Science Center provides research and technical assistance relating to management concerns for invasive species, including understanding how these species are introduced, identifying areas vulnerable to invasion, forecasting invasions, and developing control methods. To disseminate this information, branch scientists are developing platforms to share invasive species information with DOI cooperators, other agency partners, and the public. From these and other data, branch scientists are constructing models to understand and predict invasive species distributions for more effective management. The branch also has extensive herpetological and population biology expertise that is applied to harmful reptile invaders such as the Brown Treesnake on Guam and Burmese Python in Florida.

Fact Sheet↗
USGS2011

Derived crop management data for the LandCarbon Project

The LandCarbon project is assessing potential carbon pools and greenhouse gas fluxes under various scenarios and land management regimes to provide information to support the formulation of policies governing climate change mitigation, adaptation and land management strategies. The project is unique in that spatially explicit maps of annual land cover and land-use change are created at the 250-meter pixel resolution. The project uses vast amounts of data as input to the models, including satellite, climate, land cover, soil, and land management data. Management data have been obtained from the U.S. Department of Agriculture (USDA) National Agricultural Statistics Service (NASS) and USDA Economic Research Service (ERS) that provides information regarding crop type, crop harvesting, manure, fertilizer, tillage, and cover crop (U.S. Department of Agriculture, 2011a, b, c). The LandCarbon team queried the USDA databases to pull historic crop-related management data relative to the needs of the project. The data obtained was in table form with the County or State Federal Information Processing Standard (FIPS) and the year as the primary and secondary keys. Future projections were generated for the A1B, A2, B1, and B2 Intergovernmental Panel on Climate Change (IPCC) Special Report on Emissions Scenarios (SRES) scenarios using the historic data values along with coefficients generated by the project. The PBL Netherlands Environmental Assessment Agency (PBL) Integrated Model to Assess the Global Environment (IMAGE) modeling framework (Integrated Model to Assess the Global Environment, 2006) was used to develop coefficients for each IPCC SRES scenario, which were applied to the historic management data to produce future land management practice projections. The LandCarbon project developed algorithms for deriving gridded data, using these tabular management data products as input. The derived gridded crop type, crop harvesting, manure, fertilizer, tillage, and cover crop products are used as input to the LandCarbon models to represent the historic and the future scenario management data. The overall algorithm to generate each of the gridded management products is based on the land cover and the derived crop type. For each year in the land cover dataset, the algorithm loops through each 250-meter pixel in the ecoregion. If the current pixel in the land cover dataset is an agriculture pixel, then the crop type is determined. Once the crop type is derived, then the crop harvest, manure, fertilizer, tillage, and cover crop values are derived independently for that crop type. The following is the overall algorithm used for the set of derived grids. The specific algorithm to generate each management dataset is discussed in the respective section for that dataset, along with special data handling and a description of the output product.

Open-File Report↗
USGS2019

The Mw 6.0 South Napa earthquake of August 24, 2014—Observations of surface faulting and ground deformation, with recommendations for improving post-earthquake field investigations

The M w 6.0 South Napa earthquake of August 24, 2014, produced complex and extensive surface faulting and other ground deformation features. Following the event, geologists made more than 1,200 field observations at locations where tectonic faulting and ground failure produced visible deformation that fractured and disturbed the ground surface. At a few locations, large-scale, detailed, field-based maps of fault rupture and ground deformation were produced. The South Napa earthquake response was one of the first times when post-earthquake reconnaissance data were mostly collected and disseminated electronically. The advantages and opportunities these new methods bring to our research also pose new challenges to large-scale compilation efforts and demonstrate the value of developing guidelines and better standardization across the community to more optimally utilize developing technology in future post-earthquake investigations. Some suggestions for standardizing the collection and dissemination of post-earthquake field reconnaissance data are provided herein. Field observations and maps were integrated with airborne imagery, lidar, and InSAR to produce a comprehensive, large-scale digital map of fault rupture and zones of ground deformation. The map, observations, and photo database are summarized here in appendixes and figures and are also available as a series of digital data products within a companion U.S. Geological Survey data release ( Ponti and others, 2019 ); the characteristics of fault rupture and ground deformation features are summarized in detail in the body of this report. The results of this compilation reveal that faulting occurred within a 2-km-wide zone on six, roughly parallel traces within the West Napa Fault System. Most of the fault slip, and all the afterslip, occurred on the 21-km-long westernmost trace (Trace A). Maximum coseismic slip was greater than 40 cm and possibly as great as 60 cm, with the slip maximum located about 10 km north of the epicenter. Extensive ground deformation also occurred off the principal fault traces. Deformation characteristics of these features were not consistent with either primary faulting or shaking-induced ground failure and remain enigmatic, although this report includes speculation about possible origins. The use of InSAR was invaluable for identifying and mapping secondary traces with small displacements, and for delineating the overall details of the extensive rupture. InSAR data also highlighted other areas with possible ground deformation—some of which are found coincident with previously mapped fault traces, whereas others are in areas where no faults were previously mapped. Several of these regions had no visible ground deformation, whereas others did produce features that were inconsistent with tectonic faulting, so care must be taken not to over interpret the InSAR data without careful, corroborating field investigations.

California↗
USGS2007

Methods of analysis by the U.S. Geological Survey Organic Geochemistry Research Group--Determination of dissolved isoxaflutole and its sequential degradation products, diketonitrile and benzoic acid, in water using solid-phase extraction and liquid chromatography/tandem mass spectrometry

An analytical method for the determination of isoxaflutole and its sequential degradation products, diketonitrile and a benzoic acid analogue, in filtered water with varying matrices was developed by the U.S. Geological Survey Organic Geochemistry Research Group in Lawrence, Kansas. Four different water-sample matrices fortified at 0.02 and 0.10 ug/L (micrograms per liter) are extracted by vacuum manifold solid-phase extraction and analyzed by liquid chromatography/tandem mass spectrometry using electrospray ionization in negative-ion mode with multiple-reaction monitoring (MRM). Analytical conditions for mass spectrometry detection are optimized, and quantitation is carried out using the following MRM molecular-hydrogen (precursor) ion and product (p) ion transition pairs: 357.9 (precursor), 78.9 (p), and 277.6 (p) for isoxaflutole and diketonitrile, and 267.0 (precursor), 159.0 (p), and 223.1 (p) for benzoic acid. 2,4-dichlorophenoxyacetic acid-d3 is used as the internal standard, and alachlor ethanesulfonic acid-d5 is used as the surrogate standard. Compound detection limits and reporting levels are calculated using U.S. Environmental Protection Agency procedures. The mean solid-phase extraction recovery values ranged from 104 to 108 percent with relative standard deviation percentages ranging from 4.0 to 10.6 percent. The combined mean percentage concentration normalized to the theoretical spiked concentration of four water matrices analyzed eight times at 0.02 and 0.10 ug/L (seven times for the reagent-water matrix at 0.02 ug/L) ranged from approximately 75 to 101 percent with relative standard deviation percentages ranging from approximately 3 to 26 percent for isoxaflutole, diketonitrile, and benzoic acid. The method detection limit (MDL) for isoxaflutole and diketonitrile is 0.003 ug/L and 0.004 ug/L for benzoic acid. Method reporting levels (MRLs) are 0.011, 0.010, and 0.012 ug/L for isoxaflutole, diketonitrile, and benzoic acid, respectively. On the basis of the calculated MRLs and MDLs and evaluation of the signal-to-noise ratios for each compound, the MRLs and MDLs are set at 0.010 and 0.003 ug/L, respectively, for all three compounds.

Techniques and Methods↗