SEARCH · USGS Science

Results for “Petrology”

Search indexed USGS publications on groundwater, aquifers, geologic maps, mineral resources and earthquakes. Explore source records by subject and place.

SourceResearch connectionFrom yearThrough year

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 973 records · Page 54Linked to original sources

USGS1971

Origin and emplacement of the ultramafic rocks of the Emigrant Gap area, California

The ultramafic bodies of the Emigrant Gap area are part of a mafic complex within a large composite pluton of the northern Sierra Nevada. The pluton was magmatically emplaced and is surrounded by an aureole of hornblende-hornfels facies rocks. Inclusions of country rock in ultramafic rock are of pyroxene-hornfels facies and appear to have been partly melted. Gravity studies indicate that the ultramafic bodies have near-vertical contacts extending to depths of at least 1½ to 2½ km. The mafic complex shows rough concentric zoning of rock types: ultramafic bodies occur at the core; gabbro forms a discontinuous intermediate unit; and diorite, tonalite, and granodiorite occur at the margins. Within the ultramafic bodies, unserpentinized wehrlitic peridotite is dominant; dunite and olivine clinopyroxenite are present but greatly subordinate. The ultramafic rocks consist almost entirely of olivine (FO 80 ) and diopside (Ca 46 Mg 46 Fe 8 ); orthopyroxene, hornbolende, and plagioclase occur locally. The gabbro, diorite, tonalite, and granodiorite contain both ortho- and clinopyroxene. Both ultramafic and two-pyroxene-bearing rocks were emplaced nearly simultaneously, as partly crystallized magmas and magmatic crystal mushes that had similar temperature. In all the rocks the structures are dominantly magmatic and were produced by sorting and orientation of crystals by magmatic flow. Structures produced by post-consolidation deformation and replacement are minor and local. The structural and chemical relations within the mafic complex suggest that all the rocks are derived from a single gabbroic magma by crystal fractionation, with the ultramafic rocks formed by mechanical accumulation of early crystallized mafic minerals, and the two pyroxene-bearing granodiorite crystallized from a felsic differentiate. It is likely that flowage differentiation was the dominant process of crystal segregation. The Emigrant Gap mafic complex is similar in structure, rock texture, and mineralogy to zoned ultramafic complexes, such as those of south-eastern Alaska, and is very different from either stratiform or alpine-type bodies. Though unlike the Alaskan bodies in detail, it appears that this complex should be classed with the zoned complexes in any broad grouping of ultramafic occurrences.

California↗

USGS1973

Phase relations of basalts in their melting range at PH2O = 5 kb as a function of oxygen fugacity: Part I. Mafic phases

The phase relations of three basalts, the Picture Gorge tholeiite, the 1921 Kilauea olivine tholeiite, and the 1801 Hualalai alkali basalt, were studied at 5 kb water pressure, 680–1000°C, at the oxygen fugacities of the quartz-fayalite-magnetite (QFM) and hematite-magnetite (HM) buffers. In the range 680–850 °C, the crystalline assemblage on the QFM buffer is dominantly hornblende+ plagioclase, ± ilmenite, magnetite, sphene, fayalitic olivine, and phlogopitic mica. From 875 to 1000 °C the crystalline assemblage is hornblende+ olivine± augite+ ilmenite± magnetite. A melt phase is present from 700 to 1000 °C; a vapor phase was present in all charges. The hornblendes formed on the QFM buffer range in composition from common green hornblendes at low temperatures to kaersutitic hornblendes at 1000 °C. A1(IV) and Ti increase temperature. AI(VI) passes through a maximum near 825 °C, decreasing both above and below this temperature. AI(IV) is proportional to the sum A1(VI)+2Ti. There is a positive linear correlation of approximately 3 : 1 between AI(IV) and the number of cations in the A-site. The most likely explanation for this correlation at present is that the substitution of AI(VI) or Ti +4 for a divalent cation creates local charge imbalances in the amphibole structure which can be compensated only by further A-site substitution. There also appears to be a correlation between the a-cell dimension of hornblende and the A-site occupancy. Above a thresh hold value of approxmately 0.5 cations in A, a increases as A-site occupancy increases. Phase relations on the hematite-magnetite buffer are considerably simpler. The hornblendes show relatively little change in composition as temperature increases, and in the tholelitic compositions break down at or below 970 °C 35–60 °C above the first appearance of augite±olivine. The melting of hornblende is incongruent in all cases. The Fe-Ti oxides are pseudo-brookite and titanohematite; at 1000 °C these oxides make up 10 per cent by weight of the assemblage and contain most of the Tio 2 and FeO in the charge. The patterns of hornblende variation observed in this study compare closely with those reported in a wide range of experimental and field data. The appearance of high-TiO 2 kaersutitic hornblendes in the tholeities at 1000° C, P H2O = 5 kb on the QFM buffer implies that the restricted occurence of kaersutite in nature (where it is associated only with mafic to intermediate alkalic rocks) is controlled by volatile content (H 2 O , F 2 )rather than by differences in condensed bulk composition.

Journal of Petrology↗

USGS1973

Oxidation during magmatic differentiation, Finnmarka Complex, Oslo area, Norway: Part 2, the mafic silicates

Electron-microprobe analyses are presented for pyroxene, amphibole, and biotite from monzonite, granodiorite, and granite at Finnmarka, Norway. Compositional trends measured in biotite, present in all three rock types, and in amphibole, present in the monzonite and granodiorite, are markedly atypical and are interpreted as reflecting crystallization under progressively more oxidizing conditions. The average Fe/Fe + Mg for biotites from successively more silicic rock types changes from 0.64 → 0.35 → 0.28, and for amphiboles changes from 0.58 in the monzonite to 0.29 in the granodiorite. Analyses of selected areas within amphibole grains in the granodiorite show marked chemical variations, although single-crystal X-ray photographs are sharp and do not reveal multiple phases. On the basis of 33 such analyses, four coupled substitutions are identified as operative; the most unusual finding is the relation of 1 Ti cation to 4 Al IV cations in the unit cell. Variations within individual amphibole grains of the granodiorite resemble changes noted in evolution of amphibole composition from monzonite to granodiorite and are interpreted as reflecting progressive oxidation. Consideration of these data for the mafic silicates, data for the opaque oxides, and the extensive formation of sphene in the granodiorite, has allowed development of schematic reactions and an overall picture of magmatic environment and evolution at Finnmarka. Crystallization apparently took place at PH 2 o of 1000 bars or less and a temperature of about 700 °C. The trend of oxidation during differentiation is more extreme than any heretofore reported. Amphiboles, as well as biotites, may participate in oxidation reactions and may reflect the oxidation-reduction processes that occurred during magmatic evolution.

Oslo↗

USGS1974

Prehnite- and pumpellyite-bearing mineral assemblages, west side of the Appalachian metamorphic belt, Pennsylvania to Newfoundland

Prehnite- and/or pumpellyite-bearing meta-igneous rocks are found on the west side of the Appalachian metamorphic belt (1) near Jonestown, south-eastern Pennsylvania; (2) on Rensselaer Plateau, eastern New York; (3) near Quebec City, Quebec; and (4) at Little Port, Humber Arm, western Newfoundland. The assemblages critical to determining the conditions of metamorphism are (1) chlorite-epidote-hematite-pumpellyite-prehnite; actinolite-chlorite-hematite-pumpellyite-stilpnomelane; (2) actinolite-chlorite-epidote-stilpnomelane; chlorite-epidote-pumpellyite-stilpnomelane; chlorite-epidote-hematite-pumpellyite; (3) chlorite-epidote-hematite-pumpellyite-stilpnomelane; chlorite-epidote-pumpellyite-prehnite; and (4) chlorite-epidote-prehnite; chlorite-prehnite-stilpnomelane; chlorite-epidote-pumpellyite-prehnite. One pumpellyite-bearing rock from western Newfoundland shows a later vein of analcime-calcite. All the assemblages also include quartz, sphene, calcite, K-mica, and albite. Analysis of the mineral assemblages by the Schreinemakers method for the phases actinolite-chlorite-epidote-hematite-prehnite-pumpellyite-stilpnomelane shows that the different localities can be assigned different metamorphic grades. Though the detailed results of the Schreinemakers analysis depend on the assumed source of ferric iron in epidote, the major conclusions are not affected. The thermodynamic role of calcite is more problematic, but it appears that CO 2 did not behave as a boundary-value component during metamorphism. If calcite is treated as an excess phase, the Schreinemakers bundle decomposes to a net in a multisystem. Plotted on such a net, the various localities again occupy different parts signifying different metamorphic grades. The occurrence of pumpellyite-bearing assemblages on the west flank of the northern Appalachian metamorphic belt might suggest that these assemblages, contrary to the ideas of Miyashiro and of others, do not indicate high-pressure and low-temperature type of metamorphism. These assemblages, however, are compatible with an alternative interpretation as remnants of a high-pressure, low-temperature Taconic metamorphic regime, whose imprint within most of the Appalachian metamorphic belt has been obliterated by later events. Such a reconstruction is compatible with the suggestion that this zone, lying near the margin of the early Paleozoic craton, was an active subduction zone during the Taconic orogeny.

Appalachian metamorphic belt↗

USGS1961

Jadeite deposits of the clear creek area, New Idria district, San Benito county, California

Tectonic inclusions within the New Idria serpentine body contain jadeite in two distinct assemblages: (1) Lenslike inclusions containing a monomineralic green jadeite core surrounded by a calc-silicate rim. (2) Jadeite veins cross-cutting albite-crossite schist inclusions. In these veins jadeite coexists with low albite; green jadeite (Jd 75 Ac+Di+He 25) coexists with low albite within the host schist. Albite schists are related to the pre-metamorphic keratophyres and it can be shown that desilication of such rocks produces a bulk composition similar to that of jadeite. Metamor-phism of keratophyric tectonic inclusions within serpentine produced jadeite-albite schists along margins of the inclusions. Jadeite-albite veins formed from mobilized liquids rich in the jadeite molecule and deficient in water. Geological evidence such as would indicate extreme pressures or temperatures during jadeite formation is lacking; rather, a low silica and dry system allowed its formation at reduced temperatures and pressures.

California↗

USGS1961

Magmatic differentiation in the Uwekahuna Laccolith, Kilauea Caldera, Hawaii

Petrographic and chemicoal studies of a suite of rocks from the Uwekahuna laccolith of Kilauea Volcano show that the original mafic tholeiitic magma differentiated into tholeiitic picrite, tholeiitic olivine gabbro, and an aphanitic rock approaching quartz-basalt in composition. Mechanisms involved were an initial gravity settling of olivine and a final filter pressing of the residual liquid. The range of composition represented by the rocks of the laccolith is as great as that found among all hitherto analysed lavas of the volcano.

Hawaii↗

USGS1984

Metamorphic history of a high-grade blueschist exotic block from the Franciscan complex, California

A high-grade blueschist tectonic block from the Franciscan Complex of the northeast Diablo Range shows evidence of three episodes of retrograde blueschist facies metamorphism ± deformation developed under progressively declining P-T conditions. The first retrograde metamorphism involved formation of an outer rind of actinolite + chlorite + rutile ± phengite, and the growth of coarse-grained chlorite + pumpellyite within the block. During the second event the rind and outer edge of the blueschist were folded, sheared and fractured, and primary glaucophane within the blueschist was replaced by albite, medium-grained chlorite, and glaucophane-crossite. The third retrograde metamorphism was marked by the pseudomorphic replacement of rind actinolite by aragonite and quartz. Aragonite also crystallized extensively within th block, accompanied by lawsonite, chlorite, jadeitic pyroxene, and crossite; this last mineral assemblage is identical to that of the surrounding Franciscan metasedimentary rocks. Features characteristic of the first and second retrograde metamorphic events are readily observed in other high-grade tectonic blocks of the Franciscan Complex and the correlative Otter Point Formation of Oregon. In contrast, evidence of a third retrograde metamorphism, matching that of presently associated Franciscan and Otter Point rocks, has been found in some but not all blocks examined so far. The high P/T conditions of prograde metamorphism and the available metamorphic age determinations suggest that the tectonic blocks originally formed in a pre-Franciscan subduction zone setting. Fragments of blueschist and eclogite from this metamorphic terrain were tectonically incorporated in a serpentinite diapir, and they developed alteration rinds through interaction with the enclosing ultramafic rock. The available data suggest that the examined exotic block and at least some others were transferred to the Franciscan as detritus from a body of serpentinite that reached the earth's surface. Such blocks were then resubducted and metamorphosed along with their presently associated sedimentary sequences.

Journal of Petrology↗

USGS1986

Aluminum enrichment in silicate melts by fractional crystallization: some mineralogic and petrographic constraints.

The degree of aluminum saturation of an igneous rock may be described by its Aluminum Saturation Index (ASI) defined as the molar ratio Al 2 O 3 (CaO + K 2 O + Na 2 O). One suggested origin for mildly peraluminous granites (ASI between 1 and about 1.1) is by fractional crystallization of subaluminous (ASI < 1) magmas; hornblende, having ASI < 0.5, could be a major driving force in such a fractionation process. The efficacy of the process depends not only on precipitation of hornblende and its effective removal from the reacting system, but on the composition and nature of other coprecipitating phases, weighted by their modal abundances in the reactive system. Precipitation of feldspar (ASI = 1), for instance, would retard or even prevent aluminum enrichment in the melt if the ASI of melt is < 1, but would enhance such evolution if the ASI of the melt is > 1. Discussion of the efficacy of any mineral must be made in the context of the total reacting system. For hornblende to effectively cause a melt to evolve into a peraluminous composition, it must be able to coexist with peraluminous magmas. Experimental phase equilibrium data show that at pressure > 5 kb hornblende can coexist with strongly peraluminous melts (ASI ˜ 1.5). Scantily phyric volcanic rocks show that hornblende can coexist with granitic magma having ASI ˜ 1.1 –1.2. The aggregate ASI of last-stage minerals of a typical granite is less than this value; therefore, even after hornblende has reacted out, the residual magma may be expected to continue to evolve toward more aluminous compositions.

Journal of Petrology↗

USGS1986

Lower crustal xenoliths, Chinese Peak lava flow, central Sierra Nevada

An assemblage of pyroxenite, peridotite, and mafic granulite xenoliths contained in the toe of a 10 Ma trachybasalt flow remnant overlying Late Cretaceous granitoids indicates the presence of a mafic-ultramafic complex beneath the Sierra Nevada batholith. Olivine-free pyroxenites that include orthopyroxenites, websterites, and clinopyroxenites are dominant. Primary igneous textures are displayed by some pyroxenites, but commonly are masked by recrystallization. Fe-rich harzburgites and lherzolites are rare. A few of the ultramafic xenoliths contain ovoid opaque patches that are apparently pseudomorphs after garnet and have pyralspite garnet compositions. A pressure corresponding to a lower crustal depth of approximately 40 km has been determined from two of these xenoliths using a garnet-orthopyroxene geobarometer. Abundant mafic granulites can be subdivided into those containing 12 per cent or less A 12 O 3 and chemically gradational with pyroxenites and others containing more than 15 per cent A 12 O 3 and showing considerable scatter on oxide variation diagrams. The high-alumina granulite xenoliths have relatively low 87 Rb/ 86 Sr but high 87 Sr/ 86 Sr, whereas low-alumina and ultramafic xenoliths have a wide range of 87 Rb/ 86 Sr, but lower 87 Sr/ 86 Sr; the isotopic data indicate an age for the complex roughly the same as that of overlying granitoid plutons. However, the granitoids have initial 87 Sr/ 86 Sr ratios intermediate between the high-alumina and ultramafic xenoliths, suggesting that they may have resulted from mixing of basaltic magma, represented by the ultramafics, and crustal materials, with subsequent crystal fractionation. The trachybasalt may represent a partial melt of the ultramafic rocks. Rocks analogous to the Chinese Peak xenoliths are exposed in the Giles complex of central Australia, a series of several deformed layered mafic and ultramafic intrusions, emplaced in a granulite facies terrain. Contemporaneous development of mafic-ultramafic complexes and the Sierra Nevada batholith may explain the present day thick (˜ 50 km) crust in this region

Journal of Petrology↗

USGS1987

Geochemistry of high-silica peralkaline rhyolites, Naivasha, Kenya rift valley

The Recent (<15000 y) volcanic complex of southwest Naivasha, Kenya, consists of mildly peralkaline (comenditic) rhyolite domes, lava flows, air fall pumices, and lake sediments, with minor, peripheral, basalts and hawaiites. The comendites are either aphyric or sparsely porphyritic, few samples containing >5 per cent phenocrysts. Phenocryst minerals are quartz-sanidine-ferrohedenbergite-fayalite-titanomagnetite-ilmenite-riebeckite-arfvedsonite-aenigmatite-biotite-zircon. Ferrohedenbergite and zircon are restricted to less peralkaline, and amphibole, aenigmatite, and biotite to more peralkaline, rocks.The comendites show unusually strong enrichment in Cs, F, Hf, Nb, Rb, REE, Ta, Th, U, Y, Zn, and Zr, and extreme depletion in Mg, Ca, Ba, Co, and Sr. REE patterns are moderately LREE-enriched, with large, negative Eu anomalies. Values of LIL/HFS element ratios, such as Th/Ta and Rb/Zr, are unusually high for peralkaline rhyolites, and are consistent with a substantial crustal component in the comendites. Parameters such as LREE/HREE and Zr/Nb ratios indicate that the Naivasha rhyolites represent several pulses of closely related, but subtly different, magmas. Sanidine/glass partition coefficients for Ba, Pb, Rb, Sr, U, and the REE are presented for one specimen.Major and trace element modelling, and feldspar-rock relationships, show that closed system crystal fractionation cannot alone account for the overall compositional variations in the comendites. A model involving partial melting of variable crustal source rocks and migration of dissolved volatile-metal complexes may be appropriate at Naivasha. © 1987 Oxford University Press.

Journal of Petrology↗

USGS1962

Stability relations of the ferruginous biotite, annite

Annite , KFe 3 AISi 3 O 10 (OH) 2 a member of the iron biotites and the ferrous analogue of phlogopite, has been synthesized and its phase relations have been determined as functions of temperature, fugacity of oxygen (fo 2 ), and total pressure (P total ≈PH 2 O+PH 2 ). A method for controlling fo 2 at high total pressures is described, and data for the 'oxygen buffers' used are given. Buffers range from quartz+iron+fayalite assemblages (low fo 2 ) to magnetite-hematite assemblages (high fo 2 ). Optical properties and unit-cell dimensions of synthetic annites depend on the conditions of synthesis.By recalculating published analyses of natural iron-rich biotites it can be shown that one cannot assume a constant hydrogen content for such biotites. Oxidation may have occurred by drying at 115°C. Octahedral occupancy therefore cannot be calculated from such data.Phase relations of annite are presented in 2,070 and 1,035 bar sections. Depending on fo 2 -T values annite was found to decompose to one of the following assemblages: hematite+ sanidine, magnetite+sanidine, fayalite+leucite+kalsilite, iron+sanidine. All decompositions are dehydration and redox reactions and are sensitive to changes in fH 2 0 and fo 2 (or fH 2 0 and fH 2 ). At 2, 070 bars total pressure annite +magnetite+sanidine can coexist between 425°C and 825° C, depending upon the magnitude of fo 2 .In the presence of quartz the stability field of annite is more restricted. Phase equilibria in the system KAlSiO 4 -SiO 2 -Fe-O 2 -H 2 have been summarized schematically.Wherever possible, thermodynamic extrapolations are made to test the internal consistency of the data. Enthalpies of formation are calculated for both annite and phlogopite. Ranges of fo 2 values in nature as well as mechanisms for changes in fo 2 are investigated. It is useful to distinguish between assemblages which are internally buffered with respect to fo 2 changes and those which are not buffered. The applications of individual reactions involving annite to specific geologic problems are discussed with respect to igneous, metamorphic, and sedimentary rocks.

Journal of Petrology↗

USGS1962

Lower temperature terminations of the three-phase region plagioclase-alkali feldspar-liquid

Geological and experimental evidence indicate that the three-phase field, plagioclase-alkalifeldspar-liquid, may terminate in several different ways. The possible terminations have been developed from Schreinemakers' rules governing the disappearance of three-phase fields. In igncous rocks, these different terminations may arise from variations in the relative amounts of additional components in magmas, or from changes of total pressure, or from structural changes that effect the extent of solid solution in feldspar.The three-phase region originates from the intersection of the solidus and the feldspar solvus. The available evidence regarding this intersection is reviewed, as is the evidence for the existence and form of the boundary curve on the feldspar liquidus. The data are used to project a series of isobaric polythermal and isobaric isothermal diagrams for each possible termination . Subsequent discussions relate the theoretical arguments to the natural evidence, suggest the more probable geological environments of some of the terminations , and indicate characteristic features of each termination .It may be possible to identify the type of termination involved in the crystallization of some rocks. The necessary data are the amounts and compositions of both kinds of coexisting feldspars and of the feldspar components of the coexisting liquid at one or more stages of the crystallization process. Volcanic rocks are most suitable for such studies.The terminations explain many of the compositional relationships possible between feldspar crystals and silicate melt under geological and experimental conditions. These compositional relationships are fundamental to understanding the crystallization of igneous rocks and the formation of melts by partial fusion. Other geological applications include a simple explanation for some resorbed feldspars, the separation, correlation, and comparison of porphyritic rock units, interpretation of compositional changes of successive zones of zoned feldspars, and mantling of one feldspar by another. With all types of termination , extensive fractionation yields a liquid rich in Or and Ab that may crystallize to alkali feldspar or feldspars.

Journal of Petrology↗

USGS1990

Formation of anorthosite-Gabbro rhythmic phase layering: an example at North Arm Mountain, Bay of Isands ophiolite

Rhythmically layered anorthosite and gabbro are exposed in a 4–10-m thick interval at the base of the layered gabbro unit on North Arm Mountain, one of four massifs that compose the Bay of Islands ophiolite, Newfoundland. Within the rhythmically layered interval, up to 37 anorthosite layers 1–2 cm thick alternate with gabbroic layers 7–10 cm thick. Anorthosites are adcumulates (most contain <6ppm Zr) with 98–99% plagioclase (Plag) and 1–2% intergranular clinopyroxene (Cpx), whereas gabbros are adcumulates to mesocumulates (<6–20ppm Zr) with 35–55% Plag, and the balance olivine (Ol) + Cpx ± orthopyroxene (Opx). Average mineral compositions are: Ol mg -number [100 ×Mg/(Mg + Fe)]=84·9, NiO=0·13wt. % Plag An = 87·9; Cpx mg -number = 88·3, TiO 2 =0·20 wt %; and Opx mg -number = 85·7. Rare earth element (REE) concentrations in clinopyroxene and plagioclase are low throughout the rhythmically layered interval (<5 times chondrites). The rhythmically layered interval is sandwiched between thick layers of adcumulate to orthocumulate uniform gabbro with average modal proportions of 54% Plag-39% Cpx-3% Ol-4% Opx. Average mineral compositions are: Ol mg -number = 75·5, NiO = 0·08 wt. %; Plag An=69%6; Cpx mg -number = 81·2, TiO 2 =0·53 wt. %, and Opx mg -number = 77·5. Clinopyroxene and plagioclase REE abundances are systematically higher in the uniform gabbro interval than in the rhythmically layered interval. Calculated fractional crystallization paths and correlated cryptic variation patterns suggest that uniform and rhythmically layered gabbros represent 20–30% in situ crystallization of two distinct magma batches, one more evolved and the other more primitive. When the more primitive magma entered the crystallization site of the NA300–301 gabbros, it is estimated to have been ∼40°C hotter than the resident evolved magma, and may have been chilled by contact with a magma chamber margin composed of uniform gabbro. In this model, chilling caused the liquid to become supercooled with respect to plagioclase nucleation temperatures, resulting in crystallization of gabbro deficient in plagioclase relative to equilibrium cotectic proportions. Subtraction of a plagioclase-poor melagabbro enriched the liquid in normative plagioclase, which in turn led to crystallization of an anorthosite layer. Alternating anorthosite and gabbro layers in the rhythmically layered interval built up by coupled and sustained variations in crystal nucleation and growth rates, and associated variations in liquid compositions at the crystallization front. Relatively stagnant magma-flow conditions may be required to accumulate substantial thicknesses of rhythmically layered cumulates by sustained oscillatory crystallization. The rarity of anorthosite-gabbro rhythmic phase layering on North Arm Mountain may indicate that convective magma currents in the Bay of Islands magma chamber were too vigorous for oscillatory crystallization to commonly occur.

Journal of Petrology↗

USGS1990

Calc-alkaline, shoshonitic, and primitive tholeiitic lavas from monogenetic volcanoes near Crater Lake, Oregon

Quaternary monogenetic volcanism in the High Cascades of Oregon is manifested by cinder cones, lava fields, and small shields. Near Crater Lake caldera, monogenetic lava compositions include: low-K (as low as 0·09% K 2 O) high-alumina olivine tholeiite (HAOT); medium-K. calc-alkaline basalt, basaltic andesite, and andesite; and shoshonitic basaltic andesite (2·1% K 2 O, 1750 ppm Sr at 54% SiO 2 ). Tholeiites have MORB-like trace element abundances except for elevated Sr, Ba, and Th and low high field strength elements (HFSE), and they represent near-primary liquids. They are similar to HAOTs from the Cascades and adjacent Basin and Range, and to many primitive basalts from intraoceanic arcs. Calc-alkaline lavas show a well-developed arc signature of high large-ion lithophile elements (LILE) and low HFSE. Their Zr and Hf concentrations are at least partly decoupled from those of Nb and Ta; HREE are low relative to HAOT. Incompatible element abundances and ratios vary widely among basaltic andesites. Some calc-alkaline lavas vented near Mount Mazama contain abundant gabbroic microxcnoliths, and are basaltic andesitic magmas contaminated with olivine gabbro. A calc-alkaline basalt and a few basaltic andesites have MgO and compatible trace element contents that suggest only minor fractionation. There appears to be a compositional continuum between primitive tholeiitic and calc-alkaline lavas. Compositional variation within suites of comagmatic primitive lavas, both tholeiitic and calc-alkaline, mainly results from different degrees of partial melting. Sources of calc-alkaline primary magmas were enriched in LILE and LREE by a subduction component and contained residual garnet, whereas sources of HAOTs had lower LILE and LREE concentrations and contained residual clinopyroxene. High and variable LILE and LREE contents of calc-alkaline lavas reflect variations in fluid-transported subduction component added to the mantle wedge, degree of partial melting, and possibly also interaction with rocks or partial melts in the lower crust. Andesites were derived from calc-alkaline basaltic andesites by fractionation of plagioclase+augite+magnetite+apatite ± orthopyroxene or olivine, commonly accompanied by assimilation. Many andesites are mixtures of andesitic or dacitic magma and a basaltic or basaltic andesitic component, or are contaminated with gabbroic material. Mingled basalt, andesite, and dacite of Williams Crater formed by multi-component, multi-stage mixing of basaltic andesitic magma, gabbro, and dacitic magma. The wide range of compositions vented from monogenetic volcanoes near Crater Lake is a result of the thick crust coupled with mild tectonic extension superimposed on a subduction-related magmatic arc.

Oregon↗

USGS1990

Petrogenetic evolution of the torfajökull volcanic complex, Iceland I. relationship between the magma types

The Torfajökull volcano, Iceland's largest silicic centre, is situated close to the junction of the active, southerly propagating Eastern Rift Zone and the South Eastern Zone, an older crustal segment. This paper provides major, trace, and some Sr isotope data on postglacial (<10000 y) rocks, i.e., tholeiitic magmas of the Eastern Rift Zone and transitional basalts, icelandites, and rhyolites of the Torfajökull centre, and assesses the relationships between the magma types in terms of the development of the Icelandic crust.Tholeiitic magmas from the Eastern Rift Zone are LILE-enriched relative to MORB. They have undergone extensive olivine-plagioclase-clinopyroxene fractionation at low pressures. Compared with the tholeiites, Torfajökull transitional basalts show LILE/HFS enrichment and higher ( 87 Sr/ 86 Sr) 1 ratios. They define several magmatic lineages and have equilibrated over a wide range of pressures. Both basalt types were derived by very small degrees of partial melting of compositionally similar mantle sources, the main difference being that the tholeiites were generated in the spinel Iherzolite, and the transitional basalts in the garnet lherzolite, stability fields, a conclusion previously reached by Meyer et al. (1985). The mantle sources may have contained LILE-enriched streaks.Low-pressure differentiation of Torfajökull transitional basalt produced an iceiandite to sub-alkaline rhyolite sequence by crystal fractionation, the rhyolites representing >90% crystallization of parental basalts. The rhyolites were emplaced as nine separate lava fields, formed during 11 eruptive episodes. The compositional range within each field is limited, and, although similar, the ranges define several magmatic lineages. Continued fractionation of plagioclase-alkali feldspar-clinopyroxene-magnetite-apatite-zircon assemblages generated peralkaline rhyolites in certain post-glacial eruptions. Chemical variations in the deposits from the Hrafntinnusker peralkaline eruption were related predominantly to alkali feldspar fractionation, and the melts were erupted from a zoned magma chamber. All postglacial volcanic rocks at Torfajokull have been mantle derived and thus represent new additions to the Icelandic crust. © 1990 Oxford University Press.

Journal of Petrology↗

USGS1990

Petrogenetic evolution of the torfajökull volcanic complex, Iceland II. The role of magma mixing

In southern Iceland, tholeiitic basalt magmas propagating laterally from the active Eastern Rift Zone into the older cmstal segment of the South Eastern Zone have been injected into Torfajökull, a mature volcanic centre dominated by rhyolites. Eruptions of complex suites of mixed and hybrid rocks have been triggered, involving tholeiites of the rift zone and transitional basalts and rhyolites of the Torfajökull centre. Three-component hybrids are an unusual feature of the activity. The distribution of various magma mixing and hybrid types is related to the periodic injection of tholeiite into a magma chamber, or chambers, where rhyolite overlies parental transitional basalts.Pre-postglacial rhyolites (>10000 y) at Torfajokull are predominantly peralkaline, whereas later rhyolites are, with few exceptions, subalkaline. Furthermore, the injection of rift zone magmas, and the consequent abundance of rhyolite-basalt mixing, have been important features of magmatism at the centre only in postglacial times. Reduced repose times in the magma reservoirs have prevented the production of peralkaline rhyolites. These trends are interpreted in terms of the southerly migration of the Eastern Rift Zone. © 1990 Oxford University Press.

Journal of Petrology↗

USGS1990

Metamorphism in the Adirondacks: II. The role of fluids

Quantitative estimates of metamorphic fluid speciation, stable isotopic analyses, and studies of fluid inclusions all document the local complexity of fluids in the deep crustal rocks exposed in the Adirondack Mountains, NY. Estimates of the activity of H 2 O in the granulite facies are substantially lower than in the amphibolite facies gneisses. The onset of low water activities in semi-pelitic gneisses generally correlates with migmatitic textures in the uppermost amphibolite facies, suggesting that partial melts absorbed H 2 O at the peak of metamorphism. In granulite facies marbles and calc-silicates, conditions varied from extremely undersaturated in H 2 O-CO 2 fluid to fluid saturated, and α H2O and α CO2 show sharp gradients within single outcrops. Low values of f O2 and f H2O , or of f CO2 , and f H2O indicate fluid-absent conditions for some orthogneisses and marbles, which are inferred to have been ‘dry’ rocks before and during granulite facies recrystallization. Wollastonite is preserved from early contact metamorphism and serves as an index mineral for fluid-absent conditions in granulites where α H2O is low. Values of f O2 range from near the hematite + magnetite buffer in metamorphosed iron formation to substantially below the quartz + magnetite + fayalite buffer in some orthogneisses. The anorthosite suite is more oxidized than some associated granitic gneisses. Halogens (F and Cl) substitute extensively for OH in micas and amphiboles, extending their stability, although F 2 , Cl 2 , HCl, and HF are minor components in any fluid. Oxybiotite-type exchanges involving O for OH are also important, extending the stability of biotite. Stable isotopic ratios of O and C demonstrate that premetamorphic whole-rock compositions are commonly preserved whereas mineral compositions generally reflect equilibration at the peak of metamorphism. The Marcy Anorthosite Massif was intruded as a high δ 18 O magma. The combination of mineral equilibria, stable isotope data, and fluid inclusions is used to identify and to distinguish among pre-orogenic contact metamorphic/hydrothermal events, peak metamorphic events, and retrograde/postmetamorphic events. Polymetamorphism is documented at skarn zones adjacent to anorthosite, where large volumes of hydrothermal fluid were channeled during early, shallow contact metamorphism and where conditions were fluid poor during subsequent regional metamorphism. Peak metamorphic events are inferred to have been caused primarily by magmatic processes of intrusion and anatexis. Partial melting has caused low values of α H2O in many rocks, but in other cases low values of α H2O are recorded in orthogneisses derived from H 2 O-poor magmas. Isotopic studies show that maximum fluid/rock ratios were <0·l and possibly 0·0 for infiltrating fluids at the peak of metamorphism in many localities. No evidence of pervasive, regional infiltration by a fluid at the peak of metamorphism has been substantiated in the Adirondacks. Fluid inclusions containing high-density CO 2 or CO 2 + H 2 O represent conditions from after the peak of metamorphism and document isobaric cooling, in agreement with estimates from garnet zoning. Fine-scale retrograde veins are common and are associated with high-density CO 2 -rich fluid inclusions.

New York↗

USGS1990

Geochemistry and intrusive history of the Ashland pluton, Klamath Mountains, California and Oregon

The Ashland pluton is a calc-alkaline plutonic complex that intruded the western Paleozoic and Triassic belt of the Klamath Mountains in late Middle Jurassic time. The pluton comprises a series of compositionally distinct magma pulses. The oldest rocks are hornblende gabbro and two-pyroxene quartz gabbro with initial 87 Sr/ 86 Sr = 0˙7044, δ 18 O = 8˙7%, and REE patterns with chondrite normalized La/Lu = 7. These units were followed by a suite of tonalitic rocks (La N /Lu N = 7) and then by a suite of K 2 O- and P 2 O 5 rocks of quartz monzodioritic affinity (La N /Lu N = 13–21; La N /Sm N = 2˙4–3˙) The quartz monzodioritic rocks were then intruded by biotite granodiorite and granite with lower REE abundances but more fractionated LREE(La N /Lu N = 13–19; La N /Sm N = 4˙3–6 and they, in turn, were host to dikes and bosses of hornblende diorite. The latest intrusive activity consisted of aplitic and granitic dikes. Combined phase equilibria and mineral composition data, indicate emplacement conditions of approximately P total = 2˙3kb, P H2O between 1˙5 and 2˙2 kb, and f O2 between the nickel-nickel oxide and hematite-magnetite buffers. Successive pulses of magma display increasing SiO 2 together with increasing δ 18 O and decreasing initial 87 Sr/ 86 Sr. The isotopic data are consistent with either (1) combined fractional crystallization of andesitic magma and concurrent assimilation of crustal material characterized by low Sr 1 and high (δ 18 O or, more probably, (2) a series of partial melting events in which sources were successively less radiogenic but richer in 18 O Each intrusive stage displays evidence for some degree of crystal accumulation and/or fractional crystallization but neither process adequately accounts for their compositional differences. Consequently, each stage appears to represent a distinct partial melting or assimilation event. The P 2 O 5 -rich nature of the quartz monzodiorite suite suggests accumulation of apatite. However, the suite contains abundant mafic microgranitoid enclaves and most apatite in the suite is acicular. These observations suggest that magma mixing affected the compositional variation of the quartz monzodiorite suite. Mass balance calculations are consistent with a simple mixing process in which P 2 O 5 -rich alkalic basalt magma (represented by the mafic microgranitoid enclaves) was combined with a crystal-poor felsic magma (represented by the tonalite suite), yielding a quartz monzodioritic magma that then underwent differentiation by crystal fractionation and accumulation.

California, Oregon↗