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At least 973 records · Page 54Linked to original sources

Are brook trout streams in Western Virginia and Shenandoah National Park recovering from acidification?

Streamwater composition data obtained through periodic sampling of streams that support brook trout ( Salvelinus fontinalis ) in the mountains of western Virginia were examined for evidence of recovery from acidification during the 1988−2001 period. Measurements of sulfate deposition in precipitation indicate that sulfate deposition in the region declined approximately 40% between 1985 and 2000. While no significant regional trends in acid−base constituents were observed for the set ( n = 65) of western Virginia study streams, significant regional trends were observed for a subset ( n = 14) of streams in Shenandoah National Park (SNP). For the subset of SNP streams, the median increase in acid-neutralizing capacity (ANC) was 0.168 μequiv L -1 year -1 and the median decrease in sulfate concentration was −0.229 μequiv L -1 year -1 . Although these trends are consistent with recovery from acidification, the degree of apparent recovery is small compared to estimates of historic acidification in SNP streams and much less than observed in other, more northern regions in the United States. Correlation between sulfate concentration trends and current sulfate concentrations in streamwater suggests that recovery from stream acidification in the western Virginia region is determined by sulfur retention processes in watershed soils. A transient increase in nitrate concentrations that occurred among some western Virginia streams following forest defoliation by the gypsy moth ( Lymantria dispar ) complicates interpretation of the observed patterns of change in acid−base status.

Virginia↗

Thioarsenates in geothermal waters of Yellowstone National Park: Determination, preservation, and geochemical importance

Mono-, di-, tri-, and tetrathioarsenate, as well as methylated arsenic oxy- and thioanions, were determined besides arsenite and arsenate in geothermal waters of Yellowstone National Park using anion-exchange chromatography inductively coupled plasma mass spectrometry. Retention time match with synthetic standards, measured S:As ratios, and molecular electrospray mass spectra support the identification. Acidification was unsuitable for arsenic species preservation in sulfidic waters, with HCl addition causing loss of total dissolved arsenic, presumably by precipitation of arsenic-sulfides. Flash-freezing is preferred for the preservation of arsenic species for several weeks. After thawing, samples must be analyzed immediately. Thioarsenates occurred over a pH range of 2.1 to 9.3 in the geothermal waters. They clearly predominated under alkaline conditions (up to 83% of total arsenic), but monothioarsenate also was detected in acidic waters (up to 34%). Kinetic studies along a drainage channel showed the importance of thioarsenates for the fate of arsenic discharged from the sulfidic hot spring. The observed arsenic speciation changes suggest three separate reactions: the transformation of trithioarsenate to arsenite (major initial reaction), the stepwise ligand exchange from tri- via di- and monothioarsenate to arsenate (minor reaction), and the oxidation of arsenite to arsenate, which only becomes quantitatively important after thioarsenates have disappeared.

Wyoming↗

Evaluating regional patterns in nitrate sources to watersheds in national parks of the Rocky Mountains using nitrate isotopes

In the Rocky Mountains, there is uncertainty about the source areas and emission types that contribute to nitrate (NO 3 ) deposition, which can adversely affect sensitive aquatic habitats of high-elevation watersheds. Regional patterns in NO 3 deposition sources were evaluated using NO 3 isotopes in five National Parks, including 37 lakes and 7 precipitation sites. Results indicate that lake NO 3 ranged from detection limit to 38 μeq/L, δ 18 O (NO 3 ) ranged from −5.7 to +21.3‰, and δ 15 N (NO 3 ) ranged from −6.6 to +4.6‰. δ 18 O (NO 3 ) in precipitation ranged from +71 to +78‰. δ 15 N (NO 3 ) in precipitation and lakes overlap; however, δ 15 N (NO 3 ) in precipitation is more depleted than δ 15 N (NO 3 ) in lakes, ranging from −5.5 to −2.0‰. δ 15 N (NO 3 ) values are significantly related ( p < 0.05) to wet deposition of inorganic N, sulfate, and acidity, suggesting that spatial variability of δ 15 N (NO 3 ) over the Rocky Mountains may be related to source areas of these solutes. Regional patterns show that NO 3 and δ 15 N (NO 3 ) are more enriched in lakes and precipitation from the southern Rockies and at higher elevations compared to the northern Rockies. The correspondence of high NO 3 and enriched δ 15 N (NO 3 ) in precipitation with high NO 3 and enriched δ 15 N (NO 3 ) in lakes, suggests that deposition of inorganic N in wetfall may affect the amount of NO 3 in lakes through a combination of direct and indirect processes such as enhanced nitrification.

Environmental Science & Technology↗

Chemical characteristics of particulate, colloidal, and dissolved organic material in Loch Vale Watershed, Rocky Mountain National Park

The chemical relationships among particulate and colloidal organic material and dissolved fulvic acid were examined in an alpine and subalpine lake and two streams in Loch Vale Watershed, Rocky Mountain National Park. The alpine lake, Sky Pond, had the lowest dissolved organic carbon (DOC) (0.37 mgC/L), the highest particulate carbon (POC) (0.13 mgC/L), and high algal biomass. The watershed of Sky Pond is primarily talus slope, and DOC and POC may be autochthonous. Both Andrews Creek and Icy Brook gain DOC as they flow through wet sedge meadows. The subalpine lake, The Loch, receives additional organic material from the surrounding forest and had a higher DOC (0.66 mgC/L). Elemental analysis, stable carbon isotopic compositon, and 13C-NMR characterization showed that: 1) particulate material had relatively high inorganic contents and was heterogeneous in compositon, 2) colloidal material was primarily carbohydrate material with a low inorganic content at all sites; and 3) dissolved fulvic acid varied in compositon among sites. The low concentration and carbohydrate-rich character of the colloidal material suggests that this fraction is labile to microbial degradation and may be turning over more rapidly than particulate fractions or dissolved fulvic acid. Fulvic acid from Andrews Creek had the lowest N content and aromaticity, whereas Sky Pond fulvic acid had a higher N content and lower aromaticity than fulvic acid from The Loch. The UV-visible spectra of the fulvic acids demonstrate that variation in characteristics with sources of organic carbon can explain to some extent the observed nonlinear relationship between UV-B extinction coefficients and DOC concentrations in lakes.

Colorado↗

Aspen structure and variability in Rocky Mountain National Park, Colorado, USA

Elk, fire and climate have influenced aspen populations in the Rocky Mountains, but mostly subjective studies have characterized these factors. A broad-scale perspective may shed new light on the status of aspen in the region. We collected field measurements of aspen (Populus tremuloides Michx.) patches encountered within 36 randomly located belt transects in 340 km2 of Rocky Mountain National Park, Colorado, to quantify the aspen population. Aspen covered 5.6% of the area in the transects, much more than expected based on previously collected remotely sensed data. The distribution and structure of aspen patches were highly heterogeneous throughout the study area. Of the 123 aspen patches encountered in the 238 ha surveyed, all but one showed signs of elk browsing or had conifer species mixed with the aspen stems. No significant difference occurred in aspen basal area, density, regeneration, browsing of regeneration and patch size, between areas of concentrated elk use (elk winter range) and areas of dispersed elk use (elk summer range). Two-thirds of the aspen patches were mixed with conifer species. We concluded that the population of aspen in our study area is highly variable in structure and that, at a landscape-scale, evidence of elk browsing is widespread but evidence of aspen decline is not.

Landscape Ecology↗

Air blasts generated by rockfall impacts: Analysis of the 1996 Happy Isles event in Yosemite National Park

The July 10, 1996, Happy Isles rockfall in Yosemite National Park, California, released 23,000 to 38,000 m 3 of granite in four separate events. The impacts of the first two events which involved a 550-m free fall, generated seismic waves and atmospheric pressure waves (air blasts). We focus on the dynamic behavior of the second air blast that downed over 1000 trees, destroyed a bridge, demolished a snack bar, and caused one fatality and several injuries. Calculated velocities for the air blast from a two-phase, finite difference model are compared to velocities estimated from tree damage. From tornadic studies of tree damage, the air blast is estimated to have traveled <108–120 m/s within 50 m from the impact and decreased to <10–20 m/s within 500 m from the impact. The numerical model simulates the two-dimensional propagation of an air blast through a dusty atmosphere with initial conditions defined by the impact velocity and pressure. The impact velocity (105–107 m/s) is estimated from the Colorado Rockfall Simulation Program that simulates rockfall trajectories. The impact pressure (0.5 MPa) is constrained by the kinetic energy of the impact (10 10 –10 12 J) estimated from the seismic energy generated by the impact. Results from the air blast simulations indicate that the second Happy Isles air blast (weak shock wave) traveled with an initial velocity above the local sound speed. The size and location of the first impact are thought to have injected <50 wt% dust into the atmosphere. This amount of dust lowered the local atmospheric sound speed to ∼220 m/s. The discrepancy between calculated velocity data and field estimated velocity data (∼220 m/s versus ∼110 m/s) is attributed to energy dissipated by the downing of trees and additional entrainment of debris into the atmosphere not included in the calculations.

Journal of Geophysical Research B: Solid Earth↗

Relations between basin characteristics and stream water chemistry in alpine/subalpine basins in Rocky Mountain National Park, Colorado

Relations between stream water chemistry and topographic, vegetative, and geologic characteristics of basins were evaluated for nine alpine/subalpine basins in Rocky Mountain National Park, Colorado, to identify controlling parameters and to better understand processes governing patterns in stream water chemistry. Fractional amounts of steep slopes (≥30°), unvegetated terrain, and young surficial debris within each basin were positively correlated to each other. These terrain features, which commonly occur on steep valley side slopes underlain by talus, were negatively correlated with concentrations of base cations, silica, and alkalinity and were positively correlated with nitrate, acidity, and runoff. These relations might result from the short residence times of water and limited soil development in the talus environment, which limit chemical weathering and nitrogen uptake. Steep, unvegetated terrains also tend to promote high Ca/Na ratios in stream water, probably because physical weathering rates in those areas are high. Physical weathering exposes fresh bedrock that contains interstitial calcite, which weathers relatively quickly. The fractional amounts of subalpine meadow and, to a lesser extent, old surficial debris in the basins were positively correlated to concentrations of weathering products and were negatively correlated to nitrate and acidity. These relations may reflect more opportunities for silicate weathering and nitrogen uptake in the lower‐energy environments of the valley floor, where soils are finer‐grained, older, and better developed and slopes are relatively flat. These results indicate that in alpine/subalpine basins, slope, vegetation (or lack thereof), and distribution and age of surficial materials are interrelated and can have major effects on stream water chemistry.

Colorado↗

Determination of hydrologic pathways during snowmelt for alpine/subalpine basins, Rocky Mountain National Park, Colorado

Alpine/subalpine ecosystems in Rocky Mountain National Park may be sensitive to atmospherically derived acidic deposition. Two‐ and three‐component hydrograph separation analyses and correlation analyses were performed for six basins to provide insight into streamflow generation during snowmelt and to assess basin sensitivity to acidic deposition. Three‐component hydrograph separation results for five basins showed that streamflow contained from 42 to 57% direct snowmelt runoff, 37 to 54% subsurface water, and 4 to 13% direct rain runoff for the May through October 1994 study period. Subsurface contributions were 89% of total flow for the sixth basin. The reliability of hydrograph separation model assumptions was explored. Subsurface flow was positively correlated with the amount of surficial material in a basin and was negatively correlated with basin slope. Basins with extensive surficial material and shallow slopes are less susceptible to ecosystem changes due to acidic deposition than basins with less surficial material and steeper slopes. This study was initiated to expand the intensive hydrologic research that has been conducted in Loch Vale basin to a more regional scale.

Water Resources Research↗

Interpretation of concentration‐discharge patterns in acid‐neutralizing capacity during storm flow in three small, forested catchments in Shenandoah National Park, Virginia

Episodic concentration‐discharge ( c‐Q ) plots are a popular tool for interpreting the hydrochemical response of small, forested catchments. Application of the method involves assuming an underlying conceptual model of runoff processes and comparing observed c‐Q looping patterns with those predicted by the model. We analyzed and interpreted c‐Q plots of acid‐neutralizing capacity (ANC) for 133 storms collected over a 7‐year period from three catchments in Shenandoah National Park, Virginia. Because of their underlying lithologies the catchments represent a gradient in both hydrologic and geochemical behavior, ranging from a flashy, acidic, poorly buffered catchment to a moderate, neutral, well‐buffered catchment. The relative frequency of observed anticlockwise c‐Q loops in each catchment decreased along this gradient. Discriminant function analysis indicated that prestorm base flow ANC was an important predictor of loop rotation direction; however, the strength of the predictive relationship decreased along the same gradient. The trends were consistent with several equally plausible three‐component mixing models. Uncertainty regarding end‐member timing and relative volume and possible time variation in end‐member concentrations were key factors precluding identification of a unique model. The inconclusive results obtained on this large data set suggest that identification of underlying runoff mechanisms on the basis of a small number of c‐Q plots without additional supporting evidence is likely to be misleading.

Virginia↗

Decadal-scale climate drivers for glacial dynamics in Glacier National Park, Montana, USA

Little Ice Age (14th-19th centuries A.D.) glacial maxima and 20th century retreat have been well documented in Glacier National Park, Montana, USA. However, the influence of regional and Pacific Basin driven climate variability on these events is poorly understood. We use tree-ring reconstructions of North Pacific surface temperature anomalies and summer drought as proxies for winter glacial accumulation and summer ablation, respectively, over the past three centuries. These records show that the 1850's glacial maximum was likely produced by ???70 yrs of cool/wet summers coupled with high snowpack. Post 1850, glacial retreat coincides with an extended period (>50 yr) of summer drought and low snowpack culminating in the exceptional events of 1917 to 1941 when retreat rates for some glaciers exceeded 100 m/yr. This research highlights potential local and ocean-based drivers of glacial dynamics, and difficulties in separating the effects of global climate change from regional expressions of decadal-scale climate variability. Copyright 2004 by the American Geophysical Union.

Montana↗

Analyses of unusual long-period earthquakes with extended coda recorded at Katmai National Park, Alaska, USA

A swarm of six long-period (LP) events with slowly decaying coda wave amplitudes and durations up to 120 s, was recorded by seismic stations located in the proximity of Mt. Griggs, a fumarolically active volcano in the Katmai National Park, Alaska, during December 8–21, 2004. Spectral analyses reveal the quasi-monochromatic character of the waveforms, dominated by a 2.5 Hz mode frequently accompanied by a weaker high-frequency onset (6.0–9.0 Hz). Particle motion azimuths and inclination angles show a dominant WNW-ESE direction of polarization for all the signals, and suggest that seismic energy is radiated by a stable source at shallow depth. Damping coefficients between 0.0014 and 0.0063 are estimated by fitting an exponential decay model to the signal's coda; corresponding quality factors range from 78 to 351. The source of the waveforms is modelled as a resonant cavity filled with a fluid/gas mixture.

Alaska↗

Time series and recurrence interval models to predict the vulnerability of streams to episodic acidification in Shenandoah National Park, Virginia

Acid rain affects headwater streams by temporarily reducing the acid‐neutralizing capacity (ANC) of the water, a process termed episodic acidification. The increase in acidic components in stream water can have deleterious effects on the aquatic biota. Although acidic deposition is uniform across Shenandoah National Park (SNP) in north central Virginia, the stream water quality response during rain events varies substantially. This response is a function of the catchment's underlying geology and topography. Geologic and topographic data for SNP's 231 catchments are readily available; however, long‐term measurements (tens of years) of ANC and accompanying discharge are not and would be prohibitively expensive to collect. Transfer function time series models were developed to predict hourly ANC from discharge for five SNP catchments with long‐term water‐quality and discharge records. Hourly ANC predictions over short time periods (≤1 week) were averaged, and distributions of the recurrence intervals of annual water‐year minimum ANC values were model‐simulated for periods of 6, 24, 72, and 168 hours. The distributions were extrapolated to the rest of the SNP catchments on the basis of catchment geology and topography. On the basis of the models, large numbers of SNP streams have 6‐ to 168‐hour periods of low‐ANC values, which may stress resident fish populations. Smaller catchments are more vulnerable to episodic acidification than larger catchments underlain by the same bedrock. Catchments with similar topography and size are more vulnerable if underlain by less basaltic/carbonate bedrock. Many catchments are predicted to have successive years of low‐ANC values potentially sufficient to extirpate some species.

Virginia↗

A multitracer approach for characterizing interactions between shallow groundwater and the hydrothermal system in the Norris Geyser Basin area, Yellowstone National Park

Multiple environmental tracers are used to investigate age distribution, evolution, and mixing in local‐ to regional‐scale groundwater circulation around the Norris Geyser Basin area in Yellowstone National Park. Springs ranging in temperature from 3°C to 90°C in the Norris Geyser Basin area were sampled for stable isotopes of hydrogen and oxygen, major and minor element chemistry, dissolved chlorofluorocarbons, and tritium. Groundwater near Norris Geyser Basin is comprised of two distinct systems: a shallow, cool water system and a deep, high‐temperature hydrothermal system. These two end‐member systems mix to create springs with intermediate temperature and composition. Using multiple tracers from a large number of springs, it is possible constrain the distribution of possible flow paths and refine conceptual models of groundwater circulation in and around a large, complex hydrothermal system.

Wyoming↗

Temporal variations of geyser water chemistry in the Upper Geyser Basin, Yellowstone National Park, USA

Geysers are rare features that reflect a delicate balance between an abundant supply of water and heat and a unique geometry of fractures and porous rocks. Between April 2007 and September 2008, we sampled Old Faithful, Daisy, Grand, Oblong, and Aurum geysers in Yellowstone National Park's Upper Geyser Basin and characterized temporal variations in major element chemistry and water isotopes (δ 18 O, δD, 3 H). We compare these temporal variations with temporal trends of Geyser Eruption Intervals (GEI). SiO 2 concentrations and geothermometry indicate that the geysers are fed by waters ascending from a reservoir with temperatures of ∼190 to 210°C. The studied geysers display small and complex chemical and isotopic seasonal variations, and geysers with smaller volume display larger seasonal variations than geysers with larger volumes. Aurum and Oblong Geysers contain detectable tritium concentrations, suggesting that erupted water contains some modern meteoric water. We propose that seasonal GEI variations result from varying degrees of evaporation, meteoric water recharge, water table fluctuations, and possible hydraulic interaction with the adjacent Firehole River. We demonstrate that the concentrations of major dissolved species in Old Faithful Geyser have remained nearly constant since 1884 despite large changes in Old Faithful's eruption intervals, suggesting that no major changes have occurred in the hydrothermal system of the Upper Geyser Basin for >120 years. Our data set provides a baseline for monitoring future changes in geyser activity that might result from varying climate, earthquakes, and changes in heat flow from the underlying magmatic system.

Wyoming↗

Origin and properties of hydrothermal tremor at Lone Star Geyser, Yellowstone National Park, USA

Geysers are rare geologic features that intermittently discharge liquid water and steam driven by heating and decompression boiling. The cause of variability in eruptive styles and the associated seismic signals are not well understood. Data collected from five broadband seismometers at Lone Star Geyser, Yellowstone National Park are used to determine the properties, location, and temporal patterns of hydrothermal tremor. The tremor is harmonic at some stages of the eruption cycle and is caused by near‐periodic repetition of discrete seismic events. Using the polarization of ground motion, we identify the location of tremor sources throughout several eruption cycles. During preplay episodes (smaller eruptions preceding the more vigorous major eruption), tremor occurs at depths of 7–10 m and is laterally offset from the geyser's cone by ~5 m. At the onset of the main eruption, tremor sources migrate laterally and become shallower. As the eruption progresses, tremor sources migrate along the same path but in the opposite direction, ending where preplay tremor originates. The upward and then downward migration of tremor sources during eruptions are consistent with warming of the conduit followed by evacuation of water during the main eruption. We identify systematic relations among the two types of preplays, discharge, and the main eruption. A point‐source moment tensor fit to low‐frequency waveforms of an individual tremor event using half‐space velocity models indicates average V S ≳ 0.8 km/s, source depths ~4–20 m, and moment tensors with primarily positive isotropic and compensated linear vector dipole moments.

Wyoming↗

The relation between decadal droughts and eruptions of Steamboat Geyser in Yellowstone National Park, USA

In the past century, most eruptions of Steamboat Geyser in Yellowstone National Park's Norris Geyser Basin were mainly clustered in three episodes: 1961–1969, 1982–1984, and ongoing since 2018. These eruptive episodes resulted in extensive disturbance to surrounding trees. To characterize tree response over time as an indicator of geyser activity adjustments to climate variability, aerial and ground images were analyzed to document changes in tree coverage around the geyser since 1954. Radiocarbon dating of silicified tree remnants from within 14 m of the geyser vent was used to examine geyser response to possible variations in decadal to centennial precipitation patterns. We searched for atypical or absent growth rings in cores from live trees in years associated with large geyser eruptions. Photographs indicate that active eruptive phases have adversely affected trees up to 30 m from the vent, primarily in the dominant downwind direction. Radiocarbon dates indicate that the geyser formed before 1878, in contrast to the birthdate reported in historical documents. Further, the ages of the silicified trees cluster within three episodes that are temporally correlated with periods of relative drought in the Yellowstone region during the 15th–17th centuries. The discontinuous growth of trees around the geyser suggests that changes in eruptive patterns occur in response to decadal to multidecadal droughts. This inference is supported by the lack of silicified specimens with more than 20 annual rings and by the existence of atypical or missing rings in live trees during periods of extended geyser activity.

Wyoming↗

Rapid seismic and infrasound assessment of large landslides: A case study from Denali National Park and Preserve (Alaska)

Large, rapid landslides are a global hazard that can occur in remote, mountainous areas. Eyewitness reports of landslides and satellite imagery can often be limited or delayed, particularly during inclement weather. However, landslide-generated seismic and infrasound (low-frequency atmospheric sound) waves can be remotely detected in near real-time. This information can significantly expedite characterization and possible landslide response activities. Here, we highlight these capabilities using a > 4 million m³ ice–rock avalanche in Denali National Park and Preserve (Alaska). This event was detected via a landslide-specific seismic location and volume estimation algorithm deployed in Alaska, and — notably — by standard earthquake monitoring systems. Following rapid detection of this event, we combined its seismic and infrasound dataset with optical, synthetic aperture radar, and oblique aerial imagery, multitemporal digital elevation models, and a numerical flow model to reconstruct its failure timeline and dynamics. We apply array processing to infrasound signals traveling > 250 km and find that two precursory events occurred minutes prior to the main failure. We use long-period seismic signals to infer the force exerted by the landslide on the Earth and constrain the rheological parameters of our numerical flow simulation with this result and deposit morphology. The main failure produced a steeply-dipping impulsive initial downward force and reached speeds exceeding 60 m/s. This impulsive force generated relatively strong seismic body waves, which contributed to the earthquake system detection. This large, remote Alaska landslide underscores the key value of seismic and infrasound analysis for rapid landslide assessment and motivates efforts to further operationalize these approaches.

Alaska↗

A geodetic network in the Novarupta area, Katmai National Park, Alaska

A small geodetic network was established in 1989 and 1990 to monitor ground deformation in the Novarupta area, Katmai National Park, Alaska. Slope distances and zenith angles for three lines were repeated in 1990. A comparison of the two surveys indicates changes that are within the error of the measurements. Mean mark-to-mark slope distance changes are 1.17±1.46 ppm. Two benchmarks were added to the network in 1990 to configure a five-endpoint braced quadrilateral centered about the Novarupta dome.

Geophysical Research Letters↗