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1,661 records · Page 54Linked to original sources
USGS2025

Kiloyear cycles of carbonate and Mg-silicate replacement at Von Damm hydrothermal vent field

The Von Damm vent field (VDVF) on the Mid-Cayman Rise in the Caribbean Sea is unique among modern hydrothermal systems in that the chimneys and mounds are almost entirely composed of talc. We analyzed samples collected in 2020 and report that in addition to disordered talc of variable crystallinity, carbonates are a major class of mineral at VDVF. The carbonate minerals include aragonite, calcite, magnesium-rich calcite, and dolomite. Talc and carbonate mineral textures indicate that, rather than replacing volcanic host rock, they precipitate from the mixing of hydrothermal fluids and seawater at the seafloor, occurring in chimneys and surrounding rubble. Alternating precipitation of this mineral assemblage is pervasive, with carbonate minerals typically being succeeded by talc, and with indications that in some cases talc and carbonate minerals replace one another. Stable carbon isotopic data indicate the carbonate minerals originate from the mixing of seawater and hydrothermal fluid, which is supported by U-Th data. Radiocarbon calcite ages and talc 234 U- 230 Th isochron ages indicate mineral ages spanning over thousands to tens of thousands of years. Analyses of these samples illustrate a dynamic system that transitions from carbonate-dominated to Mg-silicate−dominated precipitation over time scales of thousands of years. Our observations raise questions regarding the eventual fate of seafloor precipitates and whether carbonate and silicate minerals in such settings are sequestered and represented in the rock record.

Geology↗
USGS2024

Field evidence and indicators of rockfall fragmentation and implications for mobility

Rockfall fragmentation can play an important role in hazard studies and the design of protective measures. However, the current lack of modeling tools that incorporate rock fragmentation mechanics is a limitation to enhancing studies and design. This research investigates the fragmentation patterns of rockfalls and analyzes the resulting distribution of fragment sizes within corresponding rockfall deposits. We focus on small rock fragments, which provide insights into the dynamics of the rockfall event and can be used as input for numerical modeling. We analyzed multiple rockfall events from locations worldwide, each exhibiting different degrees of fragmentation. Using image analysis techniques, we mapped all visible blocks, determined their volumes, and measured the distances they travelled from the initial point of impact. A key finding is the identification of three indicators of fragmentation. First, in cases where fragmentation was largely absent, we observed a trend of increasing block size with distance from the impact point or source area, which aligns with previously published findings. However, for energetic rockfall events characterized by intense fragmentation, we observed that small fragments exhibited longer travel distances compared to larger fragments. This distinction allowed us to differentiate blocks primarily resulting from the disaggregation process from those primarily resulting from dynamic fragmentation, with implications for rockfall mobility. Second, although the size distribution of rockfall deposits exhibits a power-law scaling for volumes larger than a minimum size threshold corresponding to a rollover of the distribution, in some case studies a deviation from power-law scaling is observed, indicating a process of larger block comminution due to fragmentation. Third, we found that rockfalls with fragmentation experience reduced mobility, indicated by higher reach angles, and higher lateral dispersion showing a wider distribution of trajectories. We interpret these findings as being directly related to the energy-consuming nature of fragmentation, which prevents farther deposition of fragmented rock blocks.

Albacete province, Lombardy and Aosta Valley, Yose↗
USGS2026

Streamflow, base-flow, and precipitation trends and simulated effects of groundwater withdrawals from the North Fork Red River aquifer on base flows upgradient from Lake Altus, western Oklahoma, 1980–2022

The U.S. Geological Survey, in cooperation with the Bureau of Reclamation, used five scenarios created from a previously published numerical groundwater-flow model (1980–2013) and historical streamflow records (1980–2022) to investigate the relation between groundwater withdrawals from the North Fork Red River aquifer and inflows to Lake Altus from the North Fork Red River in western Oklahoma. The five scenarios were (1) a scaled-equal-proportionate-share (EPS) groundwater-withdrawal scenario, (2) a study-area-scaled-reported groundwater-withdrawal scenario, (3) a zonal-scaled-reported groundwater-withdrawal scenario, (4) a historical drought-threshold scenario, and (5) a base-flow and evapotranspiration depletion scenario. For the scaled-EPS groundwater-withdrawal scenario, EPS groundwater withdrawals were often much higher than reported groundwater withdrawals and greatly decreased base flows for most scale factors. For the study-area-scaled-reported groundwater-withdrawal scenario, base flows were reduced more but by smaller percentages during wet periods than during dry periods when scaling simulated reported groundwater withdrawals. For the zonal-scaled-reported groundwater-withdrawal scenario, scaling simulated reported groundwater withdrawals within selected zones with more groundwater withdrawals did not always affect base flows more than scaling reported groundwater withdrawals within zones with less groundwater withdrawals. For the historical drought-threshold scenario, curtailing groundwater withdrawals at the drought thresholds increased annual base flows to Lake Altus by about 1,169 to 3,665 acre-feet. For the base-flow and evapotranspiration depletion scenario, the distance between a groundwater well and a stream was a major factor affecting base flow to the North Fork Red River when increasing groundwater withdrawals; however, spatially variable hydrologic properties and saturated-zone evapotranspiration could also affect the relation between base flows and groundwater withdrawals.

Oklahoma↗
USGS2025

Melt generation sources and conditions in the wake of a migrating slab window: Geochemistry and petrology of the million-year history of primitive volcanism at Clear Lake volcanic field, California

Clear Lake volcanic field (CLVF) is the northernmost and youngest (~2.2 Ma to 8 ka) of the volcanic centers distributed along the San Andreas transform fault in western California. The initial phase of CLVF volcanism (interval one) occurred between ~2.2 and 1.3 Ma and extends ~35 km southeast of Clear Lake, forming a semi-continuous upland plateau capped by lava flows, with isolated volcanic remnants on the periphery. This volcanism is broadly characterized by geochemically primitive compositions that reflect three source compositions and conditions of melt generation. (1) Partial melting of upwelling asthenospheric mantle lherzolite at moderate pressures (1.2–1.4 GPa) and temperatures (1297–1329 °C) produced high-CaO (9.8–11.3 wt %) basalts with high Al 2 O 3 (16.8–17.6 wt %), Mg#s (66–70), MgO (8–10 wt %), Ni (103–262 μg/g), and Cr (284–609 μg/g). These high-CaO basalts contain olivine (Fo 87–91 ) phenocrysts with Cr-spinel inclusions ± subordinate plagioclase and crop out only in the southern part of the CLVF. (2) Partial melting of depleted sub-continental lithospheric mantle harzburgite at variable pressures (0.7–1.5 GPa) and temperatures (1097–1299 °C) produced a compositional continuum of med-K 2 O, calc-alkaline, high-MgO basalts through high-MgO andesites with high Mg#s (67–77), MgO (8–14 wt %) and high Ni and Cr abundances (154–439 and 340–1124 μg/g, respectively). Mineral assemblages are olivine (Fo 88–93 ) with Cr-spinel inclusions ± subordinate clinopyroxene, orthopyroxene and plagioclase. Small (<2.5 cm) mantle harzburgite xenoliths and mantle olivine xenocrysts are also found in several of these samples. These high-MgO basalts through andesites represent the largest volume of primitive compositions and have erupted predominantly along the main, fault-controlled northwest-southeast trending axis of volcanism with peripheral outcrops to the north, west, and east. (3) Partial melting of the Gorda eclogite slab edge produced adakitic silicic slab melts with strong depletion in the heavy rare earth elements (Yb = 0.6 μg/g). Subsequent reaction of those melts with depleted ultramafic rocks during ascent imprinted the adakitic dacites with high Mg#s (65–78) and elevated Ni (117–210 μg/g) and Cr (191–283 μg/g). Phenocrysts of orthopyroxene (En 87–94 ) with spinel inclusions (Cr# = 80–88) and extremely Ni-rich (9483 μg/g) olivine cores (Fo 84–93 ) record those reactions. Small-volume outcrops of the adakites on the eastern periphery of the CLVF track the passing slab edge. The trio of melting sources recorded by early CLVF magmatism reflect the tectonically complex environment and the hot (1097–1329 °C), shallow (0.7–1.5 GPa) melting conditions for these primitive compositions and provide estimates of the heat delivered to the crust. Over time, this flux led to maturation of the CLVF magmatic system toward the more voluminous and silicic volcanism that characterizes the balance of its subsequent volcanic history and maintains the present-day anomalously high heat flow in the region. The current interval (interval four) of volcanic activity at CLVF is characterized by low-volume, fault-controlled eruptions of basaltic andesite and andesite suggestive of mantle magma and heat delivery to the crust, similar to interval one. This analogous activity provides motivation for the current study and begs the question of whether the system is undergoing thermal priming for renewed silicic volcanism.

California↗
USGS2025

Wetlands, groundwater and seasonality influence the spatial distribution of stream chemistry in a low-relief catchment

Evaluating stream water chemistry patterns provides insight into catchment ecosystem and hydrologic processes. Spatially distributed patterns and controls of stream solutes are well-established for high-relief catchments where solute flow paths align with surface topography. However, the controls on solute patterns are poorly constrained for low-relief catchments where hydrogeologic heterogeneities and river corridor features, like wetlands, may influence water and solute transport. Here, we provide a data set of solute patterns from 58 synoptic surveys across 28 sites and over 32 months in a low-relief wetland-rich catchment to determine the major surface and subsurface controls along with wetland influence across the catchment. In this low-relief catchment, the expected wetland storage, processing, and transport of solutes is only apparent in solute patterns of the smallest subcatchments. Meanwhile, downstream seasonal and wetland influence on observed chemistry can be masked by large groundwater contributions to the main stream channel. These findings highlight the importance of incorporating variable groundwater contributions into catchment-scale studies for low-relief catchments, and that understanding the overall influence of wetlands on stream chemistry requires sampling across various spatial and temporal scales. Therefore, in low-relief wetland-rich catchments, given the mosaic of above and below ground controls on stream solutes, modeling efforts may need to include both surface and subsurface hydrological data and processes.

Michigan↗
USGS2017

Field-trip guide to Mount Hood, Oregon, highlighting eruptive history and hazards

This guidebook describes stops of interest for a geological field trip around Mount Hood volcano. It was developed for the 2017 International Association of Volcanology and Chemistry of the Earth’s Interior (IAVCEI) Scientific Assembly in Portland, Oregon. The intent of this guidebook and accompanying contributions is to provide an overview of Mount Hood, including its chief geologic processes, magmatic system, eruptive history, local tectonics, and hazards, by visiting a variety of readily accessible localities. We also describe coeval, largely monogenetic, volcanoes in the region. Accompanying the field-trip guidebook are separately authored contributions that discuss in detail the Mount Hood magmatic system and its products and behavior (Kent and Koleszar, this volume); Mount Hood earthquakes and their relation to regional tectonics and the volcanic system (Thelen and Moran, this volume); and young surface faults cutting the broader Mount Hood area whose extent has come to light after acquisition of regional light detection and ranging coverage (Madin and others, this volume). The trip makes an approximately 175-mile (280-kilometer) clockwise loop around Mount Hood, starting and ending in Portland. The route heads east on Interstate 84 through the Columbia River Gorge National Scenic Area. The guidebook points out only a few conspicuous features of note in the gorge, but many other guides to the gorge are available. The route continues south on the Mount Hood National Scenic Byway on Oregon Route 35 following Hood River, and returns to Portland on U.S. Highway 26 following Sandy River. The route traverses rocks as old as the early Miocene Eagle Creek Formation and overlying Columbia River Basalt Group of middle Miocene age, but chiefly lava flows and clastic products of arc volcanism of late Miocene to Holocene age.

Oregon↗
USGS2025

A review of post-wildfire adaptations of surface-water-quality models: Synthesis, gaps, and opportunities

As wildfires increasingly affect water-supply watersheds, the demand for models to predict water-quality responses is increasing. This work reviews and synthesizes existing post-wildfire applications of water-quality models in the context of geographic and ecohydrological distribution, hydrologic and water-quality response process representation, model parameterization, model and input data scales, model calibration data availability, as well as calibration and performance evaluation approaches. Emphasis is placed on models that simulate water-quality output, rather than sediment and erosional response as the primary focus. Here, identified gaps and opportunities to advance the post-wildfire application of water-quality models include: 1. applying models in under-represented geographic and ecohydrologic regions, 2. simulating multiple streamflow generation mechanisms, including groundwater, with an emphasis on shifting dominant flow pathways as the landscape recovers following wildfire, 3. adding studies that include the simulation of metals, 4. incorporating more biogeochemical and in-stream processes to model applications, 5. applying finer spatial and temporal resolution of precipitation data input as well as finer spatial resolution hydrologic response units, 6. implementing fully distributed grid or element models or finer resolution response units to capture burn severity heterogeneity, 7. collecting enhanced water-quality data for model calibration and validation, 8. conducting model-intercomparison studies, and 9. developing model parameter value guidance in post-wildfire applications. These identified gaps and opportunities may assist users in deciding on key processes and approaches to consider in modeling post-wildfire water-quality conditions.

Science of the Total Environment↗
USGS2025

Deformation mechanisms in quartz veins and shear zones elucidate the origin of gold mineralization at Pogo, Alaska

Pogo is a quartz vein hosted, ca. 8 Moz gold deposit. Although it has similarities to orogenic and magmatic-hydrothermal deposits, its origin remains enigmatic. Observations from surface exposures, underground workings, and drill core provide new constraints on quartz vein origins with implications for mineralization. Abundant, largely barren metamorphic segregation quartz veins are found throughout interior Alaska and share characteristics with mineralized quartz veins at Pogo. Pogo quartz veins show crystal plastic deformation fabrics consistent with greenschist to amphibolite facies metamorphism and a lack of internal shear. In contrast, gold in Pogo quartz veins occurs in brittle microfaults and fractures with sulphides such as arsenopyrite and pyrrhotite. Major and minor cataclastic shear zones also exist at Pogo. Cataclastic shear zones commonly cut the mineralized quartz veins and porphyroclasts are dominated by quartz with the same plastic deformation fabrics found in the major Pogo quartz veins. The porphyroclasts, and the carbonaceous clay-rich matrix they sit in, also contain gold indicating that the shear zones postdate quartz and earliest gold deposition. These observations suggest that competency contrasts between the quartz veins and their phyllosilicate-rich host rocks controlled transient permeability formed by late, preferential brittle deformation events localizing sulphide ± gold deposition.

Alaska↗
USGS2025

Ubiquity and causes of soil water preferential flow across 17 ecoregions

Preferential flow (PF) in soil causes the rapid transport of water, nutrients, and contaminants into the subsurface, influencing groundwater recharge and streamflow. Data scarcity has hindered the quantification of PF occurrence and the identification of its drivers across diverse ecoregions. We address this gap by analyzing high-frequency, multi-depth soil moisture data across 17 ecoregions in the USA, using ∼1,500 sensors at 40 sites. We discovered that PF is widespread, with sites experiencing PF in up to 60% of rainfall events ≥2 mm. Multiple approaches consistently show that PF is more likely to occur with increased peak rainfall intensity, finer textured material, low soil moisture variability, humid climate, and higher net primary productivity. This suggests that PF patterns could shift with projected climate changes, increasing uncertainty in predictions of groundwater recharge, water quality, and streamflow generation.

conterminous United States and Puerto Rico↗
USGS2026

Structural evolution and slip rate variations through time of the Puente-Hills blind-thrust fault beneath Los Angeles: Implications for seismic hazard and folding kinematics

Using seismic reflection profiles, historical well logging data, and luminescence and radiocarbon ages, we determine a Pleistocene-Holocene slip history for the central, Santa Fe Springs segment of the Puente Hills blind-thrust fault (PHT), a major seismogenic fault situated beneath the urbanized Los Angeles metropolitan region. We analyze the geometry of correlative stratigraphic units in the forelimb and backlimb of the overlying growth-fold, the Santa Fe Springs anticline, and determine the uplift of seven age-correlative markers. Uplift measurements are converted to thrust displacements on the underlying PHT using a structural method laid out by Don et al. (2022, https://doi.org/10.1785/0120220048 ) that accounts for the geometry of the fault. These data indicate that deep thrust displacement on the PHT is partially consumed updip in the creation of a hanging-wall fault-bend fold, with forelimb growth strata recording <80% of the slip documented within the backlimb. Chronological data from growth strata yield age constraints for folding and faulting on the underlying PHT, providing a detailed incremental slip history derived from both the forelimb and backlimb folding for seven discrete growth horizons, spanning the past 1.4 million years. The resulting six incremental slip rates demonstrate that fault slip has varied through time from the middle Pleistocene to the Holocene. Moreover, these results reveal synchronous acceleration of both the central, Santa Fe Springs and western, Los Angeles segments of the fault system since late Pleistocene time (after 200 ka) and slip rates of greater than 2 mm/yr on the downdip, backlimb, fault-ramp below the anticline.

California↗
USGS2025

Machine learning provides reconnaissance-type estimates of carbon dioxide storage resources in oil and gas reservoirs

Oil and gas reservoirs represent suitable containers to sequester carbon dioxide (CO 2 ) in a supercritical state because they are accessible, reservoir properties are known, and they previously contained stored buoyant fluids. However, planners must quantify the relative magnitude of the CO 2 storage resource in these reservoirs to formulate a comprehensive strategy for CO 2 mitigation. Even reconnaissance-type estimates of CO 2 storage resources of known oil and gas reservoirs may require complicated calculations involving 1) estimates of recoverable oil and gas, 2) reservoir properties (depth, temperature, pressure, etc.), and 3) the physical qualities of the retained fluids. We demonstrate the application of machine learning (ML) algorithms to bypass these computations to yield more rapid estimates of CO 2 storage resources in reservoirs capable of hosting CO 2 in a supercritical state. ML algorithms are computationally efficient because they do not impose the strong assumptions on the data-generating process that standard statistical or engineering procedures require. Further, ML algorithms can capture highly complex, particularly nonlinear, relationships among predictor variables. We demonstrate the application of four different ML algorithms using data from onshore and offshore oil and gas reservoirs in Europe, and show they perform well when predictions are compared to engineering estimates. The proposed methods and models provide an effective and novel way to more rapidly and directly determine the subsurface CO 2 storage capacity of oil and gas reservoirs around the world, information that operators, researchers, and policymakers alike require to meet energy transition and decarbonization goals.

Frontiers in Enviornmental Science↗
USGS2026

Water-withdrawal and groundwater-level fluctuations, physical and infiltration characteristics of Ohio River sediment, and isotope-based estimates of water sources relative to a riverbank filtration system in an alluvial aquifer, Louisville, Kentucky, 2000–20

The U.S. Geological Survey and the Louisville Water Company, from 2000 to 2020, cooperatively investigated physical and hydrologic conditions in the Ohio River alluvial aquifer and adjacent riverbed sediments in the northeast part of Louisville, Kentucky, to increase knowledge of processes affecting water sources to collector wells during operation of a riverbank filtration system (RBF). The RBF, in 2020, included an initial collector well (CW1) completed in 1999 and a tunnel and collector well system (TCWS) composed of four collector wells (CW2–CW5) completed in late 2010 that were connected by a tunnel that routed water to a pumping station and a treatment plant. Daily mean water-withdrawal rates typically ranged from about 10.4 to 20.7 million gallons per day (Mgal/d) from 2005 to 2007, then were cyclic from 2008 to 2010 and ranged from as low as about 9 to 13 Mgal/d in winter-spring months up to about 19 to 20 Mgal/d in summer-autumn months. From 2011 through 2017, peak daily mean water-withdrawal rates from CW2–CW5 fluctuated between winter-spring lows of about 20–30 Mgal/d to summer-autumn peak rates of about 41.6 Mgal/d in 2013 to about 48.2 Mgal/d in 2012. From 2017 to 2020, TCWS peak daily mean water-withdrawal rates decreased from about 45.7 Mgal/d in 2017 to about 37.5 Mgal/d in 2020 and peak daily mean rates from CW1 ranged from about 20.7 Mgal/d in 2020 to about 21.6 Mgal/d in 2018. Periods in 2019–20 with tunnel pumping station daily mean water-withdrawal rates smaller than about 30 Mgal/d had generally stable water levels in CW2 and indicated the sustainable yield of the TCWS collector wells under the prevailing hydrologic conditions. Drawdown during July–August of 2008 and 2009 was associated with CW1, the sole operating collector well. Groundwater-flow directions outside the CW1 cone of depression during July–August of 2008 and 2009 were from areas near the alluvial valley margin toward the Ohio River and in 2009 toward Harrods Creek. Collector wells CW2 through CW5 derived water during 2011–19 surveys from surface-water infiltration, as indicated by drawdown that extended beneath the Ohio River and Harrods Creek. Increases in drawdown toward the alluvial valley margins in July–August of 2013 and 2015, compared with July 2011, indicated less available recharge from those flow directions and decreased yield of groundwater from the aquifer after progressively longer TCWS water withdrawals. Drawdown at CW2–CW5 and at observation wells between them lessened in October 2019 and indicated that onshore groundwater levels can recover when collector well withdrawals decrease. Overlapping cones of depression in 2011–15 potentiometric surfaces centered around CW2, CW3, CW4, and CW5, and drawdown along divides between those wells indicated well interference between collector wells. Well-interference effects increased during 2013 and 2015 survey periods, despite decreased water-withdrawal rates compared with July 2011, and expanded to include CW1 when its use resumed. Groundwater-level fluctuations in observation wells near the Ohio River were consistent with gradual depletion of groundwater yield during tunnel pumping station operation at river elevations of about 420 feet above the National Geodetic Vertical Datum of 1929 (NGVD 29) and enhanced recharge of the aquifer when river elevations were above flood stage of about 430 feet above NGVD 29. Groundwater-level declines in observation wells near the Ohio River were most apparent in summer and some autumn months between 2012 and 2017 during periods when tunnel pumping station mean daily water-withdrawal rates were about 35 Mgal/d or more. Periods of relatively stable groundwater levels during 2019–20 in observation wells between CW2–CW5, when tunnel pumping station water-withdrawal rates were about 30–33 Mgal/d or less, also indicated that the prevailing sustainable yield was about 30 Mgal/d or less. Wells associated with CW3 and CW4 had the largest increases in slopes of best-fit lines relating water-level difference to water-withdrawal rate between 2012 and 2020, an indication of decreased efficiencies of those wells to supply water or of changes in groundwater yield around the well. Increased slopes of best-fit lines relating water-level difference to water-withdrawal rate from 2019 to 2020, when groundwater levels were otherwise relatively stable, also indicated that the specific capacity of one or more TCWS collector wells may have declined during that period. Riverbed surface elevation, roughness, and hardness changes between hydroacoustic surveys indicated active accretion and erosion of bed sediment offshore from the riverbank filtration system in 2002–4. Riverbed hydraulic conductivity computed from 2013 to 2015 in tests at 11 sites ranged from 0.2 to 230 feet per day. Ten temporary piezometer sites with adjacent operating collector wells had drawdowns that ranged from about 4 to 11.7 feet and hammer blows greater than or equal to 49 counts, which indicated a relatively great density of alluvial sediments and the potential for diminished riverbed infiltration rates. Contributions of Ohio River infiltration to collector wells estimated from deuterium and oxygen-18 isotopic ratios in representative Ohio River and groundwater samples were considerably larger in warmer months than cooler months and ranged from 80–90 percent in CW1–CW5 in May 2020 to 100 percent in May 2019 at CW2, CW4, and CW5. Groundwater contributions to water withdrawals by collector wells increased in cooler autumn months and ranged from 40 percent at CW3 and CW5 in November 2020 to 70 percent at CW2, CW4, and CW5 in November–December 2019. November 2019 and November 2020 isotopic compositions of water from the collector wells had enriched deuterium and oxygen-18 isotopic ratios consistent with mixtures of evaporation-modified water from the Ohio River and meteoric-origin groundwater.

Indiana, Kentucky↗
USGS2018

Divisions of geologic time—Major chronostratigraphic and geochronologic units

Introduction Effective communication in the geosciences requires a consistent nomenclature for stratigraphic units and, especially, for divisions of geologic time. A geologic time scale is composed of standard stratigraphic divisions based on rock sequences and is calibrated in years. Geologists from the U.S. Geological Survey (USGS), State geological surveys, academia, and other organizations require a consistent time scale to be used in communicating ages of geo­logic units in the United States. Many international debates have occurred over names and boundaries of units, and various time scales have been used by the geoscience community. For consistent usage of time terms, the USGS Geologic Names Committee and the Association of American State Geologists devel­oped the Divisions of Geologic Time ; the 2018 update in this fact sheet contains the unit names and boundary age estimates ratified by the International Commission on Stratigraphy in 2018. Scientists may use other published time scales, provided that these are specified and referenced.

Fact Sheet↗
USGS2024

Compositional and structural mapping of Northwest Africa 15507 angrite

Angrite meteorites represent interesting sampling of planetary crustal environments. Quench-textured angrites with strong crystal zoning originated from the shallow surface region, with evidence of reducing conditions during solidification. Plutonic angrites have more coarse-grained igneous and metamorphic textures with comparatively less zoning and are interpreted as having equilibrated at greater depth. Plutonic angrites contain the minerals magnetite Fe 3 O 4 comprised of Fe 2+ and Fe 3+ , and rhönite, where Fe 3+ is required by inspection of mineral stoichiometry. NWA 15507 is a plutonic angrite with a microgabbroic texture (mean grainsize ∼1.4 mm) composed of zoned Al-Ti-augite, Ca-bearing olivine, anorthite, with accessory kirschsteinite, rhönite, hercynite, low-Ni kamacite, merrillite, Ti-free magnetite and troilite [ 1 ]. Rhönite analyzed by electron-probe microanalysis (EPMA) has the formula Ca 2.04 (Mg 0.32 Fe 2+ 4.25 Fe 3+ 0.47 Ti 0.33 Al 0.61 )(Si 3.74 Al 2.26 )O 20 , where Fe 3+ was estimated by stoichiometric analysis. During preliminary cathodoluminescence (CL) analysis, complex subgrain and oscillatory zoning was observed in the anorthite. In this study we use a combined approach of electron probe microanalysis (EPMA), cathodoluminescence (CL), electron-backscatter diffraction (EBSD), and laser ablation inductively-coupled plasma mass spectrometry (LA-ICP-MS) to further investigate the anorthite and distribution of Fe 3+ in NWA 15507.

Microscopy and Microanalysis↗