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Hydrogeologic framework and salinity distribution of the Floridan aquifer system of Broward County, Florida

Concerns about water-level decline and seawater intrusion in the surficial Biscayne aquifer, currently the principal source of water supply to Broward County, prompted a study to refine the hydrogeologic framework of the underlying Floridan aquifer system to evaluate its potential as an alternative source of supply. This report presents cross sections that illustrate the stratigraphy and hydrogeology in eastern Broward County; maps of the upper surfaces and thicknesses of several geologic formations or units within the Floridan aquifer system; and maps of two of the potentially productive water-bearing zones within the system, the Upper Floridan aquifer and the Avon Park permeable zone. An analysis of data on rock depositional textures, associated pore networks, and flow zones in the Floridan aquifer system shows that groundwater moves through the system in two ways. These data support a conceptual, dual-porosity model of the system wherein groundwater moves either as concentrated flow in discrete, thin bedding-plane vugs or zones of vuggy megaporosity, or as diffuse flow through rocks with primarily interparticle and moldic-particle porosity. Because considerable exchange of groundwater may occur between the zones of vuggy and matrix-dominated porosity, understanding the distribution of that porosity and flow zone types is important to evaluating the suitability of the several units within the Floridan aquifer system for managing the water through practices such as aquifer storage and recovery (ASR). The salinity of the water in the Floridan aquifer system is highest in the central part of the study area, and lower toward the north and south. Although salinity generally increases with depth, in the western part of the study area a zone of relatively high saline water is perched above water of lower salinity in the underlying Avon Park permeable zone. Overall, the areas of highest salinity in the aquifer system coincide with those with the lowest estimated transmissivity, so that the occurrence of perched saline water in the system may be the consequence of incompletely flushed connate water or intruded seawater. A seismic reflection profile along the Hillsboro Canal, at the northern edge of the study area, shows seven seismic-sag structures that are interpreted as downward deformation of overlying strata into collapsed deep cave systems. These structures may compromise the integrity of the confinement created by the underlying strata by allowing upconing of saline water from depth, which has implications for successful application of ASR and use of the Floridan aquifer system as an alternative water supply.

Florida↗

Status of groundwater levels and storage volume in the Equus Beds aquifer near Wichita, Kansas, 2012 to 2014

Development of the Wichita well field in the Equus Beds aquifer in southwest Harvey County and northwest Sedgwick County began in the 1940s to supply water to the city of Wichita. The decline of water levels in the Equus Beds aquifer was noted soon after the development of the Wichita well field began. Development of irrigation wells began in the 1960s. City and agricultural withdrawals led to substantial water-level declines. Water-level declines likely enhanced movement of brines from past oil and gas activities near Burrton, Kansas, as well as natural saline water from the Arkansas River into the Wichita well field area. Large chloride concentrations may limit use, or require the treatment of water from the well field for irrigation or public supply. In 1993, the city of Wichita adopted the Integrated Local Water Supply Program to ensure an adequate water supply for the city through 2050 and manage effectively the part of the Equus Beds aquifer Wichita uses. The Integrated Local Water Supply Program uses several strategies to do this, including the Equus Beds Aquifer Storage and Recovery project. The purpose of the Aquifer Storage and Recovery project is to store water in the aquifer for later recovery, and help protect the aquifer from encroachment of a known oil-field-brine plume near Burrton and saline water from the Arkansas River. Since 1940, the U.S. Geological Survey, in cooperation with the city of Wichita, has monitored changes in the Equus Beds aquifer as part of Wichita’s effort to manage this resource effectively. Average water-level changes since predevelopment (before substantial pumpage began in the area) for winter 2012, summer 2012, winter 2013, and winter 2014 generally indicate greater declines in the central part of the study area than in either the basin storage or entire study area. In contrast, average water-level rises since 1993 for winter 2012, summer 2012, winter 2013, and winter 2014 were greater for the central part of the study area than for either the basin storage area or entire study area. This indicates the central part of the study area had more post-1993 water-level recovery than did the rest of the study area. In the central part of the study area, city water use decreased by about 40 percent, and irrigation water use increased by about 3 percent compared to pre-1993 peaks in 1992 and 1991, respectively, whereas irrigation water use outside the central part of the study area increased by about 24 percent from the pre-1993 peak in 1991. Part of the larger increase in irrigation pumpage probably was a result of drought-term and multiyear flex account permits, which were estimated to account for about 8 and 4 percent of irrigation pumpage in the study area in 2011 and 2012. There was a larger percentage storage-volume increase since 1993 in the central part of the study area than in either the basin storage area or the entire study area. Storage-volume in the central part of the study area during winter 2012, summer 2013, winter 2013, and winter 2014 recovered about 46,300 acre-feet or more compared to the storage volume in 1993. In summer 2012 and winter 2013, the storage-volume increase since 1993 was larger in the central part of the study area than in the entire study area, indicating the storage-volume increases in the central part of the study area offset decreases in storage volume in the rest of the study area. The larger increase in storage volume in the central part of the study area than in the rest of the study area probably was because of the Integrated Local Water Supply Program strategy that reduced city pumpage from the Equus Beds aquifer by about 40 percent. The current (winter 2014) storage volumes in the entire study area and the central part of the study area are about 94 and 96 percent of their respective predevelopment storage volumes or about 3,067,000 and 962,000 acre-feet, respectively.

Kansas↗

Aquifer tests at the Jackpile-Paguate uranium mine, Pueblo of Laguna, west-central New Mexico

The transmissivity of the Jackpile sandstone bed in the Brushy Basin Shale Member of the Morrison Formation, west-central New Mexico, was determined to be 24 sq ft/day at well M2 and 47 sq ft/day at well M3 from constant-discharge aquifer tests conducted at the Jackpile-Paguate Uranium Mine. The storage coefficient of the Jackpile sandstone bed was estimated to be 0.00018 at well M2 and 0.00029 at well M3 from the same tests. An aquifer test conducted at well M21 indicated the transmissivity of the Jackpile sandstone bed was 2.0 sq ft/day and the storage coefficient was 0.00002. The transmissivity of an unnamed sandstone bed in the Brushy Basin Shale Member of the Morrison Formation was estimated from ' slug-test ' results to be about 20 sq ft/day. Water levels in this sandstone probably did not change due to pumping from the overlying Jackpile sandstone bed for 88 hours at an average discharge of 15.3 gallons/min. A constant discharge aquifer test at well M4C indicated that the transmissivity of the alluvium at this location was about 430 sq ft/day. Water levels in the underlying Jackpile sandstone bed began declining within 15 minutes after withdrawals of groundwater from the alluvial aquifer began. (USGS)

New Mexico↗

Incorporating uncertainty into high-resolution groundwater supply models

Groundwater modeling is a useful tool for evaluating whether an acquifer system is capable of supporting groundwater withdrawals over long periods of time and what effect, if any, such activity will have on the regional flow dynamics as well as on specific public water, agricultural and industrial supplies. An overview is given of an ongoing groundwater modeling study of the Chicot Aquifer in southwestern Louisiana where a low-resolution groundwater model is being used to study the regional flow in the Chicot acquifer and to provide boundary conditions for higher-resolution inset models created using telescopic mesh refinement (TMR).

Conference Paper↗

Estimated 2008 groundwater potentiometric surface and predevelopment to 2008 water-level change in the Santa Fe Group aquifer system in the Albuquerque area, central New Mexico

The water-supply requirements of the Albuquerque metropolitan area of central New Mexico have historically been met almost exclusively by groundwater withdrawal from the Santa Fe Group aquifer system. Previous studies have indicated that the large quantity of groundwater withdrawal relative to recharge has resulted in water-level declines in the aquifer system throughout the metropolitan area. Analysis of the magnitude and pattern of water-level change can help improve understanding of how the groundwater system responds to withdrawals and variations in the management of the water supply and can support water-management agencies' efforts to minimize future water-level declines and improve sustainability. This report, prepared by the U.S. Geological Survey in cooperation with the Albuquerque Bernalillo County Water Utility Authority, presents the estimated groundwater potentiometric surface during winter (from December to March) of the 2008 water year and the estimated changes in water levels between predevelopment and water year 2008 for the production zone of the Santa Fe Group aquifer system in the Albuquerque and surrounding metropolitan and military areas. Hydrographs from selected wells are included to provide details of historical water-level changes. In general, water-level measurements used for this report were measured in small-diameter observation wells screened over short intervals and were considered to best represent the potentiometric head in the production zone-the interval of the aquifer, about 300 feet below land surface to 1,100 feet or more below land surface, in which production wells generally are screened. Water-level measurements were collected by various local and Federal agencies. The 2008 water year potentiometric surface map was created in a geographic information system, and the change in water-level elevation from predevelopment to water year 2008 was calculated. The 2008 water-level contours indicate that the general direction of groundwater flow is from the Rio Grande towards clusters of production wells in the east, north, and west. Water-level changes from predevelopment to 2008 are variable across the area. Hydrographs from piezometers on the east side of the river generally indicate a trend of decline in the annual highest water level through most of the period of record. Hydrographs from piezometers in the valley near the river and on the west side of the river indicate spatial variability in water-level trends.

New Mexico↗

Bedrock aquifers and population growth in the Denver Basin, Colorado, USA

The Denver Basin bedrock aquifer system consists of Tertiary and Cretaceous age sedimentary rocks known as the Dawson, Denver, Arapahoe and Laramie-Fox Hills aquifers. The number of bedrock wells has increased from 12,000 in 1985 to over 33,700 in 2001 and the withdrawal of groundwater has caused water level declines in excess of 75 meters. Water level declines now range from 3 to 12 meters per year in the critical Arapahoe Aquifer. The groundwater supplies were once thought to be sufficient for 100 years but there is concern that they may be depleted in 10 to 15 years in areas on the west side of the basin. Groundwater is being mined from the aquifer system because the withdrawal through wells exceeds the rate of recharge. Increased groundwater withdrawal will cause further water level declines, increased costs to pump groundwater, and reduced yield from existing wells. In the Denver Basin, hydrologists have some capability to monitor declines in water levels for the Arapaho Aquifer, but generally have a limited ability to monitor water use. More complete and accurate water use data are needed to predict groundwater longevity for the Arapahoe Aquifer. The life of the Arapahoe Aquifer can be extended with artificial recharge using imported surface water, water reuse, restrictions on lawn watering, well permit restrictions and other conservation measures. Availability of groundwater may limit growth in the Denver Basin over the next 20 years unless residents are willing to pay for additional new sources of supply.

Episodes↗

Groundwater-flow and land-subsidence model of Antelope Valley, California

Antelope Valley, California, is a topographically closed basin in the western part of the Mojave Desert, about 50 miles northeast of Los Angeles. The Antelope Valley groundwater basin is about 940 square miles and is separated from the northern part of Antelope Valley by faults and low-lying hills. Prior to 1972, groundwater provided more than 90 percent of the total water supply in the valley; since 1972, it has provided between 50 and 90 percent. Most groundwater pumping in the valley occurs in the Antelope Valley groundwater basin, which includes the rapidly growing cities of Lancaster and Palmdale. Groundwater-level declines of more than 270 feet in some parts of the groundwater basin have resulted in an increase in pumping lifts, reduced well efficiency, and land subsidence of more than 6 feet in some areas. Future urban growth and limits on the supply of imported water may increase reliance on groundwater. In 2011, the Los Angeles County Superior Court of California ruled that the Antelope Valley groundwater basin is in overdraft—groundwater extractions are in excess of the Court-defined safe yield of the groundwater basin. The Court determined that the safe yield of the adjudicated area of the basin was 110,000 acre-feet per year (acre-ft/yr). Natural recharge is an important component of total groundwater recharge in Antelope Valley; however, the exact quantity and distribution of natural recharge, primarily in the form of mountain-front recharge, is uncertain, with total estimates ranging from 30,000 to 160,000 acre-ft/yr. Technical experts, retained by parties to the adjudication, used 60,000 acre-ft/yr to estimate the sustainable yield of the basin, and this value was used in this study. In order to better understand the uncertainty associated with natural recharge and to provide a tool to aid in groundwater management, a numerical model of groundwater flow and land subsidence in the Antelope Valley groundwater basin was developed using old and new geohydrologic information. The groundwater-flow system consists of three aquifers: the upper, middle, and lower aquifers. The three aquifers, which were identified on the basis of the hydrologic properties, age, and depth of the unconsolidated deposits, consist of gravel, sand, silt, and clay alluvial deposits and clay and silty clay lacustrine deposits. Prior to groundwater development in the valley, recharge was primarily the infiltration of runoff from the surrounding mountains. Groundwater flowed from the recharge areas to discharge areas around the playas where it discharged from the aquifer system as either evapotranspiration or from springs. Partial barriers to horizontal groundwater flow, such as faults, have been identified in the groundwater basin. Water-level declines owing to groundwater development have eliminated the natural sources of discharge, and pumping for agricultural and urban uses have become the primary source of discharge from the groundwater system. Infiltration of return flow from agricultural irrigation has become an important source of recharge to the aquifer system. The groundwater-flow model of the basin was discretized horizontally into a grid of 130 rows and 118 columns of square cells 1 kilometer (0.621 mile) on a side, and vertically into four layers representing the upper (two layers), middle (one layer), and lower (one layer) aquifers. Faults that were thought to act as horizontal-flow barriers were simulated in the model. The model was calibrated to simulate steady-state conditions, represented by 1915 water levels and transient-state conditions during 1915–95, by using water-level and subsidence data. Initial estimates of the aquifer-system properties and stresses were obtained from a previously published numerical model of the Antelope Valley groundwater basin; estimates also were obtained from recently collected hydrologic data and from results of simulations of groundwater-flow and land-subsidence models of the Edwards Air Force Base area. Some of these initial estimates were modified during model calibration. Groundwater pumpage for agriculture was estimated on the basis of irrigated crop acreage and crop consumptive-use data. Pumpage for public supply, which is metered, was compiled and entered into a database used for this study. Estimated annual agricultural pumpage peaked at 395,000 acre-feet (acre-ft) in 1951 and then declined because of declining agricultural production. Recharge from irrigation return flows was assumed to be 30 percent of agricultural pumpage; delays associated with return flow moving through the unsaturated zone were also simulated. The annual quantity of mountain-front recharge initially was based on estimates from previous studies. The model was calibrated using the PEST software suite; prior information from the area was incorporated through the use of Tikhonov regularization. During model calibration, the estimated mountain-front recharge was reduced from the previous estimate of 30,300 acre-ft/yr to 29,150 acre-ft/yr. Results of the simulations using the calibrated model indicate that simulated groundwater pumpage exceeded recharge in most years, resulting in an estimated cumulative depletion in groundwater storage of 8,700,000 acre-ft during the transient-simulation period (1915–2005). About 15,000,000 acre-ft of cumulative groundwater pumpage was simulated during the transient-simulation period (1915–2005), reaching a maximum rate of about 400,000 acre-ft/yr in 1951. Groundwater pumpage resulted in simulated hydraulic heads declining by more than 150 feet (ft) compared to 1915 conditions in agricultural areas. The decline in hydraulic head in the groundwater basin is the result of this depletion of groundwater storage. In turn, the simulated decline in hydraulic head in the groundwater basin has resulted in the decrease in natural discharge from the basin and has caused compaction of aquitards, resulting in land subsidence. The areal distribution of total simulated land subsidence for 2005, after about 90 years of groundwater development, indicates that land subsidence occurred throughout almost the entire Lancaster subbasin, with a maximum of about 9.4 ft in the central and eastern parts of the subbasin. An important objective of this study was to systematically address the uncertainty in estimates of natural recharge and related aquifer parameters by using the groundwater-flow and land-subsidence model with observational data and expert knowledge. After the model was calibrated to the observations and a reasonable parameter set obtained, the parameter null space—parameter values that do not appreciably affect the model calibration but may have importance for prediction—was identified. The effect of parameter uncertainty on the estimation of mountain-front recharge was addressed using the Null-Space Monte Carlo method. The Pareto trade-off method of visualizing uncertainty was also used to portray the reasonableness of larger natural-recharge rates. Results indicate that the total mountain-front recharge likely ranges between 28,000 and 44,000 acre-ft/yr, which is appreciably less than published estimates of 60,000 acre-ft/yr. Additionally, expected errors associated with agricultural pumpage estimates used in this study were found to have relatively little effect on the estimates of mountain-front recharge, reflecting the difficulty in increasing recharge through manipulation of other components of the water budget. The calibrated model was used to simulate the response of the aquifer to potential future pumping scenarios: (1) no change in the distribution of pumpage, or status quo; (2) redistribution of pumpage; and (3) artificial recharge. All three of these scenarios specify a total pumpage throughout the Antelope Valley of 110,000 acre-ft/yr according to the safe yield value ruled by the Los Angeles County Superior Court of California. This reduction in groundwater pumpage is assumed uniform throughout the basin, based on a 10-percent reduction of the total pumpage in 2005 to achieve the 110,000 acre-ft/yr level. The calibrated Antelope Valley groundwater-flow and land-subsidence model was used to simulate the hydrologic effects of the three groundwater-management scenarios during a 50-year period by using the reduced, temporally constant, pumpage distribution. Results from the first scenario indicated that the total drawdown observed since predevelopment would continue, with values exceeding 325 ft near Palmdale; consequently, land subsidence would also continue, with additional subsidence (since 2005) exceeding 3 ft in the central part of the Lancaster subbasin. The second scenario evaluated redistributing pumpage from areas in the Lancaster subbasin where simulated hydraulic-head declines were the greatest to areas where declines were smallest. Neither a formal optimization algorithm nor water-rights allocations were considered when redistributing the pumpage. Results indicated that hydraulic heads near Palmdale, where the pumpage was reduced, would recover by about 200 ft compared to 2005 conditions, with only 30 ft of additional drawdown in the northwestern part of the Lancaster subbasin, where the pumpage was increased. The magnitude of the simulated additional land subsidence decreased slightly compared to the first, status quo, scenario but land subsidence continued to be simulated throughout most of the northern part of the Lancaster subbasin. The third scenario consisted of two artificial-recharge simulations along the Upper Amargosa Creek channel and at a site located north of Antelope Buttes. Results indicate that applying artificial recharge at these sites would yield continued drawdowns and associated land subsidence. However, the magnitudes of drawdown and subsidence would be smaller than those simulated in the status quo scenario, indicating that artificial-recharge operations in the Antelope Valley could be expected to reduce the magnitude and extent of continued water-level declines and associated land subsidence.

California↗

Rates of microbial metabolism in deep coastal plain aquifers

Rates of microbial metabolism in deep anaerobic aquifers of the Atlantic coastal plain of South Carolina were investigated by both microbiological and geochemical techniques. Rates of [2- 14 C]acetate and [U- 14 C]glucose oxidation as well as geochemical evidence indicated that metabolic rates were faster in the sandy sediments composing the aquifers than in the clayey sediments of the confining layers. In the sandy aquifer sediments, estimates of the rates of CO 2 production (millimoles of CO 2 per liter per year) based on the oxidation of [2- 14 C] acetate were 9.4 × 10 −3 to 2.4 × 10 −1 for the Black Creek aquifer, 1.1 × 10 −2 for the Middendorf aquifer, and <7 × 10 −5 for the Cape Fear aquifer. These estimates were at least 2 orders of magnitude lower than previously published estimates that were based on the accumulation of CO 2 in laboratory incubations of similar deep subsurface sediments. In contrast, geochemical modeling of groundwater chemistry changes along aquifer flowpaths gave rate estimates that ranged from 10 −4 to 10 −6 mmol of CO 2 per liter per year. The age of these sediments (ca. 80 million years) and their organic carbon content suggest that average rates of CO 2 production could have been no more than 10 −4 mmol per liter per year. Thus, laboratory incubations may greatly overestimate the in situ rates of microbial metabolism in deep subsurface environments. This has important implications for the use of laboratory incubations in attempts to estimate biorestoration capacities of deep aquifers. The rate estimates from geochemical modeling indicate that deep aquifers are among the most oligotrophic aquatic environments in which there is ongoing microbial metabolism.

South Carolina↗

Simulation of groundwater flow at the former Badger Army Ammunition Plant, Sauk County, Wisconsin

To help support remedial efforts at the former Badger Army Ammunition Plant the U.S. Geological Survey built and calibrated a transient groundwater flow model using the Newton Raphson formulation (MODFLOW–NWT) of the U.S. Geological Survey’s modular three-dimensional finite-difference code. The model simulates the groundwater flow system at the site from 1984 to 2020. The former Badger Army Ammunition Plant is a 7,275-acre site in Sauk County, Wisconsin. The plant produced smokeless gunpower and solid rocket propellent as munitions components. Peak production periods were during World War II, the Korean War, and the Vietnam War. Subsequent groundwater contamination investigations have found four plumes at the site. A health risk assessment identified at least one contaminant of concern for human health risk present in three of the plumes: the propellant burning ground plume, the deterrent burning ground plume, and the central plume. A cooperative study began between the U.S. Army Environmental Command and U.S. Geological Survey to better understand the groundwater flow system at the former Badger Army Ammunition Plant. Field data, including aquifer tests, streamflow measurements, continuous groundwater elevations, and groundwater gradients with the Wisconsin River were collected and used to inform and calibrate the groundwater flow model. The model was used to assess the variability of the groundwater system over the study period, the components of the groundwater budget, and groundwater flow directions from identified source areas towards the Wisconsin River. Model performance assessment focused on using particle tracking to compare groundwater flowpaths that originate in the contaminant source areas to the observed plume footprints. This focus on plume behavior geometry should help constrain the advective component of a future groundwater transport model of the site.

Wisconsin↗

Evaluation of bias associated with capture maps derived from nonlinear groundwater flow models

The impact of groundwater withdrawal on surface water is a concern of water users and water managers, particularly in the arid western United States. Capture maps are useful tools to spatially assess the impact of groundwater pumping on water sources (e.g., streamflow depletion) and are being used more frequently for conjunctive management of surface water and groundwater. Capture maps have been derived using linear groundwater flow models and rely on the principle of superposition to demonstrate the effects of pumping in various locations on resources of interest. However, nonlinear models are often necessary to simulate head-dependent boundary conditions and unconfined aquifers. Capture maps developed using nonlinear models with the principle of superposition may over- or underestimate capture magnitude and spatial extent. This paper presents new methods for generating capture difference maps, which assess spatial effects of model nonlinearity on capture fraction sensitivity to pumping rate, and for calculating the bias associated with capture maps. The sensitivity of capture map bias to selected parameters related to model design and conceptualization for the arid western United States is explored. This study finds that the simulation of stream continuity, pumping rates, stream incision, well proximity to capture sources, aquifer hydraulic conductivity, and groundwater evapotranspiration extinction depth substantially affect capture map bias. Capture difference maps demonstrate that regions with large capture fraction differences are indicative of greater potential capture map bias. Understanding both spatial and temporal bias in capture maps derived from nonlinear groundwater flow models improves their utility and defensibility as conjunctive-use management tools.

Groundwater↗

Geochemical assessment of the Hueco Bolson, New Mexico and Texas, 2016–17

Understanding groundwater quality in transboundary aquifers like the Hueco Bolson is important for the 2.7 million people along the United States and Mexico border living in and near the combined metropolitan areas of Ciudad Juárez, Mexico, and El Paso, Texas, who rely on groundwater for water supply. To better understand water-quality conditions in the Mexico–New Mexico–Texas transboundary area, 23 water-supply wells were sampled in the Hueco Bolson within the United States near El Paso, Tex., during August–September 2016 and May–June 2017. Groundwater samples were analyzed for physical properties, major ions, dissolved solids, nutrients, trace elements, organic compounds, and selected isotopes such as strontium, hydrogen, oxygen, tritium, and carbon-14. Most of the water samples from the Hueco Bolson water-supply wells were classified as a sodium-chloride type water. Only four wells sampled in the study area had dissolved-solids concentrations greater than 1,000 milligrams per liter (mg/L), with three of those wells closest to the Rio Grande/Río Bravo del Norte (hereinafter referred to as the Rio Grande). Nitrate concentrations in the groundwater samples collected in the study area ranged from below the long-term method detection level of 0.04 to 6.2 mg/L. Arsenic was the only trace element detected in the wells sampled that had concentrations exceeding the designated drinking-water standard of 10 micrograms per liter (μg/L). Four of the 23 wells had arsenic concentrations greater than 10 μg/L, and these wells were all located near the Rio Grande. Three of the wells with the highest uranium concentrations (greater than 10 μg/L) were also located near the Rio Grande, and two of those wells were the same wells that had arsenic concentrations greater than 10 μg/L. Groundwater samples were analyzed for 83 organic compounds, but only 6 were detected—simazine, prometryn, prometon, atrazine, deethylatrazine, and dichloroaniline. All concentrations for the organic compounds detected were less than 0.03 μg/L, and the detections were only in five groundwater wells, three of which were located near the Rio Grande. Strontium, hydrogen, and oxygen isotopic values indicate that recharge water to the central and northern sections of the study area originates from near the Franklin Mountains, whereas groundwater in the southern section of the study area is likely from the Rio Grande valley. Tritium and carbon-14 values indicate that most of the wells that were sampled contained water that is considered premodern, which means that it is more than several hundred years old. Three wells with modern groundwater (approximately less than 70 years old) are located near the Rio Grande and are the same wells that had elevated arsenic or uranium concentrations and organic compound detections. Most of the results of the geochemical analyses indicate that groundwater near the Rio Grande has higher dissolved-solids concentrations, higher concentrations of several trace elements, and slightly more organic compound detections than the groundwater farther away from the Rio Grande; therefore, the groundwater may be affected by the Rio Grande and surrounding land-use activities.

New Mexico, Texas↗

Climate variability controls on unsaturated water and chemical movement, High Plains aquifer, USA

Responses in the vadose zone and groundwater to interannual, interdecadal, and multidecadal climate variability have important implications for groundwater resource sustainability, yet they are poorly documented and not well understood in most aquifers of the USA. This investigation systematically examines the role of interannual to multidecadal climate variability on groundwater levels, deep infiltration (3–23 m) events, and downward displacement (>1 m) of chloride and nitrate reservoirs in thick (15–50 m) vadose zones across the regionally extensive High Plains aquifer. Such vadose zone responses are unexpected across much of the aquifer given a priori that unsaturated total-potential profiles indicate upward water movement from the water table toward the root zone, mean annual potential evapotranspiration exceeds mean annual precipitation, and millennia-scale evapoconcentration results in substantial vadose zone chloride and nitrate reservoirs. Using singular spectrum analysis (SSA) to reconstruct precipitation and groundwater level time-series components, variability was identified in all time series as partially coincident with known climate cycles, such as the Pacific Decadal Oscillation (PDO) (10–25 yr) and the El Niño/Southern Oscillation (ENSO) (2–6 yr). Using these lag-correlated hydrologic time series, a new method is demonstrated to estimate climate-varying unsaturated water flux. The results suggest the importance of interannual to interdecadal climate variability on water-flux estimation in thick vadose zones and provide better understanding of the climate-induced transients responsible for the observed deep infiltration and chemical-mobilization events. Based on these results, we discuss implications for climate-related sustainability of the High Plains aquifer.

Vadose Zone Journal↗

Preliminary machine learning models of manganese and 1,4-dioxane in groundwater on Long Island, New York

Manganese and 1,4-dioxane in groundwater underlying Long Island, New York, were modeled with machine learning methods to demonstrate the use of these methods for mapping contaminants in groundwater in the Long Island aquifer system. XGBoost, a gradient boosted, ensemble tree method, was applied to data from 910 wells for manganese and 553 wells for 1,4-dioxane. Explanatory variables included soil properties, groundwater flow, land use, and other features that describe the hydrogeology and geochemistry of the aquifer system. Four models were developed to predict the probability of manganese concentrations greater than a detection level of 10 micrograms per liter (μg/L) and greater than three threshold concentrations (50, 150, and 300 μg/L) relevant to drinking-water quality. One model was developed to predict the probability of 1,4-dioxane concentrations greater than a detection level of 0.07 μg/L. The 1,4-dioxane model was limited geographically to Suffolk County because of data availability. Predictions were made for two layers in the upper glacial aquifer and three layers in the Magothy aquifer, which are the upper two of the three major aquifers of the Long Island aquifer system. The objective of the study described in this report was to demonstrate the application of the methods rather than to develop precise estimates of manganese or 1,4-dioxane concentrations at any given location. The predictive models developed in the study are considered preliminary in the sense that they are an initial effort at developing these kinds of models specifically for Long Island. The models could be improved by the inclusion of additional data, by the use of methods to improve the modeling of infrequent high concentrations of manganese and 1,4-dioxane (above threshold concentrations), and by including more explanatory variables that specifically describe conditions and contaminant sources on Long Island. Nonetheless, the distribution of model predictions and the influence of explanatory variables in the models were consistent with the expected relations between contaminant concentrations and groundwater-flow-system characteristics and the distribution of manmade sources. Mapped predictions indicated that manganese detections were more probable in the upper glacial aquifer and along the southern shore of Long Island, consistent with the distribution of anoxic conditions in groundwater in the Long Island aquifer system. Manganese was infrequently predicted at concentrations greater than thresholds of concern for drinking-water quality in any of the aquifer layers. Detections of 1,4-dioxane were predicted in the western, more highly developed parts of Suffolk County, in the upper glacial aquifer and the top and middle layers of the Magothy aquifer, and in northwestern Suffolk County in the bottom layer of the Magothy aquifer. Although preliminary in nature and based on limited data, these mapped predictions can be used to generally identify areas where manganese and 1,4-dioxane may be present at concentrations of concern to prioritize areas for future monitoring and to guide future modeling and mapping efforts.

New York↗

Regional study of the Castle Hayne Aquifer of eastern North Carolina

The Castle Hayne aquifer is an eastward sloping and thickening wedge of limestone and sandstone, located in a 12,500 sq mi area in the eastern part of North Carolina. The Castle Hayne aquifer is the major source of freshwater for much of coastal North Carolina where the aquifers underlying the Castle Hayne contain saltwater. A regional study of the Castle Hayne aquifer was conducted to provide definitive information on the declines in water levels and of saltwater intrusion in the area. A series of geohydrologic maps produced from the study, show the altitude of the top of the aquifer, location of saltwater in the aquifer, aquifer thickness, aquifer transmissivity, and confining-unit thickness. The history of groundwater pumpage can be compared with historical water levels in the aquifer. These geohydrologic, pumpage, and water level data can be used to develop estimates of aquifer and confining-unit hydraulic coefficients and to develop a groundwater flow model for the Castle Hayne aquifer. The model will increase the understanding of the groundwater flow system and also can be used to assess various groundwater development scenarios for the entire Castle Hayne aquifer.

North Carolina↗

Estimation of the recharge area of a pumped, stratified-drift aquifer in Connecticut by simulation modeling

Groundwater quality management plans in Connecticut require information about the size and shape of recharge areas that contribute flow to pumping centers in extensive, stratified-drift aquifers. Flow models of a hypothetical aquifer , and a stratified-drift aquifer in Farmington are used to evaluate how contributing areas change in response to variations in recharge and hydraulic conductivity. A series of simulations of a hypothetical aquifer model were made during which average annual recharge rates of 0, 15, 25, and 35 inches were combined with aquifer hydraulic conductivity values of 25, 75, and 225 ft/day. Under steady-state conditions, and a withdrawal rate of 1.2 million gal/day, the size of the contributing recharge area ranges from 0.16 to 0.75 sq mi as recharge from precipitation and average aquifer hydraulic conductivity range from highest to lowest values. Three simulations of the Farmington aquifer model were made: they assumed steady-state conditions, a withdrawal rate of 2.8 million gal/day, and combinations of recharge and aquifer hydraulic conductivity that represented highest, average and lowest rates. The size of the contributing recharge area, under these conditions, ranges from 0.89 to 1.94 sq mi. (USGS)

Water-Resources Investigations Report↗

U.S. Geological Survey research in Handcart Gulch, Colorado—An alpine watershed with natural acid-rock drainage

Handcart Gulch is an alpine watershed along the Continental Divide in the Colorado Rocky Mountain Front Range. It contains an unmined mineral deposit typical of many hydrothermal mineral deposits in the intermountain west, composed primarily of pyrite with trace metals including copper and molybdenum. Springs and the trunk stream have a natural pH value of 3 to 4. The U.S. Geological Survey began integrated research activities at the site in 2003 with the objective of better understanding geologic, geochemical, and hydrologic controls on naturally occurring acid-rock drainage in alpine watersheds. Characterizing the role of groundwater was of particular interest because mountain watersheds containing metallic mineral deposits are often underlain by complexly deformed crystalline rocks in which groundwater flow is poorly understood. Site infrastructure currently includes 4 deep monitoring wells high in the watershed (300&ndash; 1,200 ft deep), 4 bedrock (100&ndash;170 ft deep) and 5 shallow (10&ndash;30 ft deep) monitoring wells along the trunk stream, a stream gage, and a meteorological station. Work to date at the site includes: geologic mapping and structural analysis; surface sample and drill core mineralogic characterization; geophysical borehole logging; aquifer testing; monitoring of groundwater hydraulic heads and streamflows; a stream tracer dilution study; repeated sampling of surface and groundwater for geochemical analyses, including major and trace elements, several isotopes, and groundwater age dating; and construction of groundwater flow models. The unique dataset collected at Handcart Gulch has yielded several important findings about bedrock groundwater flow at the site. Most importantly, we find that bedrock bulk permeability is nontrivial and that bedrock groundwater apparently constitutes a substantial fraction of the hydrologic budget. This means that bedrock groundwater commonly may be an underappreciated component of the hydrologic system in studies of alpine watersheds. Additionally, despite the complexity of the fracture controlled aquifer system, it appears that it can be represented with a relatively simple conceptual model and can be treated as an equivalent porous medium at the watershed scale. Interpretation of existing data, collection of new monitoring data, and efforts to link geochemical and hydrologic processes through modeling are ongoing at the site.

Colorado↗

Plan of study for the regional aquifer systems analysis of the Michigan Basin

Quaternary glacial deposits and Pennsylvanian and Mississippian sandstones, -the Saginaw Formation and Marshall Sandstone- are the major aquifers in the Michigan basin. These aquifers supply approximately 188 million gal/day to municipalities in the 29 ,000 sq mi study area. The most significant problems related to groundwater supplies are the identification of potable sources of groundwater in large quantities and the migration of saline groundwater toward pumping centers. Saline water underlies the entire lower Peninsula of Michigan at indeterminate depth in the deeper parts of the Saginaw Formation and Marshall Sandstone in the center of the Michigan basin. In places, saline water is present in glacial deposits. Overdraft has resulted in severe drawdown in the Lansing area and the abandonment of wells near Flint because of saline water encroachment. Increased demand on the groundwater resources of the study area are expected to cause further problems. In 1985, the U.S. Geological Survey began a 5-yr study to define the geohydrologic framework, describe the geochemistry of groundwater in the glacial and bedrock aquifers, and analyze regional groundwater flow patterns. The scope, plan of study, organization and work elements are described in this report.

Michigan↗

Rethinking groundwater flow on the South Rim of the Grand Canyon, USA: Characterizing recharge sources and flow paths with environmental tracers

In the arid landscape south of the Grand Canyon, natural springs and seeps are a critical resource for endemic species and Native American tribes. Groundwater is potentially threatened by expanding populations, visitations, and mineral extraction activities. Environmental tracers including noble gases, stable isotopes of hydrogen and oxygen in water, tritium, and carbon-14 were used to characterize recharge sources and flow paths in South Rim aquifers. Results confirm the regional Redwall-Muav Aquifer as the primary groundwater source to springs. However, a second local recharge source is required to explain the detection of tritium. Two probable sources are identified as: low-elevation infiltration of surface run-off with warm noble gas recharge temperatures, high excess air, and relatively low fractions of winter recharge, and high-elevation plateau recharge with cool recharge temperatures, low excess air, and fraction of winter recharge of ~ 1. Previous investigators have linked spring occurrence with regional faults and fractures. We show such features are also the likely control chemical mixing between the regional and local groundwater sources, the transport of deeply sourced and local recharge fluids, groundwater age, and thus the relative vulnerability of groundwater to depletion and contamination. The new conceptual model of groundwater sources and flow paths suggest many South Rim springs may respond on the order of 10s to 100s of years to groundwater depletion and contamination, even though the majority of groundwater flow is along longer flow paths with longer lag times. The magnitude of response to short term changes in the flow system remains unclear.

Arizona↗