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Epithermal beryllium deposits in water-laid tuff, western Utah

Epithermal beryllium deposits in western Utah have distinctive geological and geochemical associations that provide guides to exploration for new resources of beryllium and associated metals. Beryllium deposits at Spor Mountain and the Honeycomb Hills are uniquely associated with topaz-bearing rhyolite of Late Tertiary age and are restricted to porous water-laid tuff and breccia that contains carbonate clasts. The beryllium deposits are near both local and regional faults that probably provided conduits for mineralizing fluids.The beryllium deposits contain sizable but uneconomic concentrations of fluorite, lithium (in smectite), manganese oxides, zinc (in smectite and manganese oxides), and uranium, as well as many trace elements. Distinctive zones of argillic and feldspathic alteration enclose the beryllium deposits and generally are parallel to the original stratification of the host tuff. Anomalous concentrations of fluorine, beryllium, cesium, lithium, gallium, niobium, and yttrium occur in relatively unmineralized tuff nearby; these elements form extensive but discontinuous halos around the Spor Mountain beryllium and fluorspar district.The mineralized areas at Spor Mountain and the Honeycomb Hills may be the tops of extensive altered zones that contain deep ore deposits. Anomalous molybdenum, lead, tin, and tungsten in beryllium deposits at Spor Mountain may indicate such leakage. Consideration of possible zonation of ore deposits suggests that if ore deposits do exist at depth, they are in greisens, banded tactites, and medium to high temperature veins similar to the tin-beryllium deposits in the York Mountains of Alaska.

Utah↗

Tintina Gold Province Study, Alaska and Yukon Territory, 2002-2007

The Tintina gold province is an arc-shaped 2,000-kilometer-long metallogenic province that extends from northern British Columbia, through the Yukon Territory, and across and into southwestern Alaska. In the United States, the province remains a prime area for gold exploration and includes such large gold deposits as Pogo, Fort Knox-True North, and Donlin Creek. In recent years, gold exploration and development and mining activity have accelerated in the area. Plans have been discussed for public and private projects and infrastructures associated with development. A U.S. Geological Survey study undertaken from 2002 to 2007 provides a context for understanding why and how the mineral resources of the area were formed, why this area is so abundantly endowed, and how the environmental signatures that are characteristic of the area are related to the development of mineral resources. Characterization of natural baseline metal concentrations in the area's watersheds is necessary to address future land-use issues related to mining and/or infrastructure activities. A thorough understanding of water-rock and element-bioavailability processes will help predict the possible environmental impact of development. The five tasks of this study add to the science of defining and understanding an 'intrusion-related gold system.'

Fact Sheet↗

Circum-North Pacific tectonostratigraphic terrane map

The companion tectonostratigraphic terrane and overlap assemblage of map the Circum-North Pacific presents a modern description of the major geologic and tectonic units of the region. The map illustrates both the onshore terranes and overlap volcanic assemblages of the region, and the major offshore geologic features. The map is the first collaborative compilation of the geology of the region at a scale of 1:5,000,000 by geologists of the Russian Far East, Japanese, Alaskan, Canadian, and U.S.A. Pacific Northwest. The map is designed to be a source of geologic information for all scientists interested in the region, and is designed to be used for several purposes, including regional tectonic analyses, mineral resource and metallogenic analyses (Nokleberg and others, 1993, 1994a), petroleum analyses, neotectonic analyses, and analyses of seismic hazards and volcanic hazards. This text contains an introduction, tectonic definitions, acknowledgments, descriptions of postaccretion stratified rock units, descriptions and stratigraphic columns for tectonostratigraphic terranes in onshore areas, and references for the companion map (Sheets 1 to 5). This map is the result of extensive geologic mapping and associated tectonic studies in the Russian Far East, Hokkaido Island of Japan, Alaska, the Canadian Cordillera, and the U.S.A. Pacific Northwest in the last few decades. Geologic mapping suggests that most of this region can be interpreted as a collage of fault-bounded tectonostratigraphic terranes that were accreted onto continental margins around the Circum- . orth Pacific mainly during the Mesozoic and Cenozoic (Fujita and ewberry, 1983; 1987; Parfenov, 1984, 1991; Howell, 1985; Watson and Fujita, 1985; Parfenov and Natal'in, 1984; Jones and others. 1987; Monger and Berg, 1987, Fujita and Cook. 1990; Zonenshain and others. 1990; Natal'in, 1991, 1993; Moore and others, 1992; Silberling and others, 1992; Nokleberg and others. 1992, 1993, 1994a; Parfenov and others. 1993; Plaflcer and Berg, 1994; Tabor, 1994). This map is the result of extensive geologic mapping and associated tectonic studies in the Russian Far East, Hokkaido Island of Japan, Alaska, the Canadian Cordillera, and the U.S.A. Pacific Northwest in the last few decades. Geologic mapping suggests that most of this region can be interpreted as a collage of fault-bounded tectonostratigraphic terranes that were accreted onto continental margins around the Circum- . orth Pacific mainly during the Mesozoic and Cenozoic (Fujita and ewberry, 1983; 1987; Parfenov, 1984, 1991; Howell, 1985; Watson and Fujita, 1985; Parfenov and Natal'in, 1984; Jones and others. 1987; Monger and Berg, 1987, Fujita and Cook. 1990; Zonenshain and others. 1990; Natal'in, 1991, 1993; Moore and others, 1992; Silberling and others, 1992; Nokleberg and others. 1992, 1993, 1994a; Parfenov and others. 1993; Plaflcer and Berg, 1994; Tabor, 1994). On the companion map and in the descriptions bel?w· terranes are interpreted according to inferred tectonic environments. These environments are (I) cratonai; (2) passive continental margin; (3) metamorphosed continental margin; (4) continental-margin arc; (5) island arc; (6) oceanic crust, seamount, and ophiolite; (7) accretionary wedge and subduction zone: (8) turbidite basin; and (9) metamorphic for terranes that are too highly-deformed and metamorphosed to de~ermine the original tectonic environment. For terranes with complex geologic histories, the chosen color indicates the tectonic environment most prevalent during this history of the terrane. The tectonic environments inf~rred for igneous rocks are both temporal and genetic. The temporal environments are preaccretion and postaccretion. The genetic environments are subduction-related, rift-related, and collisional (anatectic)- related. In addition to terranes, the map also depicts postaccretion units that include: (I) Cenozoic and Mesozoic overlap assemblages of sedimentary and volcanic rocks that are deposited across two or more terranes that formed generally after accretion of most terranes in the region; (2) Cenozoic and Mesozoic basinal deposits that occur within a terrane or on the craton; (3) plutonic rocks. The postaccretion igneous units are identified by age-lithologic abbreviations and by name. These overlap assemblages and basinal deposits formed mainly during sedimentation and magmatism that occurred after accretion of terranes to each other or to a continental margin. Overlap assemblages provide minimum ages on the timing of accretion of terranes. Some Cenozoic and Mesozoic overlap assemblages and basinal deposits, as well as fragments of terranes, are extensively offset by movement along postaccretion faults. In addition, in onshore areas, the map depicts major preaccretion plutonic rocks that are limited to individual terranes. and in offshore areas. the map depicts major oceanic plates,-ocean floor magnetic lineations. oceanic spreading ridges, and seamounts. The map consists of five sheets. Sheets I and 2 depict, at a scale of I :5.000.000. the tectonostratigraphic terranes. preaccretion plutonic rocks, and postaccretion Cenozoic and Mesozoic overlap sedimentary, volcanic. and plutonic assemblages, and basinal deposits for the Circum- orth Pacific including the Russian Far East, northern Hokkaido Island of Japan, Alaska. the Canadian Cordillera, part of the U.S.A. Pacific Northwest. and adjacent offshore areas. Sheet 3 provides the list of map units for Sheets I and 2. Sheet 4 is a index map showing generalized onshore terranes and overlap assemblages for onshore parts of the Circum-North Pacific at a scale of I: I 0,000,000. Sheet 4 is a guide to the more complicated onshore features depicted on Sheets I and 2. Sheet 5 is an index map showing the major geographic regions for the Circum-North Pacific. Significant differences exist between the representation of onshore and offshore geology on Sheets I and 2. These are: (I) compared to the onshore part of the map, the offshore part is depicted in a more schematic fashion because of more limited data and because the offshore terranes and early Cenozoic and older overlap assemblages generally are obscured by extensive late Cenozoic sedimentary cover that is not shown unless thicker than two kilometers; (2) marginal contacts of offshore Cenozoic and Cretaceous sedimentary basins do not match contacts of onshore Cenozoic and Cretaceous sedimentary units because offshore basins are limited to those regions with sediment thicknesses greater than two kilometers; (3) stratigraphic columns, included at the end of this explanation. are provided only for onshore terranes because the geology of offshore terranes is generally less well-known; and (4) for simplicity, the major onshore Cenozoic sedimentary basins are generally not defined and described separately because the onshore part of the map is designed to emphasize terranes and overlap volcanic assemblages that are crucial for both for tectonic and metallogenic analyses published elsewhere (Nokleberg and others, 1993, 1994a). Several key geologic sources were used in the compilation of the map. For Alaska. the basic outcrop pattern for the map is from Beikman (1980), Gehrels and Berg (1992, 1994). Barker and others ( 1994). Brew (1994), and Moli-Stalcup and others ( 1994b). The distribution of terranes is from Jones and others (1987) and Monger and Berg (1987), with modification by Grantz and other (1991 ). Worall (199 1 ), okleberg and others (1993, 1994a), the cited references, and the Alaskan co-authors of this report. For the Canadian Cordillera. the basic outcrop pattern is from Monger and Berg ( 1987), Wheeler and other (1988). and Wheeler and McFeeley ( 1991) with modifications by the Canadian authors. For the northern part of the Russian Far East. the basic outcrop pattern is from So unov (1985) with modifications by the Russian authors. For the outhern part of the Russian Far East, the basic outcrop pattern is from Krasny (1991) and Bazhanov and Oleinik ( 1986) with modification by the Russian authors. The Russian Far East part of the map is the first attempt to define and delineate terranes in that region. In their compilation. the Russian authors utilized the methodology of U.S.A. and Canadian geologists. Because this map is the first attempt to display the terranes. Cenozoic and Mesozoic overlap assemblages. basinal deposit , and plutonic belts of the Russian Far East. the Russian author will appreciate constructive sugge tions for improving the map.

Open-File Report↗

Preliminary geologic interpretation of aeromagnetic data in the Nixon Fork district, Alaska

An aeromagnetic map covering 480 square miles was compiled for the Nixon Fork district, which is located approximately 35 miles northeast of McGrath, Alaska. The survey was flown in search of concealed intrusive rocks which may have produced contact metamorphic deposits in limestone similar to the known lode deposits which have been the principal source of gold in the district. The exposed quartz monzonite stocks with which the lode deposits are associated produce negative magnetic anomalies. Slight to moderately strong positive anomalies correlate with granitic intrusives in contact with Upper Cretaceous rocks in the Iditarod-Nixon Fork fault zone. No significant mineral deposits have been found in conjunction with these granitic bodies. Positive anomalies, delineating buried intrusives, occur near the east and west boundaries of the mapped area. The nature of the westernmost intrusive is unknown. An area of possible economic interest lies between Limestone Mountain and Whirlwind-Canyon Creeks in the eastern sector of the mapped area. An elliptical positive anomaly is superimposed on an elongate, slightly negative anomaly. This negative anomaly may represent an intrusive similar to the quartz monzonite with which the lode deposits are affiliated. The positive anomaly may be a near-vertical mafic dike intruded to within 50 feet of the surface of a limestone ridge. Limestone in the vicinity of the dike may be a favorable area for prospecting for lode deposits similar to the known gold-producing deposits of the district.

Alaska↗

Lead-, zinc-, and barite-bearing samples from the western Brooks Range, Alaska, with a section on petrography and mineralogy

Concentrations of base metal and barite of potential economic significance may be present in the western De Long Mountains, northwestern Alaska. Greater than 2 percent lead and 1 percent zinc were detected semiquantitatively in sulfide-bearing hand samples from one locality, and more than 10 percent lead was analyzed in a related stream sediment sample. The base metals as sulfides, along with barite, have been concentrated in Paleozoic and(or) Mesozoic sedimentary chert. Several other localities at which sulfides appear to be weathering are present within a 100-square-mlle area. Systematic prospecting should determine if the mineralization has regional significance and has resulted in deposits' of possible economic importance.

Alaska↗

Assessment of boreal forest historical C dynamics in the Yukon River Basin: relative roles of warming and fire regime change

Carbon (C) dynamics of boreal forest ecosystems have substantial implications for efforts to mitigate the rise of atmospheric CO 2 and may be substantially influenced by warming and changing wildfire regimes. In this study we applied a large-scale ecosystem model that included dynamics of organic soil horizons and soil organic matter characteristics of multiple pools to assess forest C stock changes of the Yukon River Basin (YRB) in Alaska, USA, and Canada from 1960 through 2006, a period characterized by substantial climate warming and increases in wildfire. The model was calibrated for major forests with data from long-term research sites and evaluated using a forest inventory database. The regional assessment indicates that forest vegetation C storage increased by 46 Tg C, but that total soil C storage did not change appreciably during this period. However, further analysis suggests that C has been continuously lost from the mineral soil horizon since warming began in the 1970s, but has increased in the amorphous organic soil horizon. Based on a factorial experiment, soil C stocks would have increased by 158 Tg C if the YRB had not undergone warming and changes in fire regime. The analysis also identified that warming and changes in fire regime were approximately equivalent in their effects on soil C storage, and interactions between these two suggests that the loss of organic horizon thickness associated with increases in wildfire made deeper soil C stocks more vulnerable to loss via decomposition. Subbasin analyses indicate that C stock changes were primarily sensitive to the fraction of burned forest area within each subbasin and that boreal forest ecosystems in the YRB are currently transitioning from being sinks to sources at ∼0.7% annual area burned. We conclude that it is important for international mitigation efforts focused on controlling atmospheric CO 2 to consider how climate warming and changes in fire regime may concurrently affect the CO 2 sink strength of boreal forests. It is also important for large-scale biogeochemical and earth system models to include organic soil dynamics in applications to assess regional C dynamics of boreal forests responding to warming and changes in fire regime.

Ecological Applications↗

Metamorphic rocks of the Yakutat-St. Elias area, south-central Alaska

Metamorphic rocks in the Yakutat-St. Elias area range in grade from zeolite to amphibolite facies. Radiometric age determinations on selected metamorphic rocks have helped to identify two major metamorphic events, one in Late Cretaceous time that was characterized by penetrative deformation, and one in the Miocene Epoch that resulted in widespread recrystallization and igneous intrusions. Mapped facies units show many discontinuities across major faults, and their distribution indicates major differential uplift between several structurally bound crustal blocks within a strongly deformed mobile belt west of the Art Lewis fault. Late Cretaceous metamorphic gradients indicate that the blocks have been tilted to the west or northwest parallel to their general structural grain. As mineral assemblages that were recrystallized during Miocene time occur on both sides of the Fairweather fault, large-scale, post-Miocene strike-slip movement along the fault is not indicated.

Alaska↗

Geophysical investigation of Red Devil mine using direct-current resistivity and electromagnetic induction, Red Devil, Alaska, August 2010

Red Devil Mine, located in southwestern Alaska near the Village of Red Devil, was the state's largest producer of mercury and operated from 1933 to 1971. Throughout the lifespan of the mine, various generations of mills and retort buildings existed on both sides of Red Devil Creek, and the tailings and waste rock were deposited across the site. The mine was located on public Bureau of Land Management property, and the Bureau has begun site remediation by addressing mercury, arsenic, and antimony contamination caused by the minerals associated with the ore deposit (cinnabar, stibnite, realgar, and orpiment). In August 2010, the U.S. Geological Survey completed a geophysical survey at the site using direct-current resistivity and electromagnetic induction surface methods. Eight two-dimensional profiles and one three-dimensional grid of direct-current resistivity data as well as about 5.7 kilometers of electromagnetic induction profile data were acquired across the site. On the basis of the geophysical data and few available soil borings, there is not sufficient electrical or electromagnetic contrast to confidently distinguish between tailings, waste rock, and weathered bedrock. A water table is interpreted along the two-dimensional direct-current resistivity profiles based on correlation with monitoring well water levels and a relatively consistent decrease in resistivity typically at 2-6 meters depth. Three settling ponds used in the last few years of mine operation to capture silt and sand from a flotation ore processing technique possessed conductive values above the interpreted water level but more resistive values below the water level. The cause of the increased resistivity below the water table is unknown, but the increased resistivity may indicate that a secondary mechanism is affecting the resistivity structure under these ponds if the depth of the ponds is expected to extend below the water level. The electromagnetic induction data clearly identified the three monofills and indicate, in conjunction with the three-dimensional resistivity data, additional possible landfill features on the north side of Red Devil Creek. No obvious shallow feature was identified as a possible source for a spring that is feeding into Red Devil Creek from the north bank. However, a discrete, nearly vertical conductive feature observed on the direct-current resistivity line that passes within 5 meters of the spring may be worth investigating. Additional deep soil borings that better differentiate between tailings, waste rock, and weathered bedrock may be very useful in more confidently identifying these rock types in the direct-current resistivity data.

Open-File Report↗

Trace elements investigations in the Sweepstakes Creek area, Koyuk district, Seward Peninsula, Alaska

A significant content of radioactive material was recognized in a few placer concentrates from Sweepstakes and Rube Creeks in the Koyuk district of eastern Seward Peninsula, Alaska, when old collections were scanned for radioactivity in the spring of 1945. Subsequent field investigations with a Geiger-Mueller counter were made of the creek gravels and the placer-gold paystreak on the bench ground of Sweepstakes Creek and its tributaries, the syenite stock of Granite Mountain to the north, of Sweepstakes Creek, and the creek gravels of Rube and Anzac Creeks which are tributaries of the Peace River east of the syenite stock. The content of radioactive minerals in the gravels and in the placer-gold paystreak was found to be disappointingly low. There concentration ratios were between 45 and 169 to 1, the content of concentrates from the creek gravels is only .001 to .016 percent equivalent uranium the average content of the creek gravels in place is computed as .0001 percent equivalent uranium. The placer-gold paystreak was not accessible in place, but the content was computed as .0003 percent equivalent uranium from the sluice-box concentrates and tailings at Winder's open-cut,the only active placer mine in the area in 1945. The radioactive minerals are relatively abundant in such gravity concentrates as the sluice-box concentrates, and are particularly abundant in certain size fractions of these sluice concentrates Thus the concentrates from the aluiee-fcex, after screening through 20-mesh, showed 0.04 percent equivalent uranium. An even greater concentration of radioactive minerals is obtained in the "blowings," which represent a further cleaning of the sluice-box concontrates, one saample showing 14.20 percent equivalent uranium.

Alaska↗

Magmatic differentiation in tertiary and quaternary volcanic rocks from Adak and Kanaga Islands, Aleutian Islands, Alaska

Samples of 17 volcanic rocks of Tertiary and Quaternary age from Adak and Kanaga islands have been chemically analyzed and studied microscopically. Spectrograms have been made of 10 of them. The rocks from Adak represent one center of possibly older Tertiary age and two centers of younger Tertiary or Quaternary age. The rocks from Kanaga Island represent both a shield volcano of possibly Tertiary age, partly destroyed by the formation of a caldera, and a young cone of Quaternary age that has grown within the caldera. All the rocks are basalt or andesite. Modally, all are characterized by relatively large crystals of plagioclase more calcic than andesine, and by one or more of the following ferromagnesian minerals: olivine, hypersthene, augite, and hornblende. Apatite and iron ores are common, and late silica minerals and orthoclase occur interstitially in the groundmasses of some rocks . As analyses of no more than four samples are available for each center, the small differences between sets of analyses representing different centers are of doubtful significance. Consequently, the analyses representing all the centers have been plotted on each of the several diagrams used. The several types of variation diagrams show that the province is a calc-alkaline one. The alkali-lime index is in the neighborhood of 63. This very high value is comparable with that for Katmai and is only slightly less than the maximum for the Japanese volcanic rock series. The quantities of minor constituents present are not exceptional for the rock types analyzed; the rocks from Adak are apparently more strontium-rich than those from Kanaga . The chemical analyses of the more basic rock types, as compared with the average analysis of plateau basalt, suggest that the Aleutian parental magma could have been derived from a plateau basalt magma by the addition of plagioclase and the subtraction of pyroxene, iron ore, and some quartz. The distribution of the minor elements can be explained more easily by postulating that, at least on Kanaga Island , some sediments have been assimilated. The derivation of the analyzed rocks from the Aleutian parental magma is most easily explained by the hypothesis that the plagioclase remained in suspension while the ferromagnesian minerals were settling out.

Alaska↗

Origin of the Red Dog Zn-Pb-Ag deposits, Brooks Range, Alaska: Evidence from regional Pb and Sr isotope sources

Pb and Sr isotope data were obtained on the shale-hosted Zn-Pb-Ag Red Dog deposits (Qanaiyaq, Main, Aqqaluk, and Paalaaq), other shale-hosted deposits near Red Dog, and Zn-Pb-Ag sulfide and barite deposits in the western and central Brooks Range. The Red Dog deposits and other shale-hosted Zn-Pb-Ag deposits near Red Dog are hosted in the Mississippian Kuna Formation, which is underlain by a sequence of marine-deltaic clastic rocks of the Upper Devonian to Lower Mississippian Endicott Group. Ag-Pb-Zn vein-breccias are found in the Endicott Group. Galena formed during the main mineralization stages in the Red Dog deposits and from the Anarraaq and Wulik deposits have overlapping Pb isotope compositions in the range 206Pb/204Pb = 18.364 to 18.428, 207Pb/204Pb = 15.553 to 15.621, and 208Pb/204Pb = 38.083 to 38.323. Galena and sphalerite formed during the main ore-forming stages in the Red Dog deposits define a narrow field on standard uranogenic and thorogenic Pb isotope diagrams. Lead in sulfides of the Red Dog district is less radiogenic (238U/204Pb: ?? = 9.51-9.77) than is indicated by the average crustal lead evolution model (?? = 9.74), a difference consistent with a long history of evolution at low ratios of ?? before the Carboniferous. The homogeneous regional isotopic reservoir of Pb may indicate large-scale transport and leaching of minerals with various ?? ratios and Th/Pb ratios. Younger and genetically unrelated fluids did not significantly disturb the isotopic compositions of galena and sphalerite after the main mineralization event in the Red Dog district. Some pyrite shows evidence of minor Pb remobilization. The overall lead isotope homogeneity in the shale-hosted massive sulfide deposits is consistent with three types of control: a homogeneous regional source, mixing of lead during leaching of a thick sedimentary section and fluid transport, or mixing at the site of deposition. Isotopic variability of the hydrothermal fluids, as represented by galena in the Red Dog district, appears to be consistent with a simple mixing system. Evidence indicates that galena was deposited from largely similar hydrothermal solutions throughout the Red Dog district. A shared regional isotopic reservoir is also supported by the correspondence of Pb isotope compositions of galena in deposits of the Red Dog district and galena in clastic rocks (vein-breccias). Leaching of metals and progressive extraction of radiogenic lead from the clastic rocks in the Endicott Group may account for the trend of increasing 206Pb/204Pb in galena of the Red Dog district. Galena in the Red Dog deposits is unlikely to have been derived entirely from the same isotopic reservoir as that represented by the lead in the Kuna Formation or from the igneous rocks in the Red Dog district. Sr isotope data for barite, calcite, and witherite from the Red Dog deposits are compared with data from regional barite that is associated with sulfides and from barite in sulfide-poor occurrences. Fluids with heterogeneous Sr isotope signatures are indicated. Barite in the Main deposit extends to higher ratios of 87Sr/86Sr (0.709034-0.709899) than barite in the Anarraaq deposit (0.708615-0.709256). All barite is more radiogenic than Carboniferous seawater. Other Mississippian(?) shale-hosted deposits and mineral occurrences containing barite in the Red Dog district and barite in regional occurrences east of Red Dog in the western and central Brooks Range also have heterogeneous 87Sr/86Sr ratios. Carbonate (87Sr/86Sr = 0.710319-0.713637) and witherite (87 Sr/86 Sr = 0.710513) in the Main deposit are more radiogenic than barite. In contrast, carbonate (87Sr/86Sr = 0.708196-0.709740) intergrown with massive sulfides at Anarraaq has isotopic compositions similar to that of barite. Paragenetic and isotop ic studies suggest that early barite is similar to barite typically formed in cold seeps along continental margins. This early fine-grained barite formed before the main mineralizat

Economic Geology↗

Water and Sediment Chemical Data and Data Summary for Samples Collected in 1999 and 2001 in the Goodpaster River Basin, Big Delta B-2 Quadrangle, Alaska

We report the chemical analysis for water and sediment collected from the Big Delta B-2 quadrangle. These data are part of a study located in the Big Delta B-2 quadrangle that focused on the integration of geology and bedrock geochemistry on with the biogeochemistry of water, sediments, soil, and vegetation. The discovery of the Pogo lode gold deposit in the northwest corner of the quadrangle was the impetus for this study. The study objectives were to create a geologic map, evaluate the bedrock geochemical influence on the geochemical signature of the surficial environment, and define landscape-level predevelopment geochemical baselines. Important to baseline development is an evaluation of what, if any, geochemical difference exists between the mineralized and non-mineralized areas within a watershed or between mineralized and non-mineralized watersheds. The analytic results for the bedrock, soils, and vegetation are reported elsewhere. Presented here, with minimal interpretation, is the analytic data for the water and sediment samples collected in the summers of 1999 and 2001, and a summary statistics of these analyses.

Open-File Report↗

Geology of the Golden Zone mine area, Alaska

The Golden Zone mine area, in the upper Chulitna district, is underlain mainly by siltstone and tuff, volcanic conglomerate and breccia, and limestone. These rocks were invaded, probably in the Tertiary, by dikes and a small stock of porphyry. The ore deposits of the area are the Golden Zone breccia pipe, a nearly vertical body about in the center of the porphyry stock, and steeply dipping veins. Most veins strike north to northeast and are commonly only 1-5 feet thick, but locally are as much as 15 feet thick. Both pipe and vein deposits are gold deposits of low to moderate grade that are characterized by abundant arsenopyrite; some contain possibly economic amounts of copper, lead and zinc minerals. Of the deposits of the mine area, only the Golden Zone has been explored to any extent, and both it and some of. the veins deserve further exploration to determine their potential.

Alaska↗

Diagenetic barite-pyrite-wurtzite formation and redox signatures in Triassic mudstone, Brooks Range, northern Alaska

Mineralogical and geochemical studies of interbedded black and gray mudstones in the Triassic part of the Triassic-Jurassic Otuk Formation (northern Alaska) document locally abundant barite and pyrite plus diverse redox signatures. These strata, deposited in an outer shelf setting at paleolatitudes of ~45 to 60°N, show widespread sedimentological evidence for bioturbation. Barite occurs preferentially in black mudstones (TOC = 0.93–6.46 wt%), forming displacive euhedral crystals with pyrite inclusions and rims, and late albite inclusions or intergrowths. Pyrite also occurs as small (3–20 μm) framboids, discontinuous laminae, euhedral and anhedral crystals, and replacements of barite and fossils (mainly radiolarians). Paragenetically early wurtzite is present as clusters of very small (1–3 μm) aggregates of radiating crystals 0.5 to 1.0 μm long with cores of organic matter that overgrow framboidal pyrite; later wurtzite forms 10- to 30-μm bladed crystals. Equant grains (3–30 μm) and small (20 μm) angular clusters of zinc sulfide that include <1-μm-long, comb-like structures are sphalerite or wurtzite, or both. Minor siderite forms euhedral crystals intergrown with albite that enclose wurtzite and barite. Illite shows intergrowths with sphalerite; rare K-feldspar is intergrown with barite. Formation of these minerals and assemblages is attributed to early diagenetic processes. Whole-rock geochemical data for 15 samples show large ranges in redox proxies including Post Archean Average Shale (PAAS)-normalized enrichment factors (EFs) for V, U, Mo, and Re, and Al-normalized ratios for V, U, and Mo. Results for most black mudstones, with or without abundant barite and/or pyrite, suggest deposition within an oxygen minimum zone. Cerium anomalies, PAAS-normalized and calculated on a detrital-free basis, range widely from 0.49 to 0.96 and may reflect diagenetic overprinting by Ce-depleted fluids. Considering data for both black and gray mudstones, the overall geochemical pattern together with evidence from pyrite framboid sizes suggest that redox conditions fluctuated greatly from euxinic to oxic, like the redox profiles reported for modern shelf sediments offshore Peru and Namibia. The euxinic redox signatures in some Otuk black mudstones may correlate with widespread Early to Middle Triassic ocean anoxic events proposed for other regions. Calculations of median EFs for trace elements in Otuk black mudstones reveal both enrichments and depletions. Normalizations to the median composition of the three least-mineralized black mudstones show that barite- and/or pyrite-rich samples display large (>50%) positive changes for Li (+80.4%), V (+75.6%), Sr (+75.9%), Ba (+790%), Cu (+92.1%), Ni (+169%), Ag (+156%), Au (+3091%), As (+109%), Sb (+476%), and Se (+205%); Zn shows a moderate positive change of +42.1%. Moderate negative changes are evident only for Ge (−47.2%) and W (−30.6%). The local enrichments may reflect one or more factors including redox variations in bottom waters and pore fluids, element mobility during diagenesis, and selective fractionation into minerals such as barite, pyrite, and wurtzite. Anomalously low U/Al and UEF values, compared to those for other modern and ancient organic-rich sediments and sedimentary rocks, are attributed to increased solubility and loss of U during bioturbation-related oxygenation in the subsurface. Physicochemical constraints on barite, pyrite, and wurtzite formation are informed by use of a pH-fO2 plot constructed at 10 °C. Based on paragenetic evidence for multistage deposition of these three minerals, together with the presence of illite intergrown with ZnS and K-feldspar with barite, proposed diagenetic trends involve an increase in pH and fO2 related to the ingress of sulfate-rich pore fluids during bioturbation, followed by a return to lower then higher pH and fO2 conditions linked to carbon, sulfur, barium, and iron cycling during diagenesis. Labile Ba of marine pelagic origin was mobilized from organic-rich sediment upward to the sulfate-methane transition zone where barite precipitated during the interaction of reduced Ba- and CH4-rich fluids with sulfate-bearing pore fluids. The formation of paragenetically early wurtzite (ZnS) crystals, as well as locally high EF values for Cu, Ni, Ag, and Au, is attributed to metal enrichment of pore fluids, with sources being derived in part from water-column deposition from hydrothermal plumes related to coeval Triassic seafloor vent systems including a volcanogenic massive sulfide deposit in British Columbia and the Wrangellia Large Igneous Province in Alaska.

Alaska↗

The United States Geological Survey in Alaska: Organization and status of programs in 1977

United States Geological Survey projects in Alaska include a wide range of topics of economic and scientific interest. Studies in 1976 include economic geology, regional geology, stratigraphy, environmental geology, engineering geology, hydrology, and marine geology. Discussions of the findings or, in some instances, narratives of the course of the investigations are grouped in eight subdivisions corresponding to the six major onshore geographic regions, the offshore projects, and projects that are statewide in scope. Locations of the study areas are shown. In addition, many reports and maps covering various aspects of the geology and mineral and water resources of the State were published. These publications are listed. (Woodard-USGS)

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The United States Geological Survey in Alaska: Accomplishments during 1976

United States Geological Survey projects in Alaska include a wide range of topics of economic and scientific interest. Studies in 1976 include economic geology, regional geology, stratigraphy, environmental geology, engineering geology, hydrology, and marine geology. Discussions of the findings or, in some instances, narratives of the course of the investigations are grouped in eight subdivisions corresponding to the six major onshore geographic regions, the offshore projects, and projects that are statewide in scope. Locations of the study areas are shown. In addition, many reports and maps covering various aspects of the geology and mineral and water resources of the State were published. These publications are listed. (Woodard-USGS)

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Results of geological and geochemical investigations in an area northwest of the Chulitna River, central Alaska Range

Sedimentary and volcanic rock units of Paleozoic and Mesozoic age, faults, and elongate bodies of intrusive rock, particularly serpentinites, have a dominant northeasterly trend in an area northwest of the Chulitna River between Eldridge Glacier and Bull River. The serpentinites locally contain abnormal (as much as 0.5 percent) concentrations of nickel, have one newly identified occurrence of chromite, and are hosts to small epigenetic lodes containing copper, gold, and silver. Other epigenetic concentrations of copper or other metals occur in interlayered basalt and limestone at Partin and Canyon Creeks in the southwestern part of the area and in porphyry near Costello Creek in the northern part of the area. Tin occurs in greisen on upper Ohio Creek, and abnormal concentrations of tin also characterize mineralized rocks along Canyon Creek and at a prospect near Long Creek. Mineralized rocks characterized by silver, lead, and zinc crop out near Lookout Mountain. Anomalous concentrations of gold and other metals occur in stream sediments at isolated sites in upper Long Creek and at Coal Creek, as well as in several areas near known lode mineral occurrences. Shotgun and McCallie Creeks both contain stream sediments with anomalous concentrations of metals and both head into the basalt-limestone unit which is the host rock at Partin and Canyon Creeks; these facts suggest that other concentrations may be found.

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Lead in the United States, exclusive of Alaska and Hawaii

The productive lead districts in the United States (exclusive of Alaska and Hawaii) are shown on the accompanying map. The map is at a scale of 1: 3,168,000, (50 miles to the inch). Only those districts known or believed to contain 1,000 short tons or more of lead are shown; individual deposits within districts are not represented.

Mineral Investigations Resource Map↗