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Geologic map of the northwest flank of Mauna Loa volcano, Island of Hawai‘i, Hawaii

Mauna Loa, the largest active volcano on Earth, has erupted 34 times since written descriptions became available in A.D. 1832. The most recent eruption of Mauna Loa occurred on November 27, 2022, after a 38 year hiatus; it lasted for 12 days. Some eruptions began with only brief seismic unrest, whereas others followed several months to a year of increased seismicity. Once underway, Mauna Loa’s eruptions can produce lava flows that may reach the sea in less than 24 hours, severing roads and utilities. For example, lava flows that erupted from the Southwest Rift Zone in 1950 advanced at an average rate of 9.3 kilometers per hour (5.8 miles per hour); all three lobes reached the ocean within ~24 hours. Near the eruptive vents, the flows likely traveled even faster. In terms of eruption frequency, pre-eruption warning, and rapid flow emplacement, Mauna Loa has great volcanic-hazard potential for the Island of Hawai‘i. Volcanic hazards on Mauna Loa can be anticipated, and risk substantially mitigated, by documenting its past activity to refine our knowledge of the hazards, and by alerting the public and local government officials of our findings and their implications for hazards assessments and risk. The map of the north and west flanks of Mauna Loa shows the distribution and relation of volcanic and surficial sedimentary deposits. It incorporates previously reported work published as generalized small-scale maps and a more detailed map. Within the mapped area, lava has flowed from three different source regions: the Northeast Rift Zone (22 percent), the summit (64 percent), and radial vents (14 percent). All three have different points of origin which, in turn, affect the flow characteristics and periodicity of activity. The map area includes the uppermost part of the NERZ and extends from the highest elevation––13,040 feet at the south end of the Kokoolau quadrangle, just below the summit caldera––to the sea northwest and west of the summit. Lava that erupts from the north and west flanks typically flows to the west, northwest, or north, depending on the vent location. Both morphologic lava flow types—‘a‘ā and pāhoehoe—are present. Pāhoehoe units tend to spread out or widen in low-slope regions, such as in the saddle regions between Mauna Loa and Mauna Kea or between Mauna Loa and Hualālai. In comparison, ʻaʻā flows generally produce narrower flow lobes that have higher relief. This map is the fifth in a series of five maps that will cover Mauna Loa volcano. NOTE: Map sheet 1 contains lines and type with overprint. This feature may be turned on or off in the Adobe Acrobat page display preferences.

Hawaii

Recent advances in characterizing the crustal stress field and future applications of stress data: Perspectives from North America

The stress field controls patterns of crustal deformation, including which faults are likeliest to cause earthquakes or transmit fluids. Since the 1950s, maps of maximum horizontal stress ( S Hmax ) orientations have advanced dramatically, and the style of faulting (relative principal stress magnitudes) has recently been mapped in some regions as well. This perspectives paper summarizes developments in characterizing stress orientations and (relative) magnitudes, including new seismic and borehole methods, as well as progress in identifying the causes of stress variations. Despite these advances, adding far more spatiotemporal detail would allow geoscientists to address many of today's key challenges regarding natural hazards, energy development, and geodynamics. In particular, it is critically important to characterize stress heterogeneity at multiple scales while also recognizing the coherent variability of the stress field. The second part of the paper considers how more detailed stress datasets could prove essential to addressing some of the grand questions in geoscience, including deciphering the poorly understood feedbacks between crustal dynamics and surface processes, improving earthquake and eruption forecasts, and determining the origins and shared properties of plate boundaries.

Geological Society, London, Special Publications

Geologic map and structure sections along the southern part of the Bartlett Springs Fault Zone and adjacent areas from Cache Creek to Lake Berryessa, northern Coast Ranges, California

Introduction Located in the Coast Ranges of northern California, the Bartlett Springs Fault Zone is the easternmost fault in the San Andreas Fault system in northern California. The fault is a right-lateral, strike-slip structure considered capable of producing an earthquake of moment magnitude 7. The purpose of this mapping is to better characterize the geology and earthquake hazards associated with the southern part of the Bartlett Springs Fault Zone and to help identify any evidence of active uplift on the faults bounding the Coast Ranges. Although the area immediately surrounding the Bartlett Springs Fault Zone is sparsely populated, its southern segment presents a potential seismic hazard to northern California communities as far away as the San Francisco Bay region and Sacramento. There are also nearby water resources, mineral resources, and public lands used for public recreation. The Coast Ranges of northern California are a series of northwest-southeast-oriented mountain ranges and valleys located north of the San Francisco Bay region, between the Pacific Ocean to the west and the Sacramento Valley to the east. The region has rugged terrain, high mountain peaks that reach more than 2,400 meters above sea level, isolated and narrow valley bottoms on which most human settlements are located, and large drainage systems that tend to follow the northwest-southeast-oriented topographic grain. The physiographic character of the region is shaped by its bedrock geology, deformational history, and active faulting. The basement rocks of the northern Coast Ranges consist of the Franciscan Complex and the Great Valley complex, the latter of which consists of two informal units, the Coast Range ophiolite and the Great Valley sequence. The Franciscan Complex and the Great Valley complex are in structural contact along the Coast Range Fault, a regional-scale structure and fundamental crustal boundary. The Franciscan Complex and the Great Valley complex are superposed by active, northwest-southeast-striking strike-slip faults that are associated with seismicity swarms. These active strike-slip faults can produce moderate to large earthquakes that have moment magnitudes of 7–8. In places, these active structures bound large ranges and valleys, suggesting that much of the modern topographic expression is the result of active deformation processes. This report contains new 1:24,000-scale geologic mapping along the southern part of the Bartlett Springs Fault Zone between Clear Lake and Lake Berryessa. The map area spans 738 square kilometers in northern Napa County, southern Lake County, and parts of Yolo and Colusa Counties. The south and east borders of the map are 90 kilometers north of San Francisco and 70 kilometers west of Sacramento, respectively. The map area is within the Knoxville mining district, which has a history of mercury and gold mining dating back to the mid-19th century. The two main towns in the region, Lower Lake and Clearlake, California, are west-northwest of the map area. Approximately 71,000 people live in the cities and rural communities located within a 40-kilometer radius of the center of the map area. The bedrock geology, cross sections, and structural data presented herein are critical for evaluating the long-term evolution of the Bartlett Springs Fault Zone. This work will supplement studies on local seismic hazards, liquefaction potential, landslide hazards, earthquake geology, natural resources, groundwater resources, engineering geology, and tectonic history by providing the background information for site-specific investigations on these subjects.

California

The Hardscrabble Creek complex: A newly discovered, mostly buried, Mesoproterozoic mafic-ultramafic pluton in the Wet Mountains, Colorado, USA

The origin of prolific ca. 1.4 Ga ferroan magmatism between the southwestern USA and eastern Canada is enigmatic and has been explained by various models, including extensional, mantle plume, and convergent plate-margin models. Rare mafic plutons are associated with the ferroan plutons, which may help constrain their mantle source and tectonic setting. In the southwestern USA, only two such mafic plutons are known to exist. We present the first evidence for a third, mostly buried, potentially layered, mafic-ultramafic Mesoproterozoic pluton, informally referred to as the Hardscrabble Creek complex, in the central Wet Mountains of Colorado, USA. Recent geophysical data show an elliptical magnetic and gravity high spatially coincident with local gabbroic outcrops. New field and petrographic analyses of these exposed rocks reveal that they consist of ultramafic to mafic cumulates, including orthopyroxenite, olivine norite, norite, and anorthosite. High-precision U-Pb dating of zircon from orthopyroxenite and norite yield weighted mean 206 Pb/ 238 U dates of 1352.36 ± 1.60 Ma and 1352.37 ± 1.71 Ma, respectively. These dates indicate that the complex formed over a narrow timeframe, after the adjacent 1362 ± 7 Ma ferroan San Isabel Granite, and during the waning stages of the regional ca. 1.4 Ga ferroan magmatism. Whole-rock geochemistry and Nd-Sr-Pb isotope compositions of samples from the Hardscrabble Creek complex are similar to those of the San Isabel Granite, suggesting that they were derived from the same or a similar mantle source. The mineral chemistry of the samples is comparable to Proterozoic massif-type anorthosites and related mafic intrusions, indicating that the Hardscrabble Creek complex and San Isabel Granite together represent a rare anorthosite-mangerite-charnockite-granite (AMCG) suite in the southwestern USA. The Hardscrabble Creek complex is unique because it formed ~80 m.y. after the other few mafic plutons in the southwestern USA, and it contains an ultramafic section that is absent from these plutons and rare to the AMCG suite in general. A combination of arc-like whole-rock geochemistry, chondrite uniform reservoir-like Nd-Sr-Pb isotopes, and ocean island basalt (OIB)-like zircon trace element chemistry suggests that the complex was derived from a partial melt of OIB-like mantle and interacted with metasomatically enriched lithospheric mantle. The enriched lithospheric mantle signature, combined with the long ~160 m.y. duration of magmatism in the region, is consistent with a period of protracted convergent tectonism.

Colorado

The importance of nodal plane orientation diversity for earthquake focal mechanism stress inversions

Inversions of earthquake focal mechanisms are among the most accessible and reliable methods for determining crustal stress. However, the use of this method varies widely, and assumptions that underpin it are often violated, potentially compromising stress estimates. We investigate the consequences of violating the little-studied assumption that the focal mechanisms have diverse orientations. Our approach is to employ data-informed synthetic mechanisms, with nodal plane orientations defined by recent earthquake lineaments in the Midland Basin, western Texas, and rakes consistent with slip in the mapped stress field. Using both the traditional stress inversion method that assumes constant shear stress magnitudes on the causative faults as well as a recently published variable shear stress method, we show that low fault plane diversity can cause maximum horizontal stress ( S Hmax ) orientation and relative principal stress magnitude (faulting regime) estimates to differ markedly from the true values. This problem is compounded for catalogs with even modest amounts of noise (≤15°) or few (e.g., 20) mechanisms. Significantly, traditional approaches for quantifying uncertainty such as the bootstrap can severely underestimate the true uncertainty under these circumstances. To remedy this, we provide simple tools to quantify nodal plane orientation diversity and stress inversion reliability.

Geological Society of London Special Publications

Stormflow chemistry in the Santa Ana River below Prado Dam and at the diversion downstream from Imperial Highway, southern California, 1995-98

The Santa Ana River drains about 2,670 square miles of the densely populated coastal area of southern California, near Los Angeles. Almost all the flow in the river, more than 200,000 acre-feet annually, is diverted into ponds where it infiltrates and recharges underlying aquifers. About 2 million people are dependent on these aquifers for water supply. Stormflow in the Santa Ana River is considered a source of "high-quality" water suitable for use as a source of ground-water recharge. To test this assumption, stormflow samples were collected at two locations--below Prado Dam and at the diversion point downstream from Imperial Highway--for 12 winter storms between 1995 and 1998. Nitrate concentrations decreased during stormflow from a median concentration of 7.8 milligrams per liter in base flow to concentrations less than 1 milligram per liter in some large storms. Concentrations of chemically reduced forms of nitrogen (nitrite, ammonia, and organic nitrogen) increased during stormflow and are the predominant forms of nitrogen in large stormflows. Dissolved organic carbon (DOC) concentrations increased from a median concentration of 4.6 milligrams per liter in base flow to more than 20 milligrams per liter in some stormflows. Concentrations of DOC were especially high during the first storm of the rainy season, and large increases in DOC concentrations were measured even as a result of small early season storms that did not cause large increases in streamflow. DOC present during early season stormflow had less ultraviolet absorbance at 254 nanometers (UV 254 ) per unit of carbon than did DOC from late season stormflows. DOC in water held in storage behind Prado Dam had the highest UV 254 absorbance per unit of carbon. Maximum pesticide concentrations in stormflow did not exceed U.S. Environmental Protection Agency Maximum Contaminant Levels. Most pesticide concentrations were less than 1 microgram per liter and less than the detection limits obtained using standard drinking water analyses. Increases in concentrations of pesticides such as diazinon, malathion, and chlorpyrifos in stormflow result from runoff from urban areas downstream from Prado Dam. In general, large late season stormflows have the most pesticide detections of all stormflows sampled. Concentrations of methyl tert-butyl ether (MTBE), a gasoline additive, during base flow were as high as 0.9 microgram per liter and concentrations decreased during stormflow. Like pesticides, the concentrations did not exceed the U.S. Environmental Protection Agency Maximum Contaminant Levels for MTBE.

California

Turbidite correlation for paleoseismology

Marine turbidite paleoseismology relies on the assumption of synchronous triggering of turbidity currents by earthquake shaking to infer rupture extent and recurrence. Such inference commonly depends on age dating and correlation of the physical stratigraphy of deposits carried by turbidity currents (i.e., turbidites) across great distances. Along the Cascadia subduction zone, which lies offshore the Pacific Northwest, USA, turbidite facies in core photographs, X-ray computed tomography images, and magnetic susceptibility (MS) data exhibit differences in character over relatively short distances, which implies that not all deposits can be correlated with confidence. Thus, subjective correlation based on expected similarity over great distances and weak age constraints does not independently support paleoseismic models. We present a new method for correlating turbidites along the Cascadia margin that can yield a more objective and repeatable stratigraphic framework to underpin earthquake recurrence. We use dynamic time warping to correlate MS logs and measure correlation coefficients of core pairs to evaluate correlation strength. We then compare these measures to a distribution of correlation coefficients of randomly generated turbidite sequences and find that only a small number of core pairs can be correlated more confidently than randomly stacked turbidites. This methodology promises a more robust correlation strategy for future stratigraphic studies.

Oregon, Washington

Computing flow-field distortion coefficients from well-construction and formation properties

Direct measurements of groundwater velocity made with borehole flowmeters in screened wells must be compensated for the effects of flow-field distortion (also known as borehole acceleration). A theoretical equation developed by Drost et al. (1968) and simple inputs describing hydraulic properties of well construction and geologic formation were programmed into an Excel workbook to facilitate computation by groundwater-flowmeter users. Tables describing the physical and hydraulic properties for well constructions and gravel pack media are provided with an example to facilitate use of the workbook. Groundwater flowlines converge or diverge as they pass from a geologic formation, through a gravel pack and well screen. The extent of flowline convergence or divergence and the value of the flow-field distortion coefficient is related to the relative changes in hydraulic conductivity of the well screen, gravel pack, and geologic formation. Convergence or divergence is accompanied by acceleration or deceleration of groundwater. Direct measurements of groundwater velocity at the center of the monitoring well can be adjusted to provide a more accurate estimate of velocity in the formation by applying a correction for flow-field distortion. Variables required to compute the flow-field distortion coefficient include the hydraulic conductivity of the gravel pack, well screen, and the geologic formation surrounding the well screen; the borehole radius, and the inside radius and outside radius of the well screen.

Groundwater

Assessment of water chemistry of the Coconino aquifer in northeastern Arizona

The Coconino aquifer was investigated as a potential groundwater resource for the Hopi Tribe and Navajo Nation in northeastern Arizona. Basic groundwater chemistry, including major ions, total dissolved solids, and selected trace metal concentrations, are presented and analyzed to characterize the Coconino aquifer. The geochemical compositions of groundwater are associated with changes in geology and groundwater movement and are compared to drinking-water standards to determine suitable areas for potential groundwater resource development. Dissolved-solids concentrations in much of the Coconino aquifer water were higher than the U.S. Environmental Protection Agency’s secondary drinking-water standard of 500 milligrams per liter (mg/L) due to a buried halite body in the southeastern part of the study area. However, trace metal concentrations were generally low. Groundwater may need to be treated for high dissolved-solids concentrations before it is suitable for use as a resource for the Hopi Tribe and Navajo Nation.

Arizona

The feasibility of using lidar-derived digital elevation models for gravity data reduction

Gravity data require submeter elevation accuracy for data processing, and differential global navigation satellite system (dGNSS) equipment is commonly used to acquire three-dimensional positional data to achieve such accuracy. However, lidar (light detection and ranging) data are commonly used to develop digital elevation models (DEMs) of Earth’s surface. Therefore, using elevations from lidar-derived DEMs for gravity-data acquisition and reduction may improve field efficiency and reduce cost. This study examines the feasibility of using DEMs for gravity-data reduction by comparing dGNSS elevation data from 435 gravity stations in Michigan, Wyoming, and Colorado with their respective DEM elevations. The results show that the average difference between DEM and dGNSS elevations is 13 centimeters (cm) and that 93 percent of those differences are less than 50 cm, even in areas with steep terrain. Because an elevation discrepancy of 50 cm corresponds to an error of roughly 0.1 milligals (mGal) in the simple Bouguer gravity anomaly, the results suggest that lidar-derived DEMs are a viable source for acquiring the elevation data needed to process gravity data, thus improving both the cost and efficiency of data collection for regional surveys where an accuracy of less than 1.0 mGal is desired.

Open-File Report

A method to obtain remotely sensed grain size distributions from nonplanar granular deposits

Constraining the grain size distribution of granular deposits with complex surfaces is difficult with existing approaches. Field and laboratory techniques are time consuming and limited by the maximum grain size that laboratories can accommodate. In this study, we present a new method to identify the coarse fraction of the grain size distribution at a debris-flow fan deposit surveyed with terrestrial laser scanning (TLS) in Glenwood Canyon, Colorado, USA. This method is a novel grain segmentation algorithm developed for application to point cloud data of deposits with complex surfaces and angular grains ranging in size from centimeters to a meter. This approach combines an existing random forest machine learning method with a novel iterative clustering algorithm. We compared the grain size distribution from our algorithm with a Wolman pebble count conducted in the field, and found a root mean squared error of less than 2 cm from the 5th to 95th percentile of the grain size distribution of grains ranging from cobble to boulder sized (6.3–78 cm in our application). Finally, we compared our new algorithm with an existing open-source grain segregation algorithm, and our method outperformed the selected alternative when applied to the debris-flow deposit point cloud.

Colorado

Late Jurassic igneous rocks in south-central Arizona and north-central Sonora: Magmatic accompaniment of crustal extension

In Middle Jurassic time, the region of south-central Arizona and north-central Sonora was part of a continental magmatic arc. In early Late Jurassic time, this magmatic arc gradually gave way to a extensional regime. Late Jurassic rifting was accompanied by magmatism, typically small in volume relative to the preceding arc phase, and with mildly alkaline compositions. These igneous rocks, the 158- to 146-Ma Ko Vaya Suite, make up much or most of the Comobabi, Artesa, Quijotoa, and Brownell Mountains and Sierra del Cobre. The bimodal Ko Vaya Suite constitutes volcanic to shallow plutonic complexes comprising chiefly trachyandesite and volcanic wacke; monzodiorite; rhyolite porphyry; distinctive, compositionally and texturally heterogeneous, quartzpoor granite (the Ko Vaya Granite); A-type perthite granite and quartz syenite; aphyric intrusive rhyolite; and locally abundant hematite veins. Alteration, particularly potassic alteration, is widespread. Minimally altered samples of granite and quartz syenite have the composition of trachyte or trachydacite and alkali rhyolite. The Ko Vaya Suite is nonconformably overlain by the latest Jurassic Sand Wells Formation, approximately correlative with the Glance Conglomerate, the basal unit of the Bisbee Group. The Ko Vaya Suite is in some ways analogous to the coeval Independence dike swarm of eastern California, but less diffuse. We infer that the Ko Vaya Suite represents especially intense or focused Late Jurassic extensional magmatism.

Arizona, Sonora

Tectonic controls on volcanism and associated hydrothermal activity in a sediment-dominated mid-ocean ridge; Escanaba Trough

Mid-ocean ridges, the Earth's most extensive volcanic system, exhibit unique characteristics in sediment-dominant environments. Thick sediment cover insulates the crust and channels fluid along pathways that can lead to the formation of distinct crustal alteration patterns, exceptionally large mineral deposits, and specialized chemosynthetic ecosystems. This study presents an interdisciplinary investigation into the tectonics of the Escanaba Trough, a heavily sedimented axial valley at the southern Gorda Ridge in the Northeast Pacific Ocean. A primary challenge in such environments is overcoming the masking effect of thick sediments on basement structures that control magmatic and hydrothermal activity. We address this by employing three-dimensional (3D) magnetic modeling of high-resolution near-seafloor magnetic data collected by an autonomous underwater vehicle (AUV). The 2022 surveys with AUV Sentry provided data for 3D magnetic susceptibility models, refining our understanding of the geometry of sub-sediment laccoliths/saucer-shaped sills and hydrothermal alteration. In conjunction with a new 1:100,000 scale lithostratigraphic map, we outline the tectonic controls on the emplacement of Escanaba Trough's three main volcanic centers, characterize the geometry of its spreading segments, and provide volumetric data on the distribution of sub-sediment volcanism in the southern Gorda Ridge.

Escanaba Trough, Pacific Ocean

Future water constraints on United States lithium mining under climate change

Lithium is necessary for low-carbon technologies that combat climate change, but lithium extraction is water-intensive. Changes in temperature and precipitation arising from climate change are altering water distribution, which could further strain supplies for new mines and industry, farms, and households. Here we explored how climate change, water use, and mining siting could impact lithium mining in the United States. We analyzed whether there would be sufficient water available to support the single existing and 22 proposed U.S. lithium mines at mid-century under four socioeconomic-climate scenarios and five climate models. Though dependent on socioeconomic-climate scenario, climate model, and lithium deposit type, available water supply in most subbasins would likely be unable to support new mines’ water demands, or even non-mining water demands from other sectors. Water scarcity could hinder the ability of the United States to produce enough lithium to meet domestic demand thereby necessitating higher imports.

conterminous United States

Complex landslide patterns explained by local intra-unit variability of stratigraphy and structure: Case study in the Tyee Formation, Oregon, USA

Lithology and geologic structure are important controls on landslide susceptibility and are incorporated into many regional landslide hazard models. Typically, metrics for mapped geologic units are used as model input variables and a single set of values for material strength are assumed, regardless of spatial heterogeneities that may exist within a map unit. Here we describe how differences in bedding thickness, grain size, inferred uniaxial compressive strength, and bedding dip control the inherent susceptibility of slopes to deep-seated failure within a single mapped geologic unit - the Tyee Formation of Oregon, USA. The Tyee, which covers over 15,000 km2 and underlies much of the Oregon Coast Range, comprises gently folded alternating beds of sandstone and siltstone deposited as turbidites, forming a 2-km thick Eocene submarine fan which has been uplifted and exhumed through the Cenozoic. Deep-seated landslides are widespread in the Tyee, but form a complex spatial pattern such that landslide density ranges from 0 to 24% of the total landscape area. These slides are often extensive and sufficiently deep to reduce local hillslope gradients, resulting in a strong negative correlation between landslide density and mean local slope. Mean annual precipitation and predicted strong ground motions from Cascadia earthquake scenarios also fail to explain the spatial distribution of deep-seated landslides. Consequently, landslide stability models, which are strongly influenced by landscape slope, pore-water pressure, and seismic acceleration, yield landslide susceptibility maps which are broadly anti-correlated with mapped deep-seated landslide density. Through a multivariable linear regression model, we show that much of the variance in deep-seated landslide density can be explained by variability of intra-unit stratigraphic and structural characteristics, which we measure at 128 sites across two study areas totaling ∼3000 km2. Our results suggest bedding dip is only weakly correlated to landslide density, but strongly influences landslide failure style. Subtle increases in bedding dip, even in the gently folded Tyee Formation, result in a substantially higher likelihood of a landslide being cataclinal, or parallel to bedding. Overall, we find a slight majority of landslides fail within these cataclinal slopes, and that these landslides tend to be larger than non-cataclinal landslides. We also show that the lithological and structural properties that influence landslide susceptibility are distinct for these two populations of landslides. Our results demonstrate how localized, intra-unit, geologic variability can exert strong control on landslide susceptibility and failure style. This suggests that in some locations, landslide hazard models could be significantly improved by incorporating detailed, spatially variable, geologic properties rather than relying solely on generalized geologic map units.

Oregon

Wetlands, groundwater and seasonality influence the spatial distribution of stream chemistry in a low-relief catchment

Evaluating stream water chemistry patterns provides insight into catchment ecosystem and hydrologic processes. Spatially distributed patterns and controls of stream solutes are well-established for high-relief catchments where solute flow paths align with surface topography. However, the controls on solute patterns are poorly constrained for low-relief catchments where hydrogeologic heterogeneities and river corridor features, like wetlands, may influence water and solute transport. Here, we provide a data set of solute patterns from 58 synoptic surveys across 28 sites and over 32 months in a low-relief wetland-rich catchment to determine the major surface and subsurface controls along with wetland influence across the catchment. In this low-relief catchment, the expected wetland storage, processing, and transport of solutes is only apparent in solute patterns of the smallest subcatchments. Meanwhile, downstream seasonal and wetland influence on observed chemistry can be masked by large groundwater contributions to the main stream channel. These findings highlight the importance of incorporating variable groundwater contributions into catchment-scale studies for low-relief catchments, and that understanding the overall influence of wetlands on stream chemistry requires sampling across various spatial and temporal scales. Therefore, in low-relief wetland-rich catchments, given the mosaic of above and below ground controls on stream solutes, modeling efforts may need to include both surface and subsurface hydrological data and processes.

Michigan

Chemostratigraphy of the Cretaceous Hue Shale in Arctic Alaska: Exploring paleoceanographic controls on trace element enrichment, organic matter accumulation, and source-rock evolution

We document chemostratigraphy in an outcrop of late Albian to early Campanian (∼103–82 Ma) marine source rocks to better understand paleoenvironmental controls on trace element (TE) enrichment and organic matter accumulation in the distal Colville foreland basin of Arctic Alaska and how those drivers are linked to arc volcanism and successions of Cretaceous oceanographic and climatic biogeochemical events. This unique, 113-m-thick section of Cretaceous Hue Shale deposited during a series of previously undocumented Arctic Cretaceous oceanic anoxic events (Lease et al., 2024) is the only known exposure of thermally immature (0.48–0.52% R o , random vitrinite reflectance) Hue Shale in Arctic Alaska. Strata comprise mainly clay-rich mudstone with elevated total organic carbon (TOC) and hydrogen index values reaching 26.3 wt% (mean = 7.5 wt%) and 689 mg hydrocarbon (HC)/g TOC (mean = 385 mg HC/g TOC), respectively. Maceral composition consists predominantly of fluorescent amorphous organic matter, with abundant brightly fluorescent alginite, including Tasmanites , acritarchs, and Leiosphaeridia . Discrete layers of volcanic ash (preserved as bentonite) are present throughout the section and provide quantitative age control based on U–Pb dates. Chemostratigraphic trends are investigated to advance our understanding of local oceanographic conditions and controls on stratigraphic and temporal heterogeneity of Brookian source rocks. Concurrent sedimentary enrichment in Mo, U, V, Pb, and Cu across the Albian–Cenomanian boundary of the exposed basal gamma-ray zone, may reflect anoxic to euxinic benthic redox conditions favoring organic matter accumulation and preservation. Fluctuating degrees of anoxia-euxinia are inferred throughout the overlying Hue Shale succession, reflected by varying patterns of TE enrichment and TE–TOC covariation. Elevated C org /P molar ratios (>250) across most of the section, with several values exceeding 690, signify that enhanced biological productivity is sustained throughout deposition. Enhanced productivity, recorded by both C org /P and excess Ba, also parallels increases in source rock richness (elevated TOC and S 2 values) during the late Albian–early Cenomanian and late Cenomanian – Turonian. Enhanced productivity and variations in oceanic circulation/stratification likely both drove changes in benthic redox conditions that favored organic carbon accumulation and preservation. Increased continental arc volcanism (e.g., Okhotsk–Chukotka volcanic belt) and High Arctic Large Igneous Province magmatic eruptions throughout the Cretaceous, inferred to have influenced nutrient cycling and local aqueous nutrient availability, also have been invoked as potential drivers of organic carbon burial and source-rock development across the sedimentary sequence. Results presented here document the organic-rich and oil-prone source-rock quality of the Hue Shale in the distal part of the Colville foreland basin and bolster the potential for a Cretaceous petroleum system beneath the eastern North Slope.

Alaska

Formation of the Mount Weld rare earth deposit, Western Australia: Geochronology constraints

Constraining the age of protracted chemical weathering in stable cratonic areas that may form thick regoliths and the potential enrichment of various elements is challenging. Economic deposits of aluminium, iron, copper, nickel, cobalt, niobium, and rare earth elements (REEs) form in this manner. Determining the age of formation can provide key information for exploration of similar deposits as well as to better constrain paleoclimatic conditions. This study describes our effort to constrain the age of formation of the Mount Weld deposit, a world-class carbonatite-derived REE laterite deposit. We utilize multiple geochronological techniques on different minerals. The oldest dates, ranging from ca. 100 to 50 Ma, were from laser ablation ICPMS, Lu-Hf dating of churchite, a heavy REE phosphate mineral formed by mineral saturation in groundwater. Growth bands on individual minerals show a younging outwards. 40 Ar/ 39 Ar geochronology of cryptomelane, a potassium-bearing manganese oxide mineral, yielded ages ranging from ca. 40 to 26 Ma. Similarly, (U–Th)/He geochronology of goethite yielded ages from ca. 45 to 19 Ma.

Mount Weld deposit