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Inset groundwater-flow models for the Cache and Grand Prairie Critical Groundwater Areas, northeastern Arkansas

The water resources in the Mississippi alluvial plain, located in parts of Missouri, Kentucky, Tennessee, Mississippi, Louisiana, and Arkansas, supports a multibillion-dollar agricultural industry that relies heavily on pumping of groundwater for irrigation of crops and aquaculture. The primary source of groundwater for agricultural-related pumping is the Mississippi River Valley alluvial aquifer, which has declined in storage for decades; secondary groundwater sources include the middle Claiborne aquifer and Wilcox aquifer system. Two areas in northeastern Arkansas that lie within the Mississippi alluvial plain, part of the Cache and Grand Prairie regions, have been designated as Critical Groundwater Areas owing to decades of groundwater declines that resulted from past and current water use. The multidisciplinary Mississippi Alluvial Plain project, led by the U.S. Geological Survey, and funded by their Water Availability and Use Science Program, included objectives to develop numerical groundwater models in focus regions, including the part of the Cache and Grand Prairie regions of northeastern Arkansas. Two inset models were developed using the child model capabilities of MODFLOW 6, the U.S. Geological Survey’s Modular Hydrologic Model simulation software. Both models, called the Cache model and Grand Prairie model, simulated the groundwater system and surface-water/groundwater interactions for the Mississippi River Valley alluvial aquifer and underlying Tertiary-age aquifers and confining units to the Midway confining unit. Each model was spatially discretized into 500-meter x 500-meter orthogonal cells on a grid with 5-meter constant-thickness vertical layers that represented the Mississippi River Valley alluvial aquifer and increasing thickness layers for the aquifers and confining units below the alluvial aquifer. The Cache and Grand Prairie models were calibrated with the PEST++ iterative ensemble smoother Version 5 and employed high dimensional parameterization schemes of 13,740 and 30,436 parameters, respectively. The Cache mean absolute residual for groundwater-level observations within each model domain for the priority well was 1.58 meters. Grand Prairie mean absolute residuals for the alluvial aquifer and middle Claiborne aquifer groundwater-level observations were 2.71 and 10.78 meters, respectively. The groundwater budgets for the Cache and Grand Prairie models were characterized by substantial outflows to irrigation wells, which constituted about 52 and 54 percent of all outflows, with the primary source of water to those wells being releases from unconfined aquifer storage.

Arkansas

Evidence of nitrate attenuation in intertidal and subtidal groundwater in a subterranean estuary at a Cape Cod embayment, East Falmouth, Massachusetts, 2015–16

Nitrogen dynamics in intertidal and nearshore subtidal groundwater (subterranean estuary) adjacent to the Seacoast Shores peninsula, Falmouth, Massachusetts, were investigated during 2015–16 by the U.S. Geological Survey. The peninsula is a densely populated residential area with septic systems and cesspools that are substantial sources of nitrogen to groundwater. The study area is in the Eel River, an estuarine saltwater embayment connected to the ocean adjacent to the western shore of the peninsula, that was the subject of an earlier study by Colman and others (2018, https://doi.org/10.3133/sir20185095 ) on nitrogen transport and transformations in groundwater between onshore and offshore locations. The previous study documented the distribution of nitrate concentrations and nitrate attenuation reactions in fresh groundwater beneath the peninsula and the estuary. The current study extended those observations with more detailed sampling and analysis of shallow groundwater from wells near discharge sites beneath the estuary. The current field investigation included sampling of existing wells and installation and sampling of clusters of wells and temporary sampling points in the subterranean estuary, including (1) shallow transects 0.3 to 1.2 meters (m) deep extending from 1 to 13.5 m offshore and (2) deeper wells (from 1.83 to 4.88 m deep) extending from 4.3 to 14.3 m offshore. Measurements of hydraulic-head gradients 2–5 m below the sediment/water interface in the intertidal and nearshore subtidal zones indicated that groundwater flow generally was upwards (towards the estuary) under all tide conditions in October 2016. The magnitude of the gradient was greatest during low tide conditions, indicating that groundwater discharge likely decreased during high tides. Measurements of specific conductance in shallow groundwater in the subterranean estuary in three transects perpendicular to shore were consistent with the existence of saltwater flow cells (infiltration of overlying saline water, mixing with fresh groundwater, and discharge to the overlying saline water) in the intertidal and nearshore subtidal regions. The size of these flow cells was variable in space and time and dependent on the elevation of the tide (spring or neap). At this location in the Eel River subterranean estuary, and offshore to at least 13.5 m, offshore flow of fresh groundwater apparently prevented a deeper saltwater wedge from discharging to the surface. Nitrate concentrations in shallow groundwater (30 to 122 centimeters [cm] depth) were variable in space and time, ranging from not detectable to 600 micromoles per liter (μmol/L) (8.4 milligrams per liter as N), and were highest in June 2016 at depths from 61 to 122 cm below the sediment/water interface and from 4 to 9 m offshore. Nitrate generally was not detectable in saline shallow groundwater at 30-cm depth or at any depth from 30 to 122 cm from 10 to 13.5 m offshore. Dissolved oxygen concentrations were suboxic (less than 16 μmol/L) in 60 percent of the sampled subterranean groundwater beneath the intertidal and subtidal zones. In the remaining sites, the range of dissolved oxygen concentrations was from 18 to 272 μmol/L and the median concentration was 43 μmol/L. Evidence for microbial nitrate reduction (denitrification and possibly anammox) was provided by the distribution of the reaction product nitrogen gas (excess N 2 , or N 2MIC ), as determined from analysis of the dissolved nitrogen gas and argon gas (Ar) concentrations in groundwater samples. Excess nitrogen gas provided evidence for nitrate reduction in shallow groundwater below the subtidal and, to a lesser extent, intertidal zones adjacent to the Seacoast Shores peninsula. These zones, where evidence for nitrate reduction was detected, were in fresh and brackish groundwater near subtidal or intertidal saltwater cells where discharging fresh groundwater mixed with infiltrating saline water. Infiltrating seawater may have supplied organic carbon, one of several potential electron donors that are required for denitrification. Other potential electron donors, such as organic carbon, iron, manganese, hydrogen, methane, ammonium, elemental sulfur, or sulfide phases, may have been supplied by the estuarine sediments. Drainage from surface runoff near the shore also may have supplied organic carbon to fresh groundwater near the intertidal saltwater cell. The highest amounts of nitrate converted to excess nitrogen gas were estimated to be in the range of 230 to 430 μmol/L in nearly fresh groundwater near the subtidal saltwater cell at depths of 61 to 122 cm below the sediment/water interface and from 10 to 13.5 m offshore. Evidence of denitrification within 10 m of the shore was sparse (generally limited to less than 50 μmol/L of N 2 -N) despite the presence of high nitrate concentrations. The spatial distribution of estimated nitrate reduction in the intertidal and nearshore subtidal fresh and brackish groundwater may be related to local variability in the distribution of reactive electron donors in those zones. Variations in the amount of nitrate reduction to nitrogen gas were not clearly related to potential aqueous electron donors such as dissolved organic carbon, nor to potential reaction products such as alkalinity, but may have been controlled by combinations of aqueous and solid-phase reactants. The distribution of relatively shallow fresh groundwater containing nitrate could indicate potential nitrate discharge areas in the lower intertidal zone and uncertain locations farther offshore; however, the data did not extend all the way to the sediment/water interface or to the offshore freshwater limit. This study confirmed substantial loss of nitrate from some of the fresh and brackish groundwater in shallow subestuarine sediments prior to discharge but did not quantify how much nitrate eventually discharged to the estuary.

Massachusetts

Land-use interactions, Oil-Field infrastructure, and natural processes control hydrocarbon and arsenic concentrations in groundwater, Poso Creek Oil Field, California, USA

Like many hydrocarbon production areas in the U.S., the Poso Creek Oil Field in California includes and is adjacent to other land uses (agricultural and other developed lands) that affect the hydrology and geochemistry of the aquifer overlying and adjacent to oil development. We hypothesize that the distributions of hydrocarbons and arsenic in groundwater in such areas will be controlled by complex interactions between mixed land uses, oil-field infrastructure, and natural processes. In 2020–2021, samples of groundwater and surface water were collected and analyzed for a large suite of inorganic and organic chemicals and isotope and gas tracers to test this hypothesis. Those data are supplemented with ancillary data on historical geochemistry, hydrology, geology, and oil-field infrastructure. Hydrocarbons in groundwater (e.g., methane through pentane gases and benzene) are associated with natural processes (e.g., fault offsets or transition in sediment depositional environment) and oil-field infrastructure (e.g., fluid-migration pathways associated with uncemented annulus in oil wells or unlined pits). Arsenic concentrations >10 μg per liter (μg/L; maximum concentration 12.9 μg/L) are associated with natural processes in old, high-pH groundwater, and more recent recharge of water from natural and/or engineered recharge processes. Along the southwest margin of the oil field, pumping for drinking-water and irrigation supplies in combination with engineered groundwater recharge produce a depression in groundwater elevations where groundwater with elevated sulfate concentrations from agricultural areas and groundwater with hydrocarbons from the oil field mix to produce a zone of sulfate reduction that removes hydrocarbons and arsenic from groundwater but produces elevated sulfide (S 2- ) concentrations (maximum concentration 29 mg per liter, mg/L). In this study, multiple approaches were required to resolve the overlapping effects of land uses, oil-field infrastructure, and natural processes on the distributions of hydrocarbons and arsenic in groundwater. The combined use of geographic, historical, physical, chemical, isotopic, and other information to constrain processes could be a useful approach for studies in other hydrocarbon-production areas. This is particularly important where land uses affect aquifer hydrology to an extent that causes mixing of groundwaters with different chemical compositions.

California

Hydrogeologic mapping and three-dimensional geologic modeling of glacial deposits in a multicounty area of southeastern Michigan, northeastern Indiana, and northwestern Ohio

The glacial deposits underlying southeastern Michigan, northeastern Indiana, and northwestern Ohio are a substantial source of water to communities, agriculture, and industry in the region. Previous efforts to characterize aquifer materials in the area cited a need for additional information about the underlying hydrogeologic characteristics and related groundwater availability as well as improved mapping of the extent and properties of the glacial deposits. Recent U.S. Geological Survey multi-State compilations of water-well drilling records have greatly increased access to high-resolution geologic data, particularly in glacial depositional environments. This study by the U.S. Geological Survey, in cooperation with the Ohio Environmental Protection Agency, uses processed data from the State-managed collections of well records to characterize the glacial deposits in the study area using two methods. The first method creates two-dimensional maps of basic hydrogeologic information commonly required for assessments of groundwater availability, including (1) total thickness of glacial deposits, (2) total thickness of coarse-grained deposits, (3) specific-capacity-based transmissivity and hydraulic conductivity, and (4) texture-based estimated equivalent horizontal and vertical hydraulic conductivity and transmissivity. The second method builds a hydrogeologic framework of the complex glacial aquifer through construction of a volumetric geologic model by using three-dimensional kriging. Results of the volumetric model indicate that aquifer materials are primarily concentrated in the western parts of the study area near the Indiana-Ohio border. Coarse-grained sediments are also present as surficial deposits in the north of the study area where intermixing glacial advances created complex distributions of unconsolidated deposits. Two-dimensional maps of hydrogeologic properties support the volumetric model, showing thicknesses of coarse-grained deposits that reach up to 250 feet in the western sections of the study area and progressively thin to near absence in the east. Visualization of the aquifer materials with a volumetric model generally shows a highly discontinuous distribution of coarse- and fine-grained materials, with no clearly defined boundaries to delineate the extent of the aquifer. Comparisons of cross sections derived from the volumetric model with existing published maps support previous near-surface hydrogeologic interpretations while filling gaps where data are sparse, particularly in deeper parts of the aquifer. Both the two-dimensional maps and the volumetric model provide data that can directly inform assessments of groundwater availability, in addition to having future applications to studies of groundwater flow and transport.

Indiana, Michigan, Ohio

Ground-water quality atlas of Oakland County, Michigan

The U.S. Geological Survey (USGS), in cooperation with Oakland County Health Division (OCHD), collected 140 water samples from 38 wells in Oakland County during 1998 to better understand ground-water quality. OCHD had observed temporal variations in concentrations of various constituents, so two additional sets of samples were collected to evaluate potential short-term variability related to sample collection procedures and long-term seasonal variability. Replicate samples from 28 wells were analyzed in the Michigan Department of Environmental Quality (MDEQ) Drinking Water Laboratory to compare MDEQ’s analytical results to those obtained from the USGS National Water Quality Laboratory. Several additional databases describing population, land use, water supply, soils, geology, and flows of ground water and surface water are presented in the first part of the report to assist in interpreting the water-quality data. Maps created from these databases are provided in the first portion of the report as an extension of the study-area description. The U.S. Environmental Protection Agency (USEPA) has established Maximum Contaminant Levels (MCL) and Secondary Maximum Contaminant Levels (SMCL) for which samples were analyzed in this study. Water from the 38 wells sampled by the USGS did not exceed the SMCL or MCL for sulfate, fluoride, or nitrite. However, water from 26 wells exceeded the SMCL for iron, water from 12 wells exceeded the SMCL for manganese, and water from 12 wells exceeded the SMCL for dissolved solids. Water from two wells exceeded the MCL for nitrate, although nitrate concentrations in water from most wells was below the detection limit. Water from seven wells exceeded the SMCL for chloride, and water from all wells contained detectable concentrations of chloride. Water from five wells exceeded the MCL for arsenic, and most of the wells sampled contained detectable concentrations of arsenic. These five wells were identified from previous MDEQ analyses to have elevated arsenic concentrations, and were sampled to obtain additional chemistry information. Replicate samples were collected from 26 of the 38 wells for analysis at the MDEQ Drinking-Water Laboratory to compare the results with the USGS National Water Quality Laboratory. The results of the replicate analyses indicate close agreement between the laboratories, with mean differences for nitrate, chloride, and arsenic of 0.10 milligrams per liter (mg/L) as nitrogen, 6.8 mg/L, and 0.0008 mg/L, respectively between the USGS and MDEQ analyses. Potential health effects associated with ingesting nitrate, chloride, and arsenic are provided with the water-quality data, along with references for further information.

Michigan

Geologic map of the Guinevere Planitia quadrangle (V–30), Venus

This 1:5,000,000-scale geologic map of the Guinevere Planitia quadrangle divides the region into 15 geologic material units, defined using Magellan synthetic aperture radar (12.6-centimeter-wavelength radar system; 75 meters per pixel) datasets and including upland terrain units (2.4 percent of the surface area), plains materials units (59 percent), flow materials associated with named and unnamed eruptive centers (37.2 percent), small volcanic edifices, and impact crater materials (1.4 percent). Upland terrain units consist of tessera and lineated upland material, plains materials consist of Guinevere regional plains and Guinevere lineated and mottled plains, and flow materials consist of lobate flow material and plains-forming flow material. Specific lobate flows associated with Atanua Mons, Tuli Mons, Var Mons, and Uilata Fluctus are mapped separately. Other mapped units are impact crater material and small volcanic edifice. In addition to geologic units, we mapped linear features that show patterns of deformation or flow across the quadrangle. These consist of faults, wrinkle ridges, broad arches, channels, troughs, and flow direction indicators. The map region also contains several small volcanic features: shields, depressions, and craters. These, in combination with the plains, large volcanoes, and coronae, show the pervasive influence of volcanism across Venusian lowlands. The rims of nine identified impact features are delineated; large bright and dark haloes, which in some cases are associated with individual impact craters, are mapped as surficial mantling deposits. We documented spatial relationships using the stratigraphic and cross-cutting relationships of the quadrangle’s geologic units and features to provide a synthesis of the region’s geologic history. The upland terrain of the quadrangle indicates intense tectonic deformation and uplift. It is exposed as embayed remnants, typically within the plains, and represents the oldest geologic materials locally and across the region. Guinevere plains and the plains-forming flow unit appear to be assemblages of volcanic flows from multiple sources, including distinct coronae and corona-like structures. The temporal evolution of Guinevere lineated and mottled plains was likely protracted, with continued formation of small volcanic edifices over a long period. The morphologic and radar brightness characteristics of volcanoes in the region indicate their growth may have involved (1) multiple large-scale eruptive centers with recognizable spatial and temporal sequences, (2) extensive lava flow fields with a multitude of flows producing complex, overlapping patterns, and (3) numerous small volcanic edifices, including shields, domes, and cones. Although geologic patterns common to other regions of Venus are evident in the Guinevere Planitia quadrangle, local relative age relationships are inconsistent or unclear, preventing robust stratigraphic correlation. The mapping results do, however, indicate complicated local sequences of volcanic and tectonic activity.

Scientific Investigations Map

Explosive trachyte eruptions from the Al Efairia volcanic center in northern Harrat Rahat, Kingdom of Saudi Arabia

Harrat Rahat is an alkali basalt, continental, intraplate volcanic field located within the central-western part of the Kingdom of Saudi Arabia. The northern quarter of Harrat Rahat contains evolved volcanic products that achieve trachyte compositions (>60 weight percent SiO 2 ). Within the Al Efairia volcanic center, pyroclastic-flow and -surge deposits that reflect explosive trachyte volcanism (and minor exposed lava domes that reflect effusive trachyte eruptions) sit at the surface as the youngest expression of volcanic activity within this part of the Harrat Rahat volcanic field. Five trachyte deposits emplaced explosively have been identified within the Al Efairia volcanic center based on geologic mapping, petrography, geochemistry, and paleomagnetism. These units are the trachytes of Um Rgaibah, Gura 5, Gura 4, Al Efairia, and Al Qayf, in descending stratigraphic order. Here, we present 14 40 Ar/ 39 Ar analyses from four of these units, which yield eruption ages of 4.2±5.2 thousand years (ka) for the trachyte of Um Rgaibah, 79.7±1.6 ka for the trachyte of Gura 5, 84.3±1.6 ka for the trachyte of Gura 4, and 88.0±1.8 ka for the trachyte of Al Efairia. The eruption age of the trachyte of Al Qayf has been constrained to between 410.3±3.4 and 418.8±1.9 ka using paleomagnetic correlations and 40 Ar/ 39 Ar ages from overlying and underlying intermediate composition lava flows. Most of these trachytes have distinct geochemical compositions, petrographic characteristics, and directions of remanent magnetization. The exceptions are for the trachytes of Gura 4 and Gura 5, which overlap in their geochemical, petrographic, paleomagnetic, and geochronologic affinities. Based on these similarities, we interpret the trachytes of Gura 4 and Gura 5 to have erupted during a closely spaced (a few decades) time interval from the same magma batch but from craters that are >2 kilometers (km) apart. The eruption of the trachyte of Al Efairia at 88.0±1.8 ka is the result of a different magma batch that erupted a few thousand years prior to the trachytes of Gura 4 and Gura 5. The Al Efairia volcanic center is remarkably different from the Matan volcanic center located ~10 km to the north, which has also erupted young (<150 ka) trachytes. The Matan volcanic center has been shown to produce trachyte compositions only after eruption of basalt followed by intermediate lava flows, whereas only trachyte compositions have erupted within the Al Efairia volcanic center over this same time interval.

Al Efairia volcanic center, Harrat Rahat

Spatiotemporal variability of algal biomass and nitrate in Owasco and Seneca Lakes in the Finger Lakes Region, New York, in 2019

Cyanobacterial harmful algal blooms (CyanoHABs) have become increasingly common, threatening the security of water resources globally. The U.S. Geological Survey conducted high-resolution nearshore mapping surveys using boat-mounted multiparameter sondes and nitrate sensors during the summer and fall of 2019 on Owasco Lake and Seneca Lake, two lakes with documented CyanoHABs in the Finger Lakes region of New York State. Discrete sensor measurements and water-quality samples were collected at fixed points along survey routes and continuous data were generated at open-water monitoring platforms. This investigation examined whether water-quality information from nearshore surveys was representative of open-water conditions and if nearshore surveys could be used to identify areas with localized nearshore CyanoHABs and potential sources of nutrients not captured by tributary sampling. In addition to comparisons across methods, nearshore concentrations of nitrate and chlorophyll were evaluated relative to tributary outlets, cyanobacterial abundance and biovolume at discrete locations, and the locations of near-surface CyanoHABs that were designated as “confirmed with high toxins” by the New York State Department of Environmental Conservation. Nitrate and chlorophyll concentrations were comparable across methods for each lake, although concentration ranges were typically higher for nearshore mapping datasets than for nearshore discrete datasets. Nearshore surveys indicated areas of nitrate enrichment that varied temporally in both lakes. Orthophosphate was not routinely detected. Across methods, median chlorophyll concentrations were higher for the summer survey than for the fall survey in Owasco Lake. Nearshore chlorophyll concentrations varied more temporally in Owasco Lake than in Seneca Lake. Phytoplankton and cyanobacterial abundance and biovolume were about five times higher in Owasco Lake than in Seneca Lake. Cyanobacteria dominated the phytoplankton community in most samples, and Microcystis comprised the bulk of the cyanobacterial biovolume. The most abundant potential cyanotoxin-producing (specifically microcystins) genera were Microcystis , Synechococcus , Aphanocapsa , and Pseudanabaena . The cyanobacterial community composition was comparable between open-water monitoring platforms and nearshore samples. Microcystins were detected in seven survey samples from Owasco Lake, in one survey sample from Seneca Lake, and in one sample each from the open-water monitoring platforms on Owasco and Seneca Lakes that were collected about 7 days before the fall surveys. Microcystin detections were not consistently associated with high cyanobacterial cell counts or cyanotoxin-producing genera. Results from nearshore surveys were comparable to open-water monitoring platforms and discrete nearshore observations in the absence of nearshore or open-water CyanoHABs in these systems during the study. Patterns of nearshore concentrations of nitrate and chlorophyll from nearshore surveys may aid in the identification of areas with localized nitrate loading and shifts in phytoplankton abundance and community composition.

New York

Ground-water quality near an inactive landfill and sludge-spreading area, Tallahassee, Florida

Ground-water quality of a 120-acre area encompassing an inactive landfill southwest of Tallahassee, Florida, was assessed by installing and sampling 21 monitoring wells. Sludge from a municipal sewage-treatment plant was also applied to the land surface near the landfill site. Water samples were collected from the 21 monitoring wells from June 1987 through September 1990 and analyzed for concentrations of major ions, nitrogen species, trace metals, field measurements, and more than 140 organic constituents. Water quality in the Upper Floridan aquifer at the study site was compared to background water quality in other areas of Leon County. Ground-water quality of the study site was evaluated by the location of wells sampled in relation to the landfill and the sludge-spreading areas. Results of nonparametric statistical analysis indicated that potassium and nitrite plus nitrate as nitrogen concentrations in water samples from wells completed in the Upper Floridan aquifer at the study site were significantly different at the 5 percent probability level from those in samples from background wells completed in this aquifer in Leon County. Median potassium concentrations were 0.4 mg/L (milligrams per liter) in water from wells at the study site and 0.7 mg/L in water from background wells in Leon County. Median nitrite plus nitrate concentrations were 6.48 mg/L in water samples from wells at the study site and 0.51 mg/L in water samples from background wells. Graphical comparison of the water quality characteristics in water from six categories of wells; upgradient, landfill, adjacent to the landfill, downgradient onsite, downgradient offsite, and background Leon County, indicated that sodium, bicarbonate, sulfate, iron, manganese, and dissolved solids concentrations and specific conductance values were highest within the landfill. Upgradient and downgradient well categories include wells in areas affected by sludge spreading. Localized reducing conditions were indicated in a downgradient area by median iron concentrations of 930 and 30 ug/L (micrograms per liter) in samples from wells only 5 feet apart. Nitrite plus nitrate concentrations were lowest in water from wells in the landfill compared to water from the other categories. Concentrations of most trace elements and organic compounds were mostly below detection limits, although State maximum contaminant levels of 1 ug/L for benzene and vinyl chloride and 3 ug/L for tetrachloroethene were exceeded in 14 samples. Concentrations of sodium, potassium, chloride, sulfate, nitrite plus nitrate, total organic and ammonia nitrogen, and ammonia nitrogen in ground water were statistically analyzed in areas affected by sludge-spreading and other areas. Only nitrite plus nitrate and chloride concentrations were significantly different between the two areas. Median nitrite plus nitrate and chloride concentrations in sludge-spreading areas were 6.9 mg/L and 2.9 mg/L, respectively, compared to 1.1 mg/L and 1.8 mg/L in other areas.

Florida

Assessing spatial variability of nutrients, phytoplankton, and related water-quality constituents in the California Sacramento–San Joaquin Delta at the landscape scale—2018 high resolution mapping surveys

Executive Summary This study examined the abundance and distribution of nutrients and phytoplankton in the tidal aquatic environments of the Sacramento–San Joaquin Delta (Delta) and Suisun Bay, comprising three spatial surveys conducted in May, July, and October of 2018 that used continuous underway high frequency sampling and measurements onboard a high-speed boat to characterize spatial variation across the extent of the Delta. The method used involves simultaneously collecting information about the concentration and spatial distribution of all major nutrient forms with analogous information about the major classes of phytoplankton and associated water-quality conditions. The results showed substantial variation across space and time, providing an unprecedented snapshot of the dynamic environmental processes that shape the ways nutrients interact with and affect aquatic habitats in the Delta. The purposes of this study were to improve our understanding of how hydrodynamics, landscape features, and aquatic primary productivity interact to drive nutrient cycling and transport in the Delta and to provide insights into the underlying processes most directly responsible for the conditions at the time of this study, and thus into the range of conditions that may be expected following the wide array of prospective future changes to the Delta. One major anticipated change at the time of this study was the planned upgrade to the Sacramento Regional Wastewater Treatment Plant, but the study also informs our understanding of potential effects from other changes to the Delta, such as those caused by other nutrient-management actions, flow actions, large-scale wetland restoration, drought, flood, levee failure, and changes to water management. Nutrient loading is the primary driver of nutrient concentrations in the Delta, but several other major drivers interact to shape their distribution and effects: geomorphology, hydrodynamics, landscape features, and aquatic productivity. Hydrodynamics affect timescales of transport and dilution of nutrient loads in the Delta. During transit through the system, channel geometry, tidal mixing, and water exports affect hydrodynamics in diverse ways that influence water-residence and transport times, thereby markedly affecting the range of times during which natural internal cycling can alter nutrient concentrations and forms. Channel geometry and location shape tidal energy and river currents into these observed dynamics. Interactions with Delta aquatic landscapes such as herbaceous tidal marsh, submerged aquatic vegetation, and large expanses of intertidal or subtidal sediments (all highly productive landscapes) exert demand on available nutrient supplies but can also simultaneously transform and generate nutrients. Finally, while phytoplankton require nutrients to sustain production and thus are a potential nutrient sink, the amount and form of nutrients also can influence the occurrence of harmful algal blooms (HABs) that adversely affect aquatic organisms as well as affect the occurrence of beneficial algal blooms that result in production of algae that are favorable for imperiled Delta pelagic aquatic food webs. The surveys revealed a complex mosaic of spatial variation, with nutrient concentrations varying from near zero to well above concentrations considered eutrophic; nutrient concentrations were more often related to the extent of hydrologic transport and mixing than to specific geographic locations or to specific landscape features. Similarly, the surveys identified phytoplankton abundance ranging from near detection to the level of large phytoplankton blooms, with large variation in phytoplankton community composition. Although the study occurred during a period of low bloom activity, phytoplankton productivity appeared to be the strongest potential sink for inorganic nutrients in the Delta, indicating that it is a larger control on nutrient concentrations and distribution than previously understood. Cycling and transformation within the water column only appeared to substantially lower total nutrient concentrations at the longest estimated transport timescales. Contrary to expectations, we did not observe substantial nutrient depletion near landscape-scale features such as open-water habitats, submerged aquatic vegetation beds, extensive wetlands, or exposed sediments, indicating that these habitat types did not act as major sinks for nutrients in the Delta during these surveys. These results indicated that nutrient reduction efforts may have the greatest effect on pelagic phytoplankton productivity in the more productive reaches of the Delta and estuary, but these effects are unlikely to be magnified by changes to nutrient loss within the Delta over conceivable changes in flow conditions, Delta water management actions, or large-scale wetland restoration activities. Nevertheless, local processes were shown to cause substantial loss, and thus integrating of nutrient effects with other indicators of aquatic habitat conditions will help inform planning future actions at specific sites. Finally, we note that the primary contribution of this study was intended to be the survey data themselves. Aside from the results highlighted in this report, the surveys are a benchmark against which future environmental change may be evaluated, including changes to nutrient management or water exports, drought, large-scale wetland restoration, and climate change. Further, although we highlight some of the main findings from the surveys in this report, the necessarily limited scope precludes examination of many topics for which these surveys may be highly informative. To facilitate the utility of these data to stakeholders, managers, and researchers, we have released the data online (Bergamaschi and others, 2020) and created an online data exploration portal ( https:​//ca.water​.usgs.gov/​bay-​delta/​2018-​delta-​wide-​mapping-​surveys.html ) where users may query the surveys in a variety of ways to test hypotheses, examine relationships, assess spatial trends, and download data. The data exploration portal is intended to be an immersive experience that allows users to gain greater understanding of the complex interactions that shape Delta aquatic environments. This report is intended as a companion to the portal, allowing the reader to challenge and further explore the highlighted findings. This study was a collaboration between the U.S. Geological Survey and the Delta Regional Monitoring Program, with additional funding provided from U.S. Geological Survey Cooperative Matching Funds Program.

California

Eruptive history of northern Harrat Rahat—Volume, timing, and composition of volcanism over the past 1.2 million years

Harrat Rahat, one of several large, basalt-dominated volcanic fields in the western part of the Kingdom of Saudi Arabia, is a prime example of continental, intraplate volcanism. Excellent exposure makes this an outstanding site to investigate changing volcanic flux and composition through time. We present 93 40 Ar/ 39 Ar ages and 6 36 Cl surface-exposure ages for volcanic deposits throughout northern Harrat Rahat that, integrated with a new geologic map, define 12 eruptive stages. Exposed volcanic deposits in the study area erupted less than 1.2 million years ago (Ma), and 214 of 234 identified eruptions occurred less than 570 thousand years ago (ka). Two eruptions were in the Holocene, including a historically described basaltic eruption in 1256 C.E. and a trachyte eruption newly recognized as Holocene (4.2±5.2 ka). An estimated approximately 82 cubic kilometers (km 3 ; dense rock equivalent) of volcanic products can be documented as having erupted since 1.2 Ma, though this is a lower limit because of concealment of deposits older than 570 ka. Over the last 570 thousand years (k.y.), the average eruption rate was 0.14 cubic kilometers per thousand years (km 3 /k.y.), but volcanism was episodic with periods alternating between low (0.04–0.06 km 3 /k.y.) and high (0.1–0.3 km 3 /k.y.) effusion rates. Before 180 ka, eruptions vented from the volcanic field’s dominant eastern vent axis and from a subsidiary, diffuse, western vent axis. After 180 ka, volcanism focused along the eastern vent axis, and the composition of volcanism varied systematically along its length from basalt dominated in the north to trachyte dominated in the south. We hypothesize that these compositional variations younger than 180 k.y. reflect the growth of a mafic intrusive complex beneath the southern part of the vent axis, which led to the development of evolved magmas. Lastly, these new age data allow for a reassessment of the volcanic recurrence interval at northern Harrat Rahat. Based on available data, volcanism in northern Harrat Rahat over the last 180 k.y. is poorly described using a Poisson distribution with a single recurrence interval. Instead, data for northern Harrat Rahat are better described using a mixed exponential distribution that is applicable for volcanic systems characterized by two different eruptive states, where one state with a longer recurrence interval corresponding to periods of low eruption frequency and one state with a shorter recurrence interval corresponding to periods of high eruption frequency. The preferred model for northern Harrat Rahat over the last 180 k.y. uses a long recurrence interval of 4.0 k.y. and a short recurrence interval of 0.22 k.y.

Professional Paper

The EnMAP spaceborne imaging spectroscopy mission: Initial scientific results two years after launch

Imaging spectroscopy has been a recognized and established remote sensing technology since the 1980s, mainly using airborne and field-based platforms to identify and quantify key bio- and geo-chemical surface and atmospheric compounds, based on characteristic spectral reflectance features in the visible-near infrared (VNIR) and short-wave infrared (SWIR). Spaceborne missions, a leap in technology, were sparse, starting with the CHRIS/PROBA and EO1/Hyperion missions in the early 2000s, and providing spectroscopy data with limited spectral coverage and/or low data quality in the SWIR. Since 2019, several countries and agencies have successfully launched a number of spaceborne imaging spectroscopy systems into orbit or deployed them on the International Space Station (ISS) such as DESIS, PRISMA, HISUI, GF-5, EnMAP and EMIT. Among these recent missions, the German Environmental Mapping and Analysis Program (EnMAP) stands for its long-term development, sophisticated design with on-board calibration, high data quality requirements, and extensive accompanying science program. EnMAP was launched in April 2022 and, following a successful commissioning phase, started its operational activities in November 2022. The EnMAP mission encompasses global coverage from 80° N to 80° S through on-demand data acquisitions. Data are free and open access with 30 m spatial resolution, a high spectral resolution with a spectral sampling distance of 6.5 nm and 10 nm in the VNIR and SWIR regions respectively, and a high signal-to-noise ratio. In this paper, we aim to present the mission's current status, coverage, science capabilities and performance two years after launch. We show the potential of EnMAP for space-based imaging spectroscopy to operate in various environments, including high and low light levels, dense forests, Antarctic glaciers, and arid agricultural areas. EnMAP enables various applications in fields such as agriculture and forestry, soil compositional, raw materials, and methane mapping, as well as water quality assessment, and snow and ice properties. The results show that EnMAP's performance exceeds the mission requirements, and highlights the significant potential for contribution to scientific exploitation in various geo- and biochemical sciences. EnMAP is also expected to serve as a key tool for the development and testing of data processing algorithms for upcoming global operational missions.

Remote Sensing of Environment

Nonpoint-source pollutant discharges of the three major tributaries to Reelfoot Lake, west Tennessee, October 1987-September 1989

An investigation of the concentration and loads of nitrogen, phosphorus, and suspended sediment in storm runoff to Reelfoot Lake, in western Tennessee, was conducted from October 1987 through September 1989. Concentrations of selected herbicides also were defined. Reelfoot Lake, with a surface area of about 15,500 acres, is the largest natural lake in Tennessee and an important recreation and fisheries resource. Previous studies showed that the lake is hypereutrophic, a condition caused by high concentrations of nutrients in water and sediments discharged from the three principal tributaries (South Reelfoot Creek, North Reelfoot Creek, and Running Slough) to the lake. Pesticides, including herbicides, have been detected in the lake's bottom sediments. Storm runoff contributed about 87percent of the total water discharge of the three main tributaries to Reelfoot Lake. South Reelfoot Creek contributed about 4.7 tons per acre per year of suspended sediment, while North Reelfoot Creek contributed about 1.9 tons per acre per year. Running Slough contributed only about 0.31 ton per acre per year of suspended sediment. Most of the suspended sediment was transported by storm runoff between October and March. About 80 percent of the annual streamflow of the three tributaries occurs during these months. The North Reelfoot Creek basin contributed 8.2 pounds per acre per year of total nitrogen and 2.4 pounds per acre per year of total phosphorus. South Reelfoot Creek basin contributed about 6.5 and 1.3 pounds per acre per year of total nitrogen and phosphorus, respectively, while Running Slough basin contributions were 3.4 and 0.86 pounds per acre per year, respectively. The differences in nutrient yields appear to result from more row-crop agriculture and the relatively steeply sloping agricultural land in the North Reelfoot Creek basin. Ninety-one percent of the total nitrogen load and 95 percent of the total phosphorus load in the three streams was transported by storm runoff. Significant differences in the mean concentrations of nutrients in runoff were defined between the active agricultural months (April through September) and the inactive months (October through March). Storm-runoff samples were analyzed for II selected triazine herbicides. Alachlor and atrazine were the most commonly detected herbicides. Thirty-two percent of the samples contained detectable levels of alachlor and 93 percent of the samples contained detectable levels of atrazine. Ninety percent of the samples collected during the active agricultural months contained detectable leveki of alachlor and all 29 samples contained detectable levels of atrazine. Sixteen samples exceeded lifetime health-advisory levels for atrazine in drinking water (3 micrograms per liter); two samples collected from the April IS, 1988, storm at North Reelfoot Creek and South Reelfoot Creek contained 42 and 57 micrograms per liter of atrazine, respectively. Concentrations of the other nine triazine herbicides were generally less than the level of detection (0.1 microgram per liter).

Tennessee

Groundwater-level elevations in the bedrock aquifers of the Denver Basin aquifer system, Elbert County, Colorado, 2015–23

Water users in Elbert County, Colorado, rely on groundwater from bedrock aquifers in the Denver Basin aquifer system (upper Dawson, lower Dawson, Denver, Arapahoe, and Laramie-Fox Hills aquifers) for approximately half of their water uses. Withdrawals from the bedrocks aquifers have increased to meet the water use needs of expanding regional population growth and development. The U.S. Geological Survey, in cooperation with the Elbert County Board of County Commissioners, began a study in 2015 to monitor groundwater levels within Elbert County. The primary purpose of this report is to present a summary of groundwater levels measured during the study period (2015–23) and present results from statistical analyses of changes in groundwater-level elevations through time. Discrete groundwater levels were measured at 36 wells within Elbert County. Seven of those wells contained equipment to make and record continuous groundwater-level measurements at hourly intervals. All aquifers, except the lower Dawson aquifer, had only declining groundwater-level elevations in discrete measurements for wells with statistically significant trends. Of the eight statistically significant trends in the lower Dawson aquifer, two wells indicated increasing groundwater-level elevation from discrete measurements. The groundwater-level elevation trend medians in the upper Dawson, lower Dawson, Denver, Arapahoe, and Laramie-Fox Hills aquifers were −0.23, −0.66, −0.64, −0.39, and −0.63 feet per year, respectively, for discrete groundwater-level elevation measurements. Trends in continuous groundwater-level elevations were in agreement with statistically significant trends in discrete groundwater-level elevations for all wells. The groundwater-level elevation trend medians in this study, compared to the overall trends in a 2015−2018 study, both indicated declining groundwater-level elevations except in the upper Dawson aquifer, where the trend direction was opposite, a positive trend from 2015 to 2018 and a negative trend (declining groundwater elevations) from 2015 to 2023. The change in trends within the upper Dawson aquifer may be affected by differences in the study period and the trend analysis applied. Trends during the 2015–23 study period were compared to departures from the median 2015 groundwater-level elevation for each site in each aquifer. In general, the departures from the 2015 median supported trends observed at each site and correlated spatially with greater departures near the western border of Elbert County. Additionally, 30-year precipitation data showing wet and dry periods were overlaid with the departure from the 2015 median to assess groundwater-level patterns in wells in the five aquifers. Departures from the 2015 median groundwater-level elevations appeared greatest during the dry period between 2020 and 2023. Potentiometric-surface maps of the upper and lower Dawson aquifers created from static April 2023 groundwater elevations indicated groundwater-flow direction is generally from the south to the north. Results of this study could be used to guide additional groundwater monitoring in Elbert County and could aid in long-term planning of water resources.

Colorado

Hydrogeologic investigation and simulation of ground-water flow in the Upper Floridan Aquifer of north-central Florida and southwestern Georgia and delineation of contributing areas for selected city of Tallahassee, Florida, water-supply wells

A 4-year investigation of the Upper Floridan aquifer and ground-water flow system in Leon County, Florida, and surrounding counties of north-central Florida and southwestern Georgia began in 1990. The purpose of the investigation was to describe the ground-water flow system and to delineate the contributing areas to selected City of Tallahassee, Florida, water-supply wells. The investigation was prompted by the detection of low levels of tetrachloroethylene in ground-water samples collected from several of the city's water-supply wells. Hydrologic data and previous studies indicate that; ground-water flow within the Upper Floridan aquifer can be considered steady-state; the Upper Floridan aquifer is a single water-bearing unit; recharge is from precipitation; and that discharge occurs as spring flow, leakage to rivers, leakage to the Gulf of Mexico, and pumpage. Measured transmissivities of the aquifer ranged from 1,300 ft 2 /d (feet squared per day) to 1,300,000 ft2/d. Steady-state ground-water flow in the Upper Floridan aquifer was simulated using a three-dimensional ground- water flow model. Transmissivities ranging from less than 5,000 ft2/d to greater than 11,000,000 ft 2 /d were required to calibrate to observed conditions. Recharge rates used in the model ranged from 18.0 inches per year in areas where the aquifer was unconfined to less than 2 inches per year in broad areas where the aquifer was confined. Contributing areas to five Tallahassee water-supply wells were simulated by particle- tracking techniques. Particles were seeded in model cells containing pumping wells then tracked backwards in time toward recharge areas. The contributing area for each well was simulated twice, once assuming a porosity of 25 percent and once assuming a porosity of 5 percent. A porosity of 25 percent is considered a reasonable average value for the Upper Floridan aquifer; the 5 percent porosity simulated the movement of ground-water through only solution-enhanced bedding plains and fractures. The contributing areas were generally elliptical in shape, reflecting the influence of the sloping potentiometric surface. The contributing areas delineated for a 5 percent porosity were always much larger than those determined using a 25 percent porosity. The lowest average ground-water velocity computed within a contributing area, using a 25 percent porosity, was 1.0 ft/d (foot per day) and the highest velocity was 1.6 ft/d. The lowest average ground-water velocity, determined using a 5 percent porosity, was 2.4 ft/d and the highest was 7.4 ft/d. The contributing areas for each of the five wells was also determined analytically and compared to the model-derived areas. The upgradient width of the simulated contributing areas were larger than the upgradient width of the analytically determined contributing areas for four of the five wells. The model could more accurately delineate contributing areas because of the ability to simulate wells as partially penetrating and by incorporating complex, three-dimensional aquifer characteristics, which the analytical method could not.

Florida, Georgia

Effective site coefficients for the 2024 International Building Code (IBC)

The U.S. National Seismic Hazard Models (NSHMs), developed by the U.S. Geological Survey (USGS), have long been the scientific foundation of seismic design guidelines and have been used to compute design ground motions for construction of new buildings and retrofit of existing buildings in the United States and its territories. The 2018 NSHM is adopted by the 2024 International Building Code (IBC). Prior to the 2018 NSHM update, hazard calculations were required only at one reference site condition defined by V S30 =760 m/s (where V S30 is the time-averaged shear wave velocity from the surface to a depth of 30 m) and three periods (peak ground acceleration, PGA, and pseudo spectral accelerations at periods of 0.2 and 1 s, S s and S 1 ). Site coefficients, F PGA , F a , and F v , were then defined by the Building Seismic Safety Council (BSSC) Provisions Update Committee (PUC) in the site-specific procedures of National Earthquake Hazard Reduction Program (NEHRP) Recommended Seismic Provisions to calculate ground motions for other site classes with different V S30 values at the given periods. The design ground motions at other periods were then estimated using a generic spectral shape that was also defined by the BSSC PUC in NEHRP provisions. In recent years, the engineering community has realized there were deficiencies with the F a and F v site coefficients and the generic spectral shape. To avoid potentially dangerous underestimations of design ground motions for long period structures on soft site conditions in high seismicity regions, the BSSC PUC recommended the use of multi-period response spectra (MPRS) in 2017. As a result, the USGS produced multi-period and multi-V S30 response spectral values in the 2018 NSHM for calculations of design ground motions and the site coefficients F a and F v were eliminated from the 2020 NEHRP Provisions. As these site coefficients were widely used inside and outside of the United States, in this study we back-calculate the “effective” site coefficients F a,eff , and F v,eff by comparing MPRS for various site classes with the MPRS for the reference site condition, and discuss the changes that are observed in the 2024 IBC compared to its previous version in 2021. The effective site coefficients are presented for test site locations and their dependence on various factors including period, ground motion intensity, and regional models are discussed. Ratio maps between the new effective site coefficients and the old ones are then presented for soft site classes and for short and long periods. For soft site classes at short periods, the new effective site coefficients are lower than the old site coefficients for high seismicity regions and higher for low seismicity regions. As it was expected, for soft site classes at long periods and high seismicity regions, the new effective site coefficients are much larger than the old site coefficients without imposing the 50% increase as a penalty that was suggested in the 2021 IBC, whereas they could be much smaller if the 50% increase would have been imposed particularly around New Madrid and Charleston high seismicity regions. For low seismicity regions, the long period effective site coefficients can be smaller or larger by 20% compared to the 2021 IBC coefficients.

Conference Paper

Timing and geometry of the Chemehuevi Formation reveal a late Pleistocene sediment pulse into the Lower Colorado River

The Chemehuevi Formation is a distinctive 50−150-m-thick wedge-shaped Pleistocene sedimentary unit deposited by the Colorado River. It lines the perimeters of the river’s floodplains and bedrock canyons for more than 600 km between the mouth of the Grand Canyon and the delta region in the Gulf of California. The formation is composed of a basal tan to light-yellowish-brown and pale-orange mud-dominated facies overlain and interbedded by a light-yellow-brown sand-dominated facies. The unit is one of two extensively exposed aggradational packages in the Lower Colorado River corridor, in addition to a series of other smaller alluvial terrace deposits. The Chemehuevi Formation appears to represent the response of a fully integrated Colorado River system to a significant perturbation, in contrast to the Bullhead Alluvium, which is likely a unique result of Pliocene river integration. The aggradation of the Chemehuevi Formation in the Lower Colorado River corridor may be similarly due to a unique event in the Colorado River system, or it may instead be a well-preserved sedimentary sequence recording typical behavior of the Colorado River below the Grand Canyon in the late Pleistocene. As such, multiple causal mechanisms have been proposed, but no study to date has conclusively explained the Chemehuevi Formation. To help resolve its timing, duration, and origin, we applied post-infrared infrared stimulated luminescence, carbonate U-Th series, and zircon sensitive high-resolution ion microprobe U-Th series geochronology to determine the ages of key exposures of the unit over a wide spatial area. These new data demonstrate that the Chemehuevi Formation was deposited ca. 110−90 ka. The depositional ages collectively overlap, suggesting that deposition occurred rapidly relative to the resolution of the geochronometers. The new depositional timing coincides with a shift from glacial to interglacial conditions after the marine isotope stage 5-6 transition. This observation is consistent with a climate-induced sediment pulse as a causal mechanism, yet correlations with similar deposits in the Colorado River headwaters or in neighboring catchments appear elusive. Potentially, climate transitions between glacial and interglacial periods induced a sediment pulse from hillslopes of the Colorado River system that resulted in the Chemehuevi Formation. An alternative or additional explanation is that the Chemehuevi Formation represents release of lava dam−impounded sediment in the Grand Canyon. The surface geometry of the Chemehuevi Formation projects upstream to the approximate location of lava dams, and the largest possible lava dam impoundment (the Upper Prospect dam) is comparable in volume to the formation. The lava dam hypothesis appears to be a possible explanation for the Chemehuevi Formation. However, tying deposition to a specific lava dam or series of lava dams remains challenging due to discrepancies in timing and volume. The combined effects of a series of lava dams may have led to the Chemehuevi Formation, as the last Pleistocene lava dam eruption coincides with the onset of deposition. Alternatively, the formation may result from the combined effects of both regional climate transitions and the lava dams that created a transient reservoir to compound a climate transition−driven sediment pulse. The geochronologic data presented here do not allow us to distinguish between the lava dam or climate transition hypotheses but will need to be reconciled with any future proposed depositional model.

Arizona, California, Nevada

Concentrations and distribution of manmade organic compounds in the Lake Tahoe Basin, Nevada and California, 1997-99

The U.S. Geological Survey, in cooperation with the Tahoe Regional Planning Agency and the Lahontan Regional Water-Quality Control Board, sampled Lake Tahoe, major tributary streams to Lake Tahoe, and several other lakes in the Lake Tahoe Basin for manmade organic compounds during 1997-99. Gasoline components were found in all samples collected from Lake Tahoe during the summer boating season. Methyl tert -butyl ether (MTBE), benzene, toluene, ethylbenzene, and xylenes (BTEX) were the commonly detected compounds in these samples. Most samples from tributary streams and lakes with no motorized boating had no detectable concentrations of gasoline components. Motorized boating activity appears to be directly linked in space and time to the occurrence of these gasoline components. Other sources of gasoline components to Lake Tahoe, such as the atmosphere, surface runoff, and subsurface flow, are minor compared to the input by motorized boating. Water sampled from Lake Tahoe during mid-winter, when motorized boating activity is low, had no MTBE and only one sample had any detectable BTEX compounds. Soluble pesticides rarely were detected in water samples from the Lake Tahoe Basin. The only detectable concentrations of these compounds were in samples from Blackwood and Taylor Creeks collected during spring runoff. Concentrations found in these samples were low, in the 1 to 4 nanograms per liter range. Organochlorine compounds were detected in samples collected from semipermeable membrane devices (SPMD's) collected from Lake Tahoe, tributary streams, and Upper Angora Lake. In Lake Tahoe, SPMD samples collected offshore from urbanized areas contained the largest number and highest concentrations of organochlorine compounds. The most commonly detected organochlorine compounds were cis- and trans-chlordane, p , p' -DDE, and hexachlorobenzene. In tributary streams, SPMD samples collected during spring runoff generally had higher combined concentrations of organochlorine compounds than those collected during baseflow conditions. Upper Angora Lake had the fewest number of organochlorine compounds detected of all lake samples. Dioxins and furans were not detected in SPMD samples from two sites in Lake Tahoe or from two tributary streams. The number of polycyclic aromatic hydrocarbon (PAH) compounds and their combined concentrations generally were higher in samples from Lake Tahoe than those from tributary streams. Areas of high-motorized boating activity at Lake Tahoe had the largest number and highest concentrations of PAH's. PAH compounds were detected in samples from SPMD's in four of six tributary streams during spring runoff, all tributary streams during baseflow conditions, and at all lake sites. The most commonly detected PAH's in tributary streams during spring runoff were phenanthrene, fluoranthene, pyrene, and chrysene, and during baseflow conditions were phenanthrene, 1-methylphenanthrene, diethylnaphthalene, and pyrene. Upper Truckee River, which has an urban area in its drainage basin, had the largest number and highest combined concentration of PAH's of all stream samples. Bottom-sediment from Lake Tahoe had detectable concentrations of p-cresol, a phenol, in all but one sample. A sample collected near Chambers Lodge contained phenol at an estimated concentration of 4 micrograms per kilogram (µg/kg). Bottom-sediment samples from tributary streams had no detectable concentrations of organochlorine or PAH compounds. Several compounds were detected in bottom sediment from Upper Angora Lake at high concentrations. These compounds and their concentrations were p , p' -DDD (10 µg/kg), p , p' -DDE (7.4 µg/kg), 2,6-dimethylnaphthalene (estimated at 190 µg/kg), pentachlorophenol (3,000 µg/kg), and p-cresol (4,400 µg/kg).

California, Nevada