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At least 955 records · Page 53Linked to original sources

USGS1971

Data for wells in the Modesto-Merced area, San Joaquin Valley, California

The Modesto-Merced area is in the northeastern part of the San Joaquin Valley. The area includes about 1,800 square miles that lie in the eastern portions of Merced and Stanislaus Counties. Specifically the boundaries are: North, the Stanislaus River; south, the Merced-Madera County line; east, the Merced-Mariposa and the Stanislaus-Tuolumne County lines; west, the San Joaquin River. Between September 1970 and May 1971, 859 wells were selectively canvassed in the area. The resulting data are on file in the U.S. Geological Survey office at 2800 Cottage Way, Sacramento, Calif. Selected well data are tabulated in table 1, and the location of these wells is shown on maps 1-65. Selected chemical analyses are shown in table 2. Table 3 is a listing of the well numbers of all wells canvassed in the area by the U.S. Geological Survey through April 1971.

California↗

USGS2009

U.S. Geological Survey Groundwater Modeling Software: Making Sense of a Complex Natural Resource

Computer models of groundwater systems simulate the flow of groundwater, including water levels, and the transport of chemical constituents and thermal energy. Groundwater models afford hydrologists a framework on which to organize their knowledge and understanding of groundwater systems, and they provide insights water-resources managers need to plan effectively for future water demands. Building on decades of experience, the U.S. Geological Survey (USGS) continues to lead in the development and application of computer software that allows groundwater models to address scientific and management questions of increasing complexity.

Fact Sheet↗

USGS2011

Characterization of the Cretaceous aquifer structure of the Meskala region of the Essaouira Basin, Morocco

The aquifer of early Cretaceous age in the Meskala region of the Essaouira Basin is defined by interpretation of geological drilling data of oil and hydrogeological wells, field measurement and analysis of in situ fracture orientations, and the application of a morphostructural method to identify lineaments. These analyzes are used to develop a stratigraphic–structural model of the aquifer delimited by fault zones of two principal orientations: NNE and WNW. These fault zones define fault blocks that range in area from 4 to 150 km 2 . These blocks correspond either to elevated zones (horsts) or depressed zones (grabens). This structural setting with faults blocks of Meskala region is in accordance with the structure of the whole Essaouira Basin. Fault zones disrupt the continuity of the aquifer throughout the study area, create recharge and discharge zones, and create dip to the units from approximately 10° to near vertical in various orientations. Fracture measurements and morphometric-lineament analyzes help to identify unmapped faults, and represent features important to groundwater hydraulics and water quality within fault blocks. The above geologic features will enable a better understanding of the behaviour and hydro-geo-chemical and hydrodynamics of groundwater in the Meskala aquifer.

Essaouira Basin↗

USGS1983

Geochemical map and rock and stream-sediment data from the Wild Rogue Wilderness, Coos and Curry counties, Oregon

The Wild Rogue Wilderness is located in Coos and Curry Counties, southwestern Oregon and covers part of the Bone Mountain, Marial, and Agness 15' quadrangles (fig. 1). It is an elongate area, 19 mi by 0.8 to 3 mi (31 km by 1.3 to 5 km) and includes approximately 35,818 acres extending from the town of Agness northeast to Mount Bolivar. The area is characterized by several diverse geologic terranes described in detail by Gray and others (1982). This paper summarizes semiquantitative chemical analyses of 256 rocks for 23 elements and analyses of 40 stream-sediment samples for 33 elements as presented in Gray and Peterson (1982).

Oregon↗

USGS2004

Chemical analyses of tertiary volcanic rocks, central San Juan caldera complex, southwestern Colorado

In conjunction with integrated mapping of the Oligocene central San Juan caldera cluster, southwestern Colorado (USGS I-Map 2799, in press), all modern chemical analyses of volcanic rocks for this area determined in laboratories of the U.S. Geological Survey have been re-evaluated in terms of the stratigraphic sequence as presently understood. These include approximately 700 unpublished analyses made between 1986 and 2003, as well as all USGS analyses published since 1965 when the widespread presence of regional welded ash-flow tuffs erupted from large calderas was first recognized. All the analyses are assigned unit identifiers consistent with those used for the new geologic map; quite a few of these differ from those used on sample submittal forms and in prior USGS publications.

Colorado↗

USGS2015

Simulation of nitrogen attenuation in a subterranean estuary, representative of the southern coast of Cape Cod, Massachusetts

A two-dimensional model was developed by the U.S. Geological Survey, in cooperation with the U.S. Environmental Protection Agency, to assess flow and chemical reaction associated with groundwater discharge through the subterranean estuary representative of coastal salt ponds of southern Cape Cod. The model simulated both the freshwater and saltwater flow systems and accounted for density-dependent flow, tidal fluctuation, and chemical reactivity among oxygen, dissolved organic carbon, nitrate, and ammonia. Not previously incorporated into one model, the interaction of these effects can now be simulated in the subterranean estuary context. An analysis of the flow system under mean-tide conditions was conducted first to provide the initial conditions for a subsequent analysis that included the effects of tidal fluctuations. Tidal fluctuations were simulated with a repeated couplet that represented a high tide-low tide sequence and alternating locations of head-dependent flux boundaries placed along the simulated seabed, above and below the levels of the respective high and low tides. Boundary conditions for chemical species included nitrate in recharge, and oxygen and organic matter (including organic nitrogen) in infiltrating solutions of head-dependent boundaries. Reaction chemistry was limited to oxidative degradation of organic matter (including remineralization of ammonia) with oxygen or nitrate as electron acceptors and nitrification of ammonia in the presence of oxygen. Simulations using the SEAWAT-2000 computer program resulted in two mixing zones-between freshwater and saltwater in a deep saltwater wedge and in an intertidal salt zone, which results from tidal fluctuation. The mixing zones are the principal locations where nitrogen attenuation reactions occurred-between organic matter in the saltwater zones of the aquifer and nitrate in the freshwater zone. In mean-tide PHT3D model simulations, 15 percent of nitrogen that is recharged was attenuated because of reaction with dissolved organic matter, a denitrification reaction that reduces nitrate to nitrogen gas. When a fluctuating tide was simulated, the amount of recharged nitrogen that was denitrified increased to 20 percent. Chemical reaction was controlled by the rate of mixing of freshwater and saltwater, which contained the reactants nitrate and dissolved organic matter, respectively, necessary for nitrogen attenuation reactions to take place. Reaction occurred in both the deep saltwater wedge and in an increased denitrification. However, mixing may also have been enhanced partly by numerical dispersion.

Massachusetts↗

USGS2023

Summary of the history and research of the U.S. Geological Survey gas hydrate properties laboratory in Menlo Park, California, active from 1993 to 2022

The U.S. Geological Survey (USGS) Clathrate Hydrate Properties Project, active from 1993 to 2022 in Menlo Park, California, stemmed from an earlier project on the properties of planetary ices supported by the National Aeronautics and Space Administration’s (NASA’s) Planetary Geology and Geophysics Program. We took a material science approach in both projects, emphasizing chemical purity of samples, having controlled grain size and grain texture, and having verified crystal structures and phase relations. A foundational contribution from our USGS Gas Hydrate Properties Laboratory (GHPL) was in demonstrating the ability to reproducibly create such pure clathrate hydrate samples for study. Clathrate sample synthesis was achieved by heating sieved and weighed pure granular water ice in the presence of cold clathrate-forming gas or liquid. During heating, the ice melts at the grain scale and reacts with the gas to form clathrate. The resulting material has the desired uniformity and purity, with known intergranular porosity; our subsequent measurements showed that these clathrates exhibited the established clathrate structures and phase relations. This novel synthesis method was successful in creating clathrates of pure methane, ethane, propane, carbon dioxide, and multi-component gases. By mixing sand or silt with granular ice, we were also able to make clathrate-sediment aggregates with controlled grain textures. This simple method, adopted by many others in the community, permitted us to measure the physical and chemical properties of well-characterized and well-crystallized clathrates and clathrate/sediment aggregates. At about the same time, we adapted conventional scanning electron microscopy to cryogenic conditions for analysis of grain-scale characteristics of clathrates made in the GHPL as well as those collected from nature by drill core. The uniformity and reproducibility of our samples also allowed us to investigate how clathrates respond to environmental changes in chemistry, temperature, and pressure: we measured chemical exchange rates with dissolved gas species—such as noble gases and chlorofluorocarbons—as well as rates of clathrate dissolution and decomposition. These advances include the first accurate mapping of the conditions that promote the remarkable process of “anomalous preservation” at room pressure, a metastability that offers potential application for low-cost and safe transportation of natural gas from gas fields far from pipelines. Another advancement stemming from the GHPL was the compaction of as-synthesized porous clathrates to nearly full density by applying external pressure using three different techniques. Compaction allows for high-accuracy measurements of many fundamental physical and chemical properties of these materials, such as elastic wavespeeds and moduli, complete thermal properties, decomposition rates, thermal expansion, and clathrate equations of state. These properties and others, in turn, have helped USGS scientists to interpret geophysical well logs and active geophysical surveys, as well as model the rates of gas production from hydrate deposits in nature. Studying this class of icy minerals that occur in abundance on Earth and in the outer solar system has been a fascinating laboratory journey. Here, we summarize the history and major findings of the USGS GHPL in Menlo Park, including both in-house research as well as findings from the synergistic collaborations with other agencies and institutes that were key to the success of our laboratory. The Menlo Park GHPL was more formally incorporated within the USGS Gas Hydrates Project, a collaboration among multiple USGS Science Centers, in the early 2000s under the leadership of Deborah Hutchinson, and now under the leadership of Carolyn Ruppel and Timothy Collett.

Open-File Report↗

USGS1985

Chemical and physical characteristics of water in estuaries of Texas; October 1978-September 1983

The Texas Water Plan (Texas Water Development Board, 1968) proposed development and utilization of water resources in Texas and included a provision for the use and preservation of water in the estuaries of the State. Management of estuarine waters requires knowledge of the hydrodynamics and of the continuing changes in the chemical and physical characteristics of water in the estuaries. In September 1967, the U.S. Geological Survey and the Texas Department of Water Resources began a cooperative water-resources data-collection program of the principal estuaries along the Texas coast except for the Rio Grande estuary, which is under the jurisdiction of the International Boundary and Water Commission, United States and Mexico. The data-collection program for the first 11 years were published in 9 separate publications by the Texas Department of Water Resources. This report is the final publication for the project which ended in September 1983, and contains the data collected for the last 5 years (October 1978-September 1983). Approximately 243 data-collect!*on sites were visited during the 1979-83 water years. The properties or constituents measured in the field were dissolved oxygen (DO), specific conductance, temperature, pH, and transparency by Secchi disk. Analyses conducted in the laboratory included the principal inorganic ions, biochemical oxygen demand (BOD), total organic carbon (TOC), ammonia nitrogen, nitrite nitrogen, nitrate nitrogen, total phosphate, insecticides and herbicides, and other selected metals such as aluminium, arsenic, cadmium, chromium, cobalt, iron, lead, lithium, manganese, mercury, nichol, strontium, and zinc. Streamfl ow-measuring sites are used to monitor both the amount and quality of water that enter the estuarine embayments. The farthest downstream sites available are located many miles upstream from the estuaries because of the effect of changes in water stage in the estuaries. Consequently, there is inflow into the bays below these sites that can and do affect the amount and quality of water entering the estuaries.

Open-File Report↗

USGS2005

Hydrogeology of the Mogollon Highlands, central Arizona

The Mogollon Highlands, 4,855 square miles of rugged, mountainous terrain at the southern edge of the Colorado Plateau in central Arizona, is characterized by a bedrock-dominated hydrologic system that results in an incompletely integrated regional ground-water system, flashy streamflow, and various local water-bearing zones that are sensitive to drought. Increased demand on the water resources of the area as a result of recreational activities and population growth have made necessary an increased understanding of the hydrogeology of the region. The U.S. Geological Survey conducted a study of the geology and hydrology of the region in cooperation with the Arizona Department of Water Resources under the auspices of the Arizona Rural Watershed Initiative, a program launched in 1998 to assist rural areas in dealing with water-resources issues. The study involved the analysis of geologic maps, surface-water and ground-water flow, and water and rock chemical data and spatial relationships to characterize the hydrogeologic framework. The study area includes the southwestern corner of the Colorado Plateau and the Mogollon Rim, which is the eroded edge of the plateau. A 3,000- to 4,000-foot sequence of early to late Paleozoic sedimentary rocks forms the generally south-facing scarp of the Mogollon Rim. The area adjacent to the edge of the Mogollon Rim is an erosional landscape of rolling, step-like terrain exposing Proterozoic metamorphic and granitic rocks. Farther south, the Sierra Ancha and Mazatzal Mountain ranges, which are composed of various Proterozoic rocks, flank an alluvial basin filled with late Cenozoic sediments and volcanic flows. Eight streams with perennial to intermittent to ephemeral flow drain upland regions of the Mogollon Rim and flow into the Salt River on the southern boundary or the Verde River on the western boundary. Ground-water flow paths generally are controlled by large-scale fracture systems or by karst features in carbonate rocks. Stream channels are also largely controlled by structural features, such as regional joint or fault systems. Precipitation, which shows considerable variability in amount and intensity, recharges the ground-water system along the crest of the Mogollon Rim and to a lesser extent along the crests and flanks of the rim and the Mazatzal Mountains and Sierra Ancha. Flashy runoff in the mainly bedrock stream channels is typical. Springs are distributed throughout the region, typically discharging at or above the contact of variably permeable formations along the face of the Mogollon Rim with a scattering of low-discharge springs in the Proterozoic rocks below the rim. The surface of the Colorado Plateau is the primary recharge area for the C aquifer in which ground-water flows north toward the Little Colorado River and south toward the Mogollon Highlands. Within the study area, flow from the C aquifer primarily discharges from large, stable springs in the upper East Verde River, Tonto Creek, and Canyon Creek Basins along the top of the Mogollon Rim and to the west as base flow in West Clear Creek. On the basis of chemical evidence and the distribution and flow characteristics of springs and perennial streams, the C aquifer is also the source of water for the limestone aquifer that discharges from carbonate rocks near the base of the Mogollon Rim. Vertical flow from the C aquifer, the base of which is in the Schnebly Hill Formation, recharges the limestone aquifer that discharges mainly at Fossil Springs in the western part of the study area and as base flow in Cibecue Creek on the eastern edge of the study area. Local, generally shallow aquifers of variable productivity occur in plateau and mesa-capping basalts in the sedimentary rocks of the Schnebly Hill and Supai Formations, in fractured zones of the Proterozoic Payson granite, and in the alluvium of the lower Tonto Creek Basin. Where time series data exist, such water-bearing zones are shown to be sensitive to short-

Scientific Investigations Report↗

USGS1974

Availability of ground water in the Blackstone River area Rhode Island and Massachusetts

The Blackstone River study area covers 83 square miles of northern Rhode Island and 5 square miles of adjacent Massachusetts (fig. 1). It includes parts of the Blackstone, Moshassuck, and Tenmile River basins, and a coastal area that drains to the brackish Seekonk and Providence Rivers. In Rhode Island, all or parts of the suburban towns of Cumberland, Lincoln, North Smithfield, and Smithfield and all or parts of the cities of Central Falls, East Povidence, Pawtucket, Providence, and Woonsocket are within the study area. Also included are parts of the towns Attleboro and North Attleborough in Massachusetts. In 1970, total population was about 240,000, which was equivalent to about one-fourth of the total population of Rhode Island. Fresh water usage in 1970 by public-supply systems and self-supplied industry was about 33 mgd (million gallons per day), which was equal to 22 percent of total fresh water use in Rhode Island for all purposes except generation of electric power (fig. 2). Anticipated increases in population and per capita water requirements are likely to cause the demand for water to more than double within the next 50 years. A significant part of this demand can be met from wells that tap the principal streams. This aquifer yielded an average of 10 mgd in 1970 and is capable of sustaining a much higher yield. The primary objectives of the study were to determine and map the saturated thickness and transmissivity of the stratified-drift aquifer and to assess the potential sustained yield of those parts of the aquifer favorable for large-scale development of water. A secondary objective was to describe ground-water quality and to evaluate the impact of induced infiltration of polluted stream water on the quality of native ground water. This report is based on analysis of drillers' records of more than 700 wells and borings which include 462 lithologic logs; 35 specific-capacity determinations; 12 aquifer tests, including detailed tests at two sites to determine streambed infiltration rates; chemical analyses of 92 ground-water and 15 stream-water samples; and geologic mapping. Selected base data are published in a separate (Johnston and Dickerman, in press). The authors are indebted to well drillers, especially American Drilling and Boring Company, R.E. Chapman Company, and Layne New England Company, for making their records available; to the water departments of the towns of Cumberland and Lincoln, for allowing aquifer tests of their well fields; to the Rhode Island Department of Health, for providing data on water quality and use; and to many other federal, state, and municipal agencies, companies, and individuals who supplied information. Their contributions are gratefully acknowledged.

Massachusetts;Rhode Island↗

USGS1984

Maps showing distribution of dissolved solids and dominant chemical type in ground water, Basin and Range Province, Southern California

This map report is one of a series of geologic and hydrologic maps of States in the Basin and Range Province. These map reports contain information on ground-water hydrology, ground-water quality, surface distribution of selected rock types, data on tectonic conditions, areal geophysical data, Pleistocene lakes and marshes and natural resources. This information is the basis for a summary report that characterizes the Basin and Range Province. The geologic and hydrologic characterization will be used to evaluate the Province for prospective regions for further study relative to isolation of high-level radioactive waste. (Bedinger, Sargent and Reed, 1984).

California↗

USGS1984

Maps showing distribution of dissolved solids and dominant chemical type in ground water, Basin and Range Province, New Mexico

New Mexico↗

USGS1987

Selected chemical analyses of water from formations of Mesozoic and Paleozoic age in parts of Oklahoma, northern Texas, and Union County, New Mexico

Hydrochemical data were compiled into a data base as part of the Central Midwest Regional Aquifer System Analysis project. The data consist of chemical analyses of water samples collected from wells that are completed in formations of Mesozoic and Paleozoic age. The data base includes data from the National Water Data Storage and Retrieval System, the Petroleum Data System, the National Uranium Resource Evaluation, and selected publications. Chemical analyses were selected for inclusion within the hydrochemical data base if the total concentration of the cations differed from the total 10 percent or less of the total concentration of all ions. Those analyses which lacked the necessary data for an ionic balance were included if the ratios of dissolved-solids concentration to specific conductance were between 0.55 and 0.75. The tabulated chemical analyses, grouped by county, and a statistical summary of the analyses, listed by geologic unit, are presented.

Water-Resources Investigations Report↗

USGS2000

Microbiological and chemical quality of ground water used as a source of public supply in southern Missouri — Phase II, April–July, 1998

The protection of public health through quality public ground-water systems is the responsibility of the U. S. Environmental Protection Agency and the State of Missouri, through the Missouri Department of Natural Resources, Public Drinking Water Program. Approximately 95 percent of the public-water supplies in Missouri use ground water as their source of drinking water through more than 3,700 public wells. Karst terrain, intensive agricultural operations, extensive numbers of on-site sewage systems, and poor well construction can lead to chemical and microbiological contamination of the contributing aquifers. Sitespecific studies and routine regulatory monitoring have produced information on the overall quality and potability of the State's public-drinking-water supplies, but little is known about the presence of viruses. The U.S. Geological Survey, in cooperation with the Missouri Department of Natural Resources, sampled 109 public-water supplies to characterize the physical, chemical, bacterial, and viral conditions in southern Missouri. During April to July 1998, these wells were sampled for nutrients, total organic carbon, optical brighteners, indicator bacteria, enteric viruses, and ribonucleic acid and somatic coli phages. These constituents indicate possible surface contamination of the sampled aquifer. Selection of the wells to be sampled depended on the age of the well (pre-1970), land use, geohydrology, and well construction. None of the physical or chemical constituents measured or analyzed exceeded Missouri's Drinking Water Standards set by the Public Drinking Water Program of the Missouri Department of Natural Resources. The majority of ammonia plus organic nitrogen, nitrite, and phosphorus concentrations were below the laboratory's minimum reporting levels. There were a greater number of detects above the minimum reporting level with respect to the nitrite plus nitrate, ammonia, orthophosphate, and total organic carbon concentrations. Analyses included comparing and contrasting the data by grouping according to well age and construction, karst type, geohydrology, soil type, and land use. There was little variation in well construction between selected wells. The results indicated several groupings of similar and dissimilar concentrations, most expected because of hydrological, physical, or land use differences. Dissolved oxygen values indicated distinct variation in the different groupings. There were significant differences in dissolved oxygen values between the secondary and non-karst areas, the Ozark confined and Ozark unconfined geohydrologic groups, and between agricultural and other land uses. In groupings by soil and geohydrology, the Missouri bootheel region differed with respect to ammonia, total organic carbon, and phosphorus when compared with the other groups. Less than 10 percent of the wells sampled tested positive for bacterial contamination. E. coli was the most frequently detected bacterium. The public wells at Monett and West Plains, Missouri, had plates with colonies too numerous to count for all three indicator bacteria. Further analyses by rRNA (ribosomal RiboNucleic Acid) hybridization techniques detennined that much of the bacteria present were from ruminant and human sources. No enteric viruses were detected in the 109 samples. Both ribonucleic acid and somatic coliphage were detected at two wells. One additional well had ribonucleic acid coliphage and another had somatic coliphage for a total of four wells with coliphage selects.

Missouri↗

USGS2018

Geochemistry of groundwater in the eastern Snake River Plain aquifer, Idaho National Laboratory and vicinity, eastern Idaho

Nuclear research activities at the U.S. Department of Energy (DOE) Idaho National Laboratory (INL) in eastern Idaho produced radiochemical and chemical wastes that were discharged to the subsurface, resulting in detectable concentrations of some waste constituents in the eastern Snake River Plain (ESRP) aquifer. These waste constituents may pose risks to the water quality of the aquifer. In order to understand these risks to water quality the U.S. Geological Survey, in cooperation with the DOE, conducted a study of groundwater geochemistry to improve the understanding of hydrologic and chemical processes in the ESRP aquifer at and near the INL and to understand how these processes affect waste constituents in the aquifer. Geochemistry data were used to identify sources of recharge, mixing of water, and directions of groundwater flow in the ESRP aquifer at the INL. The geochemistry data were analyzed from 167 sample sites at and near the INL. The sites included 150 groundwater, 13 surface-water, and 4 geothermal-water sites. The data were collected between 1952 and 2012, although most data collected at the INL were collected from 1989 to 1996. Water samples were analyzed for all or most of the following: field parameters, dissolved gases, major ions, dissolved metals, isotope ratios, and environmental tracers. Sources of recharge identified at the INL were regional groundwater, groundwater from the Little Lost River (LLR) and Birch Creek (BC) valleys, groundwater from the Lost River Range, geothermal water, and surface water from the Big Lost River (BLR), LLR, and BC. Recharge from the BLR that may have occurred during the last glacial epoch, or paleorecharge, may be present at several wells in the southwestern part of the INL. Mixing of water at the INL primarily included mixing of surface water with groundwater from the tributary valleys and mixing of geothermal water with regional groundwater. Additionally, a zone of mixing between tributary valley water and regional groundwater, trending southwesterly, extended from near the northeastern boundary of the INL to the southern boundary of the INL. Groundwater flow directions for regional groundwater were southwesterly, and flow directions for tributary groundwater were southeasterly upon entering the ESRP, but eventually began to flow southwesterly in a direction parallel with regional groundwater. Several discrepancies were identified from comparison of sources of recharge determined from geochemistry data and backward particle tracking with a groundwater-flow model. Some discrepancies observed in the particle tracking results included representation of recharge from BC near the north INL boundary, groundwater from the BC valley not extending far enough south, regional groundwater that extends too far west in the southern part of the INL, and no representation of recharge from geothermal water in model layer 1 or recharge from the BLR in the southwestern part of the INL.

Idaho↗

USGS1996

Ground-water resources data for Warren County, Pennsylvania

This report presents lithologic, hydrologic, and chemical data collected during a study of the ground-water resources of Warren County, Pa. The study was conducted during 1983-90 by the U.S. Geological Survey, in cooperation with the Pennsylvania Department of Conservation and Natural Resources, Bureau of Topographic and Geologic Survey, and the Warren County Commissioners. The data include information on aquifers, water levels, and yields for about 600 wells, and records for 57 springs. Descriptions of aquifer lithology and chemical analyses of water samples collected at well and spring sites are provided. Chemical analyses include major cations, anions, nutrients, and selected trace elements. Also included are data on concentrations of volatile organic compounds, dissolved methane, ethane, propane, and total organic carbon. The report presents a summary of the source and significance of selected chemical constituents in ground water, a listing of Federal drinking water standards, and information on selected methods of removing or reducing concentrations of undesirable chemical constituents from water. Daily ground- water levels for five observation wells are tabulated. Maps of Warren County show the location of townships, boroughs, and 7-1/2-minute quadrangles. Data-collection sites are shown on 18 figures. A glossary is provided for readers unfamiliar with ground-water terminology.

Open-File Report↗

USGS1951

Geologic history of sea water: An attempt to state the problem

Paleontology and biochemistry together may yield fairly definite information, eventually, about the paleochemistry of sea water and atmosphere. Several less conclusive lines of evidence now available suggest that the composition of both sea water and atmosphere may have varied somewhat during the past; but the geologic record indicates that these variations have probably been within relatively narrow limits. A primary problem is how conditions could have remained so nearly constant for so long. It is clear, even from inadequate data on the quantities and compositions of ancient sediments, that the more volatile materials—H 2 O, CO 2 , Cl, N, and S— are much too abundant in the present atmosphere, hydrosphere, and biosphere and in ancient sediments to be explained, like the commoner rock-forming oxides, as the products of rock weathering alone. If the earth were once entirely gaseous or molten, these “excess” volatiles may be residual from a primitive atmosphere. But if so, certain corollaries should follow about the quantity of water dissolved in the molten earth and the expected chemical effects of a highly acid, primitive ocean. These corollaries appear to be contradicted by the geologic record, and doubt is therefore cast on this hypothesis of a dense primitive atmosphere. It seems more probable that only a small fraction of the total “excess” volatiles was ever present at one time in the early atmosphere and ocean. Carbon plays a significant part in the chemistry of sea water and in the realm of living matter. The amount now buried as carbonates and organic carbon in sedimentary rocks is about 600 times as great as that in today's atmosphere, hydrosphere, and biosphere. If only 1/100 of this buried carbon were suddenly added to the present atmosphere and ocean, many species of marine organisms would probably be exterminated. Furthermore, unless CO 2 is being added continuously to the atmosphere-ocean system from some source other than rock weathering, the present rate of its subtraction by sedimentation would, in only a few million years, cause brucite to take the place of calcite as a common marine sediment. Apparently, the geologic record shows no evidence of such simultaneous extinctions of many species nor such deposits of brucite. Evidently the amount of CO 2 in the atmosphere and ocean has remained relatively constant throughout much of the geologic past. This calls for some source of gradual and continuous supply, over and above that from rock weathering and from the metamorphism of older sedimentary rocks. A clue to this source is afforded by the relative amounts of the different “excess” volatiles. These are similar to the relative amounts of the same materials in gases escaping from volcanoes, fumaroles, and hot springs and in gases occluded in igneous rocks. Conceivably, therefore, the hydrosphere and atmosphere may have come almost entirely from such plutonic gases. During the crystallization of magmas, volatiles such as H 2 O and CO 2 accumulate in the remaining melt and are largely expelled as part of the final fractions. Volcanic eruptions and lava flows have brought volatiles to the earth's surface throughout the geologic past; but intrusive rocks are probably a much more adequate source of the constituents of the atmosphere and hydrosphere. Judged by the thermal springs of the United States, hot springs (carrying only 1 per cent or less of juvenile matter) may be the principal channels by which the “excess” volatiles have escaped from cooling magmas below. This mechanism fails to account for a continuous supply of volatiles unless it also provides for a continuous generation of new, volatile-rich magmas. Possibly such local magmas form by a continuous process of selective fusion of subcrustal rocks, to a depth of several hundred kilometers below the more mobile areas of the crust. This would imply that the volume of the ocean has grown with time. On this point, geologic evidence permits differences of interpretation; the record admittedly does not prove, but it seems consistent with, an increasing growth of the continental masses and a progressive sinking of oceanic basins. Perhaps something like the following mechanism could account for a continuous escape of volatiles to the earth's surface and a relatively uniform composition of sea water through much of geologic time: (1) selective fusion of lower-melting fractions from deep-seated, nearly anhydrous rocks beneath the unstable continental margins and geosynclines; (2) rise of these selected fractions (as granitic and hydrous magmas) and their slow crystallization nearer the surface; (3) essentially continuous isostatic readjustment between the differentiating continental masses and adjacent ocean basins; and (4) renewed erosion and sedimentation, with resulting instability of continental margins and mountainous areas and a new round of selective fusion below.

Geological Society of America Bulletin↗

USGS2012

Quaternary geologic map of the Havre 1° x 2° quadrangle

The Havre quadrangle encompasses approximately 16,084 km 2 (6,210 mi 2 ). The northern boundary is the Montana/Saskatchewan (U.S./Canada) boundary. The quadrangle is in the Northern Plains physiographic province and it includes parts of the Bearpaw Mountains, the Little Rocky Mountains, and the Boundary Plateau. The primary river is the Milk River. The ancestral Missouri River was diverted south of the Bearpaw Mountains by a Laurentide ice sheet. The fill in the buried ancestral valley at and southwest of Havre contains a complex stratigraphy of fluvial, glaciofluvial, ice-contact, glacial, lacustrine, and eolian deposits. The old valley east of Havre now is occupied by the Milk River. The map units are surficial deposits and materials, not landforms. Deposits that comprise some constructional landforms (e.g., ground-moraine deposits, end-moraine deposits, stagnation-moraine deposits, all composed of till) are distinguished for purposes of reconstruction of glacial history. Surficial deposits and materials are assigned to 24 map units on the basis of genesis, age, lithology or composition, texture or particle size, and other physical, chemical, and engineering characteristics. It is not a map of soils that are recognized in engineering geology, or of substrata or parent materials in which pedologic or agronomic soils are formed. Glaciotectonic (ice-thrust) structures and deposits are mapped separately, represented by a symbol. On the glaciated plains and on the Boundary Plateau the surficial deposits are glacial, ice-contact, glaciofluvial, catastrophic flood, alluvial, lacustrine, eolian, and colluvial deposits. In the Bearpaw Mountains and Little Rocky Mountains beyond the limit of Quaternary glaciation they are fluvial, colluvial, and mass-wasting deposits and residual materials. Tills of late Wisconsin and Illinoian ages are represented by map units. Tills of two pre-Illinoian glaciations are not mapped but are widespread in the subsurface and are identified in stratigraphic sections. Thirteen stratigraphic sections document a complex glacial and interglacial history in the quadrangle. Pliocene continental glaciation possibly is represented by erratic blocks of garnet gneiss and pegmatite from the Canadian Shield, perched high on drainage divides in the western Bearpaw Mountains. Glacial striations on bedrock, two boulder trains, and linear ice-molded landforms (primarily drumlins) indicate the possible presence of an east-southeast flowing ice stream in the Havre glacial lobe during late Wisconsin glaciation.

Montana↗