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Status and understanding of groundwater quality in the North San Francisco Bay Shallow Aquifer study unit, 2012; California GAMA Priority Basin Project (ver. 1.1, February 2018)

Groundwater quality in the North San Francisco Bay Shallow Aquifer study unit (NSF-SA) was investigated as part of the Priority Basin Project of the California Groundwater Ambient Monitoring and Assessment (GAMA) Program. The study unit is in Marin, Mendocino, Napa, Solano, and Sonoma Counties and included two physiographic study areas: the Valleys and Plains area and the surrounding Highlands area. The NSF-SA focused on groundwater resources used for domestic drinking water supply, which generally correspond to shallower parts of aquifer systems than that of groundwater resources used for public drinking water supply in the same area. The assessments characterized the quality of untreated groundwater, not the quality of drinking water. This study included three components: (1) a status assessment , which characterized the status of the quality of the groundwater resources used for domestic supply for 2012; (2) an understanding assessment , which evaluated the natural and human factors potentially affecting water quality in those resources; and (3) a comparison between the groundwater resources used for domestic supply and those used for public supply. The status assessment was based on data collected from 71 sites sampled by the U.S. Geological Survey for the GAMA Priority Basin Project in 2012. To provide context, concentrations of constituents measured in groundwater were compared to U.S. Environmental Protection Agency (EPA) and California State Water Resources Control Board Division of Drinking Water regulatory and non-regulatory benchmarks for drinking-water quality. The status assessment used a grid-based method to estimate the proportion of the groundwater resources that has concentrations of water-quality constituents approaching or above benchmark concentrations. This method provides statistically unbiased results at the study-area scale and permits comparisons to other GAMA Priority Basin Project study areas. In the NSF-SA study unit as a whole, inorganic constituents with human-health benchmarks were detected at high relative concentrations (RCs) in 27 percent of the shallow aquifer system, and inorganic constituents with secondary maximum contaminant levels (SMCL) were detected at high RCs in 24 percent of the system. The inorganic constituents detected at high RCs were arsenic, boron, fluoride, manganese, nitrate, iron, sulfate, and total dissolved solids (TDS). Organic constituents with human-health benchmarks were detected at high RCs in 1 percent of the shallow aquifer system. Of the 148 organic constituents analyzed, 30 constituents were detected, although only 1, chloroform, had a detection frequency greater than 10 percent. Natural and anthropogenic factors that could affect the groundwater quality were evaluated by using results from statistical testing of associations between constituent concentrations and values of potential explanatory factors. Groundwater age class (modern, mixed, or pre-modern), redox class (oxic or anoxic), aquifer lithology class (metamorphic, sedimentary, or volcanic), and dissolved oxygen concentrations were the explanatory factors that explained distribution patterns of most of the inorganic constituents best. Groundwater classified primarily as pre-modern or mixed in age was associated with higher concentrations of arsenic and fluoride than waters classified as modern. Anoxic or mixed redox conditions were associated with higher concentrations of boron, fluoride, and manganese. Similar patterns of association with explanatory variables were seen for inorganic constituents with aesthetic-based benchmarks detected at high concentrations. Nitrate and perchlorate had higher concentrations in oxic than in the anoxic redox class and were positively correlated with urban land use. The NSF-SA water-quality results were compared to those of the GAMA North San Francisco Bay Public-Supply Aquifer study unit (NSF-PA). The NSF-PA was sampled in 2004 and covers much of the same area as the NSF-SA, but focused on the deeper public-supply aquifer system. The comparison of the NSF-PA to the NSF-SA showed that there were more differences between the Valleys and Plains study areas of the two study units than between the Highlands study areas of the two study units. As expected from the shallower depth of wells, the NSF-SA Valleys and Plains study area had a lesser proportion of pre-modern age groundwater and greater proportion of modern age groundwater than the NSF-PA Valleys and Plains study area. In contrast, well depths and groundwater ages were not significantly different between the two Highlands study areas. Arsenic, manganese, and nitrate were present at high RCs, and perchlorate was detected in greater proportions of the NSF-SA Valleys and Plains study area than the NSF-PA Valleys and Plains study area.

California↗

Comparison of the results of enzyme-linked immunosorbent assay (ELISA) to mass-spectrometry based analytical methods for six unregulated contaminants in source water and finished drinking-water samples

Regulatory entities, such as the Minnesota Department of Health, monitor public water systems for conformance with Federal and State monitoring requirements and water-quality standards. Although some contaminants have Federal and (or) State regulations and guidance values, many contaminants, such as pesticides and pharmaceuticals, are unregulated in that only non-enforceable health-based guidance values have been assigned to them. Furthermore, because these contaminants are not regulated, commonly only limited resources are available to public water systems or regulatory entities to monitor them in drinking water. Focused screening efforts on contaminants that are frequently detected in the environment can provide information to help monitoring entities prioritize their sampling efforts. Here we assess the use of enzyme-linked immunosorbent assay (ELISA) method, a rapid, inexpensive screening method, as an alternative to more expensive methods to analyze source and finished drinking-water samples collected from public water systems throughout Minnesota for three commonly detected pesticides (atrazine, imidacloprid, and pyrethroids) and three commonly detected pharmaceuticals (caffeine, carbamazepine, and sulfamethoxazole). The ELISA results were compared to results provided by more advanced mass-spectrometry analytical methods at the U.S. Geological Survey National Water Quality Laboratory (NWQL) and SGS AXYS Analytical Services Ltd. (AXYS). Overall, these datasets are highly censored (>80 percent) and contain multiple reporting limits within and between laboratories. To discern agreement between paired contaminant group results (target contaminant plus immunologically similar contaminants) by ELISA and the advanced analytical methods at NWQL and AXYS, presence-absence agreement analysis was coupled with false negative and false positive analysis. Analysis of presence-absence agreement shows that ELISA has generally good agreement (77.9 to 100 percent) with both NWQL and AXYS for all unregulated contaminant groups. Imidicloprid, pyrethroids, and caffeine contaminant groups have relatively low false positivity rates (16, 6, and 5 percent, respectively) when analyzed by ELISA, which indicates the ELISA method, for these contaminant groups, could be experiencing low-level interference attributed to the detection of immunologically similar contaminants. Similarly, sulfamethoxazole has a low false positivity rate (0.8 percent), which indicates ELISA is likely not overestimating results for this contaminant group. Analyses for carbamazepine and sulfamethoxazole by ELISA resulted in low false negativity rates (1.6 and 0.8 percent, respectively), which indicates the ELISA method is likely not underestimating the results for this contaminant group. Conversely, the atrazine contaminant group has a high false negativity rate (84 percent), which indicates the method has a strong negative bias and that ELISA underestimates results for this contaminant. These qualitative results indicate that the ELISA method could potentially serve as a reliable and cost-effective screening method to help drinking water monitoring entities prioritize sampling efforts for analyzing carbamazepine and sulfamethoxazole in source and finished drinking-water samples collected from public water systems. At the same time, although ELISA did not prove to be a good screening method for atrazine, evaluation of ELISA results indicated that its use for screening imidacloprid, pyrethroids, and caffeine could be beneficial for water testing.

Minnesota↗

Hydrogeologic framework and extent of saltwater intrusion in Kings, Queens, and Nassau Counties, Long Island, New York

In 2016, the U.S. Geological Survey began a multiyear cooperative study with the New York State Department of Environmental Conservation to evaluate the sustainability of Long Island’s sole-source aquifer system through hydrogeologic mapping, compilation of groundwater chloride concentrations, and groundwater flow modeling. In the initial phase of the islandwide study, the hydrogeologic framework and extent of saltwater intrusion in aquifers in Kings, Queens, and Nassau Counties on western Long Island, N.Y., were investigated. The aquifer system underlying western Long Island has been under stress from pumping of public, irrigation (golf course), and industrial supply wells. Saltwater intrusion has occurred from surrounding embayments (East River, Long Island Sound, Jamaica Bay, and the Atlantic Ocean) due to pumping. Eighteen boreholes were drilled and cores taken during 2019–21 to collect hydrogeologic, geochemical, and geophysical data to delineate the complex subsurface hydrogeology and extent of saltwater intrusion within the study area. Evaluation of the new cores, reexamination of legacy core descriptions, and analysis of borehole geophysical logs was used to refine the previously published hydrogeologic framework of Pleistocene and Cretaceous unconsolidated sediments in the area, including delineation of a previously undefined hydrogeologic unit between the Magothy aquifer and the Raritan confining unit, herein named the “upper Raritan aquifer.” The upper Raritan aquifer was first recognized in southeastern Nassau County from an analysis of about 50 closely spaced boreholes with high-resolution core descriptions and gamma-ray (gamma) logs. Further analysis of borehole logs across the study area indicated that the upper Raritan aquifer was also present in Kings and Queens Counties. Nuclear magnetic resonance (NMR) logging was used for the first time on Long Island to provide estimates of the hydraulic properties of the major aquifer and confining units. Unlike other geophysical logs that record responses to the rock matrix and fluid properties and are strongly dependent on mineralogy, NMR logs record responses to the presence of hydrogen protons in the formation fluid to determine water fraction and pore-size distribution. NMR log analysis provided estimates of the clay-bound, capillary-bound, and mobile water fractions and hydraulic conductivity of aquifers and confining units penetrated by five wells in Nassau County. Pumpage for public-supply and industrial wells on Long Island began in the 1870s with small, localized suppliers of populated areas in Kings and Queens Counties. By 1904–16, pumpage for public water supply in Kings County averaged 21 million gallons per day, and averaged 37 million gallons per day in Queens County, mostly from the upper glacial aquifer. Saltwater intrusion was reported as early as the beginning of the 20th century and included the upper glacial-Jameco-Magothy and Lloyd-North Shore aquifer systems. By 1936, pumping in central Kings County created a major cone of depression in the water table extending to the south shore of much of Kings County and into southwestern Queens County. Saltwater intrusion has caused the shutdown of public-supply wells in Kings, Queens, and Nassau Counties. A large saltwater intrusion wedge in the Lloyd aquifer was indicated in southern Queens County in the early part of the 20th century, and the saltwater interface may have been onshore predevelopment. Most of Kings and Queens Counties are intruded with saltwater in both the upper glacial-Jameco-Magothy and Lloyd-North Shore aquifers systems. Saltwater increased during the 20th century and continues to increase to the present (2023) in the Lloyd-North Shore aquifer system in Great Neck and Manhasset Neck in northern Nassau County. A major wedge of saltwater intrusion in the upper glacial-Jameco-Magothy aquifer in southwestern Nassau County appears to be increasing.

New York↗

U.S. Geological Survey Trace Elements and related reports through 1953

This report combines and brings up-to-date the information previously given in Trace Elements Investigations Report 325, "Numerical list of U.S. Geological Survey Trace Elements Reports to April 30, 1953," and Trace Elements Investigations Report 301, "Topical index and bibliography of U.S. Geological Survey Trace Elements and related reports." Part I is a numerical list of U.S. Geological Survey Trace Elements Investigations and Memorandum reports. It supersedes TEI-325. This part lists not only reports (followed by a date) that have been transmitted to the U.S. Atomic Energy Commission, but also reports in preparation (followed by an asterisk) for which tentative titles were available on December 31, 1953. Reports that have been published are indicated by the abbreviation of the medium of publication. (See also part II.) Part II is a reference guide to Trace Elements and related reports that are available to the public; this part supersedes Part 2 of the TEI-301 (published as Geological survey Circular 281). These reports are grouped according to the type of publication or release. Abstracts published in Nuclear Science Abstracts are not included in Part II, although certain TEI and TEM reports, the abstracts of which have been published in NSA, are so indicated in Part I. Publications in process on December 31, 1953, are designated by an asterisk. Part III is a finding list of states, areas, and subjects. It is based on information derived mostly from the titles of reports and, where titles are of a general nature, from a cursory review of the reports. This list is not a complete index of the information given in Trace Elements and related reports, but is designed to find subjects of major interest. Because of the numerous entries for Colorado and Utah, information has been listed by counties and, where possible, by subject under these states. Other states have county listings only if a county is included in the title of a report; otherwise, areas may be listed separately under the state. Major subjects are listed separately in the index and also where appropriate under states. Analytical methods and subjects related to analytical research are listed under Analytical Methods and Research, but not separately throughout the index. Most mineralogic studies are included under the heading Mineralogy, but are not necessarily listed according to location. Part IV is a finding list of authors. The words “with” and “and” are used to indicate seniority of authorship. For example, a listing of Jones and Brown indicates that Jones is the senior author. A listing of Jones with Brown indicates that Brown is the senior author. In both parts III and IV all Trace Elements reports are listed, as well as other related reports that have not been issued as Trace Elements reports. The following standard abbreviations have been used: TEI, Trace Elements Investigations report; TEM, Trace Elements Memorandum report; P, Professional Paper; B, Bulletin; C, Circular; J, Journal; OF, open file; TIS, Technical Information Service release; NSA, Nuclear Science Abstracts; QM, Quadrangle Map Series; and OM, Oil and Gas map or Mineral Investigations map or report.

Trace Elements Investigations↗

Geologic investigations of radioactive deposits, semiannual progress report for June 1 to November 30, 1955

This report is a statement of progress during the six-months period from June 1 to November 30, 1955 on investigations of radioactive materials in the United States and Alaska, undertaken by the U.S. Geological Survey under the sponsorship of the U.S. Atomic Energy Commission. During the period the Geological Survey's program has been directed to an increasing extent toward the understanding of geologic conditions favorable for the concentration of uranium, rather than the search for minable deposits as such. This shift in emphasis is reflected in the decreased amount of exploration drilling during the period, and the accompanying increase in geologic programs of a long-range nature. The program is now directed toward a comprehensive understanding of the many factors involved in uranium geology, and the publication of reports that will make available information on all phases of the uranium program. Many investigations have progressed to the point where final reports are in preparation for future publication with the permission of the Atomic Energy Commission; for other investigations of a continuing nature it will be several years before final reports can be prepared. Formal publications (as distinguished from administrative Trace Elements Reports) published during the period include 10 Geological Survey Bulletins or Bulletin Chapters; 116 Geological Survey maps; 15 reports published in scientific journals; seven Trace Elements Reports sent to the Technical Information Service of the Atomic Energy Commission for distribution and sale to the public; and four Trace Elements reports placed on open file. In addition, a large number •of papers by geologists in the program were presented before scientific societies, and the 61 papers prepared for the United Nations International Conference .on the Peaceful Uses of Atomic Energy during the preceding report period were published by the United Nations.

Trace Elements Investigations↗

Social Values for Ecosystem Services, version 4.0 (SolVES 4.0)—Documentation and user manual

The geographic information system tool, Social Values for Ecosystem Services (SolVES), was developed to incorporate quantified and spatially explicit measures of social values into ecosystem service assessments. SolVES 4.0 provides an open-source version of SolVES, which was designed to assess, map, and quantify the social values of ecosystem services. Social values—the perceived, nonmarket values the public ascribes to ecosystem services, particularly cultural services, such as aesthetics and recreation—can be evaluated for various stakeholder groups. These groups are distinguishable by factors such as their attitudes and preferences regarding public uses (for example, motorized recreation and logging). As with previous versions, SolVES 4.0 derives a quantitative 10-point, social-values metric—the value index—from a combination of spatial and nonspatial responses to public value and preference surveys. The tool also calculates metrics characterizing the underlying environment, such as average distance to water and dominant landcover. SolVES 4.0 has been developed with Python using a QGIS user interface and a PostgreSQL database for required data. SolVES is integrated with Maxent maximum entropy modeling software to generate more complete social-value maps and offer robust statistical models describing the relation between the value index and explanatory environmental variables. A model’s goodness of fit to a primary study area and its potential performance in transferring social values to similar areas using value-transfer methods can be evaluated. SolVES 4.0 provides an improved open-source, public-domain tool for decision makers and researchers to evaluate the social values of ecosystem services and to facilitate discussions among diverse stakeholders regarding the tradeoffs among ecosystem services in a variety of biophysical and social contexts including mountain, forest, coastal, riparian, agricultural, and urban environments around the globe.

Techniques and Methods↗

Analysis of nitrate and volatile organic compound data for ground water in the Great Salt Lake Basins, Utah, Idaho, and Wyoming, 1980-98

In 1995, ground water was the source of drinking water to about 52 percent of the population served by public drinking water systems in the Great Salt Lake Basins study unit, which includes parts of Utah, Idaho, and Wyoming. Existing nitrate and volatile organic compound data for ground water collected in the study unit were compiled and summarized as part of the National Water-Quality Assessment Program’s objective to describe water-quality conditions in the Nation’s aquifers. Prerequisites for the inclusion of nitrate and volatile organic compound data into this retrospective analysis are that the data set is available in electronic form, the data were collected during 1980-98, the data set is somewhat regional in coverage, and the locations of the sampled sites are known. Ground-water data stored in the U.S. Geological Survey’s National Water Information System and the Idaho and Utah Public Drinking Water Systems databases were reviewed. Only the most recent analysis was included in the data sets if more than one analysis was available for a site. The National Water Information System data set contained nitrate analyses for water from 480 wells. The median concentration of nitrate was 1.30 milligrams per liter for the 388 values above minimum reporting limits. The maximum contaminant level for nitrate as established by the U.S. Environmental Protection Agency was exceeded in water from 10 of the 200 wells less than or equal to 150 feet deep and in water from 3 of 280 wells greater than 150 feet deep. The Public Drinking Water Systems data set contained nitrate analyses for water from 587 wells. The median concentration of nitrate was 1.12 milligrams per liter for the 548 values above minimum reporting limits. The maximum contaminant level for nitrate was exceeded at 1 site and 22 sites had concentrations equal to or greater than 5 milligrams per liter. The types of land use surrounding a well and the well depth were related to measured nitrate concentrations in the sampled ground water. Overall, water sampled from wells in rangeland areas had a lower median measured nitrate concentration (0.76 milligrams per liter) than water from areas with an agricultural or urban/residential land use (1.41 and 1.20 milligrams per liter, respectively). In the National Water Information System data set, the median measured nitrate concentration in water from urban/residential areas varied from 1.00 milligrams per liter for wells greater than 150 feet deep to 1.84 milligrams per liter for wells less than or equal to 150 feet deep. The Public Drinking Water Systems and the National Water Information System data sets contained analyses for most of the State and Federally regulated volatile organic compounds in water from about 368 and 74 wells, respectively. Fifteen different volatile organic compounds were detected at least once in ground water sampled from the Great Salt Lake Basins study unit. Water from 21 wells contained at least 1 volatile organic compound at detectable concentrations. About 68 percent of the volatile organic compounds detected were in water sampled from wells in Salt Lake County, Utah. Tetrachloroethylene was the most commonly detected volatile organic compound in ground water sampled from the study unit, present in 8 out of 442 samples. Maximum contaminant levels for tetrachloroethylene and 1,1-dichloroethylene as established by the U.S. Environmental Protection Agency were exceeded in water from one well each.

Idaho,Utah, Wyoming↗

Hydrogeology and extent of saltwater intrusion on Manhasset Neck, Nassau County, New York

Manhasset Neck, a peninsula on the northern shore of Long Island, N.Y., is underlain by unconsolidated deposits that form a sequence of aquifers and confning units. Ground water at several public-supply wells has been affected by the intrusion of saltwater from the surrounding embayments (Manhasset Bay, Long Island Sound, Hempstead Harbor). Twenty-two boreholes were drilled during 1992-96 for the collection of hydrogeologic, geochemical, and geophysical data to delineate the subsurface geology and the extent of saltwater intrusion within the peninsula. A series of continuous high-resolution seismic- reflection surveys was completed in 1993 and 1994 to delineate the character and extent of the hydrogeologic deposits beneath the embayments surrounding Manhasset Neck. The new drill-core data indicate two hydrogeologic units--the North Shore aquifer and the North Shore confining unit--where the Lloyd aquifer, Raritan confining unit, and the Magothy aquifer have been completely removed by glacial erosion. Water levels at selected observation wells were measured quarterly throughout the study. These data, and continuous water-level records, indicate that (1) the upper glacial (water-table) and Magothy aquifers are hydraulically connected and that their water levels do not respond to tidal fluctuations, and (2) the Lloyd and North Shore aquifers also are hydraulically connected, but their water levels do respond to pumping and tidal fluctuations. Offshore seismic-reflection surveys in the surrounding embayments, and drill-core samples, indicate at least four glacially eroded buried valleys with subhorizontal, parallel reflectors indicative of draped bedding that is interpreted as infilling by silt and clay. The buried valleys (1) truncate the surrounding coarse-grained deposits, (2) are asymmetrical and steep sided, (3) trend northwest-southeast, (4) are 2 to 4 miles long and about 1 mile wide, and (5) extend to more than 400 feet below sea level. Water from 12 public-supply wells screened in the Magothy and upper glacial aquifers contained volatile organic compounds in concentrations above the New York State Department of Health Drinking Water maximum contaminant levels, as did water from one public- supply well screened in the Lloyd aquifer and from two observation wells screened in the upper glacial aquifer. Five distinct areas of saltwater intrusion have been delineated in Manhasset Neck; three extend into the Lloyd and North Shore aquifers, and two extend into the upper glacial and Magothy aquifers. Borehole-geophysical-logging data indicate that several of these saltwater wedges range from a few feet to more than 125 feet in thickness and have sharp freshwater-saltwater interfaces, and that chloride concentrations within these wedges in 1997 ranged from 102 to 9,750 milligrams per liter. Several public-supply wells have either been shut down or are currently being affected by these saltwater wedges. Data show active saltwater intrusion in at least two of the wedges.

New York↗

History and hydrologic effects of ground-water use in Kings, Queens, and western Nassau Counties, Long Island, New York, 1800's through 1997

Ground-water withdrawals from the aquifers underlying Kings and Queens Counties varied temporally and spatially during the 20th century and caused extreme changes in water levels. The resultant lowering of water levels during periods of heavy pumping caused saltwater intrusion in nearshore areas and the migration of contaminants from land surface into deep aquifers. The recovery of water levels in response to countywide curtailment of pumping has resulted in the flooding of underground structures. Combined withdrawals for public and industrial supply in Kings and Queens Counties were greatest during the 1930's--about 130 million gallons per day. During this period, a large cone of depression developed in the water table in Kings County; within this depression, water levels were about 45 feet lower than in 1903. All pumping for public supply was halted in Kings County in 1947, and in Jamaica (in Queens County) in 1974. Water levels in Kings County had recovered by 1974 and have remained similar to those of 1903 since then, except for minor localized drawdowns due to industrial-supply or dewatering withdrawals. A large cone of depression that had formed in southeastern Queens County before 1974 has now (1997) disappeared. The estimated combined withdrawal for public supply and industrial supply in Kings and Queens Counties in 1996 was only about 50 million gallons per day. The water-level recoveries in the water-table and confined aquifers generally have resulted in the dilution and dispersion of residual salty and nitrate-contaminated ground water. The majority of recently sampled wells indicate stable or decreasing chloride and nitrate concentrations in all aquifers since 1983. Organic contaminants remain in ground water in Kings, Queens, and Nassau Counties, however; the most commonly detected compounds in 1992-96 were tetrachloroethene, trichloroethene, chloroform, and total trihalomethanes. Water samples from monitoring wells in Kings County indicate a greater number of occurrences of these compounds in the upper glacial aquifer than in the Jameco-Magothy aquifer, whereas samples from public-supply wells in Queens County indicated a greater number of occurrences in the Jameco- Magothy aquifer than in the upper glacial aquifer. This distribution suggests that organic contaminants were not drawn into the deeper aquifers in Kings County before 1947, when their use was limited and deep withdrawals were greatest, and (or) that the longer period of waterlevel recovery in Kings County than in Queens has allowed greater degradation, dilution, and dispersion of any organic contaminants that might have entered the deep aquifers before the cessation of pumping in 1947.

New York↗

Stable isotopes and volatile organic compounds along seven ground-water flow paths in divergent and convergent flow systems, southern California, 2000

Ground water is a major source of drinking water in southern California. In an effort to understand factors influencing the susceptibility of ground water tapped by public supply wells, the U.S. Geological Survey has undertaken studies in cooperation with the California State Water Resources Control Board. The vertical and lateral distribution of stable isotopes (deuterium and oxygen-18) and volatile organic compounds (VOC) were examined along seven ground-water flow paths in three urban ground-water basins in southern California: Central Basin in Los Angeles County, Main Basin in Orange County, and Bunker Hill Basin in San Bernardino County. Forty-seven monitoring wells and 100 public supply wells were sampled. The results of this study suggest that the direction of flow and perhaps the degree of confinement in an aquifer system are important controls on the distribution of VOCs. Ground-water flow in the Central and Main Basins in the southern California coastal plain is characterized as radially divergent, with ground-water flow directions moving outward from focused areas of recharge in the unconfined part of the aquifer system toward dispersed areas of discharge in the more confined part. In these basins, there is a volume of water containing VOCs that extends out into a volume of water containing no VOCs. This pattern suggests that radially divergent flow systems disperse VOCs in distal areas. The overall pattern also suggests that ground water in the pressure area is generally insulated from compounds introduced at land surface. These two factors?dispersion of VOCs due to divergence of flow and insulation from land-surface inputs?suggest that the susceptibility of public supply wells to surface contamination decreases with distance in radially divergent, well confined ground-water flow system. In the inland Bunker Hill Basin, ground-water flow is characterized as radially convergent; ground-water flow directions move inward from dispersed recharge areas in the unconfined part of the aquifer system, toward an area of focused discharge in the more confined part. The number of VOCs increased and the concentrations of individual VOCs increased, or remained the same, with increasing travel distance. Methyl tert-butyl ether was detected only in wells in the confined part of the aquifer system, suggesting that the confining units present in the distal part of the Bunker Hill Basin do not prevent VOCs from reaching ground water. These results suggest that VOCs in the Bunker Hill Basin are collected and concentrated as ground water moves downgradient because of radial convergenence of flow. They also suggest that ground water in the Bunker Hill Basin has an increasing opportunity to pick up VOCs introduced at land surface as it moves along a flow path. Some of the downgradient increase in VOC occurrence and concentration may be due to pumping that selectively removes cleaner ground water, thus leaving ground water containing more VOCs in the aquifer. These two factors?collection of VOCs due to convergence of flow and increasing opportunity to collect surficial contaminants perhaps due to a relative absence of confinement?suggest that the susceptibility of public supply wells to surface contamination increases with distance in radially convergent ground-water flow systems, particularly those that are unconfined.

Water-Resources Investigations Report↗

Estimated use of water in the Tennessee River watershed in 2000 and projections of water use to 2030

Estimates indicate that after increases in water withdrawals from 1965 to 1980 in the Tennessee River watershed, withdrawals declined from 1980 to 1985 and remained steady from 1985 to 1995. Water withdrawals in the Tennessee River watershed during 2000 averaged about 12,211 million gallons per day (Mgal/d) of freshwater for offstream uses?22 percent more than the 1995 estimate. The 2000 estimate is nearly the same as the estimate for 1980, the highest year of record, with 12,260 Mgal/d. The reuse potential of water from the Tennessee River is high because most of the water withdrawn for offstream use is returned to the river system. Besides water quality, reuse potential reflects the quantity of water available for subsequent uses and is gaged by consumptive use, which is the difference between water withdrawals and return flow. For the Tennessee River watershed, return flow was estimated to be 11,562 Mgal/d, or 95 percent of the water withdrawn during 2000. Total consumptive use accounts for the remaining 5 percent, or 649 Mgal/d. Estimates of water withdrawals by source indicate that during 2000, withdrawals from surface water accounted for 98 percent of the total withdrawals, or 11,996 Mgal/d, 23 percent more than during 1995. Total ground-water withdrawals during 2000 were 215 Mgal/d, or 17 percent less than during 1995. During 2000, thermoelectric power withdrawals were estimated to be 10,276 Mgal/d; industrial, 1,205 Mgal/d; public supply, 662 Mgal/d; and irrigation, 68.9 Mgal/d. Return flows were estimated to be: thermoelectric power, 10,244 Mgal/d; industrial, 942 Mgal/d; and public supply, 377 Mgal/d. Consumptive use was estimated to be: thermoelectric power, 32.2 Mgal/d; industrial, 263 Mgal/d; public supply, 285 Mgal/d; and irrigation, 68.9 Mgal/d. Each category of use affects the reuse potential of the return flows differently. The consumptive use in the river is comparatively small because most of the water withdrawn from the Tennessee River watershed is used for once-through cooling for the thermoelectric power and industrial sectors. Average per capita use for all offstream uses was 2,710 gallons per day per person in 2000, compared to the record high of 3,200 in 1975 and 1980. The intensity of use for the Tennessee River watershed as measured as a function of area was 298,489 gallons per day per square mile in 2000. In 2030, water withdrawals are projected to increase by about 15 percent to 13,990 Mgal/d. By category, water withdrawals are projected to increase as follows: thermoelectric power, 11 percent or 1,152 Mgal/d; industry, 31 percent or 368 Mgal/d; public supply, 35 percent or 232 Mgal/d; and irrigation, 37 percent or 25.2 Mgal/d. Total consumptive use is projected to increase about 51 percent or 334 Mgal/d to 980 Mgal/d. Per capita use in 2030 is calculated to be about 2,370 gallons per day, about 26 percent less than in 1980. Water transfers to the Tennessee-Tombigbee waterway for navigation lockages were estimated as 200 Mgal/d for 2000 and 800 Mgal/d for 2030. Water transfers for hydropower commitments through Barkley Canal averaged 3,361 Mgal/d for 2000 and are estimated to be an average of 4,524 Mgal/d in 2030.

Water-Resources Investigations Report↗

Ground-Water Quality and its Relation to Land Use on Oahu, Hawaii, 2000-01

Water quality in the main drinking-water source aquifers of Oahu was assessed by a one-time sampling of untreated ground water from 30 public-supply wells and 15 monitoring wells. The 384 square-mile study area, which includes urban Honolulu and large tracts of forested, agricultural, and suburban residential lands in central Oahu, accounts for 93 percent of the island's ground-water withdrawals. Organic compounds were detected in 73 percent of public-supply wells, but mostly at low concentrations below minimum reporting levels. Concentrations exceeded drinking-water standards in just a few cases: the solvent trichloroethene and the radionuclide radon-222 exceeded Federal standards in one public-supply well each, and the fumigants 1,2-dibromo-3-chloropropane (DBCP) and 1,2,3-trichloropropane (TCP) exceeded State standards in three public-supply wells each. Solvents, fumigants, trihalomethanes, and herbicides were prevalent (detected in more than 30 percent of samples) but gasoline components and insecticides were detected in few wells. Most water samples contained complex mixtures of organic compounds: multiple solvents, fumigants, or herbicides, and in some cases compounds from two or all three of these classes. Characteristic suites of chemicals were associated with particular land uses and geographic locales. Solvents were associated with central Oahu urban-military lands whereas fumigants, herbicides, and fertilizer nutrients were associated with central Oahu agricultural lands. Somewhat unexpectedly, little contamination was detected in Honolulu where urban density is highest, most likely as a consequence of sound land-use planning, favorable aquifer structure, and less intensive application of chemicals (or of less mobile chemicals) over recharge zones in comparison to agricultural areas. For the most part, organic and nutrient contamination appear to reflect decades-old releases and former land use. Most ground-water ages were decades old, with recharge dates ranging from pre-1940 to the present, and with most dates falling within the 1950s to 1980s time span. Several widely detected compounds were discontinued as long ago as the 1970s but have yet to be flushed from the ground-water system. Although large tracts of land in central Oahu have been converted from agriculture to residential urban use since the 1950s, water quality in the converted areas still more closely reflects the former agricultural land. It appears to be too early to detect a distinct water-quality signature characteristic of the newer urban use, although several urban turfgrass herbicides in use for just 10 years or so were detected in monitoring wells and may represent early arrivals of urban contaminants at the water table.

Water-Resources Investigations Report↗

Water-temperature data acquisition activities in the United States

Along with the growing interest in water quality during the last decade, the need for data on all types of water-quality parameters has also increased. One parameter of particular interest, because of its many ramifications, is temperature. It influences many of the chemical and physical processes that take place in water. The solubility of gases--for example, oxygen and carbon dioxide--and the solution of mineral matter in water are functions of temperature. Such physical properties as density and viscosity vary with temperature. Oxidation of organic materials, as well as algal and bacterial growth, is promoted or retarded by favorable or unfavorable temperatures. Further, temperature bears on the utility of water: as a source of public water supplies; for industrial use, particularly if the water is used for cooling; and in the field of recreation involving contact sports, fishing, and fish culture. In recent years, temperature changes resulting from inflow of heated industrial waste, particularly effluent from power generating plants, have increased the need for temperature data to determine the degree of change, its effect on ecology, and the effect of any remedial action. Thus, because of the many extensive and intensive effects, a large amount of temperature data is collected on surface and ground waters by many agencies throughout the country. Moreover, because of its importance, there is a widespread interest in temperature even by those who are not active collectors of the data themselves. The industrialist, the manager, the public official, and others at one time or another may have need for temperature data and may well raise the questions: Who is collecting temperature data? What is the extent of the activity? Where are the data being collected? The purpose of this report is to answer these questions. The information in the report is confined to the activities of Federal and non-Federal agencies. It is based on information furnished to the Office of Water Data Coordination, U.S. Geological Survey, and published in the "Catalog of Information on Water Data, Index to Water Quality Section, Edition 1970." This is one of four indexes, each of which is a separate section of the Catalog. Three of the indexes, "Index to Water-Quality Section," "Index to Surface-Water Section," and "Index to Ground-.Water Stations," contain information on data acquired on a recurrent basis at specific locations for a period of 3 years or more. The fourth section, "Index to Areal Investigations and Miscellaneous Activities," is concerned with specific projects or shorter-term data activities that involve field or laboratory measurements or observations not included in any other section of the Catalog. The Catalog is a record of activities throughout the country (and in some places along the international border between the United States and Canada) conducted by Federal and non-Federal agencies engaged in the acquisition of water data and who furnish such information for presentation in the Catalog. The Catalog itself is an outgrowth of an assignment to the Department of the Interior and in turn to the Geological Survey, by the Office of Management and Budget, through the medium of OMB Circular A-67. This Circular states in part that one of the assigned responsibilities will be maintenance of a "central catalog of information on...water data and on Federal activities being planned or conducted to acquire such data." As an extension of this activity, non-Federal agencies are solicited to participate in the program. In this report, information is presented by means of tables and illustrations preceded by brief explanations. It includes the agencies collecting the data, the number of stations located on surface and ground waters where temperature measurements are made, the distribution of stations by States and by the 21 regions of the Water Resources Council (WRC) (a Federal agency created in accordance with the Water Resources Planning Act of 1965), and the frequency of measurements. Acquisition activities were not reported for those areas left blank on some illustrations. The report does not contain the actual temperature data. For this information, the particular agency, Federal or non-Federal, acquiring the data will have to be contacted. However, a bibliography at the end of this report lists 194 references which contain temperature data. Many of these references, especially the publications of the Geological Survey, may be available in major public and university libraries and libraries of Federal and non-Federal agencies.

Water-Resources Investigations Report↗

Determination of water use in Rockford and Kankakee areas, Illinois

Amounts of water withdrawn, delivered, consumed, released, returned, and lost or gained during conveyance were determined for six communities--Rockford, Loves Park, North Park, Kankakee, Bourbonnais, and Bradley--served by the public-water systems in the Rockford and the Kankakee areas of Illinois. Water-use categories studied were commercial, industrial, domestic, and municipal uses; public supply; and sewage treatment. The availability and accuracy of water-use data are described, and water-use coefficients and methods of estimating water use are provided to improve the collection and the analysis of water-use information. Water-use data were obtained from all the water utilities and from 30 major water users in the Rockford and the Kankakee areas. Data were available for water withdrawals by water suppliers; deliveries by water suppliers to water users; returns by sewage-treatment plants and water users; releases by water users to sewers; and sewer-conveyance losses. Accuracy of the water-use data was determined from discharge measurements or reliability tests of water meters, or was estimated according to the completeness of the data. Accuracy of withdrawal and sewage-treatment-return data for the Rockford area and of withdrawal, delivery, industrial release, and sewage-treatment-return data for the Kankakee area was considered to be at least 90 percent. Where water-use data were inadequate or unavailable, various methods were used to estimate consumptive uses; releases; returns by commercial, domestic, and municipal users; and conveyance losses and gains. The methods focused on water budgeting to assure that water uses balanced. Consumptive uses were estimated by use of the consumption-budget method, the types-of-use method, consumptive-use ratios, the winter base-rate method, and the maximum lawn-watering method. The winter base-rate method provided the best domestic consumptive-use estimates, whose ratios (consumptive use from the winter base-rate method divided by deliveries and self-supply withdrawals), by community, ranged from 0.03 to 0.136 and averaged 0.068. The consumption-budget and types-of-use methods, as well as consumptive-use ratios, were used to estimate consumptive use for commercial, industrial, and municipal categories. Water budgeting was generally used to estimate releases, and conveyance losses and gains. Estimates of nonconsumptive uses by cooling systems, boilers, and lawn watering; data of deliveries to septic-system owners; and (or) water budgeting were used to estimate commercial, domestic, industrial, and municipal returns. Proportions of water use were similar in the Rockford and the Kankakee areas. Of the public-supply withdrawals in each area, about one-half was delivered for commercial and industrial uses; about one-third for domestic use; and about one-sixth for municipal use and public-supply conveyance losses.Consumptive use by all water users in the Rockford and the Kankakee areas was 13 +/- 1 percent, releases were 78 +/- 2 percent, and returns were 9 +/- 2 percent of deliveries and self-supply withdrawals. Total returns were greater than total withdrawals in the two areas because-of sewer-conveyance gains, which amounted to about 34 percent of the sewage-treatment returns for each area. Delivery rates (deliveries divided by the number of users [establishments or households]) and domestic per capita use were similar for all six communities. At a 95-percent confidence level, domestic delivery rates for each community range from 0.067 to 0.075 million gallons per household per year. Commercial delivery rates range from 0.277 to 0.535 million gallons per establishment per year. Delivery rates for all categories combined range from 0.100 to 0.192 million gallons per user per year. Domestic per capita use, which ranged from 67.2 to 71.0 gallons per day, averaged 69.2 +/- 1.1 gallons per day.

Water-Resources Investigations Report↗

Geohydrology and vertical distribution of volatile organic compounds in ground water, Fischer and Porter Company Superfund Site, Warminster, Bucks County, Pennsylvania

The Fischer and Porter Company Superfund Site is underlain by sedimentary rocks of the Upper Triassic Stockton Formation, which consists of interbedded siltstone, very-fine grained to coarse-grained sandstone, and conglomerate in crudely defined, upward fining cycles. These rocks form a complex, heterogeneous, leaky, multiaquifer system comprised of a series of gently dipping lithologic units with different hydraulic properties. Ground water is unconfined in the shallower part of the aquifer and confined or semiconfined in the deeper part of the aquifer. Water levels measured in monitor well clusters and borehole-flow measurements made in open boreholes show a downward hydraulic head gradient at the site, caused in part by the pumping of nearby, deep public-supply wells and the Fischer and Porter treatment system extraction wells. Downward borehole flow was measured at rates up to 9 gallons per minute. Aquifer-isolation tests were run in the six boreholes to obtain depth-discrete specific-capacity and water-quality data. On the basis of specific-capacity data for 27 isolated intervals, specific capacity is not related to depth. Water levels in monitor wells at the Fischer and Porter Site are greatly affected by the pumping of nearby public-supply wells, as well as the pumping of the Fischer and Porter treatment system extraction wells. Pumping of the public-supply wells causes daily water-level fluctuations in wells at the site as great as 5.3 feet. The shutdown of the Fischer and Porter treatment system extraction wells caused a rise in water level in all wells screened in the intermediate and deep zones. The rise in water level was as great as 4.3 feet in the intermediate zone and as great as 5.9 feet in the deep zone. The direction of ground-water flow is toward the north in the shallow and intermediate zones and toward the west and west-southwest in the deep zone. Ground-water discharge probably is to the unnamed tributary to Pennypack Creek north and west of the site. Volatile organic compounds (VOC's) were detected in most depth-discrete water samples. No general trend of increasing or decreasing concentrations of VOC's with depth were observed, and none of the isolated intervals had highly elevated concentrations of VOC's. Observed fairly constant concentrations of VOC's with depth are the result of the downward head gradient and the former presence of open boreholes on the site. The downward head gradient and pumping of nearby, deep public-supply wells caused the vertical migration and outward movement of VOC's into the aquifer through former supply and monitor wells of open-hole construction in the main area of contamination.

Pennsylvania↗

Influences of environmental settings on aquatic ecosystems in the Apalachicola-Chattahoochee-Flint River basin

The watershed boundary of the Apalachicola-Chattahoochee-Flint (ACF) River basin defines an aquatic ecosystem whose water quality is the result of complex interactions of natural and human influences on land and water resources. Topics relating to the basin's environmental setting-its physical, biological, and cultural characteristics-are summarized to provide an understanding of factors that influence water quality and the health of aquatic ecosystems. The ACF River basin lies partly in southwestern Georgia, southeastern Alabama, and northwestern Florida and covers 19,800 square miles in the Blue Ridge, the Piedmont, and the Coastal Plain Provinces. The basin includes the drainages of the Chattahoochee River and the Flint River, which meet to form the Apalachicola River. The Apalachicola River flows into the Gulf of Mexico at Apalachicola Bay. Basin hydrology and water quality are influenced by 16 mainstem reservoirs, 13 of which are on the Chattahoochee River. Ground water in the basin is contained in six aquifers-the surficial aquifer system, the Floridan aquifer system, the Claiborne aquifer, the Clayton aquifer, the Providence aquifer, and the crystalline-rock aquifer. Physiography, climate, and hydrology of the ACF River basin provide natural conditions that support a rich and abundant diversity of plants and animals. Although most of the ACF River basin has been altered by human activities, the basin's environment is noteworthy for its remaining biological diversity and the role it plays in sustaining biological productivity in Apalachicola Bay. The Bay produces 90 percent of Florida's and 13 percent of the Nation's oyster harvest; and functions as a nursery for penaeid shrimp, blue crabs, and a variety of fin fish. The diversity of the basin's aquatic fauna is noteworthy because the basin is home to (1) the largest number of fish species among Gulf Coast drainages east of the Mississippi River, (2) the largest assemblage of freshwater fish in Florida, (3) the largest number of mollusc species among western Florida drainages, and (4) the highest species density of amphibians and reptiles on the continent north of Mexico. Population of the ACF River basin in 1990 was estimated at 2.6 million. Nearly 90 percent of the total population lived in Georgia, and nearly 60 percent lived in the Metropolitan Atlanta area. The 1990 basin population is projected to increase by 15 percent to 3.0 million by the year 2000, and by 30 percent to 3.4 million by 2010. The largest increases in populations are projected for the Metropolitan Atlanta area. In 1972-76, approximately 59 percent of the basin was covered by forest, 29 percent was agricultural, 5 percent was wetland, 4 percent was urban, and 3 percent was water or barren land. Most of the original land cover of the basin has been transformed by human activity. Timber is the basin's largest cash crop and most forests consist of second-growth stands or large acreages of planted pine. The dominant agricultural land use in the Piedmont Province is pasture and confined feeding for dairy, livestock, and poultry production. Row-crop agriculture, orchards, and silviculture are most common in the Coastal Plain Province. The top five crops in order from most to least acres harvested in 1990 were peanuts, corn, soybeans, wheat, and cotton. The water in the basin is used for public and industrial supply, irrigation, power generation, navigation, and recreation. Although most public-supply withdrawals in the Blue Ridge and Piedmont Provinces are from surface-water sources, with the exception of counties near or immediately below the Fall Line, all publicly supplied water in the Coastal Plain is withdrawn from ground-water sources. Ground water supplied 18 percent of the basin's population served by public supply. Total water withdrawn in the ACF River basin in 1990 was 2,098 million gallons per day (Mgal/d), of which Georgia withdrew 82 percent and Florida and Alabama each withdrew 9 percent. Power generation is the single largest water use. Sixteen of the basin's 22 power generating plants are located along the mainstem of the Chattahoochee River. The U.S. Army Corps of Engineers maintains a navigation channel from the mouth of the Apalachicola River to Columbus, Ga., on the Chattahoochee River and to Bainbridge, Ga., on the Flint River. Water quality in the basin is influenced by the operation of 137 municipal wastewater-treatment facilities. In 1990, 354 Mgal/d of municipal wastewater was discharged within the ACF River basin. Eighty-eight percent of the wastewater was discharged into the Chattahoochee River basin, 10.6 percent into the Flint River basin, and 1.4 percent into the Apalachicola River basin. Two-thirds of the 938 stream miles in the Georgia portion of the ACF River basin having water quality that does not meet or only partially meets the designated-use criteria in the Chattahoochee River basin. The Chattahoochee River is the most heavily-used water resource both in the ACF River basin and in Georgia. Urban runoff or unknown nonpoint sources are cited as the causes of water-quality regulations in 72 percent of violations. The remaining causes primarily are combined sewer overflows in the Atlanta area, and discharges from municipal or industrial treatment facilities with inadequate treatment capabilities or operational deficiencies.

Alabama, Florida, Georgia↗

Estimated use of water in Lincoln County, Wyoming, 1993

Total water use in Lincoln County, Wyoming in 1993 was estimated to be 405,000 Mgal (million gallons). Water use estimates were divided into nine categories: public supply, self-supplied domestic, commercial, irrigation, livestock, indus ial, mining, thermoelectric power, and hydro- electric power. Public supply water use, estimated to be 2,160 Mgal, primarily was obtained from springs and wells. Shallow ground water wells were the primary source of self-supplied domestic water, estimate to be 1.7 Mgal, and 53 percent of those wells were drilled to a depth of 100 feet or less. Commercial water use, estimated to be 117 Mgal, was obtained from public-supply systems. Surface water supplied an estimated 153,000 Mgal of the total estimated water use of 158,000 Mgal for irrigation in 1993. Sprinkler and flood irrigation technology were used about equally in the northern part of Lincoln County and flood irrigation was the primary technology used in the southern part. Livestock, industrial, and mining were not major water users in Lincoln County in 1993. Livestock water use totaled an estimated 203 Mgal. Industrial water use was estimated to be 120 Mgal from self-supplied water sources and 27 Mgal from public supplied water source Mining water use was an estimated 153 Mgal. Thermoelectric and hydroelectric power generation used surface water sources. Thermoelectric power water use was an estimated 5,900 Mgal. An estimated 238,000 Mgal of water was used to generate hydroelectc power at Fontenelle Reservoir on the Green River.

Water-Resources Investigations Report↗

Ground-water resources in the vicinity of Cortland, Trumbull County, Ohio

The city of Cortland lies on the southeast ern shoreline of the 12.3-square-mile Mosquito Creek Lake in Trumbull County, Ohio. Cortland relies upon public wells completed in the Cussewago Sandstone for potable water. The Cussewago Sandstone, the principal aquifer in the study area, is a subcrop of the glaciofluvial sediments in the lake; the unit dips gently towards the southeast. Thickness of the Cussewago Sandstone ranges from less than 20 feet in south-central Bazetta Township to 152 feet in Cortland. The Bedford Shale overlies and confines the Cussewago Sandstone and separates it hydraulically from the Berea Sandstone. The Bedford Shale and Berea Sandstone are not a prolific source of ground water. In places, the Bedford Shale was completely eroded away prior to deposition of the Berea Sandstone. Where the Bedford Shale is absent, such as at the City of Cortland North Well Field, the Berea Sandstone and Cussewago Sandstone are likely in hydraulic connection. Throughout most of the study area, the Cussewago Sandstone is a confined aquifer. Ground-water flow is to the east and southeast. Pumping at both Cortland well fields has created cones of depression in the potentiometric surface. These cones of depression cause a local reversal in ground-water flow immediately east of both well fields. The absence of detectable concentrations of tritium in water samples from wells completed in the Cussewago Sandstone at Cortland indicates that ground water predates the atmospheric nuclear testing of the 1950's. Ground water requires about 60 to 110 years to flow from the Cussewago Sandstone subcrop of the glaciofluvial sediments in the lake to the Cortland public-supply wells. A comparison of aquifer storage and pumpage in the study area shows that the Cussewago Sandstone receives adequate recharge to support current withdrawals by Cortland public-supply wells. In the immediate vicinity of Cortland- between Route 305 and the Bazetta-Mecca Town ship line and between the Mosquito Creek Lake shoreline and the Bazetta-Fowler Township line-approximately 15,000 million gallons of water currently in the Cussewago Sandstone can be gravity drained from the aquifer without considering recharge to the aquifer. The 15,000 million gallons is equivalent to about 75 years of withdrawals by Cortland public-supply wells at current (1990-95) rates. A numerical flow model rather than an analytical or semianalytical model would be needed to accurately simulate flow and ground-water withdrawals in the Cussewago Sandstone in the vicinity of Cortland. Computer simulations of flow would likely involve conditions where a fully saturated, confined Cussewago Sandstone becomes a partially saturated aquifer.

Water-Resources Investigations Report↗