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At least 937 records · Page 52Linked to original sources

Twenty-first-century projections of shoreline change along inlet-interrupted coastlines

Sandy coastlines adjacent to tidal inlets are highly dynamic and widespread landforms, where large changes are expected due to climatic and anthropogenic influences. To adequately assess these important changes, both oceanic (e.g., sea-level rise) and terrestrial (e.g., fluvial sediment supply) processes that govern the local sediment budget must be considered. Here, we present novel projections of shoreline change adjacent to 41 tidal inlets around the world, using a probabilistic, reduced complexity, system-based model that considers catchment-estuary-coastal systems in a holistic way. Under the RCP 8.5 scenario, retreat dominates (90% of cases) over the twenty-first century, with projections exceeding 100 m of retreat in two-thirds of cases. However, the remaining systems are projected to accrete under the same scenario, reflecting fluvial influence. This diverse range of response compared to earlier methods implies that erosion hazards at inlet-interrupted coasts have been inadequately characterised to date. The methods used here need to be applied widely to support evidence-based coastal adaptation.

Nature--Scientific Reports↗

The global carbon dioxide budget

The increase in atmospheric CO 2 levels during the last deglaciation was comparable in magnitude to the recent historical increase. However, global CO 2 budgets for these changes reflect fundamental differences in rates and in sources and sinks. The modern oceans are a rapid net CO 2 sink, whereas the oceans were a gradual source during the deglaciation. Unidentified terrestrial CO 2 sinks are important uncertainties in both the deglacial and recent CO 2 budgets. The deglacial CO 2 budget represents a complexity of long-term dynamic behavior that is not adequately addressed by current models used to forecast future atmospheric CO 2 levels.

Science↗

Volcano spacing and plate rigidity

In-plane stresses, which accompany the flexural deformation of the lithosphere under the load of adjacent volcanoes, may govern the spacing of volcanoes in hotspot provinces. Specifically, compressive stresses in the vicinity of a volcano prevent new upwelling in this area, forcing a new volcano to develop at a minimum distance that is equal to the distance in which the radial stresses change from compressional to tensile (the inflection point). If a volcano is modeled as a point load on a thin elastic plate, then the distance to the inflection point is proportional to the thickness of the plate to the power of 3/4. Compilation of volcano spacing in seven volcanic groups in East Africa and seven volcanic groups of oceanic hotspots shows significant correlation with the elastic thickness of the plate and matches the calculated distance to the inflection point. In contrast, volcano spacing in island arcs and over subduction zones is fairly uniform and is much larger than predicted by the distance to the inflection point, reflecting differences in the geometry of the source and the upwelling areas.

Geology↗

Aeromagnetic legacy of early Paleozoic subduction along the Pacific margin of Gondwana

Comparison of the aeromagnetic signatures and geology of southeastern Australia and northern Victoria Land, Antarctica, with similar data from ancient subduction zones in California and Japan, provides a framework for reinterpretation of the plate tectonic setting of the Pacific margin of early Paleozoic Gondwana. In our model, the plutons in the Glenelg (south-eastern Australia) and Wilson (northern Victoria Land) zones formed the roots of continental-margin magmatic arcs. Eastward shifting of arc magmatism resulted in the Stavely (south-eastern Australia) and Bowers (northern Victoria Land) volcanic eruptions onto oceanic forearc crust. The turbidites in the Stawell (southeastern Australia) and Robertson Bay (northern Victoria Land zones) shed from the Glenelg and Wilson zones, respectively, were deposited along the trench and onto the subducting oceanic plate. The margin was subsequently truncated by thrust faults and uplifted during the Delamerian and Ross orogenies, leading to the present-day aeromagnetic signatures.

Geology↗

High-resolution seismic-reflection data offshore of Dana Point, southern California borderland

The U.S. Geological Survey collected high-resolution shallow seismic-reflection profiles in September 2006 in the offshore area between Dana Point and San Mateo Point in southern Orange and northern San Diego Counties, California. Reflection profiles were located to image folds and reverse faults associated with the San Mateo fault zone and high-angle strike-slip faults near the shelf break (the Newport-Inglewood fault zone) and at the base of the slope. Interpretations of these data were used to update the USGS Quaternary fault database and in shaking hazard models for the State of California developed by the Working Group for California Earthquake Probabilities. This cruise was funded by the U.S. Geological Survey Coastal and Marine Catastrophic Hazards project. Seismic-reflection data were acquired aboard the R/V Sea Explorer, which is operated by the Ocean Institute at Dana Point. A SIG ELC820 minisparker seismic source and a SIG single-channel streamer were used. More than 420 km of seismic-reflection data were collected. This report includes maps of the seismic-survey sections, linked to Google Earth? software, and digital data files showing images of each transect in SEG-Y, JPEG, and TIFF formats.

Open-File Report↗

Ideas and perspectives: A strategic assessment of methane and nitrous oxide measurements in the marine environment

>In the current era of rapid climate change, accurate characterization of climate-relevant gas dynamics – namely production, consumption, and net emissions – is required for all biomes, especially those ecosystems most susceptible to the impact of change. Marine environments include regions that act as net sources or sinks for numerous climate-active trace gases including methane (CH4) and nitrous oxide (N2O). The temporal and spatial distributions of CH4 and N2O are controlled by the interaction of complex biogeochemical and physical processes. To evaluate and quantify how these mechanisms affect marine CH4 and N2O cycling requires a combination of traditional scientific disciplines including oceanography, microbiology, and numerical modeling. Fundamental to these efforts is ensuring that the datasets produced by independent scientists are comparable and interoperable. Equally critical is transparent communication within the research community about the technical improvements required to increase our collective understanding of marine CH4 and N2O. A workshop sponsored by Ocean Carbon and Biogeochemistry (OCB) was organized to enhance dialogue and collaborations pertaining to marine CH4 and N2O. Here, we summarize the outcomes from the workshop to describe the challenges and opportunities for near-future CH4 and N2O research in the marine environment.

Biogeosciences↗

Satellite observations of the 2016–2017 eruption of Bogoslof volcano: Aviation and ash fallout hazard implications from a water-rich eruption

Satellite data (GOES, VIIRS, MODIS, AVHRR) were used in near real-time during the 2016–2017 eruption of Bogoslof volcano, Alaska, to detect explosive eruptive activity and to characterize the resulting volcanic clouds. This study examines satellite data to estimate volcanic cloud heights and mass eruption rates for 47 of the 70 explosive events. Eighteen of the volcanic clouds reached an altitude in excess of 8.5 km asl, where they posed a potential hazard to aviation. We estimate eruption rates were in the range of 10 4 –10 7 kg/s. Eruption durations were available for 28 events, and the total mass of these events was 5.7 × 10 10 kg. Most of the explosions occurred from submarine vents, producing volcanic clouds with water-rich characteristics in satellite data. We infer that these water-rich (phreatomagmatic) events contained ice-coated ash particles, which changed their visible and multispectral characteristics. Only two of the explosions produced clouds with satellite characteristics that would be considered ash-rich. We conclude that these events were relatively dry eruptions with limited access to ocean water. Although some of the explosive events transitioned from submarine to subaerial vents, we observed no change in the character of the volcanic clouds during these transitions. We speculate that enhanced removal of fine-grained volcanic ash likely occurred due to aggregation, with implications for modeling ash transport and fallout. We conclude that the majority of Bogoslof’s water-rich volcanic clouds did contain volcanic ash despite the lack of conventional “ash signature” in satellite data. This has implications for satellite monitoring of future water-rich/shallow submarine eruptions.

Alaska↗

A new deglacial climate and sea-level record from 20 to 8 ka from IODP381 site M0080, Alkyonides Gulf, eastern Mediterranean

Records of relative sea-level rise for the last deglaciation are mostly limited to coral reef records and geophysical model estimates, but observational data from regions with temperate climates is sparse. We present a new relative climatic and regional sea-level rise record for glacial Termination 1 (Marine Isotope Stages [MIS] 2–1) based on ostracode paleoecology from the upper 8 m of the International Ocean Discovery Program (IODP) Site M0080 collected on Expedition 381, in the Gulf of Alkyonides, eastern Corinth basin of the Mediterranean Sea. Results show a series of major faunal transitions from lacustrine (Ponto-Caspian, Lake Corinth) glacial-age assemblages to fully marine (Mediterranean) interglacial assemblages between 20 and 8 ka. During glacial and early deglacial intervals, the Gulf of Alkyonides was characterized by non-marine lacustrine conditions with episodic sediment input from coastal, saline lake environments. Relatively stable lake shoreline conditions marked by the distinctive Tuberoloxoconcha sp. Existed from ∼17.5 to 15 ka. During the peak deglacial interval, the BØlling-AllerØd (B-A, ∼15–13.5 ka), rapid sea-level rise is indicated by a fully marine ostracode fauna colonization, which persisted from 13.5 to 7.5 ka (Late Pleistocene-Early to Middle Holocene).

Quaternary Science Reviews↗

Seasonal comparisons of sea ice concentration estimates derived from SSM/I, OKEAN, and RADARSAT data

The Special Sensor Microwave Imager (SSM/I) microwave satellite radiometer and its predecessor SMMR are primary sources of information for global sea ice and climate studies. However, comparisons of SSM/I, Landsat, AVHRR, and ERS-1 synthetic aperture radar (SAR) have shown substantial seasonal and regional differences in their estimates of sea ice concentration. To evaluate these differences, we compared SSM/I estimates of sea ice coverage derived with the NASA Team and Bootstrap algorithms to estimates made using RADARSAT, and OKEAN-01 satellite sensor data. The study area included the Barents Sea, Kara Sea, Laptev Sea, and adjacent parts of the Arctic Ocean, during October 1995 through October 1999. Ice concentration estimates from spatially and temporally near-coincident imagery were calculated using independent algorithms for each sensor type. The OKEAN algorithm implemented the satellite's two-channel active (radar) and passive microwave data in a linear mixture model based on the measured values of brightness temperature and radar backscatter. The RADARSAT algorithm utilized a segmentation approach of the measured radar backscatter, and the SSM/I ice concentrations were derived at National Snow and Ice Data Center (NSIDC) using the NASA Team and Bootstrap algorithms. Seasonal and monthly differences between SSM/I, OKEAN, and RADARSAT ice concentrations were calculated and compared. Overall, total sea ice concentration estimates derived independently from near-coincident RADARSAT, OKEAN-01, and SSM/I satellite imagery demonstrated mean differences of less than 5.5% (S.D.<9.5%) during the winter period. Differences between the SSM/I NASA Team and the SSM/I Bootstrap concentrations were no more than 3.1% (S.D.<5.4%) during this period. RADARSAT and OKEAN-01 data both yielded higher total ice concentrations than the NASA Team and the Bootstrap algorithms. The Bootstrap algorithm yielded higher total ice concentrations than the NASA Team algorithm. Total ice concentrations derived from OKEAN-01 and SSM/I satellite imagery were highly correlated during winter, spring, and fall, with mean differences of less than 8.1% (S.D.<15%) for the NASA Team algorithm, and less than 2.8% (S.D.<13.8%) for the Bootstrap algorithm. Respective differences between SSM/I NASA Team and SSM/I Bootstrap total concentrations were less than 5.3% (S.D.<6.9%). Monthly mean differences between SSM/I and OKEAN differed annually by less than 6%, with smaller differences primarily in winter. The NASA Team and Bootstrap algorithms underestimated the total sea ice concentrations relative to the RADARSAT ScanSAR no more than 3.0% (S.D.<9%) and 1.2% (S.D.<7.5%) during cold months, and no more than 12% and 7% during summer, respectively. ScanSAR tended to estimate higher ice concentrations for ice concentrations greater than 50%, when compared to SSM/I during all months. ScanSAR underestimated total sea ice concentration by 2% compared to the OKEAN-01 algorithm during cold months, and gave an overestimation by 2% during spring and summer months. Total NASA Team and Bootstrap sea ice concentration estimates derived from coincident SSM/I and OKEAN-01 data demonstrated mean differences of no more than 5.3% (S.D.<7%), 3.1% (S.D.<5.5%), 2.0% (S.D.<5.5%), and 7.3% (S.D.<10%) for fall, winter, spring, and summer periods, respectively. Large disagreements were observed between the OKEAN and NASA Team results in spring and summer for estimates of the first-year (FY) and multiyear (MY) age classes. The OKEAN-01 algorithm and data tended to estimate, on average, lower concentrations of young or FY ice and higher concentrations of total and MY ice for all months and seasons. Our results contribute to the growing body of documentation about the levels of disparity obtained when seasonal sea ice concentrations are estimated using various types of satellite data and algorithms.

Remote Sensing of Environment↗

Wide-angle seismic constraints on the evolution of the deep San Andreas plate boundary by Mendocino triple junction migration

Recent, wide-angle seismic observations that constrain the existence and structure of a mafic layer in the lower crust place strong constraints on the evolution of the San Andreas plate boundary system in northern and central California. Northward migration of the Mendocino Triple Junction and the subducted Juan de Fuca lithospheric slab creates a gap under the continent in the new strike-slip system. This gap must be filled by either asthenospheric upwelling or a northward migrating slab attached to the Pacific plate. Both processes emplace a mafic layer, either magmatic underplating or oceanic crust, beneath the California Coast Ranges. A slab of oceanic lithosphere attached to the Pacific plate is inconsistent with the seismic observation that the strike-slip faults cut through the mafic layer to the mantle, detaching the layer from the Pacific plate. The layer could only be attached to the Pacific plate if large vertical offsets and other complex structures observed beneath several strike-slip faults are original oceanic structures that are not caused by the faults. Otherwise, if oceanic slabs exist beneath California, they do not migrate north to fill the growing slab gap. The extreme heat pulse created by asthenospheric upwelling is inconsistent with several constraints from the seismic data, including a shallower depth to the slab gap than is predicted by heat flow models, seismic velocity and structure that are inconsistent with melting or metamorphism of the overlying silicic crust, and a high seismic velocity in the upper mantle. Yet either the Pacific slab model or the asthenospheric upwelling model must be correct. While the mafic material in the lower crust could have been emplaced prior to triple junction migration, the deeper slab gap must still be filled. A preexisting mafic layer does not reduce the inconsistencies of the Pacific slab model. Such material could, however, compensate for the decrease in mafic magma that would be produced if asthenospheric upwelling occurred at a lower temperature. These low temperatures, however, may be inconsistent with asthenospheric rheology.

California, Oregon↗

Petrogenesis of basaltic volcanic rocks from the Pribilof Islands, Alaska, by melting of metasomatically enriched depleted lithosphere, crystallization differentiation, and magma mixing

The Pribilof Islands, Alaska, are located in the Bering Sea in a continental intraplate setting. In this study we examine the petrology and geochemistry of volcanic rocks from St. Paul (0??54-0??003 Ma) and St. George (2??8-1??4 Ma) Islands, the two largest Pribilof Islands. Rocks from St. George can be divided into three groups: group 1 is a high-MgO, low-SiO. 2 suite composed primarily of basanites; group 2 is a high-MgO, high-SiO 2 suite consisting predominantly of alkali basalts; group 3 is an intermediate- to low-MgO suite that includes plagioclase-phyric subalkali basalts and hawaiites. Major and trace element geochemistry suggests that groups 1 and 2 formed by small-degree partial melting of amphibole-bearing to amphibole-free garnet peridotite. Group 1 rocks were the earliest melts produced from the most hydrous parts of the mantle, as they show the strongest geochemical signature of amphibole in their source. The suite of rocks from St. Paul ranges from 14??4 to 4??2 wt % MgO at relatively constant SiO 2 contents (43??1-47??3 wt %). The most primitive St. Paul rocks are modeled as mixtures between magmas with compositions similar to groups 1 and 2 from St. George Island, which subsequently fractionated olivine, clinopyroxene, and spinel to form more evolved rocks. Plagioclase-phyric group 3 rocks from St. George are modeled as mixtures between an evolved melt similar to the evolved magmas on St. Paul and a fractionated group 2 end-member from St. George. Mantle potential temperatures estimated for primitive basanites and alkali basalts are ???1400??C and are similar to those of mid-ocean ridge basalts (MORB). Similarly, 87 Sr/. 86 Sr and 143 Nd/. 144 Nd values for all rocks are MORB-like, in the range of 0??702704-0??703035 and 0??513026-0??513109, respectively. 208 Pb/. 204 Pb vs 206 Pb/. 204 Pb values lie near the MORB end-member but show a linear trend towards HIMU (high time-integrated 238 U/. 204 Pb). Despite isotopic similarities to MORB, many of the major and trace element characteristics are similar to those of ocean island basalts (OIB), including enrichment in alkalis and incompatible trace elements. These characteristics are interpreted to indicate that their mantle source experienced an ancient melt-removal event that is reflected in depleted radiogenic isotopic compositions and was then re-enriched by metasomatism that elevated incompatible trace element contents, but was too young to produce a time-integrated change in radiogenic isotopic ratios. Evidence suggests that the Pribilof Island basalts did not form in either a plume or a back-arc basin tectonic setting. Rather, they were produced by melting of metasomatically hydrated upper mantle peridotite at relatively low temperatures and were able to erupt at the surface through extensional or transtensional faults that served as conduits for the magmas. ?? The Author 2009. Published by Oxford University Press.

Journal of Petrology↗

Climate regimes and water temperature changes in the Columbia River: bioenergetic implications for predators of juvenile salmon

We examined how climatic regime shifts may have affected predation rates on juvenile Pacific salmonids (Oncorhynchus spp.) by northern squawfish (Ptychocheilus oregonensis, also called northern pikeminnow), smallmouth bass (Micropterus dolomieu), and walleye (Stizostedion vitreum) in the Columbia River. During 1933-1996, oceanic, coastal, and freshwater indices of climate were highly correlated, and an index for the Columbia River Basin suggested that climate shifts may have occurred about 1946, 1958, 1969, and 1977. Summer water temperature varied as much as 2??C between climate periods. We used a bioenergetics model for northern squawfish, the most important piscivore, to predict that predation on salmonids would have been 26-31% higher during two periods with relatively warm spring-summer water temperatures (1933-1946, 1978-1996) than during an extremely cold period (1947-1958). Predicted predation rates of northern squawfish were 68-96% higher in the warmest year compared with the coldest year. Predation rates of smallmouth bass and walleye on juvenile salmonids varied among climate periods similar to rates predicted for northern squawfish. Climatic effects need to be understood in both freshwater and nearshore marine habitats, since growth rates of salmon populations are especially sensitive to mortality during early life stages.

Columbia River Basin↗

Performance metrics for the assessment of satellite data products: An ocean color case study

Performance assessment of ocean color satellite data has generally relied on statistical metrics chosen for their common usage and the rationale for selecting certain metrics is infrequently explained. Commonly reported statistics based on mean squared errors, such as the coefficient of determination (r 2 ), root mean square error, and regression slopes, are most appropriate for Gaussian distributions without outliers and, therefore, are often not ideal for ocean color algorithm performance assessment, which is often limited by sample availability. In contrast, metrics based on simple deviations, such as bias and mean absolute error, as well as pair-wise comparisons, often provide more robust and straightforward quantities for evaluating ocean color algorithms with non-Gaussian distributions and outliers. This study uses a SeaWiFS chlorophyll-a validation data set to demonstrate a framework for satellite data product assessment and recommends a multi-metric and user-dependent approach that can be applied within science, modeling, and resource management communities.

Optics Express↗

Sea‐level rise will drive divergent sediment transport patterns on fore reefs and reef flats, potentially causing erosion on atoll islands

Atoll reef islands primarily consist of unconsolidated sediment, and their ocean‐facing shorelines are maintained by sediment produced and transported across their reefs. Changes in incident waves can alter cross‐shore sediment exchange and, thus, affect the sediment budget and morphology of atoll reef islands. Here we investigate the influence of sea level rise and projected wave climate change on wave characteristics and cross‐shore sediment transport across an atoll reef at Kwajalein Island, Republic of the Marshall Islands. Using a phase‐resolving model, we quantify the influence on sediment transport of quantities not well captured by wave‐averaged models, namely, wave asymmetry and skewness and flow acceleration. Model results suggest that for current reef geometry, sea level, and wave climate, potential bedload transport is directed onshore, decreases from the fore reef to the beach, and is sensitive to the influence of flow acceleration. We find that a projected 12% decrease in annual wave energy by 2100 CE has negligible influence on reef flat hydrodynamics. However, 0.5–2.0 m of sea level rise increases wave heights, skewness, and shear stress on the reef flat and decreases wave skewness and shear stress on the fore reef. These hydrodynamic changes decrease potential sediment inputs onshore from the fore reef where coral production is greatest but increase potential cross‐reef sediment transport from the outer reef flat to the beach. Assuming sediment production on the fore reef remains constant or decreases due to increasing ocean temperatures and acidification, these processes have the potential to decrease net sediment delivery to atoll islands, causing erosion.

Journal of Geophysical Research – Earth Surface↗

Paleozoic magmatism and porphyry Cu-mineralization in an evolving tectonic setting in the North Qilian Orogenic Belt, NW China

The NWW-striking North Qilian Orogenic Belt records the Paleozoic accretion&ndash;collision processes in NW China, and hosts Paleozoic Cu&ndash;Pb&ndash;Zn mineralization that was temporally and spatially related to the closure of the Paleo Qilian-Qinling Ocean. The Wangdian Cu deposit is located in the eastern part of the North Qilian Orogenic Belt, NW China. Copper mineralization is spatially associated with an altered early Paleozoic porphyritic granodiorite, which intruded tonalites and volcaniclastic rocks. Alteration zones surrounding the mineralization progress outward from a potassic to a feldspar-destructive phyllic assemblage. Mineralization consists mainly of quartz-sulfide stockworks and disseminated sulfides, with ore minerals chalcopyrite, pyrite, molybdenite, and minor galena and sphalerite. Gangue minerals include quartz, orthoclase, biotite, sericite, and K-feldspar. Zircon LA-ICPMS U&ndash;Pb dating of the ore-bearing porphyritic granodiorite yielded a mean 206 Pb/ 238 U age of 444.6 &plusmn; 7.8 Ma, with a group of inherited zircons yielding a mean U&ndash;Pb age of 485 &plusmn; 12 Ma, consistent with the emplacement age (485.3 &plusmn; 6.2 Ma) of the barren precursor tonalite. Rhenium and osmium analyses of molybdenite grains returned model ages of 442.9 &plusmn; 6.8 Ma and 443.3 &plusmn; 6.2 Ma, indicating mineralization was coeval with the emplacement of the host porphyritic granodiorite. Rhenium concentrations in molybdenite (208.9&ndash;213.2 ppm) suggest a mantle Re source. The tonalities are medium-K calc-alkaline. They are characterized by enrichment of light rare-earth elements (LREEs) and large-ion lithophile elements (LILEs), depletion of heavy rare-earth elements (HREEs) and high-field-strength elements (HFSEs), and minor negative Eu anomalies. They have &epsilon; Hf ( t ) values in the range of +3.6 to +11.1, with two-stage Hf model ages of 0.67&ndash;1.13 Ga, suggesting that the ca. 485 Ma barren tonalites were products of arc magmatism incorporating melts from the mantle wedge and the lithosphere. In contrast, the 40-m.y.-younger ore-bearing porphyritic granodiorite is sub-alkaline and peraluminous. They are enriched in LREEs and LILEs, depleted in HFSEs, and show weak negative Eu anomalies. They display &epsilon; Hf ( t ) values of captured or inherited zircons in the range of +8.5 to +10.0, and younger two-stage Hf model ages of 0.78 Ga and 0.86 Ga, similar to those of ca. 485 Ma tonalite. The ca. 445 Ma zircons have &epsilon; Hf ( t ) values of &minus;2.1 to +9.9, with two-stage Hf model ages of 0.75&ndash;1.27 Ga. Moreover, they have relatively high oxygen fugacity than that of the precursor barren tonalite. The ca. 445 Ma magmas at Wangdian thus formed in a subduction setting, and incorporated melts from the subduction-modified lithosphere that had previously been enriched by additions of chalcophile and siderophile element-rich materials by the earlier magmatism and metasomatism during the Paleo Qilian-Qinling Ocean subduction event.

North Qilian Orogenic Belt↗

Ice and ocean constraints on early human migrations into North America along the Pacific Coast

Founding populations of the first Americans likely occupied parts of Beringia during the Last Glacial Maximum (LGM). The timing, pathways, and modes of their southward transit remain unknown, but blockage of the interior route by North American ice sheets between ~26 and 14 cal kyr BP (ka) favors a coastal route during this period. Using models and paleoceanographic data from the North Pacific, we identify climatically favorable intervals when humans could have plausibly traversed the Cordilleran coastal corridor during the terminal Pleistocene. Model simulations suggest that northward coastal currents strengthened during the LGM and at times of enhanced freshwater input, making southward transit by boat more difficult. Repeated Cordilleran glacial-calving events would have further challenged coastal transit on land and at sea. Following these events, ice-free coastal areas opened and seasonal sea ice was present along the Alaskan margin until at least 15 ka. Given evidence for humans south of the ice sheets by 16 ka and possibly earlier, we posit that early people may have taken advantage of winter sea ice that connected islands and coastal refugia. Marine ice-edge habitats offer a rich food supply and traversing coastal sea ice could have mitigated the difficulty of traveling southward in watercraft or on land over glaciers. We identify 24.5 to 22 ka and 16.4 to 14.8 ka as environmentally favorable time periods for coastal migration, when climate conditions provided both winter sea ice and ice-free summer conditions that facilitated year-round marine resource diversity and multiple modes of mobility along the North Pacific coast.

Pacific Coast↗

An evaluation of temporal changes in sediment accumulation and impacts on carbon burial in Mobile Bay, Alabama, USA

The estuarine environment can serve as either a source or sink of carbon relative to the coastal ocean carbon budget. A variety of time-dependent processes such as sedimentation, carbon supply, and productivity dictate how estuarine systems operate, and Mobile Bay is a system that has experienced both natural and anthropogenic perturbations that influenced depositional processes and carbon cycling. Sediments from eight box cores provide a record of change in bulk sediment accumulation and carbon burial over the past 110 years. Accumulation rates in the central part of the basin (0.09 g cm −2 ) were 60–80 % less than those observed at the head (0.361 g cm −2 ) and mouth (0.564 g cm −2 ) of the bay. Sediment accumulation in the central bay decreased during the past 90 years in response to both anthropogenic (causeway construction) and natural (tropical cyclones) perturbations. Sediment accumulation inevitably increased the residence time of organic carbon in the oxic zone, as observed in modeled remineralization rates, and reduced the overall carbon burial. Such observations highlight the critical balance among sediment accumulation, carbon remineralization, and carbon burial in dynamic coastal environments. Time-series analysis based solely on short-term observation would not capture the long-term effects of changes in sedimentation on carbon cycling. Identifying these relationships over longer timescales (multi-annual to decadal) will provide a far better evaluation of coastal ocean carbon budgets.

Alabama↗

Stable isotope reference materials and scale definitions – Outcomes of the 2024 IAEA experts meeting

The participants of the 12 th International Atomic Energy Agency (IAEA) meeting on stable isotope reference materials reached a consensus, acknowledging the existence and use of two carbon isotope delta scales: the VPDB (Vienna Peedee belemnite) scale and the VPDB-LSVEC (LSVEC - lithium carbonate prepared by H. J. Svec). Conversion models between the two scales can be established and used but introduce uncertainty. A format for isotope delta scale definition was agreed upon and was used to define the two carbon isotope delta scales and the two main oxygen isotope delta scales, VSMOW-SLAP (Vienna Standard Mean Ocean Water–Standard Light Antarctic Precipitation) and VPDB. Confirmation or identification of a second-scale–defining point is still necessary for the nitrogen and sulfur isotope delta scales. Efforts are encouraged to improve consistency among laboratories in the isotopic analysis of “non-exchangeable hydrogen” in bulk organic materials and oxygen in carbonates using the phosphoric acid reaction. Additional topics discussed include (1) need for improvement in reference materials for accurate greenhouse gas isotopic analyses; (2) reference materials under production by the IAEA, the US Geological Survey (USGS), and the US National Institute of Standards and Technology (NIST); (3) methods for value and uncertainty assignment of reference materials; and (4) calculation of carbon-13 isotope delta and oxygen-18 isotope delta of CO 2 measured by dual-inlet isotope ratio mass spectrometry.

Rapid Communications in Mass Spectrometry↗