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At least 937 records · Page 52Linked to original sources

USGS2004

Chemical Data for Detailed Studies of Irrigation Drainage in the Salton Sea Area, California, 1995?2001

The primary purpose of this report is to present all chemical data from the Salton Sea area collected by the U.S. Geological Survey between 1995 and 2001. The data were collected primarily for the Department of the Interior's National Irrigation Water Quality Program (NIWQP). The report also contains a brief summary and citation to investigations done for the NIWQP between 1992 and 1995. The NIWQP began studies in the Salton Sea area in 1986 to evaluate effects on the environment from potential toxins, especially selenium, in irrigation-induced drainage. This data report is a companion to several reports published from the earlier studies and to interpretive publications that make use of historical and recent data from this area. Data reported herein are from five collection studies. Water, bottom material, and suspended sediment collected in 1995-96 from the New River, the lower Colorado River, and the All-American Canal were analyzed for elements, semi-volatile (extractable) organic compounds, and organochlorine compounds. Sufficient suspended sediment for chemical analyses was obtained by tangential-flow filtration. A grab sample of surficial bottom sediment collected from near the deepest part of the Salton Sea in 1996 was analyzed for 44 elements and organic and inorganic carbon. High selenium concentration confirmed the effective transfer (sequestration) of selenium into the bottom sediment. Similar grab samples were collected 2 years later (1998) from 11 locations in the Salton Sea and analyzed for elements, as before, and also for nutrients, organochlorine compounds, and polycyclic aromatic hydrocarbons. Nutrients were measured in bottom water, and water-column profiles were obtained for pH, conductance, temperature, and dissolved oxygen. Element and nutrient concentrations were obtained in 1999 from cores at 2 of the above 11 sites, in the north subbasin of the Salton Sea. The most-recent study reported herein was done in 2001 and contains element data on suspended material isolated by continuous-flow centrifugation on samples collected in transects extending out from the Whitewater, the Alamo, and the New Rivers into the Salton Sea. Chemical data on suspended sediment and bottom material from tributory rivers and the Salton Sea itself show that many insoluble constituents, including selenium and DDE, are concentrated in the fine-grained, organic- and carbonate-rich bottom sediment from deep areas near the center of the Salton Sea. Data also show that selenium and arsenic are markedly enriched in seston (plankton, partially-degraded algal detritus, and mineral matter that compose suspended particulates in the lake) collected just below the water surface in the Salton Sea. This result indicates that bio-concentration in primary producers in the water column provides an important pathway whereby high selenium residues accumulate in fish and fish-eating birds at the Salton Sea.

Scientific Investigations Report↗

USGS2010

A deposit model for Mississippi Valley-Type lead-zinc ores

This report is a descriptive model of Mississippi Valley-Type (MVT) lead-zinc deposits that presents their geological, mineralogical and geochemical attributes and is part of an effort by the U.S. Geological Survey Mineral Resources Program to update existing models and develop new models that will be used for an upcoming national mineral resource assessment. This deposit modeling effort by the USGS is intended to supplement previously published models for use in mineral-resource and mineral-environmental assessments. Included in this report are geological, geophysical and geochemical assessment guides to assist in mineral resource estimation. The deposit attributes, including grade and tonnage of the deposits described in this report are based on a new mineral deposits data set of all known MVT deposits in the world. Mississippi Valley-Type (MVT) lead-zinc deposits are found throughout the world but the largest, and more intensely researched deposits occur in North America. The ores consist mainly of sphalerite, galena, and generally lesser amounts of iron sulfides. Silver is commonly an important commodity, whereas Cu is generally low, but is economically important in some deposits. Gangue minerals may include carbonates (dolomite, siderite, ankerite, calcite), and typically minor barite. Silicification of the host rocks (or quartz gangue) is generally minor, but may be abundant in a few deposits. The deposits have a broad range of relationships with their host rocks that includes stratabound, and discordant ores; in some deposits, stratiform and vein ore are important. The most important characteristics of MVT ore deposits are that they are hosted mainly by dolostone and limestone in platform carbonate sequences and usually located at flanks of basins, orogenic forelands, or foreland thrust belts inboard of the clastic rock-dominated passive margin sequences. They have no spatial or temporal relation to igneous rocks, which distinguishes them from skarn or other intrusive rock-related Pb-Zn ores. Abundant evidence has shown that the ore fluids were derived mainly from evaporated seawater and were driven within platform carbonates by large-scale tectonic events. MVT deposits formed mainly during the Phanerozoic with more than 80 percent of the deposits hosted in Phanerozoic rocks and less than 20 percent in Precambrian rocks. Phanerozoic-hosted MVT deposits also account for 94 percent of total MVT ore, and 93 percent of total MVT lead and zinc metal. Many MVT deposits formed during Devonian to Permian time, corresponding to a series of intense tectonic events during assimilation of Pangea. The second most important period for MVT deposit genesis was Cretaceous to Tertiary time when microplate assimilation affected the western margin of North America and Africa-Eurasia. Many subtypes or alternative classifications have been applied to MVT deposits. These alternative classifications reflect geographic and or specific geological features that some workers believe set them apart as unique (for example, Appalachian-, Alpine-, Reocin-, Irish-, Viburnum trend-types). However, we do not consider these alternative classifications or sub-types to be sufficiently different to warrant using them. This report also describes the geoenvironmental characteristic of MVT deposits. The response of MVT ores in the supergene environment is buffered by their placement in carbonate host rocks which commonly results in near-neutral associated drainage water. The geoenvironmental features and anthropogenic mining effects presented in this report illustrates this important environmental aspect of MVT deposits which separates them from other deposit types (especially coal, VHMS, Cu-porphyry, SEDEX, acid-sulfate polymetallic vein).

Scientific Investigations Report↗

USGS2006

Comparative evaluation of short-term leach tests for heavy metal release from mineral processing waste

Evaluation of metal leaching using a single leach test such as the Toxicity Characteristic Leaching Procedure (TCLP) is often questionable. The pH, redox potential (Eh), particle size and contact time are critical variables in controlling metal stability, not accounted for in the TCLP. This paper compares the leaching behavior of metals in mineral processing waste via short-term extraction tests such as TCLP, Field Leach Test (FLT) used by USGS and deionized water extraction tests. Variation in the extracted amounts was attributed to the use of different particle sizes, extraction fluid and contact time. In the controlled pH experiments, maximum metal extraction was obtained at acidic pH for cationic heavy metals such as Cu, Pb and Zn, while desorption of Se from the waste resulted in high extract concentrations in the alkaline region. Precipitation of iron, caused by a pH increase, probably resulted in co-precipitation and immobilization of Cu, Pb and Zn in the alkaline pH region. A sequential extraction procedure was performed on the original waste and the solid residue from the Eh-pH experiments to determine the chemical speciation and distribution of the heavy metals. In the as-received waste, Cu existed predominantly in water soluble or sulfidic phases, with no binding to carbonates or iron oxides. Similar characteristics were observed for Pb and Zn, while Se existed mostly associated with iron oxides or sulfides. Adsorption/co-precipitation of Cu, Se and Pb on precipitated iron hydroxides was observed in the experimental solid residues, resulting in metal immobilization above pH 7.

Science of the Total Environment↗

USGS2024

An accuracy assessment of the surface reflectance product from the EMIT imaging spectrometer

The Earth surface Mineral dust source InvesTigation (EMIT) is an imaging spectrometer launched to the International Space Station in July 2022 to measure the mineral composition of Earth’s dust-producing regions. We present a systematic accuracy assessment of the EMIT surface reflectance product in two parts. First, we characterize the surface reflectance product’s overall performance using multiple independent vicarious calibration field experiments with hand-held and automated field spectrometers. We find that the EMIT surface reflectance product has a standard error of ±1.0 % in absolute reflectance units for temporally coincident observations. Discrepancies rise to ±2.7 % for spectra acquired at different dates and times of day, which we attribute mainly to changes in solar geometry. Second, we develop an error budget that explains the differences between EMIT and in-situ field spectrometer data. We find that uncertainties in spatial footprints, field spectroscopy, and the EMIT-reported measurement were sufficient to explain discrepancies in most cases. Our approach did not detect any systematic calibration or reflectance errors in the timespan considered. Together, these findings demonstrate that a space-based imaging spectrometer can acquire high-quality spectra across a wide range of observational and atmospheric conditions.

Nevada↗

USGS2020

Soil organic carbon stocks and sequestration rates of inland, freshwater wetlands: Sources of variability and uncertainty

Impacts of land use, specifically soil disturbance, are linked to reductions of soil organic carbon (SOC) stocks. Correspondingly, ecosystem restoration is promoted to sequester SOC to mitigate anthropogenic greenhouse gas emissions, which are exacerbating global climate change. Restored wetlands have relatively high potential to sequester carbon compared to other ecosystems, but SOC accumulation rates are variable, which leads to high uncertainty in sequestration rates. To assess soil properties and carbon sequestration rates of freshwater mineral soil wetlands, we analyzed an extensive database of SOC concentrations from the Prairie Pothole Region (549 wetlands over 160,000 km 2 ), which is considered one of the largest wetland ecosystems in North America. We demonstrate that SOC of wetland catchments varies among inner, transition, toe slope, and upland landscape positions (LSPs), as well as among land uses and soil depth segments. Soil organic carbon concentrations were greatest in the inner portion of the catchment (66 Mg ha −1 ) and progressively decrease towards the upland LSP (43 Mg ha −1 ). We also conducted a regional extrapolation based on LSP- and land-use-specific SOC stocks, and estimated that wetland and upland areas of PPR wetland catchments contain 141 and 178 Tg of SOC in the upper 15 cm of the soil profile, respectively. Regressing SOC by restoration age (years restored) showed that sequestration rates, which differ by LSP and depth, ranged from 0.35 to 1.10 Mg ha −1 year −1 . Using these SOC sequestration rates, along with data from natural and cropland reference sites, we estimated that it takes 20 to 64 years for SOC levels of restored wetlands to return to natural reference conditions, depending on LSP and depth segment. Accounting for LSP reduces uncertainty and should refine future assessments of the greenhouse gas mitigation potential from wetland restoration.

Iowa, Minnesota, Montana, North Dakota, South Dako↗

USGS1994

Circum-North Pacific tectonostratigraphic terrane map

The companion tectonostratigraphic terrane and overlap assemblage of map the Circum-North Pacific presents a modern description of the major geologic and tectonic units of the region. The map illustrates both the onshore terranes and overlap volcanic assemblages of the region, and the major offshore geologic features. The map is the first collaborative compilation of the geology of the region at a scale of 1:5,000,000 by geologists of the Russian Far East, Japanese, Alaskan, Canadian, and U.S.A. Pacific Northwest. The map is designed to be a source of geologic information for all scientists interested in the region, and is designed to be used for several purposes, including regional tectonic analyses, mineral resource and metallogenic analyses (Nokleberg and others, 1993, 1994a), petroleum analyses, neotectonic analyses, and analyses of seismic hazards and volcanic hazards. This text contains an introduction, tectonic definitions, acknowledgments, descriptions of postaccretion stratified rock units, descriptions and stratigraphic columns for tectonostratigraphic terranes in onshore areas, and references for the companion map (Sheets 1 to 5). This map is the result of extensive geologic mapping and associated tectonic studies in the Russian Far East, Hokkaido Island of Japan, Alaska, the Canadian Cordillera, and the U.S.A. Pacific Northwest in the last few decades. Geologic mapping suggests that most of this region can be interpreted as a collage of fault-bounded tectonostratigraphic terranes that were accreted onto continental margins around the Circum- . orth Pacific mainly during the Mesozoic and Cenozoic (Fujita and ewberry, 1983; 1987; Parfenov, 1984, 1991; Howell, 1985; Watson and Fujita, 1985; Parfenov and Natal'in, 1984; Jones and others. 1987; Monger and Berg, 1987, Fujita and Cook. 1990; Zonenshain and others. 1990; Natal'in, 1991, 1993; Moore and others, 1992; Silberling and others, 1992; Nokleberg and others. 1992, 1993, 1994a; Parfenov and others. 1993; Plaflcer and Berg, 1994; Tabor, 1994). This map is the result of extensive geologic mapping and associated tectonic studies in the Russian Far East, Hokkaido Island of Japan, Alaska, the Canadian Cordillera, and the U.S.A. Pacific Northwest in the last few decades. Geologic mapping suggests that most of this region can be interpreted as a collage of fault-bounded tectonostratigraphic terranes that were accreted onto continental margins around the Circum- . orth Pacific mainly during the Mesozoic and Cenozoic (Fujita and ewberry, 1983; 1987; Parfenov, 1984, 1991; Howell, 1985; Watson and Fujita, 1985; Parfenov and Natal'in, 1984; Jones and others. 1987; Monger and Berg, 1987, Fujita and Cook. 1990; Zonenshain and others. 1990; Natal'in, 1991, 1993; Moore and others, 1992; Silberling and others, 1992; Nokleberg and others. 1992, 1993, 1994a; Parfenov and others. 1993; Plaflcer and Berg, 1994; Tabor, 1994). On the companion map and in the descriptions bel?w· terranes are interpreted according to inferred tectonic environments. These environments are (I) cratonai; (2) passive continental margin; (3) metamorphosed continental margin; (4) continental-margin arc; (5) island arc; (6) oceanic crust, seamount, and ophiolite; (7) accretionary wedge and subduction zone: (8) turbidite basin; and (9) metamorphic for terranes that are too highly-deformed and metamorphosed to de~ermine the original tectonic environment. For terranes with complex geologic histories, the chosen color indicates the tectonic environment most prevalent during this history of the terrane. The tectonic environments inf~rred for igneous rocks are both temporal and genetic. The temporal environments are preaccretion and postaccretion. The genetic environments are subduction-related, rift-related, and collisional (anatectic)- related. In addition to terranes, the map also depicts postaccretion units that include: (I) Cenozoic and Mesozoic overlap assemblages of sedimentary and volcanic rocks that are deposited across two or more terranes that formed generally after accretion of most terranes in the region; (2) Cenozoic and Mesozoic basinal deposits that occur within a terrane or on the craton; (3) plutonic rocks. The postaccretion igneous units are identified by age-lithologic abbreviations and by name. These overlap assemblages and basinal deposits formed mainly during sedimentation and magmatism that occurred after accretion of terranes to each other or to a continental margin. Overlap assemblages provide minimum ages on the timing of accretion of terranes. Some Cenozoic and Mesozoic overlap assemblages and basinal deposits, as well as fragments of terranes, are extensively offset by movement along postaccretion faults. In addition, in onshore areas, the map depicts major preaccretion plutonic rocks that are limited to individual terranes. and in offshore areas. the map depicts major oceanic plates,-ocean floor magnetic lineations. oceanic spreading ridges, and seamounts. The map consists of five sheets. Sheets I and 2 depict, at a scale of I :5.000.000. the tectonostratigraphic terranes. preaccretion plutonic rocks, and postaccretion Cenozoic and Mesozoic overlap sedimentary, volcanic. and plutonic assemblages, and basinal deposits for the Circum- orth Pacific including the Russian Far East, northern Hokkaido Island of Japan, Alaska. the Canadian Cordillera, part of the U.S.A. Pacific Northwest. and adjacent offshore areas. Sheet 3 provides the list of map units for Sheets I and 2. Sheet 4 is a index map showing generalized onshore terranes and overlap assemblages for onshore parts of the Circum-North Pacific at a scale of I: I 0,000,000. Sheet 4 is a guide to the more complicated onshore features depicted on Sheets I and 2. Sheet 5 is an index map showing the major geographic regions for the Circum-North Pacific. Significant differences exist between the representation of onshore and offshore geology on Sheets I and 2. These are: (I) compared to the onshore part of the map, the offshore part is depicted in a more schematic fashion because of more limited data and because the offshore terranes and early Cenozoic and older overlap assemblages generally are obscured by extensive late Cenozoic sedimentary cover that is not shown unless thicker than two kilometers; (2) marginal contacts of offshore Cenozoic and Cretaceous sedimentary basins do not match contacts of onshore Cenozoic and Cretaceous sedimentary units because offshore basins are limited to those regions with sediment thicknesses greater than two kilometers; (3) stratigraphic columns, included at the end of this explanation. are provided only for onshore terranes because the geology of offshore terranes is generally less well-known; and (4) for simplicity, the major onshore Cenozoic sedimentary basins are generally not defined and described separately because the onshore part of the map is designed to emphasize terranes and overlap volcanic assemblages that are crucial for both for tectonic and metallogenic analyses published elsewhere (Nokleberg and others, 1993, 1994a). Several key geologic sources were used in the compilation of the map. For Alaska. the basic outcrop pattern for the map is from Beikman (1980), Gehrels and Berg (1992, 1994). Barker and others ( 1994). Brew (1994), and Moli-Stalcup and others ( 1994b). The distribution of terranes is from Jones and others (1987) and Monger and Berg (1987), with modification by Grantz and other (1991 ). Worall (199 1 ), okleberg and others (1993, 1994a), the cited references, and the Alaskan co-authors of this report. For the Canadian Cordillera. the basic outcrop pattern is from Monger and Berg ( 1987), Wheeler and other (1988). and Wheeler and McFeeley ( 1991) with modifications by the Canadian authors. For the northern part of the Russian Far East. the basic outcrop pattern is from So unov (1985) with modifications by the Russian authors. For the outhern part of the Russian Far East, the basic outcrop pattern is from Krasny (1991) and Bazhanov and Oleinik ( 1986) with modification by the Russian authors. The Russian Far East part of the map is the first attempt to define and delineate terranes in that region. In their compilation. the Russian authors utilized the methodology of U.S.A. and Canadian geologists. Because this map is the first attempt to display the terranes. Cenozoic and Mesozoic overlap assemblages. basinal deposit , and plutonic belts of the Russian Far East. the Russian author will appreciate constructive sugge tions for improving the map.

Open-File Report↗

USGS2000

Detection of crystalline hematite mineralization on Mars by the Thermal Emission Spectrometer: evidence for near-surface water

The Thermal Emission Spectrometer (TES) instrument on the Mars Global Surveyor (MGS) mission has discovered a remarkable accumulation of crystalline hematite (α-Fe 2 O 3 ) that covers an area with very sharp boundaries approximately 350 by 350–750 km in size centered near 2°S latitude between 0° and 5°W longitude (Sinus Meridiani). Crystalline hematite is uniquely identified by the presence of fundamental vibrational absorption features centered near 300, 450, and >525 cm −1 and by the absence of silicate fundamentals in the 1000 cm −1 region. Spectral features resulting from atmospheric CO 2 , dust, and water ice were removed using a radiative transfer model. The spectral properties unique to Sinus Meridiani were emphasized by removing the average spectrum of the surrounding region. The depth and shape of the hematite fundamental bands show that the hematite is crystalline and relatively coarse grained (>5–10 μm). Diameters up to and greater than hundreds of micrometers are permitted within the instrumental noise and natural variability of hematite spectra. Hematite particles <5–10 μm in diameter (as either unpacked or hard-packed powders) fail to match the TES spectra. The spectrally derived areal abundance of hematite varies with particle size from ∼10% (>30 μm diameter) to 40–60% (10 μm diameter). The hematite in Sinus Meridiani is thus distinct from the fine-grained (diameter <5–10 μm), red, crystalline hematite considered, on the basis of visible, near-IR data, to be a minor spectral component in Martian bright regions like Olympus-Amazonis. Sinus Meridiani hematite is closely associated with a smooth, layered, friable surface that is interpreted to be sedimentary in origin. This material may be the uppermost surface in the region, indicating that it might be a late stage sedimentary unit or a layered portion of the heavily cratered plains units. We consider five possible mechanisms for the formation of coarse-grained, crystalline hematite. These processes fall into two classes depending on whether they require a significant amount of near-surface water: the first is chemical precipitation that includes origin by (1) precipitation from standing, oxygenated, Fe-rich water (oxide iron formations), (2) precipitation from Fe-rich hydrothermal fluids, (3) low-temperature dissolution and precipitation through mobile ground water leaching, and (4) formation of surface coatings, and the second is thermal oxidation of magnetite-rich lavas. Weathering and alteration processes, which produce nanophase and red hematite, are not consistent with the coarse, crystalline hematite observed in Sinus Meridiani. We prefer chemical precipitation models and favor precipitation from Fe-rich water on the basis of the probable association with sedimentary materials, large geographic size, distance from a regional heat source, and lack of evidence for extensive groundwater processes elsewhere on Mars. The TES results thus provide mineralogic evidence for probable large-scale water interactions. The Sinus Meridiani region may be an ideal candidate for future landed missions searching for biotic and prebiotic environments, and the physical characteristics of this site satisfy all of the engineering requirements for the missions currently planned.

Journal of Geophysical Research E: Planets↗

USGS1986

Geohydrology of the Vamoosa-Ada aquifer east-central Oklahoma with a section on chemical quality of water

The Vamoosa-Ada aquifer, which underlies an area of about 2,320 mi 2 , consists principally of the Vamoosa Formation and the overlying Ada Group of Pennsylvanian age. Rocks comprising the aquifer were deposited in a nearshore environment ranging from marine on the west to nonmarine on the east. Because of changes in depositional environments with time and from place to place, the aquifer is a complex sequence of fine- to very fine-grained sandstone, siltstone, shale, and conglomerate, with interbedded very thin limestone. The aggregate thickness of water-bearing sandstones is greatest south of the Cimarron River, where it reaches a maximum of 550 ft in the vicinity of Seminole. North of the Cimarron River, the average aggregate thickness of the sandstones is about 100 ft, but locally it may be as much as 200 ft. Transmissivity values derived from seven aquifer tests made for this study range from 70 to 490 ft 2 per day; values decrease from south to north with decreasing sandstone thickness. Hydraulic-conductivity values range from 2 to 4 ft per day. Storage coefficients for the confined part of the aquifer, as determined from four aquifer tests made during 1944, have an average value of 0.0002. The average storage coefficient for the unconfined part of the aquifer is estimated at 0.12, based on an analysis of geophysical logs and grain-size data. The specific capacity of wells tested is generally less than 1 gallon per minute per foot of drawdown. An approximate hydrologic budget for the aquifer for 1975 gives values, in acre-feet per year, of 93,000 for recharge, 233,000 for runoff, and 2,003,000 for evapotranspiration. The total of these values is almost equal to the average annual precipitation of 2,330,000 acre-ft per year. The estimated amount of water containing a maximum of 1,500 milligrams per liter of dissolved solids stored in the aquifer is estimated at 60 million acre-ft. Of this amount, an estimated 36 million acre-ft is available for use. The quality of water in the Vamoosa-Ada aquifer generally is suitable for municipal, domestic, and stock use. Of 55 water samples analyzed in the laboratory, about 75 percent were of the sodium bicarbonate or sodium calcium bicarbonate type; the remainder were of the sodium sulfate, calcium sulfate, sodium chloride, or indeterminate types. Laboratory and on-site chemical-quality data indicate that mineralization of both ground and surface waters is greater than normal in some areas. Water samples from 7 wells and 12 stream sites had concentrations of bromide exceeding 1 milligram per liter; the only known source of bromide in the area is brine associated with petroleum production.

Oklahoma↗

USGS1994

Geology of the Blue Mountains region of Oregon, Idaho, and Washington: Stratigraphy, physiography, and mineral resources of the Blue Mountains region

PART 1: Stratigraphic and sedimentological analysis of sedimentary sequences from the Wallowa terrane of northeastern Oregon has provided a unique insight into the paleogeography and depositional history of the terrane, as well as establishing important constraints on its tectonic evolution and accretionary history. Its Late Triassic history is considered here by examining the two most important sedimentary units in the Wallowa terrane-the Martin Bridge Limestone and the Hurwal Formation. Conformably overlying epiclastic volcanic rocks of the Seven Devils Group, the Martin Bridge Limestone comprises shallow-water platform carbonate rocks and deeper water, off-platform slope and basin facies. Regional stratigraphic and tectonic relations suggest that the Martin Bridge was deposited in a narrow, carbonate-dominated (forearc?) basin during a lull in volcanic activity. The northern Wallowa platform was a narrow, rimmed shelf delineated by carbonate sand shoals. Interior parts of the shelf were characterized by supratidal to shallow subtidal carbonates and evaporites, which were deposited in a restricted basin. In the southern Wallowa Mountains, lithofacies of the Martin Bridge are primarily carbonate turbidites and debris flow deposits, which accumulated on a carbonate slope apron adjacent to the northern Wallowa rimmed shelf from which they were derived. Drowning of the platform in the latest Triassic, coupled with a renewed influx of volcanically derived sediments, resulted in the progradation of fine-grained turbidites of the Hurwal Formation over the carbonate platform. Within the Hurwal, Norian conglomerates of the Excelsior Gulch unit contain exotic clasts of radiolarian chert, which were probably derived from the Bakei terrane. Such a provenance provides evidence of a tectonic link between the Baker and Wallowa terranes as early as the Late Triassic, and offers support for the theory that both terranes were part of a more extensive and complex Blue Mountains island-arc terrane. PART 2: Mesozoic rocks exposed along the Snake River in the northern Wallowa terrane represent a volcanic island and its associated sedimentary basins within the Blue Mountains island arc of Washington, Oregon, and Idaho. In the northern part of the Wallowa terrane, rock units include the Wild Sheep Creek, Doyle Creek, and Coon Hollow Formations, the (informal) Imnaha intrusion, and the (informal) Dry Creek stock. The volcanic rocks of the Ladinian to Karnian Wild Sheep Creek Formation show two stages of evolution-an early dacitic phase Gower volcanic faciesY and a late mafic phase (upper volcanic facies). The two volcanic facies are separated by eruption-generated turbidites of siliceous argillites and arkosic arenites (argillitesandstone facies). The two magmatic phases of the Wild Sheep Creek Formation may be recorded by the compositional zoning from older quartz diorite and diorite to younger gabbro in the Imnaha intrusion. Although the Late Triassic Imnaha intrusion is in fault contact with the Wild Sheep Creek Formation, it may be a subduction-related pluton and was the likely magma source for the Wild Sheep Creek Formation. Interbedded with the upper volcanic facies are eruption-generated turbidite and debris flow deposits (sandstone-breccia facies) and thick carbonate units (limestone facies). The limestone facies consists of two marker units, which may represent carbonate platform environments. Clast imbrication, fossil orientation, and cross-stratification in the Wild Sheep Creek Formation indicate a shoaling to subaerial volcanic island to the south and southeast; sediment was transported to the north and northwest. The Karnian Doyle Creek Formation consists largely of epiclastic conglomerate, sandstone, and shale that were deposited in welloxygenated basins. Vitric tuffs interbedded with these sediments suggest shallow or subaerial pyroclastic eruptions. Quartz diorite clasts in this formation may indicate uplift

Idaho, Oregon, Washington↗

USGS2009

Evolution and preservation potential of fluvial and transgressive deposits on the Louisiana inner shelf: Understanding depositional processes to support coastal management

The barrier-island systems of the Mississippi River Delta plain are currently undergoing some of the highest rates of shoreline retreat in North America (~20 m/year). Effective management of this coastal area requires an understanding of the processes involved in shoreline erosion and measures that can be enacted to reduce loss. The dominant stratigraphy of the delta plain is fluvial mud (silts and clays), delivered in suspension via a series of shallow-water delta lobes that prograded across the shelf throughout the Holocene. Abandonment of a delta lobe through avulsion leads to rapid land subsidence through compaction within the muddy framework. As the deltaic headland subsides below sea level, the marine environment transgresses the bays and wetlands, reworking the available sands into transgressive barrier shorelines. This natural process is further complicated by numerous factors: (1) global sea-level rise; (2) reduced sediment load within the Mississippi River; (3) diversion of the sediment load away from the barrier shorelines to the deep shelf; (4) storm-induced erosion; and (5) human alteration of the littoral process through the construction of hardened shorelines, canals, and other activities. This suite of factors has led to the deterioration of the barrier-island systems that protect interior wetlands and human infrastructure from normal wave activity and periodic storm impact. Interior wetland loss results in an increased tidal prism and inlet cross-sectional areas, and expanding ebb-tidal deltas, which removes sand from the littoral processes through diversion and sequestration. Shoreface erosion of the deltaic headlands does not provide sufficient sand to balance the loss, resulting in thinning and dislocation of the islands. Abatement measures include replenishing lost sediment with similar material, excavated from discrete sandy deposits within the muddy delta plain. These sand bodies were deposited by the same cyclical processes that formed the barrier islands, and understanding these processes is necessary to characterize their location, extent, and resource potential. In this paper we demonstrate the dominant fluvial and marine-transgressive depositional processes that occur on the inner shelf, and identify the preservation and resource potential of fluvio-deltaic deposits for coastal management in Louisiana.

Geo-Marine Letters↗

USGS1990

Microbanded manganese formations; protoliths in the Franciscan Complex, California

The Buckeye manganese deposit, 93 km southeast of San Francisco in the California Coast Ranges, preserves a geologic history that provides clues to the origin of numerous lenses of manganese carbonate, oxides, and silicates that occur with interbedded radiolarian chert and metashale of the Franciscan Complex. Compositionally and mineralogically laminated Mn-rich protoliths were deformed and dismembered, in a manner that mimics in smaller scale the deformation of the host complex, and then were incipiently metamorphosed at blueschistfacies conditions. Eight phases occur as almost monomineralic protoliths and mixtures: rhodochrosite, caryopilite, chlorite, gageite, taneyamalite, braunite, hausmannite, and laminated chert (quartz). Braunite, gageite, and some chlorite and caryopilite layers were deposited as gel-like materials; rhodochrosite, most caryopilite, and at least some hausmannite layers as lutites; and the chert as turbidites of radiolarian sand. Some gel-like materials are now preserved as transparent, sensibly isotropic relics of materials that fractured or shattered when deformed, creating curved surfaces. In contrast, the micrites flowed between the fragments of gel-like materials. The orebody and most of its constituent minerals have unusually Mn-rich compositions that are described by the system MnO-SiO2-O2-CO2-H2O. High values of Mn/Fe and U/Th, and low concentrations of Co, Cu, and Ni, distinguish the Buckeye deposit from many high-temperature hydrothermal deposits and hydrogenous or diagenetic manganese and ferromanganese nodules and pavements. This chemical signature suggests that ore deposition was related to fluids from the sediment column and seawater. Tungsten is associated exclusively with gageite, in concentrations as high as 80 parts per million. The source of the manganese is unknown; because basalts do not occur near the deposit, it was probably manganese leached from the sediment column by reducing solutions. Low concentrations of calcium (CaO approximately 0.6 weight percent) suggest that the host sediments formed beneath the carbonate-compensation depth. The most probable cause of the microbanding is changing proportions of chemical fluxes supplied to the sediment-seawater interface. The principal fluxes were biogenic silica from the water column, carbon dioxide from organic matter in the sediment column, O2 and other seawater constituents, and Mn +2-bearing fluid. The presence of Al2O3 and TiO2 (supplied by a detrital flux) in the metashale but not the ore lens suggests rapid ore deposition. Material supply-rate changes were probably due to a complex combination of episodic variations in the hydrothermal flux and periodic flows of radiolarian sand (silica and CO2 fluxes) that may be related to climate variations. The processes that form recent marine hydrothermal mounds may be the same as processes that formed the Buckeye deposit. Features common to both include the presence of Mn-oxyhydroxide crusts (corresponding to the Buckeye orebody), a large Mn/Fe ratio, low abundances of most minor elements, and small size. The most important differences are the absence of rhodochrosite and manganese silicates, interlayered with oxide, and the absence of adjacent chert in the contemporary deposits. These differences may be due to an absence of the debris of siliceous pelagic organisms, which accumulated in the Buckeye paleoenvironment. Periodic turbidity flows of chert-forming radiolarian sand could provide the changes in the fluxes of silica and organic matter necessary to form manganese carbonate and silicates. Turbidity flows of graywacke indicate proximity to an environment with high relief. A possible paleodepositional environment is an oceanic spreading center approaching a continental margin at which subduction occurred.

Professional Paper↗

USGS2005

Mapping variations in weight percent silica measured from multispectral thermal infrared imagery - Examples from the Hiller Mountains, Nevada, USA and Tres Virgenes-La Reforma, Baja California Sur, Mexico

Remotely sensed multispectral thermal infrared (8-13 ??m) images are increasingly being used to map variations in surface silicate mineralogy. These studies utilize the shift to longer wavelengths in the main spectral feature in minerals in this wavelength region (reststrahlen band) as the mineralogy changes from felsic to mafic. An approach is described for determining the amount of this shift and then using the shift with a reference curve, derived from laboratory data, to remotely determine the weight percent SiO2 of the surface. The approach has broad applicability to many study areas and can also be fine-tuned to give greater accuracy in a particular study area if field samples are available. The approach was assessed using airborne multispectral thermal infrared images from the Hiller Mountains, Nevada, USA and the Tres Virgenes-La Reforma, Baja California Sur, Mexico. Results indicate the general approach slightly overestimates the weight percent SiO2 of low silica rocks (e.g. basalt) and underestimates the weight percent SiO2 of high silica rocks (e.g. granite). Fine tuning the general approach with measurements from field samples provided good results for both areas with errors in the recovered weight percent SiO2 of a few percent. The map units identified by these techniques and traditional mapping at the Hiller Mountains demonstrate the continuity of the crystalline rocks from the Hiller Mountains southward to the White Hills supporting the idea that these ranges represent an essentially continuous footwall block below a regional detachment. Results from the Baja California data verify the most recent volcanism to be basaltic-andesite. ?? 2005 Elsevier Inc. All rights reserved.

Remote Sensing of Environment↗

USGS2009

Diel Sampling of Groundwater and Surface Water for Trace Elements and Select Water-Quality Constituents at a Former Zinc Smelter Site near Hegeler, Illinois, August 1-3, 2007

Surface water can exhibit substantial diel variations in the concentration of a number of constituents. Sampling regimens that do not characterize diel variations in water quality can result in an inaccurate understanding of site conditions and of the threat posed by the site to human health and the environment. Surface- and groundwater affected by acid drainage were sampled every 60 to 90 minutes over a 48-hour period at a former zinc smelter known as the Hegeler Zinc Superfund Site, in Hegeler, Ill. Groundwater-quality data from a well at the site indicate stable, low pH, weakly oxidizing geochemical conditions in the aquifer. With the exceptions of temperature and pH, no constituents exhibited diel variations in groundwater. Variations in temperature and pH likely were not representative of conditions in the aquifer. Surface water was sampled at a site on Grape Creek. Diel variations were observed in temperature, dissolved oxygen, pH, and specific conductance, and in the concentrations of nitrite, barium, iron, lead, vanadium, and possibly uranium. Concentrations during the diel cycles varied by about an order of magnitude for nitrite and varied by about a factor of two for barium, iron, lead, vanadium, and uranium. Temperature, dissolved oxygen, specific conductance, nitrite, barium, lead, and uranium generally reached maximum values during the afternoon and minimum values during the night. Iron, vanadium, and pH generally reached minimum values during the afternoon and maximum values during the night. These variations would need to be accounted for during sampling of surface-water quality in similar hydrologic settings. The temperature variations in surface water were affected by variations in air temperature. Concentrations of dissolved oxygen were affected by variations in the intensity of photosynthetic activity and respiration. Nitrite likely was formed by the oxidation of ammonium by dissolved oxygen and degraded by its anaerobic oxidation by ammonium or as part of the decomposition of organic matter. Variations in pH were affected by the photoreduction of Fe3+ to Fe2+ and the precipitation of iron oxyhydroxides. Diel variations in concentrations of iron and vanadium were likely caused by variations in the dissolution and precipitation of iron oxyhydroxides, oxyhydroxysulfates, and hydrous sulfates, which may have been affected by in the intensity of insolation, iron photoreduction, and the concentration of dissolved oxygen. The concentrations of lead, uranium, and perhaps barium in Grape Creek may have been affected by competition for sorption sites on iron oxyhydroxides. Competition for sorption sites was likely affected by variations in pH and the concentration of Fe2+. Constituent concentrations likely also were affected by precipitation and dissolution of minerals that are sensitive to changes in pH, temperature, oxidation-reduction conditions, and biologic activity. The chemical and biologic processes that resulted in the diel variations observed in Grape Creek occurred within the surface-water column or in the underlying sediments.

Scientific Investigations Report↗

USGS2006

A 16-year record of eolian dust in Southern Nevada and California, USA: Controls on dust generation and accumulation

An ongoing project monitors modern dust accumulation in the arid southwestern United States to (1) determine the rate and composition of dust inputs to soils and (2) relate dust accumulation to weather patterns to help predict the effects of climate change on dust production and accumulation. The 16-year records of 35 dust-trap sites in the eastern Mojave Desert and southern Great Basin reveal how generation and accumulation of dust, including the silt-clay, carbonate, and soluble-salt fractions, is affected by the amount and seasonal distribution of rainfall and the behavior of different source types (alluvium, dry playas, and wet playas). Accumulation rates (fluxes) of the silt-clay fraction of dust, including carbonates, range from about 2-20 g/m2/yr. Average rates are higher in the southern part of the study area (south of latitude 36.5??N) and annually fluctuate over a larger range than rates in the northern part of the area. Sites throughout the study area show peaks in dust flux in the 1984-1985 sampling period and again in 1997-1999; northern sites also show increased flux in 1987-1988 and southern sites in 1989-1991. These peaks of dust flux correspond with both La Nina (dry) conditions and with strong El Nino (wet) periods. The accumulation rates of different components of mineral dusts fluctuate differently. For example, soluble-salt flux increases in 1987-1988, coincident with a moderate El Nino event, and increases very strongly in 1997-1999, overlapping with a strong El Nino event. Both of these high-rainfall winters were preceded and accompanied by strong summer rains. In contrast, little or no change in soluble-salt flux occurred during other periods of high winter rainfall but little summer rain, e.g. 1992-1995. The differences between northern vs. southern sites and between sites with playa dust sources vs. alluvial dust sources indicate that regional differences in the response of precipitation and vegetation growth to ENSO influence and differences in the response of source types control dust production and accumulation. A major factor is the hydrologic condition of surface sediments. The silt-clay and soluble-salt fluxes increased during the El Nino events of 1987-1988 and 1997-1998 at sites close to "wet" playas with shallow depths to groundwater (<10 m), consistent with the concept that active evaporative concentration of salts disrupts surface crusts and increases the susceptibility of surface sediment to deflation. The silt-clay flux also increased during drought periods (1989-1991, 1995-1997) at sites downwind of alluvial sources and "dry" playas with deeper groundwater (<10 m). These increases are probably related to the die-off of drought-stressed vegetation on alluvial sediments, and in some cases to local runoff events that deliver fresh sediment to playa margins and distal portions of alluvial fans. ?? 2006 Elsevier Ltd. All rights reserved.

Journal of Arid Environments↗

USGS2006

Distribution of hydrothermally altered rocks in the Reko Diq, Pakistan mineralized area based on spectral analysis of ASTER data

The Reko Diq, Pakistan mineralized study area, approximately 10??km in diameter, is underlain by a central zone of hydrothermally altered rocks associated with Cu-Au mineralization. The surrounding country rocks are a variable mixture of unaltered volcanic rocks, fluvial deposits, and eolian quartz sand. Analysis of 15-band Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) data of the study area, aided by laboratory spectral reflectance and spectral emittance measurements of field samples, shows that phyllically altered rocks are laterally extensive, and contain localized areas of argillically altered rocks. In the visible through shortwave-infrared (VNIR + SWIR) phyllically altered rocks are characterized by Al-OH absorption in ASTER band 6 because of molecular vibrations in muscovite, whereas argillically altered rocks have an absorption feature in band 5 resulting from alunite. Propylitically altered rocks form a peripheral zone and are present in scattered exposures within the main altered area. Chlorite and muscovite cause distinctive absorption features at 2.33 and 2.20????m, respectively, although less intense 2.33????m absorption is also present in image spectra of country rocks. Important complementary lithologic information was derived by analysis of the spectral emittance data in the 5 thermal-infrared (TIR) bands. Silicified rocks were not distinguished in the 9 VNIR + SWIR bands because of the lack of diagnostic spectral absorption features in quartz in this wavelength region. Quartz-bearing surficial deposits, as well as hydrothermally silicified rocks, were mapped in the TIR bands by using a band 13/band 12 ratio image, which is sensitive to the intensity of the quartz reststrahlen feature. Improved distinction between the quartzose surficial deposits and silicified bedrock was achieved by using matched-filter processing with TIR image spectra for reference. ?? 2006 Elsevier Inc. All rights reserved.

Remote Sensing of Environment↗

USGS2013

Knowledge and understanding of dissolved solids in the Rio Grande–San Acacia, New Mexico, to Fort Quitman, Texas, and plan for future studies and monitoring

Availability of water in the Rio Grande Basin has long been a primary concern for water-resource managers. The transport and delivery of water in the basin have been engineered by using reservoirs, irrigation canals and drains, and transmountain-water diversions to meet the agricultural, residential, and industrial demand. In contrast, despite the widespread recognition of critical water-quality problems, there have been minimal management efforts to improve water quality in the Rio Grande. Of greatest concern is salinization (concentration of dissolved solids approaching 1,000 mg/L), a water-quality problem that has been recognized and researched for more than 100 years because of the potential to limit both agricultural and municipal use. To address the issue of salinization, water-resource managers need to have a clear conceptual understanding of the sources of salinity and the factors that control storage and transport, identify critical knowledge gaps in this conceptual understanding, and develop a research plan to address these gaps and develop a salinity management program. In 2009, the U.S. Geological Survey (USGS) in cooperation with the U.S. Army Corps of Engineers (USACE), New Mexico Interstate Stream Commission (NMISC), and New Mexico Environment Department (NMED) initiated a project to summarize the current state of knowledge regarding the transport of dissolved solids in the Rio Grande between San Acacia, New Mexico, and Fort Quitman, Texas. The primary objective is to provide hydrologic information pertaining to the spatial and temporal variability present in the concentrations and loads of dissolved solids in the Rio Grande, the source-specific budget for the mass of dissolved solids transported along the Rio Grande, and the locations at which dissolved solids enter the Rio Grande. Dissolved-solids concentration data provide a good indicator of the general quality of surface water and provide information on the factors governing salinization within the Rio Grande study area. The pattern in dissolved-solids concentrations along the Rio Grande is one of increasing concentration with increasing distance downstream from Elephant Butte and Caballo Reservoirs. The concentration of dissolved solids in the Rio Grande doubles (approximately 500 to 1,000 mg/L) from below Elephant Butte Reservoir to El Paso and increases by more than a factor of 5 (approximately 500 to 3,200 mg/L) from below Elephant Butte Reservoir to Fort Quitman. Marked increases in the concentration of dissolved solids commonly coincide with contributions from agricultural drains, wastewater-treatment plants, regional groundwater, and upward-flowing saline groundwater. The greatest factor, from the surface-water system, in controlling dissolved solids in the Rio Grande is the amount of water that is being transported or stored. Annual variation in streamflow is influenced primarily by climate (precipitation and evaporation) and management of Elephant Butte and Caballo Reservoirs (water storage and release cycles). Seasonal variation in streamflow within the Rio Grande study area is generally categorized generally as irrigation (March–September) and nonirrigation (October–February) seasons; with streamflow in the Rio Grande is highest during the irrigation season and lowest during the nonirrigation season. Dissolved-solids loads during the irrigation season decrease between Leasburg and Fort Quitman primarily because of irrigation diversions and losses to the underlying alluvial aquifer. Conversely, dissolved-solids loads during the nonirrigation season increase between Caballo Dam and Fort Quitman primarily because of the inflow of dissolved solids from agricultural drains, wastewater-treatment plants, and groundwater with elevated concentrations of dissolved solids. Many studies have mass-balance budgets that account for the mass of dissolved solids transported along the Rio Grande. Results from mass-balance budgets developed for dissolved solids indicated that (1) the inflow of saline groundwater, inflow of regional groundwater, and chemical reactions between mineral phases are the primary sources controlling dissolved solids in the Rio Grande, and (2) groundwater pumping and mineral precipitation are causing a net storage of dissolved solids in the Leasburg to El Paso and El Paso to Fort Quitman reaches of the Rio Grande. Looking forward, multiple water-resource managers from State and local agencies in New Mexico and Texas and Federal agencies formed the Rio Grande Salinity Management Coalition with the goal to reduce the amount of dissolved solids that are transported and stored in the Rio Grande study area. The recommendations for additional monitoring to assist the coalition are as follows: -Monitoring: Couple water-quality and streamflow monitoring in the Rio Grande and agricultural drains; perform groundwater-seepage investigations in the Rio Grande and major agricultural drains; nonitor groundwater water-quality conditions in the Mesilla and Hueco Basins. -Focused Hydrogeology Studies at Inflow Sources: Map dissolved-solids concentrations in the Rio Grande and underlying alluvial aquifer; perform hydrogeologic characterization of subsurface areas containing unusually high concentrations of dissolved solids. -Modeling of Dissolved Solids: Develop models to simulate the transport and storage of dissolved solids in both surface-water and groundwater systems.

New Mexico;Texas↗

USGS2005

Questa baseline and pre-mining ground-water quality investigation. 14. Interpretation of ground-water geochemistry in catchments other than the Straight Creek catchment, Red River Valley, Taos County, New Mexico, 2002-2003

The U.S. Geological Survey, in cooperation with the New Mexico Environment Department, is investigating the pre-mining ground-water chemistry at the Molycorp molybdenum mine in the Red River Valley, New Mexico. The primary approach is to determine the processes controlling ground-water chemistry at an unmined, off-site but proximal analog. The Straight Creek catchment, chosen for this purpose, consists of the same Tertiary-age quartz-sericite-pyrite altered andesite and rhyolitic volcanics as the mine site. Straight Creek is about 5 kilometers east of the eastern boundary of the mine site. Both Straight Creek and the mine site are at approximately the same altitude, face south, and have the same climatic conditions. Thirteen wells in the proximal analog drainage catchment were sampled for ground-water chemistry. Eleven wells were installed for this study and two existing wells at the Advanced Waste-Water Treatment (AWWT) facility were included in this study. Eight wells were sampled outside the Straight Creek catchment: one each in the Hansen, Hottentot, and La Bobita debris fans, four in a well cluster in upper Capulin Canyon (three in alluvial deposits and one in bedrock), and an existing well at the U.S. Forest Service Questa Ranger Station in Red River alluvial deposits. Two surface waters from the Hansen Creek catchment and two from the Hottentot drainage catchment also were sampled for comparison to ground-water compositions. In this report, these samples are evaluated to determine if the geochemical interpretations from the Straight Creek ground-water geochemistry could be extended to other ground waters in the Red River Valley , including the mine site. Total-recoverable major cations and trace metals and dissolved major cations, selected trace metals, anions, alkalinity; and iron-redox species were determined for all surface- and ground-water samples. Rare-earth elements and low-level As, Bi, Mo, Rb, Re, Sb, Se, Te, Th, U, Tl, V, W, Y, and Zr were determined on selected samples. Dissolved organic carbon (DOC), mercury, sulfate stable isotope composition (δ 34 S and δ 18 O of sulfate), stable isotope composition of water (δ 2 H and δ 18 O of water) were measured for selected samples. Chlorofluorocarbons (CFC) and 3 He and 3 H were measured for age dating on selected samples. Linear regressions from the Straight Creek ground-water data were used to compare ground-water chemistry trends in non-Straight Creek ground waters with Straight Creek alluvial ground-water chemistry dilution trends. Most of the solute trends for the ground waters are similar to those for Straight Creek but there are some notable exceptions. In lithologies that contain substantial pyrite mineralization, acid waters form with similar chemistries to those in Straight Creek and all the waters tend to be calcium-sulfate type. Hottentot ground waters contain substantially lower calcium concentrations relative to those in Straight Creek. This anomaly results from the exposure of rhyolite porphyry in the Hottentot scar and weathering zone. The rhyolite contains less calcium than the altered andesites and tuffs in the Straight Creek catchment and probably does not have the abundant gypsum and calcite. The Hansen ground waters have reached gypsum saturation and have similar calcium, magnesium, and beryllium concentrations as Straight Creek ground waters but have lower concentrations of fluoride, manganese, zinc, cobalt, nickel, copper, and lithium. Lower concentrations of elements related to mineralization at Hansen likely reflect the more distal location of Hansen with respect to intrusive centers that provided the heat source for hydrothermal alteration. The other ground water with water chemistry trends that are outside the Straight Creek trends was from an alluvial well from Capulin Canyon (CC2A). Although it had pH values near 6.0 and most major ions similar to the other Capulin Canyon ground waters, it contained high concentrations of fluoride, manganese, aluminum, iron, beryllium, and zinc similar to a mineralized zone and had low alkalinity. Saturation indices indicate that solubility constraints continue to provide upper limits on some solute concentrations. Siderite, ferrihydrite, calcite, gypsum, rhodochrosite, and barite provide limits for concentrations of Fe(II), Fe(III), Ca, Mn, and Ba, respectively. Beryllium concentrations may be subject to an upper concentration limit by the solubility of Be(OH) 2 but these concentrations probably are not reached in the ground waters. Ground-water isotopic data were consistent with the meteoric water line estimated for precipitation in the Red River Valley, indicating that all the ground waters examined in this study were meteoric, recent in origin, and showed no substantial indication of evaporation. Tritium-helium-3 and chlorofluorocarbon (CFC) age dating were partially successful. Generally, dates were consistent with location and depth of wells. Two samples had good agreement between CFC dates and tritium-helium dates, whereas a third reflected either substantial mixing with younger or older waters or complications arising from excess helium-4. The well at La Bobita appeared to contain a large component of modern water, most likely as a result of mixing with water from Red River alluvial deposits.

New Mexico↗

USGS2012

Zinc isotope investigation of surface and pore waters in a mountain watershed impacted by acid rock drainage

The pollution of natural waters with metals derived from the oxidation of sulfide minerals like pyrite is a global environmental problem. However, the metal loading pathways and transport mechanisms associated with acid rock drainage reactions are often difficult to characterize using bulk chemical data alone. In this study, we evaluated the use of zinc (Zn) isotopes to complement traditional geochemical tools in the investigation of contaminated waters at the former Waldorf mining site in the Rocky Mountains, Colorado, U.S.A. Geochemical signatures and statistical analysis helped in identifying two primary metal loading pathways at the Waldorf site. The first was characterized by a circumneutral pH, high alkalinity, and high Zn/Cd ratios. The second was characterized by acidic pHs and low Zn/Cd ratios. Zinc isotope signatures in surface water samples collected across the site were remarkably similar (the δ 66 Zn, relative to JMC 3-0749-L, for most samples ranged from 0.20 to 0.30‰ ± 0.09‰ 2σ). This probably suggests that the ultimate source of Zn is consistent across the Waldorf site, regardless of the metal loading pathway. The δ 66 Zn of pore water samples collected within a nearby metal-impacted wetland area, however, were more variable, ranging from 0.20 to 0.80‰ ± 0.09‰ 2σ. Here the Zn isotopes seemed to reflect differences in groundwater flow pathways. However, a host of secondary processes might also have impacted Zn isotopes, including adsorption of Zn onto soil components, complexation of Zn with dissolved organic matter, uptake of Zn into plants, and the precipitation of Zn during the formation of reduced sulfur species. Zinc isotope analysis proved useful in this study; however, the utility of this isotopic tool would improve considerably with the addition of a comprehensive experimental foundation for interpreting the complex isotopic relationships found in soil pore waters.

Colorado↗