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USGS2019

Arsenic, antimony, mercury, and water temperature in streams near Stibnite mining area, central Idaho, 2011–17

Mineralization and historical mining of stibnite (antimony sulfide), tungsten, gold, silver, and mercury in the headwaters of the East Fork of the South Fork Salmon River (EFSFSR) near the former town of Stibnite in central Idaho resulted in water-quality impairments related to mercury, antimony, and arsenic. Additionally, mining-related disturbances and wildfires have resulted in a lack of riparian shade in some areas, likely impacting water temperatures. In 2011, the U.S. Geological Survey, in cooperation with Midas Gold Corporation and the Idaho Department of Lands, began a study to characterize the spatial and temporal occurrence of trace metals to the EFSFSR. Five sites on the EFSFSR and its tributaries (Meadow and Sugar Creeks) were sampled about six times annually during 2011–17, during a range of streamflow conditions, for a total of 36–40 samples per location. Continuous water temperature, specific conductance, and streamflow also were measured at each site. The purpose of this report is to update previously reported information related to arsenic, antimony, mercury, and water temperature. Concentrations of dissolved arsenic and antimony generally increased from upstream to downstream in the EFSFSR. At the upstream site, upstream of the Meadow Creek confluence, dissolved arsenic and antimony concentrations averaged 8.86 and 0.93 micrograms per liter (μg/L), respectively. Downstream, upstream from the Sugar Creek confluence, average dissolved concentrations increased to 56.5 and 27.9 μg/L, respectively. All samples from the downstream EFSFSR site exceeded the human-health based criterion for both dissolved arsenic (10 µg/L) and dissolved antimony (5.6 µg/L). The chronic aquatic life criterion for dissolved arsenic (150 μg/L) was not exceeded (the maximum sample concentration was 108 μg/L), and aquatic life criteria for antimony have not been established. The highest concentrations of both dissolved arsenic and dissolved antimony occurred during low-flow periods (July–March), suggesting the constituents are present in groundwater. In contrast, total mercury concentrations were highest during high-flow periods (April–June) and were particulate-associated, suggesting that mercury is present in surface materials. At Sugar Creek, where the highest total mercury concentrations were measured, 97 percent of samples exceeded the chronic aquatic life criterion (0.012 μg/L) and 11 percent exceeded the acute criterion (2.1 μg/L). At all sites, summertime water temperatures frequently exceeded criteria related to salmonid spawning. Surrogate models previously developed to estimate continuous concentrations of arsenic, antimony, and mercury were reevaluated and updated, and the importance of explanatory variables on constituent concentrations is discussed. Results from this study can help guide future remediation locations and strategies, and provide a baseline against which future changes can be measured.

Idaho↗
USGS2020

Quantification of trace element loading in the upper Tenmile Creek drainage basin near Rimini, Montana, September 2011

The principle sources of trace elements entering upper Tenmile Creek, Montana, during September 2011, four trace metals and the metalloid arsenic, were identified and quantified by combining and analyzing streamflow data determined from tracer injection with trace-element concentrations and related water-quality data determined from synoptic sampling. The study reach was along upper Tenmile Creek, beginning downstream from the city of Helena’s diversion and extending 5,020 feet downstream. Results from the 2011 study, completed by the U.S. Geological Survey in cooperation with the Montana Department of Environmental Quality, were compared to results from a similar study conducted in 1998 to assess the effectiveness of mine reclamation and remediation work to reduce trace-element loading to upper Tenmile Creek, which has been ongoing throughout the drainage basin. Main-stem concentrations of most trace elements analyzed were generally greater in 1998 than in 2011. However, the State of Montana human-health criteria for total-recoverable cadmium and arsenic were exceeded in parts of upper Tenmile Creek, and concentrations of cadmium and zinc exceeded the acute aquatic-life criteria at all main-stem sites during both studies. Total-recoverable copper concentrations observed in 2011 exceeded the chronic aquatic-life criterion upstream from the Lee Mountain adit, whereas, in 1998, all sites exceeded the acute aquatic-life criteria. Direct comparison of loads from the 1998 and 2011 tracer studies were complicated by the differences in hydrologic conditions. Streamflow in 1998 was about 10 percent of the 2011 streamflow. The Lee Mountain Mine and Susie Lode adit were identified as major contributors of trace elements to upper Tenmile Creek in both studies. However, trace-element loading from the Lee Mountain Mine area was substantially reduced between 1998 and 2011. Total-recoverable loads of all trace elements showed substantial loss in 1998 but increased in 2011 downstream from the Susie Lode adit to the end of the study reach. This reach was one of the primary sources of trace-element loading to upper Tenmile Creek in 2011. This difference indicated that the streambed may act as a sink or a source for trace elements, depending on hydrologic conditions.

Montana↗
USGS2002

Water quality of the Flint River basin, Alabama and Tennessee, 1999-2000

The U.S. Geological Survey monitored eight stream sites in the Flint River Basin during the period January 1999 through May 2000, to characterize patterns in the occurrence of pesticides, fecal-indicator bacteria, and nutrients in relation to season and streamflow conditions and to land-use patterns. This study is part of the National Water-Quality Assessment Program, which was designed to assess water quality as it relates to various land uses. Every water sample collected from the Flint River Basin had detectable levels of at least two pesticides; 64 percent of the samples contained mixtures of at least five pesticides. In general, pesticides detected most frequently and at highest concentrations in streams corresponded to the pesticides with the highest rates of use in the watersheds. Detections of fluometuron, norflurazon, and atrazine were more frequent (by a margin of 15 percent or more) in samples from the Flint River when compared with the frequencies of pesticide detections at 62 agricultural stream sites across the Nation. Detections of fluometuron in the Flint River were more frequent even when compared with a cotton-cultivation subset of the 62 sites. For most pesticides, maximum concentrations did not exceed criteria to protect aquatic life; however, maximum concentrations of atrazine, cyanazine, and malathion exceeded aquatic-life criteria in at least one sample. Concentrations near or exceeding the aquatic-life criteria occurred only during the spring and summer (April-July), and generally occurred during storm flows. Less than 5 percent of the estimated mass of pesticides applied annually to agricultural areas in the Flint River Basin was transported to the stream at the monitoring points on the Flint River near Brownsboro, Alabama, and on Hester Creek near Plevna, Alabama. The pesticides with the highest ratios (greater than 3 percent) of the amount transported instream to the amount applied—atrazine, metolachlor, fluometuron, and norflurazon—are preemergent herbicides applied to the soil before the crops have emerged, which increases the probability of transport in surface runoff. Concentrations of the fecal-bacteria indicator Escherichia coli ( E. coli ) in the Flint River and Hester Creek exceeded the U.S. Environmental Protection Agency criterion for recreation in almost all storm samples, and in many samples collected up to 6 days following a storm. Concentrations in the Flint River were strongly correlated with sample turbidity, suggesting that turbidity might be useful as a surrogate for estimating E. coli concentrations. Concentrations of the nutrients nitrogen and phosphorus in samples from the Flint River generally exceeded thresholds indicating eutrophic potential, whereas concentrations in samples from Hester Creek were generally below the thresholds. When compared with nutrient data from a set of 24 agricultural basins across the southeastern region of the United States, concentrations in the Flint River and Hester Creek were slightly above the regional median. Base-flow concentrations of certain pesticides, nutrients, and E. coli were compared to land-use information for eight sites in the Flint River Basin. The highest base-flow concentrations of aldicarb sulfoxide, fluometuron, and phosphorus were found in the tributaries with the greatest density of cotton acreage in the watershed. Similarly, high base-flow concentrations of total nitrogen were correlated with a high percentage of cultivated land in the watershed. Lack of information about distribution of stream access by livestock weakened the analysis of correlation between livestock and base-flow concentrations of E. coli and nutrients. Input of dissolved and suspended chemicals from the Flint River during storms influences water quality in the reach of the Tennessee River from which the City of Huntsville, Alabama, withdraws about 40 percent of its drinking water. During the storm of April 2-5, 2000, concentrations of several pesticides were at least a factor five times greater in Huntsville's intake water when compared with concentrations in the Tennessee River upstream from the Flint River, although concentrations of all pesticides were below the U.S. Environmental Protection Agency drinking-water standards at all sites on the Tennessee River and in Huntsville's intake water.

Alabama, Tennessee↗
USGS2003

Surface-water quality of the Skokomish, Nooksack, and Green-Duwamish rivers and Thornton Creek, Puget Sound Basin, Washington, 1995-98

Streamflow and surface-water-quality data were collected from November 1995 through April 1998 (water years 1996-98) from a surface-water network in the Puget Sound Basin study unit of the U.S. Geological Survey National Water-Quality Assessment program. Water samples collected monthly and during storm runoff events were analyzed for nutrients, major ions, organic carbon, and suspended sediment, and at selected sites, samples were analyzed for pesticides and volatile organic compounds. Eleven sites were established in three major watersheds--two in the Skokomish River Basin, three in the Nooksack River Basin, five in the Green-Duwamish River Basin, and one site in Thornton Creek Basin, a small tributary to Lake Washington. The Skokomish River near Potlatch, Nooksack River at Brennan, and Duwamish River at Tukwila are integrators of mixed land uses with the sampling sites locally influenced by forestry practices, agriculture, and urbanization, respectively. The remaining eight sites are indicators of relatively homogeneous land use/land cover in their basins. The site on the North Fork Skokomish River is an indicator site chosen to measure reference or background conditions in the study unit. In the Nooksack River Basin, the site on Fishtrap Creek is an indicator of agriculture, and the Nooksack River at North Cedarville is an indicator site of forestry practices in the upper watershed. In the Green-Duwamish River Basin, Springbrook Creek is an urban indicator, Big Soos Creek is an indicator of a rapidly developing suburban basin; Newaukum Creek is an indicator of agriculture; and the Green River above Twin Camp Creek is an indicator of forestry practices. Thornton Creek is an indicator of high-density urban residential and commercial development. Conditions during the first 18 months of sampling were dominated by above-normal precipitation. For the Seattle-Tacoma area, water year 1997 was the wettest of the 3 years during the sample-collection period. Nearly 52 inches fell (about 14 inches above average) and monthly precipitation was often 200 percent of normal. The wet years kept streamflows generally above normal and contributed to high concentrations of pesticides, nutrients, suspended sediment, and organic carbon in samples. On the basis of chemical concentrations, dissolved oxygen concentrations, and water temperature, the relative quality of water among the 11 study sites ranged from exceptionally high in the North Fork Skokomish and the Green to fair in Springbrook and Thornton. Water in the large rivers (Skokomish, Nooksack, Green-Duwamish) and in two of the small streams in the Puget Sound Lowlands (Big Soos and Newaukum) was characterized by dilute water chemistry with dissolved solids concentrations less than 130 milligrams per liter. Water in three other small streams in the Lowlands (Fishtrap, Springbrook, and Thornton) had dissolved solids concentrations as high as 320 milligrams per liter. Nutrient and pesticide concentrations mostly were higher in the small streams than in the large rivers. Suspended-sediment concentrations, however, were highest in the large rivers, with averages ranging from 85 to 443 milligrams per liter. During storm and flood events, suspended-sediment concentrations in samples from the Nooksack were as much as 2,800 milligrams per liter, and from the Skokomish, 1,500 milligrams per liter. Out of 86 pesticides and 86 volatile organic compounds analyzed, a total of 35 pesticides and 11 volatile organic compounds were detected at concentrations above laboratory reporting levels in samples collected from the four intensively studied sites, the lower Nooksack River, Duwamish River, Fishtrap Creek, and Thornton Creek. Herbicides were detected more frequently than insecticides. The herbicide prometon was detected in 66 percent of all 124 samples collected, followed by simazine (65 percent), atrazine (64 percent), and the insecticide diazinon (50 percent). The detected volatile organic compounds belonged to one of three general classes--fuel-related, the trihalomethanes, or solvents. Water-quality standards and criteria for drinking water or for the protection of aquatic life were nearly always met, except on occasion by concentrations of dissolved oxygen, iron, and manganese in samples from Springbrook and Fishtrap, and concentrations of diazinon in Thornton and Fishtrap. Concentrations of three other insecticides (carbaryl, chlorpyrifos, and lindane) also did not meet criteria protecting aquatic life in a few samples (from 1 to 5) from Thornton and Fishtrap and from the Duwamish River. Water-quality conditions at the sampling sites resulted from natural characteristics of the watersheds and from human activities. In the Nooksack and Skokomish, natural conditions were probably important contributors to the large suspended-sediment concentrations observed during high streamflow events. However, logging and road building in the basins might also have contributed to the suspended-sediment loads. In the forested study basins, the water chemistry was more dilute, based on dissolved solids and nutrient concentrations. The North Fork Skokomish (indicator site of background conditions) and the Green (indicator site of forestry and natural conditions) were characterized by high-quality water with low concentrations of dissolved solids, nutrients, and sediment and by standards or criteria that were nearly always met. Unlike the high-quality water at the background and forestry sites, natural conditions appear to have adversely affected the quality of water in Springbrook. High concentrations of iron and manganese and low dissolved-oxygen concentrations were possibly the result of ground-water discharge at this site. Of all the sites, nutrient concentrations were highest in the agricultural streams (Fishtrap and Newaukum) and next highest in the urban streams, indicating that human activities affect the water quality of these streams. Of the three large rivers integrating a mix of land uses, the lower Nooksack, in an agricultural setting, on average had the highest total nitrogen and phosphorus concentrations, followed by the Duwamish in an urban setting, and the Skokomish in a forestry-practices setting. In both urban and agricultural settings, pesticides affected water quality at the four sites sampled for organic compounds. However, more types of pesticides were found at the agricultural sites than at the urban sites. The most pesticides were detected in Fishtrap. Many of these were pesticides applied for agricultural purposes, but several were pesticides applied in urban settings, such as those used in maintaining rights-of-way. In urban Thornton Creek, however, high application rates and retail availability of pesticides likely resulted in generally higher concentrations, the detections of certain pesticides in many samples year round, and the number of times insecticide concentrations did not meet chronic criteria for the protection of freshwater aquatic life. The two sites located in urban areas also had more detections of volatile organic compounds and at a higher detection frequency than the two sites in agricultural areas. The most compounds were detected in Thornton, and in the highest concentrations. Conversely, the least number of compounds was detected in the lower Nooksack, with only 2 percent urban land upstream. Methyl tert -butyl ether, an automotive fuel additive, was detected in a few samples from Fishtrap. Many solvents, such as trichloroethene and tetrachloroethene, were detected only in samples from the urban sites on the Duwamish River and Thornton Creek. The only volatile organic compound with a distinctly agricultural signature was 1,2-dichloropropane, detected only in Fishtrap Creek samples.

Washington↗
USGS2004

Assessment of Fish Habitat, Water Quality, and Selected Contaminants in Streambed Sediments in Noyes Slough, Fairbanks, Alaska, 2001-2002

During 2001-2002, the U.S. Geological Survey sampled streambed sediment at 23 sites, measured water quality at 26 sites, and assessed fish habitat for the entire length of Noyes Slough, a 5.5-mile slough of the Chena River in Fairbanks, Alaska. These studies were undertaken to document the environmental condition of the slough and to provide information to the public for consideration in plans to improve environmental conditions of the waterway. The availability of physical habitat for fish in the slough does not appear to be limited, although some beaver dams and shallow water may restrict movement, particularly during low flow. Elevated water temperatures in summer and low dissolved-oxygen concentrations are the principle factors adversely affecting water quality in Noyes Slough. Increased flow mitigated poor water-quality conditions and reduced the number of possible fish barriers. Flow appears to be the most prominent mechanism shaping water quality and fish habitat in Noyes Slough. Streambed sediment samples collected at 23 sites in 2001 were analyzed for 24 trace elements. Arsenic, lead, and zinc were the only trace elements detected in concentrations that exceed probable effect levels for the protection of aquatic life. The background concentration for arsenic in Noyes Slough is naturally elevated because of significant concentrations of arsenic in local bedrock and ground water. Sources of the zinc and lead contamination are uncertain, however both lead and zinc are common urban contaminants. Streambed-sediment samples from 12 sites in 2002 were analyzed for organochlorine pesticides, polychlorinated biphenyls (PCBs), and semivolatile organic compounds (SVOCs). The concentration of bis(2-ethylhexyl)phthalate of 2,600 micrograms per kilogram (?g/kg) for one sample from the site above Aurora Drive approached the aquatic-life criterion of 2,650 ?g/kg. Low concentrations of p-cresol, chrysene, and fluoranthene were detected in most of the sediment samples. The presence of these compounds in Noyes Slough sediment was expected because cresols are emitted to the atmosphere in the exhaust from motor vehicles and chrysene and fluoranthene are formed during the incomplete burning of coal, oil, gas, wood, garbage, or other organic substances. Low-level concentrations of DDT or its degradation products DDD and DDE were detected in all samples collected during 2002. However, total DDT (DDT+DDD+DDE) concentrations are less than the effects range median aquatic-life criterion of 46.1 ?g/kg. In general, total DDT concentrations were less than 10 ?g/kg, except for samples from two sites that have estimated concentrations of about 14 and 20 ?g/kg.

Water-Resources Investigations Report↗
USGS2004

Seasonal Variability and Effects of Stormflow on Concentrations of Pesticides and their Degradates in Kisco River and Middle Branch Croton River Surface Water, Croton Reservoir System, New York, May 2000-February 2001

Seven herbicides (2,4-D, 2,4-D methyl ester, bromacil, dicamba, diuron, imazaquin, and sulfometuron), four insecticides (carbaryl, diazinon, imidacloprid, and malathion), two fungicides (metalaxyl and myclobutanil), and caffeine (an indicator of wastewater) were detected in at least one sample from the Kisco River at concentrations above 0.1 ug/L (micrograms per liter). Four of these compounds - 2,4-D, 2,4-D methyl ester, dicamba, and metalaxyl - were detected in at least one sample from the Kisco River at a concentration above 1 ug/L. Only three herbicides (2,4-D, imazethapyr, and prometon) and caffeine were detected at concentrations above 0.1 ug/L in one or more of the Middle Branch Croton River samples, and no compounds were detected above 0.4 ug/L in Middle Branch Croton River samples. No samples contained concentrations of pesticides that exceeded human health-based water-quality standards. However, samples from the Kisco River contained four insecticides (carbaryl, chlorpyrifos, diazinon, and malathion) and one herbicide (2,4-D) in concentrations that exceeded water-quality criteria for the protection of aquatic life. Aquatic-life protection criteria were generally exceeded only in stormflow samples collected in June, September, and December 2000. No samples from the Middle Branch Croton River contained target compounds that exceeded water-quality criteria for the protection of aquatic life. Pesticide concentrations were generally higher, and the numbers of compounds generally larger in samples from the Kisco River than in samples from the Middle Branch Croton River, probably because the Kisco River watershed has a greater population density and is more extensively developed. The highest concentrations of most compounds in both streams were detected in stormflow samples collected in June, September, and December 2000. This indicates that stormflow sampling is essential in assessments of pesticide occurrence in streams that drain developed lands. The lowest concentrations of most compounds at both sites were detected in baseflow samples collected from October 2000 through February 2001, although the concentrations of several compounds increased substantially during stormflows at the Kisco River site in November and December, 2000.

Water-Resources Investigations Report↗
USGS1989

Geochemistry of soils and shallow ground water, with emphasis on arsenic and selenium, in part of the Garrison Diversion Unit, North Dakota, 1985-87

The Garrison Diversion Unit is being constructed to transfer water from the Missouri River (Lake Sakakawea) to areas in east-central and southeastern North Dakota for expanded irrigation of agricultural lands. During initial investigations of irrigation return flows in 1969-76, the potential effects of toxic elements were considered, and the U.S. Bureau of Reclamation concluded these elements would have no adverse effects on streams receiving return flows. After the development of problems associated with selenium in irrigation return flows in the western San Joaquin Valley, Calif., in 1985, the U.S. Bureau of Reclamation initiated additional studies, including an investigation conducted in cooperation with the U.S. Geological Survey, to assist in collecting and evaluating trace-element data. Also, in 1986, with the passage of the Garrison Diversion Unit Reformulation Act, Congress mandated that soil surveys be conducted to determine if there are "*** soil characteristics which might result in toxic or hazardous irrigation return flows." In order to address this issue, an investigation was conducted during 1995-87 by the U.S. Geological Survey in cooperation with the U.S. Bureau of Reclamation to determine the occurrence and distribution of arsenic, selenium, and other trace elements in the soils of six potential irrigation areas along the Garrison Diversion Unit route and in the James River basin. A total of 165 soil samples were collected and analyzed for total concentrations of as many as 42 elements, including arsenic and selenium. In addition, 81 of the samples were analyzed for water-extractable concentrations of 14 elements, including arsenic and selenium, to aid in determining the extent to which they might be mobilized by the irrigation water. In a detailed phase of the investigation, 376 water samples were collected in one of the six potential irrigation areas, the west Oakes irrigation area. Most of these samples were analyzed for arsenic, selenium, and as many as 28 other elements. Results of the investigation indicate that soils in the potential irrigation areas contain small concentrations of arsenic, selenium, and other trace elements. The geometric mean concentrations of total arsenic and selenium were 4.15 and 0.13 milligrams per kilogram, respectively, which are considerably smaller than those measured in the western San Joaquin Valley, Calif., and soils from other areas in the western United States. Water-extractable concentrations of arsenic and selenium, determined on 1:5 soil to water extractions, generally were less than 10 percent of the total concentrations. The geometric mean water-extractable concentrations for both elements were 0.02 milligram per kilogram or less. The median and maximum concentrations of all constituents and properties indicative of irrigation drainage were tens to hundreds of times smaller in the Oakes test area drains than in western San Joaquin Valley drains. The maximum arsenic concentration in ground-water samples was 44 micrograms per liter, and the median concentration was 4 micrograms per liter. The maximum concentration in drain samples was 11 micrograms per liter, and the median concentration was 3 micrograms per liter. Only 22 percent of the water samples collected from wells in the Oakes test area contained detectable concentrations (1 microgram per liter or more) of selenium. However, selenium was detected in 63 percent of the samples collected from sites on drains. The greater incidence of detection of selenium in the drain samples is interpreted as an effect of the more oxidizing environment of the drains, which are about 8 feet below land surface near the top of the water table. The median selenium concentration in the drain samples, however, was only 1 microgram per liter, and the maximum concentration in 63 drain samples was 4 micrograms per liter. For comparison, the median selenium concentrations reported for drains in the western San Joaquin Valley, Calif., ranged from 84 to 320 micrograms per liter. Mater from two observation wells had the largest selenium concentrations (8 and 9 micrograms per liter) measured during the investigation. These were the only two samples that exceeded any of the water-quality regulations, standards, or criteria for selenium. Mercury and boron were the only other trace elements that exceeded standards and criteria. The median concentration of mercury was less than 0.1 microgram per liter, and the maximum concentration was 0.8 microgram per liter. The chronic freshwater-aquatic-life criterion for mercury (0.012 microgram per liter) is about 10 times less than the laboratory detection limit and is derived from bioconcentration factors based on methylmercury. Two boron samples exceeded the irrigation criteria of 750 micrograms per liter. Comparisons with criteria and standards indicate that the concentrations of trace elements determined in samples from wells and drains in the Oakes test area during this investigation should not adversely affect human and aquatic life or irrigated crops. The data collected indicate that the soils and ground water in the Garrison Diversion Unit contain small concentrations of trace elements, including arsenic and selenium. Based on a detailed study of soils and ground water in the west Oakes irrigation area, however, there is no evidence that expanded irrigation will mobilize these elements in concentrations large enough to adversely affect aquatic life in the James River ecosystem, based on current regulations, standards, and criteria. Data are not currently available to make definitive statements about selenium concentrations in ground water in Garrison Diversion Unit irrigation areas other than the west Oakes Irrigation area. Data available on total and water-extractable selenium concentrations in soils t however, indicate that concentrations in ground water would be similar to those determined in the west Oakes irrigation area. Plans have been developed to sample ground water in the additional areas.

Water-Resources Investigations Report↗
USGS1993

Surface-water hydrology and quality, and macroinvertebrate and smallmouth bass populations in four stream basins in southwestern Wisconsin, 1987-90

Data on streamflow, water quality, and macroinvertebrate and smallmouth bass (microptercus dolomieni) populations were collected from July 1987 through September 1990, in four streams in southwestern Wisconsin to determine the effect of surface-water hydrology and quality on populations of macroinvertebrates and smallmouth bass. The study was a joint project of the U.S. Geological Survey and the Wisconsin Department of Natural Resources. Drought conditions greatly affected streamflows in southwestern Wisconsin throughout much of the period of study. Precipitation in all four basins in 1988 and 1989 was 9.91 to12.41 inches less than 1951-80 normal precipitation of 32.88 inches. The lowest annual mean discharge was recorded in water year 1988 at all of the streamflow- gaging stations except at Rattlesnake Creek, where annual mean discharge was lowest in water year 1990. Overland-flow runoff during the reproductive period of smallmouth bass (mid-May to mid-July) was 0.02 inch in 1988 at the Sinsinawa River and Rattlesnake Creek. Overland-flow runoff in the Little Platte River and the Livingston Branch of the Pecatonica River also was low in 1988 (0.03 inch and 0.04 inch, respectively) during the reproductive period of smallmouth bass. The trend of low overland-flow runoff continued in 1989; in water year 1990, however, overland-flow runoff during the reproductive period of smallmouth bass was 1.38 inches at Livingston Branch of the Pecatonica River and 0.22 inch at Rattlesnake Creek. Turbidity ranged from 1.5 nephelometric turbidity units at Rattlesnake Creek to 3,700 nephelometric turbidity units at the Sinsinawa River. Suspended-solid concentrations ranged from 2 milligrams per liter at Rattlesnake Creek to a maximum 24,300 milligrams per liter at the Livingston Branch of the Pecatonica River. The high turbidities and suspended-solid concentrations, which occurred during storms, did not last for long periods of time and are not thought to have been harmful to the biota of the rivers. Un-ionized ammonia concentrations exceeded the State of Wisconsin, Department of Natural Resources' standard of 0.04 milligram per liter for warmwater streams at all four of the streams. The maximum concentration of un-ionized ammonia measured was 0.10 milligram per liter at Rattlesnake Creek and there was no discernible effects on smallmouth bass or macroinvertebrates. Dissolved-oxygen concentrations at all four study streams occasionally decreased to below or near the concentration of 1 milligram per liter considered necessary to sustain life of smallmouth bass. Two fish kills were documented as the result of low dissolved-oxygen concentrations. All of these episodes of low dissolved-oxygen concentrations occurred during or just after rainstorms and subsequent increasing streamflows. Samples of water-sediment mixture and bottom material were analyzed for pesticides commonly used in the basins. Samples from all of the stations had concentrations of herbicides that exceeded the analytical reporting limit. Water-sediment samples at the Sinsinawa River had the highest herbicide concentration. The concentration of metolachlor was the highest of the herbicides-- 110 micrograms per liter; concentrations of atrazine and cyanazine were next highest at 97 and 84 micrograms per liter, respectively. All of the water-sediment mixture samples had insecticide concentrations below the analytical reporting limit, with the exception of carbofuran. One water-sediment mixture sample collected at the Little Platte River had a carbofuran concentration of 0.44 microgram per liter. No pesticides were detected in the bottom-material samples collected at the four study streams. Richness of macroinvertebrate taxa did not differ substantially among the four streams during the study, but the abundances of several taxa differed significantly among streams. Livingston Branch of the Pecatonica River had comparatively few midges but many caddisflies, whereas Rattlesnake Creek had many non-insect taxa and relatively few caddisflies. The Little Platte River had consistently high numbers of caddisflies, mayflies, and riffle beetles. Macroinvertebrate-community composition, as measured by Bray-Curtis dissimilarity coefficients, varied considerably over time within and among the streams. The macroinvertebrate community composition of the Little Platte River changed very little during the winter of 1987-88 as compared to the other streams, but the community composition of the Livingston Branch of the Pecatonica River changed substantially. The communities of Rattlesnake Creek and Livingston Branch of the Pecatonica River became more similar to the community of the Little Platte River from fall 1987 through fall 1988, whereas the community in the Sinsinawa River remained distinct. Water quality, as estimated by biotic-index values, generally was better in the Little Platte River than in the other streams from fall 1987 through fall 1988. However, water quality appeared to have deteriorated (biotic-index values increased) in the Little Platte River during the winter of 1988-89. Water quality in the Livingston Branch of the Pecatonica River also deteriorated during the same period. The drought of 1988-89 and accompanying decrease in frequency of storms contributed to an uncharacteristically stable environment for macroinvertebrate development in most streams. Total taxa richness increased in three of the four streams. Total taxa richness did not increase in the Little Platte River, possibly because of moderate flooding that occurred prior to the spring 1989 sampling period or, more likely, because of changes in dissolved-oxygen concentrations. Although dissolved-oxygen concentrations were fairly similar in all streams, dissolved-oxygen concentrations were lower in 1989 in the Little Platte River than in other streams. The observed increase in biotic-index values in the Little Platte River during the spring of 1989 supports a decline in water quality. Smallmouth bass reproduction was related to precipitation and streamflow during the critical mid-May to mid-July reproductive period. Reproductive success was good (38-297 Age 0 smallmouth bass per acre) in 1988 and 1989 and poor (0-3 Age 0 smallmouth bass per acre) in 1987 and 1990. This pattern corresponded with total precipitation of less than 7 inches in May and June in 1988 and 1989 and greater than 7 inches in 1989 and 1990. In years when runoff exceeded 0.10 inch, only three or fewer Age 0 (smallmouth bass less than 1 year old) smallmouth bass per acre were caught in late summer to fall sampling surveys. In contrast, when overland runoff was less than 0.10 inch, 32 to 297 Age 0 smallmouth bass per acre were found in late summer or fall. The numbers of Age 0 smallmouth bass per acre were significantly different from each other at the 1 -percent probability level (p=0.0001). Smallmouth bass reproductive success indicated that smallmouth bass in these streams were extremely vulnerable to the amount of runoff during the early stage of their life. Low concentrations of dissolved oxygen constituted the most detrimental water-quality problem affecting smallmouth bass populations. Dissolved-oxygen concentrations were occasionally less than 3 milligrams per liter, a dissolved-oxygen concentration that may be detrimental to early-life stages of smallmouth bass in the streams; however, smallmouth bass were apparently able to withstand these low dissolved-oxygen concentrations and seem to have survived in some situations when dissolved-oxygen concentration decreased to1 milligram per liter.

Wisconsin↗
USGS1995

Reconnaissance investigation of water quality, bottom sediment, and biota associated with irrigation drainage in the Dolores Project area, southwestern Colorado and southeastern Utah, 1990-91

Water, bottom-sediment, and biota samples were collected in 1990-91 to identify water-quality problems associated with irrigation drainage in the Dolores Project area. Concentrations of cadmium, mercury, and selenium in some water samples exceeded aquatic-life criteria. Selenium was associated with irrigaton drainage from the Dolores Project, but other trace elements may be transported into the area in the irrigation water supply. Selenium concentrations exceeded the chronic aquatic-life criterion in water samples from lower McElmo Creek and Navajo Wash, which drain the Montezuma Valley, from newly irrigated areas, and from the Mancos River. The maximum selenium con- centration in water was 88 micrograms per liter from Navajo Wash. Concentrations of herbicides in water were less than concentrations harmful to aquatic life. Selenium concentrations in four bottom-sediment samples exceeded the baseline concentrations for soils in the Western United States. The largest selenium concentrations in biota were in samples from Navajo Wash, from newly irrigated areas north of the Montezuma Valley, and from the Mancos River basin. Selenium concentrations in aquatic-invertebrate samples from the newly irrigated areas exceeded a guideline for food items consumed by fish and wildlife. Selenium concen- trations in whole-body suckers were larger in the San Juan River downstream from the Dolores Project than upstream from the project at Four Corners. Selenium concentrations in fathead minnow samples from two sites were at adverse-effect levels. Mercury concentrations in warm-water game fish in reservoirs in the study area may be of concern to human health. Some concentrations of other trace elements exceeded background concentrations, but the concentrations were not toxicologically significant or the toxicologic significance is not known.

Water-Resources Investigations Report↗
USGS1995

Agricultural pesticide applications and observed concentrations in surface waters from four drainage basins in the Central Columbia Plateau, Washington and Idaho, 1993-94

As part of the U.S. Geological Survey's National Water-Quality Assessment Program, the use and occurrence of agricultural pesticides were investigated in four drainage basins--two dominated by irrigated agriculture and two by dryland agriculture--in the Central Columbia Plateau of eastern Washington. For this study, 85 pesticides or pesticide metabolites were selected for analysis from a list of nearly 400 compounds commonly used in the United States. Pesticide-use data included estimates of the total quantity of herbicides, insecticides, and fungicides applied to croplands in each of the four drainage basins and reported times of application for selected pesticides. Pesticide-occurrence data included concentrations of pesticides in samples collected at one surface-water site at or near the outflow of each of the four drainage basins, where surface waters were sampled one to five times a month from March 1993 through May 1994. Of the 85 pesticides or pesticide metabolites targeted for analysis, a total of 45 different compounds were detected in samples from the four sites, ranging in concentration from at or near the limit of detection (as low as 0.001 microgram per liter) to a maximum of 8.1 micrograms per liter. None of the concentrations of pesticides exceeded the U.S. Environmental Protection Agency (USEPA) drinking water standards, but concentrations of five pesticides exceeded the USEPA freshwater-chronic criteria for the protection of aquatic life. Forty-one different pesticides or pesticide metabolites were detected in surface waters sampled at the two sites representing irrigated agriculture drainage basins. The herbicides atrazine, DCPA, and EPTC were detected most frequently at the two sampling sites. Not all pesticides that were applied were detected, however. For example, disulfoton, phorate, and methyl parathion accounted for 15 percent of the insecticides applied in the two irrigated drainage basins, yet none of these pesticides were detected in samples from the two irrigated-agricultural sites. Concentrations of pesticides found in surface waters at the two sites representing irrigated agriculture did not exceed drinking water standards, but some concentrations of the insecticides carbaryl, chlorpyrifos, diazinon, and azinphos-methyl exceeded the freshwater-chronic criteria for the protection of aquatic life. Twenty-three different pesticides or pesticide metabolites were detected in samples from the two sites representing dryland agricultural drainage basins. Herbicides were the type of pesticides most heavily applied in these drainage basins, and the herbicides atrazine, triallate, and simazine were detected most frequently in samples. Some herbicides, for example triallate in the Palouse River drainage basin, were both heavily applied and frequently detected. Others, like atrazine and simazine, were not typically applied to cropland, but were frequently detected in surface-water samples. Several insecticides (Lindane, ethoprop, carbaryl, and azinphos-methyl) were detected in samples from the two sites, although they were not reported as commonly applied to croplands in the dryland agricultural drainage basins. Concentrations of pesticides found in surface waters at the two sites did not exceed drinking water guidelines, but concentrations of the insecticides diazinon and azinphos-methyl and the herbicide triallate exceeded freshwater-chronic criteria for the protection of aquatic life.

Water-Resources Investigations Report↗
USGS1996

Occurrence of selenium and mercury in surface water, Wind River Indian Reservation, Wyoming, 1995

Surface-water samples for chemical analyses were collected during May and August 1995 from 13 sites in an irrigated area of the Wind River Federal Irrigation Project, Wind River Indian Reservation, Wyoming. Sites included irrigation drains, ponds, and streams in an irrigated area partially underlain by seleniferous geologic materials described as having the potential to support vegetation that may be toxic to animals. Samples were analyzed for dissolved selenium, mercury, and other inorganic constituents. The study was done in cooperation with the Shoshone Tribe and the Northern Arapaho Tribe. Six samples analyzed from the May sampling period had dissolved selenium concentrations greater than the aquatic-life chronic criterion of 5 μg/L (micrograms per liter) established by the U.S. Environmental Protection Agency (USEPA). The largest dissolved selenium concentration (49 μg/L) exceeded the aquatic-life acute criterion of 20 μg/L established by the USEPA. Selenium concentrations in all 12 samples collected during the August sampling period were less than the laboratory minimum reporting level of 5 μg/L. The Goose Pond Drain site was dry in August. The dissolved solids concentrations were larger in samples collected in May than in August from all but two sites. The large dissolved selenium concentrations in the May samples, collected prior to the start of the irrigation season, were associated with large dissolved solids concentrations. Dissolved mercury concentrations were less than the minimum reporting level of 0.1 jig/L for 24 of the 25 samples collected during May and August. One sample collected in May had a concentration of 0.3 μg/L. This concentration was less than the aquatic-life acute criterion of 2.4 μg/L for mercury established by the USEPA.

Wyoming↗
USGS1998

Occurrence and distribution of dissolved pesticides in the San Joaquin River basin, California

The effects of pesticide application, hydrology, and chemical and physical properties on the occurrence of pesticides in surface water in the San Joaquin River Basin, California, were examined. The study of pesticide occurrence in the highly agricultural San Joaquin?Tulare Basins is part of the National Water-Quality Assessment Program of the U.S. Geological Survey. One hundred forty-three water samples were collected throughout 1993 from sites on the San Joaquin River and three of its tributaries: Orestimba Creek, Salt Slough, and the Merced River. Of the 83 pesticides selected for analysis in this study, 49 different compounds were detected in samples from the four sites and ranged in concentration from less than the detection limit to 20 micrograms per liter. All but one sample contained at least one pesticide, and more than 50 percent of the samples contained seven or more pesticides. Six compounds were detected in more than 50 percent of the samples: four herbicides (dacthal, EPTC, metolachlor, and simazine) and two insecticides (chlorpyrifos and diazinon). None of the measured concentrations exceeded U.S. Environmental Protection Agency drinking water criteria, and many of the measured concentrations were very low. The concentrations of seven pesticides exceeded criteria for the protection of freshwater aquatic life: azinphos-methyl, carbaryl, chlorpyrifos, diazinon, diuron, malathion, and trifluralin. Overall, some criteria for protection of aquatic life were exceeded in a total of 97 samples. Factors affecting the spatial patterns of occurrence of the pesticides in the different subbasins included the pattern of application and hydrology. Seventy percent of pesticides with known application were detected. Overall, 40 different pesticides were detected in Orestimba Creek, 33 in Salt Slough, and 26 in the Merced River. Samples from the Merced River had a relatively low number of detections, despite the high number (35) of pesticides applied, owing to the generally low percentage of irrigation return flow and contribution of pesticide-free streamflow from reservoir releases. Irrigation return flows in the Orestimba Creek and Salt Slough subbasins generally contained more pesticides at higher concentrations. In addition, the distribution of seven pesticides (alachlor, cyanazine, dacthal, fonofos, molinate, napropamide, and trifluralin) in the subbasins showed a direct spatial correspondence between occurrence and application rates. Temporal patterns of occurrence also were affected by patterns of application and hydrology. Most pesticides showed a clear correspondence between the times of their application and their occurrence. Fourteen pesticides had maximum application and concentrations during the summer irrigation season. However, several pesticides exhibited maximum concentrations during winter storms, although maximum application occurred at some other time of year?the result of differences in precipitation and streamflow between seasons. In some subbasins, precipitation runoff was more effective than irrigation return flows at transporting pesticides from the site of application to the stream. Also, during autumn, when there was neither precipitation nor irrigation, the transport of pesticides to streams was limited. The effect of chemical and physical properties on the occurrence of pesticides was examined for the San Joaquin River Basin as a whole. The runoff potential of each pesticide, calculated from the solubility, water-soil organic carbon partition coefficient Koc, and hydrolysis half-life, is generally consistent with the frequency of detection of pesticides in surface water in relation to the amount applied. These three properties each were generally, and weakly, correlated with the relative load of the pesticides in surface water. Pesticide occurrence and concentrations at the mouth of the basin (the San Joaquin River near Vernalis) was compared with pesticide occurrence and concentration in the three

Water-Resources Investigations Report↗
USGS2000

Benthic invertebrates and quality of streambed sediments in the White River and selected tributaries in and near Indianapolis, Indiana, 1994-96

During this study, 369 benthic-invertebrate samples were collected at 21 sites and 33 streambed-sediment samples were collected at 14 sites to help develop and evaluate control strategies to mediate the impact of point and nonpoint sources of pollution on the White River and selected tributaries in and near Indianapolis, Indiana. Data analyses show that 124 taxa were identified and that most of the benthic invertebrates found belong to one of three taxa: the pollution-tolerant Diptera and the pollution-intolerant Ephemeroptera and Trichoptera. The Hilsenhoff Biotic Index, which was calculated from the number of arthropods and their tolerance to pollution, ranged from 4.4 (very good) to 9.4 (very poor) on the White River, and from 4.9 (good) to 9.1 (very poor) on the tributaries. The Ephemeroptera, Plecoptera, and Trichoptera (EPT) Richness Index, which was calculated from the number of taxa in pollution-intolerant species, ranged from 0 to 9 for the White River and from 0 to 9 for the tributaries. A high EPT Richness Index value reflects a great diversity of pollution-intolerant invertebrates at a site and generally indicates good water quality. A comparison of data collected during the 1994 through 1996 study to data collected during a 1981 through 1987 study indicates that the proportion of pollution-tolerant taxa increased in the immediate vicinity of Indianapolis. This increase may be an indicator that the water quality in the immediate vicinity of Indianapolis has declined since the earlier study. Comparison of the Hilsenhoff Biotic Index values, however, indicates there has been no change since the previous study. In the analysis of streambed sediments, small amounts of 12 metals were detected. Of those, only lead exceeded sediment-quality guidelines for the protection of aquatic life in three samples from two sites. Thirteen insecticides were detected in the streambed sediments, and of those only chlordane exceeded sediment-quality guidelines for the protection of aquatic life. Seventeen semivolatile organic compounds also were detected in streambed sediments at nine sites: four on the White River and five on the tributaries. Six of these compounds exceeded sedimentquality guidelines for the protection of aquatic life.

Indiana↗
USGS2009

Retrospective characterization of ontogenetic shifts in killer whale diets via δ13C and δ15N analysis of teeth

Metabolically inert, accretionary structures such as the dentin growth layers in teeth provide a life history record of individual diet with near-annual resolution. We constructed ontogenetic δ 13 C and δ 15 N profiles by analyzing tooth dentin growth layers from 13 individual killer whales Orcinus orca collected in the eastern northeast Pacific Ocean between 1961 and 2003. The individuals sampled were 6 to 52 yr old, representing 2 ecotypes—resident and transient—collected across ~25° of latitude. The average isotopic values of transient individuals (n = 10) are consistent with a reliance on mammalian prey, while the average isotopic values of residents (n = 3) are consistent with piscivory. Regardless of ecotype, most individuals show a decrease in δ 15 N values of ~2.5‰ through the first 3 yr of life, roughly equivalent to a decrease of one trophic level. We interpret this as evidence of gradual weaning, after which, ontogenetic shifts in isotopic values are highly variable. A few individuals (n = 2) maintained relatively stable δ 15 N and δ 13 C values throughout the remainder of their lives, whereas δ 15 N values of most (n = 11) increased by ~1.5‰, suggestive of an ontogenetic increase in trophic level. Significant differences in mean δ 13 C and δ 15 N values among transients collected off California suggest that individuality in prey preferences may be prevalent within this ecotype. Our approach provides retrospective individual life history and dietary information that cannot be obtained through traditional field observations of free-ranging and elusive species such as killer whales, including unique historic ecological information that pre-dates modern studies. By providing insights into individual diet composition, stable isotope analysis of teeth and/or bones may be the only means of evaluating a number of hypothesized historical dietary shifts in killer whales of the northeast Pacific Ocean

California↗
USGS2012

Age, growth, and reproductive biology of three catostomids from the Apalachicola River, Florida

Riverine catostomids can show a wide range of interspecific variation in life-history characteristics. Understanding these differences is an important consideration in evaluating the sensitivity of these fishes to disturbance and in formulating effective conservation strategies, particularly when dealing with an assemblage consisting of multiple species within a watershed. We collected Apalachicola redhorse Moxostoma n. sp. cf. poecilurum ( n = 125), spotted sucker Minytrema melanops ( n = 94), and quillback Carpiodes cyprinus ( n = 94) to determine age, growth, and reproductive biology of spawning catostomids in the Apalachicola River, Florida, during 2007. Quillback was the smallest in total length at age; longest-lived; most fecund; and produced the smallest eggs. Apalachicola redhorse was the largest in body size; had an intermediate life span; and produced the fewest yet largest eggs. Spotted sucker was more similar to Apalachicola redhorse in most characteristics. Growth during ages 1-3 in all three species seemed to be negatively related to the proportion of observations of extreme flow, both high (Q 90 ) and low (Q 10 ), per year and a positive response in growth rate to high flows (>Q 75 but < Q 90 ). However, Apalachicola redhorse and spotted sucker growth was more sensitive to flow conditions than that of quillback. Our results suggest the life histories and ecological response of Apalachicola River catostomids to flow regulation are important components for developing strategies that incorporate the needs of these fishery resources into an ecosystem-based management approach.

Florida↗
USGS2025

Direct effects of pesticides and other grassland management practices on the North American Monarch Butterfly (Danaus plexippus plexippus): A systematic review

This review synthesizes recent scientific literature on the effects of grassland management practices and pesticide applications on monarch butterflies ( Danaus plexippus ), focusing on studies published since the 2020 U.S. Fish and Wildlife Service Species Status Assessment (SSA). While the SSA highlighted habitat conservation efforts to enhance monarch populations, there has been limited empirical research on the direct effects of these management strategies on monarch survival and fitness. Following PRISMA guidelines, we conducted a systematic review to evaluate research published during and after the SSA (2019-2024) on the direct effects of common grassland management practices (mowing, grazing, burning, haying) and pesticides (herbicides, insecticides, fungicides) across monarch life stages. This search identified 29 studies that met our criteria. Of these, only two studies addressed the impacts of grassland management on monarchs, indicating a substantial and important information gap. The other 27 studies reviewed indicate significant risks of pesticide exposure to monarchs, particularly at immature life stages from lethal and sublethal effects. The effects of chronic insecticide exposure, particularly neonicotinoids, are especially critical to consider, as research shows insecticides can result in impairment of growth, development, and reproductive behaviors. Additionally, fungicides pose overlooked risks to monarchs due to their toxicity to non-target organisms. Notably, most studies evaluating pesticide effects were conducted in a laboratory setting and thus it is unclear how these results relate to fieldrealistic exposure, as well as exposure over multiple life history stages and potential synergistic effects of pesticides. Additional relevant information gaps remain, especially on studies of southern migratory paths critical for monarch population persistence. Data gaps at relevant scales for grassland management combined with growing evidence of pesticide persistence and subsequent threats to insects, highlight how more ecologically applicable metrics for monitoring environmental chemicals could help improve understanding of the effects of pesticides on monarchs and characterize contamination of milkweed and nectar resources.

Cooperator Science Series↗
USGS2021

Epigean crayfish of the Potomac River Basin in West Virginia: Zoogeography, natural history and conservation

Crayfish are an aquatic fauna of conservation concern, yet regional studies are lacking on zoogeography and life history. We compared recent and historical species distribution data and assessed conservation standings of native and nonindigenous crayfish of the Potomac River Basin in West Virginia. From 2007–2011, a total of 1764 crayfish were collected from 159 sites. Data collection included species abundance, morphometrics, and life history parameters. Percentages of the number of individuals of each species of the total catch were 36.3% ( Cambarus bartonii ), 34.6% ( Faxonius obscurus ), 23.4% ( Faxonius virilis ), 3.6% ( Procambarus cf. zonangulus ) and 2.0% ( Cambarus carinirostris ). Cambarus bartonii was present throughout the drainage, F. obscurus was collected primarily from the North Branch, South Branch, and Cacapon river watersheds, and C. carinirostris was only collected in the South Branch watershed. Two nonnative species, F. virilis and P. cf. zonangulus , were only present in tributaries downstream of the Cacapon River watershed. Spinycheek crayfish ( Faxonius limosus ) were not collected during our survey, which suggests its possible extirpation from the West Virginia portion of its range. Our zoogeographic and life history data could serve as a baseline for future conservation-oriented monitoring efforts of the Potomac River watershed.

West Virginia↗
USGS2007

Comparison of immune responses of brown-headed cowbird and related blackbirds to West Nile and other mosquito-borne encephalitis viruses

The rapid geographic spread of West Nile virus (family Flaviviridae , genus Flavivirus , WNV) across the United States has stimulated interest in comparative host infection studies to delineate competent avian hosts critical for viral amplification. We compared the host competence of four taxonomically related blackbird species (Icteridae) after experimental infection with WNV and with two endemic, mosquito-borne encephalitis viruses, western equine encephalomyelitis virus (family Togaviridae , genus Alphavirus , WEEV), and St, Louis encephalitis virus (family Flaviviridae , genus Flavivirus , SLEV). We predicted differences in disease resistance among the blackbird species based on differences in life history, because they differ in geographic range and life history traits that include mating and breeding systems. Differences were observed among the response of these hosts to all three viruses, Red-winged Blackbirds were more susceptible to SLEV than Brewer's Blackbirds, whereas Brewer's Blackbirds were more susceptible to WEEV than Red-winged Blackbirds. In response to WNV infection, cowbirds showed the lowest mean viremias, cleared their infections faster, and showed lower antibody levels than concurrently infected species. Brown-headed Cowbirds also exhibited significantly lower viremia responses after infection with SLEV and WEEV as well as coinfection with WEEV and WNV than concurrently infected icterids. We concluded that cowbirds may be more resistant to infection to both native and introduced viruses because they experience heightened exposure to a variety of pathogens of parenting birds during the course of their parasitic life style.

Journal of Wildlife Diseases↗