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USGS1998

Water quality in the central Columbia Plateau, Washington and Idaho, 1992-95

Water quality in the Central Columbia Plateau of eastern Washington and western Idaho has been adversely affected by agriculture, especially in irrigated areas, according to the results of a five-year investigation by the U. S. Geological Survey (USGS). Some improvements, however, are noticeable, such as less sediment being washed into streams. These improvements may be the result of increased use of best management practices (BMPs) by area farmers. Areas with intensive fertilizer use and irrigation, such as in the Columbia Basin Irrigation Project (CBIP), showed the greatest impacts on ground-water quality. (The CBIP includes parts of Franklin, Grant, and Adams counties in eastern Washington.) <Shallow wells, generally those less than 150 feet deep, are the most susceptible to contamination, the USGS report says. A reassuring aspect of this finding, however, is that many public water supplies draw from wells at greater depths and are less susceptible to contamination from agricultural practices. From the standpoint of human health, we were most concerned about checking for nitrate and pesticides in drinking water,' said Sandy Williamson, USGS hydrologist and chief of the study. 'We found nitrate levels exceeding the maximum contaminant level in about 20 percent of all wells.' (A maximum contaminant level-or MCL-is a drinking water regulatory standard that is set by the U.S. Environmental Protection Agency.) 'The story on pesticides is a mixed bag,' Williamson said. 'We found at least one pesticide in nearly half of the drinking water wells sampled, but pesticide levels were only a very small fraction of their MCLs.' As a cautionary note, however, Williamson said that about half of the pesticides detected in Central Columbia Plateau wells do not have MCLs established. A lack of information makes it difficult to assess the significance of finding pesticides in drinking water. 'As scientists, we don't know enough yet about what happens when these pesticides are combined,' he said. 'In some of the very shallow wells that the USGS installed for monitoring purposes, we found up to seven different pesticides.' Encouraging news is that none of the newer pesticides, which break down more rapidly in the environment, were found at concentrations exceeding MCLs. Compounds that exceed drinking water standards were found in only 1 percent of the wells sampled-and those compounds have not been sold as pesticides since the mid-1980s. However, agricultural impacts on water quality go beyond the concerns for drinking water-the aquatic ecosystem of the plateau also has been significantly affected. 'Very little surface water is used for drinking water in this area, but fish are harmed by decreased stream-water quality,' said Mark Munn, the biologist for the USGS study. 'Pesticides and habitat degradation are the main concerns.' He noted that stream sampling by the USGS showed seven currently used pesticides at concentrations above the limits recommended for protecting aquatic life. Soil erosion, a long-term problem for farmers in the Palouse River Basin, transports some soil to streams, degrading habitat and carrying with it older pesticides and their breakdown products. A breakdown product of the banned insecticide DDT was found in both streambed sediment and bottom fish at concentrations exceeding guidelines for the protection of aquatic life. 'Another problem for fish habitat is excessive plant growth caused by high levels of nutrients in streams,' said Munn, who explained that these nutrients enter streams in runoff from agricultural fields and discharge from urban wastewater treatment plants. Some agricultural practices, such as allowing cattle to graze near streams, are associated with higher rates of erosion. However, increased use of BMPs may improve water quality of the plateau. The USGS study showed that use of sprinkler or drip rather than furrow irrigation has decreased soil erosion in the CBIP area. In the Palouse, erosion

Circular↗

USGS1981

The geology of Hess Rise, central north Pacific Ocean

The geology of Hess Rise is interpreted from studies of morphology and structure, igneous petrology, sediment lithofacies, seismic stratigraphy, and paleoenvironments. Hess Rise probably formed at a triple junction, between 116 and 95 m.y. ago, in the equatorial zone of the southern hemisphere. A large archipelago, formed by volcanism, subsequently moved northward as part of the Pacific Plate and subsided. A Late Cretaceous-early Tertiary tectonic and(or) volcanic event created oceanic islands and probably influenced the normal subsidence rate. The lithofacies reflect both the northward movement under various surface water masses of differing productivity and the subsidence history, which influenced calcareous-sediment accumulation and dissolution. Hess Rise is informally divided into three physiographic or morphologic provinces: northern Hess Rise, the central platform, and southern Hess Rise. Southern Hess Rise is further subdivided into the northwestern ridge, Mellish Bank, and the eastern ridge. The structure of Hess Rise is dominated by normal faults which bound grabens and horsts. The west and south boundaries of the rise are fault scarps. Most faults trend about 345 ° on northern Hess Rise, 039° to 060° on southern Hess Rise. Igneous rocks are tholeiitic basalt on northern Hess Rise at Site 464, and trachyte at Site 465 on southern Hess Rise. The tholeiite probably is not a mid-ocean-ridge basalt; more likely it is a transitional basalt erupted during off-ridge volcanism. The trachyte at Site 465 was erupted either in shallow water or subaerially; it represents a late-stage differentiate of alkali-basalt magma. Geochemically, the trachyte is similar to late-stage eruptives on many oceanic islands. The alkali basalt clasts in Upper Cretaceous calcareous ooze at Site 466 probably record a Late Cretaceous-early Tertiary tectonic event that brought old crust above sea level, where it was eroded; alternatively, volcanism may have built the islands. Cores recovered from Holes 464, 310, 310A, 465,465A, and 466 (north to south) show three major lithofacies: limestone of mid-Cretaceous (Albian-Cenomanian) age, calcareous ooze and chalk of Late Cretaceous to Quaternary age, and pelagic clay that is Late Cretaceous to Quaternary in age at Site 464 and Eocene in age at Site 310. Minor lithofacies in the carbonates and pelagic clay include siliceous microfossils and chert. The limestone contains as much as 8.6% by weight of organic carbon. The organic-carbon-rich sediments apparently were deposited along the sides of Hess Rise, above the CCD and within a mid-water oxygen minimum, as the rise crossed the highly productive equatorial divergence. Surface sediments are influenced by present-day near-surface water-mass productivity and the depth of deposition. Above about 3000 meters calcareous ooze is deposited, and below about 4000 meters pelagic clay is dominant. Between 3000 meters and 4000 meters, greater clay contents correlate with increased water depth. The seismic stratigraphy interpreted from single-channel seismic-reflection records can be correlated with the lithofacies. Three major acoustic units apparently vary in age, composition, thickness, and geographic distribution. The lowest acoustic unit generally is acoustically opaque; it corresponds to volcanic basement. In places, however, the top parts of this unit may be well-lithified limestone or chert. The middle acoustic unit, in general strongly layered acoustically, is Albian and Cenomanian limestone, chalk, and chert on southern Hess Rise and Albian and Cenomanian chert, chalk, limestone, and clay stone on northern Hess Rise. The middle unit probably is Albian to at least lower Tertiary chalk, chert, and nannofossil ooze on the central platform. The upper acoustic unit is weakly stratified to acoustically transparent and corresponds to Upper Cretaceous to Recent nannofossil ooze on southern Hess Rise and to pelagic clay of the same age on northern Hess Rise. On the central platform, it probably corresponds to Eocene to Recent nannofossil ooze, marl, and pelagic clay

Initial Reports of the D.S.D.P.↗

USGS2012

Uranium-lead isotopic ages from the Sierra Nevada Batholith, California

This study provides new information on the timing and distribution of Mesozoic magmatic events in the Sierra Nevada batholithic complex chiefly between 36° and 37°N. latitude. U-Pb ages have been determined for 133 zircon and 7 sphene separates from 82 samples of granitoid rocks. Granitoid rocks in this area range in age from 217 to 80 m.y. Triassic intrusions are restricted to the east side of the batholith; Jurassic plutons occur south of the Triassic plutons east of the Sierra Nevada, as isolated masses within the Cretaceous batholith, and in the western foothills of the range; Cretaceous plutons form a continuous belt along the axis of the batholith and occur as isolated masses east of the Sierra Nevada. No granitic intrusions were emplaced for 37 m.y. east of the Sierra Nevada following the end of Jurassic plutonism. However, following emplacement of the eastern Jurassic granitoids, regional extension produced a fracture system at least 350 km long into which the dominantly mafic, calc-alkalic Independence dike swarm was intruded 148 m.y. ago. The dike fractures probably represents a period of regional crustal extension caused by a redistribution of the regional stress pattern accompanying the Nevadan orogeny. Intrusion of Cretaceous granitic plutons began in large volume about 120 m.y. ago in the western Sierra Nevada and migrated steadily eastward for 40 m.y. at a rate of 2.7 mm/y. This slow and constant migration indicates remarkably uniform conditions of subduction with perhaps downward migration of parent magma generation or a slight flattening of the subduction zone. Such steady conditions could be necessary for the production of large batholithic complexes such as the Sierra Nevada. The abrupt termination of plutonism 80 m.y. ago may have resulted from an increased rate of convergence of the American and eastern Pacific plates and dramatic flattening of the subduction zone. U-Pb ages of the Giant Forest-alaskite sequence in Sequoia National Park are all in the range 99±3 m.y., indicating a relatively short period of emplacement and cooling for this nested group of plutons. U-Pb ages of a mafic inclusion and its host granodiorite indicate that both were derived from a common source or that the mafic inclusion was totally equilibrated with the granodioritic magma. Comparison of isotopic ages determined by different methods such as zircon U-Pb, sphene U-Pb, hornblende K-Ar, and biotite K-Ar suggests that zircon U-Pb ages generally approximate the emplacement age of a pluton. However, some plutons probably contain inherited or entrained old zircons, and the zircons of some samples are disturbed by younger thermal and metamorphic events. The ages reported here are consistent with U-Pb age determinations previously made on granitic rocks to the north [Stern et al., 1981], The age distribution of granitic belts determined here is in general agreement with those established by K-Ar dating [Evernden and Kistler, 1970] but does not differentiate the five epochs of plutonism determined in their study.

California↗

USGS2002

Occurrence and status of volatile organic compounds in ground water from rural, untreated, self-supplied domestic wells in the United States, 1986-99

Samples of untreated ground water from 1,926 rural, self-supplied domestic wells were analyzed for volatile organic compounds (VOCs) during 1986-99. This information was used to characterize the occurrence and status of VOCs in domestic well water. The samples were either collected as part of the U.S. Geological Survey?s National Water-Quality Assessment (NAWQA) Program occurrence-assessment studies or were compiled by NAWQA from existing ambient ground-water or source-water-quality monitoring programs conducted by local, State, and other Federal agencies. Water samples were collected at the wellhead prior to treatment or storage. In most samples, 55 target VOCs were analyzed, and occurrence and status information generally was computed at an assessment level of 0.2 mg/L (microgram per liter). At least one VOC was detected in 12 percent of samples (232 samples) at an assessment level of 0.2 mg/L. This detection frequency is relatively low compared to the 26 percent detection frequency of at least one VOC in public sup-ply wells sampled by NAWQA, and the difference may be due, in part, to the higher pumping rates, pumping stress factors, and larger contributing areas of public supply wells. Samples with detections of at least one VOC were collected from wells located in 31 of 39 States. Solvents were the most frequently detected VOC group with detections in 4.6 percent of samples (89 samples) at an assessment level of 0.2 mg/L. The geographic distribution of detections of some VOC groups, such as fumigants and oxygenates, relates to the use pattern of com-pounds in that group. With the exception of com-pounds used in organic synthesis, detection frequencies of VOCs by group are proportional to the average half-life of compounds in the group. When the organic synthesis group is excluded from the analysis, a good correlation exists between the detection frequency of VOCs by group and average half-life of compounds in the group. Individually, VOCs were not commonly detected at an assessment level of 0.2 mg/L, with the seven most frequently detected VOCs found in only 1 to 5 percent of samples. Mixtures (two or more compounds) were a common mode of occurrence for VOCs when no assessment level was applied, and mixtures occurred in one-half of all samples that contained at least one VOC. Only 1.4 percent of samples (27 samples) had one or more VOC concentrations that exceeded a federally established drinking-water standard or health criterion. Only 0.1 percent of samples (2 samples) had one or more VOC concentrations that exceeded a taste/odor threshold. Potential point sources of VOCs near domestic wells are numerous. Leaks from under-ground storage tanks and aboveground storage tanks that hold gasoline, diesel fuel, or heating oil have the potential to be major point sources of contaminants to domestic wells. Shock chlorination may be a source of trichloromethane and other trihalomethanes in some domestic wells. Septic systems are believed to be an important source of contaminants to domestic wells, but extensive research on this subject does not exist. VOCs frequently are ingredients in household products such as cleansers and insecticides, and some VOCs have been found in septic systems.

Water-Resources Investigations Report↗

USGS1973

Ground water in the Eugene-Springfield area, southern Willamette Valley, Oregon

The cities of Eugene and Springfield and their outlying suburban and rural districts constitute an area of rapid population growth where progressively greater volumes of ground water are being required for irrigation and industrial and public supplies. The area is also one of diverse geologic and hydrologic conditions. As used in this report, the Eugene-Springfield area covers about 450 square miles and includes a part of the lower foothills of the Coast and Cascade Ranges and a strip of the main valley plain of the southern Willamette Valley. Volcanic and sedimentary rock units exposed in the foothills range in age from Eocene to Miocene. In the main valley plain the older units are overlain by Pleistocene and Holocene alluvial deposits. Marine-deposited sandstone, siltstone, shale, and mudstone of the older sedimentary units are fine grained and poorly permeable and yield water slowly to wells. The volcanic rocks, primarily of dacitic and andesitic composition, yield small quantities of water that are generally adequate only for domestic use. The alluvial deposits (sand and gravel) of the valley plain (central lowland) contain the most productive aquifers in the area and are considered to be the only ground-water reservoir for which large-scale development of ground-water supplies is feasible. Aquifers in the area are recharged principally by direct infiltration of precipitation. Most of the precipitation, which averages about 4C inches per year, occurs during late autumn and winter. Minimum recharge by infiltration of precipitation to the alluvial aquifers beneath the valley plain is estimated to be about 100,000 acre-feet. Ground water is discharged naturally from the central lowland by seepage and spring flow to small streams, by subsurface outflow to adjacent areas, and by evapotranspiration. Storage capacity of the central lowland in the Eugene-Springfield area is estimated to be about 2.1 million acre-feet in the zone 10-150 feet below land surface. The quantity of ground water available annually from this area is far greater than the 23,000 acre-feet pumped for all uses in 1968. This pumpage was about 23 percent of the perennial yield (100,000 acre-ft), and about 77,000 acre-feet of water was left available for additional withdrawal. If annual withdrawals of water were increased to 100,000 acre-feet per year, the levels in the ground-water reservoir would be lowered. Once new equilibriums are established, increased withdrawals could be accommodated without progressive losses in aquifer storage or excessive losses in flow of the larger streams. Ground water from the alluvial deposits of the valley plain is chemically suitable for irrigation and other uses, as is most of the water obtained from perched-water bodies in the sedimentary and volcanic rocks. However, the mineral content of water from the older sedimentary rocks, particularly from deeper producing zones, is greater than the mineral content of water from the alluvial deposits. Locally, some of the water from the older rocks is too saline for most uses. Increased use of ground water may result in certain problems pertaining to waste-disposal practices, local overdraft of aquifers, well interference, and well construction. Present data are adequate to evaluate some of the factors relating to foreseeable problems but allow only tentative conclusions to be drawn about other factors, which include local direction of flow, rate of ground-water movement, and areas of possible ground-water contamination. Additional information obtained through systematic study will be needed to deal with these problems.

Oregon↗

USGS2010

Methylmercury cycling, bioaccumulation, and export from agricultural and non-agricultural wetlands in the Yolo Bypass

This 18-month field study addresses the seasonal and spatial patterns and processes controlling methylmercury (MeHg) production, bioaccumulation, and export from natural and agricultural wetlands of the Yolo Bypass Wildlife Area (YBWA). The data were collected in conjuntion with a Proposition 40 grant from the State Water Resources Control Board in support of the development of Best Management Practices (BMP's) for reducing MeHg loading from agricultural lands in the wetland-dominated Yolo Bypass to the Sacramento-San Joaquin River Delta. The four managemenr-based questions addressed in this study were: 1. Is there a different among agricultural and managfed wetland types in terms of Me Hg dynamic (production, degradation, bioaccumulation, or export)? 2. Does water residence time influence MeHg dynamics? 3. Does the application of sulfate-based fertilizer impact MeHg production rates? 4. Does the presence (or absence) of vegetation influence MeHg production rates? Measurements of MeHg concentrations in sediment, water, and biota (plants, invertebrates, and fish) were made to assess management-level patterns in five wetland types, which included three type of shallowly-flooded agricultural wetlands (white rice, wild rice, and fallow) and two types of managed wetlands (permanently and seasonally flooded). To strengthen our understanding of the processes underlying the seasonal and spatial patterns of MeHg cycling, additional exploratory factors were measured including ancillary sediment and water quality parameters, stable isotope fractionation (oxygen, sulfur, carbon, and nitrogen), photodemethylation rates, and daily-integrated hydrologic budgets. Samples and field data were collected from May 2007 to July 2008, and nearly all sample analyses were completed by September 2008 as per the Quality Assurance Program Plan (QAPP) requirements. Although wetland type was a major factor that drove the study design, within-field hydrology also proved to be an important factor controlling aqueous MeHg and total mercury (THg) concentrations and export. Overall, agricultural wetlands exhibited higher MeHg concentrations in overlying water, sediment, and biota than did managed seasonal and permanent wetlands. This appears to be partly due to higher rates of sediment in microbial production of MeHg on agricultural wetlands during the fall through spring period. Both sulfate- and iron-reducing bacteria have been implicated in the MeHg production process, and both were demonstrably active in all wetlands studied; however, sulfate-reducing bacteria were not stimulated by the addition of sulfate-based fertilizer to agricultural wetlands, suggesting that easily-degraded (labile) organic matter, rather than sulfate, was limiting their activity in these field types. The data suggest that agriculturally-managed soils promoted MeHg production through 1) enhanced microbial activity via higher temperatures and larger pools of labile carbon, and 2) enhanced pools of microbially available inorganic divalent mercury (Hg(II)) resulting from a decrease in reduced-sulfur, solid-phase minerals under oxic or only mildly reducing conditions. MeHg mass balances were assessed by comparing filed-specific MeHg loads for inlets vs. outlet flows. The overall mass balance for MeHg in surface water during the summer irrigation period (June - September 2007) indicated little to no net MeHg export from the six agricultural wetlands taken as a whole. Of the six agricultural wetlands, there was net overall MeHg export from two fields (one fallow and one white rice) during August, and from four of the six fields (one fallow, one white rice, and two wild rice) during September) Over the entire summer irrigation period, two of the fields (one fallow and one wild rive) showed net MeHg export, and the other four fields showed wither net import or no significant change. Rates of measured photomethylation and exchange between sediment and water pools suggest that both processes may be responsible for the lack of MeHg export. Despite significant differences during winter months between fields in surface water concentrations of MeHg, MeHg loads were not calculated in mid-winter because flood waters had overtopped field boundaries and field fidelity could not be established. During the summer 2007 irrigation season, surface water out-flows from agricultural wetlands were 9%-36% of inlet flows, and evaporation rates explained most of this water loss, with infiltration likely accounting for the remainder. Unfiltered aqueous MeHg concentrations increased from <1 ng L -1 in source waters to up to 10 ng L -1 in agricultural wetland drains during the summer irrigation period. Increases in solute concentration caused by evapoconcentration were estimated by determining concentration factors (outflow/inflow) for chloride (a conservative dissolved constituent) and by measuring oxygen isotope ratios ( 18 O/ 16 O, expressed as δ 18 O) in water. Increases in MeHg concentration from inflows-to-outflows exceeded those caused by evapoconcentration on several fields during the summer irrigation season. This was especially true when initial surface water MeHg concentrations were low, as seen in the southern block of fields receiving irrigation water directly from the Toe Drain. The northern block of fields received irrigation water from Greens Lake, which included Toe Drain water plus recirculated drain water from other agricultural fields within the Yolo Bypass and west of the Yolo Bypass; as such, the northern fields showed a smaller percentage increase in MeHg concentration because initial MeHg concentrations in surface water inflows were greater than in inputs to the southern fields. Mercury concentrations in fish were greater in agricultural wetlands white rice and wild rice) than in the two permanently flooded wetlands. Additionally, Hg concentrations in biota showed a general increase from inlets to outlets withing agricultural wetlands, but not within permanent wetlands. This was particular evident in white rice fields where caged western mosquitofish at the outlets had Hg concentrations that were more than 4 times higher than in caged fish held at the inlets. Similar spatial patterns in Hg bioaccumulation in agricultural and permanent wetlands were seen for wild populations of western mosquitofish and Mississippi silversides. In contrast to fish, invertebrates, such as water-boatman (Corixidae) and back swimmers (Notonectidae), had greater Hg concentrations in permanent wetlands than in tempoarirly flooded agricultural wetlands, Fish THg concentrations were weakly correlated with water MeHg,a and not correlated with sediment MeHg. In contrast, invertebrate MeHg concentrations were more strongly correlated with sediment MeHg than with water MeHg concentrations. These results illustrate the complexity of MeHg bioaccumulation through food webs and indicate the importance of simultaneously using multiple biosentinels when monitoring MeHg production and bioaccumulation. Despite high sediment production rates and water concentrations in agricultural wetlands, MeHg export was physically limited by hydrologic export for all wetlands studied. We suggest that load reduction is maximized by limiting water throughout, but that on-site biota exposure is maximized by this loner water residence time. While field-specific hydrologic loads could not be fully quantified during flood conditions in February 2008, we suggest that the primary period of MeHg export from Yolo Bypass Wildlife Area is during those winter flooding periods when overall microbial activity and MeHg production in agricultural soils is fueled by the decomposition of rice straw, and when hydrologic flowthrough is maximal. Local stakeholders participated in two workshops related to this study, demonstrating an interest in understanding factors controlling MeHg production, export, and bioaccumulation. The results of this field study show that permanently flooded, naturally vegetated wetlands are unlikely to a large source of MeHg production within the YBWA, in contrast with agriculturally-managed wetlands. MeHg loading to Toe Drain waters of the Yolo Bypass may be reduced by lowering rated of hydrologic export from agricultural wetlands during the growing season and especially during rice harvest, However, under these water-holding conditions, biota living within agricultural wetlands may thus be exposed to higher MeHg concentrations in surface water, As observed in this study, rapid bioacculumaltion over a 2-month period led to MeHg concentrations in invertebrates and fish more than 6 and 11 times higher, respectively, than proposed TMDL target values to protect wildlife (0.03 ppm ww). The results of this field study, together with the information from YBWA stakeholders, provide a more definitive understanding of how MeHg cycling and bioaccumulation respond to habitat differences and specific management practices. These results directly address 4 core components of CBDA's Mercury Strategy for the Bay-Delta Ecosystem (Wiener et al., 2003a): a) Quantification and evaluation of THg and MeHg sources, b) Quantification of effects of ecosystem restoration on MeHg exposure, c) Assessment of ecological risk, and d) Identification and testing of potential management approaches for reducing MeHg contamination. In addition, the quantitative results reported here assess the effect of current land use practices in the Yolo Bypass MeHg production, bioaccumulation and export, and provide process-based advice towards achieving current goals of the RWQCB-CVR's Sacramento -- San Joaquin Delta Estuary TMDL for Methyl & Total Mercury (Wood et al., 2010b). Further work is necessary to evaluate biotic exposure in the Yolo Bypass Wildlife Area at higher trophic levels (e.g. birds), to quantify winter hydrologic flux of MeHg to the larger Delta ecosystem, and to evaluate rice straw management options to limit labile carbon supplies to surface sediment during winter months. In summary, agricultural management of rice fields -- specifically the periodic flooding and production of easily degraded organic matter -- promotes the production of MeHg beyond rates seen in naturally vegetated wetlands, whether seasonally or permanently flooded., The exported load from MeHg from these agricultural wetlands may be controlled by limiting hydrologic export from fields to enhance on-site MeHg removal processes, but the tradeoff is that this impoundement increases Me Hg exposure to resident organisms.

California↗

USGS1954

Geology and uranium deposits of the Caribou area, Boulder County, Colorado

Pitchblende was discovered in the Caribou mine, Boulder County. Colo., in 1948 by Consolidated Caribou Silver Mines, incorporated during the reopening of the 1040-level. Since 1948, a small quantity of pitchblende has been produced from the Radium vein during exploratory work that was done under contract with the Atomic Energy Commission. The Caribou mine, primarily a silver mine, develops five veins (Caribou. No Name, Poorman, Sherman and Silver Dollar) that were formerly worked as separate mines. Three other veins, the Radium, Elmer, and Nelson, are exposed in the Caribou mine only at and below the 920-level. The general geology of the Caribou area, known since 1869 as a silver district, has been discussed by Bastin and Hill (1917) and more recently by Lovering and Goddard (1950). In 1937 a detailed study of the petrography of the Caribou stock was made by Smith (1938). In 1948 and 1949, R.U. King (1950) of the U. S., Geological Survey examined the Caribou mine to evaluate the uranium deposit. In 1950, D.M. Sheridan and E.N. Hinrichs of the U. S. Geological Survey made a radioactivity reconnaissance of the mine dumps at Caribou and vicinity. This reconnaissance included examination of most of the accessible workings of the Caribou mine. Other reports on the area are listed in the bibliography. As a result of King’s preliminary examination and the later exploration for uranium on the property, the U.S. Geological Survey in 1951 began a detailed investigation of the Caribou area on behalf of the Division of Raw Materials of the Atomic Energy Commission, the principal purpose of which was to evaluate the uranium occurrences in the area. The study was begun by E. P. Kaiser and W. S., Cavender, who established a triangulation net, using a base line in Caribou Park for horizontal control and a U.S. Geological Survey bench mark on the top of Caribou Hill for vertical control. Upon the assignment of Kaiser to another project in August 1951 the investigation was continued until November 1951, by F.B. Moore and W. S. Cavender. During the study of the district the writers prepared a geologic map at a scale of 1 inch to 100 feet of an area of about one square mile. The mapped area includes most of the mines in the Caribou district and embraces the eastern half of Caribou Hill and adjacent areas to the east and north. In addition, all accessible underground workings were mapped at a scale of 1 inch to 40 feet. The writers wish to acknowledge the cooperation of the staff of the Consolidated Caribou Silver Mines incorporated, who made the Caribou mine available for examination at all times and who furnished maps and suggestions that were of great assistance. Mr. A.E. Blakesley, owner of the Comstock mine, was also most cooperative in making possible the examination of his mine. Thanks are due Dr., E.E. Wahlstrom of the University of Colorado and to the Boulder Daily Camera for the use of their files containing information on the Caribou mine. To S. Lovering of the U.S. Geological Survey made many valuable suggestions on the identification of alteration products in thin section.

Colorado↗

USGS2002

Geohydrology of Southeastern Pennsylvania

Rapid population growth in southeastern Pennsylvania has increased the demand for ground water. In an effort to address the increased ground-water needs, a ground-water investigation in a 5,200-square-mile area of southeastern Pennsylvania was initiated. Information on the geohydrologic system of the area and the water-bearing capabilities of 51 geohydrologic units in six physiographic provinces or sections (Coastal Plain, Piedmont Upland, Piedmont Lowland, Gettysburg-Newark Lowland, South Mountain, and Reading Prong) has been summarized. Also included are statistical summaries by geohydrologic unit for well construction and discharge data (according to water use), as well as inorganic and radiochemical ground-water-quality data. Characteristics of the ground-water-flow system in the study area, as well as aquifer hydrologic properties, are related to geology, but can be modified by human development. Ground-water flow in the Coastal Plain Physiographic Province, is through intergranular or primary openings under either unconfined or confined aquifer conditions. Historically, ground-water flowed toward the Delaware and Schuylkill Rivers, but the original flow paths and water quality have been altered significantly by urbanization. In igneous and metamorphic rocks (Piedmont Upland, South Mountain, and Reading Prong), ground-water flows through a network of interconnected secondary openings (fractures, joints, cleavage planes). Ground water in the carbonate rocks (Piedmont Lowland) also flows through a network of secondary openings, but these openings have been enlarged by solution. In the Triassic sedimentary rocks (Gettysburg-Newark Lowland), thin tabular aquifers are separated by much thicker, strata-bound aquitards. The fractured Triassic bedrock forms a very complex, anisotropic, and heterogeneous aquifer with horizontal permeability much greater than vertical permeability. In general, ground-water flow in southeastern Pennsylvania takes place within local flow systems that discharge within days or weeks to adjacent stream valleys or surface-water bodies. Intermediate (South Mountain) and regional (Gettysburg-Newark Lowland) scale systems, however, in which residence times have been measured in months or years discharge to major streams or rivers that are located in different physiographic provinces or sections or tens of miles distant. Well depths, casing lengths, reported yields, and specific capacities can vary significantly by geohydrologic unit, use of well, and topographic setting. Wells drilled in the Weverton and Loudon Formations, undivided, and the Montalto Quartzite Member (South Mountain) have median well and casing lengths of 374 and 130 feet, respectively, significantly greater than in almost every other geohydrologic unit in the study area. Wells drilled in the Peach Bottom Slate and Cardiff Conglomerate, undivided (Piedmont Upland) are typically shallow, with a median well depth of 90 feet. Wells in the Marburg Schist (Piedmont Upland) have the lowest median casing length—5.5 feet. Wells in the Stonehenge Formation (Piedmont Lowland), the most productive unit in the study area, have a median reported yield of 200 gallons per minute and a median specific capacity of 27 gallons per minute per foot. The Cocalico Formation (Piedmont Lowland) is the least productive unit with a median reported well yield of 2.5 gallons per minute and a median specific capacity of 0.01 gallons per minute per foot. In general, high-demand wells are significantly deeper, use significantly more casing, and have significantly greater yields than domestic wells drilled in the same unit. Commonly, wells drilled in valleys will have greater reported yields and specific capacities than wells drilled in the same unit on slopes or hilltops. Except where adversely affected by human activities, the quality of ground water in southeastern Pennsylvania is suitable for most purposes. Yet several water-quality criteria are exceeded in many wells throughout the area. Water from 51 percent of 2,075 wells sampled had a pH higher or lower than the range specified in the U.S. Environmental Protection Agency (USEPA) secondary maximum contaminant level (SMCL). Of water samples analyzed, about 1 percent of 1,623 wells contained concentrations of chloride and 27 percent of 1,624 wells sampled contained concentrations of iron that exceeded the USEPA SMCL. Twenty-seven percent of 1,397 wells sampled contained water with manganese concentrations greater than the USEPA SMCL. Sulfate concentrations in the water of 3 percent of 1,699 wells sampled and total dissolved solids in the water from 10 percent of 1,590 wells sampled exceeded the USEPA SMCL. Concentrations of cadmium, chromium, cyanide, mercury, nickel, radium-226, selenium, and zinc in the water exceeded the USEPA maximum contaminant level (MCL) in less than 5 percent of the 183 to 620 wells sampled. Nine percent of 625 wells sampled contained water with lead concentrations that exceeded the USEPA MCL. Radon concentrations in the water of 92 percent of the 285 wells sampled exceeded the proposed USEPA MCL. Radium-228 in the water of 10 percent of the 240 wells sampled and nitrate in the water of 13 percent of 1,413 wells sampled exceeded the USEPA MCL. Gross-alpha activity in the water was measured only in the Chickies and Harpers Formations of the Piedmont Upland, with 23 percent of the 168 wells sampled exceeding the USEPA MCL.

Water-Resources Investigations Report↗

USGS2015

Hydrogeologic and geochemical characterization of groundwater resources in Deep Creek Valley and adjacent areas, Juab and Tooele Counties, Utah, and Elko and White Pine Counties, Nevada

The water resources of Deep Creek Valley were assessed during 2012–13 with an emphasis on better understanding the groundwater flow system and groundwater budget. Surface-water resources are limited in Deep Creek Valley and are generally used for agriculture. Groundwater is the predominant water source for most other uses and to supplement irrigation. Most groundwater withdrawal in Deep Creek Valley occurs from the unconsolidated basin-fill deposits, in which conditions are generally unconfined near the mountain front and confined in the lower-altitude parts of the valley. Productive aquifers are also present in fractured bedrock that occurs along the valley margins and beneath the basin-fill deposits. The consolidated-rock and basin-fill aquifers are hydraulically connected in many areas with much of the recharge occurring in the consolidated-rock mountain blocks and most of the discharge occurring from the lower-altitude basin-fill deposits. Average annual recharge to the Deep Creek Valley hydrographic area was estimated to be between 19,000 and 29,000 acre-feet. Groundwater recharge occurs mostly from the infiltration of precipitation and snowmelt at high altitudes. Additional, but limited recharge occurs from the infiltration of runoff from precipitation near the mountain front, infiltration along stream channels, and possible subsurface inflow from adjacent hydrographic areas. Groundwater moves from areas of recharge to springs and streams in the mountains, and to evapotranspiration areas, springs, streams, and wells in the basins. Discharge may also occur as subsurface groundwater outflow to adjacent hydrographic areas. Average annual discharge from the Deep Creek Valley hydrographic area was estimated to be between 21,000 and 22,000 acre-feet, with the largest portion of discharge occurring as evapotranspiration. Groundwater samples were collected from 10 sites for geochemical analysis. Dissolved-solids concentrations ranged from 126 to 475 milligrams per liter, and none of the sites sampled during this study had dissolved-solids concentrations that exceeded the Environmental Protection Agency secondary standard for drinking water of 500 milligrams per liter. Tritium concentrations from 1.6 to 10.1 tritium units at 3 of the 10 sample sites indicate the presence of modern (less than 60 years old) groundwater, and apparent tritium/helium-3 ages calculated for these sites ranged from 7 to 29 years. The other seven sample sites had tritium concentrations less than or equal to 0.4 tritium units and are assumed to be pre-modern. Adjusted minimum radiocarbon ages of these seven pre-modern water samples ranged from 1,000 to 8,000 years with the ages of at least four of the samples being more than 3,000 years. Noble-gas recharge temperatures indicate that groundwater sampled along the valley axis recharged at both mountain and valley altitudes, providing evidence for both mountain-block and mountain-front recharge. Water-level altitude contours and groundwater ages indicate the potential for a long flow path from southwest to northeast between northern Spring and Deep Creek Valleys through Tippett Valley. Although information gathered during this study is insufficient to conclude whether or not groundwater travels along this interbasin flow path, dissolved sulfate and chloride data indicate that a small fraction of the lower altitude, northern Deep Creek Valley discharge may be sourced from these areas. Despite the uncertainty due to limited data collection points, a hydraulic connection between northern Spring Valley, Tippett Valley, and Deep Creek Valley appears likely, and potential regional effects resulting from future groundwater withdrawals in northern Spring Valley warrant ongoing monitoring of groundwater levels across this area.

Nevada, Utah↗

USGS1999

Evaluation of water quality and bulk atmospheric deposition in the Guanella Pass area, Clear Creek and Park Counties, Colorado, water year 1995

A study of water quality and bulk atmospheric deposition in the Guanella Pass area during water year 1995 (October 1994 to September 1995) has provided information to characterize conditions in the South Clear Creek and Geneva Creek Basins about 40 miles west of Denver, Colorado, prior to a possible roadreconstruction project. Analytical results of water samples collected from streams, ground water, and lakes and reservoirs indicate that water in the study area generally contained small concentrations of dissolved solids (low-flow stream sample median, 43 milligrams per liter; ground-water median, 104 milligrams per liter) and suspended sediment (high-flow stream sample median, 115 milligrams per liter). Nutrient, trace-element, and organic-carbon concentrations also were small. Acidic pH and large trace-element concentrations were associated with areas affected by natural acid-sulfate weathering or mining. Increases in particulate nutrients, total recoverable trace elements, and suspended sediment were related to seasonal snowmelt and thunderstorms. Benthic macroinvertebrate and periphyton (algae) samples collected from selected sites in August 1995 indicated large variability in characteristics among sites. Macroinvertebrate density ranged from 6.5 to 1,300 organisms per square meter, and periphyton biovolume ranged from 0.023 to 4,700 x 10 6 cubic microns per square centimeter. The discharge of road runoff from any single drainage feature (ditch or culvert) was small compared to streamflows. Analytical results from samples of road runoff indicated a large range in specific conductance, pH in a neutral range, large values of turbidity, and calcium bicarbonate type water. Sodium or magnesium and chloride, however, were predominant in some samples and were probably related to applications of sodium and magnesium chloride to the roads. Although dissolved nutrients and trace elements were detected in samples of road runoff, particulate forms had the largest concentrations. Suspended-sediment concentrations in road runoff were large, and the sediment was primarily fine grained. Large concentrations of dissolved and total recoverable nutrients, total recoverable trace elements, total organic carbon, and suspended sediment in road runoff could cause increased concentrations in streams, lakes, and reservoirs. Ground-water concentrations of chloride, nitrite plus nitrate, and dissolved iron and manganese·could increase if the large concentrations present in road runoff infiltrate shallow aquifers. Bulk atmospheric deposition was collected at three sites with a paved road surface, five sites with a gravel or dirt surface, and five sites with collectors at least 500 feet away from a road. The median bulk -atmospheric-deposition rate for gravel (or dirt) roads was 106 times the median rate at a reference site (located at least 500 feet away from a road) and 39 times the median rate at a typical paved road site. If a stream, lake, or reservoir is located near the road, bulk-atmospheric- deposition products may settle directly onto open water or be washed in by surface runoff. Because the predominant road-runoff trace-element phase is particulate, potential toxic effects on receiving water may be minimal when compared to aquatic-life standards and regulations in the State of Colorado, which are primarily based on dissolved concentrations. U.S. Environmental Protection Agency primary maximum contaminant levels for drinking water were exceeded for dissolved uranium (proposed) in one ground-water sample.

Colorado↗

USGS2024

Snake River Fall Chinook Salmon research and monitoring

In Chapter 1, we report on development and application of an integrated population model (IPM) for the natural-origin fall Chinook salmon population upstream of Lower Granite Dam. This year’s efforts represent the third update to the model. Initial efforts focused on generating juvenile and adult abundance estimates, with estimates of uncertainty, for informing the life-cycle model and estimating the effects of covariates on key demographic parameters. The goals of this year’s report are to 1) describe the modifications and advances made since the previous report, 2) to annually update and report the abundance estimates and other quantities used in the model, 3) to provide annual estimates of population parameters estimated by the IPM, and 4) to outline the next year’s tasks for advancing and/or applying the model. Since our last report on the life-cycle model, we have made a number of changes including: 1) incorporating jack abundance and age-structure data into the observation model, 2) changing smolt-to-adult survival (SAR) for subyearling and yearling to partial SARs that represent the joint probability surviving and entering the ocean at a given juvenile age, 3) combining age categories for rarely observed ages, 4) using scale data from unmarked fish to estimate age structure, and 5) generating composite life-cycle demographic parameters (cumulative capacity and productivity) from stage-specific parameters. We also generated juvenile abundance estimates, extended the model to include three additional brood years (1992– 2021), and ran the model to forecast returns to Lower Granite in 2022. For posterior medians of life stage-specific parameters, we estimated a mean productivity of 438 natural-origin juvenile recruits per female spawner, a capacity of 1.36 million juveniles, and a mean smolt-to-adult survival (SAR) of 1.2%. We detected strong density-dependent regulation, with juvenile recruits per spawner declining to about 50 juvenile recruits per female spawner at high spawner abundance. Across the entire life cycle, these stage-specific parameters resulted in a median cumulative intrinsic productivity of 1.93 adult female recruits per female spawner and a median equilibrium abundance of 2,851 female spawners (7,842 total spawners). Annual juvenile productivity varied from about 250–1,000 juveniles per spawner but displayed no temporal trends or patterns. For the three most recent brood years added to the model, recruits per spawner were higher than average but well within the range of uncertainty observed over the entire time series. In contrast to juvenile recruitment variability, SAR varied considerably among years and exhibited two periods of high survival (1996–2001 and 2007–2012) when SAR ranged from 2% to 6% and cumulative productivity ranged from 2 to 8 recruits per spawner. Partial SARs revealed that yearling outmigrants contributed substantially to the high SARs in the first high-survival period, but the second period was dominated by subyearlings. Yearlings contributed >30% to SAR in most years prior to 2007, and <30% since 2007. Our two-stage IPM provides a wealth of information about population dynamics affecting two key life-stage transitions (spawner to juvenile, and juvenile to spawner) centered on passage at Lower Granite Dam. By summarizing these stage-specific demographic parameters across the entire life cycle, this information will be useful for informing the recovery status of this threatened population. Whereas previous versions introduced hydrosystem and ocean covariates into the model, this phase of model development focused on solidifying the underlying model structure by introducing the concept of partial SARs and developing composite productivity and capacity as a function of underlying stage-specific parameters. Given this advancement, our next steps are to re-incorporate covariates into the model, specifically to understand how different factors affect partial SARs of subyearling and yearlings. Longer term model developments include:1) incorporating hatchery fish to explicitly estimate their survival as an alternative method for estimating natural-origin age composition, 2) expanding the model’s structure to include the three major spawning aggregates, 3) more explicitly modeling hydrosystem effects including transportation, and 4) using the model to assess retrospective and prospective management actions. In 2022, the U.S. Geological Survey (USGS) focused adult salmon survey efforts in the Snake River on deepwater redd searches and fish collection for parentage-based tagging (PBT) analyses. We use used a boat-mounted underwater video camera to count 99 deepwater redds at 16 of the 29 sites surveyed. Redd depths averaged 4.4 m. In conjunction with the Idaho Power Company, we collected genetic samples from 318 live fall Chinook salmon (Oncorhynchus tshawytscha) and 19 carcasses at 40 unique geographic locations that spanned 91 river kilometers. Eighty fish were collected at three sites (High Range [rkm 332.3], Dug Bar [rkm 315.4], and Three Creek [rkm 384.0]), which accounted for 23% of all collected fish in 2022. Most (333 fish) post-spawned salmon were collected from early to mid-November just after the peak of spawning. A summary of 2021 PBT results produced by the Idaho Power Company can be found in Appendix A.2. Beach seining and PIT tagging of subyearling fall Chinook salmon was conducted in Snake and Salmon rivers to obtain information on population metrics and growth as well as to provide data for ongoing life-cycle modeling. In the Snake River, we collected 7,496 subyearlings, tagged 4,139, and recaptured 502 (12.1%). Using 8-mm tags in 45–49-mm fish allowed us to represent an additional 25% of the juvenile population through PIT tagging beyond just using standard 9- and 12-mm tags. In the Salmon River, we captured 206 natural subyearlings with the majority (52%) of fish being captured at two sites: rkm 20 and 26. We tagged 145 subyearlings and recaptured 9 fish. Many of the subyearlings we tagged in the Snake River were detected passing Lower Granite Dam, but only 4 fish tagged in the Salmon River were detected. In total we detected 484 (11.3%) tagged fish at Lower Granite Dam, and detection rates varied by tag size and passage route. More subyearlings were detected passing via the removable spill weir (RSW) earlier in the season while more fish were detected passing through the juvenile fish bypass system (JBS) earlier in the season while more fish were detected passing via the removable spill weir (RSW) later in the season. In general, fish tagged with 12-mm PIT tags had higher detection rates than fish tagged with smaller tags. Survival to Lower Granite Dam was low and ranged from 0.22 to 0.36. Season-wide, growth of subyearlings was higher in the lower reach than in the upper reach of the Snake River.

Idaho, Oregon, Washington↗

USGS2014

Geologic and hydrogeologic frameworks of the Biscayne aquifer in central Miami-Dade County, Florida

Evaluations of the lithostratigraphy, lithofacies, paleontology, ichnology, depositional environments, and cyclostratigraphy from 11 test coreholes were linked to geophysical interpretations, and to results of hydraulic slug tests of six test coreholes at the Snapper Creek Well Field (SCWF), to construct geologic and hydrogeologic frameworks for the study area in central Miami-Dade County, Florida. The resulting geologic and hydrogeologic frameworks are consistent with those recently described for the Biscayne aquifer in the nearby Lake Belt area in Miami-Dade County and link the Lake Belt area frameworks with those developed for the SCWF study area. The hydrogeologic framework is characterized by a triple-porosity pore system of (1) matrix porosity (mainly mesoporous interparticle porosity, moldic porosity, and mesoporous to megaporous separate vugs), which under dynamic conditions, produces limited flow; (2) megaporous, touching-vug porosity that commonly forms stratiform groundwater passageways; and (3) conduit porosity, including bedding-plane vugs, decimeter-scale diameter vertical solution pipes, and meter-scale cavernous vugs. The various pore types and associated permeabilities generally have a predictable vertical spatial distribution related to the cyclostratigraphy. The Biscayne aquifer within the study area can be described as two major flow units separated by a single middle semiconfining unit. The upper Biscayne aquifer flow unit is present mainly within the Miami Limestone at the top of the aquifer and has the greatest hydraulic conductivity values, with a mean of 8,200 feet per day. The middle semiconfining unit, mainly within the upper Fort Thompson Formation, comprises continuous to discontinuous zones with (1) matrix porosity; (2) leaky, low permeability layers that may have up to centimeter-scale vuggy porosity with higher vertical permeability than horizontal permeability; and (3) stratiform flow zones composed of fossil moldic porosity, burrow related vugs, or irregular vugs. Flow zones with a mean hydraulic conductivity of 2,600 feet per day are present within the middle semiconfining unit, but none of the flow zones are continuous across the study area. The lower Biscayne aquifer flow unit comprises a group of flow zones in the lower part of the aquifer. These flow zones are present in the lower part of the Fort Thompson Formation and in some cases within the limestone or sandstone or both in the uppermost part of the Pinecrest Sand Member of the Tamiami Formation. The mean hydraulic conductivity of major flow zones within the lower Biscayne aquifer flow unit is 5,900 feet per day, and the mean value for minor flow zones is 2,900 feet per day. A semiconfining unit is present beneath the Biscayne aquifer. The boundary between the two hydrologic units is at the top or near the top of the Pinecrest Sand Member of the Tamiami Formation. The lower semiconfining unit has a hydraulic conductivity of less than 350 feet per day. The most productive zones of groundwater flow within the two Biscayne aquifer flow units have a characteristic pore system dominated by stratiform megaporosity related to selective dissolution of an Ophiomorpha-dominated ichnofabric. In the upper flow unit, decimeter-scale vertical solution pipes that are common in some areas of the SCWF study area contribute to high vertical permeability compared to that in areas without the pipes. Cross-hole flowmeter data collected from the SCWF test coreholes show that the distribution of vuggy porosity, matrix porosity, and permeability within the Biscayne aquifer of the SCWF is highly heterogeneous and anisotropic. Groundwater withdrawals from production well fields in southeastern Florida may be inducing recharge of the Biscayne aquifer from canals near the well fields that are used for water-management functions, such as flood control and well-field pumping. The SCWF was chosen as a location within Miami-Dade County to study the potential for such recharge to the Biscayne aquifer from the C–2 (Snapper Creek) canal that roughly divides the well field in half. Geologic, hydrogeologic, and hydraulic information on the aquifer collected during construction of monitoring wells within the SCWF could be used to evaluate the groundwater flow budget at the well-field scale.

Florida↗

USGS1997

Depositional sequence stratigraphy and architecture of the cretaceous ferron sandstone: Implications for coal and coalbed methane resources - A field excursion

This Field Excursion will visit outcrops of the fluvial-deltaic Upper Cretaceous (Turonian) Ferron Sandstone Member of the Mancos Shale, known as the Last Chance delta or Upper Ferron Sandstone. This field guide and the field stops will outline the architecture and depositional sequence stratigraphy of the Upper Ferron Sandstone clastic wedge and explore the stratigraphic positions and compositions of major coal zones. The implications of the architecture and stratigraphy of the Ferron fluvial-deltaic complex for coal and coalbed methane resources will be discussed. Early works suggested that the southwesterly derived deltaic deposits of the the upper Ferron Sandstone clastic wedge were a Type-2 third-order depositional sequence, informally called the Ferron Sequence. These works suggested that the Ferron Sequence is separated by a type-2 sequence boundary from the underlying 3rd-order Hyatti Sequence, which has its sediment source from the northwest. Within the 3rd-order depositional sequence, the deltaic events of the Ferron clastic wedge, recognized as parasequence sets, appear to be stacked into progradational, aggradational, and retrogradational patterns reflecting a generally decreasing sediment supply during an overall slow sea-level rise. The architecture of both near-marine facies and non-marine fluvial facies exhibit well defined trends in response to this decrease in available sediment. Recent studies have concluded that, unless coincident with a depositional sequence boundary, regionally extensive coal zones occur at the tops of the parasequence sets within the Ferron clastic wedge. These coal zones consist of coal seams and their laterally equivalent fissile carbonaceous shales, mudstones, and siltstones, paleosols, and flood plain mudstones. Although the compositions of coal zones vary along depositional dip, the presence of these laterally extensive stratigraphic horizons, above parasequence sets, provides a means of correlating and defining the tops of depositional parasequence sets in both near-marine and non-marine parts of fluvial-deltaic depositional sequences. Ongoing field studies, based on this concept of coal zone stratigraphy, and detailed stratigraphic mapping, have documented the existence of at least 12 parasequence sets within the Last Chance delta clastic wedge. These parasequence sets appear to form four high frequency, 4th-order depositional sequences. The dramatic erosional unconformities, associated with these 4th-order sequence boundaries, indicate that there was up to 20-30 m of erosion, signifying locally substantial base-level drops. These base-level drops were accompanied by a basin ward shift in paleo-shorelines by as much as 5-7 km. These 4th-order Upper Ferron Sequences are superimposed on the 3rd-order sea-level rise event and the 3rd-order, sediment supply/accommodation space driven, stratigraphie architecture of the Upper Ferron Sandstone. The fluvial deltaic architecture shows little response to these 4th-order sea-level events. Coal zones generally thicken landward relative to the mean position of the landward pinch-out of the underlying parasequence set, but after some distance landward, they decrease in thickness. Coal zones also generally thin seaward relative to the mean position of the landward pinch-out of the underlying parasequence set. The coal is thickest in the region between this landward pinch-out and the position of maximum zone thickness. Data indicate that the proportion of coal in the coal zone decreases progressively landward from the landward pinch-out. The effects of differential compaction and differences in original pre-peat swamp topography have the effect of adding perturbations to the general trends. These coal zone systematics have major impact on approaches to exploration and production, and the resource accessment of both coal and coalbed methane.

Brigham Young University Geology Studies↗

USGS2016

Hydrogeological framework, numerical simulation of groundwater flow, and effects of projected water use and drought for the Beaver-North Canadian River alluvial aquifer, northwestern Oklahoma

This report describes a study of the hydrology, hydrogeological framework, numerical groundwater-flow models, and results of simulations of the effects of water use and drought for the Beaver-North Canadian River alluvial aquifer, northwestern Oklahoma. The purpose of the study was to provide analyses, including estimating equal-proportionate-share (EPS) groundwater-pumping rates and the effects of projected water use and droughts, pertinent to water management of the Beaver-North Canadian River alluvial aquifer for the Oklahoma Water Resources Board. The Beaver-North Canadian River alluvial aquifer consists of unconsolidated sand, gravel, silt, and clay in varying proportions that underlies the Beaver and North Canadian River Valleys for approximately 175 miles (mi) from the Oklahoma Panhandle to the western edge of Oklahoma City in central Oklahoma. The aquifer as delineated for this study varies from 4 to 12 mi wide and is as thick as 308 feet (ft) in the northwest where the aquifer includes the Ogallala Formation. There are two distinct but in most areas hydraulically connected alluvial units that compose the Beaver-North Canadian River alluvial aquifer: a Quaternary-age topographically higher terrace deposit and a topographically lower, younger alluvium along the active river channel that includes active and Quaternary-age alluvium. The Beaver River composes the headwaters of the North Canadian River, which begins at the confluence of the Beaver River and Wolf Creek. The aquifer is divided for water management into two geographic areas: Reach I upstream from Canton Dam and Reach II downstream from Canton Dam. Reach I covers an area of approximately 874 square miles (mi 2 ), and Reach II covers an area of approximately 371 mi 2 . The Beaver-North Canadian River alluvial aquifer crosses several climatic zones, from semiarid in the west to continental subhumid in the east. Mean annual precipitation varies from 23.5 inches (in.) in the western part of this aquifer to 35.7 in. in the east. Surface-water demands were met through numerous temporary and permanent surface-water diversions from the Beaver and North Canadian Rivers during the period of study. During the study period, seven diversions removed a mean annual 2,000 acre-feet (acre-ft) of water from Reach I. There were 14 diversions from Reach II with a mean annual permitted volume of approximately 81,000 acre-ft, including diversion into the Lake Hefner Canal for the Oklahoma City public water supply. During the period of this study, 17 temporary surface-water diversion permits were active in Reach I, with total permitted volumes of 2,000 acre-ft, and 41 diversions were active in Reach II, with total permitted volumes of 38,000 acre-ft. The total water use for each temporary permit was assumed to be taken over the 3-month period allotted to temporary withdrawal permits. The groundwater-use analysis full period of record, 1967–2011, was divided into two sub-intervals because of varying water use, 1970–80 and 1981–2011. Groundwater use in Reach I and Reach II was substantially greater from 1970 to 1980 compared to the rest of the period, and the sub-period 1981–2011 was used because this period includes recent population growth and modern irrigation methods. The total mean annual groundwater use in Reach I was 15,309 acre-feet per year (acre-ft/yr) during 1967–2011; 20,724 acre-ft/yr during 1970–80, and 13,739 acre-ft/yr during 1981–2011. Total mean annual groundwater use in Reach II was similar but slightly less than in Reach I, with 14,098 acre-ft/yr during 1967–2011; 19,963 acre-ft/yr during 1970–80; and 12,285 acre-ft/yr during 1981–2011. Irrigation composed 72 percent of groundwater use in Reach I and 48 percent of groundwater use in Reach II during the 1967–2011 period. Public water supply was a much smaller proportion of total groundwater use in Reach I (15 percent) than in Reach II (39 percent). The proportion of groundwater use for power was 10 percent in Reach I and 5.2 percent in Reach II. All other water-use categories in Reach I only composed 2.2 percent of groundwater use in Reach I. In Reach II, industrial, mining, and commercial categories combined accounted for 4.4 percent of groundwater use; recreation, fish, and wildlife groundwater use accounted for 2.3 percent; and nonirrigated agriculture accounted for 1.5 percent of groundwater use. Permian-age bedrock underlies the Beaver-North Canadian River alluvial aquifer. In the east, the Dog Creek Shale, the Duncan Sandstone, and the Blaine and Chickasha Formations, none of which are notable sources of groundwater in the study area, underlie the Beaver-North Canadian River alluvial aquifer. In the northwestern part of Reach I, bedrock is composed of the Rush Springs and Marlow Formations, which are productive aquifers in some areas. The Cloud Chief Formation is not a source of groundwater. One hydrogeological unit was delineated in the Beaver-North Canadian River alluvial aquifer, composed of the terrace deposits and alluvium, with limited flow between this unit and bedrock units. Groundwater in this aquifer generally flows from northwest to southeast and across the aquifer toward the Beaver and North Canadian Rivers. Groundwater recharge from precipitation was estimated for the entire Beaver-North Canadian River alluvial aquifer and then itemized for both reaches by using a soil-water-balance (SWB) model. At two locations in Reach I, a water-table fluctuation method was used to estimate local recharge. Total mean annual groundwater recharge from the soil-water-balance method was estimated to be approximately 136,400 acre-ft in Reach I and 82,400 acre-ft in Reach II; the mean annual recharge for both reaches combined was approximately 218,800 acre-ft. Two sites in Reach I located at observation wells with continuous water-level measurements and nearby streamflow-gaging stations with precipitation gages were used to estimate the percentage of precipitation that becomes groundwater recharge. The Woodward site was located at observation well OW-4 near the Woodward, Okla. (07237500), streamflow-gaging station. Total precipitation and recharge for the Woodward and Seiling sites were calculated for the water year 2013. The Woodward site had a total of 14.18 in. of precipitation and 6.3 in. of recharge was calculated, equaling 44 percent of precipitation. The mean percentage of precipitation that was estimated to become recharge in the SWB model for the period 1980–2011 at that location was 9.2 percent, although adjacent SWB-model cells were as high as 20 percent of precipitation. The Seiling site had a total of 26.84 in. of precipitation during the water year 2013, and a total of 6.9 in. of recharge was estimated, equaling 25.9 percent of precipitation. At the Seiling site, the mean percentage of precipitation that became recharge in the SWB model for the period 1980–2011 was 23.0 percent. The principal inflow to the Beaver-North Canadian River alluvial aquifer was estimated to be surface recharge from precipitation, and plant evapotranspiration was estimated to be the greatest discharge, followed by stream and lake base flow, groundwater pumping, and flow to seeps and springs along the eastern margin of the aquifer. Reach I also included inflow from the High Plains aquifer as lateral inflow of groundwater, though this flow was estimated to be a very minor component of the total water budget. Most of the Beaver and North Canadian Rivers were determined to be gaining streamflow from groundwater, but several reaches in Reach I upstream from Wolf Creek were determined to be losing streamflow through infiltration to the aquifer. Aquifer hydrogeologic characteristics were estimated from borehole lithologic logs, well-construction information, and published aquifer tests and during numerical model calibration. The maximum saturated aquifer thickness in Reach I was estimated to be 308 ft, and the mean thickness was estimated to be 36 ft. The maximum saturated thickness in Reach II was estimated to be 86 ft, and the mean thickness was estimated to be 29 ft. Mean hydraulic conductivity of Reach I was estimated to be 70 feet per day (ft/d) with a range of 7–279 ft/d. Mean hydraulic conductivity in Reach II was estimated to be 92 ft/d with a range of 4–279 ft/d. Both reach models were calibrated manually by using trial-and-error adjustment of recharge, hydraulic conductivity, specific yield, and conductance of boundary conditions. The Reach I model used 28 head observations during the steady-state period of 1980 and 487 head observations during the transient period of 1981–2011. The root-mean-square error of head residuals (observed minus simulated head) was 3.86 ft, and 83 percent of head residuals were between -5 and 5 ft. The Reach II model was calibrated to 75 steady-state head observations and 134 head observations during the transient period. The root-mean-square error of head residuals for that reach was 3.58 ft, and similar to Reach I, 85 percent of residuals were between -5 and 5 ft. Several analyses were performed by using the numeric groundwater-flow models as predictive tools, including estimating the EPS pumping rate for both reaches. The EPS is defined by the Oklahoma Water Resources Board as an annual per-acre groundwater-pumping rate that will reduce saturated thickness in half of the aquifer to 5 ft or less over a period of 20 years; additional estimates were made for periods of 40 and 50 years. Other analyses included using models to estimate the effects of groundwater pumping and a prolonged drought on groundwater in storage and streamflow and lake storage of water. The EPS pumping rate was found to be approximately 0.57 acre-feet per acre per year ([acre-ft/acre]/yr) in Reach I and 0.73 (acre-ft/acre)/yr in Reach II for a 20-year period. For a 40-year period, the annual EPS pumping rate was determined to be 0.54 (acre-ft/acre)/yr in Reach I and 0.61 (acre-ft/acre)/yr in Reach II. For a 50-year period, the EPS pumping rate was determined to be 0.53 (acre-ft/acre)/yr in Reach I and 0.61 (acre-ft/acre)/yr in Reach II. Groundwater pumping at the 2011 rate for 50 years resulted in a 3.6-percent decrease in the amount of water in groundwater storage in Reach I and a decrease of 2.5 percent in the amount of groundwater in storage in Reach II. A cumulative 32-percent increase in pumping greater than the 2011 rate over a period of 50 years caused a decrease in groundwater storage of 4.0 percent in Reach I and 3.3 percent in Reach II. A hypothetical severe drought was simulated by using aquifer recharge flow rates during the drought year of 2011 for a period of 10 years. All other flows including evapotranspiration and groundwater pumping were set at estimated 2011 rates. The hypothetical drought caused a decrease in water in aquifer storage by about 7 percent in Reach I and 7 percent in Reach II. Another analysis of the effects of hypothetical drought estimated the effects of drought on streamflow and lake storage. The hypothetical drought was simulated by decreasing recharge by 75 percent for a selected 10-year period (1994–2004) during the 1980–2011 simulation. In Reach I, the amounts of water stored in Canton Lake and streamflow at the Seiling, Okla., streamflow-gaging station were analyzed. Streamflow at the Seiling station decreased by a mean of 75 percent and was still diminished by 10 percent after 2011. In Reach II, the effect of drought on the streamflow at the Yukon, Okla., streamflow-gaging station was examined. The greatest mean streamflow decrease was approximately 60 percent during the simulated drought, and after 2011, the mean decrease in streamflow was still about 5 percent. Canton Lake storage decreased by as much as 83 percent during the simulated drought and did not recover by 2011.

Oklahoma↗

USGS1959

Iron-ore resources of the United States including Alaska and Puerto Rico, 1955

The importance of iron ore, the basic raw material of steel, as a fundamental mineral, resource is shown by the fact that about 100 million long tons of steel is used annually in the economy of the United States, as compared with a combined total of about 5 million long tons of copper, lead, zinc, and aluminum. Satisfying this annual demand for steel requires about 110 million tons of iron ore and 70 million tons of scrap iron and steel. The average annual consumption of iron ore in the United States from 1951 to 1955, inclusive, was about 110 million long tons, which is about twice the annual average from 1900 to 1930. Production of iron ore in the United States in this 5-year period averaged approximately 100 million long tons annually, divided by regions as follows (in percent): Lake Superior, 84.1; southeastern, 6.7; western, 6.7; northeastern, 1.4; and central and gulf, 1.1. Mining of iron ore began in the American Colonies about 1619, and for 225 years it was limited to eastern United States where fuel and markets were readily available. Production of iron ore from the Lake Superior region began in 1846; the region became the leading domestic source by 1890, and the Mesabi range in Minnesota has been the world's most productive area since 1896. Proximity of raw materials, water transportation, and markets has resulted in centralization of the country's iron and steel industry in the lower Great Lakes area. Increased imports of iron ore being delivered to eastern United States as well as demands for steel in nearby markets have given impetus to expansion in the steel-making capacity in this area. The four chief iron-ore minerals - hematite, liminite, magnetite, and siderite - are widely distributed but only locally form deposits of sufficient tonnage and grade to be commercially valuable at the present time. The iron content of these minerals, of which hematite is the most important, ranges from 48 percent in siderite to 72 percent in magnetite, but as these minerals are associated with other rock-forming minerals, the iron content of marketable ore has a lower range from 30 to 67 percent. Chemical constituents other than iron also are important in determining the marketability of iron ore. Although some iron ores can be used in the blast furnace as mined, others must first be improved either chemically by reduction of undesirable constituents, or physically by aggregation. Phosphorus and sulfur particularly are common deleterious elements; excessive silica is also undesirable but within certain limits can be controlled by additional flux. Lime and magnesia are beneficial in specified amounts because of their fluxing qualities, and a small amount of alumina improves the fluidity of slag. Manganese is especially desirable as a deoxidizing and desulfurizing agent. Titanium, chromium, and nickel must also be considered in the use of ore containing these elements. The principal iron-ore deposits in the United States have been formed by three processes. Hematite-bearing bedded deposits such as those at Birmingham, Ala., are marine sedimentary rocks which, except for weathering along the outcrop, have remained practically unaltered since deposition. Deposits of the Lake Superior region, also in sedimentary strata, originally had a slightly lower iron content than those at-Birmingham, but ore bodies of hematite and limonite were formed by removal of other constituents in solution after deposition of the beds, with a relative increase of iron content in the material remaining. Limestone adjacent to igneous intrusions has been replaced by magnetite deposits at Cornwall, Pa., and by hematite-magnetite deposits near Cedar City, Utah. Magnetite deposits in New Jersey and in the Adirondack Mountains of New York are generally believed to have been formed by replacement of grains of other minerals in metamorphic rocks. Iron-ore resources are made up of reserves of iron ore, material usable under existing economic and technologic conditions; and potential ore, material likely to become usable under more favorable conditions. The tonnage and grade of material of combined reserves and potential ore in each of the deposits known or believed to contain at least 200,000 long tons of iron-ore resources are tabulated in this report, and numerous sources of additional information are given in a selected bibliography. The total domestic iron-ore resources are estimated at approximately 75,000 million long tons of crude ore. About 10,000 million tons of the resources is reserves of crude ore that will probably yield 5,500 million tons of concentrates and direct-shipping ore. About 65,000 million tons is potential ore and may yield 25,000 million tons of concentrates and some direct-shipping ore.

Bulletin↗

USGS2008

Water Quality Conditions in Upper Klamath and Agency Lakes, Oregon, 2006

The U.S. Geological Survey Upper Klamath Lake water quality monitoring program gathered information from multiparameter continuous water quality monitors, physical water samples, dissolved oxygen production and consumption experiments, and meteorological stations during the June-October 2006 field season. The 2006 study area included Agency Lake and all of Upper Klamath Lake. Seasonal patterns in water quality were similar to those observed in 2005, the first year of the monitoring program, and were closely related to bloom dynamics of the cyanobacterium (blue-green alga) Aphanizomenon flos-aquae (AFA) in the two lakes. High dissolved oxygen and pH conditions in both lakes before the bloom declined in July, which coincided with seasonal high temperatures and resulted in seasonal lows in dissolved oxygen and decreased pH. Dissolved oxygen and pH in Upper Klamath and Agency Lakes increased again after the bloom recovered. Seasonal low dissolved oxygen and decreased pH coincided with seasonal highs in ammonia and orthophosphate concentrations. Seasonal maximum daily average temperatures were higher and minimum dissolved oxygen concentrations were lower in 2006 than in 2005. Conditions potentially harmful to fish were influenced by seasonal patterns in bloom dynamics and bathymetry. Potentially harmful low dissolved oxygen and high un-ionized ammonia concentrations occurred mostly at the deepest sites in the Upper Klamath Lake during late July, coincident with a bloom decline. Potentially harmful pH conditions occurred mostly at sites outside the deepest parts of the lake in July and September, coincident with a heavy bloom. Instances of possible gas bubble formation, inferred from dissolved oxygen data, were estimated to occur frequently in shallow areas of Upper Klamath and Agency Lakes simultaneously with potentially harmful pH conditions. Comparison of the data from monitors in nearshore areas and monitors near the surface of the water column in the open waters of Upper Klamath Lake revealed few differences in water quality dynamics. Median daily temperatures were higher in nearshore areas, and dissolved oxygen concentrations were periodically higher as well during periods of high AFA bloom. Differences between the two areas in water quality conditions potentially harmful to fish were not statistically significant (p < 0.05). Chlorophyll a concentrations varied temporally and spatially throughout Upper Klamath Lake. Chlorophyll a concentrations indicated an algal bloom in late June and early July that was followed by an algae bloom decline in late July and early August and a subsequent recovery in mid-August. Sites in the deepest part of the lake, where some of the highest chlorophyll a concentrations were observed, were the same sites where the lowest dissolved oxygen concentrations and the highest un-ionized ammonia concentrations were recorded during the bloom decline, indicating cell senescence. Total phosphorus concentrations limited the initial algal bloom in late June and early July. The rate of net dissolved oxygen production (that is, production in excess of community respiration) and consumption (due to community respiration) in the lake water column as measured in light and dark bottles, respectively, ranged from 2.79 to -2.14 milligrams of oxygen per liter per hour. Net production rate generally correlated positively with chlorophyll a concentration, except episodically at a few sites where high chlorophyll a concentrations resulted in self-shading that inhibited photosynthesis. The depth of photic zone was inversely correlated with chlorophyll a concentration. Calculations of a 24-hour change in dissolved oxygen concentration indicated that oxygen-consuming processes predominated at the deep trench sites and oxygen-producing processes predominated at the shallow sites. In addition, calculations of the 24-hour change in dissolved oxygen indicate that oxygen-consuming processes in the water column di

Scientific Investigations Report↗

USGS1975

Preliminary hydrogeologic appraisal of selected hydrothermal systems in northern and central Nevada

Several hydrothermal systems in northern and central Nevada were explored in a hydrogeologic reconnaissance. The systems studied comprise those at Stillwater and Soda Lakes-Upsal Hogback in the Carson Desert, Gerlach, Fly Ranch-Granite Range, and Double Hot Springs in the Black Rock Desert, Brady's Hot Springs, Leach Hot Springs in Grass Valley, Buffalo Valley Hot Springs, and Sulphur Hot Springs in Ruby Valley. The investigation focused on (1) delineating of areas of high heat flow associated with rising thermal ground water, (2) determining the nature of the discharge parts of the hydrothermal systems, (3) estimating heat discharge from the systems, (4) estimating water discharge from the systems, (5) obtaining rough estimates of, conductive heat flow outside areas of hydrothermal discharge, and (6) evaluating several investigative techniques that would yield the required information quickly and at relatively low cost. The most useful techniques were shallow test drilling to obtain geologic, hydraulic, and thermal data and hydrogeologic mapping of the discharge areas. The systems studied are in the north-central part of the Basin and Range province. Exposed volcanic rocks of latest Tertiary and Quaternary age are chiefly basaltic. Basaltic terranes are generally regarded as less favorable for geothermal resources than terranes that contain large volumes of young volcanic mocks of felsic to intermediate composition. Most of the known hydrothermal systems are associated with Basin and Range faults which are caused by crustal extension across the province. An area of high heat flow centered at Battle Mountain and possibly other areas of high heat flow may be related to crustal heat sources. However, some of the hydrothermal systems studied appear to be related to deep circulation of meteoric water in areas of 'normal' regional heat flow rather than to shallow-crustal heat sources. Discharge temperatures of thermal springs in the region range from slightly above mean annual air temperature (8?-12?C at most places) to boiling or slightly hotter. Geochemical data indicate that, in the major systems, subsurface temperatures at which thermal waters equilibrate with reservoir rocks range from 150? to more than 200?C. These data also indicate that the major systems are of the hot-water type rather than the vapor-dominated type. Depths of thermal-water circulation probably range from 2 to 6 kilometres in areas of 'normal' regional heat flow (~2 heatflow units) and from 1 to 3 kilometres in areas of high heat flow (~3-4 heat-flow units) such as near Battle Mountain. Most of the heat is discharged from the hydrothermal systems studied by (1) conduction through near-surface materials heated as a consequence of thermal-water convection, (2) convection as springflow, and (3) convection as steam discharge from spring pools, vents, fumaroles, and cracks. The mate of heat discharge by radiation from warm ground and by convection as lateral ground-water outflow is believed to be small in most systems and is not estimated. Estimates of net heat discharge from the systems studied range from about 0.8 x 106 calories per second at Buffalo Valley Hot Springs to about 14 x 106 calories per second at Stillwater. These estimates represent the approximate magnitude of the excess heat discharge from the thermal areas that results from the upward convection of hot water from deep sources. Water discharges from the hydrothermal systems by springflow, evapotranspiration, steam discharge, and lateral ground-water outflow. Estimated discharges range from about 0.2 x 106cubic metres per year from the Buffalo Valley Hot Springs system to about 3 x 106 cubic metres per year from the Stillwater system. In most of the hydrothermal systems studied and, by inference, in other similar systems in northern and central Nevada, the scale for potential .commercial development for production of electricity or for other uses may be constrained by the

Open-File Report↗

USGS1991

Geohydrology and ground-water resources of Philadelphia, Pennsylvania

The aquifers underlying the 134.6-square-mile city of Philadelphia are divided by the Fall Line into the unconsolidated aquifers (chiefly sand and gravel) of the Coastal Plain and the consolidated-rock aquifers (chiefly schist of the Wissahickon Formation) of the Piedmont. Ground water is present under confined and unconfined conditions. The principal units of the confined-aquifer system are the lower and middle sands of the Potomac-Raritan-Magothy aquifer system. The lower sand unit is the most productive aquifer in Philadelphia. The median yield of wells screened in the lower sand unit is 275 gal/min (gallons per minute), and yields of some wells are as high as 1,350 gal/min. The median specific capacity is 16 (gal/min)/ft (gallons per minute per foot of drawdown). The principal units of the unconsolidated unconfined-aquifer system are the upper sand unit of the Potomac-Raritan-Magothy aquifer system and the informally named Trenton gravel. The median yield of wells tapping these two undifferentiated units is 90 gal/min, and yields of some wells are as high as 1,370 gal/min. The median specific capacity is 12 (gal/min)/ft. The consolidated unconfined-aquifer system consists mainly of the Wissahickon Formation. The median yield of nondomestic wells that tap the Wissahickon Formation is 45 gal/min, and yields are as high as 350 gal/min. The median specific capacity is 0.5 (gal/min)/ft. Urbanization has considerably modified the hydrologic cycle in Philadelphia. Impervious surfaces have reduced recharge areas and evapotranspiration and have increased direct runoff. Leakage from the water-distribution system, which is supplied from the Delaware and Schuylkill Rivers, was about 60 to 72 Mgal/d (million gallons per day) in 1980. Groundwater infiltration to sewers is estimated to be as much as 135 Mgal/d when the water table is high. The potentiometric surface of the lower sand unit has been lowered substantially by pumping. By 1954, cones of depression were more than 50 ft (feet) below sea level at the U.S. Naval Base and more than 70 ft below sea level along the Delaware River northeast of the naval base. As a result of withdrawals, declining heads in the lower sand unit caused water to flow downward from the overlying unconsolidated deposits and the water table to decline below sea level along the Delaware River. Beginning in the mid1960's, ground-water withdrawals from the lower sand unit decreased, and, by 1979, water levels had risen 25 ft at the U.S. Naval Base and 45 ft farther north along the Delaware River. As of 1985, water levels in the lower sand unit were controlled largely by pumping in nearby parts of New Jersey. Urbanization also has caused substantial degradation of the quality of ground water in Philadelphia. By 1945, the quality of water in the unconfined aquifer system began to deteriorate as contaminants present at the land surface migrated down- ward. Withdrawal of water from the deeper confined aquifers caused a head decline that resulted in downward movement of contaminated water from the overlying unconfined aquifer system. Consequently, water in the confined aquifers deteriorated progressively in chemical quality so it resembles water in the unconfined aquifer system. The concentration of dissolved solids in water samples collected during 1979-80 ranged from 90 to 4,480 mg/L (milligrams per liter). The average concentration of 778 mg/L was 45 percent higher than that of samples collected during 1945-58. Water from the unconfined unconsolidated aquifers generally had the highest dissolved-solids concentration. The concentration of dissolved iron in water samples collected during 197980 ranged from 0 to 220 mg/L and exceeded 0.30 mg/L in 71 percent of the samples. The average concentration of 17 mg/L was nearly 30 percent higher than that of samples collected during 1945-58. Many wells have been abandoned because of elevated iron concentrations. The concentration of dissolved manganese in water

Water Supply Paper↗