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Hydrological information products for the Off-Project Water Program of the Klamath Basin Restoration Agreement

The Klamath Basin Restoration Agreement (KBRA) was developed by a diverse group of stakeholders, Federal and State resource management agencies, Tribal representatives, and interest groups to provide a comprehensive solution to ecological and water-supply issues in the Klamath Basin. The Off-Project Water Program (OPWP), one component of the KBRA, has as one of its purposes to permanently provide an additional 30,000 acre-feet of water per year on an average annual basis to Upper Klamath Lake through "voluntary retirement of water rights or water uses or other means as agreed to by the Klamath Tribes, to improve fisheries habitat and also provide for stability of irrigation water deliveries." The geographic area where the water rights could be retired encompasses approximately 1,900 square miles. The OPWP area is defined as including the Sprague River drainage, the Sycan River drainage downstream of Sycan Marsh, the Wood River drainage, and the Williamson River drainage from Kirk Reef at the southern end of Klamath Marsh downstream to the confluence with the Sprague River. Extensive, broad, flat, poorly drained uplands, valleys, and wetlands characterize much of the study area. Irrigation is almost entirely used for pasture. To assist parties involved with decisionmaking and implementation of the OPWP, the U.S. Geological Survey (USGS), in cooperation with the Klamath Tribes and other stakeholders, created five hydrological information products. These products include GIS digital maps and datasets containing spatial information on evapotranspiration, subirrigation indicators, water rights, subbasin streamflow statistics, and return-flow indicators. The evapotranspiration (ET) datasets were created under contract for this study by Evapotranspiration, Plus, LLC, of Twin Falls, Idaho. A high-resolution remote sensing technique known as Mapping Evapotranspiration at High Resolution and Internalized Calibration (METRIC) was used to create estimates of the spatial distribution of ET. The METRIC technique uses thermal infrared Landsat imagery to quantify actual evapotranspiration at a 30-meter resolution that can be related to individual irrigated fields. Because evaporation uses heat energy, ground surfaces with large ET rates are left cooler as a result of ET than ground surfaces that have less ET. As a consequence, irrigated fields appear in the Landsat images as cooler than nonirrigated fields. Products produced from this study include total seasonal and total monthly (April-October) actual evapotranspiration maps for 2004 (a dry year) and 2006 (a wet year). Maps showing indicators of natural subirrigation were also provided by this study. "Subirrigation" as used here is the evapotranspiration of shallow groundwater by plants with roots that penetrate to or near the water table. Subirrigation often occurs at locations where the water table is at or above the plant rooting depth. Natural consumptive use by plants diminishes the benefit of retiring water rights in subirrigated areas. Some agricultural production may be possible, however, on subirrigated lands for which water rights are retired. Because of the difficulty in precisely mapping and quantifying subirrigation, this study presents several sources of spatially mapped data that can be used as indicators of higher subirrigation probability. These include the floodplain boundaries defined by stream geomorphology, water-table depth defined in Natural Resources Conservation Service (NRCS) soil surveys, and soil rooting depth defined in NRCS soil surveys. The two water-rights mapping products created in the study were "points of diversion" (POD) and "place of use" (POU) for surface-water irrigation rights. To create these maps, all surface-water rights data, decrees, certificates, permits, and unadjudicated claims within the entire 1,900 square mile study area were aggregated into a common GIS geodatabase. Surface-water irrigation rights within a 5-mile buffer of the study area were then selected and identified. The POU area was then totaled by water right for primary and supplemental water rights. The maximum annual volume (acre-feet) allowed under each water right also was calculated using the POU area and duty (allowable annual irrigation application in feet). In cases where a water right has more than one designated POD, the total volume for the water right was equally distributed to each POD listed for the water right. Because of this, mapped distribution of diversion rates for some rights may differ from actual practice. Water-right information in the map products was from digital datasets obtained from the Oregon Water Resources Department and was, at the time acquired, the best available compilation of water-right information available. Because the completeness and accuracy of the water-right data could not be verified, users are encouraged to check directly with the Oregon Water Resources Department where specific information on individual rights or locations is essential. A dataset containing streamflow statistics for 72 subbasins in the study area was created for the study area. The statistics include annual flow durations (5-, 10-, 25-, 50-, and 95-percent exceedances) and 7-day, 10-year (7Q10) and 7-day, 2-year (7Q2) low flows, and were computed using regional regression equations based on measured streamflow records in the region. Daily streamflow records used were adjusted as needed for crop consumptive use; therefore the statistics represent streamflow under more natural conditions as though irrigation diversions did not exist. Statistics are provided for flow rates resulting from streamflow originating from within the entire drainage area upstream of the subbasin pour point (referring to the outlet of the contributing drainage basin). The statistics were computed for the purpose of providing decision makers with the ability to estimate streamflow that would be expected after water conservation techniques have been implemented or a water right has been retired. A final product from the study are datasets of indicators of the potential for subsurface return flow of irrigation water from agricultural areas to nearby streams. The datasets contain information on factors such as proximity to surface-water features, geomorphic floodplain characteristics, and depth to water. The digital data, metadata, and example illustrations for the datasets described in this report are available on-line from the USGS Water Resources National Spatial Data Infrastructure (NSDI) Node Website http://water.usgs.gov/lookup/getgislist or from the U.S. Government website DATA.gov at http://www.data.gov with links provided in a Microsoft® Excel® workbook in appendix A.

California;Oregon↗

Evapotranspiration from successional vegetation in a deforested area of the Lake Wales Ridge, Florida

The suitability of three evapotranspiration models (Penman-Monteith, Penman, and a modified Priestley-Taylor) was evaluated at a site of successional vegetation in a deforested area of the Lake Wales Ridge, Florida. Eddy correlation measurements of evapotranspiration made during 22 approximately 1-day periods at a temporal resolution of 20 minutes from September 1993 to August 1994 were used to calibrate the evapotranspiration models. Three variants of the eddy correlation method that ascribe measurement error to three different sources were considered in the analysis. The Penman-Monteith and modified Priestley- Taylor models were successful in approximating measured 20-minute values of evapotranspiration (r 2 ≥0.918). The most successful approaches were the modified Priestley-Taylor model (r 2 =0.972) and a nontraditional and simplified form of the Penman-Monteith model (r 2 =0.967). The Penman approach was unsuccessful as a predictor of evapotranspiration. The evapotranspiration models were used to estimate evapotranspiration between measurements. When evapotranspiration values measured with a Bowen ratio variant of the eddy correlation method were used for model calibration, estimated daily evapotranspiration rates varied seasonally ranging from 0.2 millimeters per day (0.008 inch per day) in late December 1993 to 5 millimeter per day (0.2 inch per day) in mid-July 1994. Annual evapotranspiration (September 15, 1993, to September 15, 1994) was estimated to be about 680 millimeters (27 inches). Evapotranspiration models calibrated to the standard eddy correlation method and to an energy-balance residual variant provided estimates of annual evapotranspiration that were about 10 per cent lower and higher, respectively. These data indicate that of the 1,320 millimeters (52 inches) of precipitation during the 1-year period, about 570 to 700 millimeters (22 to 28 inches) recharged the surficial aquifer. Evapotranspiration at this study site probably defines the lower limit of evapotranspiration from vegetated surfaces in central Florida because of the shallow-rooted plants, rapidly-drained soils, and relatively deepwater table.

Florida↗

Tracking heat in the Willamette River system, Oregon

The Willamette River Basin in northwestern Oregon is home to several cold-water fish species whose habitat has been altered by the Willamette Valley Project, a system of 13 dams and reservoirs operated by the U.S. Army Corps of Engineers. Water-resource managers use a variety of flow- and temperature-management strategies to ameliorate the effects of upstream Willamette Valley Project dams on the habitat and viability of these anadromous and native fish. In this study, new capabilities were added to the CE-QUAL-W2 two-dimensional flow and water-quality model to inform those flow- and temperature-management strategies by tracking the quantities and ages of water and heat from individual upstream sources to downstream locations in the Willamette River system. Specifically, the fraction of water and heat attributable to upstream dam releases or other water inputs, and the fraction of heat sourced from environmental heat fluxes across the water and sediment surfaces, were tracked and quantified in the river at all locations and times simulated by the model. Applying the updated CE-QUAL-W2 models to the Willamette River system for the months of March through October in the years 2011 (cool and wet), 2015 (hot and dry), and 2016 (warm and somewhat dry) demonstrated that the influence of upstream dam releases on downstream water temperature diminished within a few days as water moved downstream. At sites that are roughly two or more days of travel from upstream dams (Albany and downstream), the July–August fraction of riverine heat content that could be tracked back to upstream dam releases typically diminished to less than 20 percent, despite the fact that roughly 50 percent of July–August streamflow could be attributed to upstream dam releases at the same sites. In contrast, the fraction of riverine heat content that could be attributed to environmental energy fluxes continued to increase with downstream distance, from about 59 to 67 percent at Albany during July–August to 62 to 73 percent at Keizer and 68 to 79 percent at Newberg. At locations sufficiently far downstream, upstream dam releases affect water temperature mainly through a decrease in travel time (less time for environmental heat fluxes to warm the river during summer) and an increase in thermal mass (more water to dilute and buffer incoming heat fluxes) rather than through the simple transport of heat content (water temperature) released from the dams. This concept was explored not only for the baseline conditions that occurred in March–October of 2011, 2015, and 2016, but also for a hypothetical high-flow release during August 2016 and an actual high-flow release during August 2017. In these high-flow releases, an extra 2,500 cubic feet per second (roughly) was released from Dexter Dam on the Middle Fork Willamette River, and downstream effects were measured (2017, actual) and simulated (2016, hypothetical). Results of the simulations were consistent with insights gained from the baseline conditions, such that temperature changes caused by flow augmentation were substantial in upstream reaches (measured cooling of about 1.5 °C near Harrisburg [43 miles downstream] and Albany [84 miles downstream] in 2017, and cooling of about 0.5 °C near Albany in 2016) and diminished farther downstream, but still measurable (more than a few tenths of a degree Celsius) even at Newberg, which is about 154 miles downstream. The direct downstream effects of dam releases on the river heat content attributable to those releases were increased by the hypothetical flow augmentation, with increases of 20 percent at Harrisburg and 12 percent at Keizer. Even with a decreased influence of environmental energy fluxes on river heat content, however, the fraction of heat content attributable to such fluxes was still more than 50 percent at and downstream of Albany and more than 70 percent at Newberg, where the river temperature was less affected by upstream dam-release temperatures and instead was affected primarily by a decreased travel time and increased thermal mass.

Oregon↗

Patterns of bubble bursting and weak explosive activity in an active lava lake—Halema‘uma‘u, Kīlauea, 2015

The rise of the Halemaʻumaʻu lava lake in 2013–2018 to depths commonly 40 meters or less below the rim of the vent was an excellent opportunity to study outgassing and the link to associated eruptive activity. We use videography to investigate the rise and bursting of bubbles through the free surface of the lake in 2015. We focus on low-energy explosive activity (spattering) in which the ascent and bursting of meter-sized, mechanically decoupled bubbles trigger the ejection of fluidal bombs to tens of meters above the free surface. A decay in initial pyroclast velocity with time follows the same functional form as that observed for ejecta at Stromboli (Italy), suggesting a similar bubble-burst mechanism. We also find that the upward velocity of the bubble crust as it bursts is around 2.5 times higher than the velocity of the bubble as it rises through the lake surface, indicating that the bubbles are over-pressurized. Prior to bursting, bubbles emerge at velocities of 4 to 14 meters per second, suggesting rise from depths of at least tens of meters but unaffected by the deeper circulation of the lava lake. We identify three styles of bubble bursting: (1) isolated, widely spaced, single bursts, (2) recurring clusters of discrete bubbles, and (3) prolonged episodes of overlapping bubble bursts along elongate narrow sources typically parallel to the margins of the lava lake. We call these styles of bursting isolated events, clusters, and prolonged episodes, respectively. The frequency of bubble bursting and the mass fluxes of gas and pyroclasts increase from styles 1 to 3. The intensity (mass eruption rate) for single bubble bursts ranges from 280 to 3,500 kilograms per second. The total erupted mass of pyroclasts for a single burst is <4,000 kilograms (kg) and for a single well-constrained prolonged episode is about 10 7 kg. These numbers place the observed spattering at the lowest end of basaltic explosivity in terms of erupted mass (that is, magnitude). Most ejecta fell back into the crater; only strands of Pele’s hair rose to heights where they could be advected downwind from the vent. Collectively, the explosive activity accompanying the three styles of bubble bursting spans from impulsive, transient eruptive behaviors to sustained discharge; this shift represents progressively higher frequency and intensity of bubble bursting.

Hawaii↗

Effects of elevated water temperature on physiological responses in adult freshwater mussels

Freshwater mussels (order Unionoida) face multiple environmental stressors, which pose serious conservation challenges to this diverse assemblage of aquatic invertebrates. Of these stressors, elevated water temperature from global climate change and other anthropogenic sources may be the most ubiquitous and could be placing many mussel populations dangerously close to their thermal maxima. We tested the hypothesis that elevated water temperatures (20, 25, 30 and 35 &deg;C) adversely affected physiological responses in adults of four North American species of mussels ( Amblema plicata , Elliptio complanata, Fusconaia flava and Lampsilis cardium) in 21-d laboratory tests. Oxygen consumption rates were directly affected by temperature in E. complanata and L. cardium , and indirectly affected by temperature in A. plicata and F. flava . Rates of O 2 consumption were generally positively correlated with water temperature. Ammonium excretion rates varied significantly with temperature in E. complanata and generally increased with temperature. The amount of O 2 consumed relative to nitrogen excreted (O : N ratio), varied significantly with temperature in A. plicata , E. complanata and F. flava . The tissue condition index varied among temperatures and species. These data suggest that elevated temperatures can alter metabolic rates in native mussels and may decrease the amount of energy that is available for key biological processes, such as survival, growth and reproduction.

Freshwater Biology↗

Encylopedia of Caves

For many people, a visit to a cave is a wondrous event directing our minds to ponder the mysteries presented by these unique places and inspiring questions: How old is the cave? What was the role of water in forming the cave and where did the water come from? How is the cave connected to the surface environment? These are intriguing questions to ask, and karst scientists use isotope geochemistry to help solve these mysteries. Isotopes are atoms of the same chemical element that have the same number of protons but vary in their number of neutrons. As a result of their atomic mass difference, isotopes of a single element may exhibit slightly different chemical behavior. Radioisotopes are unstable and the nucleus of a parent isotope will spontaneously break apart (decay), releasing energy and changing into another element (daughter product) by loss or gain of protons, neutrons, or electrons. Stable isotopes, as implied by the name, are stable and do not spontaneously decay. These two types of isotopes are used widely by scientists to understand ancient and modern karst systems. Generally, radioisotopes are used for absolute dating karst water, cave sediments, cave formations (speleothems), and other material preserved in caves (such as bones). Stable isotopes can provide information about relative ages of cave water and speleothems. An absolute age provides a numeric date—such as 100,000 years old—whereas a relative age provides information that something is older or younger than something else—such as cave art is younger than a speleothem found in the same cave. Stable isotopes are used to study ancient karst systems because isotopic signals of past climate (paleoclimate) and environmental conditions (paleoenvironment) are preserved in speleothems and sediments. Stable isotopes are also used to understand modern systems, primarily through studies that distinguish sources of karst water, cave air, or contaminants, mixing of those sources, and biologic or chemical reactions that process compounds, such as breakdown of contaminants or organic matter. The variation in mass among isotopes is small, and isotope abundances are measured as a ratio of a common isotope to its less common isotopic counterparts (stable isotopes) or the abundance of a parent compared to daughter isotope (radioisotopes). As an example, hydrogen (H) has three naturally occurring isotopes. Most H comprises one proton (1H), but the rarer stable isotope (called deuterium) comprises one proton and one neutron (2H), and the radioisotope (called tritium) comprises one proton and two neutrons (3H). Because scientists use the minute differences in isotopes to test hypotheses, a scientist must understand the accuracy, precision, and error of the available methods, the assumptions about the chemical conditions of interest, and the limitations of the isotopic method being used. Many isotopic studies employ multiple isotopic tracers to better leverage the strengths and offset the limitations of using a single isotope. This article focuses on isotopes used to study the geology and hydrology of caves, but much additional isotopic work has been used to characterize the biology of caves.

Book chapter↗

Trophic structure of mesopelagic fishes in the Gulf of Mexico revealed by gut content and stable isotope analyses

Mesopelagic fishes represent an important component of the marine food web due to their global distributions, high abundances and ability to transport organic material throughout a large part of the water column. This study combined stable isotope (SIAs) and gut content analyses (GCAs) to characterize the trophic structure of mesopelagic fishes in the North-Central Gulf of Mexico. Additionally, this study examined whether mesopelagic fishes utilized chemosynthetic energy from cold seeps. Specimens were collected (9–25 August 2007) over three deep (>1,000 m) cold seeps at discrete depths (surface to 1,503 m) over the diurnal cycle. GCA classified 31 species (five families) of mesopelagic fishes into five feeding guilds: piscivores, large crustacean consumers, copepod consumers, generalists and mixed zooplanktivores. However, these guilds were less clearly defined based on stable isotope mixing model (MixSIAR) results, suggesting diets may be more mixed over longer time periods (weeks–months) and across co-occurring species. Copepods were likely important for the majority of mesopelagic fishes, consistent with GCA (this study) and previous literature. MixSIAR results also identified non-crustacean prey items, including salps and pteropods, as potentially important prey items for mesopelagic fishes, including those fishes not analysed in GCA ( Sternoptyx spp. and Melamphaidae). Salps and other soft-bodied species are often missed in GCAs. Mesopelagic fishes had δ 13 C results consistent with particulate organic matter serving as the baseline organic carbon source, fueling up to three trophic levels. Fishes that undergo diel vertical migration were depleted in 15 N relative to weak migrators, consistent with depth-specific isotope trends in sources and consumers, and assimilation of 15 N-depleted organic matter in surface waters. Linear correlations between fish size and δ 15 N values suggested ontogenetic changes in fish diets for several species. While there was no direct measure of mesopelagic fishes assimilating chemosynthetic material, detection of infrequent consumption of this food resource may be hindered by the assimilation of isotopically enriched photosynthetic organic matter. By utilizing multiple dietary metrics ( e.g . GCA, δ 13 C, δ 15 N, MixSIAR), this study better defined the trophic structure of mesopelagic fishes and allowed for insights on feeding, ultimately providing useful baseline information from which to track mesopelagic trophodynamics over time and space.

Marine Ecology↗

Metabolizable energy in Chinese tallow fruit for Yellow-rumped Warblers, Northern Cardinals, and American Robins

The invasive exotic Chinese tallow tree (Triadica sebifera) produces an abundant fruit crop, which is primarily bird-dispersed. The fruit pulp of tallow is lipid-rich, high in saturated fatty acids, and consumed by many bird species. Long-chained fatty acids can be difficult for many birds to digest and we investigated the ability of tallow consumers to assimilate energy in the pulp. We used the total collection method and compared apparent metabolizable energy (AME) of tallow fruit for three species of birds with differing fruit composition in their natural diets. All birds exhibited nitrogen deficits and lost body mass during the trials. Northern Cardinals (Cardinalis cardinalis) lost more mass (8.73%/day) than Yellow-rumped Warblers (Dendroica coronata) (5.29%/day) and American Robins (Turdus migratorius) (5.48%/day), and had larger nitrogen deficits (-120.1 mg N/g diet) than both species as well (-36.4 mg N/g diet and -68.9 mg N/g diet, respectively). Food intake relative to metabolic body mass was highest in Yellow-rumped Warblers (0.70 g-dry/g 0.75??day). Northern Cardinal and American Robin food intake was lower and did not differ from each other (both species: 0.13 g-dry/g 0.75??day). Nitrogen corrected values of AME were used to make species comparisons. Yellow-rumped-Warblers exhibited the highest values of AME (30.00 kJ/g), followed by American Robins (23.90 kJ/g), and Northern Cardinals (14.34 kJ/g). We suggest tallow may be an important winter food source for Yellow-rumped Warblers where their ranges overlap.

Wilson Journal of Ornithology↗

Non-linear resonant coupling of tsunami edge waves using stochastic earthquake source models

Non-linear resonant coupling of edge waves can occur with tsunamis generated by large-magnitude subduction zone earthquakes. Earthquake rupture zones that straddle beneath the coastline of continental margins are particularly efficient at generating tsunami edge waves. Using a stochastic model for earthquake slip, it is shown that a wide range of edge-wave modes and wavenumbers can be excited, depending on the variability of slip. If two modes are present that satisfy resonance conditions, then a third mode can gradually increase in amplitude over time, even if the earthquake did not originally excite that edge-wave mode. These three edge waves form a resonant triad that can cause unexpected variations in tsunami amplitude long after the first arrival. An M &sim; 9, 1100 km-long continental subduction zone earthquake is considered as a test case. For the least-variable slip examined involving a Gaussian random variable, the dominant resonant triad includes a high-amplitude fundamental mode wave with wavenumber associated with the along-strike dimension of rupture. The two other waves that make up this triad include subharmonic waves, one of fundamental mode and the other of mode 2 or 3. For the most variable slip examined involving a Cauchy-distributed random variable, the dominant triads involve higher wavenumbers and modes because subevents, rather than the overall rupture dimension, control the excitation of edge waves. Calculation of the resonant period for energy transfer determines which cases resonant coupling may be instrumentally observed. For low-mode triads, the maximum transfer of energy occurs approximately 20&ndash;30 wave periods after the first arrival and thus may be observed prior to the tsunami coda being completely attenuated. Therefore, under certain circumstances the necessary ingredients for resonant coupling of tsunami edge waves exist, indicating that resonant triads may be observable and implicated in late, large-amplitude tsunami arrivals.

Geophysical Journal International↗

Rare earth element mineral deposits in the United States

Because of their unique special chemical properties, many of the metals in the group of rare earth elements (REEs) have essential applications in 21st century technologies. Examples of products that use REEs are cell phones, computers, fluorescent and light-emitting-diode lights, flat-screen television and computer monitors, and in high-strength magnets used by clean energy technologies such as the generators of wind turbines and batteries of hybrid and electric vehicles. REEs are used in many defense applications, such as in components of jet engines, missile guidance systems, antimissile defense systems, satellites, and communication systems. The rare earth elements have become vital to manufacturing numerous high-tech products, which has been accompanied by a large increase in their demand. At the same time, there has been concern by the United States and many other Nations about the near-monopoly of mining, processing, and supply of REEs from one Nation, China. Between 2011 and 2017, China produced approximately 84 percent of the world’s REEs, and during this time the United States only produced REEs between 2012 and 2015. The U.S. production came entirely from the Mountain Pass mine in California, providing only about 4 percent of the world REE supply. Because REEs are essential for technological applications and are primarily supplied by one Nation, there has been an increased concern in identifying new sources of REEs, including economic REE deposits. In response to these concerns, since 2009, the U.S. Geological Survey (USGS) has conducted numerous studies focused on the distribution, geology, and potential resources for the REE-bearing mineral deposits in the United States. The basic characteristics of mineral deposit types that host REE enrichments in the United Sates are summarized in this report, with selected examples. Several types of REE-enriched mineral deposits are reviewed, including deposits in carbonatites, alkaline igneous rocks, sedimentary phosphate-rich rocks (phosphorite), regions containing REE-rich veins, iron oxide deposits containing REE-bearing apatite, monazite-xenotime-bearing placer deposits (heavy-mineral sands), and ion-adsorption clay deposits (REE in granite-derived regolith). A better understanding of these mineral deposits will assist in identifying domestic resources to help alleviate the dependence on imported REEs. The economic development of REE mineral deposits is affected by many factors beyond mining, such as commodity prices and mineral processing costs. Most of the REEs are hosted by minerals that have complex chemical formulas; this presents more challenges to process and extract the REEs. Continued advancements and refinements in mineral processing techniques may allow REE deposits with complex mineralogy to be economically developed in the future.

Circular↗

Iodine-129 in the eastern Snake River Plain aquifer at and near the Idaho National Laboratory, Idaho, 2021–22

Between the 1950s and 1980s, wastewater generated at the Idaho National Laboratory contained Iodine-129 ( 129 I); this wastewater was discharged directly into the eastern Snake River Plain (ESRP) aquifer through a deep disposal well, unlined infiltration ponds, or leaked from distribution systems below industrial facilities. During 2021–22, the U.S. Geological Survey, in cooperation with the U.S. Department of Energy and the Idaho Department of Environmental Quality Idaho National Laboratory Oversight Program, collected groundwater samples from 64 monitoring wells in the ESRP aquifer, 6 of which are part of a multilevel monitoring system, to determine the concentration of 129 I in the groundwater. These samples were analyzed by accelerator mass spectrometry as part of a long-term ongoing study to track trends and occurrences of this carcinogenic, long-lived radionuclide in the environment. Concentrations ranged from slightly above the locally determined background concentration of 5.4×10 −6 picocuries per liter, to just below the U.S. Environmental Protection Agency’s maximum contaminant level of 1 picocurie per liter. Discharge of wastewater containing 129 I has been discontinued to the aquifer, and long-term trends from a subset (n=15) of sampled wells show decreasing 129 I concentrations over the last three decades. Concentrations of 129 I in groundwater from monitoring wells near facilities at the Idaho National Laboratory are affected by episodic recharge from an ephemeral surface-water source and by the fracture-flow dominated hydrologic regime in the ESRP aquifer. The spatially focused sampling effort has also identified a low-level 129 I plume that affects long-term water quality near and downgradient from the Advanced Test Reactor Complex in the southwestern part of the facility that had not been clearly defined in previous sampling efforts, although the definition of the plume is somewhat limited by available data.

Idaho↗

Mineralogical anomalies and their influences on elemental geochemistry of the main workable coal beds from the Dafang Coalfield, Guizhou, China

Mineralogy and geochemistry of the No. 11 Coal bed were investigated by using inductively-coupled plasma mass spectrometry (ICP-MS), X-ray fluorescence (XRF), scanning electron microscopy equipped with energy-dispersive X-ray (SEM-EDX), sequential chemical extraction procedure (SCEP), and optical microscopy. The results show that the No. 11 Coal bed has very high contents of veined quartz (Vol. 11.4%) and veined ankerite (Vol. 10.2 %). The veined ankerite was generally coated by goethite and the veined quartz embraced chalcopyrite, sphalerite, and selenio-galena. In addition, a trace amount of kaolinite was filled in the veins. These seven minerals often occur in the same veins. The formation temperatures of the veined ankerite and quartz are 85??C and 180??C respectively, indicating their origins of iron-rich calcic and siliceous low-temperature hydrothermal fluids in different epigenetic periods. Studies have also found that the veined quartz probably formed earlier than the veined ankerite, and at least three distinct ankerite formation stages were observed by the ration of Ca/Sr and Fe/Mn of ankerite. The mineral formation from the early to late stage is in order of sulfide, quartz, kaolinite, ankerite, and goethite. The veined ankerite is the dominant source of Mn, Cu, Ni, Pb, and Zn, which are as high as 0.09%, 74.0 ??g/g, 33.6 ??g/g, 185 ??g/g, and 289 ??g/g in this coal seam, respectively. However, the veined quartz is the main carrier of Pd, Pt, and Ir, which are 1.57 ??g/g, 0.15 ??g/g, and 0.007 ??g/g in this coal seam, respectively. In addition, chalcopyrite, sphalerite, and selenio-galena of hydrothermal origin were determined in the veined quartz, and these three sulfide minerals are also important carriers of Cu, Zn and Pb in the No. 11 Coal bed.

Acta Geologica Sinica↗

Kinderhookian (Lower Mississippian) calcareous rocks of the Howard Pass quadrangle, western Brooks Range: A section in Geologic studies in Alaska by the U.S. Geological Survey, 1995

Calcareous rocks of Kinderhookian (early Early Mississippian) age are widely distributed across the Howard Pass quadrangle in the western Brooks Range. Most occur in the lower part of the Lisburne Group (herein called the Rough Mountain Creek unit) and the upper part of the Endicott Group (Kayak Shale) in two sequences (Key Creek and Aniuk River) of the Endicott Mountains allochthon. Kinderhookian strata are also found in the Kelly River allochthon (Utukok Formation?) and in sections of uncertain stratigraphic affinity and structural level spatially associated with mafic volcanic rocks. Predominant Kinderhookian lithologies in the Lisburne Group are skeletal supportstone (rich in pelmatozoans, bryozoans, and brachiopods) and lesser spiculite; skeletal supportstone and calcarenite are the chief calcareous rock types in the Kayak Shale. Conodont and brachiopod faunas indicate that all of the Rough Mountain Creek unit and much of the Kayak Shale in the study area are of late Kinderhookian age. Lithologic and paleontologic data suggest that Kinderhookian strata in the Howard Pass quadrangle were deposited largely in inner- and middle-shelf settings with normal marine salinity and locally high energy. Overall, calcareous beds in the Rough Mountain Creek unit accumulated in a wider range of environments, less subject to siliciclastic input, than did calcareous beds in the Kayak, and Kinderhookian beds of both units in the Key Creek sequence formed in less diverse, somewhat shallower environments than correlative rocks in the Aniuk River sequence. Lithofacies patterns and contact relations imply that decreased siliciclastic influx, perhaps accompanied by relative sea-level rise, initiated deposition of the Rough Mountain Creek unit; relative sea-level rise and concurrent circulatory restriction most likely ended its deposition. Kinderhookian calcareous rocks in the Howard Pass quadrangle have several implications for middle Paleozoic paleogeography of the western Brooks Range. First, sequences of the Endicott Mountains allochthon that contain the Rough Mountain Creek unit contrast sharply with other sequences included in this allochthon that contain thicker and younger Carboniferous platform carbonate successions. These differences in stratigraphic succession suggest significant shortening within the Endicott Mountains allochthon. Second, Kinderhookian calcareous rocks in the Howard Pass quadrangle may have been a secondary source for carbonate turbidites of the Rim Butte unit (Ipnavik allochthon).

Alaska↗

Vibrio population dynamics in Mid-Atlantic surface waters during Saharan dust events

Vibrio is a cosmopolitan genus of marine bacteria, highly investigated in coastal and estuarine environments. Vibrio have also been isolated from pelagic waters, yet very little is known about the ecology of these oligotrophic species. In this study we examined the relative change in bacterial abundance and more specifically the dynamics of Vibrio in the tropical North Atlantic in response to the arrival of pulses of Saharan dust aerosols, a major source of biologically important nutrients for downwind marine surface waters. Aerosol and surface water samples were collected over 1 month coinciding with at least two distinct dust events. Total bacterial counts increased by 1.6-fold correlating with the arrival of Saharan dust ( r = 0.76; p = 0.001). Virus-like particles (VLP) also followed this trend and were correlated with bacterial counts ( r = 0.67; p = 0.01). Vibrio specific qPCR targeting the 16S rRNA gene ranged from below detection limits to a high of 9,145 gene copies ml −1 with the arrival of dust. This increase equated to 6.5 × 10 2 −1.5 × 10 3 individual genome equivalents ml −1 based on the known range of 16S rRNA copies among this genus. Vibrio exhibited bloom-bust cycles potentially attributed to selective viral lysis or bloom depletion of organic carbon. This work is one of the few studies to examine the open ocean ecology of Vibrio , a conditionally rare taxon, whose bloom-bust lifestyle likely is a contributing factor in the flow of nutrients and energy in pelagic ecosystems.

Frontiers in Marine Science↗

Erosional valleys in the Thaumasia region of Mars: Hydrothermal and seismic origins

Analysis of erosional valleys, geologic materials and features, and topography through time in the Thaumasia region of Mars using co-registered digital spatial data sets reveals significant associations that relate to valley origin. Valleys tend to originate (1) on Noachian to Early Hesperian (stages 1 and 2) large volcanoes, (2) within 50–100 km of stages 1 and 2 rift systems, and (3) within 100 km of Noachian (stage 1) impact craters >50 km in diameter. These geologic preferences explain observations of higher valley-source densities (VSDs) in areas of higher elevations and regional slopes (>1°) because the volcanoes, rifts, and craters form high, steep topography or occur in terrain of high relief. Other stage 1 and stage 2 high, steep terrains, however, do not show high VSDs. The tendency for valleys to concentrate near geologic features and the overall low drainage densities in Thaumasia compared to terrestrial surfaces rule out widespread precipitation as a major factor in valley formation (as is proposed in wann, wet climate scenarios) except perhaps during the Early Noachian, for which much of the geologic record has been obliterated. Instead, volcanoes and rifts may indicate the presence of shallow crustal intrusions that could lead to local hydrothermal circulation, melting of ground ice and snow, and groundwater sapping. However, impact-crater melt would provide a heat source at the surface that might drive away water, fonning valleys in the process. Post-stage 1 craters mostly have low nearby VSDs, which, for valleys incised in older rocks, suggests burial by ejecta and, for younger valleys, may indicate desiccation of near-surface water and deepening of the cryosphere. Later Hesperian and Amazonian (stages 3 and 4) valleys originate within 100–200 km of three young, large impact craters and near rifts systems at Warrego Valles and the southern part of Coprates rise. These valleys likely developed when the cryosphere was a couple kilometers or more thick, inhibiting valley development by hydrothermal circulation. However, eruption of groundwater may have occurred from impact-induced fracturing and lateral and perhaps minor upward transport of water due to seismic pumping. The two smaller craters formed along the plateau margin where the highest potential hydraulic head would occur in aquifers beneath the plateau. In the case of the larger crater (Lowell, 200 km in diameter), potential aquifers would likely be at depths of kilometers below the cryosphere. Seismic energy generated by the Lowell impactor would have been much greater, pumping both groundwater and perhaps fluidized slurry to the surface from beneath the cryosphere to form the young valleys and flow deposit. Along the margin of Thaumasia, tectonic pressurization of groundwater also may have contributed to valley formation. Dissection of rim materials of the Argyre impact may relate to tectonic activity and the unconsolidated state of basin ejecta.

Journal of Geophysical Research E: Planets↗

Rupture history of the 2011 M 9 Tohoku Japan earthquake determined from strong‐motion and high‐rate GPS recordings: Subevents radiating energy in different frequency bands

Strong‐motion records from KiK‐net and K‐NET, along with 1 sample/s Global Positioning System (GPS) records from GEONET, were analyzed to determine the location, timing, and slip of subevents of the M 9 2011 Tohoku earthquake. Timing of arrivals on stations along the coast shows that the first subevent was located closer to the coast than subevent (2), which produced the largest slip. A waveform inversion of data from 0 to 0.2 Hz indicates that the first subevent primarily ruptured down‐dip and north of the hypocenter and had an M of 8.5. The areas of this subevent that generated the low (<0.2 Hz) and high (>0.2 Hz) frequency energy are located in the same vicinity. The inversion result for the second subevent ( M 9.0) has large slip on the shallow part of the fault with peak slip of about 65 m above about 25 km depth. This slip generated the tsunami. The preferred inversion has initiation of subevent 2 on the shallow portion of the fault so that rupture proceeded down‐dip and mainly to the south. Subevent 2 started about 35 s after subevent 1, which allows for the possibility of dynamic triggering from subevent 1. The slip model predicts displacements comparable to those found from ocean‐bottom transducers near the epicenter. At frequencies that most affect tall buildings (0.1–0.5 Hz), there is a strong pulse (subevent 3) in the strong‐motion records that arrives after the near‐field ramp from subevent 2. High‐frequency subevent 3 was located down‐dip and south of the high‐slip portion of subevent 2 and was initiated as rupture from subevent 2 proceeded down‐dip. The compact pulse for subevent 3 is modeled with an M 8.0 source in a 75 by 30 km area that ruptured down‐dip and to the south with a high slip velocity, indicating high stress drop.

Bulletin of the Seismological Society of America↗

Laboratory simulation of hydrothermal petroleum formation from sediment in Escanaba Trough, offshore from northern California

Petroleum associated with sulfide-rich sediment is present in Escanaba Trough at the southern end of the Gorda Ridge spreading axis offshore from northern California within the Exclusive Economic Zone (EEZ) of the U.S. This location and occurrence are important for evaluation of the mineral and energy resource potential of the seafloor under U.S. jurisdiction. In Escanaba Trough, petroleum is believed to be formed by hydrothermal processes acting on mainly terrigenous organic material in Quaternary, river-derived sediment. To attempt to simulate these processes in the laboratory, portions of a Pleistocene gray-green mud, obtained from ∼ 1.5 m below the seafloor at a water depth of ∼ 3250 m in Escanaba Trough, were heated in the presence of water in four hydrous-pyrolysis experiments conducted at temperatures ranging from 250 to 350°C and at a pressure of 350 bar for 1.0–4.5 days. Distributions of n -alkanes, isoprenoid hydrocarbons, triterpanes, and steranes in the heated samples were compared with those in a sample of hydrothermal petroleum from the same area. Mud samples heated for less than 4.5 days at less than 350°C show changes in some, but not all, molecular marker ratios of organic compounds that are consistent with those expected during hydrothermal petroleum formation. Our results suggest that the organic matter in this type of sediment serves as one possible source for some of the compounds found in the hydrothermal petroleum.

California↗

Stability of streams and lakes on Mars

Under present climatic conditions streams and lakes on Mars will freeze. Freezing is slow and would have a negligible effect in impeding flow of the large floods that are believed to have eroded the outflow channels. Valley networks are more difficult to form under current climatic conditions since they appear to have formed by slow erosion by streams of modest discharges. Freezing of small Martian streams was modeled for a variety of climatic conditions on the supposition that the Martian atmosphere may have been considerably thicker in the past when the valley networks formed. The modeling involves examination of the energy balance at the upper and lower surfaces of ice on streams to determine the rate at which the ice thickens with time. The results indicate that freezing rates are not strongly dependent on atmospheric pressure. With no wind, increasing the pressure by a factor of 10 cuts the time taken to freeze solid only by about a factor of about 2. Under windy conditions dependence on atmospheric pressure is even weaker. The distance that water could travel in a stream before flow is arrested by freezing is also calculated. The distances depend on the initial temperature of the stream and when icings develop, but in general, if a stream deeper than 2 m can be initiated and sustained, the water within it can survive long enough to cut most of the valley networks observed. The main problem with forming the valley is initiating the flow. Groundwater seepage alone appears inadequate because of the difficulty of recharging the groundwater system. Melting of ice precipitated onto the surface following injection of water into the atmosphere by large impacts is a possible source of water, but the climatic conditions under which the ice could melt and the water be collected into streams that can survive long enough to cut the valley is uncertain.

Icarus↗