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Distribution of ancient carbon in groundwater and soil gas from degradation of petroleum near the Red Hill Bulk Fuel Storage Facility, O‘ahu, Hawai‘i

The groundwater below the Red Hill Bulk Fuel Storage Facility (the facility) in Oʻahu, Hawaiʻi, contains fuel compounds from past spills. This study used carbon-14 analyses to distinguish fuel-derived carbon from background carbon, along with other biodegradation indicators, to address two goals: (1) determine the extent and migration direction of groundwater affected by residual fuel below the facility and (2) determine if residual fuel locations in the subsurface could be identified by analyzing soil gas at the surface above the facility. Groundwater from 19 wells was sampled between September 2022 and April 2023. Nonvolatile dissolved organic carbon (NVDOC) from a well presumed to be unaffected by past spills contained 38 percent ancient carbon indicating a natural source of ancient carbon in the subsurface. The NVDOC concentrations and ancient carbon percentages indicate fuel biodegradation products are likely present on the north and south of Red Hill with the greatest effects at well RHMW02 near the 2014 spill site. The NVDOC concentrations are almost three times higher than diesel range organic (DRO) concentrations in groundwater from the same sites. Major ion data indicate that iron reduction is an important biodegradation process. Soil probe samples and soil carbon traps were used to determine the carbon-14 content of soil carbon dioxide. Ancient carbon from fuel biodegradation was not detected at any soil probe or carbon trap site in contrast to a 2017 study which reported ancient carbon detections. A reanalysis of the 2017 results using a range of local values for background carbon-14 indicates that ancient carbon from fuel biodegradation was probably only detected in lower tunnel exhaust system samples and not in any soil carbon trap samples. Measurements of carbon dioxide efflux with a dynamic closed chamber were highly variable. The soil gas results indicate that soil gas measurements at land surface were not useful for detecting residual fuel at the facility.

Hawaii

Geochemistry and thermometry of magnetite veins and replacements in iron ore deposits from the Iron Springs district, SW Utah, USA: Relation to magmatic and hydrothermal processes

Ore-genesis, texture, chemical compositions, and thermometry of magnetite were used to better evaluate the origins of iron ore deposits across the Iron Spring district, Utah. Trace element compositions, determined by LA-ICP-MS, were used to calculate temperatures based on X Mg numbers and characterize the trace element signatures of magmatic and hydrothermal magnetite. Magnetite occurs as coarser crystalline grains within veins, breccias, and cavities along with finer crystalline replacements. Magnetite is most commonly intergrown with apatite, phlogopite, and carbonate in veins, breccias, and cavities where apatite occurs separately from the other gangue minerals. The results using empirical trace element discrimination diagrams generally suggest that the magnetite is overall of hydrothermal origin regardless of textural variations or field relationships. The X Mg numbers of the magnetite in the magnetite-apatite ores, however, are suggestive of high temperature magmatic conditions; whereas those of vein, breccia, and replacement occurrences containing other gangue minerals are suggestive of lower temperature hydrothermal processes.

Utah

Macroseismology

In this chapter I discuss the use of so-called macroseismic data, i.e., reports of damage and other effects of shaking on humans and the built environment, to improve the characterization of earthquakes and the ground motions they produce. Macroseismic data are critical not only to investigate earthquakes that occurred before the start of the instrumental era in seismology, but are also, by virtue of the spatially rich nature of the data, of tremendous potential importance to investigate early instrumental and even recent earthquakes. Fueled by both the advent of on-line systems that now produce unprecedented volumes of macroseismic intensity data and by recognition of the importance of understanding key historical earthquakes, there has been a growing appreciation for the value of macroseismic data. It is, however, critical to understand both the unique challenges and the unique opportunities associated with these data. I review the evolution of thought and practices regarding analysis of macroseismic data, and the use of such data to improve the characterization of historic and early instrumental earthquakes.

Book chapter

Simulation of groundwater flow in the Long Island, New York regional aquifer system for pumping and recharge conditions from 1900 to 2019

The U.S. Geological Survey has developed a transient, groundwater-flow model that simulates hydrologic conditions in the Long Island aquifer system as part of an ongoing (since 2016) multiyear, cooperative investigation with the New York State Department of Environmental Conservation. The goals of this investigation are to assist stakeholders and resource managers to evaluate the response of the hydrologic system to changes in future hydraulic stresses. Responses in the hydrologic system include changes in water levels in the hydrogeologic units; discharge to streams, coastal waters, and subsurface infrastructure; and the extent of saline groundwater in the aquifers. Hydraulic stresses include future water-supply management and changes in land use and infrastructure. The numerical model synthesizes a diverse set of physiographic, geologic, climatic, land-use, and historical population, water use, and infrastructure data to physically represent the Long Island aquifer system from land surface to bedrock and to simulate annual hydrologic conditions between 1900 and 2019. A three-dimensional hydrogeologic framework was developed from existing and recently collected borehole geologic and geophysical data collected as part of a companion drilling program. Water-transmitting properties of the principal aquifer sediments were defined in three dimensions from new and existing lithologic logs. The distribution of recharge from precipitation was estimated from landscape characteristics and climate data. Anthropogenic recharge from wastewater, leaky infrastructure, and storm runoff were estimated from population, infrastructure, and pumping data. Water-use data, including well locations, depths, and pumping rates, were obtained from historical sources and records and used to estimate pumping stresses continuously in time and space, at an annual average time scale. The data were incorporated into a three-dimensional numerical model using the U.S. Geological Survey finite difference modeling code MODFLOW 6; the model encompassed all of Long Island and surrounding surface waters and simulated historical hydrologic conditions from 1900 to 2019. The calibration process involved trial and error adjustments using prior knowledge to improve general fit to observations followed by an inverse calibration to update and optimize input parameters, using an iterative ensemble smoother algorithm implemented in PEST++ version 5.0. This resulted in a model that generally was in good agreement with observed, dynamically varying hydrologic conditions from 1900 to 2019. The calibrated model was used to develop two base-case models for scenario testing of future, hypothetical conditions where one represented average-annual conditions, and one represented average-seasonal conditions from 2010 to 2019. The model representing average-annual conditions was modified further to represent an alternate sea-level position of 6 feet above the North American Vertical Datum of 1988, and the model representing average-seasonal conditions was modified to represent the average seasonal effects of a 5-year drought imposed upon current hydrologic conditions. Recharge is the sole source of water to the aquifer system; groundwater discharges to coastal water and streams and is withdrawn by pumped wells. Model-estimated annual recharge ranged from about 11 inches in 1965 to 41 inches in 1983. On average, from 2010 to 2019, about 23 percent of water was pumped from wells, and about 47 and 27 percent discharged to coastal waters and streams, respectively; the remaining 4 percent was water that moved into storage in the aquifer matrix. Water levels on Long Island vary naturally during time in response to changes in recharge; the amount of variation is largest in the interior of the island, in areas with highest water table altitudes near groundwater divides and lowest near streams and the coastal waters. The total range of water table altitudes on Long Island between 1900 and 2019 ranged from near 0 to more than 70 feet in western parts of Long Island. The largest range in altitudes is in New York City and is associated with areas of large historical withdrawals between the 1920s and the late 1980s. Water table altitudes generally varied by less than 10 feet in eastern Suffolk County, where the aquifer is under more natural conditions. Saltwater intrusion is of great concern on Long Island, particularly in western Long Island where both the unconfined and confined parts of the aquifer system have been intruded in response to large-scale groundwater withdrawals; however, the volume of freshwater in the islandwide aquifer system only has changed by about 5 percent between 1900 and 2019. The decadal change in the freshwater volume was largest during the early and mid-20th century, corresponding to the largest historical pumping, but that volume change did not exceed 1 percent. The negligible change in freshwater volume suggests that saltwater intrusion as of 2019 was limited at an islandwide scale but continues to occur in local areas of Queens and Nassau Counties, adversely affecting current water supplies and limiting future water supplies for affected communities. The regional groundwater model developed for this investigation is a tool that can be used to help determine the viability of current and future water supplies at a regional scale and can be used to support development of additional models at finer scale to support more focused assessments of groundwater sustainability.

New York

Geologic framework and Holocene sand thickness offshore of Seven Mile Island, New Jersey

The U.S. Geological Survey assessed the Quaternary evolution of Seven Mile Island, New Jersey, to quantify coastal sediment availability, which is crucial for establishing sediment budgets, understanding sediment dispersal, and managing coastlines. This report presents preliminary interpretations of seismic profiles, maps of Holocene sand thickness from the shoreline to 2 kilometers offshore, and tables quantifying the volume of available sediment along the coastal margin based on data collected during 2021 and 2022. The results reveal spatial variability in the thickness and cross-shore extent of Holocene sand. The study area was separated into northern, central, and southern zones by using underlying stratigraphy and geomorphic features. The characteristics and spatial extent of the Holocene sand deposit indicate that hydrodynamic processes contribute to its spatial variability. Northern Seven Mile Island contains the thickest deposits of Holocene sand that were formed by sediment bypass around the Townsends Inlet ebb-tidal delta. Specifically, swash bars have welded to the updrift end of Seven Mile Island and have formed thick deposits of Holocene sand that thicken landward and taper seaward. Despite their thickness, these deposits have the smallest cross-shore extent; therefore, northern Seven Mile Island has the smallest volume of Holocene sand of the three geomorphic zones. Central Seven Mile Island has the thinnest Holocene sand deposits because this section of the barrier island is outside the influence of ebb-tidal deltas. Southern Seven Mile Island has the greatest volumes of Holocene sand because of increased accommodation and deposition adjacent to the Hereford Inlet ebb-tidal delta. Even though tidal inlets exert variable influence on the three geomorphic zones, sediment is distributed fairly uniformly within each geomorphic zone; each of the three zones contains 31.05–36.48 percent of the volume of available Holocene sand.

New Jersey

Fiber-optic distributed temperature sensing of hydrologic processes—Diverse deployments and new applications by the U.S. Geological Survey

Fiber-optic distributed temperature sensing instruments harness the temperature-dependent properties of glass to measure temperature continuously along optical fibers by using precise pulses of laser light. In the mid-2000s, this technology was refined for environmental monitoring purposes such as snowpack-air exchange, groundwater/surface-water exchange, and lake-water stratification. Fiber-optic distributed temperature sensing has revealed unprecedented details about preferential flow processes; however, the method is labor intensive and requires specific training, resulting in limited use by the broader water community. With the ongoing national implementation of the U.S. Geological Survey Next Generation Water Observing System, there has been renewed interest in harnessing the unique spatiotemporal monitoring capabilities of fiber-optic distributed temperature sensing. This fact sheet briefly describes this technology, highlights uses by the U.S. Geological Survey, and discusses current applications and future opportunities.

Fact Sheet

Salinas Valley integrated hydrologic and reservoir operations models, Monterey and San Luis Obispo Counties, California

The area surrounding the Salinas Valley groundwater basin in Monterey and San Luis Obispo Counties of California is a highly productive agricultural area, contributes significantly to the local economy, and provides a substantial portion of vegetables and other agricultural commodities to the Nation. This region of California provides about half of the Nation’s lettuce, celery, broccoli, and spinach each year. Thus, this agricultural area provides significant volumes of agricultural products not just for California but the entire United States. Changes in population and increased agricultural development, which includes a shift toward more water-intensive crops, and climate variability, have put increasing demand on both surface water and groundwater resources in the valley. This has resulted in water management challenges in the Salinas Valley that are predominantly related to distribution of water supply throughout the basin. Where and when the water is present in the surface and subsurface does not coincide with where and when the water is needed. To deal with the distribution issue, historically water has been used conjunctively in the valley. Conjunctive use is a water management strategy that coordinates surface water and groundwater use to maximize water availability. Groundwater is used throughout the Salinas Valley to meet water demands when surface water supplies are insufficient. Availability of surface water is constrained by climate. Precipitation and streamflow vary seasonally and year to year. Although there are two reservoirs in the Salinas Valley to capture and store water during wet periods, the only conveyance of reservoir water to coastal agricultural areas is the Salinas River. Increasing demand on groundwater and surface water resources throughout the Salinas Valley has resulted in undesirable effects of unsustainable water use, such as surface water depletion, groundwater level declines, storage depletion in the principal aquifers, and seawater intrusion. To address these escalating issues, local communities, water management agencies, and groundwater sustainability agencies are evaluating how to sustainably manage both their surface water and groundwater resources. To meet water demands and reduce undesirable effects of unsustainable water use, continued conjunctive management of surface water and groundwater would ideally incorporate strategies to deal with increases in demand and a variable climate. To evaluate the challenging water management issues in the Salinas Valley, the U.S. Geological Survey, Monterey County Water Resource Agency, and the Salinas Valley Basin Groundwater Sustainability Agency developed a comprehensive suite of models that represent the Salinas Valley Hydrogeologic system called the Salinas Valley System Model. The Salinas Valley Geologic Framework was developed to characterize the subsurface using various topographic and geologic data sources, including information on hydrogeologic units, their surfaces and extents, geologic structures, lithology, and elevations from borehole data and cross sections, as well as details on faults and existing models. The Salinas Valley Watershed Model simulates the entire Salinas River watershed. Monthly surface water inflows into the integrated hydrologic model domain were simulated using the Salinas Valley Watershed Model. The historical model uses historical climate data, water and land use data, and reservoir releases to simulate agricultural operations, including landscape water demands, diversions, and reclaimed wastewater. The operational model adds an embedded reservoir operations framework to the simulation of the historical model that allows specified operational rules to simulate reservoir releases and changes in reservoir storage. The operational model assumes current reservoir operations and constant land use, which differs from historical conditions. Thus, the operational model is a hypothetical baseline model that can be used by local water managers to evaluate and quantify potential benefits of water supply projects. Together, the geologic framework, watershed, historical, and operational models form a tool that can be used to simulate irrigated agriculture and associated reservoir operations of the integrated hydrologic system of the Salinas Valley.

EarthArXiv

Ground-water quality atlas of Oakland County, Michigan

The U.S. Geological Survey (USGS), in cooperation with Oakland County Health Division (OCHD), collected 140 water samples from 38 wells in Oakland County during 1998 to better understand ground-water quality. OCHD had observed temporal variations in concentrations of various constituents, so two additional sets of samples were collected to evaluate potential short-term variability related to sample collection procedures and long-term seasonal variability. Replicate samples from 28 wells were analyzed in the Michigan Department of Environmental Quality (MDEQ) Drinking Water Laboratory to compare MDEQ’s analytical results to those obtained from the USGS National Water Quality Laboratory. Several additional databases describing population, land use, water supply, soils, geology, and flows of ground water and surface water are presented in the first part of the report to assist in interpreting the water-quality data. Maps created from these databases are provided in the first portion of the report as an extension of the study-area description. The U.S. Environmental Protection Agency (USEPA) has established Maximum Contaminant Levels (MCL) and Secondary Maximum Contaminant Levels (SMCL) for which samples were analyzed in this study. Water from the 38 wells sampled by the USGS did not exceed the SMCL or MCL for sulfate, fluoride, or nitrite. However, water from 26 wells exceeded the SMCL for iron, water from 12 wells exceeded the SMCL for manganese, and water from 12 wells exceeded the SMCL for dissolved solids. Water from two wells exceeded the MCL for nitrate, although nitrate concentrations in water from most wells was below the detection limit. Water from seven wells exceeded the SMCL for chloride, and water from all wells contained detectable concentrations of chloride. Water from five wells exceeded the MCL for arsenic, and most of the wells sampled contained detectable concentrations of arsenic. These five wells were identified from previous MDEQ analyses to have elevated arsenic concentrations, and were sampled to obtain additional chemistry information. Replicate samples were collected from 26 of the 38 wells for analysis at the MDEQ Drinking-Water Laboratory to compare the results with the USGS National Water Quality Laboratory. The results of the replicate analyses indicate close agreement between the laboratories, with mean differences for nitrate, chloride, and arsenic of 0.10 milligrams per liter (mg/L) as nitrogen, 6.8 mg/L, and 0.0008 mg/L, respectively between the USGS and MDEQ analyses. Potential health effects associated with ingesting nitrate, chloride, and arsenic are provided with the water-quality data, along with references for further information.

Michigan

Grand Canyon landslide-dam and paleolake triggered by the Meteor Crater impact at 56 ka

This paper hypothesizes that the Meteor Crater impact in Arizona, USA, 56,000 years ago triggered landslides in Grand Canyon that dammed the Colorado River and formed Nankoweap paleolake. This is compatible with shock and earthquake physics for the impact that infer a M5.4 seismic event, attenuated to an effective magnitude of M3.5 at Grand Canyon. Results that support the hypothesis include radiocarbon dating of driftwood and luminescence dating of associated slack-water lake sediments that are preserved in caves up to 60 m above the modern Colorado River. Radiocarbon ages from two locations, including Stanton’s Cave, date the driftwood as 55.25 ± 2.44 ka (n = 4). Sediments associated with the driftwood gave a luminescence age of 56.00 ± 6.39 ka (n = 2). These six Grand Canyon dates, and three published ages for the Meteor Crater impact, show statistically indistinguishable results that support the hypothesis for a geologically instantaneous series of events with a mean age of 55.60 ± 1.30 ka. This work highlights the value of radiocarbon dating near the limits of the technique, integration of multiple dating methods, and seismic and landslide hazards associated with meteorite impacts in regions of extreme topography like Grand Canyon.

Arizona

Preface to the focus section on earthquake-induced ground deformation

Ground failure due to earthquake-induced liquefaction, surface fault rupture, and landsliding has caused substantial damage in the past and continues to pose risks to critical infrastructure in the future. The consideration of ground failure is central to engineering analysis and design, ranging from site-specific engineering assessments of ground failure potential to broader regional-scale ground failure assessments of near-real-time earthquake impacts or longer-term portfolio risk. Uncertainties in all aspects of the problem complicate the prediction of earthquake-induced ground failure, including the identification of hazard-susceptible geomaterials, characterizing their spatial extent and physical properties, spatio-temporal variability in groundwater conditions, characterization of earthquake ground motions, assessing ground failure severity, and linking ground failure severity to infrastructure damage and loss.

Seismological Research Letters

A northeast-dipping zone of low frequency earthquakes at the southern edge of Cascadia subduction

Tectonic tremor monitoring occasionally detects events in an anomalous zone in southern Cascadia, 50–100 km west of the main tremor band, near the expected southern edge of the subducting Gorda slab at the Mendocino triple junction. To investigate the geometry and temporal behavior of this tremor, we examine its constituent low-frequency earthquakes (LFEs) by developing 27 stacked LFE waveform templates that we use to detect events from 2018 to 2024. We then relocate LFE sources together with regional seismicity. We find that LFE hypocenters form a northeast-dipping alignment at 22–29 km depth, extending eastward from a zone of micro-earthquakes, ∼15 km south of the southern edge of Gorda slab seismicity. These LFE families exhibit small bursts of activity every few days. Considering the strong world-wide association of tremor and LFEs with high slip-rate, plate-bounding faults, we hypothesize these LFEs may demark the southern edge of Cascadia subduction.

California

Effects of storm-water runoff on local ground-water quality, Clarksville, Tennessee

Storm-related water-quality data were collected at a drainage-well site and at a spring site in Clarksville, Tennessee, to define the effects of storm-water runoff on the quality of ground water in the area. A dye-trace test verified the direct hydraulic connection between the drainage well and Mobley Spring. Samples of storm run off and spring flow were collected at these sites for nine storms during the period February to October 1988. Water samples were collected also from Mobley Spring and two other springs and two observation wells in the area during dry-weather conditions to assess the general quality of ground water in an urban karst terrain. Evaluation of the effect of storm-water runoff on the quality of local ground water is complicated by the presence of other sources of contaminants in the area Concentrations and load for most major constituents were much smaller in storm-water runoff at the drainage well than in the discharge of Mobley Spring, indicating that much of the chemical constituent load discharged from the spring comes from sources other than the drainage well. However, for some of the minor constituents associated with roadway runoff (arsenic, copper, lead, organic carbon, and oil and grease), the drainage well contributed relatively large amounts of these constituents to local ground water during storms. The close correlation between concentrations of total organic carbon and concentrations of most trace metals at the drainage-well and Mobley Spring sites indicates that these constituents are transported together. Many trace metals were flushed early during each runoff event. Mean storm loads for copper, lead, zinc, and four nutrient species (total nitrogen, ammonia nitrogen, total phosphorus, and orthophosphorus) in storm-water runoff at the drainage-well site were lower than mean storm load predicted from an existing regression model. The overprediction by the model may be a result of the small size of the drainage area relative to the range of drainage areas used in the development of the models, or to the below-normal amounts of rainfall during the period of sampling for this investigation. Loads& in storm-water runoff for 22 constituents were extrapolated from sampled storms to total loads for the period February to October 1988. Calculated loads for trace metals for the period ranged from 0.030pound.s for cadmium to 12pound.s for strontium. Loads of the primary nutrients ranged from 0.97pounds for nitrite as nitrogen to 34pounds of organic nitrogen. Storm-water quality at the drainage-well and Mobley Spring sites was compared to background water quality of the local aquifer; as characterized by dry-weather samples from three springs and two observation wells in the Clarksville area. Concentrations of total-recoverable cadmium, chromium, copper, lead, and nickel were higher in many stormwater samples from both the drainage-well and Mobley Spring sites than in samples from any other site. In addition, concentrations of total organic carbon, methylene blue active substances, and total-recoverable oil and grease were generally higher in storm-water samples from the drainage-well site than in any ground-water sample. Densities of fecal coliform and fecal streptococcus bacteria and concentrations of total recoverable iron, manganese, and methylene blue active substances in storm samples from the drainage-well site exceeded the maximum contaminant levels listed in Tennessee’s drinking-water standards (1988) by as much as 2,500 and 5,500 colonies per 100 milliliters, and 2.7, 0.29, and 0.05 milligrams per liter, respectively. Densities of fecal coliform and fecal streptococcus bacteria and concentrations of total-recoverable iron, manganese, and lead in storm samples from Mobley Spring exceeded the maximum contaminant levels by as much as 500 and 4,500 colonies per 100 milliliters, and 18.7,0.65, and 0.02 milligrams per liter, respectively. For iron, manganese, and bacteria, these undesirable levels are not necessarily attributable to storm-water recharge, because concentrations of these constituents also exceeded drinking-water standards in one or more of the dry-weather samples from selected springs and observation wells in the area.

Tennessee

Evaluation of water quality in the Langford Valley–Irwin Groundwater Subbasin, Fort Irwin National Training Center, California, 1993–2019

The U.S. Army Fort Irwin National Training Center (NTC), 120 miles northeast of Los Angeles in the Mojave Desert of California, obtains its potable water supply from the Bicycle Valley and Langford Valley groundwater basins; Langford Valley groundwater basin is further subdivided into the Langford Well Lake and Irwin groundwater subbasins. The Irwin groundwater subbasin contains younger, unconsolidated deposits that have a saturated thickness of as much as 200 feet (ft) and a lower aquifer within older unconsolidated deposits as thick as 650 ft. Groundwater recharge under predevelopment conditions (before 1941) occurred primarily from infiltration of intermittent streamflow in small washes that cross the Irwin groundwater subbasin. Since that time, groundwater recharge has increased because of growth of the NTC in recent years and as a result of other processes, including (1) infiltration of treated wastewater into the aquifer through ponds near the NTC wastewater treatment facility (WWTF) and (2) infiltration of imported water and treated wastewater used for landscape irrigation at base housing and athletic fields. Water samples were collected from 17 wells and analyzed for field parameters, chemical constituents, and isotope composition in the Irwin groundwater subbasin between 2014 and 2019. These data were supplemented with water-chemistry data collected during 1993–95 and at other times if available. Between 1993–95 and 2015–19, median dissolved solids and nitrate concentrations in water from wells in the Irwin groundwater subbasin increased from 620 to 1,030 milligrams per liter (mg/L) and from 2.8 to 4.5 mg/L as nitrogen, respectively. After 2014, dissolved solids and nitrate concentrations in water from wells near the NTC WWTF decreased as a result of changes in source water quality attributable to reverse osmosis of treated drinking water delivered within the Irwin groundwater subbasin and to increased levels of treatment at the NTC WWTF. Based on delta oxygen-18 and delta deuterium isotope data, increases in dissolved solids concentrations in water from most wells were consistent with evaporation prior to recharge and mobilization of soluble salts from the unsaturated zone. Arsenic and fluoride concentrations in water from wells decreased between 1993–95 and 2015–19 as the basin filled with treated wastewater, but 2015–19 concentrations generally exceeded the California State Water Resources Control Board maximum contaminant levels of 10 micrograms per liter for arsenic and 2 mg/L for fluoride. Most groundwater in the Irwin groundwater subbasin has unadjusted carbon-14 ages ranging from 18,400 to 12,350 years before present. However, water from well 10E3, located along the wash near the subbasin outflow in the southeastern part of the Irwin groundwater subbasin, contained measurable tritium, which is consistent with infiltration of intermittent streamflow and groundwater recharge from the wash after 1952. Chemical and isotopic data indicate that treated wastewater is present in water from most wells in the upper aquifer that underlies the Irwin groundwater subbasin. Wells were not sampled to adequately determine the extent of treated wastewater and changes in water quality within the lower aquifer that underlies the Irwin groundwater subbasin.

California

Water-quality conditions and relation to drainage-basin characteristics in the Scituate Reservoir Basin, Rhode Island, 1982-95

The Scituate Reservoir Basin covers about 94 square miles in north central Rhode Island and supplies more than 60 percent of the State of Rhode Island's drinking water. The basin includes the Scituate Reservoir Basin and six smaller tributary reservoirs with a combined capacity of about 40 billion gallons. Most of the basin is forested and undeveloped. However, because of its proximity to the Providence, Rhode Island, metropolitan area, the basin is subject to increasing development pressure and there is concern that this may lead to the degradation of the water supply. Selected water-quality constituent concentrations, loads, and trends in the Scituate Reservoir Basin, Rhode Island, were investigated locate parts of the basin likely responsible for exporting disproportionately large amounts of water-quality constituents to streams, rivers, and tributary reservoirs, and to determine whether water quality in the basin has been changing with time. Water-quality data collected between 1982 and 1995 by the Providence Water Supply Board PWSB) in 34 subbasins of the Scituate Reservoir Basin were analyzed. Subbasin loads and yields of total coliform bacteria, chloride, nitrate, iron, and manganese, estimated from constituent concentrations and estimated mean daily discharge records for the 1995 water year, were used to determine which subbasins contributed disproportionately large amounts of these constituents. Measurements of pH, color, turbidity, and concentrations of total coliform bacteria, sodium, alkalinity, chloride, nitrate, orthophosphate, iron, and manganese made between 1982 and 1995 by the PWSB were evaluated for trends. To determine the potential effects of human-induced changes in drainage- basin characteristics on water quality in the basin, relations between drainage-basin characteristics and concentrations of selected water-quality constituents also were investigated. Median values for pH, turbidity, total coliform bacteria, sodium, alkalinity, chloride, nitrate, and iron were largest in subbasins with predominately residential land use. Median instantaneous loads reflected drainage-basin size. However, loads normalized by drainage area (median instantaneous yields) also were largest in residential areas where point and non-point sources are likely, and in areas of poorly drained soils. Significant trends in water-quality constituents from 1982 to 1995 in the Scituate Reservoir Basin indicate that the quality of the water resources in the basin may be slowly changing. Scituate Reservoir subbasins with large amounts of residential land use showed increasing trends in alkalinity and chloride. In contrast, subbasins distributed throughout the drainage basin showed increasing trends in pH, color, nitrate, and iron concentrations, indicating that these characteristics and constituents may be affected more by atmospheric deposition. Although changing, water-quality constituent concentrations in the Scituate Reservoir Basin only occasionally exceeded Rhode Island and USEPA water-quality guidelines and standards. Result of correlation analysis between pH, color, turbidity, and concentrations total coliform bacteria, sodium, alkalinity, chloride, nitrate, orthophosphate, iron, and manganese and land use, geology, wetlands, slope, soil drainability, and roads indicated that the percentage of wetlands, roads, and slope appear have the greatest effect on water-quality in the Scituate Reservoir Basin. The percentage of urban, residential, and commercial land use also are important, but to a lesser degree than wetlands, roads, and slope. Finally, geology appears to have the least effect on water quality compared to other drainage-basin characteristics investigated.

Rhode Island

Evaluation of best management practices at an edge-of-field site in the Eagle Creek watershed, Ohio, 2012–20

In 2010, the U.S. Geological Survey worked in partnership with the Great Lakes Restoration Initiative and the Natural Resources Conservation Service to identify farm fields in priority watersheds—watersheds critically important to Great Lake health. Intensive best management practices were implemented in five States to test the efficacy of best management practices, also referred to as agricultural conservation practices, to reduce sediment and nutrient runoff on agricultural fields. These fields were chosen as representatives of the priority watersheds because their farming practices and geographical conditions were common among farms in those watersheds. A farm site located near Findlay, Ohio, in the Eagle Creek watershed used two conservation practices, cover crop (Natural Resources Conservation Service practice standard 340) and variable rate technology (VRT; Natural Resources Conservation Service practice standard 590), which represent common practices in the Maumee priority watershed. This study monitored surface runoff and subsurface tile runoff at the Eagle Creek watershed site. The effects of cover crop and VRT nutrient application on sediment and nutrient runoff were assessed from October 2012 to September 2020. Cover crops were applied in fall of 2016, 2017, and 2018, coinciding with VRT applications. The following parameters were analyzed as part of the study: runoff discharge; peak discharge; and concentrations and loads of total phosphorus, particulate phosphorus, dissolved reactive phosphorus, and suspended sediment. High peak runoff events disproportionally affected nutrient concentrations and loads in runoff. A threshold of the 85th percentile of the peak discharge was chosen to assess the effect of cover crop and VRT nutrient application on nutrient mitigation at each gage. Runoff events below the 85th percentile were considered small, and runoff events over the 85th percentile were considered large. Concentrations from collected water-quality samples were used for the analysis; estimated concentrations were excluded from the statistical evaluation. All surface runoff parameters during small runoff events, except surface runoff volume, were significantly lower in the period with cover crops and VRT implementation. Contrarily, subsurface runoff parameters during small events were not statistically different between the periods with and without cover crops and VRT implementation. Surface and subsurface parameters during large events were also not statistically different between the periods with and without cover crops and VRT implementation. These results indicate cover crops and VRT may improve water quality during small runoff events, but additional best management practices that mitigate large runoff events may lead to greater water-quality improvement given the contribution of large events to overall losses.

Ohio