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At least 919 records · Page 51Linked to original sources

Water Budget and the Effects of Land-Use Changes on Ground-Water Recharge, Oahu, Hawaii

Detailed water budgets calculated for southern and southeastern Oahu are used with a geographic information system to develop simplified methods for estimating areal water budgets for predevelopment and mid-1980's land use. The methods were applied to estimate water budgets for the Waianae area of western Oahu, and for north-central, southern, and southeastern Oahu. A water budget was calculated for windward Oahu by developing a separate geographic information system model of the area. The water budgets for these areas were combined into a single water budget for the entire island. The geographic information system model was used to calculate mid-1980's ground-water recharge to small areas of specific interest and the distribution of recharge by geologic formation. The most significant changes in the water budget and ground-water recharge have occurred in north-central and southern Oahu as a result of large-scale agricultural development and urbanization by the mid-1980's. Runoff increased by 23 million gallons per day in southern Oahu where extensive urban areas have been developed. Evapotranspiration increased by 8 million gallons per day in southern Oahu and 28 million gallons per day in north-central Oahu as result of the 146 million gallons per day of agricultural irrigation. Ground-water recharge increased in both areas: by about 56 million gallons per day in southern Oahu and by about 32 million gallons per day in north-central Oahu. Predevelopment ground-water recharge to Oahu was an estimated 792 million gallons per day. Changes in land-use practices in the mid-1980's resulted in an estimated island-wide recharge of 880 million gallons per day.

Professional Paper↗

Hard rock uranium potential in Alaska

Discussing the potential of "hardrock" (i.e., non-sedimentary type) uranium deposits in a 586,000 mi 2 portion of the North America Cordillera is a difficult task compounded by the fact that the remoteness of much of the region and the logistical difficulties have resulted in only reconnaissance geologic information being available for large parts of the state. Cobb (1970) has listed known occurrences of uranium and thorium minerals in the state and a somewhat modified version of his compilation showing chiefly hardrock occurrences is given in figure 1; it should be emphasized that these are occurrences only and not necessarily deposits of possible economic significance. The distribution pattern shows a concentration of occurrences in southeastern Alaska and particularly in the interior. The only production of uranium in Alaska from any type of deposit has been from a hardrock deposit, that being the roughly 120,000 tons of ore averaging about one percent U 3 0 8 from the Ross-Adams mine near Bokan Mountain on Prince of Wales Island close to the southern tip of southeastern Alaska. The Bokan Mountain uranium-thorium area includes about 71 mi 2 and is largely underlain by plutonic rocks (MacKevett, 1963). The plutonic rocks range from pyroxenite to peralkaline granite and syenite, but they consist chiefly of diorite, quartz diorite, granodiorite, and quartz monzonite. The peralkaline granite, a small pluton about 3 mi2 in area, is Late Triassic or Early Jurassic in age while the other plutonic rocks are early Paleozoic.

Alaska↗

Iodine-129 in the Snake River Plain Aquifer at and Near the Idaho National Laboratory, Idaho, 2003 and 2007

From 1953 to 1988, wastewater containing approximately 0.94 curies of iodine-129 (129I) was generated at the Idaho National Laboratory (INL) in southeastern Idaho. Almost all of this wastewater was discharged at or near the Idaho Nuclear Technology and Engineering Center (INTEC) on the INL site. Most of the wastewater was discharged directly into the eastern Snake River Plain aquifer through a deep disposal well until 1984; however, some wastewater also was discharged into unlined infiltration ponds or leaked from distribution systems below the INTEC. In 2003, the U.S. Geological Survey (USGS), in cooperation with the U.S. Department of Energy, collected samples for 129I from 36 wells used to monitor the Snake River Plain aquifer, and from one well used to monitor a perched zone at the INTEC. Concentrations of 129I in the aquifer ranged from 0.0000066 +- 0.0000002 to 0.72 +- 0.051 picocuries per liter (pCi/L). Many wells within a 3-mile radius of the INTEC showed decreases of as much as one order of magnitude in concentration from samples collected during 1990-91, and all of the samples had concentrations less than the Environmental Protection Agency's Maximum Contaminant Level (MCL) of 1 pCi/L. The average concentration of 129I in 19 wells sampled during both collection periods decreased from 0.975 pCi/L in 1990-91 to 0.249 pCi/L in 2003. These decreases are attributed to the discontinuation of disposal of 129I in wastewater after 1988 and to dilution and dispersion in the aquifer. Although water from wells sampled in 2003 near the INTEC showed decreases in concentrations of 129I compared with data collected in 1990-91, some wells south and east of the Central Facilities Area, near the site boundary, and south of the INL showed slight increases. These slight increases may be related to variable discharge rates of wastewater that eventually moved to these well locations as a mass of water from a particular disposal period. In 2007, the USGS collected samples for 129I from 36 wells that are used to monitor the aquifer south of INTEC and from 2 wells that are used to monitor perched zones at INTEC. Concentrations of 129I in the eastern Snake River Plain aquifer ranged from 0.000026 +- 0.000002 to 1.16 +- 0.04 pCi/L, and the concentration at one well exceeded the maximum contaminant level (1 pCi/L) for public drinking water supplies. The average concentration of 19 wells sampled in 2003 and 2007 did not differ; however, slight increases and decreases of concentrations in several areas around the INTEC were evident in the aquifer. The decreases are attributed to the discontinued disposal and to dilution and dispersion in the aquifer. The increases may be due to the movement into the aquifer of remnant perched water below the INTEC. In 2007, the USGS also collected samples from 31 zones in 6 wells equipped with multi-level WestbayTM packer sampling systems to help define the vertical distribution of 129I in the aquifer. Concentrations ranged from 0.000011 +- 0.0000005 to 0.0167 +- 0.0007 pCi/L. For three wells, concentrations of 129I between zones varied one to two orders of magnitude. For two wells, concentrations varied for one zone by more than an order of magnitude from the wells' other zones. Similar concentrations were measured from all five zones sampled in one well. All of the 31 zones had concentrations two or more magnitudes below the maximum contaminant level.

Scientific Investigations Report↗

Hydrogeologic framework of the Johns Creek subbasin and vicinity, Mason County, Washington

This report describes the hydrogeologic framework of the groundwater-flow system in the Johns Creek subbasin and vicinity. The study area covers 97 square miles in southeastern Mason County, Washington, and includes the Johns Creek subbasin, which drains an area of about 11 square miles. The study area extends beyond the Johns Creek subbasin to include major hydrologic features that could be used as regional groundwater-flow model boundaries. The subbasin is underlain by a thick sequence of unconsolidated Quaternary glacial and interglacial deposits, which overlie Tertiary igneous and sedimentary bedrock units. Geologic units were grouped into eight hydrogeologic units consisting of aquifers, confining units, undifferentiated deposits, and an underlying bedrock unit. A surficial hydrogeologic map was developed and used with lithologic information from 200 drillers' logs to construct 4 hydrogeologic sections, and unit extent and thickness maps.

Scientific Investigations Report↗

Geochemical conditions and the occurrence of selected trace elements in groundwater basins used for public drinking-water supply, Desert and Basin and Range hydrogeologic provinces, 2006-11: California GAMA Priority Basin Project

The geochemical conditions, occurrence of selected trace elements, and processes controlling the occurrence of selected trace elements in groundwater were investigated in groundwater basins of the Desert and Basin and Range (DBR) hydrogeologic provinces in southeastern California as part of the Priority Basin Project (PBP) of the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The GAMA PBP is designed to provide an assessment of the quality of untreated (raw) groundwater in the aquifer systems that are used for public drinking-water supply. The GAMA PBP is being conducted by the California State Water Resources Control Board in collaboration with the U.S. Geological Survey and the Lawrence Livermore National Laboratory. The DBR hydrogeologic provinces consist of 141 defined groundwater basins separated by mountain ranges, faults, and other features. This report presents analyses of data collected from nine study areas within the DBR hydrogeologic provinces: Antelope Valley, Borrego Valley, the Central Desert area, Coachella Valley, Colorado River, Indian Wells Valley, Low-Use Basins of the Mojave and Sonoran Deserts, the Mojave, and Owens Valley. Collectively, these nine study areas are referred to as the DBR study unit. The study unit covers approximately 7,000 square miles and includes the 63 groundwater basins in the DBR hydrogeologic provinces in which groundwater is used for public drinking-water supply. The vast majority of the 223 wells sampled for this study were long-screened production wells used primarily for public supply. Uncorrected carbon-14 ( 14 C) groundwater ages for samples collected in the DBR study unit ranged from less than (<) 100 to 33,700 years before present (BP). Sixty-six percent of sample ages were greater than (>) 100 years BP, and 40 percent were >3,800 years BP. Samples collected from wells located adjacent to mountain-front recharge areas or major surface-water features generally had younger groundwater ages than did samples collected from wells located away from mountain fronts or towards the distal ends of basin groundwater flow paths. Most groundwater sampled in the DBR study unit had alkaline pH: 89 percent of sample pH values ranged from 7.1 to 9.8, with 37 percent greater than or equal to (&ge;) 7.9. Groundwater age was significantly correlated (positively) with pH, likely because silicate weathering is a primary control on groundwater pH and is a slow process. The oxidation-reduction (redox) condition of the groundwater sampled in the DBR study unit was predominantly oxic (71 percent), except in the Colorado River study area where organic-rich fluvial aquifers provide the electron donors necessary to support iron-reducing (anoxic-Fe) redox processes. The cation type of 78 percent of the samples was either sodium- or mixed-type, and the anion type of 83 percent of the samples was either bicarbonate- or mixed-type. Sodium-type groundwaters generally were older and more alkaline than calcium-type groundwaters, consistent with the change in water chemistry expected from cation exchange between groundwater and aquifer sediments over long periods of time. Because of the correlation with young groundwater, calcium-type groundwater was predominantly from wells located adjacent to mountain-front recharge areas. Arsenic (As), boron (B), fluoride (F), molybdenum (Mo), strontium (Sr), uranium (U), and vanadium (V) were selected for assessment in this study because they occurred at concentrations greater than California Department of Public Health or U.S. Environmental Protection Agency regulatory or non-regulatory drinking-water-quality benchmarks in more than 2 percent of the 223 samples collected in the DBR study unit. As and F were detected most commonly (18 and 13 percent, respectively) at concentrations above associated water-quality benchmarks and Sr and V least frequently (both at 3 percent). Given that 14 C groundwater ages are predominantly >100 years BP, land use in the study unit is primarily undeveloped, and chemicals derived from anthropogenic sources, such as volatile organic compounds, were infrequently detected, high concentrations of these trace elements in groundwater were most likely the result of natural factors and not anthropogenic factors. As, F, Mo, and V concentrations showed significant positive correlations to groundwater age and to pH. This relation is partly due to the sources of trace elements likely being the weathering of primary minerals, such as silicate minerals, which is a slow process that takes place over hundreds to thousands of years. This relation also reflects the positive correlation between groundwater age and pH. Geochemical modeling predicted that the dominant species of As, Mo, and V in solution were oxyanions (HAsO 4 2&ndash; , MoO 4 2&ndash; , and H 2 VO 4&ndash; ), which are likely to be mobile in alkaline groundwater because mineral surfaces composing aquifer matrices have a predominantly negative surface charge under alkaline conditions. F also exists predominantly as a negatively charged ion (F &ndash; ). At pH values >7.5, saturation indices generated by the geochemical modeling program PHREEQC indicated that F solubility may be somewhat limited by the precipitation of the mineral fluorapatite [Ca 5 (PO 4 ) 3 F]. Speciation modeling of As in anoxic-Fe groundwater (iron-reducing conditions) showed that samples were supersaturated with orpiment (As 2 S 3 ), indicating that mineral precipitation may be responsible for low As concentrations observed in reducing groundwater. In contrast, U concentrations showed significant negative correlations to groundwater age and to pH. Higher U concentrations generally occurred in samples for which geochemical modeling indicated that the uncharged ternary complex Ca 2 UO 2 (CO 3 ) 3 was the dominant aqueous U species. This uncharged complex is not attracted to the charged surfaces of minerals and thus increases U solubility. Formation of Ca 2 UO 2 (CO 3 ) 3 was greater in younger groundwaters because calcium and uranium concentrations generally were lower in older groundwaters, likely due to cation-exchange processes and precipitation of the mineral calcite as groundwater pH increased. Co-precipitation of U with the calcite (CaCO 3 ) may remove U from the aqueous phase. Saturation indices indicated that the anoxic-Fe groundwaters from the Colorado River study area were supersaturated with the mineral uraninite (UO 2 ), suggesting that UO 2 precipitation may be responsible for the low concentrations of U observed in these samples. Concentrations of strontium, which exists primarily in a cationic form (Sr 2+ ), were not significantly correlated with either groundwater age or pH. Strontium concentrations showed a strong positive correlation with total dissolved solids (TDS). Dissolved constituents, such as Sr, that interact with mineral surfaces through outer-sphere complexation become increasingly soluble with increasing TDS concentrations of groundwater. Boron concentrations also showed a significant positive correlation with TDS, indicating the B may interact to a large degree with mineral surfaces through outer-sphere complexation.

California↗

Thorium investigations, 1950-52, Wet Mountains, Colorado

The Wet Mountain thorium district was discovered in 1950 by members of the U.S. Geological Survey during reconnaissance investigations for uranium made on the behalf of the Atomic Energy Commission The size of this new district is incompletely known, but the deposits found to date are in an area 20 miles long and about 10 miles wide, the southwest boundary of which extends northwest from Querida and Rosita Custer County, into Fremont County. Most of the deposits, however, are in the southeastern half of this area The thorium minerals occur in barite-sulfide veins along northwest-trending shear zones that cut a pre-Cambrian complex or amphibolite, biotite-granite gneiss, metagabbro, migmatite, microcline granites, pegmatite and white granite, and syenite (?) o Along the shear zones are premineralization basic (lamprophyre (?)) dikes. Thorite has been tentatively identified as the principal radio- active mineral It is associated with barite: quartz, galena, fluorite, limonite, and pyrite Some of the shear zones perhaps can be traced for as much as 2 miles, but the largest known thorium-bearing ore body is as much as 300 feet long, 26 feet wide, and 400 feet deep. Samples from the veins contain as much as 1.6 percent equivalent Th0 2 Eleven diamond drill holes, totaling 3,292.4 feet have explored five shear zones on the Haputa Ranch. Three ore bodies of possible economic interest are indicated in two interconnecting shear zones. No other deposits in the wet Mountains have been explored, or even sampled adequately to hazard an estimate as to grade and tonnage of reserves.

Colorado↗

The Blake Plateau Basin and Carolina Trough

Presently, the continental margin of the southeastern United States (Fig. 1) forms a zone of transition between the actively building, steep-fronted carbonate platform of the Bahamas and the typical eastern North American terrigenous clastic-dominated, drowned, shelf-slope-rise configuration. This region of the continental margin is underlain by two major sedimentary basins—the Blake Plateau Basin and the Carolina Trough (Fig. 2)—which are different in shape, basement structure, and history. Indeed, the two southern basins show some of the greatest contrasts of any basins of eastern North America, especially in their early response to rifting and in the change from rifting to drifting. The region has experienced abrupt major changes in geological conditions, most notably the onset of Gulf Stream flow in the early Tertiary. Morphologically, the area is dominated by the broad, flat Blake Plateau at about 800-1,000 m water depth (Fig. 1). The plateau is bounded to the east by the extremely steep Blake Escarpment, descending to 5,000 m water depths. To the west, a short continental slope rises to a continental shelf. This Blake Plateau morphology characterizes the margin east of Florida and north of the Bahamas. North of Florida the margin merges into the typical shelf-slope-rise morphology. Just north of the Blake Escarpment and its northern projection, the Blake Spur, the Blake Ridge extends away from the continental slope at water depths exceeding 2,000 m (Fig. 1). This broad ridge is a Cenozoic, sedimentary drift deposit controlled by bottom currents. (For the reader who is beginning to wonder why half of the features of this region seem to be named "Blake", the Blake was a Coast Survey steamer from which investigations off the southeastern U.S. were carried out in 1877 to 1880. Ferromanganese nodules were discovered on the Blake Plateau at that time [Murray, 1885].)

Blake Plateau basin; Carolina Trough↗

Geologic map of the Aristoteles Quadrangle of the Moon

The Aristoteles quadrangle, located on the northeastern periphery of the Imbrium basin on the near side of the Moon, consist of four physiographic provinces : a northern mountainous belt, chiefly of lineated crater rims and other lineated terra; a middle-northern belt covered by mare material of Mare Frigoris ; and a southern belt composed of mountainous material of diverse characteristics. The crater Aristoteles and its ejecta blanket dominate the southwestern part of the quadrangle, and ejecta from the crater Hercules (outside the quadrangle) covers a small part of the southeastern corner. Other promin ent craters are Democritus, C. Mayer, Gartner, and Kane. Two probable centers of tectonism and volcanism are present in the southern mount ainous belt.

IMAP↗

Water-quality, bed-sediment, and discharge data for the Mississippi River-Gulf Outlet and adjacent waterways, southeastern Louisiana, August 2008 through December 2009

The Mississippi River-Gulf Outlet navigation channel (MRGO) was constructed in the early 1960s to provide a safer and shorter route between the Gulf of Mexico and the Port of New Orleans for deep-draft, ocean-going vessels and to promote the economic development of the Port of New Orleans. In 2006, the U.S. Army Corps of Engineers developed a plan to de-authorize the MRGO. The plan called for a rock barrier to be constructed across the MRGO near Bayou La Loutre. In 2008, the U.S. Geological Survey, in cooperation with the Louisiana Coastal Area Science and Technology Program began a study to document the impacts of the rock barrier on water-quality and flow before, during, and after its construction. Water-quality, bed-sediment, and discharge data were collected in the MRGO and adjacent water bodies from August 2008 through December 2009.

Louisiana↗

Geology and ore deposits of the Klondike Ridge area, Colorado

The region described in this report is in the northeastern part of the Colorado Plateau and is transitional between two major structural elements. The western part is typical of the salt anticline region of the Plateau, but the eastern part has features which reflect movements in the nearby San Juan Mountains. There are five major structural elements in the report area: the Gypsum Valley anticline, Dry Creek Basin, the Horse Park fault block, Disappointment Valley, and the Dolores anticline. Three periods of major uplift are recognized In the southeastern end of the Gypsum Valley anticline. Each was followed by collapse of the overlying strata. Erosion after the first two periods removed nearly all topographic relief over the anticline; erosion after the last uplift has not yet had a profound effect on the topography except where evaporite beds are exposed at the surface. The first and greatest period of salt flow and anticlinal uplift began in the late Pennsylvanian and continued intermittently and on an ever decreasing scale into the Early Cretaceous. Most movement was in the Permian and Triassic periods. The second period of uplift and collapse was essentially contemporaneous with widespread tectonic activity on. the northwestern side of the San Juan Mountains and may have Occurred in the Oligocene and Miocene epochs. Granogabbro sills and dikes were intruded during the middle or upper Tertiary in Disappointment Valley and adjoining parts of the Gypsum Valley and Dolores anticlines. The third and mildest period of uplift occurred in the Pleistocene and was essentially contemporaneous with the post-Hinsdale uplift of the San Juan Mountains. This uplift began near the end of the earliest, or Cerro, stage of glaciation. Uranium-vanadium, manganese, and copper ore as well as gravel have been mined in the Klondike district. All deposits are small, and few have yielded more than 100 tons of ore. Most of the latter are carnotite deposits. Carnotite occurs in the lower part of the basal sandstone unit of the Salt Wash member of the Morrison formation. Most deposits are in a narrow, elongate mineral belt' that cuts obliquely across Klondike Ridge. The remaining deposits probably form a second 'mineral belt' lying about ? mile to the north. Manganese and copper deposits show both stratigraphic and structural controls of mineralization. Most manganese deposits are in red beds near Tertiary faults; most copper deposits, on the other hand, are in brown sandstone, limestone, or gray-green shale and, like manganese, are in or near Tertiary faults. The manganese and copper deposits are hydrothermal in origin and were formed in the roots of an ancient hot springs system, now deeply eroded. The ore-bearing solutions probably consisted of dilute, carbonate-sulfate ground water heated by the near-surface intrusion of small bodies of igneous rock. These solutions obtained their metals by leaching the wallrock; little, if any, material was added by the intrusives. The deposits were formed near the surface under conditions of hydrostatic pressure, and temperatures and pressures in the ore-bearing solutions were probably low. The early solutions were weakly alkaline and reducing in character. A convection cell was established as mineralization progressed, and surface water mingled at depth with the solutions. As a result of mixing and oxidation, the pH of the solution decreased in later stages of mineralization and the Eh rose.

Open-File Report↗

Bathymetric, Velocity, Streamflow, and Dissolved Oxygen Data on the Pee Dee River near Bostick Boat Landing, Florence County, South Carolina, May-August 2007

Santee Cooper is planning to construct an electricity generating station in southeastern Florence County near the Kingsburg community. As part of this project, a water-intake structure will be constructed on the Pee Dee River near the Bostick Boat Landing, which is located east of the intersection of State secondary roads S-21-57 and S-21-66. Velocity, bathymetric, and dissolved oxygen data are needed to help determine the location for the water-intake structure. The U.S. Geological Survey (USGS), in cooperation with Santee Cooper, collected these data at three different flow regimes during the period of May through August 2007. Data were collected along 15 transects located at 50-foot intervals starting 400 feet upstream from the boat landing and continuing to 300 feet downstream from the boat landing. All data were geographically referenced using a differentially corrected global positioning system (GPS).

South Carolina↗

Evaluation of the Bushy Park Reservoir three-dimensional hydrodynamic and water-quality model, South Carolina, 2012–15

The Bushy Park Reservoir is a relatively shallow impoundment in southeastern South Carolina. The reservoir, located under a semi-tropical climate, is the principal water supply for the city of Charleston, South Carolina, and the surrounding areas including the Bushy Park Industrial Complex. Although there was an adequate supply of freshwater in the reservoir in 2022, water-quality concerns are present over taste-and-odor and saltwater-intrusion issues. From 2013 to 2015, the U.S. Geological Survey (USGS), in cooperation with the Charleston Water System, engaged in a multi-year study of the hydrology and hydrodynamics of Bushy Park Reservoir to better understand factors affecting water-quality conditions in the reservoir. As part of this study, Charleston Water System worked with Tetra Tech, Inc., a consulting and engineering firm, to develop a Bushy Park Reservoir hydrodynamic and water-quality modeling framework, built upon earlier efforts by both Tetra Tech and the U.S. Army Corps of Engineers. At the completion of the new modeling framework, the USGS was requested to evaluate the calibrated hydrodynamic and water-quality model. The Bushy Park Reservoir Environmental Fluid Dynamics Code (EFDC) model was calibrated for the time period from January 1, 2012, to December 31, 2015. The general modeling approach for the newly revised modeling framework, as briefly detailed in this report, was developed with EFDC. The EFDC is a grid-based modeling package that can simulate three-dimensional flow, transport, and water quality in surface-water systems. This report evaluated the capacity of Tetra Tech’s Bushy Park EFDC model to simulate water discharge, water circulation, surface elevations, temperature, salinity, and other water-quality parameters. The USGS model review focused specifically on the following criteria: (1) determine if the model, with additional effort, could be developed into an adequate planning tool for Bushy Park Reservoir; (2) assess the capacity of the model to specifically address water-quality issues in the reservoir related to taste-and-odor and saltwater intrusions; and, (3) evaluate three preliminary water-management scenarios related to reduced water withdrawals in the reservoir and the effect on saltwater intrusion. Overall, the model was able to simulate discharge, flow velocity, and water-surface elevations with generally good agreement between the simulated and measured values. Specifically, the model was able to demonstrate good agreement for discharge at two USGS continuous discharge locations (USGS station 02172002; USGS station 02172040), with Wilmott index of agreements of 0.86 and 0.75, respectively. A total of seven USGS streamgages, located on the West Branch of the Cooper River, Durham Canal, and the Cooper River, were available for water-surface elevations, with index of agreements ranging from 0.74 to 0.99. However, model-simulated water-surface elevation ranges were appreciably high (compared to measured ranges) for two locations near Pinopolis Dam, farthest upstream on the West Branch of the Cooper River. This result may indicate that too much simulated tidal energy propagated through the model domain. For water temperature, 16 calibration stations were available for at least part of the 4-year simulation. The index of agreement range for temperature comparisons was from 0.95 to 1.00, indicating excellent agreement between the measured and simulated results. One of the primary future applications for the Bushy Park Reservoir EFDC model is to determine the extent of saltwater intrusions. A wide range in the salinity prediction quality was simulated with the model. The prediction quality ranged from an index of agreement of 0.15 at Cooper River approximately 2.75 miles southeast of the Tee, South Carolina, to 0.92 at West Branch Cooper River near Moncks Corner, South Carolina. Although the model did not accurately simulate some of the larger salinity deviations resulting during individual hydrologic events, the seasonal salinity trends were adequately simulated with the model during the study period (2012–15). Therefore, it may be difficult to simulate extreme hydrologic events, such as during large storms, where high salinity water is exchanged with Bushy Park Reservoir. There was agreement in model simulation with the measured data either on the quantitative index of agreement values or qualitative agreement in the seasonal salinity data trends. For water quality, the index of agreement values were generally low for total nitrogen, ammonia, nitrate, total Kjeldahl nitrogen, total phosphorus, and orthophosphate. Although general trends were adequately simulated at specific stations, particularly for Bushy Park Reservoir, the model-simulated fit was low across all the constituents described above with index of agreements usually below 0.50. A limitation for simulating nutrient concentrations across the model domain was the lack of characterization for the constituents directly entering Bushy Park Reservoir, or the lack of data directly attributed to the boundary condition (for example, the Cooper River). The other two calibrated water-quality constituents (besides the nutrients mentioned above) were dissolved oxygen and chlorophyll a . Dissolved oxygen varied from index of agreement values from 0.58 to 0.94 for 11 stations, generally indicating agreement with the available measured data. Chlorophyll a , calibrated for seven stations, had a wider range from 0.11 to 0.74 for the index of agreement. With the current modeling framework, taste-and-odor events, related to cyanobacterial blooms, cannot be directly simulated. However, indirect estimates of cyanobacteria concentrations may be obtained by using the chlorophyll a model outputs, which represent total phytoplankton biomass, and the phytoplankton biovolume data by group (diatoms, green algae, cyanobacteria and others) collected from 2012 to 2015. For the Bushy Park Reservoir modeling framework to be used directly for taste-and-odor issues, cyanobacteria must be simulated and calibrated based on observations of cyanobacteria biomass concentrations. In addition to the cyanobacteria sampling conducted within the reservoir between 2012 and 2015, the new model calibration would also require new algae biomass data-collection efforts to characterize the external sources of cyanobacteria entering the Bushy Park Reservoir from tributaries, as well as the internal cycling, production, and decay of cyanobacteria in the hydrologic system. Further improvements to the EFDC model would include expanding the collection of boundary condition datasets, such as water-quality monitoring to determine improved nutrient loads into the model domain. Along with improved water-quality monitoring for the major boundary conditions, continuous discharge, for both Foster Creek and the Back River, would further constrain the flow balance and the loads into Bushy Park Reservoir. In addition to better boundary-condition characterization, it is important to better characterize possible shortcomings specifically to the model domain, such as the grid resolution, bathymetry, and numerical hydrodynamic errors. Further consideration of the model may involve a sensitivity analysis to determine if errors in the simulation outputs, such as discharge, water-surface elevations, and salinity, were more likely caused by poor boundary condition characterization or, specifically, the model setup. Three model scenarios were run with the revised Bushy Park Reservoir model: (1) reduced withdrawals from one of the large intake-discharge locations for Bushy Park Reservoir, the Williams Station; (2) elevated (above background levels) ocean water level causing saltwater intrusion from the ocean through Durham Canal into Bushy Park Reservoir; and (3) overtopping of the Back River Dam at the southernmost end of Bushy Park Reservoir. For the reduced withdrawals scenarios, the largest shift in flow resulted near the Williams Station intake, with the next largest flow change at the southern end of Bushy Park Reservoir, and a net increase in flow out of the Bushy Park Reservoir to the Cooper River by way of the Durham Canal. The effect resulting from scenario 3 on water quality and salinity was small, with larger increases for dissolved oxygen than other constituents at several monitoring stations. For the two scenarios related to saltwater intrusion (including dam overtopping), the changes in salinity generally were found to dissipate in the following 2 weeks and generally back to baseline salinity conditions within 3 months. This result did vary depending on the severity of the storm or length of the dam overtopping event.

South Carolina↗

Factors Affecting Water Quality in Domestic Wells in the Upper Floridan Aquifer, Southeastern United States, 1998-2005

The Floridan aquifer system is a highly productive carbonate aquifer that provides drinking water to about 10 million people in Florida, Georgia, and South Carolina. Approximately 1.6 million people rely on domestic wells (privately owned household wells) for drinking water. Withdrawals of water from the Floridan aquifer system have increased by more than 500 percent from 630 million gallons per day (2.38 cubic meters per day) in 1950 to 4,020 million gallons per day (15.2 cubic meters per day) in 2000, largely due to increases in population, tourism, and agriculture production. Water samples were collected from 148 domestic wells in the Upper Floridan aquifer in Florida, Georgia, South Carolina, and Alabama during 1998-2005 as part of the U.S. Geological Survey (USGS) National Water-Quality Assessment Program. The wells were located in different hydrogeologic settings based on confinement of the Upper Floridan aquifer. Five networks of wells were sampled con-sisting of 28 to 30 wells each: two networks were in unconfined areas, two networks were in semiconfined areas, and one network was in the confined area. Physical properties and concentrations of major ions, trace elements, nutrients, radon, and organic compounds (volatile organic compounds and pesticides) were measured in water samples. Concentrations were compared to water-quality benchmarks for human health, either U.S. Environmental Protection Agency (USEPA) Maximum Contaminant Levels (MCLs) for public water supplies or USGS Health-Based Screening Levels (HBSLs). The MCL for fluoride of 4 milligrams per liter (mg/L) was exceeded for two samples (about 1 percent of samples). A proposed MCL for radon of 300 picocuries per liter was exceeded in about 40 percent of samples. Nitrate concentrations in the Upper Floridan aquifer ranged from less than the laboratory reporting level of 0.06 to 8 mg/L, with a median nitrate concentration less than 0.06 mg/L (as nitrogen). Nitrate concentrations did not exceed the MCL of 10 mg/L. Statistical comparisons indicated that median nitrate concentrations were significantly different by degree of confinement where the highest median nitrate concentration was 1.46 mg/L for 58 samples from unconfined areas, and by network, where the highest median nitrate concentration was 2.43 mg/L in 28 samples from unconfined areas in southwestern Georgia. Nitrate concentrations in unconfined areas were positively correlated to: (1) the percentage of agricultural land use around the well, (2) the amount of nitrogen fertilizer applied, and (3) the dissolved oxygen concentrations in groundwater. Volatile organic compounds (VOCs) were detected in about 63 percent of all samples. Chloroform, carbon disulfide, and 1,2-dichloropropane were the most frequently detected VOCs. Chloroform, a byproduct of water chlorination, was most frequently detected in unconfined urban areas. Carbon disulfide, a solvent, was most frequently detected in confined areas in southeastern Georgia. Pesticides were detected in about 21 percent of all samples, but were detected in about 69 percent of the 28 samples from unconfined areas in southwestern Georgia. The herbicides atrazine, deethylatrazine, and metolachlor were the most frequently detected pesticides.

Scientific Investigations Report↗

Documentation for initial seismic hazard maps for Haiti

In response to the urgent need for earthquake-hazard information after the tragic disaster caused by the moment magnitude (M) 7.0 January 12, 2010, earthquake, we have constructed initial probabilistic seismic hazard maps for Haiti. These maps are based on the current information we have on fault slip rates and historical and instrumental seismicity. These initial maps will be revised and improved as more data become available. In the short term, more extensive logic trees will be developed to better capture the uncertainty in key parameters. In the longer term, we will incorporate new information on fault parameters and previous large earthquakes obtained from geologic fieldwork. These seismic hazard maps are important for the management of the current crisis and the development of building codes and standards for the rebuilding effort. The boundary between the Caribbean and North American Plates in the Hispaniola region is a complex zone of deformation. The highly oblique ~20 mm/yr convergence between the two plates (DeMets and others, 2000) is partitioned between subduction zones off of the northern and southeastern coasts of Hispaniola and strike-slip faults that transect the northern and southern portions of the island. There are also thrust faults within the island that reflect the compressional component of motion caused by the geometry of the plate boundary. We follow the general methodology developed for the 1996 U.S. national seismic hazard maps and also as implemented in the 2002 and 2008 updates. This procedure consists of adding the seismic hazard calculated from crustal faults, subduction zones, and spatially smoothed seismicity for shallow earthquakes and Wadati-Benioff-zone earthquakes. Each one of these source classes will be described below. The lack of information on faults in Haiti requires many assumptions to be made. These assumptions will need to be revisited and reevaluated as more fieldwork and research are accomplished. We made two sets of maps using different assumptions about site conditions. One set of maps is for a firm-rock site condition (30-m averaged shear-wave velocity, Vs30, of 760 m/s). We also developed hazard maps that contain site amplification based on a grid of Vs30 values estimated from topographic slope. These maps take into account amplification from soils. We stress that these new maps are designed to quantify the hazard for Haiti; they do not consider all the sources of earthquake hazard that affect the Dominican Republic and therefore should not be considered as complete hazard maps for eastern Hispaniola. For example, we have not included hazard from earthquakes in the Mona Passage nor from large earthquakes on the subduction zone interface north of Puerto Rico. Furthermore, they do not capture all the earthquake hazards for eastern Cuba.

Open-File Report↗

Reservoir controls on the occurrence and production of gas hydrates in nature

Gas hydrates in both arctic permafrost regions and deep marine settings can occur at high concentrations in sand-dominated reservoirs, which have been the focus of gas hydrate exploration and production studies in northern Alaska and Canada, and offshore in the Gulf of Mexico, off the southeastern coast of Japan, in the Ulleung Basin off the east coast of the Korean Peninsula, and along the eastern margin of India. Production testing and modeling has shown that concentrated gas hydrate occurrences in sand reservoirs are conducive to existing well-based production technologies. The resource potential of gas hydrate accumulations in sand-dominated reservoirs have been assessed for several polar terrestrial basins. In 1995, the U.S. Geological Survey (USGS) assigned an in-place resource of 16.7 trillion cubic meters of gas for hydrates in sand-dominated reservoirs on the Alaska North Slope. In a more recent assessment, the USGS indicated that there are about 2.42 trillion cubic meters of technically recoverable gas resources within concentrated, sand-dominated, gas hydrate accumulations in northern Alaska. Estimates of the amount of in-place gas in the sand dominated gas hydrate accumulations of the Mackenzie Delta Beaufort Sea region of the Canadian arctic range from 1.0 to 10 trillion cubic meters of gas. Another prospective gas hydrate resources are those of moderate-to-high concentrations within sandstone reservoirs in marine environments. In 2008, the Bureau of Ocean Energy Management estimated that the Gulf of Mexico contains about 190 trillion cubic meters of gas in highly concentrated hydrate accumulations within sand reservoirs. In 2008, the Japan Oil, Gas and Metals National Corporation reported on a resource assessment of gas hydrates in which they estimated that the volume of gas within the hydrates of the eastern Nankai Trough at about 1.1 trillion cubic meters, with about half concentrated in sand reservoirs. Because conventional production technologies favor sand-dominated gas hydrate reservoirs, sand reservoirs are considered to be the most viable economic target for gas hydrate production and will be the prime focus of most future gas hydrate exploration and development projects.

Book↗

Paleoproterozoic metamorphism in the northern Wyoming province: Implications for the assembly of Laurentia

U-Pb ages measured on zircons from the Tobacco Root Mountains and monazite from the Highland Mountains indicate that the northwestern Wyoming province experienced an episode of high-grade metamorphism at ???1.77 Ga. Leucosome emplaced in Archean gneisses from the Tobacco Root Mountains contains a distinctive population of zircons with an age of 1.77 Ga but also contains zircons to ???3.5 Ga; it is interpreted to have been derived primarily by anatexis of nearby Archean schist. A granulite facies mafic dike that cuts across Archean gneissic banding in the Tobacco Root Mountains contains two distinct populations of zircons. A group of small (<50 ??m) nonprismatic grains is interpreted to be metamorphic and yields an age of 1.76 Ga; a group of slightly larger prismatic grains yields an age of 2.06 Ga, which is interpreted to be the time of crystallization of the dike. Monazite from a leucogranite from the Highland Mountains yields a well-defined age of 1.77 Ga, which is interpreted as the time of partial melting and emplacement of the leucogranite. These results suggest that the northwestern Wyoming province, which largely lies within the western part of the Great Falls tectonic zone, experienced a metamorphic maximum at 1.77 Ga. This age is ???100 m.yr. younger than the proposed time of Wyoming-Hearne collision in the central Great Falls tectonic zone (1.86 Ga) and suggests that the northwestern Wyoming province may have been involved in a separate, younger collisional event at ???1.77 Ga. An event at this time is essentially coeval with collisions proposed for the eastern and southeastern margins of the province and suggests a multiepisodic model for the incorporation of the Wyoming craton into Laurentia. ?? 2005 by The University of Chicago. All rights reserved.

Journal of Geology↗

Copper deposits at the Rush and Brown mine and Venus prospect, Prince of Wales Island, southeastern Alaska

The Rush and Brown mine and the Venus prospect are near the head of Kasaan Bay about 10 miles northwest of the village of Kasaan and about 45 miles northwest of Ketchikan, the nearest port. (See fig. 1.) They are in an area of moderate relief in in which some hills are a little more than 500 feet high. Much of the area is covered with glacial drift and dense vegetation. Muskegs are numerous. Outcrops are scarce and are confined mostly to steep slopes, stream beds, and places where development work has been done on the ore deposits. Topographic, geologic, and magnetic surveys of the vicinities of the ore deposits were made by the Geological Survey in 1943, and a brief examination of a portion of the underground workings at the Rush and Brown mine was made in 1944. The area is underlain principally by greenstone which has been intruded by bodies of pyroxenite, gabbro, and diorite. Foliation in the greenstone is obscure. post of the intrusive bodies trend northwesterly. The principal ore deposits are veins containing chiefly pyrite, chalcopyrite, and pyrrhotite. A few deposits of copper-bearing magnetite have been found. Most of these are small, but a larger one at the Rush and Brown mine has been mined for its copper and precious metals.

Alaska↗

Geologic maps and cross sections of mine levels at the Pea Ridge iron mine, Washington County, Missouri

This geologic mapping and interpretation of the Pea Ridge iron mine, Missouri, is part of a cooperative effort between the U.S. Geological Survey (USGS) and the Missouri Department of Natural Resources, Division of Geology and Land Survey (DGLS), under the auspices of the USGS Midcontinent Strategic and Critical Minerals Project. The goal of the Pea Ridge study is to compare the Middle Proterozoic iron deposits of Missouri with the Middle Proterozoic Olympic Dam deposit and similar deposits of the Stuart Shelf, South Australia. This effort developed from work by Sims and others (1987), who recognized the many similarities between the St. Francois terrane in southeastern Missouri and the Stuart Shelf and also the potential for Olympic Dam-type deposits in the Middle Proterozoic granite-rhyolite terranes of the Midcontinent. Detailed descriptions of the map units are given in Nuelle and others (1992). Results of stable-isotope, fluid-inclusion, and traceelement studies that focus on the origin of the ore deposit are presented in Day and others (1991, 1992, and 1993), Sidder and others (1991, 1993a, b), and Cordell and others (1993).

Missouri↗