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At least 919 records · Page 51Linked to original sources

Application of the Stefan-Maxwell Equations to determine limitations of Fick's law when modeling organic vapor transport in sand columns

The organic component of the vapor phase of a porous medium contaminated by an immiscible organic liquid can be significant enough to violate the condition of a dilute species diffusing in a bulk phase assumed by Fick's law. The Stefan-Maxwell equations provide a more comprehensive model for quantifying steady state transport for a vapor phase composed of arbitrary proportions of its constituents. The application of both types of models to the analysis of column experiments demonstrates that use of a Fickian-based transport model can lead to significant overestimates of soil tortuosity constants. Further, the physical displacement of naturally occurring gases (e.g., O 2 ), predicted by the Stefan-Maxwell model but not by application of Fick's Law, can be attributed improperly to a sink term such as microbial degradation in a Fickian-based transport model.

Water Resources Research↗

Climate change and the permafrost carbon feedback

Large quantities of organic carbon are stored in frozen soils (permafrost) within Arctic and sub-Arctic regions. A warming climate can induce environmental changes that accelerate the microbial breakdown of organic carbon and the release of the greenhouse gases carbon dioxide and methane. This feedback can accelerate climate change, but the magnitude and timing of greenhouse gas emission from these regions and their impact on climate change remain uncertain. Here we find that current evidence suggests a gradual and prolonged release of greenhouse gas emissions in a warming climate and present a research strategy with which to target poorly understood aspects of permafrost carbon dynamics.

Nature↗

Intra-urban variations in land surface phenology in a semi-arid environment

Urban vegetation is growing in importance as cities use 'green infrastructure' to mitigate the impacts of climate change, reduce extreme heat, and improve human health and comfort. However, due to the heterogeneity of city landscapes, urban vegetation experiences a diverse range of environmental conditions, potentially leading to differences in growing season timing and length within cities. Here, we investigate physical drivers of urban land surface phenology and timing within a semi-arid city (Denver, CO, USA) using four years (2018–2021) of remotely sensed vegetation indices, modelled air temperature, and land cover datasets. Within the metropolitan region study area, satellite-based vegetation index measurements indicate that growing season length is variable on sub-neighborhood spatial scales. This variability is largely due to differences in the timing of fall senescence, as opposed to early season growth. Areas with substantial fractions of irrigated land cover tend to remain greener for longer, while unirrigated and cooler areas are correlated with an earlier end to the growing season (up to ∼two months shorter). These findings complement those from non-arid cities where surface and air temperature are the dominant environmental control on phenological timing. Results here indicate the importance of soil moisture for phenology in semi-arid regions and suggest unique semi-arid urban growing season dynamics and temperature-vegetation feedbacks. These interactions have implications for water, heat, and vegetation management strategies to maximize ecosystem services in water-limited environments.

Colorado↗

Barrier island reconfiguration leads to rapid erosion and relocation of a rural Alaska community

Coastal erosion is one of the foremost hazards that circumpolar communities face. Climate change and warming temperatures are anticipated to accelerate coastal change, increasing risk to coastal communities. Most erosion hazard studies for Alaska communities only consider linear erosion and do not anticipate coastal morphologic changes. This study showcases the possibility and consequence of accelerated erosion by examining a shift from stability to rapid erosion that forced the rural Alaska Native village of Meshik (now Port Heiden) to abandon the original town site and relocate inland. A combination of remote sensing, coastal surveys, and community-based monitoring are used to map coastal morphologic changes and identify erosion drivers. The community’s shoreline was stable until a protective barrier island eroded away. The exposure to open ocean waves, coupled with unconsolidated, low-density sediments, led to rapid erosion rates averaging of 5.8 ± 0.6 m/y from the 1970s to 2020s. The sudden and rapid erosion put great stress on Meshik and resulted in the loss of homes, erosion of a safe boat harbor, and pollution of the beach and bay. Erosion of the barrier island coincided with a period of greater storm activity and sea ice decline, but the exact cause for its erosion could not be determined. Many polar communities are built on or behind barriers and are on easily erodible soils such as sands and thawing permafrost. This study highlights the need to study, monitor, and predict morphologic change and regime shifts that can bring catastrophic impacts to coastal communities.

Alaska↗

Nitrogen compounds in natural water—A review

Nitrogen compounds in natural water are significant in public health, agriculture, industry, and geochemistry. The many sources of nitrogen compounds and the deep involvement of nitrogen in the life processes of organisms makes the study of such compounds difficult. The sources include natural aerosols, precipitation, fixation by micro‐organisms in soil and water, decaying organic matter, and animal and industrial wastes, as well as probably undiscovered sources in consolidated and unconsolidated rocks. Nitrogen compounds are both oxidized and reduced by organisms. Some nitrogen compounds are adsorbed on clay. The theoretical end product in water and the compound probably most often determined is NO 3 −1 . The concentration of nitregen compounds ranges from 0.0 to >100 ppm (parts per million) in surface water and from 0.0 to >1000 ppm in groundwater. Seasonal fluctuations occur. Much further research is needed, including improvements in methods of analysis, further investigation of sources, and detailed study of the nitrogen cycle in small drainage basins. (Key words: Geochemistry; quality of water.) This paper is not subject to U.S. copyright. Published in 1966 by the American Geophysical Union.

Water Resources Research↗

Predicted liquefaction of East Bay fills during a repeat of the 1906 San Francisco earthquake

Predicted conditional probabilities of surface manifestations of liquefaction during a repeat of the 1906 San Francisco (M7.8) earthquake range from 0.54 to 0.79 in the area underlain by the sandy artificial fills along the eastern shore of San Francisco Bay near Oakland, California. Despite widespread liquefaction in 1906 of sandy fills in San Francisco, most of the East Bay fills were emplaced after 1906 without soil improvement to increase their liquefaction resistance. They have yet to be shaken strongly. Probabilities are based on the liquefaction potential index computed from 82 CPT soundings using median (50th percentile) estimates of PGA based on a ground-motion prediction equation. Shaking estimates consider both distance from the San Andreas Fault and local site conditions. The high probabilities indicate extensive and damaging liquefaction will occur in East Bay fills during the next M ??? 7.8 earthquake on the northern San Andreas Fault. ?? 2006, Earthquake Engineering Research Institute.

Earthquake Spectra↗

Ecological Investigations of the Federally Endangered Shivwits Milk-Vetch (Astragalus ampullarioides)--2006 Annual Report

Astragalus ampullarioides (Welsh) Welsh, the Shivwits milk-vetch, is an herbaceous perennial legume that was listed as federally endangered in September 2001. Known populations of this edaphic endemic species are restricted to Washington County, Utah, with the majority of occurrences found on gently sloping outcrops of the Triassic Petrified Forest Member of the Chinle Formation at the edge of the Mojave Desert. At the time of listing in 2001, surveys estimated a total of 1000 individuals for the species. In April-May 2006, surveys estimated approximately 4205 individuals distributed among six populations. Of the total number of individuals estimated in spring 2006, over 75 percent were distributed among three subpopulations in Zion National Park and approximately 60 percent occurred at a single 0.3-ha site in the Park. In addition to small population sizes and limited geographic distributions, the species is threatened to varying degrees by urbanization, livestock grazing, off-road vehicle use, and invasive exotic plants. In April 2006, the U.S. Geological Survey (USGS) initiated ecological investigations of the Shivwits milk-vetch to support conservation management and recovery of the species by the National Park Service (NPS; Zion National Park), the U.S. Fish and Wildlife Service (USFWS), the Bureau of Land Management (BLM), the Shivwits Band of the Paiute Tribe, and other cooperators such as The Nature Conservancy of Utah (TNC). To date, funding for this research has been provided by the Southwest Biological Science Center of the USGS Biological Resources Discipline, the USGS-NPS Park-Oriented Biological Support Project, and the Earth Surface Dynamics Program of the USGS Geologic Discipline. Additional logistical support has been provided by the Bureau of Land Management, Grand Staircase-Escalante National Monument. General objectives of this research are (1) to develop a better understanding of species-environment relations to support habitat modelling, future surveys for additional recovery populations, and potential efforts to establish new recovery populations; and (2) to evaluate effects of invasive exotic plants on habitat conditions and measures of milk-vetch performance. Specific objectives are to: Describe the distribution and abundance of milk-vetch populations and associated invasive exotic plant species within and outside of Zion National Park (Zion NP) in relation to geologic / geomorphic setting, soil properties, and plant community composition. In a field setting in Zion NP, conduct experiments to evaluate effects of invasive exotic plants on reproductive output and seedling establishment of A. ampullarioides across a gradient of exotic species biomass. Conduct greenhouse studies and analyze soils to evaluate effects of invasive exotic plants on soil biological properties (including mycorrhizal inocculation potential) that affect cycling and plant uptake of essential mineral nutrients. Based on environmental characteristics of known population locations, use Geographic Information System (GIS) tools to prepare a predictive habitat model that can be used to guide future surveys and efforts to evaluate sites for reintroduction efforts. This report describes 2006 progress and future plans for achieving these four objectives.

Open-File Report↗

Assessing simulated ecosystem processes for climate variability research at Glacier National Park, USA

Glacier National Park served as a test site for ecosystem analyses that involved a suite of integrated models embedded within a geographic information system. The goal of the exercise was to provide managers with maps that could illustrate probable shifts in vegetation, net primary production (NPP), and hydrologic responses associated with two selected climatic scenarios. The climatic scenarios were (a) a recent 12-yr record of weather data, and (b) a reconstituted set that sequentially introduced in repeated 3-yr intervals wetter–cooler, drier–warmer, and typical conditions. To extrapolate the implications of changes in ecosystem processes and resulting growth and distribution of vegetation and snowpack, the model incorporated geographic data. With underlying digital elevation maps, soil depth and texture, extrapolated climate, and current information on vegetation types and satellite-derived estimates of leaf area indices, simulations were extended to envision how the park might look after 120 yr. The predictions of change included underlying processes affecting the availability of water and nitrogen. Considerable field data were acquired to compare with model predictions under current climatic conditions. In general, the integrated landscape models of ecosystem processes had good agreement with measured NPP, snowpack, and streamflow, but the exercise revealed the difficulty and necessity of averaging point measurements across landscapes to achieve comparable results with modeled values. Under the extremely variable climate scenario significant changes in vegetation composition and growth as well as hydrologic responses were predicted across the park. In particular, a general rise in both the upper and lower limits of treeline was predicted. These shifts would probably occur along with a variety of disturbances (fire, insect, and disease outbreaks) as predictions of physiological stress (water, nutrients, light) altered competitive relations and hydrologic responses. The use of integrated landscape models applied in this exercise should provide managers with insights into the underlying processes important in maintaining community structure, and at the same time, locate where changes on the landscape are most likely to occur.

Montana↗

H-binding of size- and polarity-fractionated soil and lignite humic acids after removal of metal and ash components

A fractionation technique, combining dialysis removal of metal and ash components with hydrofluoric acid and pH 10 citrate buffer followed by chromatography of dialysis permeate on XAD-8 resin at decreasing pH values, has been applied to lignite humic acid (lignite-HA) and soil humic acid (soil-HA). H-binding data and non ideal competitive adsorption-Donnan model parameters were obtained for the HA fractions by theoretical analysis of H-binding data which reveal a significant increase of the carboxyl and the phenolic charge for the lignite-HA fractions vs. the parental lignite humic acid (L Parental HA). The fractionated lignite-HA material consisted mainly of permeate fractions, some of which were fulvic acid-like. The fractionated soil-HA material consisted mainly of large macromolecular structures that did not permeate the dialysis membrane during deashing. Chargeable groups had comparable concentrations in soil-HA fractions and parental soil humic acid (S Parental HA), indicating minimal interference of ash components with carboxyl and phenolic (and/or enolic) groups. Fractionation of HA, combined with theoretical analysis of H-binding, can distinguish the supramolecular vs. macromolecular nature of fractions within the same parental HA.

Environmental Science and Pollution Research↗

Geochemical evidence of Saharan dust parent material for soils developed on Quaternary limestones of Caribbean and western Atlantic islands

Most previous workers have regarded the insoluble residues of high-purity Quaternary limestones (coral reefs and oolites) as the most important parent material for well-developed, clay-rich soils on Caribbean and western Atlantic islands, but this genetic mechanism requires unreasonable amounts of limestone solution in Quaternary time. Other possible parent materials from external sources are volcanic ash from the Lesser Antilles island arc and Saharan dust carried across the Atlantic Ocean on the northeast trade winds. Soils on Quaternary coral terraces and carbonate eolianites on Barbados, Jamaica, the Florida Keys (United States), and New Providence Island (Bahamas) were studied to determine which, if either, external source was important. Caribbean volcanic ashes and Saharan dust can be clearly distinguished using ratios of relatively immobile elements ( Al2O3 TiO2, Ti Y, Ti Zr, and Ti Th). Comparison of these ratios in 25 soils, where estimated ages range from 125,000 to about 870,000 yr, shows that Saharan dust is the most important parent material for soils on all islands. These results indicate that the northeast trade winds have been an important component of the regional climatology for much of the Quaterary. Saharan dust may also be an important parent material for Caribbean island bauxites of much greater age. ?? 1990.

Quaternary Research↗

Effects of rainfall seasonality and soil moisture capacity on mean annual water balance for Australian catchments

An important factor controlling catchment‐scale water balance is the seasonal variation of climate. The aim of this study is to investigate the effect of the seasonal distributions of water and energy, and their interactions with the soil moisture store, on mean annual water balance in Australia at catchment scales using a stochastic model of soil moisture balance with seasonally varying forcing. The rainfall regime at 262 catchments around Australia was modeled as a Poisson process with the mean storm arrival rate and the mean storm depth varying throughout the year as cosine curves with annual periods. The soil moisture dynamics were represented by use of a single, finite water store having infinite infiltration capacity, and the potential evapotranspiration rate was modeled as an annual cosine curve. The mean annual water budget was calculated numerically using a Monte Carlo simulation. The model predicted that for a given level of climatic aridity the ratio of mean annual evapotranspiration to rainfall was larger where the potential evapotranspiration and rainfall were in phase, that is, in summer‐dominant rainfall catchments, than where they were out of phase. The observed mean annual evapotranspiration ratios have opposite results. As a result, estimates of mean annual evapotranspiration from the model compared poorly with observational data. Because the inclusion of seasonally varying forcing alone was not sufficient to explain variability in the mean annual water balance, other catchment properties may play a role. Further analysis showed that the water balance was highly sensitive to the catchment‐scale soil moisture capacity. Calibrations of this parameter indicated that infiltration‐excess runoff might be an important process, especially for the summer‐dominant rainfall catchments; most similar studies have shown that modeling of infiltration‐excess runoff is not required at the mean annual timescale.

Water Resources Research↗

Not all water becomes wine: Sulfur inputs as an opportune tracer of hydrochemical losses from vineyards

California's widespread and economically important vineyards offer substantial opportunities to understand the interface between hydrology and biogeochemistry in agricultural soils. The common use of native sulfur (S) as a fumigant or soil additive provides a novel way to isotopically differentiate among sulfate (SO 4 2− ) pools, allowing the estimation of water and SO 4 2− budgets. The objectives of this study were (1) to characterize the near‐surface hydrological flow paths in a vineyard during irrigation and storm events and (2) to determine how those flow paths affect the fate and transport of SO 4 2− across seasons. Integrating hydrological theory with measurements of SO 4 2− concentration and sulfate‐S isotopic ratios (expressed as [SO 4 2− ] and δ 34 S, respectively) in inputs, soil water, and leachate provided a means of determining flow paths. Low [SO 4 2− ] and δ 34 S in leachate during 4‐h irrigation events reflect minimal engagement of the soil matrix, indicating that preferential flow was the dominant path for water in the near surface. In contrast, high [SO 4 2− ] and δ 34 S values during 8‐h irrigation and storm events reflect near‐complete engagement of the soil matrix, indicating that lateral flow was the dominant pathway. Because hydrologic response and SO 4 2− mobility are tightly coupled in these soils, the magnitude of water fluxes through the near surface controls S cycling both on and off site. These results indicate that preferential flow is an important loss pathway to consider in managing both water resources and water quality (reactive elements) in vineyard land use systems.

Water Resources Research↗

Enhanced transfer of terrestrially derived carbon to the atmosphere in a flooding event

Rising CO 2 concentration in the atmosphere, global climate change, and the sustainability of the Earth's biosphere are great societal concerns for the 21st century. Global climate change has, in part, resulted in a higher frequency of flooding events, which allow for greater exchange between soil/plant litter and aquatic carbon pools. Here we demonstrate that the summer 2011 flood in the Mississippi River basin, caused by extreme precipitation events, resulted in a “flushing” of terrestrially derived dissolved organic carbon (TDOC) to the northern Gulf of Mexico. Data from the lower Atchafalaya and Mississippi rivers showed that the DOC flux to the northern Gulf of Mexico during this flood was significantly higher than in previous years. We also show that consumption of radiocarbon-modern TDOC by bacteria in floodwaters in the lower Atchafalaya River and along the adjacent shelf contributed to northern Gulf shelf waters changing from a net sink to a net source of CO 2 to the atmosphere in June and August 2011. This work shows that enhanced flooding, which may or may not be caused by climate change, can result in rapid losses of stored carbon in soils to the atmosphere via processes in aquatic ecosystems.

Geophysical Research Letters↗

Climate dictates magnitude of asymmetry in soil depth and hillslope gradient

Hillslope asymmetry is often attributed to differential eco‐hydro‐geomorphic processes resulting from aspect‐related differences in insolation. At midlatitudes, polar facing hillslopes are steeper, wetter, have denser vegetation, and deeper soils than their equatorial facing counterparts. We propose that at regional scales, the magnitude in insolation‐driven hillslope asymmetry is sensitive to variations in climate, and investigate the fire‐prone landscapes in southeastern Australia to evaluate this hypothesis. Patterns of asymmetry in soil depth and landform were quantified using soil depth measurements and topographic analysis across a contemporary rainfall gradient. Results show that polar facing hillslopes are steeper, and have greater soil depth, than equatorial facing slopes. Furthermore, we show that the magnitude of this asymmetry varies systematically with aridity index, with a maximum at the transition between water and energy limitation, suggesting a possible long‐term role of climate in hillslope development.

Geophysical Research Letters↗

Projecting the land cover change and its environmental impacts in the Cedar River Basin in the Midwestern United States

The physical surface of the Earth is in constant change due to climate forcing and human activities. In the Midwestern United States, urban area, farmland, and dedicated energy crop (e.g., switchgrass) cultivation are predicted to expand in the coming decades, which will lead to changes in hydrological processes. This study is designed to (1) project the land use and land cover (LULC) by mid-century using the FORecasting SCEnarios of future land-use (FORE-SCE) model under the A1B greenhouse gas emission scenario (future condition) and (2) assess its potential impacts on the water cycle and water quality against the 2001 baseline condition in the Cedar River Basin using the physically based soil and water assessment tool (SWAT). We compared the baseline LULC (National Land Cover data 2001) and 2050 projection, indicating substantial expansions of urban area and pastureland (including the cultivation of bioenergy crops) and a decrease in rangeland. We then used the above two LULC maps as the input data to drive the SWAT model, keeping other input data (e.g., climate) unchanged to isolate the LULC change impacts. The modeling results indicate that quick-response surface runoff would increase significantly (about 10.5%) due to the projected urban expansion (i.e., increase in impervious areas), and the baseflow would decrease substantially (about 7.3%) because of the reduced infiltration. Although the net effect may cause an increase in water yield, the increased variability may impede its use for public supply. Additionally, the cultivation of bioenergy crops such as switchgrass in the newly added pasture lands may further reduce the soil water content and lead to an increase in nitrogen loading (about 2.5% increase) due to intensified fertilizer application. These study results will be informative to decision makers for sustainable water resource management when facing LULC change and an increasing demand for biofuel production in this area.

Environmental Research Letters↗

James Buttle Review: A synthesis of riparian plant water use over two decades in North American drylands

Assessing riparian ecosystem water use, particularly transpiration from vegetation and evaporation from soils (‘plant water use’, hereafter), is key to developing sound water management approaches. In western North America, a multidecadal drought is reducing water availability and increasing the use of detailed water budgets. Questions related to both removal of vegetation for water salvage and budgeting water to maintain valuable riparian areas have led to a wealth of studies on riparian plant water use across dryland river systems in North America. Towards evaluating broad patterns in riparian plant water use, we synthesise results from over two decades of research, with the goal of informing water management policies and planning. This study asks: (1) Do some riparian plant communities exhibit lower plant water use than others? (2) Do riparian plant communities have higher water use under hotter climates? (3) Can statistical models based on existing data, plant communities and climate data be used to predict water use for unmeasured locations? Using hierarchical Bayesian models to synthesise data on annual and daily-scale plant water use, we show that marshes, cottonwood-willow stands and tamarisk not impacted by biocontrol use larger amounts of water at the annual scale than other vegetation communities. All plant communities have higher annual water use in hotter climates, which is likely related to a longer growing season and higher evaporative demand. Statistical models based on existing water-use data, plant communities and climate provide bounds on plant water use that can be applied to unmeasured locations and used to evaluate the effects of plant community change on water use. This synthesis produces the most complete summary of riparian plant water use in North American drylands to date and provides water use predictions across different climate and community scenarios that can be used for current and future conditions.

Arizona, California, Colorado, Idaho, Nevada, New ↗

Assessing establishment and growth of agricultural plantings on reservoir mudflats

Winter drawdowns in flood control reservoirs create expansive mudflats that lack the vegetation typical of littoral zones, which reduces the amount of structure available for fish habitat. This study investigated the feasibility of establishing agricultural plantings as a management action to ameliorate mudflats by providing structural cover following reservoir refilling. We tested cool-season annual grasses and clovers applied in several mixed and monoculture treatments that were sown on the mudflats of Enid Reservoir, Mississippi, during the winter drawdown in three consecutive years. Soil samples were taken for analysis of pH and macronutrients prior to planting. Plantings were monitored until the following spring to evaluate effectiveness of establishment through ground coverage, height, and stem density sampling. Plots were assigned a seeding treatment of either grasses (ryegrass Lolium spp. or triticale x Triticosecale sp.), clovers (balansa clover Trifolium michelianum or berseem clover Trifolium alexandrinum ), or both (mixed plantings) or left as an unseeded control. Differences among plant treatments were assessed via repeated measures analysis of variance and differences among means evaluated with Tukey's honestly significant difference test. Soil productivity within the study area was poor all 3 years. Grasses germinated both when disked into the soil and when top sown, while clover only germinated when disked. Plots seeded with grasses performed better than control plots with respect to stem density, height, and ground coverage, while plots seeded with grass and clover mixtures performed better than control plots only with respect to height, and plots seeded with only clover did not perform significantly better than control plots. Results serve as an evaluation of the efficacy of agricultural plant establishment on the mudflats of a flood control reservoir, inform the direction of future research, and identify considerations regarding the application of agricultural plantings as a management tool to create fish habitat.

Mississippi↗

Decreased atmospheric nitrogen deposition in eastern North America: Predicted responses of forest ecosystems

Historical increases in emissions and atmospheric deposition of oxidized and reduced nitrogen (N) provided the impetus for extensive, global-scale research investigating the effects of excess N in terrestrial and aquatic ecosystems, with several regions within the Eastern Deciduous Forest of the United States found to be susceptible to negative effects of excess N. The Clean Air Act and associated rules have led to decreases in emissions and deposition of oxidized N, especially in eastern U.S., representing a research challenge and opportunity for ecosystem ecologists and biogeochemists. The purpose of this paper is to predict changes in the structure and function of North American forest ecosystems in a future of decreased N deposition. Hysteresis is a property of a system wherein output is not a strict function of corresponding input, incorporating lag, delay, or history dependence, particularly when the response to decreasing input is different from the response to increasing input. We suggest a conceptual hysteretic model predicting varying lag times in recovery of soil acidification, plant biodiversity, soil microbial communities, forest carbon (C) and N cycling, and surface water chemistry toward pre-N impact conditions. Nearly all of these can potentially respond strongly to reductions in N deposition. Most responses are expected to show some degree of hysteresis, with the greatest delays in response occurring in processes most tightly linked to “slow pools” of N in wood and soil organic matter. Because experimental studies of declines in N loads in forests of North America are lacking and because of the expected hysteresis, it is difficult to generalize from experimental results to patterns expected from declining N deposition. These will likely be long-term phenomena, difficult to distinguish from other, concurrent environmental changes, including elevated atmospheric CO 2 , climate change, reductions in acidity, invasions of new species, and long-term vegetation responses to past disturbance.

Environmental Pollution↗