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At least 919 records · Page 51Linked to original sources

Total petroleum systems of the Bonaparte Gulf Basin area, Australia; Jurassic, Early Cretaceous-Mesozoic; Keyling, Hyland Bay-Permian; Milligans-Carboniferous, Permian

The Bonaparte Gulf Basin Province (USGS #3910) of northern Australia contains three important hydrocarbon source-rock intervals. The oldest source-rock interval and associated reservoir rocks is the Milligans-Carboniferous, Permian petroleum system. This petroleum system is located at the southern end of Joseph Bonaparte Gulf and includes both onshore and offshore areas within a northwest to southeast trending Paleozoic rift that was initiated in the Devonian. The Milligans Formation is a Carboniferous marine shale that sources accumulations of both oil and gas in Carboniferous and Permian deltaic, marine shelf carbonate, and shallow to deep marine sandstones. The second petroleum system in the Paleozoic rift is the Keyling, Hyland Bay-Permian. Source rocks include Lower Permian Keyling Formation delta-plain coals and marginal marine shales combined with Upper Permian Hyland Bay Formation prodelta shales. These source-rock intervals provide gas and condensate for fluvial, deltaic, and shallow marine sandstone reservoirs primarily within several members of the Hyland Bay Formation. The Keyling, Hyland Bay-Permian petroleum system is located in the Joseph Bonaparte Gulf, north of the Milligans-Carboniferous, Permian petroleum system, and may extend northwest under the Vulcan graben sub-basin. The third and youngest petroleum system is the Jurassic, Early Cretaceous-Mesozoic system that is located seaward of Joseph Bonaparte Gulf on the Australian continental shelf, and trends southwest-northeast. Source-rock intervals in the Vulcan graben sub-basin include deltaic mudstones of the Middle Jurassic Plover Formation and organic-rich marine shales of the Upper Jurassic Vulcan Formation and Lower Cretaceous Echuca Shoals Formation. These intervals produce gas, oil, and condensate that accumulates in, shallow- to deep-marine sandstone reservoirs of the Challis and Vulcan Formations of Jurassic to Cretaceous age. Organic-rich, marginal marine claystones and coals of the Plover Formation (Lower to Upper Jurassic), combined with marine claystones of the Flamingo Group and Darwin Formation (Upper Jurassic to Lower Cretaceous) comprise the source rocks for the remaining area of the system. These claystones and coals source oil, gas, and condensate accumulations in reservoirs of continental to marine sandstones of the Plover Formation and Flamingo Group. Shales of the regionally distributed Lower Cretaceous Bathurst Island Group and intraformational shales act as seals for hydrocarbons trapped in anticlines and fault blocks, which are the major traps of the province. Production in the Bonaparte Gulf Basin Province began in 1986 using floating production facilities, and had been limited to three offshore fields located in the Vulcan graben sub-basin. Cumulative production from these fields totaled more than 124 million barrels of oil before the facilities were removed after production fell substantially in 1995. Production began in 1998 from three offshore wells in the Zone of Cooperation through floating production facilities. After forty years of exploration, a new infrastructure of pipelines and facilities are planned to tap already discovered offshore reserves and to support additional development.

Open-File Report↗

Isotopic and petrologic investigation, and a thermomechanical model of genesis of large-volume rhyolites in arc environments: Karymshina Volcanic Complex, Kamchatka, Russia

The Kamchatka Peninsula of eastern Russia is currently one of the most volcanically active areas on Earth where a combination of >8 cm/yr subduction convergence rate and thick continental crust generates large silicic magma chambers, reflected by abundant large calderas and caldera complexes. This study examines the largest center of silicic 4-0.5 Ma Karymshina Volcanic Complex, which includes the 25 × 15 km Karymshina caldera, the largest in Kamchatka. A series of rhyolitic tuff eruptions at 4 Ma were followed by the main eruption at 1.78 Ma and produced an estimated 800 km 3 of rhyolitic ignimbrites followed by high-silica rhyolitic post-caldera extrusions. The postcaldera domes trace the 1.78 Ma right fracture and form a continuous compositional series with ignimbrites. We here present results of a geologic, petrologic, and isotopic study of the Karymshina eruptive complex, and present new Ar-Ar ages, and isotopic values of rocks for the oldest pre- 1.78 Ma caldera ignimbrites and intrusions, which include a diversity of compositions from basalts to rhyolites. Temporal trends in δ 18 O, 87 Sr/ 86 Sr, and 144 Nd/ 143 Nd indicate values comparable to neighboring volcanoes, increase in homogeneity, and temporal increase in mantle-derived Sr and Nd with increasing differentiation over the last 4 million years. Data are consistent with a batholithic scale magma chamber formed by primarily fractional crystallization of mantle derived composition and assimilation of Cretaceous and younger crust, driven by basaltic volcanism and mantle delaminations. All rocks have 35–45% quartz, plagioclase, biotite, and amphibole phenocrysts. Rhyolite-MELTS crystallization models favor shallow (2 kbar) differentiation conditions and varying quantities of assimilated amphibolite partial melt and hydrothermally-altered silicic rock. Thermomechanical modeling with a typical 0.001 km 3 /yr eruption rate of hydrous basalt into a 38 km Kamchatkan arc crust produces two magma bodies, one near the Moho and the other engulfing the entire section of upper crust. Rising basalts are trapped in the lower portion of an upper crustal magma body, which exists in a partially molten to solid state. Differentiation products of basalt periodically mix with the resident magma diluting its crustal isotopic signatures. At the end of the magmatism crust is thickened by 8 km. Thermomechanical modeling show that the most likely way to generate large spikes of rhyolitic magmatism is through delamination of cumulates and mantle lithosphere after many millions of years of crustal thickening. The paper also presents a chemical dataset for Pacific ashes from ODDP 882 and 883 and compares them to Karymshina ignimbrites and two other Pleistocene calderas studied by us in earlier works.

Kamchatka↗

The Puelche volcanic field: Extensive Pleistocene rhyolite lava flows in the Andes of central Chile

A remote volcanic field in the rugged headwaters of the Río Puelche and Río Invernada (35.8°S) constitutes the largest cluster of Quaternary rhyolite lava flows yet identified in the Andean Southern Volcanic Zone. The Puelche Volcanic Field belongs to an intra-arc belt of silicic magmatic centers that extends, at least, 140 km north-south and lies well east of the volcanic front but nonetheless considerably west of the intraplate extensional fields of basaltic and alkaline centers of pampean Argentina. The authors' mapping has distinguished one shallow intrusive mass of early Pleistocene biotite rhyodacite (70.5% SiO 2 ), 11 eruptive units of mid-Pleistocene high-K biotite-rhyolite lava (71.3-75.6% SiO 2 ), and 4 eruptive units of basaltic andesite (53.95-4.9% SiO 2 ), the conduits of which cut some of the rhyolites. Basal contacts of the rhyolite lava flows (and subjacent pyroclastic precursors) are generally scree covered, but glacial erosion has exposed internal flow structures and lithologic zonation superbly. Thicknesses of individual rhyolite lava flows range from 75 m to 400 m. Feeders for several units are well exposed. Cliff-draping unconformities and intracanyon relationships among the 11 rhyolite units show that the eruptive sequence spanned at least one glacial episode that accentuated the local relief. Lack of ice-contact features suggests, however, that all or most eruptions took place during non-glacial intervals probably between 400 ka and 100 ka. Post-eruptive glacial erosion reduced the rhyolites to several non-contiguous remnants that altogether cover 83 km 2 and represent a surviving volume of about 21 km 3 . Consideration of slopes, lava thicknesses, and paleotopography suggest that the original area and volume were each about three times greater. Phenocryst content of the rhyolites ranges from 1 to 12%, with plagioclase>>biotite>FeTi oxides in all units and amphibole conspicuous in the least silicic. The chemically varied basaltic andesites range from phenocryst-poor to phenocryst-rich, exhibiting large differences in proportions of clinopyroxene, olivine, plagioclase, and xenocrystic quartz. Compositional bimodality of the volcanic field is striking, there being no Quaternary eruptive units having SiO 2 contents between 55 and 70%. Major and trace element compositions of the mafic and silicic rocks are nonetheless typical of continental-margin arc suites, not of intracontinental suites. The lack of intermediate eruptive units and the differences between the mafic and rhyolitic lavas in Sr-isotope composition suggest that the rhyolites fractionated from a hybrid parent rather than continuously from basaltic magma. The rhyolites may contain larger contributions of upper-crustal partial melts than do silicic products of the volcanic-front centers 30 km to the west.

Revista Geologica de Chile↗

Mineral resources of Elko County, Nevada

Of the 66 named mining districts in Elko County, 56 have been productive of one or more of 19 different commodities: 11 metals--copper, gold, silver, lead, zinc, mercury, tungsten, manganese, iron, uranium, and antimony; 8 nonmetals--sand and gravel, stone, barite, diatomite, gems, oil shale, volcanic ash, and clay. In addition to the commodities produced, at least 5 others--beryllium, molybdenum, tin, phosphorite, and petroleum, occur in amounts sufficient to warrant exploration. The other districts have been explored, but no production has been recorded. Total value-when-sold of production recorded through 1969 was nearly $91 million; actual production was considerably greater, especially if sand and gravel, barite, and other nonmetallic products before 1953 are included. In value of metals produced, the five highest districts are Mountain City ($26 million), Tuscarora ($11 million), Jarbidge ($10 million), Aura ($6 million), and Railroad (nearly $5 million). The Rio Tinto copper mine in the Mountain City district yielded $21 million. Of the 17 districts that produced nonmetallic minerals, Bootstrap .is the largest producer, containing the Rossi mine, one of the two largest barite mines in the United States. Most of /he metals produced name from veins and replacement deposits in limestone or dolomite near granitic stocks; exceptions are manganese and mercury, which are not associated with known or inferred stocks; mercury is further excepted because it occurs in volcanic rocks, as do a few deposits of the major metals. The largest deposit--the Rio Tinto lode--was a combination of fissure filling and replacement along a bedding plane shear zone 150 ft wide and 1,200 ft long in carbonaceous shale of the Valmy Formation; this deposit is apparently older than the Mountain City stock and its mineralization may be related to Paleozoic mafic volcanism later than a major thrust fault, inferred to underlie the area at a depth of about 5,000 ft. Most of the nonmetallic minerals mined were sedimentary bedded deposits, but mica was mined from pegmatite deposits, and turquoise from both placer and hydrothermal deposits. The largest known reserves of metals (1973) are of porphyry copper in the Dolly Varden district and gold in the Bootstrap district. Reserves of barite also are presumed to be large. The greatest potential for future production of metals, notably copper and gold, appears to be in the known districts or extensions of them and peripheral to deposits that are related to known or concealed plutons and thrust faults. Potential resources in deposits too low in grade to be worked profitably at the present time include all commodities that have been produced and, in addition, known, deposits of beryllium, molybdenum, tin, and phosphorite. Speculative resources in undiscovered deposits may reasonably be predicted to include all known commodities as well as others that are unsuspected. Petroleum may yet be produced from the Elko Formation and geothermal energy from the Ruby Valley and Elko areas.

Open-File Report↗

Aqua de Ney, California, a spring of unique chemical character

The chemistry of water of Aqua de Ney, a cold spring of unusual character located in Siskiyou County, Calif., has been re-examined as part of a study of the relation of water chemistry to rock environment. The water has a pH of 11·6 and a silica content of 4000 parts per million (p.p.m.), the highest values known to occur in natural ground waters. The rocks exposed nearby consist of two volcanic sequences, one predominantly basaltic in composition, the other highly siliceous. Neither these rocks nor the sedimentary and igneous rocks presumed to underlie the area at depth seem to offer explanation of the unusual mineralization which includes 240 p.p.m. of boron, 1000 p.p.m. of sulphide (as H 2 S), and 148 p.p.m. of ammonia nitrogen (as NH 4 ) in a water that is predominantly sodium chloride and sodium carbonate in character. By analogy, it is assumed that water from Aqua de Ney is the product of an initial mixture of connate sea water with a calcium magnesium sulphate water. It is postulated that ion exchange has increased the content of sodium and reduced that of calcium and magnesium, and that sulphate reduction has brought about the high alkalinity, high pH, and high content of sulphide. The large silica value is explained as the result of solution of silica by water having the high pH observed.

California↗

The notion of climate-driven strath-terrace production assessed via dissimilar stream-process response to late Quaternary climate

Previous research results from the Gabilan Mesa are combined with new optically stimulated luminescence (OSL) age estimates and sedimentological analyses with the aim of identifying factors that inhibit climate-driven strath-terrace production, and factors that make possible strath-terrace production independent of climate forcing. The factors are revealed by comparing the morphostratigraphy and OSL age estimates of terraces in the adjacent San Lorenzo Creek and Pancho Rico Creek drainage basins of the central California Coast Ranges. OSL age estimates on San Lorenzo Creek fill-terrace alluvium overlying bedrock at two paleofluvial levels range between 50.5 and 41.3 ka and between 33.4 and 18.2 ka. These OSL age estimates indicate that although the channel of Pancho Rico Creek was degrading at these times, San Lorenzo Creek aggradation was synchronous with previously documented regional, climatically driven aggradation that elsewhere in southern California led to strath production and alluvial deposition. The regional-scale climate forcing events had different effects on San Lorenzo and Pancho Rico Creeks because of the influences of drainage-basin lithology on bedload size and tectonic tilting direction on base-level fall. The Holocene history of channel denudation and strath production of Pancho Rico Creek is also different from that of San Lorenzo Creek, and different from that of many other streams in southern California. After Pancho Rico Creek captured the upper part of the drainage basin of San Lorenzo Creek sometime after 15.5 to 11.7 ka, Pancho Rico Creek has been producing unpaired, erosional strath terraces. The weak, clay rich, fine-grained sedimentary rock underlying Pancho Rico Valley is an ideal substrate in which to form straths. The meandering channel of Pancho Rico Creek produces straths, and weathering resistant, relatively hard bedload introduced by stream capture ensures their preservation as strath terraces.

California↗

Crustal contamination and crystal entrapment during polybaric magma evolution at Mt. Somma-Vesuvius volcano, Italy: Geochemical and Sr isotope evidence

New major and trace element analyses and Sr-isotope determinations of rocks from Mt. Somma-Vesuvius volcano produced from 25 ky BP to 1944 AD are part of an extensive database documenting the geochemical evolution of this classic region. Volcanic rocks include silica undersaturated, potassic and ultrapotassic lavas and tephras characterized by variable mineralogy and different crystal abundance, as well as by wide ranges of trace element contents and a wide span of initial Sr-isotopic compositions. Both the degree of undersaturation in silica and the crystal content increase through time, being higher in rocks produced after the eruption at 472 AD (Pollena eruption). Compositional variations have been generally thought to reflect contributions from diverse types of mantle and crust. Magma mixing is commonly invoked as a fundamental process affecting the magmas, in addition to crystal fractionation. Our assessment of geochemical and Sr-isotopic data indicates that compositional variability also reflects the influence of crustal contamination during magma evolution during upward migration to shallow crustal levels and/or by entrapment of crystal mush generated during previous magma storage in the crust. Using a variant of the assimilation fractional crystallization model (Energy Conservation-Assimilation Fractional Crystallization; [Spera and Bohrson, 2001. Energy-constrained open-system magmatic processes I: General model and energy-constrained assimilation and fractional crystallization (EC-AFC) formulation. J. Petrol. 999-1018]; [Bohrson, W.A. and Spera, F.J., 2001. Energy-constrained open-system magmatic process II: application of energy-constrained assimilation-fractional crystallization (EC-AFC) model to magmatic systems. J. Petrol. 1019-1041]) we estimated the contributions from the crust and suggest that contamination by carbonate rocks that underlie the volcano (2 km down to 9-10 km) is a fundamental process controlling magma compositions at Mt. Somma-Vesuvius in the last 8 ky BP. Contamination in the mid- to upper crust occurred repeatedly, after the magma chamber waxed with influx of new mantle- and crustal-derived magmas and fluids, and waned as a result of magma withdrawal and production of large and energetic plinian and subplinian eruptions. ?? 2005 Elsevier B.V. All rights reserved.

LITHOS↗

General principles of artificial ground-water recharge

The natural subterranean reservoirs formed by the porous and permeable rocks differ from surface reservoirs chiefly in that they have complex structure and great internal resistanc• to the How of water. Their full utilization requires systematic development based on the geology and hydrology of the aquifer and the principles of hydraulics distinctive of ground water. The methods of increasing recharge are of two kinds: (1) Indirect methods, in which increased recharge is accomplished by locating production wells as close as practicable to areas of rejected recharge or natural discharge, and (2) direct methods, in which water from surface sources is conveyed to points from which it percolates into a body of ground water. The direct methods can also be divided into two groups: (1) Recharge by surface application, and (2) recharge through wells. This paper discusses the different methods in relation to geologic structure and ground-water hydraulics and gives numerous examples.

Economic Geology↗

Geology for a changing world 2010-2020-Implementing the U.S. Geological Survey science strategy

This report describes a science strategy for the geologic activities of the U.S. Geological Survey (USGS) for the years 2010-2020. It presents six goals with accompanying strategic actions and products that implement the science directions of USGS Circular 1309, 'Facing Tomorrow's Challenges-U.S. Geological Survey Science in the Decade 2007-2017.' These six goals focus on providing the geologic underpinning needed to wisely use our natural resources, understand and mitigate hazards and environmental change, and understand the relationship between humans and the environment. The goals emphasize the critical role of the USGS in providing long-term research, monitoring, and assessments for the Nation and the world. Further, they describe measures that must be undertaken to ensure geologic expertise and knowledge for the future. The natural science issues facing today's world are complex and cut across many scientific disciplines. The Earth is a system in which atmosphere, oceans, land, and life are all connected. Rocks and soils contain the answers to important questions about the origin of energy and mineral resources, the evolution of life, climate change, natural hazards, ecosystem structures and functions, and the movements of nutrients and toxicants. The science of geology has the power to help us understand the processes that link the physical and biological world so that we can model and forecast changes in the system. Ensuring the success of this strategy will require integration of geological knowledge with the other natural sciences and extensive collaboration across USGS science centers and with partners in Federal, State, and local agencies, academia, industry, nongovernmental organizations and, most importantly, the American public. The first four goals of this report describe the scientific issues facing society in the next 10 years and the actions and products needed to respond to these issues. The final two goals focus on the expertise and infrastructure needed to ensure the long-term sustainability of the geological sciences in the USGS. The ultimate goal of USGS science and of the strategy laid out in this document is to contribute to the development of a sustainable society that operates in harmony with the Earth systems that society depends upon. As we begin the second decade of the 21st century, our Nation faces growing challenges in resource availability, climate and environmental change, and natural hazards. Meeting these challenges will require strong collaboration across the natural and social sciences and extensive partnerships with both the public and private sectors. The six goals described in this document represent a mix of scientific focus areas and operational necessities that together provide a comprehensive roadmap for USGS geologic science to effectively contribute to the USGS mission, providing science for a changing world.

Circular↗

Numerical investigation of steady liquid water flow in a variably saturated fracture network

Numerical simulation was used to study steady liquid water movement in a 5-m by 5-m vertical section containing a hypothetical fracture network under conditions of variable saturation. The fracture network was assumed to be embedded within an impermeable rock matrix. Three variations of a network were considered. The “mixed” network consisted of two fracture sets, a subvertical set containing five 125 μm average aperture fractures and a subhorizontal set containing four 25 μm average aperture fractures. The other two networks had identical fracture orientation and contained either all 125 μm or all 25 μm average aperture fractures. The TOUGH simulator was used to calculate the total steady liquid water flux through the network, the flux through individual fracture segments, and the pressure head at each fracture segment. A unit hydraulic gradient was imposed on the network by applying fixed pressure head boundaries (ranging from −0.25 to 0.0 m of water) of equal value to the top and bottom. Saturation and permeability versus pressure head relations for the two sets of fractures were determined with the VSFRAC model, which assumed that aperture was variable within an individual fracture. Results showed that the spatial distributions of pressure head and flux within the network, as well as the location of the dominant pathways, depended strongly on the prescribed boundary pressure head. For the mixed network, both pressure head and flux tended to become more spatially uniform when the boundary pressure head approached the pressure head at which the permeability thickness products of the large- and small-aperture fractures are equal (the crossover pressure head). These results imply that for systems similar to the one considered here, interpretation of actual measurements of pressure head and flux may be quite complex, and that representation of variably saturated fracture networks as an equivalent continuum may be more valid for some ranges in pressure head than for others. Equivalent permeability as a function of pressure head was calculated for the fracture network, illustrating how information collected on individual fractures may be used to estimate the flow properties of rock at larger scales.

Water Resources Research↗

Detailed north-south cross section showing environments of deposition, organic richness, and thermal maturities of lower Tertiary rocks in the Uinta Basin, Utah

The Uinta Basin of northeast Utah has produced large amounts of hydrocarbons from lower Tertiary strata since the 1960s. Recent advances in drilling technologies, in particular the development of efficient methods to drill and hydraulically fracture horizontal wells, has spurred renewed interest in producing hydrocarbons from unconventional low-permeability dolomite and shale reservoirs in the lacustrine, Eocene Green River Formation. The Eocene Green River Formation was deposited in Lake Uinta, a long-lived saline lake that occupied the Uinta Basin, the Piceance Basin to the east, and the intervening Douglas Creek arch. The focus of recent drilling activity has been the informal Uteland Butte member of the Green River Formation and to a much lesser extent the overlying R-0 oil shale zone of the Green River Formation. Initial production rates ranging from 500 to 1,500 barrels of oil equivalent per day have been reported from the Uteland Butte member from horizontal well logs that are as long as 4,000 feet (ft);. The cross section presented here extends northward from outcrop on the southern margin of the basin into the basin’s deep trough, located just south of the Uinta Mountains, and transects the area where this unconventional oil play is developing. The Monument Butte field, which is one of the fields located along this line of section, has produced hydrocarbons from conventional sandstone reservoirs in the lower part of the Green River Formation and underlying Wasatch Formation since 1981. A major fluvial-deltaic system entered Lake Uinta from the south, and this new line of section is ideal for studying the effect of the sediments delivered by this drainage on hydrocarbon reservoirs in the Green River Formation. The cross section also transects the Greater Altamont-Bluebell field in the deepest part of the basin, where hydrocarbons have been produced from fractured, highly overpressured marginal lacustrine and fluvial reservoirs in the Green River, Wasatch, and North Horn Formations since 1970. Datum for the cross section is sea level so that hydrocarbon source rocks and reservoir rocks could be integrated into the structural framework of the basin.

Utah↗

Modeling the maturation history of the stacked petroleum systems of the Williston Basin, USA

A three-dimensional petroleum systems model was built to support U.S. Geological Survey assessments of undiscovered oil and gas resources in the Williston Basin of North Dakota, Montana, and South Dakota. Numerous Paleozoic source rocks have been proven or postulated in the basin, of which five were the focus of maturation and migration modeling: the Ordovician Icebox Formation, the kukersite beds of the Ordovician Red River Formation, the shales of the Devonian–Mississippian Bakken Formation, the Mississippian Madison Group, and the Pennsylvanian Tyler Formation. Calibration of the three-dimensional model to present-day temperature data indicates the existence of a north-south trend of high heat flow in western North Dakota, along with a region of high heat flow in eastern Montana. These high heat flow trends strongly control the maturity of all studied source intervals. A Bakken-specific hydrocarbon generation kinetic model was developed to match the calibrated time-temperature history of the basin to spatial trends in hydrogen index from programmed pyrolysis data. Generation of hydrocarbons occurred in the Cretaceous through Paleogene due to increased burial. Subsequent uplift and erosion in the Neogene cooled the basin, ending hydrocarbon generation for all source rocks. The cumulative volume of hydrocarbons generated by each of the source rocks was calculated and used to compare their relative robustness. The shales of the Bakken Formation are estimated to have generated approximately 460 billion barrels of oil equivalent (BBOE), while the Red River Formation generated approximately 130 BBOE, the Tyler Formation 94 BBOE, the Madison Group 44 BBOE, and the Icebox Formation 28 BBOE. Gross migration trends were analyzed with respect to historical oil and gas production in the basin and generally indicate segregation of petroleum systems throughout the stratigraphic column. However, most modeled scenarios indicated significant loss of Bakken oil to the Madison Group, suggesting that mixing of Madison and Bakken oils may be more prevalent than has recently been recognized in the U.S. portion of the Williston Basin and is particularly likely in fractured regions of the basin.

Montana, North Dakota↗

The Conterminous United States Mineral Assessment Program; background information to accompany folio of geologic, geophysical, geochemical, mineral-occurrence, mineral-resource potential, and mineral-production maps of the Charlotte 1 degree x 2 degrees Quadrangle, North Carolina and South Carolina

This Circular and the folio of separately published maps described herein are part of a series of reports compiled under the Conterminous United States Mineral Assessment Program ICUSMAP). The folio on the Charlotte 1 degree ? 2 degree quadrangle, North Carolina and South Carolina, includes (1) a geologic map; (2) four geophysical maps; (3) geochemical maps for metamorphic heavy minerals, copper, lead and artifacts, zinc, gold, tin, beryllium, niobium, tungsten, molybdenum, titanium, cobalt, lithium, barium, antimony-arsenic-bismuth-cadmium, thorium-cerium-monazite, and limonite; (4) mineral-occurrence maps for kyanite-sillimanite-lithium-mica-feldspar-copper-lead-zinc, gold-quartz-barite-fluorite, iron-thorium-tin-niobium, and construction materials-gemstones; (5) mineral-resource potential maps for copper-lead-zinc-combined base metals, gold, tin-tungsten, beryllium-molybdenum-niobium, lithium-kyanite- sillimanitebarite, thorium (monazite)-uranium, and construction materials; and (6) mineral-production maps. The Charlotte quadrangle is mainly within the Piedmont physiographic province and extends from near the Coastal Plain on the southeast into the Blue Ridge province on the northwest for a short distance. Parts of six lithotectonic belts are present--the Blue Ridge, the Inner Piedmont, the Kings Mountain belt, the Charlotte belt, the Carolina slate belt, and the Wadesboro basin. Igneous, metamorphic, and sedimentary rocks are present and range in age from Proterozoic to Mesozoic; alluvial sediments of Quaternary age occur along rivers and larger streams. Rocks of the Blue Ridge include Middle Proterozoic granitoid gneiss intruded by Late Proterozoic granite; Late Proterozoic paragneiss, schist, and other metasedimentary and metavolcaniclastic rocks (Ashe and Grandfather Mountain Formations); Late Proterozoic and Early Cambrian metasedimentary rocks (Chilhowee Group); and Early Cambrian sedimentary rocks (Shady Dolomite). Paleozoic granites intrude the Proterozoic rocks. The Inner Piedmont contains noncarbonate metasedimentary rocks and amphibolite of medium to high metamorphic grades. These rocks are intruded by the Toluca Granite and Henderson Gneiss of Cambrian and Ordovician(?) age. The Charlotte belt consists largely of Late Proterozoic to Late Paleozoic granitic and gabbroic plutonic rocks and intervening enclaves of metasedimentary and metavolcanic rocks. The narrow Kings Mountain belt is located between the Charlotte and the Inner Piedmont belts and contains mainly Late Proterozoic metasedimentary rocks and plutonic rocks similar to those of the Charlotte belt. The Carolina slate belt, flanking the Charlotte belt on the east, contains weakly metamorphosed volcanic and sedimentary rocks. East of this belt, at the southeast corner of the quadrangle, is the Wadesboro basin, which has continental sedimentary rocks of Triassic age. Layered rocks westward from and in the Charlotte belt are complexly folded, are steeply dipping, and in the Blue Ridge and Inner Piedmont are contained within major thrust slices. Rocks of the Carolina slate belt are gently folded. Rocks of the Wadesboro basin occur in downfaulted blocks. The geophysical surveys of the Charlotte quadrangle consisted of Bouguer gravity, aeromagnetic, and aeroradioactivity surveys and used both newly obtained data and information from prior work. The gravity survey disclosed a distinct northeast-trending, northwest-decreasing gradient, which is part of the major gravity gradient that extends the length of the Appalachian Mountains. Granitic plutons of the Charlotte belt, in particular, are marked by gravity lows, and gabbro plutons, by highs. Several of the geologic belts display distinct magnetic character. The aeroradioactivity surveys showed a swath of consistently high gamma-ray intensities along the central part of the Inner Piedmont belt; these high intensities correspond to the so-called monazite belt. Oval patterns of high gamma-ray readi

Circular↗

Critical minerals in orogenic (gold) and Coeur d’Alene-type mineral systems of the United States

Orogenic and Coeur d’Alene-type mineral systems are produced by metamorphic devolatilization of thick volcanic or siliciclastic sedimentary rock sequences and the focused flow of hydrothermal fluids upwards along crustal-scale faults. Most orogenic systems are found along the Cordilleran orogen, stretching from California northwards into Alaska, whereas most Coeur d’Alene-type systems occur in the Proterozoic Belt Basin in Idaho and Montana. Although the deposit types in these systems are exploited for precious and base metals, potential exists for the production of critical minerals necessary for current (2025) societal needs in the United States. Publicly available geochemical data compiled for these mineral systems, coupled with mineralogical characteristics, indicate that several critical minerals could potentially be recovered from unmined resources and processed mine waste: arsenic, antimony, tellurium, cobalt, and tungsten from orogenic gold deposits and zinc, antimony, arsenic, and manganese from Coeur d’Alene-type systems. These critical minerals reside primarily in arsenopyrite (arsenic), scheelite (tungsten), siderite (manganese), sphalerite (zinc), tetrahedrite (antimony and arsenic), stibnite (antimony), and telluride (tellurium) minerals.

continental United States↗

Hydrocarbon Source Rocks in the Deep River and Dan River Triassic Basins, North Carolina

This report presents an interpretation of the hydrocarbon source rock potential of the Triassic sedimentary rocks of the Deep River and Dan River basins, North Carolina, based on previously unpublished organic geochemistry data. The organic geochemical data, 87 samples from 28 drill holes, are from the Sanford sub-basin (Cumnock Formation) of the Deep River basin, and from the Dan River basin (Cow Branch Formation). The available organic geochemical data are biased, however, because many of the samples collected for analyses by industry were from drill holes that contained intrusive diabase dikes, sills, and sheets of early Mesozoic age. These intrusive rocks heated and metamorphosed the surrounding sediments and organic matter in the black shale and coal bed source rocks and, thus, masked the source rock potential that they would have had in an unaltered state. In places, heat from the intrusives generated over-mature vitrinite reflectance (%Ro) profiles and metamorphosed the coals to semi-anthracite, anthracite, and coke. The maximum burial depth of these coal beds is unknown, and depth of burial may also have contributed to elevated thermal maturation profiles. The organic geochemistry data show that potential source rocks exist in the Sanford sub-basin and Dan River basin and that the sediments are gas prone rather than oil prone, although both types of hydrocarbons were generated. Total organic carbon (TOC) data for 56 of the samples are greater than the conservative 1.4% TOC threshold necessary for hydrocarbon expulsion. Both the Cow Branch Formation (Dan River basin) and the Cumnock Formation (Deep River basin, Sanford sub-basin) contain potential source rocks for oil, but they are more likely to have yielded natural gas. The organic material in these formations was derived primarily from terrestrial Type III woody (coaly) material and secondarily from lacustrine Type I (algal) material. Both the thermal alteration index (TAI) and vitrinite reflectance data (%Ro) indicate levels of thermal maturity suitable for generation of hydrocarbons. The genetic potential of the source rocks in these Triassic basins is moderate to high and many source rock sections have at least some potential for hydrocarbon generation. Some data for the Cumnock Formation indicate a considerably higher source rock potential than the basin average, with S1 + S2 data in the mid-20 mg HC/g sample range, and some hydrocarbons have been generated. This implies that the genetic potential for all of these strata may have been higher prior to the igneous activity. However, the intergranular porosity and permeability of the Triassic strata are low, which makes fractured reservoirs more attractive as drilling targets. In some places, gravity and magnetic surveys that are used to locate buried intrusive rock may identify local thermal sources that have facilitated gas generation. Alternatively, awareness of the distribution of large intrusive igneous bodies at depth may direct exploration into other areas, where thermal maturation is less than the limits of hydrocarbon destruction. Areas prospective for natural gas also contain large surficial clay resources and any gas discovered could be used as fuel for local industries that produce clay products (principally brick), as well as fuel for other local industries.

North Carolina↗

Arctic Alaska’s Lower Cretaceous (Hauterivian and Barremian) mudstone succession—Linking lithofacies, texture, and geochemistry to marine processes

We present new images and descriptions of the lithofacies and organic facies of the pebble shale unit and lower part of the Hue Shale (Lower Cretaceous) of Arctic Alaska at a high magnification that illustrates their textural characteristics. Our aims were to describe and determine the distribution of facies in these petroleum source rocks and to identify the processes that formed them. We sampled at high-resolution and applied new petrographic techniques combined with scanning electron microscopy and geochemical analyses to samples collected from three widely spaced sections—located in exposures along the Canning River and continuous core from the Mikkelsen Bay State 1 and Orion 1 wells. Results from these three locations indicate that this succession consists primarily of clay-rich mudstones that are variously silt- or sand-bearing and clay-dominated mudstones that exhibit mainly relict, 2–5 millimeter thick bedding and common but variable microbioturbation, rare macrobioturbation, and common fabrics of pelleted clay and silt. These mudstones contain rare, poorly sorted, silt-rich basal laminae that are often discontinuous and have wavy, sharp bases and crude upward fining. In addition, mud-supported, outsized clasts (dropstones) of fine sand to pebble size are present throughout the succession as isolated clasts or in clusters. We interpret these textures and much of this succession to result from intermittent deposition by suspension settling from melting seasonal sea ice—sometimes sediment-laden—and associated primary productivity. Overall, this mudstone succession fines and deepens upward from the pebble shale unit into the Hue Shale. In the Hue Shale of the Orion well, however, different processes intermittently deposited thin, discrete intervals of coarser sediment that probably represent deposition from density currents. Also in the Hue Shale of the Orion well, several thicker sandstone and silt-dominated mudstone units with discordant, scoured bases and cut and fill structures represent erosion during higher energy events such as major storms. Other lithofacies within the succession are graded tuffs/bentonites and tuffaceous/bentonitic mudstones from episodic volcanic ash falls; these are abundant in the Hue Shale, and very rare in the pebble shale unit of the two wells. Organic-carbon rich strata associated with volcanic ash intervals of the pebble shale unit and Hue Shale in the Mikkelsen 1 well have some of the best petroleum source rock potential determined for this succession. Authigenic pyrite and carbonate-cement-dominated mudstone are also present in both units of all three sections. The carbonate-cemented units indicate breaks in sedimentation and are common in the Hue Shale and in sections of the pebble shale unit interpreted to be more distal, such as along the Canning River. Our results document the variation in facies and textures of the Hauterivian and Barremian Lower Cretaceous mudstone succession of Arctic Alaska. Comparison of these characteristics to the products of modern processes on the North Slope of Alaska, in the Beaufort Sea, and elsewhere suggest that this succession formed primarily from depositional processes related to seasonal sea ice with intermittent fluvial-sourced sediment deposited by density currents and episodic erosion and reworking by storms and other currents.

Alaska↗

Chapter 19: Magmatic components of a tilted plutonic system, Klamath Mountains, California

The Slinkard pluton (SP) and Wooley Creek batholith (WCB) are the lower and upper parts, respectively, of a tilted Middle Jurassic magma system. The SP and lower WCB intruded structurally lower ophiolitic mélange of the Marble Mountain terrane; the upper WCB intruded successively structurally higher metavolcanic and metasedimentary rocks of the western and eastern Hayfork terranes. The predominant volume of the system comprised a two-layer chamber in which an upper dacitic magma crystallized to form tonalite to granite in the upper WCB and a lower andesitic magma crystallized to form gabbro to tonalite in the lower WCB and SP. The upper part of the system had Sr i , = 0.7043 and a range of δ 18 O from +8.7 to +11.2%o; the lower part had average Sr i = 0.7046 and δ 18 O from +8.1 to +8.8%o The two layers of the system are separated by a transition zone that is intermediate in isotopie composition. The compositional differences between upper and lower parts of the system can be explained as (1) the result of intrusion of two separate pods of noncogenetic magma, or (2) the product of in situ assimilation-fractional crystallization. The second explanation requires that a relatively 87 Sr-rich contaminant such as the structurally lower Marble Mountain terrane was assimilated in the lower part of the system, whereas an 18 O-rich, generally 87 Sr-poor contaminant such as the structurally intermediate western Hayfork terrane was assimilated by the upper part. Trace-element evidence suggests that gradational upward zoning (from gabbro to granite) resulted from an upward decrease in the efficiency of crystal-melt segregation and crystal accumulation. H 2 O-rich basaltic magma preceded development of the two-layer system, and basaltic pulses into the lower part of the system continued during most of its solidification history. Most basaltic rocks display evidence of some degree of fractional crystallization and interaction with crustal rocks; however, a few have low Sr i and high concentrations of Cr and Ni, characteristics of undifferentiated mantle melts. Two-mica granite of the western Slinkard pluton cannot be related to the remainder of the system by fractional crystallization. High δ 18 O, high Ba, and low Sr abundances suggest that the two-mica granite is probably a partial melt of crustal material.

California↗

The geology of Hess Rise, central north Pacific Ocean

The geology of Hess Rise is interpreted from studies of morphology and structure, igneous petrology, sediment lithofacies, seismic stratigraphy, and paleoenvironments. Hess Rise probably formed at a triple junction, between 116 and 95 m.y. ago, in the equatorial zone of the southern hemisphere. A large archipelago, formed by volcanism, subsequently moved northward as part of the Pacific Plate and subsided. A Late Cretaceous-early Tertiary tectonic and(or) volcanic event created oceanic islands and probably influenced the normal subsidence rate. The lithofacies reflect both the northward movement under various surface water masses of differing productivity and the subsidence history, which influenced calcareous-sediment accumulation and dissolution. Hess Rise is informally divided into three physiographic or morphologic provinces: northern Hess Rise, the central platform, and southern Hess Rise. Southern Hess Rise is further subdivided into the northwestern ridge, Mellish Bank, and the eastern ridge. The structure of Hess Rise is dominated by normal faults which bound grabens and horsts. The west and south boundaries of the rise are fault scarps. Most faults trend about 345 ° on northern Hess Rise, 039° to 060° on southern Hess Rise. Igneous rocks are tholeiitic basalt on northern Hess Rise at Site 464, and trachyte at Site 465 on southern Hess Rise. The tholeiite probably is not a mid-ocean-ridge basalt; more likely it is a transitional basalt erupted during off-ridge volcanism. The trachyte at Site 465 was erupted either in shallow water or subaerially; it represents a late-stage differentiate of alkali-basalt magma. Geochemically, the trachyte is similar to late-stage eruptives on many oceanic islands. The alkali basalt clasts in Upper Cretaceous calcareous ooze at Site 466 probably record a Late Cretaceous-early Tertiary tectonic event that brought old crust above sea level, where it was eroded; alternatively, volcanism may have built the islands. Cores recovered from Holes 464, 310, 310A, 465,465A, and 466 (north to south) show three major lithofacies: limestone of mid-Cretaceous (Albian-Cenomanian) age, calcareous ooze and chalk of Late Cretaceous to Quaternary age, and pelagic clay that is Late Cretaceous to Quaternary in age at Site 464 and Eocene in age at Site 310. Minor lithofacies in the carbonates and pelagic clay include siliceous microfossils and chert. The limestone contains as much as 8.6% by weight of organic carbon. The organic-carbon-rich sediments apparently were deposited along the sides of Hess Rise, above the CCD and within a mid-water oxygen minimum, as the rise crossed the highly productive equatorial divergence. Surface sediments are influenced by present-day near-surface water-mass productivity and the depth of deposition. Above about 3000 meters calcareous ooze is deposited, and below about 4000 meters pelagic clay is dominant. Between 3000 meters and 4000 meters, greater clay contents correlate with increased water depth. The seismic stratigraphy interpreted from single-channel seismic-reflection records can be correlated with the lithofacies. Three major acoustic units apparently vary in age, composition, thickness, and geographic distribution. The lowest acoustic unit generally is acoustically opaque; it corresponds to volcanic basement. In places, however, the top parts of this unit may be well-lithified limestone or chert. The middle acoustic unit, in general strongly layered acoustically, is Albian and Cenomanian limestone, chalk, and chert on southern Hess Rise and Albian and Cenomanian chert, chalk, limestone, and clay stone on northern Hess Rise. The middle unit probably is Albian to at least lower Tertiary chalk, chert, and nannofossil ooze on the central platform. The upper acoustic unit is weakly stratified to acoustically transparent and corresponds to Upper Cretaceous to Recent nannofossil ooze on southern Hess Rise and to pelagic clay of the same age on northern Hess Rise. On the central platform, it probably corresponds to Eocene to Recent nannofossil ooze, marl, and pelagic clay

Initial Reports of the D.S.D.P.↗