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At least 919 records · Page 51Linked to original sources

USGS2013

Ore genesis constraints on the Idaho cobalt belt from fluid inclusion gas, noble gas isotope, and ion ratio analyses--a reply

Burlinson (2013) questions the veracity of the H 2 concentrations reported for fluid inclusion extracts from minerals in the Idaho cobalt belt (Table 2; Landis and Hofstra, 2012) and suggests that they are an analytical artifact of electron-impact mass spectrometry. He also declares that H 2 should not be present in fluid inclusions because it is invariably lost by diffusion and is never detected in fluid inclusions by laser Raman. We welcome this opportunity to reply and maintain that the reported H 2 contents are accurate. Below we explain why Burlinson’s criticisms are invalid.

Idaho↗

USGS1944

Celestite in Buffalo Cove, Fentress County, Tennessee

Mineral aggregates consisting of celestite, dolomite, calcite, and very small amounts of sphalerite, anhydrite, and pyrite occur in the uppermost beds of the Glen Dean limestone, of upper Mississippian age, which crops out along the slopes of Buffalo Cove. Proportions of minerals range widely in adjacent aggregates; maximum content of strontium sulphate is about 96 per cent. The aggregates are spherical to nearly flat, and are regular to irregular in outline; a few coalesce. The maximum dimensions of those examined range from 0.04 to 1.35 feet, and their known vertical range in the Glen Dean limestone is from 7 to 20 feet or more downward from the contact with the overlying Pennington shale. The aggregates in the uppermost beds commonly contain chert and are somewhat hollowed as a result of weathering. Those in the lower beds contain no chert, and, where unweathered, no cavities. Celestite also occurs as isolated crystals and groups of crystals embedded in the limestone. The limetone is fine-grained, brownish gray, argillaceous, and un-fractured. The isolated crystals probably were precipitated from connate water as the limestone consolidated. During subsequent erosion of the Pennington shale to a level only 200 feet above the Glen Dean limestone, meteoric water probably gained access to the upper Glen Dean beds and dissolved cavities in them. The dense, unjointed limestone prevented downward percolation of the water, which became saturated with strontium sulphate and calcium carbonate, and deposited celestite and calcite in the solution cavities. As the dolomite in the aggregates has no apparent local source, it is believed to have been introduced from depth, probably with the small amounts of sphalerite and pyrite, by hydrothermal solutions in post-Mississippian time. Although no veins were seen in the few exposures examined around the cove, it is inferred by analogy with other mineralized areas that the solutions rose along fissures and were deflected by the overlying shale, spreading laterally through the partly filled cavities in the limestone without impregnating the limestone itself. Meteoric water still present in the cavities probably promoted deposition without attack on the limestone by lowering the temperature of the solutions.The celestite zone is being developed at the Youngs quarry. Reserves in the block of ground that contains the quarry are estimated to be 2,822 tons of the mineral aggregates, or strontium ore, containing 2,148 tons of celestite. The celestite constitutes 5.89 per cent by weight of the combined rock and aggregates in the block. Four out of seven exposures examined elsewhere in the ore zone suggest that other roughly comparable blocks may be developed. Underground quarrying is not practicable because of the overlying shale, but a dozen or more similar open quarry sites might be found on the divides between the numerous ravines that drain the sides of the cove.

Tennessee↗

USGS2001

Alaska: A twenty-first-century petroleum province

Alaska, the least explored of all United States regions, is estimated to contain approximately 40% of total U.S. undiscovered, technically recoverable oil and natural-gas resources, based on the most recent U.S. Department of the Interior (U.S. Geological Survey and Minerals Management Service) estimates. Northern Alaska, including the North Slope and adjacent Beaufort and Chukchi continental shelves, holds the lion's share of the total Alaskan endowment of more than 30 billion barrels (4.8 billion m 3 ) of oil and natural-gas liquids plus nearly 200 trillion cubic feet (5.7 trillion m 3 ) of natural gas. This geologically complex region includes prospective strata within passive-margin, rift, and foreland-basin sequences. Multiple source-rock zones have charged several regionally extensive petroleum systems. Extensional and compressional structures provide ample structural objectives. In addition, recent emphasis on stratigraphic traps has demonstrated significant resource potential in shelf and turbidite systems in Jurassic to Tertiary strata. Despite robust potential, northern Alaska remains a risky exploration frontier - a nexus of geologic complexity, harsh economic conditions, and volatile policy issues. Its role as a major petroleum province in this century will depend on continued technological innovations, not only in exploration and drilling operations, but also in development of huge, currently unmarketable natural-gas resources. Ultimately, policy decisions will determine whether exploration of arctic Alaska will proceed.

Alaska↗

USGS2015

Time scales of porphyry Cu deposit formation: insights from titanium diffusion in quartz

Porphyry dikes and hydrothermal veins from the porphyry Cu-Mo deposit at Butte, Montana, contain multiple generations of quartz that are distinct in scanning electron microscope-cathodoluminescence (SEM-CL) images and in Ti concentrations. A comparison of microprobe trace element profiles and maps to SEM-CL images shows that the concentration of Ti in quartz correlates positively with CL brightness but Al, K, and Fe do not. After calibrating CL brightness in relation to Ti concentration, we use the brightness gradient between different quartz generations as a proxy for Ti gradients that we model to determine time scales of quartz formation and cooling. Model results indicate that time scales of porphyry magma residence are ~1,000s of years and time scales from porphyry quartz phenocryst rim formation to porphyry dike injection and cooling are ~10s of years. Time scales for the formation and cooling of various generations of hydrothermal vein quartz range from 10s to 10,000s of years. These time scales are considerably shorter than the ~0.6 m.y. overall time frame for each porphyry-style mineralization pulse determined from isotopic studies at Butte, Montana. Simple heat conduction models provide a temporal reference point to compare chemical diffusion time scales, and we find that they support short dike and vein formation time scales. We interpret these relatively short time scales to indicate that the Butte porphyry deposit formed by short-lived episodes of hydrofracturing, dike injection, and vein formation, each with discrete thermal pulses, which repeated over the ~3 m.y. generation of the deposit.

Montana↗

USGS1964

Mineral paragenesis and zoning in the central Kentucky mineral district

The Central Kentucky mineral district occupies the greater part of the Blue Grass lowland of Kentucky , which lies astride the Lexington dome and the Cincinnati arch. The oldest exposed rocks of the mineralized area are limestones of Middle Ordovician age. The paragenesis throughout the district is constant and traceable, although the relative abundance of minerals varies from vein to vein. The mineral association, areal distribution of the ore minerals, and comparison with other epithermal deposits indicate that the Central Kentucky veins are epithermal. The ore deposits have a district -wide lateral zoning in a concentric pattern. Near the middle of the district , and within the Lexington dome, are two centers of fluorite-calcite-dark sphalerite veins that form Zone 1. Surrounding these centers is a much larger Zone 2 in which nearly all the veins contain fluorite, barite, calcite, and two-colored (yellow-black) sphalerite. Galena is absent or present in very minute quantities in Zones 1 and 2. In Zone 3, which surrounds Zone 2, barite, galena, and bright-colored sphalerite are the principal minerals. Fluorite is absent, or present only in traces. Textures of the mineral veins change from bands of coarse comb crystals in Zone 1 to mostly colloform bands in the outer zones. Structural control of the ore is related to faults and fractures transecting the collapsed Lexington dome and is an important factor in the distribution of mineral veins. The district has many of the mineralogic, zonal, and structural features of the Central Tennessee, Kentucky -Illinois, and Pennine, England, mineral districts, which suggest that the origins of these districts were similar. The ores in the Central Kentucky district were probably deposited from ascending thermal solutions of slightly lower temperatures than those that formed the deposits in the Kentucky -Illinois district . The solutions are believed to have been derived from a deepseated magmatic source centered beneath the Lexington dome, but they may have been greatly diluted by ground waters within the dome. The innermost zone probably is nearest to the emanative centers.

Kentucky↗

USGS1984

Deformation, geochemistry, and origin of massive sulfide deposits, Gossan lead district, Virginia

The Gossan Lead district is a 28-km-long, northeast-trending belt of discontinuous massive sulfide deposits in the Blue Ridge province of southwestern Virginia. The deposits, hosted by the Ashe Formation of late Proterozoic age, consist of strata-bound lenses and layers of massive pyrrhotite, minor chalcopyrite, sphalerite, and pyrite, and rare arsenopyrite and galena. Deposits were mined principally in the Iron Ridge and Betty Baker segments, respectively, at the southwestern and northeastern ends of the belt. Detailed mapping of the Gossan Howard, Huey, and Bumbarger pits in the Iron Ridge segment indicates that the deposits occur at one horizon and have been variously folded and brecciated after sulfide deposition. The Gossan Howard consists of a single, gently dipping lens of sulfide. The Huey deposit is complexly folded and locally contains tectonically thickened ore. The Bumbarger deposit is a lens as much as 40 m thick--the thickest known in the district. This deposit contains abundant coarse breccia fragments of wall rock around which the massive sulfide has flowed (during deformation and metamorphism), probably thickening the original deposit significantly. In the northeastern part of the district, drill holes intersect several sulfide layers that possibly are structurally repeated.The Ashe Formation in the district is a sequence of metasedimentary rocks and local conformable lenses of amphibolite and actinolite-chlorite schist. The metasedimentary rocks include metapelite, quartz-feldspar granofels (metagraywacke), and minor quartzite and carbonaceous schist, and are interpreted as marine turbidites. The amphibolites and other mafic rocks have chemical compositions similar to low Ti tholeiitic basalt, with a high Y/Nb (>10) and high average contents of Co (40 ppm), Cr (403 ppm), Ni (211 ppm), and V (247 ppm). Immobile trace element signatures (Ti-Y-Zr; Th-Hf-Ta; Ti-Cr) suggest a magmatic affinity with midocean ridge basalt (MORB); rare earth elements (REE) have low abundance levels (10X-15X chondrite), broadly flat patterns [(La/Yb) N = 0.7-1.1], and a slight depletion in the light elements similar to midocean ridge basalts. An amphibolite from a much higher stratigraphic level, south of the district, differs significantly from the mafic rocks closer to the sulfide zone in having the chemical signature of a transitional, slightly alkalic tholeiite with high TiO 2 (3.87 wt %), Fe 2 O 3 (16.4 wt %), and P 2 O 5 (0.56 wt %), low Y/Nb (3.3), and a highly fractionated rare earth element distribution [(La/Yb) N = 3.9] similar to continental basalt.Some silicate wall rocks of the deposits are mineralogically and chemically unusual, and differ substantially from the clastic metasediments of the Ashe Formation. Such rocks are composed mainly or wholly of plagioclase feldspar, biotite, chlorite, muscovite, or spessartine-rich garnet. The unusual lithologies form local strata-bound lenses in the footwall and/or hanging wall of the deposits, typically within 10 m of massive sulfide. The plagioclase rocks (3.4-7.6 wt % Na 2 O) consist largely of granoblastic albite-oligoclase (Ab (sub 78-90) ) with minor quartz and biotite; rare earth elements are highly fractionated [(La/Yb) N = 6.8-7.1] and their patterns resemble those of the quartz-feldspar granofels (metagraywacke) from the district.The biotite schists, locally monomineralic, have FeO/(FeO + MgO) = 0.5 and contain high phosphorus (1 wt % P 2 O 5 ) and fluorine (0.5 wt % F), present in fluorapatite. The chlorite schist is essentially all ripidolite; rare earth elements are highly fractionated, and have a large negative Eu anomaly. The spessartine-rich rocks (6.3-8.9 wt % MnO) are in places interlayered with the other unusual wall rocks and consist of abundant Mn-rich garnet (Sp 50 Al 23 Gr 19 Py 8 ) and minor quartz, plagioclase, pyrrhotite, and biotite. The distinctive mineralogy and chemistry of these rocks suggest that they represent metamorphosed alteration zones and/or intermixed chemical and clastic sediments.The sulfide deposits are interpreted as syngenetic in origin but modified in form by deformation which accompanied metamorphism. The great length of the mineralized district parallel to the regional strike and the flyschoid (turbidite) nature of the host rocks suggest that sedimentation and initial sulfide deposition took place in a deep, elongate marine basin or graben overlying a crustal rift zone. A rift underlying the sedimentary pile is consistent with the occurrence of mafic metavolcanic rocks of midocean ridge basalt affinity and could also have served as the feeder system for a line of hydrothermal vents on the sea floor that generated the sulfide deposits.

Economic Geology↗

USGS2019

Rare earth elements in coal and coal fly ash

The rare earth elements (REEs) are a group of 17 elements sharing similar chemical properties. They include yttrium (Y, atomic number 39), scandium (Sc, atomic number 21), and the 15 elements of the lanthanide series, atomic numbers 57 (lanthanum, La) to 71 (lutetium, Lu). Because promethium (Pm, atomic number 61) does not occur in the Earth’s crust and scandium typically has different geological occurrences from other REEs, they are not discussed further herein. REEs are, on average, more abundant than precious metals (for example, gold, silver, and platinum), but because of their unique geochemical properties, they do not commonly form economically viable ore deposits. Nevertheless, REEs are increasingly required for a range of modern applications in defense and renewable energy technologies and in commercial products, primarily as magnets, batteries, and catalysts. The United States currently (2018) produces REEs from a single mine in California, accounting for just 9 percent of global production, whereas 70 percent of global REE production comes from China. For these reasons, REEs are considered a critical resource, and the U.S. Geological Survey (USGS) has an interest in helping to identify new sources of REEs for domestic production. In 2017, coal use accounted for about 30 percent of the electric power generated in the United States. Fly ash, produced during the burning of coal, is a fine-grained solid derived from noncombustible constituents of coal, such as clay minerals and quartz. When coal is burned, REEs are retained and enriched in the fly ash and, as a result, fly ash has long been considered a potential resource for REEs. The United States has the world’s largest coal reserves and, even though gas-fired power generation has increased significantly in the last decade, the United States continues to produce vast quantities of fly ash, about half of which is beneficially reused, primarily in construction materials. The remainder is stored, mostly in landfills and impoundments. Thus, annual fly ash production, combined with fly ash already in storage, constitutes a large potential resource. Research into how to utilize coal and coal fly ash as sources of REEs is ongoing. Viable recovery of REEs from coal and coal ash requires identification of coals and ashes with the highest REE concentrations and development of workable methods for REE extraction and recovery. Understanding how REEs occur within fly ash, described in this fact sheet, is one of the keys to developing possible methods for their recovery.

Fact Sheet↗

USGS1974

Stratigraphy and nahcolite resources of the saline facies of the Green River Formation, Rio Blanco County, Colorado

Based on a study of 10 drill cores, a sequence of oil shale and associated nahcolite, nearly 2,000 feet thick, in the lacustrine Green River Formation (Eocene) in the Piceance Creek basin, Rio Blanco County, Colo., was divided in ascending order into zones 1 to 13, B-groove, Mahogany zone (with lower, middle, and upper parts), and A-groove at the top. The odd-numbered zones and the Mahogany zone are mappable subsurface units of relatively thick oil shale and are distinguished from the even-numbered zones and A- and B-grooves which are thinner units of oil shale of lower grade. Large amounts of nahcolite found in zones 5 to 12 occur in (1) coarse-grained crystalline aggregates scattered through oil shale, (2) laterally continuous units of fine-grained crystals disseminated in oil shale, (3) brown microcrystalline beds, and (4) white coarse-grained beds that grade laterally into halitic rocks toward basin center. The original .upper limit of the nahcolite and halitic rocks is not yet completely known, but the present top is marked by a dissolution surface. Above this surface the rocks, extending from zones 11 or 12 upward into the Mahogany zone, form a water-saturated 'leached zone,' a geohydrologic unit in which large amounts of water-soluble minerals probably mostly nahcolite, and halite, were removed by ground-water dissolution. Rocks in the leached zone, mostly oil shale, are commonly broken and fractured and contain crystal cavities and solution breccias. Several solution breccias can be traced laterally into unleached beds of nahcolite and halite. Although evidence of salines is found in rocks above A-groove, the original saline facies that includes most of the bedded deposits extends from zone 5 upward into A-groove. Potentially ruinable beds of white nahcolite as much as 12 feet thick are found at depths of 1,560 or more feet below the surface. Some thicker beds of high-grade nahcolite are believed to be too close to the dissolution surface for safe room-and-pillar mining. Probably the most economical method of mining nahcolite would be as a coproduct of a shale-oil industry. Removal of nahcolite prior to retorting increases significantly the grade of oil shale by as much as 1.6 times, Several zones are more than 300 feet thick and average 30 or more weight percent nahcolite. Resources of nahcolite per square mile range as high as 489 million short tons. The total nahcolite resource in the basin is conservatively estimated at 32 billion short tons, which makes it the secondlargest deposit of sodium carbonate known .in the world.

Open-File Report↗

USGS2017

Niobium and tantalum

Niobium and tantalum are transition metals that are almost always found together in nature because they have very similar physical and chemical properties. Their properties of hardness, conductivity, and resistance to corrosion largely determine their primary uses today. The leading use of niobium (about 75 percent) is in the production of high-strength steel alloys used in pipelines, transportation infrastructure, and structural applications. Electronic capacitors are the leading use of tantalum for high-end applications, including cell phones, computer hard drives, and such implantable medical devices as pacemakers. Niobium and tantalum are considered critical and strategic metals based on the potential risks to their supply (because current production is restricted to only a few countries) and the significant effects that a restriction in supply would have on the defense, energy, high-tech industrial, and medical sectors. The average abundance of niobium and tantalum in bulk continental crust is relatively low—8.0 parts per million (ppm) niobium and 0.7 ppm tantalum. Their chemical characteristics, such as small ionic size and high electronic field strength, significantly reduce the potential for these elements to substitute for more common elements in rock-forming minerals and make niobium and tantalum essentially immobile in most aqueous solutions. Niobium and tantalum do not occur naturally as pure metals but are concentrated in a variety of relatively rare oxide and hydroxide minerals, as well as in a few rare silicate minerals. Niobium is primarily derived from the complex oxide minerals of the pyrochlore group ((Na,Ca,Ce) 2 (Nb,Ti,Ta) 2 (O,OH,F) 7 ), which are found in some alkaline granite-syenite complexes (that is, igneous rocks containing sodium- or potassium-rich minerals and little or no quartz) and carbonatites (that is, igneous rocks that are more than 50 percent composed of primary carbonate minerals, by volume). Tantalum is derived mostly from the mineral tantalite ((Fe,Mn)(Ta,Nb) 2 O 6 ), which is found as an accessory mineral in rare-metal granites and pegmatites that are also enriched in lithium and cesium (termed lithium-cesium-tantalum (LCT)-type pegmatites). Brazil and Canada are the leading nations that produce niobium mineral concentrates, but Brazil is by far the leading producer, accounting for about 90 percent of production, which comes mostly from weathered material derived from carbonatites. Brazil and Canada also have the largest identified niobium resources; additional resources, although they are less well reported, occur in Angola, Australia, China, Greenland, Malawi, Russia, and South Africa. Australia and Brazil have been the leading producers of tantalum mineral concentrates, although recently Ethiopia and Mozambique have also been significant suppliers of tantalum. Artisanal mining of columbite-tantalite (also called coltan) is practiced in many countries, particularly Burundi, the Democratic Republic of the Congo (Congo [Kinshasa]), Nigeria, Rwanda, and Uganda. Brazil has about 40 percent of the identified tantalum resources; other countries and regions with identified tantalum resources include, in decreasing order of resources, Australia, Asia, Russia and the Middle East, Africa, North America, and Europe. Identified niobium and tantalum resources in the United States are small, low grade, and difficult to recover and process, and are thus not commercially recoverable at current prices. Consequently, the United States meets its current and expected future needs for niobium and tantalum through imports of primary mineral concentrates and alloys and through recovery from foreign and domestic alloy scrap that contain the metals. Environmentally, the main issues related to niobium and tantalum mining are land disruptions, the volume of waste materials and their disposal, and the radioactivity of some tailings and waste materials that contain thorium and uranium. Because of the relative biological inertness of niobium and tantalum, human and ecological health concerns are generally minimal under most natural conditions. Demand for both niobium and tantalum is expected to increase as the world economy continues to recover from the downturn that began in 2008. Increased demand for niobium is linked to increased consumption of microalloyed steel, which is used in the manufacture of cars, buildings, ships, and refinery equipment. Demand for these steels will likely increase with continued economic development in such countries as Brazil, China, and India. In addition, increased global demand for cars, cell phones, computers, superconducting magnets, and other high-tech devices will likely spur increased demand for both niobium and tantalum. The estimated global reserves and resources of niobium and tantalum are large and appear more than sufficient to meet global demand for the foreseeable future, possibly the next 500 years. The sale of “conflict coltan” attributed to rebel forces waging a civil war in Congo (Kinshasa) has been of recent concern and has highlighted the need for a transparent and traceable global supply chain that can exclude illegal columbite-tantalite from the conventional market while discerning legitimate artisanal mine production in central Africa.

Professional Paper↗

USGS1997

Epithermal mercury-antimony and gold-bearing vein lodes of southwestern Alaska

Epithermal mineral deposits and occurrences of southwestern Alaska consist of Hg-Sb and gold- and sulfide-bearing vein lodes. Numerous Hg-Sb lodes are located throughout a region measuring several tens of thousands of square kilometers in and surrounding the Kuskokwim River basin in southwestern Alaska. The Hg-Sb lodes are hosted in sedimentary rocks of the Cretaceous Kuskokwim Group, the Triassic to Cretaceous Gemuk Group, and the Paleozoic Holitna Group, as well as in Late Cretaceous and early Tertiary mafic to felsic intrusive rocks. Mineralized Hg-Sb vein and vein breccia lodes are found in the sedimentary or igneous rocks or at their contacts. The minerology of the Hg-Sb lodes is dominated by cinnabar and stibnite, with subordinate realgar, orpiment, and native mercury, pyrite, gold, and hematite, as well as solid and liquid hydrocarbons; quartz, carbonate, limonite, dickite, and sercite are alteration gangue minerals. The largest mercury mine in Alaska, Red Devil, produced about 36,000 flasks of mercury, but the Hg-Sb lodes of southwestern Alaska generally consist of small, discontinuous veins that rarely exceed a few meters in width and a few tens of meters in strike length. The Hg-Sb lodes generally contain about 1 to 5 percent Hg and less than 1 percent Sb and As but are generally poor in base emtals and precious metals. Anomalous concentrations of gold in some lodes, however, suggest that gold deposits may be present in higher temperature environments below some of the Hg-Sb lodes. The formation of the Hg-Sb lodes is closely correlated with igneous activity of a Late Cretaceous and early tertiary magmatic arc in southwestern Alaska. Geologic and geochemical characteristics of the Hg-Sb lodes suggest that ore fluids were generated in local sedimentary rocks as they were intruded by magmas. These intrusions provided the heat to initiate dehydration reactions and expel fluids from hydrous minerals and formational waters in the sedimentary rocks, causing thermal convection and hydrothermal fluid flow along fractures and faults. Isotopic data from sulfide and alteration minerals of the Hg-Sb lodes indicate multiple sources for the ore fluids; most fluids appear to have originated from local sedimentary rocks. Hydrothermal fluids with isotopically heavy oxygen but isotopically light hydrogen and sulfur compositions indicate derivation of these species from sedimentary rocks. Isotopically shifted, evolved meteoric water was a primary component in ore fluids from a few Hg-Sb lodes. Geochemical, isotopic, and fluid inclusion data also indicate that Hg, Co 2 , CH 4 , N2, and local hydrocarbons were derived from breakdown of organic matter in sedimentary rocks when they were heated by intrusions. Radiometric 40 Ar/ 39 Ar ages of 70 ± 3 Ma from hydrothermal sercites in the Hg-Sb lodes indicate a temporal association of igneous activity and mineralization, which is consistent with the geologic characteristics. Most epithermal gold-bearing vein lodes on the Alaska Peninsula and Aleutian Islands are located in Eocene to Pleistocene volcanic-arc rocks, commonly andesite and dacite. These vein and vein breccia lodes, such as the Alaska-Apollo and Shumagin deposits on Unga Island, tend to be aligned along regional, northeast-striking, steeply dipping faults and fractures. The Alaska-Apollo mine produced about 500,000 metric tons (t) of ore that yielded an estimated 3,500 kg (130,000 oz) of gold from veins that were as much as 12 m wide and extended for 1,500 m laterally and 420 m vertically. Ore minerals include gold, galena, sphalerite, chalcopyrite, pyrite, marcasite, arsenopyrite, and native copper; gangue minerals are quartz, sericite, calcite, and chlorite and locally, barsite, clay, rhodonite, and adularia. Ores generally have Au-Ag-Te-Pb-Zn-Mn-Cu geochemical signatures, with wide As-Hg aureoles around some veins. Geologic and mineralogical characteristics of these lodes are similar to adularia-sericite volcanic-hosted epithermal deposits. The gold-bearing vein lodes may be related to arc porphyry systems, but more data are required to verify this association.

Alaska↗

USGS2006

Beyond the obvious limits of ore deposits: The use of mineralogical, geochemical, and biological features for the remote detection of mineralization

Far field features of ore deposits include mineralogical, geochemical, or biological attributes that can be recognized beyond the obvious limits of the deposits. They can be primary, if formed in association with mineralization or alteration processes, or secondary, if formed from the interaction of ore deposits with the hydrosphere and biosphere. This paper examines a variety of far field features of different ore deposit types and considers novel applications to exploration and discovery. Primary far field features include mineral and rock chemistry, isotopic or element halos, fluid pathways and thermal anomalies in host-rock sequences. Examples include the use of apatite chemistry to distinguish intrusive rocks permissive for iron oxide copper gold (IOCG) and porphyry deposits; resistate mineral (e.g., rutile, tourmaline) chemistry in exploration for volcanogenic massive sulfide (VMS), orogenic gold, and porphyry deposits; and pyrite chemistry to vector toward sedimentary exhalative (sedex) deposits. Distinctive whole-rock geochemical signatures also can be recognized as a far field feature of porphyry deposits. For example, unique Sr/Y ratios in whole-rock samples, used to distinguish barren versus fertile magmas for Cu mineralization, result from the differentiation of oxidized hydrous melts. Anomalous concentrations of halogen elements (Cl, Br, and I) have been found for distances of up to 200 m away from some mineralized centers. Variations in isotopic composition between ore-bearing and barren intrusions and/or systematic vertical and lateral zonation in sulfur, carbon, or oxygen isotope values have been documented for some deposit types. Owing to the thermal aureole that extends beyond the area of mineralization for some deposits, detection of paleothermal effects through methods such as conodont alteration indices, vitrinite or bitumen reflectance, illite crystallinity, and apatite or zircon thermochronology studies also can be valuable, particularly for deposits with a low-temperature thermal history. A number of newly investigated secondary far field features include the development of reduced columns by electrochemical processes in transported overburden, geochemical dispersion related to the expulsion of groundwater from tectonic and seismic compression, dispersion of vapor above ore deposits, and geochemical dispersion related to biological processes. Redox gradients have been found between underlying reduced and overlying oxidized environments associated with sulfide bodies, which result in mass transfer through electro-chemical dispersion. Recent studies have characterized the pH, oxidation-reduction potential (ORP), and self potential (SP) in overburden overlying sulfide-hosted gold and VMS deposits. Lateral migration of metals in groundwater is well understood from normal groundwater flow, but the processes responsible for vertical mass transfer of groundwater and its dissolved components have been recognized only recently. One process, termed cyclical dilatancy pumping, expels groundwater during and after earthquake events, which can cause the redistribution of metals around deposits in some environments. Soil gases are of interest owing to their high degree of mobility through the vadose zone in transported overburden. Numerous soil gas species (CO2, O2, Hg, Rn, He, sulfur compounds, and light hydrocarbons) have been measured and interpreted as diagnostic of some buried mineral deposits, and some evidence suggests a possible link between vapor dispersion and metal enrichment in soil. Geochemical enrichment in plant material and soils through successive growth-death cycles is well established, but the important role of microorganisms is now increasingly evident. Microorganisms significantly enhance the kinetics of sulfide oxidation and influence the distribution of metals around ore deposits. The presence of metal-resistant bacteria and enhanced concentrations of sulfate-reducing bacteria in exotic overburd

Economic Geology↗

USGS1958

Nickel-gold ore of the mackinaw mine, Snohomish County, Washington

The Mackinaw mine ore is of an unusual or unique type, consisting chiefly of niccolite, maucherite, pentlandite, chalcopyrite, cubanite, and magnetite in an altered peridotite. Valleriite, gold and sphalerite are minor primary minerals; chalcocite and violarite or bravoite are supergene minerals. Pyrrhotite and pyrite are absent. From the textural relations it is inferred that a complex copper-nickel-iron sulfide was deposited early. On cooling, the sulfide unmixed into two different complex sulfides, one of which in turn unmixed into chalcopyrite and cubanite, the other into chalcopyrite and pentlandite. The latter exsolution relationship has not been previously reported. Valleriite either exsolved from, or replaced, chalcopyrite. Late solutions altered the niccolite to maucherite, and introduced gold and magnetite. The gold is almost always with maucherite.

Washington↗

USGS1990

The Bayan Obo iron-rare-earth-niobium deposits, Inner Mongolia, China

The plate tectonic setting, regional geology and certain aspects of the economic geology of the iron-rare-earth-niobium ore bodies at Bayan Obo, Inner Mongolia, China, were studied by a team of geologists from the Tianjin Geologic Research Academy and the U.S. Geological Survey between 1987 and 1989. These ore bodies were formed by hydrothermal replacement of Middle Proterozoic dolomite in an intra-continental rift setting. A variety of veins and/or dikes that have a carbonatitelike mineralogy cut the footwall clastic rocks and migmatites. A stockwork of veins occurs at several locations in the footwall. The hanging wall is a shale that has been converted to a K-metasomatite and has microcrystalline potassium feldspar as its principal constituent. This shale served as a sealing caprock that contained the chemical solutions that reacted with the dolomite and created the enormous concentration of mineralized rock in an 18-kilometer-long syncline. The rocks that host these ore bodies and the associated mineralized areas occur today as roof pendants in granitoid rocks of Permian age that were emplaced during a continent-to-continent collision during that period.

LITHOS↗

USGS2015

Carbon dioxide storage in unconventional reservoirs workshop: summary of recommendations

“Unconventional reservoirs” for carbon dioxide (CO 2 ) storage—that is, geologic reservoirs in which changes to the rock trap CO 2 and therefore contribute to CO 2 storage—including coal, shale, basalt, and ultramafic rocks, were the focus of a U.S. Geological Survey (USGS) workshop held March 28 and 29, 2012, at the National Conservation Training Center in Shepherdstown, West Virginia. The goals of the workshop were to determine whether a detailed assessment of CO 2 storage capacity in unconventional reservoirs is warranted, and if so, to build a set of recommendations that could be used to develop a methodology to assess this storage capacity. Such an assessment would address only the technically available resource, independent of economic or policy factors. At the end of the workshop, participants agreed that sufficient knowledge exists to allow an assessment of the potential CO 2 storage resource in coals, organic-rich shales, and basalts. More work remains to be done before the storage resource in ultramafic rocks can be meaningfully assessed. In order to assess the CO 2 storage capacity of coals and organic-rich shales, the workshop participants agreed that the following several factors are key: sorption mechanisms and capacity, pore fluid composition and saturation, thermal maturity, formation thickness, and whether hydrocarbons have been extracted from the formation previously (for example, by enhanced gas or oil recovery). In order to assess the CO 2 storage capacity of basalts, the workshop participants agreed that key factors include temperature, pressure, pH, water chemistry, mineral chemistry, organic content, mineralogy, porosity, permeability, relative permeabilities, and CO 2 phase. The storage capacity for all unconventional reservoirs may be modeled using a volumetric equation starting with the extent of the rock unit and adjusted using these key factors and reaction terms. The ideas that were developed during this workshop can be used by USGS scientists to develop a methodology to assess the CO 2 storage resource in unconventional reservoirs. This methodology could then be released for public comment and peer review. After completing this development process, the USGS could then use the methodology to assess the CO 2 storage resource in unconventional reservoirs.

Open-File Report↗

USGS2004

Ad Duwayhi, Saudi Arabia: Geology and geochronology of a neoproterozoic intrusion-related gold system in the Arabian shield

The Ad Duwayhi gold deposit, located in the east-central part of the Arabian shield, is the newest gold discovery in Saudi Arabia. Exploration to date has identified a gold resource of greater than 1 million ounces (oz) with significant potential for expansion. Gold mineralization was closely associated, in time and space, with emplacement of a late- to postorogenic, intracrustal, northwest-oriented granite body (659 ± 7 Ma) and comagmatic square quartz porphyry (646 ± 11 Ma), a hypabyssal and perhaps younger phase of the granite. Mineralization was largely confined to northeast-striking, southeast-dipping fault zones. Hydrothermal alteration consisted of early biotitic alteration overprinted by sericitic alteration. Sericitic alteration was coincident with gold mineralization and produced a quartz-sericite-carbonate-pyrite-rutile mineral assemblage, found both as vein fill and wall-rock alteration products. Mineralization styles, in the following general paragenetic sequence, include (1) quartz-molybdenite veins in and near the granite stock, (2) low-grade gold-bearing quartz vein breccia in and along the margins of the granite stock, (3) gold-bearing stockwork and sheeted quartz veins, and (4) massive to banded gold-rich tabular quartz veins. The gold-bearing stockwork, sheeted, and tabular veins are generally spatially associated with square quartz porphyry dikes and more distal to the granite stock. Mineralized zones at Ad Duwayhi are characterized by low sulfide and base metal content and gold/silver ratios of approximately 6/1. Gold shows no significant correlation with other metals, except lead, and moderate correlation with silver. Re-Os dating of molybdenite from a quartz-molybdenite vein and a tabular quartz vein with cogenetic gold produced robust ages of 655.6 ± 2.7 and 649.9 ± 2.3 Ma, respectively, documenting that gold mineralization and crystallization of granite and square quartz porphyry were, within uncertainty, coeval events. This age correlation combined with granite textural features, the presence of unidirectional solidification textures in granite and square quartz porphyry, and the nature and time-space distribution of mineralization styles, all indicate that mineralization evolved in and near the interface between a crystallizing magma and the surrounding rocks and, thus, is consistent with an intrusion-related genesis. In light of our findings at Ad Duwayhi, a reassessment of similar intrusion-hosted deposits in the Arabian shield is warranted, and areas of late- to postorogenic plutonism, particularly in the Afif composite terrane, should be considered prospective for intrusion-related gold systems.

Economic Geology↗

USGS2016

Mineral thermometry and fluid inclusion studies of the Pea Ridge iron oxide-apatite–rare earth element deposit, Mesoproterozoic St. Francois Mountains Terrane, southeast Missouri, USA

Mineral thermometry and fluid inclusion studies were conducted on variably altered and mineralized samples from the Mesoproterozoic Pea Ridge iron oxide-apatite (IOA)-rare earth element (REE) deposit in order to constrain P-T conditions, fluid chemistry, and the source of salt and volatiles during early magnetite and later REE mineralization. Scanning electron microscopy (SEM)-cathodoluminescence and SEM-backscatter electron images show that quartz and rutile precipitated before, during, and after magnetite and REE mineral growth. Ti-in-quartz and Zr-in-rutile equilibration temperatures range from ≤350° to 750°C in the amphibole, magnetite, hematite, and silicified zones where T increased during magnetite and quartz growth and dropped precipitously after fracturing and brecciation. Late drusy quartz cements within a REE-rich breccia pipe record the lowest T (≤315°–400°C). Liquid-, vapor-rich, and hypersaline (±hematite, calcite) fluid inclusions are common and liquid CO 2 is present locally. Salinities define three populations: saline (10–27 wt % NaCl equiv), hypersaline (34–>60 wt % NaCl equiv), and dilute (0–10 wt % NaCl equiv ). The wide range of eutectic melting temperatures (−67° to −19°C) suggests that saline inclusions trapped variable proportions of a CaCl-MgCl-FeCl-bearing fluid end member and an NaCl-KCl fluid end member. Homogenization temperatures and pressures of these saline inclusions suggest they were trapped when fluids unmixed into brine and vapor at T <350°C, P <15 MPa, and a depth of ~1.5 km. Hypersaline inclusions were trapped at low T and P (~200°C and ~1 MPa) along the V + L + H curve when the system vented to the paleosurface. Data for dilute inclusions in late drusy quartz from the REE-rich breccia pipe are indicative of a boiling epithermal environment. The Na/Cl, Na/K, and Cl/Br ratios of fluid inclusion extracts provide evidence for mixtures of magmatic hydrothermal fluids and evaporated seawater. Extracts from magnetite, hematite, and pyrite plot in the magmatic-hydrothermal field, indicating that Fe was derived from a magmatic source. Their enrichments in Mg and Ca are consistent with a mafic magmatic source. The positive correlation between Na/Mg and Na/Ca ratios may be due to halite saturation or albitization of igneous rocks. Extracts from barite in the REE-rich breccia pipes are enriched in Na and Br and plot near the seawater evaporation trend. He is highly enriched relative to Ne and Ar in fluid inclusion extracts, which precludes air as a source of He. Although the He is mostly of crustal origin, pyrite with a 3 He/ 4 He (R/R A ) of 0.1 contains up to 12% mantle He. Many extracts have low 20 Ne/ 22 Ne ratios due to nucleogenic production of 22 Ne in high F/O minerals such as fluorapatite or F biotite. The arrays of data for 3 He/ 4 He (R/R A ) and 22 Ne/ 20 Ne suggest that volatiles were derived from two sources, a moderate F mafic magma containing mantle He and a high F silicic magma with crustal He. Together with other evidence cited in this report, these data (1) support a magmatic hydrothermal origin for the Mesoproterozoic magnetite-apatite deposit with ore fluids derived from a concealed mafic to intermediate-composition intrusion, (2) suggest that the REE minerals in breccia pipes were either derived from apatite or precipitated in response to decompression and cooling during breccia pipe formation, (3) provide evidence for the influx of basinal brine, magmatic fluids from granitic intrusions, and meteoric water after breccia pipe formation, and (4) show that Pea Ridge was relatively unaffected by the late Paleozoic Mississippi Valley-type (MVT) Pb-Zn system in overlying Cambrian sedimentary rocks.

Missouri↗

USGS1999

U.S. Geological Survey programs in Florida, 1999

The safety, health, and economic well-being of Florida?s citizens are important to the U.S. Geological Survey (USGS), which is involved in water-related, geologic, biological, land use, and mapping issues in many parts of the State. The USGS office in Tallahassee acts as the liaison for all studies conducted by USGS scientists in Florida. Water resources activities are conducted not only from the office in Tallahassee, but also from offices in Miami, Tampa, and Altamonte Springs (Orlando). Scientists in these offices investigate surface water, ground water and water quality in Florida, working in cooperation with other Federal, State and local agencies and organizations. The USGS Center for Coastal Geology and Regional Marine Studies was established in St. Petersburg in 1988, in cooperation with the University of South Florida. The Center conducts a wide variety of research on mineral resources and on coastal and regional marine problems, including coastal erosion, climate change, wetlands deterioration, and coastal pollution. A USGS mapping office is located in St. Petersburg. Also, the Earth Science Information Center (ESIC) in Tallahassee provides USGS information to customers and directs inquiries to the appropriate USGS office or State agency on earth science topics, particularly those related to cartography, geography, aerial photography, and digital data. Biologists at the USGS Florida Caribbean Science Center, located in Gainesville, conduct biological and ecosystem studies in Florida, Puerto Rico, and the Virgin Islands.

Florida↗

USGS1934

Zoning of ore deposits in and adjoining the Leadville District, Colorado

The ore deposits in the heart of the Leadville district , Colorado , are divisible, as shown by Emmons, Irving, and Loughlin,2 into two main classes on the basis of mineral composition: "contact-metamorphic" silicates accompanied by iron oxides, which adjoin an obscure igneous stock, and mixed sulphides accompanied by manganosiderite and quartz gangue, which cut the "contact-metamorphic" deposits and form a broad zone extending for 2 1/2 miles to the west and for shorter distances in other directions. A detailed consideration of the mineralogy of the mixed sulphide ore deposits clearly shows that they in turn are divisible into groups, referred to as hotter and intermediate mesothermal deposits . These groups, however, because of complications in structural control, are not ideally arranged from the standpoint of zoning .Emmons, Irving, and Loughlin noted that barite was a conspicuous gangue mineral in certain outlying deposits on the west slope of the Mosquito Range. The junior author during 1928-1931 had an opportunity to study the outlying deposits over an area of twenty square miles, which includes mines near the heads of Iowa Gulch and Empire Gulch, and the Weston Pass district (Fig. 1), and found that these baritic deposits form a somewhat distinct outer zone in which the primary ore consists of galena and light-colored zinc blende, with small amounts of silver and practically no gold, in a gangue of barite, jasperoid, and crystalline quartz. There is also recognized a still more remote though poorly defined zone in which the same sulphides are present but jasperoid is less conspicuous and barite is practically absent, whereas dolomite is the characteristic gangue mineral. The deposits in these two outer zones are fissure-fillings and comparatively small replacement bodies. They contrast strongly with the sulphide deposits in the heart of the Leadville district and are assigned to the outer mesothermal and epithermal zones. As they have not been described before, general features of these deposits are given in some detail, followed by their relations to the deposits within the Leadville district . Analogies are also drawn with similar deposits in other districts. In the preparation of this paper the authors have been impressed with the confusion that may result from too simple a conception of zoning . For a proper conception of Leadville , the geologist must have sufficient regard for structural conditions, must make due allowance for successive stages of mineral deposition within a small block of ground or even within a single ore shoot, and must also allow for the reactions between minerals formed at an early stage and solutions introduced during a late stage. The effects of such complications in the Leadville district might give the impression that certain minerals found in one of the inner zones were formed at relatively high temperatures, but close study of paragenesis indicates late deposition at relatively low temperatures. Again, as already stated, there is sufficient inconsistency in the distribution of certain varieties of deposits to give a confused impression of zonal arrangement unless the influence of structure on the circulation of ore -forming solutions is appreciated. The field facts give a far more complex picture than might be anticipated from a simple statement of the theory of zoning .

Colorado↗