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At least 919 records · Page 51Linked to original sources

USGS2001

Identification of alkyl dimethylbenzylammonium surfactants in water samples by solid-phase extraction followed by ion trap LC/MS and LC/MS/MS

A novel methodology was developed for the determination of alkyl (C12, C14, and C16) dimethylbenzylammonium chloride (benzalkonium chloride or BAC, Chemical Abstract Service number: 8001-54-5) in water samples. This method is based on solid-phase extraction (SPE) using polymeric cartridges, followed by high-performance liquid chromatography/ion trap mass spectrometry (LC/MS) and tandem mass spectrometry(MS/MS) detection, equipped with an electrospray interface in positive ion mode. Chromatographic separation was achieved for three BAC homologues by using a C18 column and a gradient of acetonitrile/10 millimolar aqueous ammonium formate. Total method recoveries were higher than 71% in different water matrices. The main ions observed by LC/MS were at mass-to-charge ratios (m/z) of 304, 332, and 360, which correspond to the molecular ions of the C12, C14, and C16 alkyl BAC, respectively. The unequivocal structural identification of these compounds in water samples was performed by LC/MS/MS after isolation and subsequent fragmentation of each molecular ion. The main fragmentation observed for the three different homologues corresponded to the loss of the toluyl group in the chemical structure, which leads to the fragment ions at m/z 212, 240, and 268 and a tropylium ion, characteristic of all homologues, at m/z 91. Detection limits for the methodology developed in this work were in the low nanogram-per-liter range. Concentration levels of BAC - ranging from 1.2 to 36.6 micrograms per liter - were found in surface-water samples collected downstream from different wastewater-treatment discharges, thus indicating its input and persistence through the wastewater-treatment process.

Environmental Science & Technology↗

USGS2006

Evaluation of the factors controlling the time-dependent inactivation rate coefficients of bacteriophage MS2 and PRD1

Static and dynamic batch experiments were conducted to study the effects of temperature and the presence of sand on the inactivation of bacteriophage MS2 and PRD1. The experimental data suggested that the inactivation process can be satisfactorily represented by a pseudo-first-order expression with time-dependent rate coefficients. The time-dependent rate coefficients were used to determine pertinent thermodynamic properties required for the analysis of the molecular processes involved in the inactivation of each bacteriophage. A combination of high temperature and the presence of sand appears to produce the greatest disruption to the surrounding protein coat of MS2. However, the lower activation energies for PRD1 indicate a weaker dependence of the inactivation rate on temperature. Instead, the presence of air-liquid and air-solid interfaces appears to produce the greatest damage to specific viral components that are related to infection. These results indicate the importance of using thermodynamic parameters based on the time-dependent inactivation model to better predict the inactivation of viruses in groundwater. ?? 2006 American Chemical Society.

Environmental Science & Technology↗

USGS2007

Geochemical and geophysical examination of submarine groundwater discharge and associated nutrient loading estimates into Lynch Cove, Hood Canal, WA

Geochemical tracer data (i.e., 222 Rn and four naturally occurring Ra isotopes), electromagnetic (EM) seepage meter results, and high-resolution, stationary electrical resistivity images were used to examine the bi-directional (i.e., submarine groundwater discharge and recharge) exchange of a coastal aquifer with seawater. Our study site for these experiments was Lynch Cove, the terminus of Hood Canal, WA, where fjord-like conditions dramatically limit water column circulation that can lead to recurring summer-time hypoxic events. In such a system a precise nutrient budget may be particularly sensitive to groundwater-derived nutrient loading. Shore-perpendicular time-series subsurface resistivity profiles show clear, decimeter-scale tidal modulation of the coastal aquifer in response to large, regional hydraulic gradients, hydrologically transmissive glacial terrain, and large (4-5 m) tidal amplitudes. A 5-day 222 Rn time-series shows a strong inverse covariance between 222 Rn activities (0.5−29 dpm L -1 ) and water level fluctuations, and provides compelling evidence for tidally modulated exchange of groundwater across the sediment/water interface. Mean Rn-derived submarine groundwater discharge (SGD) rates of 85 ± 84 cm d -1 agree closely in the timing and magnitude with EM seepage meter results that showed discharge during low tide and recharge during high tide events. To evaluate the importance of fresh versus saline SGD, Rn-derived SGD rates (as a proxy of total SGD) were compared to excess 226Ra-derived SGD rates (as a proxy for the saline contribution of SGD). The calculated SGD rates, which include a significant (>80%) component of recycled seawater, are used to estimate associated nutrient (NH 4+ , Si, PO 4 3- , NO 3 + NO 2 , TDN) loads to Lynch Cove. The dissolved inorganic nitrogen (DIN = NH 4 + NO 2 + NO 3 ) SGD loading estimate of 5.9 × 10 4 mol d -1 is 1−2 orders of magnitude larger than similar estimates derived from atmospheric deposition and surface water runoff, respectively.

Washington↗

USGS2013

Understanding water column and streambed thermal refugia for endangered mussels in the Delaware River

Groundwater discharge locations along the upper Delaware River, both discrete bank seeps and diffuse streambed upwelling, may create thermal niche environments that benefit the endangered dwarf wedgemussel (Alasmidonta heterodon). We seek to identify whether discrete or diffuse groundwater inflow is the dominant control on refugia. Numerous springs and seeps were identified at all locations where dwarf wedgemussels still can be found. Infrared imagery and custom high spatial resolution fiber-optic distributed temperature sensors reveal complex thermal dynamics at one of the seeps with a relatively stable, cold groundwater plume extending along the streambed/water-column interface during mid-summer. This plume, primarily fed by a discrete bank seep, was shown through analytical and numerical heat-transport modeling to dominate temperature dynamics in the region of potential habitation by the adult dwarf wedgemussel.

Pennsylvania↗

USGS2009

Fate of sulfamethoxazole, 4-nonylphenol, and 17β-estradiol in groundwater contaminated by wastewater treatment plant effluent

Organic wastewater contaminants (OWCs) were measured in samples collected from monitoring wells located along a 4.5-km transect of a plume of groundwater contaminated by 60 years of continuous rapid infiltration disposal of wastewater treatment plant effluent. Fifteen percent of the 212 OWCs analyzed were detected, including the antibiotic sulfamethoxazole (SX), the nonionic surfactant degradation product 4-nonylphenol (NP), the solvent tetrachloroethene (PCE), and the disinfectant 1,4-dichlorobenzene (DCB). Comparison of the 2005 sampling results to data collected from the same wells in 1985 indicates that PCE and DCB are transported more rapidly in the aquifer than NP, consistent with predictions based on compound hydrophobicity. Natural gradient in situ tracer experiments were conducted to evaluate the subsurface behavior of SX, NP, and the female sex hormone 17β-estradiol (E2) in two oxic zones in the aquifer: (1) a downgradient transition zone at the interface between the contamination plume and the overlying uncontaminated groundwater and (2) a contaminated zone located beneath the infiltration beds, which have not been loaded for 10 years. In both zones, breakthrough curves for the conservative tracer bromide (Br − ) and SX were nearly coincident, whereas NP and E2 were retarded relative to Br − and showed mass loss. Retardation was greater in the contaminated zone than in the transition zone. Attenuation of NP and E2 in the aquifer was attributed to biotransformation, and oxic laboratory microcosm experiments using sediments from the transition and contaminated zones show that uniform-ring-labeled 14 C 4-normal-NP was biodegraded more rapidly (30−60% recovered as 14 CO 2 in 13 days) than 4- 14 C E2 (20−90% recovered as 14 CO 2 in 54 days). There was little difference in mineralization potential between sites.

Massachusetts↗

USGS1996

Reactive solute transport in an acidic stream: Experimental pH increase and simulation of controls on pH, aluminum, and iron

Solute transport simulations quantitatively constrained hydrologic and geochemical hypotheses about field observations of a pH modification in an acid mine drainage stream. Carbonate chemistry, the formation of solid phases, and buffering interactions with the stream bed were important factors in explaining the behavior of pH, aluminum, and iron. The precipitation of microcrystalline gibbsite accounted for the behavior of aluminum; precipitation of Fe(OH)3 explained the general pattern of iron solubility. The dynamic experiment revealed limitations on assumptions that reactions were controlled only by equilibrium chemistry. Temporal variation in relative rates of photoreduction and oxidation influenced iron behavior. Kinetic limitations on ferrous iron oxidation and hydrous oxide precipitation and the effects of these limitations on field filtration were evident. Kinetic restraints also characterized interaction between the water column and the stream bed, including sorption and desorption of protons from iron oxides at the sediment-water interface and post-injection dissolution of the precipitated aluminum solid phase.

Environmental Science & Technology↗

USGS2000

Mobilization and transport of soil particles during infiltration experiments in an agricultural field, Shenandoah Valley, Virginia

Evidence that fine particles mobilized and transported in soils and aquifers can have a profound influence on contaminant migration has spawned much interest recently in understanding colloid transport in natural materials. Repeated infiltration experiments on an initially dry field soil were conducted to evaluate rates of mobilization of fine particles over time and to investigate the importance of transient-flow events on particle transport. Water flow was measured in zero-tension lysimeters at 25 cm depth. For repeated infiltration events and for all plots, water flow sharply increased shortly after initial ponding of water at the soil surface, maintained a relatively steady level during the period of ponding, and decreased gradually thereafter. Particle concentrations measured in the pan lysimeters ranged from 7 mg L - 1 to 265 mg L - 1 and were typically on the order of 10 to 100 mg L - 1 . Greatest particle mass flux was observed during the initial infiltration experiment on each plot. During four subsequent infiltration experiments, all conducted within 250 min of the first event, steady mass fluxes were observed that were approximately 70% of the average value seen in the first flush of water through a dry soil, indicating that the supply of mobile soil particles is only sparingly reduced over closely spaced infiltration events. All peak particle concentrations and mass fluxes occurred near either the rising limb or the falling limb of the water flux hydrograph, presumably reflecting the movement of air−water interfaces during imbibition and drainage.

Virginia↗

USGS1998

Optical-cell evidence for superheated ice under gas-hydrate-forming conditions

We previously reported indirect but compelling evidence that fine-grained H 2 O ice under elevated CH 4 gas pressure can persist to temperatures well above its ordinary melting point while slowly reacting to form methane clathrate hydrate. This phenomenon has now been visually verified by duplicating these experiments in an optical cell while observing the very slow hydrate-forming process as the reactants were warmed from 250 to 290 K at methane pressures of 23 to 30 MPa. Limited hydrate growth occurred rapidly after initial exposure of the methane gas to the ice grains at temperatures well within the ice subsolidus region. No evidence for continued growth of the hydrate phase was observed until samples were warmed above the equilibrium H 2 O melting curve. With continued heating, no bulk melting of the ice grains or free liquid water was detected anywhere within the optical cell until hydrate dissociation conditions were reached (292 K at 30 MPa), even though full conversion of the ice grains to hydrate requires 6−8 h at temperatures approaching 290 K. In a separate experimental sequence, unreacted portions of H 2 O ice grains that had persisted to temperatures above their ordinary melting point were successfully induced to melt, without dissociating the coexisting hydrate in the sample tube, by reducing the pressure overstep of the equilibrium phase boundary and thereby reducing the rate of hydrate growth at the ice−hydrate interface. Results from similar tests using CO 2 as the hydrate-forming species demonstrated that this superheating effect is not unique to the CH 4 −H 2 O system.

Journal of Physical Chemistry B↗

USGS1998

The hyporheic zone as a source of dissolved organic carbon and carbon gases to a temperate forested stream

The objective of this study was to examine chemical changes in porewaters that occur over small scales (cm) as groundwater flows through the hyporheic zone and discharges to a stream in a temperate forest of northern Wisconsin. Hyporheic-zone porewaters were sampled at discrete depths of 2, 10, 15, 61, and 183 cm at three study sites in the study basin. Chemical profiles of dissolved organic carbon (DOC), CO2, CH4, and pH show dramatic changes between 61 cm sediment depth and the water-sediment interface. Unless discrete samples at small depth intervals are taken, these chemical profiles are not accounted for. Similar trends were observed at the three study locations, despite each site having very different hydraulic-flow regimes. Increases in DOC concentration by an order of magnitude from 61 to 15 cm depth with a corresponding decrease in pH and rapid decreases in the molecular weight of the DOC suggest that aliphatic compounds (likely organic acids) are being generated in the hyporheic zone. Estimated efflux rates of DOC, CO2, and CH4 to the stream are 6.2, 0.79, 0.13 moles m2 d-1, respectively, with the vast majority of these materials produced in the hyporheic zone. Very little of these materials are accounted for by sampling stream water, suggesting rapid uptake and/or volatilization.

Biogeochemistry↗

USGS1998

Stable carbon and oxygen isotope record of central Lake Erie sediments

Stable carbon and oxygen isotope data from mollusc aragonite extracted from sediment cores provide new information on the origin and history of sedimentation in the southwestern area of the central basin of Lake Erie. Sediments infilling the Sandusky subbasin consist of three lithologic units overlying glacial deposits. The lowest of these is a soft gray mud overlain by a shell hash layer containing Sphaerium striatinum fragments. A fluid mud unit caps the shell hash layer and extends upwards to the sediment-water interface. New stable isotope data suggest that the soft gray mud unit is of postglacial, rather than proglacial, origin. These data also suggest that the shell hash layer was derived from erosional winnowing of the underlying soft gray mud layer. This winnowing event may have occurred as a result of the Nipissing flood. The Pelee-Lorain moraine, which forms the eastern boundary of the Sandusky subbasin, is an elevated area of till capped by a sand deposit that originated as a beach. The presence of both the shell hash layer and relict beach deposit strengthens the interpretation that the Nipissing flood was a critical event in the development of the southwestern area of the central basin of Lake Erie. This event, which returned drainage from the upper lakes to the Lake Erie basin, was a dominant influence on regional stratigraphy, bathymetry, and depositional setting.

Journal of Paleolimnology↗

USGS2002

A 1500-year record of climatic and environmental change in Elk Lake, Clearwater County, Minnesota II: Geochemistry, mineralogy, and stable isotopes

Most of the sediment components that have accumulated in Elk Lake, Clearwater County, northwestern Minnesota, over the past 1500 years are authigenic or biogenic (CaCO3, biogenic SiO2, organic matter, iron and manganese oxyhydroxides, and iron phosphate) and are delivered to the sediment-water interface on a seasonal schedule where they are preserved as distinct annual laminae (varves). The annual biogeochemical cycles of these components are causally linked through the 'carbon pump', and are recapitulated in longer-term cycles, most prominently with a periodicity of about 400 years. Organic carbon is fixed in the epilimnion by photosynthetic removal of CO2, which also increases the pH, triggering the precipitation of CaCO3. The respiration and degradation of fixed organic carbon in the hypolimnion consumes dissolved oxygen, produces CO2, and lowers the pH so that the hypolimnion becomes anoxic and undersaturated with respect to CaCO3 during the summer. Some of the CaCO3 produced in the epilimnion is dissolved in the anoxic, lower pH hypolimnion and sediments. The amount of CaCO3 that is ultimately incorporated into the sediments is a function of how much is produced in the epilimnion and how much is consumed in the hypolimnion and the sediments. Iron, manganese, and phosphate accumulate in the anoxic hypolimnion throughout the summer. Sediment-trap studies show that at fall overturn, when iron-, manganese-, and phosphate-rich bottom waters mix with carbonate- and oxygen-rich surface waters, precipitation of iron and manganese oxyhydroxides, iron phosphate, and manganese carbonate begins and continues into the winter months. Detrital clastic material in the sediments of Elk Lake deposited over the last 1500 years is a minor component (<10% by weight) that is mostly wind-borne (eolian). Detailed analyses of the last 1500 years of the Elk Lake sediment record show distinct cycles in eolian clastic variables (e.g. aluminum, sodium, potassium, titanium, and quartz), with a periodicity of about 400 years. The 400-yr cycle in eolian clastic material does not correspond to the 400-yr cycles in redox-sensitive authigenic components, suggesting that the clastic component is responding to external forcing (wind) whereas the authigenic components are responding to internal forcing (productivity), although both may ultimately be forced by climate change. Variations in the oxygen and carbon isotopic composition of CaCO3 are small but appear to reflect small variations in ground water influx that are also driven by external forcing.

Journal of Paleolimnology↗

USGS1999

Natural attenuation of chlorinated volatile organic compounds in a freshwater tidal wetland: Field evidence of anaerobic biodegradation

Field evidence collected along two groundwater flow paths shows that anaerobic biodegradation naturally attenuates a plume of chlorinated volatile organic compounds as it discharges from an aerobic sand aquifer through wetland sediments. A decrease in concentrations of two parent contaminants, trichloroethylene (TCE) and 1,1,2,2‐tetrachloroethane (PCA), and a concomitant increase in concentrations of anaerobic daughter products occurs along upward flow paths through the wetland sediments. The daughter products 1,2‐dichloroethylene, vinyl chloride, 1,1,2‐trichloroethane, and 1,2‐dichloroethane are produced from hydrogenolysis of TCE and from PCA degradation through hydrogenolysis and dichloroelimination (reductive dechlorination) pathways. Total concentrations of TCE, PCA, and their degradation products, however, decrease to below detection levels within 0.15–0.30 m of land surface. The enhanced reductive dechlorination of TCE and PCA in the wetland sediments is associated with the naturally higher concentrations of dissolved organic carbon and the lower redox state of the groundwater compared to the aquifer. This field study indicates that wetlands and similar organic‐rich environments at groundwater/surface‐water interfaces may be important in intercepting groundwater contaminated with chlorinated organics and in naturally reducing concentrations and toxicity before sensitive surface‐water receptors are reached.

Water Resources Research↗

USGS2001

Unsuccessful initial search for a midmantle chemical boundary with seismic arrays

Compositional layering of the midmantle has been proposed to account for seismic and geochemical patterns [van der Hilst and Karason, 1999], and inferred radiogenic heat source concentrations [Kellogg et al., 1999]. Compositional layering would require thermal boundary layers both above and below an interface. We construct a minimal 1-D model of a mid-mantle boundary consistent with the observed nearly adiabatic compressional velocity structure [Dziewonksi and Anderson, 1981] and the proposed high heat flow from the lower mantle [Albarede and van der Hilst, 1999; Kellogg et al., 1999]. Ray tracing and reflectivity synthetic seismograms show that a distinct triplication is predicted for short-period P waves. Although topography on a boundary would cause uncertainty in the strength and the range of the triplication, many clear observations would be expected. We examine data from the US West Coast regional networks in the most likely distance range of 60?? to 70?? for a 1770-km-depth boundary, and find no evidence for P wave triplications.

Geophysical Research Letters↗

USGS2000

Geochemical evidence for a magmatic CO 2 degassing event at Mammoth Mountain, California, September-December 1997

Recent time series soil CO 2 concentration data from monitoring stations in the vicinity of Mammoth Mountain, California, reveal strong evidence for a magmatic degassing event during the fall of 1997 lasting more than 2 months. Two sensors at Horseshoe Lake first recorded the episode on September 23, 1997, followed 10 days later by a sensor on the north flank of Mammoth Mountain. Direct degassing from shallow intruding magma seems an implausible cause of the degassing event, since the gas released at Horseshoe Lake continued to be cold and barren of other magmatic gases, except for He. We suggest that an increase in compressional strain on the area south of Mammoth Mountain driven by movement of major fault blocks in Long Valley caldera may have triggered an episode of increased degassing by squeezing additional accumulated CO 2 from a shallow gas reservoir to the surface along faults and other structures where it could be detected by the CO 2 monitoring network. Recharge of the gas reservoir by CO 2 emanating from the deep intrusions that probably triggered deep long-period earthquakes may also have contributed to the degassing event. The nature of CO 2 discharge at the soil-air interface is influenced by the porous character of High Sierra soils and by meteorological processes. Solar insolation is the primary source of energy for the Earth atmosphere and plays a significant role in most diurnal processes at the Earth surface. Data from this study suggest that external forcing due largely to local orographic winds influences the fine structure of the recorded CO 2 signals.

California↗

USGS2001

Tectonic erosion and consequent collapse of the Pacific margin of Costa Rica: Combined implications from ODP leg 170, seismic offshore data, and regional geology of the Nicoya Peninsula

The convergent margin off the Pacific coast of the Nicoya Peninsula of Costa Rica exhibits evidence for subduction erosion caused by the underthrusting Cocos plate. Critical evidence for efficacy of this process was recovered at the Ocean Drilling Program (ODP) drilling Site 1042 (Leg 170), positioned ???7 km landward of the Middle America trench axis off the Nicoya Peninsula. The primary drilling objective at this site was to identify the age and origin of a regionally extensive and prominent seismic discontinuity, the so-called base-of-slope sediment (BOSS) horizon or surface. The BOSS horizon, which can be traced landward from near the trench to the Nicoya coastal area and parallel to it for hundreds of kilometers, separates a low-velocity (??? 2.0-2.5 km s-1) sequence of slope sediment, from an underlying sequence of much higher-velocity (> 4-4.5 km s-1) rock. Site 1042 reached the acoustically defined BOSS horizon at a below sea level depth of ??? 3900 m and yielded a carbonate-cemented calcarenitic breccia of early-middle Miocene age. Sedimentological, geochemical, paleontological, and cement paragenesis data document that the breccia accumulated in a shallow water depositional environment. On the basis of coastal exposures, the BOSS horizon, as a margin-wide geologic interface, can be temporally and lithostratigraphically correlated to a regional angular unconformity. This unconformity, known as the Mal Pais unconformity, separates Neogene and younger shelf-to-littoral beds from the underlying mafic units of the Mesozoic Nicoya Complex and Cretaceous and early Tertiary sedimentary sequences. At Site 1042 it is inferred that tectonism caused the vertical subsidence of the early Neogene breccia from a shallow to a deep water setting. The Mal Pais unconformity of the BOSS horizon thus connects the rock fabric of the outermost part of margin to that of coastal Nicoya and implies that in the early Neogene the Nicoya shelf extended seaward to near the present trench axis. This circumstance requires that the early Neogene trench axis was at least 50 km seaward of where it is now located. The long-term effects of subduction erosion, similar to those described for the scientifically drilled Japan, Tonga, and Peru margins, best account for offshore and onshore evidence for a post-Paleogene history of crustal thinning and landward trench migration of Costa Rica's Pacific margin. During the past 16-17 Myr the calculated mass removal and landward migration rates are 34-36 km3 Myr-1 km-1 of margin, and 3 km Myr-1, respectively. These values are similar to those found for other Pacific margins dominated by nonaccretionary subduction zone processes.

Tectonics↗

USGS2003

The crustal structure from the Altai Mountains to the Altyn Tagh fault, northwest China

[1] We present a new crustal section across northwest China based on a seismic refraction profile and geologic mapping. The 1100‐km‐long section crosses the southern margin of the Chinese Altai Mountains, Junggar Accretional Belt and eastern Junggar basin, easternmost Tianshan Mountains, and easternmost Tarim basin. The crustal velocity structure and Poisson's ratio (σ), which provide a constraint on crustal composition, were determined from P and S wave data. Despite the complex geology, the crustal thickness along the entire profile is nearly uniform at 50 km. The thickest crust (56 km) occurs at the northern end of the profile beneath the Altai Mountains and the thinnest (46 km) crust is beneath the Junggar basin. Beneath surficial sediments, the crust is found to have three layers with P wave velocities ( V p ) of 6.0–6.3, 6.3–6.6, and 6.9–7.0 km/s, respectively. The southern half of the profile, including the eastern Tianshan Mountains and eastern margin of the Tarim basin, shows low P wave velocities and σ = 0.25 to a depth of 30 km, which suggests a quartz‐rich, granitic upper crustal composition. The northern half of the profile below the Altai Mountains and Junggar Accretional Belt has a higher Poisson's ratio of σ = 0.26–0.27 to a depth of 30 km, indicative of an intermediate crustal composition. The entire 1100‐km‐long profile is underlain by a 15–30 km thick high velocity (6.9–7.0 km/s; σ = 0.26–0.28) lower‐crustal layer that we interpret to have a bulk composition of mafic granulite. At the southern end of the profile, a 5‐km‐thick midcrustal low‐velocity layer ( V p = 5.9 km/s, σ = 0.25) underlies the Tianshan and the region to the south, and may be indicative of a near‐horizontal detachment interface. P n velocities are ∼7.7–7.8 km/s between the Tianshan and the Junggar basin, and ∼7.9–8.0 km/s below the Altai Mountains and eastern margin of the Tarim basin. We interpret the consistent three‐layer stratification of the crust to indicate that the crust has undergone partial melting and differentiation after Paleozoic terrane accretion. The thickness (50 km) of the crust appears to be related to compression resulting from the Indo‐Asian collision.

Altai Mountains↗

USGS2003

Finite element model predictions of static deformation from dislocation sources in a subduction zone: Sensitivities to homogeneous, isotropic, Poisson-solid, and half-space assumptions

Dislocation models can simulate static deformation caused by slip along a fault. These models usually take the form of a dislocation embedded in a homogeneous, isotropic, Poisson-solid half-space (HIPSHS). However, the widely accepted HIPSHS assumptions poorly approximate subduction zone systems of converging oceanic and continental crust. This study uses three-dimensional finite element models (FEMs) that allow for any combination (including none) of the HIPSHS assumptions to compute synthetic Green's functions for displacement. Using the 1995 Mw = 8.0 Jalisco-Colima, Mexico, subduction zone earthquake and associated measurements from a nearby GPS array as an example, FEM-generated synthetic Green's functions are combined with standard linear inverse methods to estimate dislocation distributions along the subduction interface. Loading a forward HIPSHS model with dislocation distributions, estimated from FEMs that sequentially relax the HIPSHS assumptions, yields the sensitivity of predicted displacements to each of the HIPSHS assumptions. For the subduction zone models tested and the specific field situation considered, sensitivities to the individual Poisson-solid, isotropy, and homogeneity assumptions can be substantially greater than GPS. measurement uncertainties. Forward modeling quantifies stress coupling between the Mw = 8.0 earthquake and a nearby Mw = 6.3 earthquake that occurred 63 days later. Coulomb stress changes predicted from static HIPSHS models cannot account for the 63-day lag time between events. Alternatively, an FEM that includes a poroelastic oceanic crust, which allows for postseismic pore fluid pressure recovery, can account for the lag time. The pore fluid pressure recovery rate puts an upper limit of 10-17 m2 on the bulk permeability of the oceanic crust. Copyright 2003 by the American Geophysical Union.

Journal of Geophysical Research B: Solid Earth↗

USGS2011

Discussions of ODP Leg 205 and drilling of Middle America Seismogenic Zone

Erosional convergent margins, where material is removed from the base of the upper plate and subducted on the lower plate, are fundamental features of the Circum Pacific. The erosional Middle America Trench convergent Pacific margin, remarkable for its broad diversity of dynamic environments, is a natural laboratory for studying convergent margin processes and seismogenesis. These environments include a shallow and deep trench axis, shallow-to-steep-dipping plate interfaces, abnormally hot-to-cold subducting plate temperatures, and a subducting plate with smooth morphology bordering basement ridges and seamounts. The subducting topography accelerates erosion and localizes seismicity.

Middle America Trench, Pacific Ocean↗