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The dominance and growth of shallow groundwater resources in continuous permafrost environments

Water is a limited resource in Arctic watersheds with continuous permafrost because freezing conditions in winter and the impermeability of permafrost limit storage and connectivity between surface water and deep groundwater. However, groundwater can still be an important source of surface water in such settings, feeding springs and large aufeis fields that are abundant in cold regions and generating runoff when precipitation is rare. Whether groundwater is sourced from suprapermafrost taliks or deeper regional aquifers will impact water availability as the Arctic continues to warm and thaw. Previous research is ambiguous about the role of deep groundwater, leading to uncertainty regarding Arctic water availability and changing water resources. We analyzed chemistry and residence times of spring, stream, and river waters in the continuous permafrost zone of Alaska, spanning the mountains to the coastal plain. Water chemistry and age tracers show that surface waters are predominately sourced from recent precipitation and have short (<50 y) subsurface residence times. Remote sensing indicates trends in the areal extent of aufeis over the last 37 y, and correlations between aufeis extent and previous year summer temperature. Together, these data indicate that surface waters in continuous permafrost regions may be impacted by short flow paths and shallow suprapermafrost aquifers that are highly sensitive to climatic and hydrologic change over annual timescales. Despite the lack of connection to regional aquifers, continued warming and permafrost thaw may promote deepening of the shallow subsurface aquifers and creation of shallow taliks, providing some resilience to Arctic freshwater ecosystems.

Proceedings of the National Academy of Sciences

Volcanic gas monitoring

Introduction As magma rises through the crust, decreasing pressure conditions allow volatiles to exsolve from the magma. These volatiles then migrate upward through the crust, where they can be stored at shallower levels or escape to the atmosphere. Rising magma also heats rock masses beneath volcanic centers, causing water in shallow aquifers and hydrothermal systems to boil and release additional gases and steam (see chapter F , this volume; Ingebritsen and Hurwitz, 2024). The chemistry and quantity of gases that reach the surface during periods of quiescence or volcanic unrest can reveal that gas-rich magma is ascending, crystallizing, or alternatively stalling, with important implications for volcanic hazard (for example, Sutton and others, 1992; Aiuppa and others, 2007, 2021; Werner and others, 2009, 2011, 2012; Moretti and others, 2013; de Moor and others, 2016; Lewicki and others, 2019; Edmonds and others, 2022; Kern and others, 2022; Kunrat and others, 2022). Most volcanoes in Alaska and the western United States are characterized by weak degassing, with one or more low-temperature fumaroles (typically near the local boiling temperature of water) and connect to a deeper and sometimes extensive hydrothermal system (for example, McGee and others, 2001; Symonds and others, 2003a, b). Hydrothermal systems will affect the chemistry of rising gases exsolved from deeper magma (Symonds and others, 2001), including sulfur dioxide (SO 2 ), hydrogen chloride (HCl), and water vapor (for example, Doukas and Gerlach, 1995; Gerlach and others, 1998, 2008; Symonds and others, 2001; Werner and others, 2013). As an example, depending on factors such as temperature, pressure, and oxidation state, rising SO 2 will react with groundwater to form hydrogen sulfide (H 2 S) gas, dissolved sulfate (SO 4 2− ), or elemental sulfur (Christenson, 2000; Symonds and others, 2001; Werner and others, 2008). The reaction and dissolution of SO 2 into shallow groundwater is commonly referred to as scrubbing, and can reduce the likelihood that ascending, degassing magma can be detected. Carbon dioxide, however, in addition to exsolving from magma early in the ascent process, is not easily removed by hydrothermal fluids (Lowenstern, 2001). As scrubbing and other processes take place, the SO 2 /H 2 S, CO 2 /SO 2 , and CO 2 /H 2 S ratios may change. High rates of SO 2 emission indicate that magma has moved to relatively shallow levels in the volcano and that the system has heated up enough to establish dry pathways from depth to the surface. Monitoring multiple gas species and the total output of those species is thereby useful for volcano monitoring during both periods of quiescence, to establish background degassing conditions, and during unrest, when gas geochemistry and emission rates can provide information on changing conditions, such as magma ascent. To provide context for multidisciplinary volcano forecasts, we focus on the following two key required capabilities: (1) characterizing baseline geochemistry and gas discharge from volcanoes and volcanic regions and (2) monitoring changes in gas geochemistry and discharge to inform forecasts of volcanic eruptions and their effects. Sufficient baseline data must be collected to identify and interpret anomalous degassing associated with volcanic unrest (for example, Sorey and others, 1998; Rouwet and others, 2014). Differences in volcano type, baseline degassing rates, local hydrology, and geography (for example, high versus low latitude) will result in a different baseline for each volcano. Volcanoes of any threat level that exhibit one or more degassing phenomena would ideally be monitored by techniques needed to establish baseline degassing data, with the sampling frequency of baseline data dictated by the threat level (table E1). Additional monitoring techniques become necessary during periods of unrest. In general, three of the most important techniques for gas monitoring are (1) direct sampling of fumarole, spring, and soil gases for laboratory geochemical measurements, (2) measurements of the chemical composition of the volcanic plume and emission rates of major gas species (for example, H 2 O, CO 2 , SO 2 , and H 2 S) by satellite, airborne, or ground-based techniques, and (3) measurements of diffuse emissions of CO 2 and other gases through soils. Various methods and instruments may be useful both for baseline studies and during unrest.

Scientific Investigations Report

Apatite and monazite geochemistry record magmatic and metasomatic processes in rare earth element mineralization at Mountain Pass, California

The largest rare earth element (REE) deposit in the United States is a carbonatite intrusion at Mountain Pass in the Mojave Desert, California. Despite a clear spatiotemporal association of alkaline silicate and carbonatite intrusions at Mountain Pass, a genetic model of their mutual formation has not been resolved. The Mountain Pass carbonatite has long been upheld as an example of a primary magmatic body, but recent work has suggested it could be fluid-derived. This study investigates the geochemistry of apatite and monazite grains from the alkaline silicate and carbonatite stocks and dikes of the Mountain Pass district, to elucidate the magmatic history of the intrusive suite and identify the role of fluids in rare earth element mineralization. Three apatite populations are identified in the alkaline silicate rocks. A primary magmatic apatite group supports intrusion of the stocks as separate pulses of magma derived from a spatially extensive metasomatized mantle source region. The second group implicates the role of a regional fluid that mobilized light rare earth elements from apatite grains. A minor group of inherited apatite cores, identified by low Sr and negative Eu anomalies, supports assimilation of crustal material in the formation of the intrusive suite. Analyses of monazite and apatite grains from the carbonatite orebody also reveal a mix of primary magmatic and metasomatic (fluid-related) minerals. Compositional similarities between primary phosphates in the carbonatite and alkaline silicate rocks support a genetic link between the intrusive suites. The presence of fluids regionally and within the carbonatite orebody indicates the Mountain Pass carbonatite should not be classified as a purely magmatic REE deposit.

Arizona, California, Nevada

Mapping karst groundwater flow paths and delineating recharge areas for springs in the Little Sequatchie and Pryor Cove watersheds, Tennessee

The Little Sequatchie River and Pryor Cove Branch, in southern Tennessee, drain the eastern escarpment of the Cumberland Plateau to the Sequatchie River near the southern end of the Sequatchie Valley. The Little Sequatchie River is the largest tributary to the Sequatchie River by drainage area, covering over 120 square miles. The hydrology of the two drainage areas has been largely altered by karst processes, which has caused the majority of the streams to sink at the contact between the Mississippian Pennington Formation and the underlying Mississippian Bangor Limestone. The U.S. Geological Survey, in cooperation with the U.S. Fish and Wildlife Service and Tennessee Department of Environment and Conservation, initiated a study in 2021 to map the karst groundwater pathways in both watersheds in order to delineate recharge areas for several springs. One of these springs, Sequatchie Cave, represents a significant habitat for two Species of Greatest Conservation Need, the Glyphopsyche sequatchie (Sequatchie caddisfly) and the federally endangered Marstonia ogmorhaphe (royal marstonia). Springs and springflow-dominated streams in the Little Sequatchie River valley and Pryor Cove also provide water for agricultural practices and serve as a drinking water source for nearby communities. During the study, a total of 25 dye injections were conducted over eight rounds from January 2022 through March 2023. Dye traces from these injections helped to delineate recharge areas for six major springs, ranging from 7.3 to 65.2 square miles in area. The majority of the dye traces remained subsurface (from sinkpoint to recovery site) for long distances, with karst groundwater travelling nearly 8 miles before resurfacing. The dye traces also had rapid traveltimes, often travelling hundreds to thousands of feet per hour. The goal of this project was to provide scientific data related to karst groundwater pathways and spring recharge areas to aid State and Federal agencies in making informed decisions to protect and preserve this unique and vulnerable karst system.

Tennessee

Thick- and thin-skinned contractional styles and the tectonic evolution of the northern Sangre de Cristo Mountains, Colorado, USA

The Sangre de Cristo Mountains of southern Colorado and northern New Mexico, USA, contain an unusual combination of thick- and thin-skinned contractional structures involving both basement and cover rocks in the Laramide Rocky Mountain foreland. These structures are truncated by down-faulted extensional basins to the east and west. Together with synorogenic sediments, these structures preserve a record of the rise of the Ancestral Rocky Mountains, the Laramide orogeny, and Rio Grande rifting. Laramide structures within the mountains provide clues to processes that link the three events and to necessary conditions for thin-skinned and thick-skinned contractional structures to form together in continental interiors. To examine the full variety of structural styles, a portion of the northern Sangre de Cristo fold- and-thrust belt in Colorado was described and interpreted using geologic maps and structural cross-sections. Stratigraphic relations of the Ancestral Rocky Mountain highlands and basin fill were reconstructed from existing maps. These relations allow identification of faults inherited from the Ancestral Rocky Mountains, differentiation of thrust sheets, and in some cases, estimation of the magnitude of displacement. To examine relations between Laramide thrusts and Rio Grande rifting, kinematic data were collected from a thrust fault adjacent to rift faults. Three thrust fault styles were recognized: thin-skinned basement, thin-skinned cover rocks, and thick-skinned basement. Thin-skinned thrusts arising from a hinterland beneath the present San Luis Valley carried sheets of Proterozoic basement rocks northeast over a Laramide foreland. These basement thrusts are interpreted to be faults of the Ancestral Rocky Mountains that reactivated during the Laramide orogeny. The Laramide foreland consists of thin-skinned thrusts and folds in sedimentary cover rocks as young as 49 Ma. Both thin-skinned thrusts in basement and cover rocks are bounded by thick-skinned basement thrusts that moved intermittently throughout the Laramide orogeny. We infer that thin-skinned thrusts form in continental interiors where deformation is focused in weak strata of thick basin fill and in fluid-reaction weakened preexisting faults in basement rocks. Both conditions are met in the Sangre de Cristo Mountains. Basement thrusts adjacent to the San Luis Valley contain evidence of plastic contractional microstructures overprinted by extensional microstructures that may record the transition from Laramide contraction to Rio Grande extension of the crust.

Colorado

The mineral chemistry networks of tin and tungsten reflect metallogenic eras of the Mesozoic

Continental remobilization is a crucial driver of metallogenesis and the formation of ore deposits. Some of the world’s largest mineral deposits of the economically valuable elements tin (Sn), tungsten (W), gold (Au), copper (Cu), lead (Pb), and zinc (Zn) formed during the Mesozoic Era. Additionally, the chemistry and distribution of the elements Sn and W have been investigated in previous studies to understand planetary formation and differentiation processes. These two elements are largely co-located during certain South China Mesozoic metallogenic events but are not co-located during other time periods in the same regions. Here, we investigated the mineral chemistry network similarities and dissimilarities of Sn and W to understand their mineral formation and distribution during the Mesozoic Era and throughout Earth history. Mineral chemistry network community detection analysis and electronegativity associations among mineral constituent elements of Sn minerals and W minerals indicate that the elements have similar chemistry among their oxide minerals. However, Sn forms a much wider range of minerals that also contain S compared to W, which occurs in a limited number of S-containing minerals. The divergent constituent element interactions among S-containing Sn minerals and W minerals reflect the redox sensitivity and importance of oxygen (O) fugacity in Sn mineral formation. Conversely, extensive W mineral deposits are known to form at both high and low O fugacities. The similarities and differences between the mineral chemistry networks of Sn and W reflect the mineral distribution of the two elements in the Sn-W mineralization event from 160 to 139 Ma vs. the Sn–uranium (U) mineralization event from 125 to 98 million years ago (Ma). The mineral chemistry and distribution of Mesozoic Sn and W deposits illustrate the contrasting importance of redox and O fugacity on the mineral formation of different elements, and the dynamic crustal evolution that took place during this period of Earth history.

Geosciences

Resurvey of the Marble Canyon and Bridge Canyon dam sites in Grand Canyon National Park—Changes in sediment storage and evidence supporting the occurrence of bedrock incision through the mid-20th century

The Bureau of Reclamation developed an extensive plan for a network of dams, water tunnels, and hydropower plants in and around Grand Canyon, Arizona, in the 1940s through 1960s. The two largest of these planned dams were the Marble Canyon and Bridge Canyon Dams on the Colorado River. Though these dams were ultimately never built, Reclamation conducted extensive topographic, bathymetric, and subsurface exploration work at the sites proposed for these dams in the 1940s and 1950s. Resurveys of these dam sites were conducted between 1998 and 2021 to determine the changes in sediment storage at these dam sites caused by the upstream construction and operation of Glen Canyon Dam and by the recession of Lake Mead, the reservoir impounded by Hoover Dam. The resurveys of the Marble Canyon dam sites indicate that the post-1950s changes in sediment storage at these dam sites are broadly consistent with flux-based estimates of voluminous sand erosion from Marble Canyon since the 1963 closure of Glen Canyon Dam. These resurveys also suggest that the pre-dam longitudinal variation in sediment thickness over bedrock played a key role in determining the locations of the sand erosion induced by Glen Canyon Dam; more sand eroded from locations where more sand was present in the 1950s. The resurvey of the Bridge Canyon dam sites indicates that the Colorado River’s incision of the Lake Mead delta is regulated both by bed-sediment grain size and downstream hydraulic controls. Finally, analyses of bed-sediment thickness and sedimentological data at the dam sites, and observations of bed scour and gravel transport, suggest that sufficient bedrock was exposed to allow bedrock incision during commonly recurring pre-dam snowmelt floods that entrained small boulders into transport.

Arizona

Hydrogeologic framework and conceptual groundwater-flow model of the panhandle and northwest parts of the High Plains (Ogallala) aquifer in Oklahoma, 1998–2022

This study was conducted by the U.S. Geological Survey, in cooperation with the Oklahoma Water Resources Board, to update the hydrogeologic framework and conceptual flow model for the panhandle and northwest parts of the High Plains (Ogallala) aquifer in Oklahoma, which together compose the Ogallala aquifer focus area. The study included the construction of a potentiometric surface, and available geologic and hydrologic data were used to evaluate saturated thickness of the aquifer. The water budget for the updated conceptual groundwater-​flow model was based on estimated inflows and outflows for the 1998–2022 study period. Saturated thickness of the Ogallala aquifer averaged 127 and 116 feet for the panhandle and northwest parts, respectively. Groundwater withdrawals from the Ogallala aquifer for 1998–2022 averaged 422,054 and 39,645 acre-feet per year (acre-ft/yr) for the panhandle and northwest parts, respectively. Recharge, the primary inflow, was estimated at 0.63 inch per year for the 1998–2022 study period, with the panhandle part of the Ogallala aquifer receiving 175,068 acre-ft/yr and the northwest part of the Ogallala aquifer receiving 49,376 acre-ft/yr. Additional inflows included irrigation return flows, estimated at 8,111 and 642 acre-ft/yr for the panhandle and northwest parts, respectively, of the Ogallala aquifer. Net lateral groundwater flows, considered to be aquifer outflows, were estimated to account for 31,908 acre-ft/yr for the Ogallala aquifer focus area. Streambed seepage, which was an outflow of 5,535 acre-ft/yr, was only present in the northwest part of the Ogallala aquifer. Vertical leakage and saturated-zone evapotranspiration were considered negligible outflows. These findings provide a revised conceptual groundwater-flow model water budget for the Ogallala aquifer focus area in Oklahoma.

Colorado, Kansas, Oklahoma, Texas

Slope Unit Maker (SUMak): An efficient and parameter-free algorithm for delineating slope units to improve landslide modeling

Slope units are terrain partitions bounded by drainage and divide lines. In landslide modeling, including susceptibility modeling and event-specific modeling of landslide occurrence, slope units provide several advantages over gridded units, such as better capturing terrain geometry, improved incorporation of geospatial landslide-occurrence data in different formats (e.g., point and polygon), and better accommodating the varying data accuracy and precision in landslide inventories. However, the use of slope units in regional ( > 100 km 2 ) landslide studies remains limited due, in part, to the large computational costs and/or poor reproducibility with current delineation methods. We introduce a computationally efficient algorithm for the parameter-free delineation of slope units that leverages tools from within TauDEM and GRASS, using an R interface. The algorithm uses geomorphic laws to define the appropriate scaling of the slope units representative of hillslope processes, avoiding the often ambiguous determination of slope unit size. We then demonstrate how slope units enable more robust regional-scale landslide susceptibility and event-specific landslide occurrence maps.

Natural Hazards and Earth Systems Sciences (NHESS)

Magnetic storms and geoelectric hazards

Magnetic storms induce geoelectric fields at Earth's surface that can interfere with grounded long-line systems. The September 1859 storm disrupted global telegraph operations, the March 1989 storm caused a blackout in Canada and interfered with electric-power-transmission systems in the United States, and other storms have had related impacts. The geographic and temporal dependence of geoelectric fields are functions of both geomagnetic variation and local surface impedance, which differ considerably across different geological regions. These dependencies can be mapped across the contiguous United States by combining magnetotelluric impedance tensors with ground magnetometer time series. This review illustrates such mapping for the 1989 storm and shows that power-system interference was experienced where surface impedance is high, and when and where geoelectric fields were intense. Statistical analyses indicate that storms comparable to that of March 1989 occur roughly once every four solar cycles. Ongoing developments in numerical modeling and real-time monitoring are anticipated to enable prediction of geoelectric hazards. ▪ Magnetic storms can induced electric fields in the solid Earth that interfere with electric-power-transmission systems. ▪ Geoelectric hazards depend on the storm-time geomagnetic disturbance and the electrical conductivity structure of Earth. ▪ Historically, impacts on telecommunication and power-transmission systems in the United States have been concentrated in the East and Midwest. ▪ The future occurrence of a magnetic superstorm could cause widespread disruption of electric-power-transmission systems.

Annual Review of Earth and Planetary Sciences

Techniques for simulating flood hydrographs and estimating flood volumes for ungaged basins in east and west Tennessee

A dimensionless hydrograph developed for a variety of basin conditions in Georgia was tested for its applicability to streams in East and West Tennessee by comparing it to a similar dimensionless hydrograph developed for streams in East and West Tennessee. Hydrographs of observed discharge at 83 streams in East Tennessee and 38 in West Tennessee were used in the study. Statistical analyses were performed by comparing simulated (or computed) hydrographs, derived by application of the Georgia dimensionless hydrograph, and dimensionless hydrographs developed from Tennessee data, with the observed hydrographs at 50 and 75% of their peak-flow widths. Results of the tests indicate that the Georgia dimensionless hydrography is virtually the same as the one developed for streams in East Tennessee, but that it is different from the dimensionless hydrograph developed for streams in West Tennessee. Because of the extensive testing of the Georgia dimensionless hydrograph, it was determined to be applicable for East Tennessee, whereas the dimensionless hydrograph developed from data on streams in West Tennessee was determined to be applicable in West Tennessee. As part of the dimensionless hydrograph development, an average lagtime in hours for each study basin, and the volume in inches of flood runoff for each flood event were computed. By use of multiple-regression analysis, equations were developed that relate basin lagtime to drainage area size, basin length, and percent impervious area. Similarly, flood volumes were related to drainage area size, peak discharge, and basin lagtime. These equations, along with the appropriate dimensionless hydrograph, can be used to estimate a typical (average) flood hydrograph and volume for recurrence-intervals up to 100 years at any ungaged site draining less than 50 sq mi in East and West Tennessee.

Tennessee

Map of topographic lineaments interpreted as recent surface ruptures along the Bennett Valley and Southern Maacama Fault Zones, Sonoma County, California

This study documents lidar-illuminated topographic lineaments interpreted as evidence of recent surface fault ruptures and surface ruptures related to distributed deformation along the Bennett Valley Fault Zone and the southernmost Maacama Fault Zone in the northern San Francisco Bay area (fig. 1, on map sheet). Together, these fault zones form a structural connection across a right stepover between the main Maacama Fault Zone and the Rodgers Creek Fault, overlapping principal strands of the San Andreas plate boundary system north of San Francisco Bay (figs. 1, 2, on map sheet) that accommodate about a quarter of the ~40 millimeters per year of regional dextral tectonic slip (Parsons and others, 2013). Although much of the Bennett Valley Fault Zone is seismically active (McLaughlin and others, 2012; Sowers and others, 2010), only the north end of the fault zone (the “Spring Valley strand,” indicated on southern map panel of map sheet and labeled “D” in figure 2, on map sheet) was previously known to have youthful geomorphic expression and to displace Holocene deposits (McLaughlin and others, 2008; Sowers and others, 2010; Sowers and others, 2016). Holocene activity along the length of the Bennett Valley Fault Zone and southernmost Maacama Fault Zone, with possible implications for rupture propagation, continuity, and slip transfer, had not been identified. However, fault splays that project eastward from the Rodgers Creek Fault have been mapped and hypothesized to accommodate slip transfer to the Bennett Valley Fault Zone (Hecker and Randolph Loar, 2018). The generally subtle and distributed nature of surface-rupture evidence along the Bennett Valley and southernmost Maacama Fault Zones, and extensive vegetation cover, had left recent faulting previously unmapped along most of the zone. The map presented here represents a new compilation of inferred surface-rupture features detected using high-resolution topographic lidar data from an airborne lidar survey of Sonoma County, California (OpenTopography, 2014). These data, which enable subtle topographic features to be discerned, indicate that recent (likely Holocene) surface ruptures extend throughout the Bennett Valley and southernmost Maacama Fault Zones. The rupture-lineament map was created using a GIS (geographic information system) framework and is included herein as an image map at a scale of 1:36,000 and as digital datasets (included as supplemental information to this report). The mapping is intended to lay the groundwork for future studies designed to better characterize how plate-boundary slip is accommodated on this important and complex system of faults.

California

Anaerobic biodegradation of perfluorooctane sulfonate (PFOS) and microbial community composition in soil amended with a dechlorinating culture and chlorinated solvents

Perfluorooctane sulfonate (PFOS), one of the most frequently detected per - and polyfluoroalkyl substances (PFAS) occurring in soil, surface water, and groundwater near sites contaminated with aqueous film-forming foam (AFFF), has proven to be recalcitrant to many destructive remedies, including chemical oxidation. We investigated the potential to utilize microbially mediated reduction (bioreduction) to degrade PFOS and other PFAS through addition of a known dehalogenating culture, WBC-2, to soil obtained from an AFFF-contaminated site. A substantial decrease in total mass of PFOS (soil and water) was observed in microcosms amended with WBC-2 and chlorinated volatile organic compound (cVOC) co-contaminants — 46.4 ± 11.0 % removal of PFOS over the 45-day experiment. In contrast, perfluorooctanoate (PFOA) and 6:2 fluorotelomer sulfonate (6:2 FTS) concentrations did not decrease in the same microcosms. The low or non-detectable concentrations of potential metabolites in full PFAS analyses, including after application of the total oxidizable precursor assay, indicated that defluorination occurred to non-fluorinated compounds or ultrashort-chain PFAS. Nevertheless, additional research on the metabolites and degradation pathways is needed. Population abundances of known dehalorespirers did not change with PFOS removal during the experiment, making their association with PFOS removal unclear. An increased abundance of sulfate reducers in the genus Desulfosporosinus (Firmicutes) and Sulfurospirillum (Campilobacterota) was observed with PFOS removal, most likely linked to initiation of biodegradation by desulfonation. These results have important implications for development of in situ bioremediation methods for PFAS and advancing knowledge of natural attenuation processes.

Science of the Total Environment

Neogene hydrothermal Fe- and Mn-oxide mineralization of Paleozoic continental rocks, Amerasia Basin, Arctic Ocean

Rocks dredged from water depths of 1,605, 2,500, 3,300, and 3,400 m in the Arctic Ocean included Paleozoic continental rocks pervasively mineralized during the Neogene by hydrothermal Fe and Mn oxides. Samples were recovered in three dredge hauls from the Chukchi Borderland and one from Mendeleev Ridge north of Alaska and eastern Siberia, respectively. Many of the rocks were so pervasively altered that the protolith could not be identified, while others had volcanic, plutonic, and metamorphic protoliths. The mineralized rocks were cemented and partly to wholly replaced by the hydrothermal oxides. The Amerasia Basin, where the Chukchi Borderland and Mendeleev Ridge occur, supports a series of faults and fractures that serve as major zones of crustal weakness. We propose that the stratabound hydrothermal deposits formed through the flux of hydrothermal fluids along Paleozoic and Mesozoic faults related to block faulting along a rifted margin during minor episodes of Neogene tectonism and were later exposed at the seafloor through slumping or other gravity processes. Tectonically driven hydrothermal circulation most likely facilitated the pervasive mineralization along fault surfaces via frictional heating, hydrofracturing brecciation, and low- to moderate temperature Fe- and Mn-rich hydrothermal fluids, which mineralized the crushed, altered, and brecciated rocks.

Geochemistry, Geophysics, Geosystems

Determination of baseline water-quality conditions using continuous specific conductance and discrete measurements of total dissolved solids and selected major ions, Arkansas River Basin, Colorado

From 2022 through 2024, the U.S. Geological Survey (USGS) in cooperation with the Regional Resources Planning Group (Southeastern Colorado Water Conservancy District, Colorado Springs Utilities, Pueblo Water, Lower Arkansas Valley Water Conservancy District, Aurora Water, and Upper Arkansas Water Conservancy District) established a basinwide water-quality monitoring network in the Arkansas River Basin in Colorado. The study leveraged ongoing continuous measurements of streamflow and specific conductance (SC) at 13 sites along the main stem Arkansas River and Fountain Creek from the USGS 07108600 Arkansas River at Granite, Colo., (Ark Granite) site to the USGS 07137500 Arkansas River near Coolidge, Kansas, (Ark Coolidge) site. Baseline water-quality conditions were established using data from October 1989 through September 2022 to help identify changes in water quality that could result from changes in land and water use. Total dissolved solids (TDS) concentration was the main indicator of general water quality in this study because it can be accurately estimated from SC and is sensitive to changes in streamflow, water operations, and source contributions. Median TDS concentrations in Arkansas River samples (October 1989 through December 2023) ranged from 75 milligrams per liter (mg/L) at Ark Granite near the headwaters to 3,660 mg/L at Ark Coolidge near the Colorado–Kansas State line. Distinct seasonal differences in median streamflow and TDS were apparent during the winter and summer months. Seasonal Kendall tests showed no significant trends in monthly mean streamflow (October 1995 through September 2022) at Arkansas River sites upstream from Pueblo Reservoir. Upward trends in TDS concentrations and loads occurred only at Ark Granite. Downward trends in streamflow, TDS concentrations, and TDS loads occurred at Arkansas River sites from USGS 07109500 Arkansas River near Avondale, Colo., to Ark Coolidge. Downward trends in streamflow and SC (surrogate for TDS) were more prevalent during winter base flow months and may indicate changes in groundwater quantity, and possibly groundwater quality, potentially affecting the river water-quality condition.

Colorado

Water, ice, meteorological, and speed measurements at South Cascade Glacier, Washington, 1999 balance year

Winter snow accumulation and summer snow, firn, and ice melt were measured at South Cascade Glacier, Washington, to determine the winter and net balances for the 1999 balance year. The 1999 winter snow balance, averaged over the glacier, was 3.59 meters, and the net balance was 1.02 meters. Since the winter balance record began in 1959, only three winters have had a higher winter balance. Since the net balance record began in 1953, only 2 years have had a greater positive net balance than 1999. Runoff was measured from the glacier and an adjacent non-glacierized basin. Air temperature, precipitation, and humidity were measured nearby, and ice speed was measured. This report makes these data available to the glaciological and climatological community.

Washington