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At least 919 records · Page 51Linked to original sources
USGS1996

Analysis and simulation of ground-water flow in Lake Wales Ridge and adjacent areas of central Florida

The Lake Wales Ridge is an uplands recharge area in central Florida that contains many sinkhole lakes. Below-normal rainfall and increased pumping of ground water have resulted in declines both in ground-water levels and in the water levels of many of the ridge lakes. A digital flow model was developed for a 3,526 square-mile area to help understand the current (1990) ground-water flow system and its response to future ground-water withdrawals. The ground-water flow system in the Lake Wales Ridge and adjacent area of central Florida consists of a sequence of sedimentary aquifers and confining units. The uppermost water-bearing unit of the study area is the surficial aquifer. This aquifer is generally unconfined and is composed primarily of clastic deposits. The surficial aquifer is underlain by the confined intermediate aquifer and confining units which consists of up to three water-bearing units composed of interbedded clastics and carbonate rocks. The lowermost unit of the ground- water flow system, the confined Upper Floridan aquifer, consists of a thick, hydraulically connected sequence of carbonate rocks. The Upper Floridan aquifer is about 1,200 to 1,400 feet thick and is the primary source for ground-water withdrawals in the study area. The generalized ground-water flow system of the Lake Wales Ridge is that water moves downward from the surficial aquifer to the intermediate aquifer and the Upper Floridan aquifer in the central area, primarily under the ridges, with minor amounts of water flow under the flatlands. The water flows laterally away from the central area, downgradient to discharge areas to the west, east, and south, and locally along valleys of major streams. Upward leakage occurs along valleys of major streams. The model was initially calibrated to the steady-state conditions representing September 1989. The resulting calibrated hydrologic parameters were then tested by simulating transient conditions for the period October 1989 through 1990. A final test of model calibration was conducted by successfully simulating transient conditions for the period October 1988 through September 1989. Altitudes of the water table, base of the surficial aquifer, riverbed conductances, confining-unit leakances, aquifer transmissivities, and net recharge and discharge rates were determine during calibration. Steady-state and transient simulations reasonably approximated measured aquifer heads and lake levels. Residuals were within the established calibration criteria that required 68 percent of all simulated heads to be within + - 2 feet of observed surficial aquifer heads and lake levels and + - 5 feet of observed intermediate and Upper Floridan aquifer heads. Simulation of streamflow was poor, probably due to the scale of the model and regulated streamflow conditions. Simulation indicates a marked difference between the ground-water flow rates of September 1989 (steady-state conditions, end of wet season) and May 1990 (large pumpage, end of dry season) in million gallons per day: September May 1989 1990 Pumping rate 126 486 Donward leakage (into 367 564 Upper Floridan aquifer) Streamflow 67 13 Net lateral boundary flow 218 115 Total discharge (excluding 479 626 evapotranspiration. The calibrated flow model was used to simulate the short-term (one year) effects of 1990 water year pumpage (349 Mgal/d) on the September 1989 ground- water flow system in response to five different pumping schemes: (2) no pumpage, (2) no public supply pumpage, (3) no industrial pumpage, (4) no agricultural pumpage, and (5) no regional pumping outside the Water Use Caution Area. Simulation of no pumpage indicated maximum aquifer head rises of about 2 feet in the surficial aquifer and lakes, about 12 feet in the intermediate aquifer and about 16 feet in the Upper Floridan aquifer. The high rate recharge areas along the Lake Wales Ridge are most affected by pumping. Simulation of no agricultural pumpage resulted in a maximum recovery of about 2 feet in each aquifer. Simulation of no industrial or mining pumpage resulted in a maximum of less than one foot in the surficial aquifer and lakes, about 10 feet in the intermediate aquifer, and about 14 feet in the Upper Floridan aquifer. Simulation of no public supply pumpage indicated a maximum recovery of less than one foot in the surficial aquifer and lakes, about 4 feet in the intermediate aquifer, and about 10 feet in the Upper Floridan aquifer. Simulation of no regional pumping outside the Water Use Caution Area indicated recoveries of less than 2 feet within the Water Use Caution Area. Simulations were used to investigate long- term aquifer changes in response to two development alternatives: (1) continuation of 1990 water year hydrologic conditions and pumping rates (349 Mgal/d), and (2) increased pumpage (506 Mgal/d). Simulation of continued 1990 water year hydrologic conditions and pumping for 20 years indicated that head decline of more than 10 feet might be expected in each aquifer in the northern part of the Water Use Caution Area. Simulation of increased pumpage (an additional 45 percent) for 20 years indicated head declines of more than 20 feet in each aquifer in the northern part of the Water Use Caution Area. Because lakes are hydraulically connected to the surficial aquifer, lake levels within the Water Use Caution Area could decline substantially as a result of present and future pumping and a continuation of 1990 hydrologic conditions. These relatively large head declines were accompanied by decreased simulated lateral boundary outflow of about 40 percent and decreased simulated streamflow of about 32 percent. Equilibrium conditions at the end of the two 20-year simulations had not been attained.

Florida↗
USGS1995

Ground-water resources of the Florida Mesa area, La Plata County, Colorado

Rapid population growth in La Plata County, Colorado, has increased the demand for ground water in the Florida Mesa area. This report was prepared in cooperation with La Plata County to provide needed information about the geology, extent, thickness, and depth of the aquifers in the area; sources of ground-water recharge and discharge; direction of ground-water movement; water-level changes; and water quality in the alluvial and bedrock aquifers. Ground water in the study area is present in bedrock formations and in terrace deposits on Florida Mesa. Porous or fractured sandstone beds that contain bedrock aquifers are present near land surface along the northern margin of the study area and are present at depths less than 3,000 feet throughout the study area. Terrace deposits as much as 200 feet thick and consisting of gravel, sand, silt, and clay are present on Florida Mesa. The terrace deposits and the upper part of the underlying Animas and Nacimiento Formations form the principal aquifer under the mesa. Ground water under the mesa is supplied from precipitation and irrigation water. A small part of the precipitation and irrigation water on the mesa percolates to depth in the soil and recharges the aquifer. Irrigation water is the largest source of this recharge. Water levels in the aquifer can decline because of a reduction in irrigation recharge, or because of an increase in well pumping. Because irrigation recharge is so much larger than pumping, changes in recharge can have a much larger effect on ground-water levels than can changes in pumping. Factors that tend to increase ground-water recharge and thereby increase or maintain ground- water levels include: maintaining large rates of surface-water diversion onto Florida Mesa, reducing surface flow off the mesa, increasing use of ponds and spreading basins to promote infiltration, and irrigating by use of flood irrigation. The general direction of ground-water movement on the mesa is from the northern part of the mesa to the south, southwest, and southeast. Most ground water discharges from the mesa to the Animas and Florida Rivers through seeps and springs along the margin of the mesa. Winter water levels in wells generally are lower than summer water levels because of the lack of irrigation recharge during the fall and winter. Potable water of low dissolved-solids concentration is present in the shallow parts of most aquifers.

Water-Resources Investigations Report↗
USGS1997

Water-quality assessment of part of the upper Mississippi River Basin, Minnesota and Wisconsin — Pesticides in streams, streambed sediment, and ground water, 1974-94

Available data on pesticides in streams, streambed sediment, and ground water from Federal, state, and local agencies are reviewed for part of the Upper Mississippi River Basin study unit of the National Water-Quality Assessment Program. The analysis focuses on a smaller study area encompassing 19,500 square miles that includes the Upper Mississippi River Basin from Lake Pepin upstream to sampling stations on the Mississippi River near Royalton, Minnesota, and the Minnesota River near Jordan, Minnesota, and the entire drainage basins of the St. Croix, Vermillion, and Cannon Rivers. Assessment is generally restricted to two groups of pesticides the most frequently detected herbicides and organochlorine insecticides although pesticides rarely or never detected are noted. Herbicides, including alachlor, atrazine, cyanazine, or metolachlor, were detected in every stream sampled except the Kettle River. Streams draining row-crop areas had the most herbicide detections. Atrazine was the most widely detected herbicide, with detections in all streams sampled except the Kettle River. Concentrations of atrazine, metolachlor, and cyanazine were greatest in July and detectable most of the year at very low (parts-per-trillion) concentrations. The herbicides EPTC and trifluralin were never detected, although they were used in amounts equal to or greater than those detected, reflecting the fact that some herbicides are less persistent than others. A small urban stream draining part of the Lake Harriet Watershed in Minneapolis, Minnesota, contained substantial concentrations of pesticides as well. Eighty-five percent of runoff events sampled in this entirely urbanized watershed had detections of herbicides commonly used for residential purposes, and 43 percent of the events had detections of alachlor, atrazine, cyanazine, or metolachlor herbicides used predominantly for agriculture. Pesticide concentrations in urban runoff remained well above detection limits throughout the summer, indicating repeated applications of pesticides. Selected organochlorine insecticides, banned since the 1970's, still were detected in recent streambed-sediment samples. Three insecticides, 4,4'-DDT, heptachlor, and lindane, and their metabolites account for almost two-thirds of the organochlorine insecticides detected. Organochlorine insecticides were detected more frequently in streambed sediment than in streamwater. Detections in both phases were most frequent within or downstream of the Twin Cities metropolitan area, indicating that most of these insecticides originated from the Twin Cities metropolitan area. The most frequently detected herbicides in ground water were the same as those frequently detected in streams. Most detections were found in the sand and gravel aquifers underlying agricultural areas, including the Anoka Sand Plain and Bonanza Valley. Atrazine, deethylatrazine, and deisopropylatrazine were detected most frequently. Detection frequencies of atrazine were extremely variable among the various agencies, ranging from 0 to 66.7 percent, probably as a result of different sampling purposes, well locations, and detection levels. Atrazine and atrazine metabolites were the only pesticides detected in bedrock aquifers, with detections found mainly in the agriculture-dominated southeastern part of the study area where bedrock commonly outcrops near the surface. Thus, most detections of herbicides in ground water were found in environmental settings where ground water is vulnerable to contamination. Atrazine was the only pesticide that equaled or exceeded a maximum contaminant level (of 3.0 micrograms per liter) for drinking water. Two stream samples from a small urban watershed in Minneapolis had atrazine concentrations of 3.6 and 3.8 micrograms per liter, and one ground-water sample had a concentration of 3.0 micrograms per liter. Trace concentrations (less than 0.06 micrograms per liter) of the organochlorine insecticides chlordane, dieldrin, endrin, and heptachlor exceeded chronic freshwater-quality criteria in stream samples from the Mississippi, Minnesota, St. Croix, and Vemillion Rivers in 1981 and 1990.

Minnesota, Wisconsin↗
USGS2002

Ground-Water Age and its Water-Management Implications, Cook Inlet Basin, Alaska

The Cook Inlet Basin encompasses 39,325 square miles in south-central Alaska. Approximately 350,000 people, more than half of Alaska?s population, reside in the basin, mostly in the Anchorage area. However, rapid growth is occurring in the Matanuska?Susitna and Kenai Peninsula Boroughs to the north and south of Anchorage. Ground-water resources provide about one-third of the water used for domestic, commercial and industrial purposes in the Anchorage metropolitan area and are the sole sources of water for industries and residents outside Anchorage. In 1997, a study of the Cook Inlet Basin was begun as part of the U.S. Geological Survey?s National Water-Quality Assessment Program. Samples of ground water were collected from 35 existing wells in unconsolidated glacial and alluvial aquifers during 1999 to determine the regional quality of ground water beneath about 790 mi2 of developed land and to gain a better understanding of the natural and human factors that affect the water quality (Glass, 2001). Of the 35 wells sampled, 31 had water analyzed for atmospherically derived substances to determine the ground water?s travel time from its point of recharge to its point of use or discharge?also known as ground-water age. Ground water moves slowly from its point of recharge to its point of use or discharge. This water starts as rain and melting snow that soak into the ground as recharge. In the Matanuska?Susitna, Anchorage, and Kenai Peninsula areas, ground water generally moves from near the mountain fronts toward Cook Inlet or the major rivers. Much of the water pumped by domestic and public-supply wells may have traveled less than 10 miles, and the trip may have taken as short a time as a few days or as long as several decades. This ground water is vulnerable to contamination from the land surface, and many contaminants in the water would follow the same paths and have similar travel times from recharge areas to points of use as the chemical substances analyzed in this study. The effects of contamination may not be seen for several years after a contaminant is introduced into the ground-water system. Many contaminants could make the water unsuitable for drinking for many years, even in concentrations too low to detect without expensive chemical tests. The travel time of a chemically conservative substance depends primarily on the velocity of ground water through the aquifer, which in turn depends on the hydrologic characteristics of the aquifer system.

Fact Sheet↗
USGS2000

Design of a shallow ground-water network to monitor agricultural chemicals, Lake Wales Ridge, central Florida

Extensive agricultural land use and dynamic hydraulic connections between the land surface and ground-water resources render many of Florida's aquifers vulnerable to chemical contamination. In these areas, there is a need to monitor shallow ground water for agricultural chemicals to evaluate potential migration of the chemicals to the subsurface and to deeper aquifers, and to assess the effects of agricultural practices on ground-water quality. Historically, efforts to monitor water-table aquifers have been minimal compared with monitoring deeper aquifers used for municipal drinking-water supply. The Florida Department of Agriculture and Consumer Services has proposed the establishment of long-term, water-quality networks to monitor shallow ground water in agricultural areas of Florida. These networks will bridge the current information gap between local-scale short-duration field studies, which are required for pesticide licensing, and statewide monitoring of deeper ground-water resources. Laboratory (experimental) and short-term field evaluations of the transport of agricultural chemicals to the subsurface contain some degree of uncertainty due to widespread variations in environmental conditions. The proposed regional-scale shallow ground-water networks will serve as "early warning" networks to avoid contamination of ground-water resources. The objectives of these shallow ground-water networks are to provide information for early detection of pesticides and nitrate in the subsurface, and for evaluating temporal trends in concentrations in relation to changes in land use and agricultural practices. Information on trends is important to the U.S. Environmental Protection Agency, State agencies, and agricultural managers, and is an integral part of Florida's Pesticide Management Plan, which evaluates the effectiveness of implementing "best management practices" to minimize environmental impacts. Lake Wales Ridge in Polk and Highlands Counties has been identified by the Florida Department of Agriculture and Consumer Services as a pilot study area for implementing a regional shallow ground-water network. Information gained from designing the Lake Wales Ridge Network will be used to develop plans as similar networks are considered for other areas of Florida. Lake Wales Ridge is heavily utilized for citrus production, but the well-drained, clean sands underlying the region, coupled with a hydraulic connection with deeper karst formations, render the area extremely vulnerable to the transport and migration of agricultural chemicals within the subsurface. The network design for Lake Wales Ridge was developed on the basis of the objectives of monitoring, factors affecting aquifer vulnerability, probability (statistical) sampling theory, and specifications regarding well construction, sampling, and laboratory analysis. The network will provide estimates of regional pesticide and nitrate concentrations in targeted ground water, monitor for trends over time, and will provide baseline, regional-scale information. The areas targeted for sampling were citrus groves located on soils classified as vulnerable to leaching of agricultural chemicals, and ground water in close proximity to the water table. The duration of monitoring is planned to be long term. Chemicals targeted for monitoring include selected nutrients, trace elements, and pesticides used for citrus management. Standardization of field sampling and laboratory methods, and construction of a computerized data-base repository will be important for long-term utility of the data. The proposed network design consists of existing and newly drilled wells. Existing wells were evaluated as candidates for the network based on location and well-construction specifications for water-quality monitoring. Using probability selection techniques, new well locations were selected in areas that lacked adequate existing wells. Implementation of the network will occur in phases. Quarterly sampling of 13 Phase I wells commenced in April 1999. An additional 11 Phase II wells were added to the network in April 2000. Proposed locations have been identified for 8 Phase III wells. Future topics for study include a regional water-quality analysis, a network design evaluation, and consideration of local-scale studies needed to support regional monitoring efforts. An analysis of historical water-quality data for Lake Wales Ridge, including Phase I wells, is needed for the purpose of examining trends, providing a preliminary description of spatial and short-term variability in water quality, and evaluating the proposed network design for cost effectively meeting program objectives. Local-scale, process-oriented studies are needed to provide important information for evaluating regional water-quality data. Coordination between individuals conducting such local-scale studies and those interpreting regional sampling results will be considered as a component of the network design, and will require coordination between multiple agencies.

Florida↗
USGS2006

Pesticides in Ground Water of the Maryland Coastal Plain

Selected pesticides are detectable at low levels (generally less than 0.1 microgram per liter) in unconfined ground water in many parts of the Maryland Coastal Plain. Samples were recently collected (2001-04) from 47 wells in the Coastal Plain and analyzed for selected pesticides and degradate compounds (products of pesticide degradation). Most pesticide degradation occurs in the soil zone before infiltration to the water table, and degradates of selected pesticides were commonly detected in ground water, often at higher concentrations than their respective parent compounds. Pesticides and their degradates often occur in ground water in mixtures of multiple compounds, reflecting similar patterns in usage. All measured concentrations in ground water were below established standards for drinking water, and nearly all were below other health-based guidelines. Although drinking-water standards and guidelines are typically much higher than observed concentrations in ground water, they do not exist for many detected compounds (particularly degradates), or for mixtures of multiple compounds. The distribution of observed pesticide compounds reflects known usage patterns, as well as chemical properties and environmental factors that affect the fate and transport of these compounds in the environment. Many commonly used pesticides, such as glyphosate, pendimethalin, and 2,4-D were not detected in ground water, likely because they were sorbed onto organic matter or degraded in the soil zone. Others that are more soluble and (or) persistent, like atrazine, metolachlor, and several of their degradates, were commonly detected in ground water where they have been used. Atrazine, for example, an herbicide used primarily on corn, was most commonly detected in ground water on the Eastern Shore (where agriculture is common), particularly where soils are well drained. Conversely, dieldrin, an insecticide previously used heavily for termite control, was detected only on the Western Shore, where urban land is more common. Use of dieldrin was suspended in 1987, but this compound is relatively persistent in the environment, and several decades are typically required for ground water to move completely through the surficial aquifer. U.S. Department of the Interior U.S. Geological Survey USGS Fact Sheet FS 2006-3119 2006 Location of the Maryland Coastal Plain.

Fact Sheet↗
USGS2001

Hydrology of the coastal springs ground-water basin and adjacent parts of Pasco, Hernando, and Citrus Counties, Florida

The coastal springs in Pasco, Hernando, and Citrus Counties, Florida consist of three first-order magnitude springs and numerous smaller springs, which are points of substantial ground-water discharge from the Upper Floridan aquifer. Spring flow is proportional to the water-level altitude in the aquifer and is affected primarily by the magnitude and timing of rainfall. Ground-water levels in 206 Upper Floridan aquifer wells, and surface-water stage, flow, and specific conductance of water from springs at 10 gaging stations were measured to define the hydrologic variability (temporally and spatially) in the Coastal Springs Ground-Water Basin and adjacent parts of Pasco, Hernando, and Citrus Counties. Rainfall at 46 stations and ground-water withdrawals for three counties, were used to calculate water budgets, to evaluate long-term changes in hydrologic conditions, and to evaluate relations among the hydrologic components. Predictive equations to estimate daily spring flow were developed for eight gaging stations using regression techniques. Regression techniques included ordinary least squares and multiple linear regression techniques. The predictive equations indicate that ground-water levels in the Upper Floridan aquifer are directly related to spring flow. At tidally affected gaging stations, spring flow is inversely related to spring-pool altitude. The springs have similar seasonal flow patterns throughout the area. Water-budget analysis provided insight into the relative importance of the hydrologic components expected to influence spring flow. Four water budgets were constructed for small ground-water basins that form the Coastal Springs Ground-Water Basin. Rainfall averaged 55 inches per year and was the only source of inflow to the Basin. The pathways for outflow were evapotranspiration (34 inches per year), runoff by spring flow (8 inches per year), ground-water outflow from upward leakage (11 inches per year), and ground-water withdrawal (2 inches per year). Recharge (rainfall minus evapotranspiration) to the Upper Floridan aquifer consists of vertical leakage through the surficial deposits. Discharge is primarily through springs and diffuse upward leakage that maintains the extensive swamps along the Gulf of Mexico. The ground-water basins had slightly different partitioning of hydrologic components, reflecting variation among the regions. Trends in hydrologic data were identified using nonparametric statistical techniques to infer long-term changes in hydrologic conditions, and yielded mixed results. No trend in rainfall was detected during the past century. No trend in spring flow was detected in 1931-98. Although monotonic trends were not detected, rainfall patterns are naturally variable from month to month and year to year; this variability is reflected in ground-water levels and spring flows. A decreasing trend in ground-water levels was detected in the Weeki Wachee well (1966-98), but the trend was statistically weak. At current ground-water withdrawal rates, there is no discernible affect on ground-water levels and spring flows. Sporadic data records, lack of continuous data, and inconsistent periods of record among the hydrologic components impeded analysis of long-term changes to the hydrologic system and interrelations among components. The ongoing collection of hydrologic data from index sites could provide much needed information to assess the hydrologic factors affecting the quantity and quality of spring flow in the Coastal Springs Ground-Water Basin.

Water-Resources Investigations Report↗
USGS1984

Investigation of ethylene dibromide (EDB) in ground water in Seminole County, Georgia

An investigation of ground water in Seminole County, Georgia, for ethylene dibromide (EDB) was conducted in August 1983 by the U.S. Geological Survey in cooperation with the Exposure Assessment Branch of the U.S. Environmental Protection Agency. The purpose of the investigation was to determine whether EDB, which was previously detected in ground-water samples from four neighboring wells, was localized in the vicinity of the wells or was more widespread in the ground-water system. EDB was detected in 6 of 19 wells sampled. Concentrations ranged from 0.03 to 11.8 micrograms per liter. Five of the six samples that contained EDB were collected from irrigation wells, and one was collected from a domestic well. Concentrations of 4.5 and 11.8 micrograms per liter were found in two irrigation wells located near Buck Hole, a sinkhole in a swampy depression in central Seminole County. EDB was not detected in samples from the remaining 10 irrigation and 3 domestic wells and the surface-water site (detection level less than 0.01 microgram per liter). Nine core samples were collected from a borehole near one of the irrigation wells that had high EDB concentrations. EDB was found in a core sample near the surface and in samples from depths of 24 to 25, 34 to 35, and 39 to 40 feet in the residuum. EDB concentrations in the core samples ranged from 0.06 to 2.4 micrograms per kilogram. EDB in the aquifer was found in a 4-square-mile area of the county in the vicinity of Buck Hole. EDB application information and the local hydrogeology indicate that EDB contamination in ground water in Seminole County probably is due to soil fumigation with EDB. Apparently, EDB moves downward through the residuum and, through undetermined pathways, enters the aquifer. However, because the high concentration of EDB in the aquifer seems to be localized in the Buck Hole area, the possibility of contamination from an EDB fumigant spill cannot be disregarded at this time.

Georgia↗
USGS2000

Analysis of selected herbicide metabolites in surface and ground water of the United States

One of the primary goals of the US Geological Survey (USGS) Laboratory in Lawrence, Kansas, is to develop analytical methods for the analysis of herbicide metabolites in surface and ground water that are vital to the study of herbicide fate and degradation pathways in the environment. Methods to measure metabolite concentrations from three major classes of herbicides — triazine, chloroacetanilide and phenyl-urea — have been developed. Methods for triazine metabolite detection cover nine compounds: six compounds are detected by gas chromatography/mass spectrometry; one is detected by high-performance liquid chromatography with diode-array detection; and eight are detected by liquid chromatography/mass spectrometry. Two metabolites of the chloroacetanilide herbicides — ethane sulfonic acid and oxanilic acid — are detected by high-performance liquid chromatography with diode-array detection and liquid chromatography/mass spectrometry. Alachlor ethane sulfonic acid also has been detected by solid-phase extraction and enzyme-linked immunosorbent assay. Six phenylurea metabolites are all detected by liquid chromatography/mass spectrometry; four of the six metabolites also are detected by gas chromatography/mass spectrometry. Additionally, surveys of herbicides and their metabolites in surface water, ground water, lakes, reservoirs, and rainfall have been conducted through the USGS laboratory in Lawrence. These surveys have been useful in determining herbicide and metabolite occurrence and temporal distribution and have shown that metabolites may be useful in evaluation of non-point-source contamination.

Science of the Total Environment↗
USGS2005

Assessment of shallow ground-water quality in recently urbanized areas of Sacramento, California, 1998

Evidence for anthropogenic impact on shallow ground-water quality beneath recently developed urban areas of Sacramento, California, has been observed in the sampling results from 19 monitoring wells in 1998. Eight volatile organic compounds (VOCs), four pesticides, and one pesticide transformation product were detected in low concentrations, and nitrate, as nitrogen, was detected in elevated concentrations; all of these concentrations were below National and State primary and secondary maximum contaminant levels. VOC results from this study are more consistent with the results from urban areas nationwide than from agricultural areas in the Central Valley, indicating that shallow ground-water quality has been impacted by urbanization. VOCs detected may be attributed to either the chlorination of drinking water, such as trichloromethane (chloroform) detected in 16 samples, or to the use of gasoline additives, such as methyl tert-butyl ether (MTBE), detected in 2 samples. Pesticides detected may be attributed to use on household lawns and gardens and rights-of-way, such as atrazine detected in three samples, or to past agricultural practices, and potentially to ground-water/surface-water interactions, such as bentazon detected in one sample from a well adjacent to the Sacramento River and downstream from where bentazon historically was used on rice. Concentrations of nitrate may be attributed to natural sources, animal waste, old septic tanks, and fertilizers used on lawns and gardens or previously used on agricultural crops. Seven sample concentrations of nitrate, as nitrogen, exceeded 3.0 milligrams per liter, a level that may indicate impact from human activities. Ground-water recharge from rainfall or surface-water runoff also may contribute to the concentrations of VOCs and pesticides observed in ground water. Most VOCs and pesticides detected in ground-water samples also were detected in air and surface-water samples collected at sites within or adjacent to the recently developed urban areas. Five arsenic sample concentrations exceeded the U.S. Environmental Protection Agency (USEPA) primary maximum contaminant level (MCL) of 10 milligrams per liter adopted in 2001. Measurements that exceeded USEPA or California Department of Health Services recommended secondary maximum contaminant levels include manganese, iron, chloride, total dissolved solids, and specific conductance. These exceedances are probably a result of natural processes. Variations in stable isotope ratios of hydrogen (2H/1H) and oxygen (18O/16O) may indicate different sources or a mixing of recharge waters to the urban ground water. These variations also may indicate recharge directly from surface water in one well adjacent to the Sacramento River. Tritium concentrations indicate that most shallow ground water has been recharged since the mid-1950s, and tritium/helium-3 age dates suggest that recharge has occurred in the last 2 to 30 years in some areas. In areas where water table depths exceed 20 meters and wells are deeper, ground-water recharge may have occurred prior to 1950, but low concentrations of pesticides and VOCs detected in these deeper wells indicate a mixing of younger and older waters. Overall, the recently urbanized areas can be divided into two groups. One group contains wells where few VOCs and pesticides were detected, nitrate mostly was not detected, and National and State maximum contaminant levels, including the USEPA MCL for arsenic, were exceeded; these wells are adjacent to rivers and generally are characterized by younger water, shallow (1 to 4 meters) water table, chemically reducing conditions, finer grained sediments, and higher organics in the soils. In contrast, the other group contains wells where more VOCs, pesticides, and elevated nitrate concentrations were detected; these wells are farther from rivers and are generally characterized by a mixture of young and old waters, intermediate to deep (7 to 35 meters) wate

Scientific Investigations Report↗
USGS2008

Estimates of Nutrient Loading by Ground-Water Discharge into the Lynch Cove Area of Hood Canal, Washington

Low dissolved oxygen concentrations in the waters of Hood Canal threaten marine life in late summer and early autumn. Oxygen depletion in the deep layers and landward reaches of the canal is caused by decomposition of excess phytoplankton biomass, which feeds on nutrients (primarily nitrogen compounds) that enter the canal from various sources, along with stratification of the water column that prevents mixing and replenishment of oxygen. Although seawater entering the canal is the largest source of nitrogen, ground-water discharge to the canal also contributes significant quantities, particularly during summer months when phytoplankton growth is most sensitive to nutrient availability. Quantifying ground-water derived nutrient loads entering an ecologically sensitive system such as Hood Canal is a critical component of constraining the total nutrient budget and ultimately implementing effective management strategies to reduce impacts of eutrophication. The amount of nutrients entering Hood Canal from ground water was estimated using traditional and indirect measurements of ground-water discharge, and analysis of nutrient concentrations. Ground-water discharge to Hood Canal is variable in space and time because of local geology, variable hydraulic gradients in the ground-water system adjacent to the shoreline, and a large tidal range of 3 to 5 meters. Intensive studies of ground-water seepage and hydraulic-head gradients in the shallow, nearshore areas were used to quantify the freshwater component of submarine ground-water discharge (SGD), whereas indirect methods using radon and radium geochemical tracers helped quantify total SGD and recirculated seawater. In areas with confirmed ground-water discharge, shore-perpendicular electrical resistivity profiles, continuous electromagnetic seepage-meter measurements, and continuous radon measurements were used to visualize temporal variations in ground-water discharge over several tidal cycles. The results of these field investigations show that ground-water discharge into the Lynch Cove area of Hood Canal is highly dynamic and strongly affected by the large tidal range. In areas with a steep shoreline and steep hydraulic gradient, ground-water discharge is spatially concentrated in or near the intertidal zone, with increased discharge during low tide. Topographically flat areas with weak hydraulic gradients had more spatial variability, including larger areas of seawater recirculation and more widely dispersed discharge. Measured total-dissolved-nitrogen concentrations in ground water ranged from below detection limits to 2.29 milligrams per liter and the total load entering Lynch Cove was estimated to be approximately 98 ? 10.3 metric tons per year (MT/yr). This estimate is based on net freshwater seepage rates from Lee-type seepage meter measurements and can be compared to estimates derived from geochemical tracer mass balance estimates (radon and radium) of 231 to 749 MT/yr, and previous water-mass-balance estimates (14 to 47 MT/ yr). Uncertainty in these loading estimates is introduced by complex biogeochemical cycles of relevant nutrient species, the representativeness of measurement sites, and by energetic dynamics at the coastal aquifer-seawater interface caused by tidal forcing.

Scientific Investigations Report↗
USGS2002

Geohydrology and ground-water quality, Big Elk Creek Basin, Chester County, Pennsylvania, and Cecil County, Maryland

A study of ground-water quantity and quality was conducted in the Big Elk Creek Basin, a rural area undergoing rapid growth. The 79.4-square mile study area is in the Piedmont Physiographic Province and is underlain almost entirely by crystalline rocks. Most of the basin in Pennsylvania is underlain by Wissahickon Schist, a fractured crystalline- rock aquifer. Yields of wells in the Wissahickon Schist range from 5 to 200 gal/min (gallons per minute); the median yield is 15 gal/min. Specific capacity ranges from 0.03 to 15 (gal/min)/ft (gallons per minute per foot) of drawdown; the median specific capacity is 0.4 (gal/min)/ft. Recharge to the basin occurs by infiltration of precipitation, and ground water discharges locally to streams. The median annual ground-water discharge to streams (base flow) for 1933-99 was 10.79 in. (inches) or 0.518 (Mgal/d)/mi 2 (million gallons per day per square mile), which was 63 percent of the median annual streamflow. The median annual ground-water discharge to streams ranged from 5.32 in. or 0.255 (Mgal/d)/mi 2 in 1966 to 17.98 in. or 0.863 (Mgal/d)/mi 2 in 1972. Estimated ground-water availability ranges from 0.127 to 0.535 (Mgal/d)/mi 2 , depending on the estimation method used. Annual water budgets were calculated for the Big Elk Creek Basin for 1998-99. The 1998-99 average annual streamflow was 15.38 in., change in ground-water storage was an increase of 1.32 in., ground-water exports were 0.03 in., and estimated evapotranspiration (ET) was 30.5 in. Despite a 12.27-in. difference in precipitation between 1998 and 1999, the percentage of precipitation as ET (65.6 and 64 percent, respectively) is similar. Estimated average annual recharge for 1998-99 was 12.12 in. [0.580 (Mgal/d)/mi 2 ]. For this study, water samples from 20 wells in the Big Elk Creek Basin were collected for analysis for inorganic constituents and pesticides. In addition, data were available from 44 additional wells. Major ions, in order of decreasing concentration, based on median concentrations for the Wissahickon Schist, are silica, calcium, chloride, sodium, sulfate, magnesium, and potassium. The Wissahickon Schist and Peters Creek Schist have similar water types; ground water from serpentinite, the basal unit of the Baltimore Mafic Complex that straddles the Pennsylvania-Maryland border, is distinctly different. For the Wissahickon Schist and Peters Creek Schist, no cation is predominant; calcium, magnesium, and sodium are in nearly equal concentrations expressed in milliequivalents per liter. Bicarbonate is the dominant anion. Water from serpentinite is of the magnesium bicarbonate type; magnesium is the dominant cation, and bicarbonate is the dominant anion. Water from 2 percent of sampled wells exceeded the U.S. Environmental Protection Agency (USEPA) secondary maximum contaminant level (SMCL) for total dissolved solids. None of the chloride or sulfate concentrations exceeded the USEPA SMCL. Water from 10 percent of sampled wells exceeded the USEPA maximum contaminant level (MCL) of 10 mg/L (milligrams per liter) nitrate as nitrogen. All of those wells are in the Wissahickon Schist. The median concentration of nitrate in water samples from the Wissahickon Schist was 3.6 mg/L, and the maximum concentration was 36 mg/L. Except for iron and manganese, metals and other trace inorganic constituents do not appear to pose a water-quality problem. Fourteen percent of water samples analyzed for iron and 29 percent of water samples analyzed for manganese exceeded the USEPA SMCL's. The median activity of radon-222 for all formations was 2,400 pCi/L (picoCuries per liter). The median activity for water from 35 wells sampled in the Wissahickon Schist in the Big Elk Creek Basin was 2,500 pCi/L. Water from 94 percent of sampled wells exceeded the proposed USEPA MCL of 300 pCi/L, and water from 25 percent of sampled wells exceeded proposed USEPA alternate MCL of 4,000 pCi/L. In addition to the 20 wells sampled for pesticides for this study, data were available for 20 other wells sampled for pesticides. The most commonly detected pesticides in the Big Elk Creek Basin are deethyl atrazine (71 percent of sampled wells), atrazine (35 percent of sampled wells), metolachlor (32 percent of sampled wells), carbaryl (19 percent of sampled wells), picloram (14 percent of sampled wells), simazine (13 percent of sampled wells), and carbofuran (11 percent of sampled wells). Most concentrations are extremely low and are in the parts per trillion range. Concentrations of pesticides detected did not exceed USEPA MCL’s. Out of 43 volatile organic compounds analyzed, only 4 were detected—chloroform, total phenols, tert-butyl methyl ether (MTBE), and toluene. None of the concentrations exceeded USEPA MCL’s.

Maryland, Pennsylvania↗
USGS2005

Basic concepts for the linear model of ground water level recession

Basic concepts are illustrated for the display of ground water level recession as a linear plot on a semilog graph, as first described by Rorabaugh. This exponential decay function can be achieved if there is a definable outflow boundary such as a lake or river and if water levels are expressed relative to the altitude of the boundary. The model can be used to estimate aquifer hydraulic diffusivity. Concepts are illustrated using three finite-difference simulations. One represents the ideal case as described by Rorabaugh, in which the altitude of the outflow boundary is uniform along its length. Another simulation includes a sloping boundary with simple geometry and demonstrates that the model can be used accurately. Based on this simulation, it appears that the ground water level must be expressed relative to the closest point on the outflow boundary. The third simulation includes a sloping boundary and complex boundary shape, and demonstrates departures from the linear model of recession and errors in the estimate of hydraulic diffusivity. Another cause of nonlinearity is the instability of the ground water head profile soon after a recharge event. The nature of these early-time departures will vary depending on the location of the water level observation site relative to the outflow boundary and the hydrologic divide of the ground water flow system. ?? 2006 National Ground Water Association.

Ground Water↗
USGS1982

Appraisal of ground-water quality near wastewater-treatment facilities, Glacier National Park, Montana

Water-level and water-quality data were collected from monitoring wells at wastewater-treatment facilities in Glacier National Park. Five additional shallow observation wells were installed at the Glacier Park Headquarters facility to monitor water quality in the shallow ground-water system. Water-level, water-quality, and geologic information indicate that some of the initial monitoring wells are not ideally located to sample ground water most likely to be affected by waste disposal at the sites. Small differences in chemical characteristics between samples from monitor wells indicate that effluent may be affecting ground-water quality but that impacts are not significant. Future monitoring of ground-water quality could be limited to selected wells most likely to be impacted by percolating effluent. Laboratory analyses for common ions could detect future impacts.

Montana↗
USGS1984

Evaluation of the ground-water resources of parts of Lancaster and Berks Counties, Pennsylvania

Secondary openings in bedrock are the avenues for virtually all ground-water flow in a 626-sqare-mile area in Lancaster and Berks Counties, Pennsylvania. The number, size, and interconnection of secondary openings are functions of lithology, depth, and topography. Ground water actively circulates to depths of 150 to 300 feet below land surface. Total average annual ground-water recharge for the area is 388 million gallons per day, most of which discharges to streams from local, unconfined flow systems. A digital ground-water flow model was developed to simulate unconfined flow under several different recharge and withdrawal scenarios. On the basis of lithologic and hydrologic differences, the modeled area was sub-divided into 22 hydrogeologic units. A finite-difference grid with rectangular blocks, each 2,015 by 2,332 feet, was used. The model was calibrated under steady-state and transient conditions. The steady-state calibration was used to determine hydraulic conductivities and stream leakage coefficients and the transient calibration was used to determine specific yields. The 22 hydrogeologic units fall into four general lithologies: Carbonate rocks, metamorphic rocks, Paleozoic sedimentary rocks, and Triassic sedimentary rocks. Average hydraulic conductivity ranges from about 8.8 feet per day in carbonate units to about .5 feet per day in metamorphic units. The Stonehenge Formation (limestone) has the greatest average hydraulic conductivity--85.2 feet per day in carbonate units to about 0.11 feet per day in the greatest gaining-strem leakage coefficient--16.81 feet per day. Specific yield ranges from 0.06 to 0.09 in carbonate units, and is 0.02 to 0.015, and 0.012 in metamorphic, Paleozoic sedimentary, and Triassic sedimentary units, respectively. Transient simulations were made to determine the effects of four different combinations of natural and artificial stresses. Natural aquifer conditions (no ground-water withdrawals) and actual aquifer conditions (current ground-water withdrawals) were simulated for two years under normal seasonal and hypothetical drought (60-percent reduction in winter-spring recharge) conditions. In October, 6 months after the hypothetical drought, simulated declines in water-table altitude due to the drought occurred everywhere and ranged from a median of 3.6 feet in carbonate units to 8.7 feet in carbonate units. Simulated base flows for five major streams were reduced by 33 to 51 percent during the hypothetical drought. Also in October, maximum simulated declines in water-table altitude due to ground-water withdrawls ranged from 33 feet in carbonate units to 79 feet in Triassic sedimentary units. Simulated base flows for five major streams were reduced by the amount of ground water withdrawn. Finally, again in October, maximum simulated declines in water-table altitude due to the combination of hypothetical drought and ground-water withdrawls ranged from 38 feet in carbonate units to 109 feet in Triassic sedimentary units. Due to aquifer dewatering, simulated declines were as much as 24 feet greater than the sum of the separate simulated declines that were caused by hypothetical drought and ground-water withdrawals. Some of the greatest simulated declines were in well fields, operated by three municipalities that experienced water-supply problems during the 1980-81 drought.

Water-Resources Investigations Report↗
USGS1994

Selected ground-water data for Yucca Mountain region, southern Nevada and eastern California, through December 1992

Tne U.S. Geological Survey. in support of the U.S. Department of Energy, Yucca Mountain Site- Characterization Project, collects, compiles, and summarizes water-resource data in the Yucca Mountain region. The data are collected to document the historical and current condition of ground-water resources, to detect and document changes in those resources through time, and to allow assessments of ground-water resources during investigations to determine the potential suitability of Yucca Mountain for storing high-level nuclear waste. Data on ground-water levels at 36 sites, ground- water discharge at 6 sites, ground-water quality at 19 sites, and ground-water withdrawals within Crater Fiat, Jackass Flats, Mercury Valley, and the Amargosa Desert are presented. Data on ground-water levels, discharges, and withdrawals collected by other agencies or as part of other programs are included to further indicate variations through time. A statistical summary of ground-water levels and median annual ground-water withdrawals in Jackass Flats is presented. The statistical summary includes the number of measurements, the maximum, minimum, and median water-level altitudes, and the average deviation of a11 water-level altitudes for selected baseline periods and for calendar year 1992. Data on ground-water quality are compared to established, proposed, or tentative primary and secondary drinking-water standards, and measures which exceeded those standards are listed for 18 sites. Detected organic compounds for which established, proposed, or tentative drinking-water standards exist also are listed.

California, Nevada↗
USGS2007

Ground-water, surface-water, and water-chemistry data, Black Mesa area, northeastern Arizona— 2005-06

The N aquifer is the major source of water in the 5,400 square-mile Black Mesa area in northeastern Arizona. Availability of water is an important issue in northeastern Arizona because of continued water requirements for industrial and municipal use and the needs of a growing population. Precipitation in the Black Mesa area averages about 6 to 14 inches per year. The water monitoring program in the Black Mesa area began in 1971 and is designed to provide information about the long-term effects of ground-water withdrawals from the N aquifer for industrial and municipal uses. This report presents results of data collected for the monitoring program in the Black Mesa area from January 2005 to September 2006. The monitoring program includes measurements of (1) ground-water pumping, (2) ground-water levels, (3) spring discharge, (4) surface-water discharge, (5) ground-water chemistry, and (6) periodic testing of ground-water withdrawal meters. In 2005, ground-water withdrawals in the Black Mesa area totaled 7,330 acre-feet, including ground-water withdrawals for industrial (4,480 acre-feet) and municipal (2,850 acre-feet) uses. From 2004 to 2005, total withdrawals increased by less than 2 percent, industrial withdrawals increased by approximately 3 percent, and total municipal withdrawals increased by 0.35 percent. From 2005 to 2006, annually measured water levels in the Black Mesa area declined in 10 of 13 wells in the unconfined areas of the N aquifer, and the median change was -0.5 foot. Measurements indicated that water levels declined in 12 of 15 wells in the confined area of the aquifer, and the median change was -1.4 feet. From the prestress period (prior to 1965) to 2006, the median water-level change for 29 wells was -8.5 feet. Median water-level changes were -0.2 foot for 13 wells in the unconfined areas and -46.6 feet for 16 wells in the confined area. Ground-water discharges were measured once in 2005 and once in 2006 at Moenkopi School Spring and Burro Spring. Discharge decreased by 3.5 percent at Moenkopi School Spring and by 15 percent at Burro Spring. During the period of record at each spring, discharges fluctuated; a decreasing trend was apparent. Continuous records of surface-water discharge in the Black Mesa area have been collected from streamflow gages at the following sites: Moenkopi Wash (1976 to 2005), Dinnebito Wash (1993 to 2005), Polacca Wash (1994 to 2005), Pasture Canyon Spring (August 2004 to December 2005), and Laguna Creek (1996 to 2005). Median flows during November, December, January, and February of each water year were used as an index of the amount of ground-water discharge to the above named sites. For the period of record at each streamflow-gaging station, the median winter flows have decreased for Moenkopi Wash, Dinnebito Wash, and Polacca Wash. There is not a long enough period of record for Pasture Canyon Spring and Laguna Creek was discontinued at the end of December 2005. In 2006, water samples were collected from 6 wells and 2 springs in the Black Mesa area and analyzed for selected chemical constituents. Dissolved-solids concentrations ranged from 111 to 588 milligrams per liter. Water samples from 5 of the wells and both of the springs had less than 500 milligrams per liter of dissolved solids. Trends in the chemistry of water samples from the 6 wells show the Pi?on NTUA 1 and Peabody 9 wells increasing in dissolved solids, Forest Lake NTUA 1 and Peabody 2 wells decreasing in dissolved solids, and Kykotsmovi PM2 and Keams Canyon PM2 wells show a steady trend. Increasing trends in dissolved-solids, chloride, and sulfate concentrations were evident from the more than 11 years of data for the 2 springs.

Arizona↗
USGS1998

Hydrology and quality of ground water in northern Thurston County, Washington

Northern Thurston County is underlain by as much as 1,800 feet of unconsolidated deposits of Pleistocene Age that are of glacial and nonglacial origin. Iterpretation of approximately 1,140 drillers' logs led to the delineation of seven major geohydrologic units, four of which are significant aquifers. Precipitation ranges from about 35 to 65 inches per year across the study area. Estimates of recharge indicate that the ground-water system of the Ground Water Management Area (GWMA), a subset of the study area, receives an average of about 28 inches per year. Ground water generally moves toward marine water bodies and to major surface drainage channels. At least 33,000 acre-feet per year of ground water discharges as springs from the GWMA. Approximately 21,000 acre-feet of water was withdrawn from the ground-water system of the GWMA through wells in 1988. Total ground-water use in the GWMA in 1988 was approximately 37,000 acre-feet. About 16,000 acre-feet of water that discharges naturally through springs was used together with water withdrawn by wells for domestic supply, agricultural, commercial, industrial, institutional, and aquaculture and livestock uses. Generally, the chemical quality of the ground water was good and 94 percent of the water samples were classified as soft or moderately hard. Of the few water-quality problems encountered, the most widespread anthropogenic problem appeared to be seawater intrusion. However, a comparison with data from 1978 indicated that the degree and extent of intrusion had not changed significantly since that time. Agricultural activities may be responsible for the presence of nitrate in ground waters at some individual wells, but septic tanks in areas of high housing density are likely responsible for elevated nitrate concentrations near the Cities of Lacey and Tumwater. The close correlation of nitrate concentrations with detergent concentrations supports the theory that the nitrate originates in septic systems, the only likely source of the detergents. Most water-quality problems in the study area, however, are due to natural causes. Iron concentrations are as large as 21,000 micrograms per liter, manganese concentrations are as large as 3,400 micrograms per liter, and connate seawater is present in ground water in the southern part of the study area.

Washington↗