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At least 919 records · Page 51Linked to original sources

Rivers and streams: Ecosystem dynamics and integrating paradigms

Full understanding of running waters requires an ecosystem perspective, which encompasses the physical and chemical setting in interaction with dependent biological communities. Several conceptual models or paradigms of river and stream ecosystems that capture critical components of lotic ecosystems have been developed, including the ‘river continuum concept’, to describe fluxes of matter and energy within the stream or river channel together with exchanges between the channel and its terrestrial setting. A complete ecosystem perspective includes consideration of hierarchical spatial scales in a temporal context. Flow of energy in lotic ecosystems is driven by two alternative energy sources: sunlight regulating in-stream photosynthesis and plant litter derived from the stream-side riparian corridor or floodplain. Energy transfers within the ecosystem pass through micro- and macroproducers (algae and vascular hydrophytes) and micro- and macroconsumers (microorganisms, invertebrates, and vertebrates). Material fluxes encompass the cycling of key nutrients, such as nitrogen and phosphorus, and the transport, storage, and metabolism of dissolved (DOM) and particulate (POM) organic matter (OM). Growth of lotic periphyton (algae and associated microbes, microzoans, and detritus) and coarse (CPOM) and fine (FPOM) particulate organic matter constitute the food resources of nonpredaceous running-water invertebrates (e.g., shredders that consume CPOM and collectors that feed on FPOM and associated microbes of both).

Book chapter↗

Development of a benchmark eddy flux evapotranspiration dataset for evaluation of satellite-driven evapotranspiration models over the CONUS

A large sample of ground-based evapotranspiration (ET) measurements made in the United States, primarily from eddy covariance systems, were post-processed to produce a benchmark ET dataset. The dataset was produced primarily to support the intercomparison and evaluation of the OpenET satellite-based remote sensing ET (RSET) models and could also be used to evaluate ET data from other models and approaches. OpenET is a web-based service that makes field-delineated and pixel-level ET estimates from well-established RSET models readily available to water managers, agricultural producers, and the public. The benchmark dataset is composed of flux and meteorological data from a variety of providers covering native vegetation and agricultural settings. Flux footprint predictions were developed for each station and included static flux footprints developed based on average wind direction and speed, as well as dynamic hourly footprints that were generated with a physically based model of upwind source area. The two footprint prediction methods were rigorously compared to evaluate their relative spatial coverage. Data from all sources were post-processed in a consistent and reproducible manner including data handling, gap-filling, temporal aggregation, and energy balance closure correction. The resulting dataset included 243,048 daily and 5,284 monthly ET values from 194 stations, with all data falling between 1995 and 2021. We assessed average daily energy imbalance using 172 flux sites with a total of 193,021 days of data, finding that overall turbulent fluxes were understated by about 12% on average relative to available energy. Multiple linear regression analyses indicated that daily average latent energy flux may be typically understated slightly more than sensible heat flux. This dataset was developed to provide a consistent reference to support evaluation of RSET data being developed for a wide range of applications related to water accounting and water resources management at field to watershed scales.

continental United States↗

Field observations and long short-term memory modeling of spectral wave evolution at living shorelines in Chesapeake Bay, USA

Living shorelines as a nature-based solution for climate change adaptation were constructed in many places around the world. The success of this type of projects requires long-term monitoring for adaptive management. The paper presents a novel framework leveraging scientific machine learning methods for accurate and rapid prediction of long-term hydrodynamic forcing impacting living shorelines using short-term measurements of water levels and wind waves in the largest estuary in the U.S. Different from existing data-driven wave prediction models focusing on significant wave heights, this study is focused on the prediction of wave energy spectra in shallow water using winds and tides as the input feature and short-term measurements of wave spectra and water depths as the label. Long Short-Term Memory (LSTM) models were developed using four-month wave measurements in the stormy seasons to predict integral wave parameters and energy spectra for multiple years. The developed models accurately predicted wave heights, peak periods, and energy spectra around the living shorelines, capturing complex wave dynamics, such as wave generation by wind, nonlinear wave-wave interactions, and depth-limited wave breaking in the shallow water of a large estuary. The validated models were then used to determine the long-term wave forcing impacting the living shorelines based on the modeled wave characteristics and spectra. Model results show that the surrogate models utilizing LSTM to predict wave spectra in the frequency domain enable long-term predictions of spectral wave evolution with a minimal computational cost. Our findings provide valuable insights into the efficacy of living shorelines in attenuating wave energy and demonstrate the utility of this approach in assessing the effectiveness of such living shoreline structures.

Applied Ocean Research↗

Component identification of solid biomass fuels using reflected light microscopy: Interlaboratory study 2

As nations transition toward sustainable energy systems , biomass has become a vital component of global energy portfolios. Derived from organic materials such as wood, agricultural residues, forestry byproducts, and organic waste, biomass is a renewable energy source with significant environmental and economic benefits. Responsible biomass energy production can improve waste management, reduce emissions of greenhouse gases, and mitigate environmental pollution. However, as the diversity of biomass-derived fuels increases, robust quality assessment methods are essential to ensure their efficiency, safety, and minimal environmental impact. Reflected light microscopy (RLM) is one such technique with the potential to complement conventional physico-chemical analyses by enabling a rapid identification of material constituents and impurities. To refine this methodology and evaluate the reproducibility of solid biomass component identification using RLM, an interlaboratory study (ILS) was conducted. The study involved the recognition of 58 components across 45 photomicrographs, with the participation of 65 scientists and students from 25 countries. The participants faced high difficulty identifying some of the marked components, and as a result, the percentage of correct answers ranged from 19.0 % to 98.3 %, with an average correct identification rate of 62.7 %. The most challenging aspects of the identification process included distinguishing between woody and non-woody (agro) biomass, accurately identifying petroleum-derived materials, and differentiating agro biomass from inorganic matter. The results suggest that while RLM is an important tool for characterizing solid biomass, further development of methodology guidelines and training are necessary to enhance its effectiveness. Future research should prioritize preparing detailed, image-rich, microscopic morphological descriptions of biomass fuel components, which could improve the accuracy and reliability of using RLM in biomass fuel characterization.

International Journal of Coal Geology↗

Waves, watersheds, and sediment in a coral reef embayment: Towards parsimonious models of accumulation and composition

High sedimentation rates can damage coral reef ecosystems. Sedimentation rates are controlled by both sediment loads from watersheds and resuspension by waves and associated circulation patterns, but the outcomes are system specific and difficult to predict. The percent terrigenous (non-organic and non-carbonaceous) material in sediment is also often used as an indicator of watershed influence, but its dynamics are poorly understood. Sediment accumulation rates, particle size, and percent terrigenous were monitored quasi-monthly for one year (March 2014-April 2015) at nine sites in a coral reef-fringed embayment in American Samoa, where an aggregate quarry had increased sediment loads to the coast but mitigation reduced loads during the monitored period. Gross and net sediment accumulation rates were measured using sediment traps and SedPods (pods), respectively. Gross accumulation rates exceeded thresholds for impacts on coral health during at least one collection period at most sites, with more exceedances on the northern reef where water residence times and sediment availability are higher and corals show signs of sediment stress. Percent terrigenous of coarse sediment was higher in the traps and pods compared with the surrounding benthic sediment, indicating that some of the terrigenous sediment was advected through the bay without accumulating on the reef. The 95th percentile of hourly wave energy density ( E 95 ) taken from a global wave model (WaveWatch 3) was the best predictor of gross accumulation rates of both total and carbonate sediment in a log-log regression at most ( n = 6) sites ( R 2 range 0.72-0.92), indicating a strong role of resuspension of benthic sediment. Gross accumulation rates of terrigenous sediment were not correlated with E 95 and only correlated with SSY at the site nearest the stream mouth, indicating that most terrigenous sediment was not from resuspended benthic material but rather from a consistent watershed source. Percent terrigenous decreased with increasing wave energy due to high accumulation rates of carbonates during periods of high wave energy. Detection of the impact of sediment mitigation at the quarry on sediment accumulation was complicated by low wave energy in the period following mitigation. The use of gross accumulation rates and percent terrigenous as indicators of the magnitude and sources of sediment accumulation over time needs to account for wave-induced resuspension, which can be modelled with a simple power function using inputs from a global wave model.

Estuarine, Coastal and Shelf Science↗

Beach response dynamics of a littoral cell using a 17-year single-point time series of sand thickness

A 17-year time series of near-daily sand thickness measurements at a single intertidal location was compared with 5 years of semi-annual 3-dimensional beach surveys at the same beach, and at two other beaches within the same littoral cell. The daily single point measurements correlated extremely well with the mean beach elevation and shoreline position of ten high-spatial resolution beach surveys. Correlations were statistically significant at all spatial scales, even for beach surveys 10s of kilometers downcoast, and therefore variability at the single point monitoring site was representative of regional coastal behavior, allowing us to examine nearly two decades of continuous coastal evolution. The annual cycle of beach oscillations dominated the signal, typical of this region, with additional, less intense spectral peaks associated with seasonal wave energy fluctuations (~ 45 to 90 days), as well as full lunar (~ 29 days) and semi-lunar (~ 13 days; spring-neap cycle) tidal cycles. Sand thickness variability was statistically linked to wave energy with a 2 month peak lag, as well as the average of the previous 7–8 months of wave energy. Longer term anomalies in sand thickness were also apparent on time scales up to 15 months. Our analyses suggest that spatially-limited morphological data sets can be extremely valuable (with robust validation) for understanding the details of beach response to wave energy over timescales that are not resolved by typical survey intervals, as well as the regional behavior of coastal systems.

California↗

The concept of land bridge marshes in the Mississippi River Delta and implications for coastal restoration

Louisiana has high coastal wetland loss rates due to natural processes such as subsidence and anthropogenic activities such as construction of river levees and dams, pervasive alteration of surface hydrology by local industries such as oil and gas, and navigation. With the exception of the Atchafalaya River discharge area, most of Louisiana's marsh coastline is retreating and coastal marshes are degrading. In the inactive degrading delta regions, there exists a previously uncharacterized landform referred to colloquially as coastal ‘land bridge’ marshes. Land bridge marshes are saline or brackish marshes fronting large estuarine bays or lakes with sufficient fetch and wave energy to supply high levels of resuspended sediments to the marsh surface. They are generally linear features that are oriented parallel to the coast and the shoreline front retreats landward due to erosion from wave energy. These marshes persist over time vertically due to input of resuspended sediments but are experiencing rapid edge erosion due to wave attack. Comparison of data from Louisiana's Coastal Reference Monitoring System (CRMS) sites show that land bridge marshes have a greater frequency of higher soil surface elevation and higher soil bulk density than non-land bridge marshes. Because land bridges are vertically stable relative to other coastal wetlands, identification of measures to sustain these landscape features is important. Simulations using MarshMorpho2D, a process-based reduced-complexity morphology model, suggest that protection barriers installed on the seaward side of land bridge marshes will attenuate wave energy and, thus, edge erosion. Shoreline protection that can reduce wave energy but still allow sediment input to marshes include living shorelines, rock barriers, and/or breakwaters. Periodic thin layer nourishment of the marsh surface may be necessary to help sustain vertical growth. Further, marsh creation projects directly landward of land bridge marshes may benefit from their protection from waves and as a source of sediment. Consideration of land bridge marshes as distinct marsh types in the State Master Plan and integrated modeling could help to identify measures to sustain these landscape features.

Louisiana↗

Productivity and linkages of the food web of the southern region of the western Antarctic Peninsula continental shelf

The productivity and linkages in the food web of the southern region of the west Antarctic Peninsula continental shelf were investigated using a multi-trophic level mass balance model. Data collected during the Southern Ocean Global Ocean Ecosystem Dynamics field program were combined with data from the literature on the abundance and diet composition of zooplankton, fish, seabirds and marine mammals to calculate energy flows in the food web and to infer the overall food web structure at the annual level. Sensitivity analyses investigated the effects of variability in growth and biomass of Antarctic krill ( Euphausia superba ) and in the biomass of Antarctic krill predators on the structure and energy fluxes in the food web. Scenario simulations provided insights into the potential responses of the food web to a reduced contribution of large phytoplankton (diatom) production to total primary production, and to reduced consumption of primary production by Antarctic krill and mesozooplankton coincident with increased consumption by microzooplankton and salps. Model-derived estimates of primary production were 187–207 g C m −2 y −1 , which are consistent with observed values (47–351 g C m −2 y −1 ). Simulations showed that Antarctic krill provide the majority of energy needed to sustain seabird and marine mammal production, thereby exerting a bottom-up control on higher trophic level predators. Energy transfer to top predators via mesozooplanton was a less efficient pathway, and salps were a production loss pathway because little of the primary production they consumed was passed to higher trophic levels. Increased predominance of small phytoplankton (nanoflagellates and cryptophytes) reduced the production of Antarctic krill and of its predators, including seabirds and seals.

Progress in Oceanography↗

Consumer isoscapes reveal heterogeneous food webs in deep-sea submarine canyons and adjacent slopes

The deep sea is the largest biome on earth, but one of the least studied despite its critical role in global carbon cycling and climate buffering. Deep-sea organisms largely rely on particulate organic matter from the surface ocean for energy – these organisms in turn play critical roles in energy transport, transformation, storage, and sequestration of carbon. Within the deep sea, submarine canyons are amongst the most complex and dynamic environments in our oceans, where varied morphology, powerful currents, and variable nutrient conditions influence the distribution of species and transport of organic material throughout the water column and the seafloor. Significant habitat heterogeneity provides ideal substrates for cold-water corals, making submarine canyons of interest to conservation and management. However, how these and other topographic features in the deep ocean influence energy flow and trophic pathways is poorly known. Thus, submarine canyons serve as model systems to track variability in organic material flux and consequential utilization and assimilation by the benthos. In this study, we used an extensive stable isotope dataset to examine food-web structure in Baltimore and Norfolk submarine canyons and compared them to their adjacent slopes located along the U.S. Atlantic margin. Linear models were used to construct geospatially-explicit consumer isoscapes that predicted variation in carbon and nitrogen isotopes across the canyon-slope seascape, providing a predictive map from which to test hypotheses on the distribution and flow of energy resources, relevant to understanding whole community function. Communities were composed of isotopically diverse feeding groups with photosynthetically-derived organic carbon providing the basal food resource. Canyon communities were distinct from the slope, with canyon consumers significantly 13 C-depleted, indicating a greater supply and/or utilization of fresh organic matter compared to the slope. Isoscapes for benthic and suspension feeders were distinct, possibly due to the consumption of different quality organic matter sources (fresh = suspension feeders, old = benthic feeders), each with distinct isotope composition. To our knowledge, our modeled isoscapes represent the first spatially extensive isotopic maps of deep-sea consumers, providing insights into regional-scale variation in stable carbon and nitrogen isotopes for different consumer groups. They provide a baseline for tracking climate-change induced fluctuations in the quality and availability of surface primary production and the consequential impact to benthic communities, which play critical roles in carbon cycling in our world’s oceans.

Progress in Oceanography↗

Temperature and precipitation history of the Arctic

As the planet cooled from peak warmth in the early Cenozoic, extensive Northern Hemisphere ice sheets developed by 2.6 Ma ago, leading to changes in the circulation of both the atmosphere and oceans. From ∼2.6 to ∼1.0 Ma ago, ice sheets came and went about every 41 ka, in pace with cycles in the tilt of Earth’s axis, but for the past 700 ka, glacial cycles have been longer, lasting ∼100 ka, separated by brief, warm interglaciations, when sea level and ice volumes were close to present. The cause of the shift from 41 ka to 100 ka glacial cycles is still debated. During the penultimate interglaciation, ∼130 to ∼120 ka ago, solar energy in summer in the Arctic was greater than at any time subsequently. As a consequence, Arctic summers were ∼5 °C warmer than at present, and almost all glaciers melted completely except for the Greenland Ice Sheet, and even it was reduced in size substantially from its present extent. With the loss of land ice, sea level was about 5 m higher than present, with the extra melt coming from both Greenland and Antarctica as well as small glaciers. The Last Glacial Maximum (LGM) peaked ∼21 ka ago, when mean annual temperatures over parts of the Arctic were as much as 20 °C lower than at present. Ice recession was well underway 16 ka ago, and most of the Northern Hemisphere ice sheets had melted by 6 ka ago. Solar energy reached a summer maximum (9% higher than at present) ∼11 ka ago and has been decreasing since then, primarily in response to the precession of the equinoxes. The extra energy elevated early Holocene summer temperatures throughout the Arctic 1–3 °C above 20th century averages, enough to completely melt many small glaciers throughout the Arctic, although the Greenland Ice Sheet was only slightly smaller than at present. Early Holocene summer sea ice limits were substantially smaller than their 20th century average, and the flow of Atlantic water into the Arctic Ocean was substantially greater. As summer solar energy decreased in the second half of the Holocene, glaciers re-established or advanced, sea ice expanded, and the flow of warm Atlantic water into the Arctic Ocean diminished. Late Holocene cooling reached its nadir during the Little Ice Age (about 1250–1850 AD), when sun-blocking volcanic eruptions and perhaps other causes added to the orbital cooling, allowing most Arctic glaciers to reach their maximum Holocene extent. During the warming of the past century, glaciers have receded throughout the Arctic, terrestrial ecosystems have advanced northward, and perennial Arctic Ocean sea ice has diminished. Here we review the proxies that allow reconstruction of Quaternary climates and the feedbacks that amplify climate change across the Arctic. We provide an overview of the evolution of climate from the hot-house of the early Cenozoic through its transition to the ice-house of the Quaternary, with special emphasis on the anomalous warmth of the middle Pliocene, early Quaternary warm times, the Mid Pleistocene transition, warm interglaciations of marine isotope stages 11, 5e, and 1, the stage 3 interstadial, and the peak cold of the last glacial maximum.

Quaternary Science Reviews↗

Growth of grain contacts in halite by solution-transfer: Implications for diagenesis, lithification, and strength recovery

Lithification of a sediment to form a rock may involve cementation, diagenetic reactions, or compaction under load. In these experiments, convex halite lenses were pressed against fiat halite plates at 50° C in a specially designed microscope stage. A saturated brine surrounded the samples, which were observed during the experiment in transmitted and reflected light. No time-dependent convergence was observed between the two crystals, even at mean normal stresses of up to 14 M Pa at the contact. In all experiments, however, the contact (or neck) between the two crystals grew with time as material dissolved from the surrounding lens surfaces, diffused through the pore fluid, and precipitated at the neck. Neck growth rates did not appear to correlate with the applied load, but did systematically increase as the misorientation between the two crystals decreased. Our analysis of the shapes of fluid inclusions formed along the grain boundary within the neck suggests that the grain boundary energy is about 1.8 times greater than the fluid-solid interfacial energy. Neck growth appears to be driven by the reduction of interfacial energy rather than by mechanical loads. Assuming that the interfacial energy is isotropic, and incorporating some geometric simplifications, two models of neck growth were formulated. The rate-controlling steps in the models were either precipitation or diffusion in the pore fluid. The data fit either model equally well. Both models predict that neck growth rate will be rapid at first but will decrease with time, as was observed. Neck growth will lead to an increase in real area of contact between grains in a granular aggregate even without the introduction of supersaturated solutions and may be important in the induration of sediments and the strengthening of fault gouge.

International Geophysics↗

Hydrologic modeling of a perennial firn aquifer in southeast Greenland

A conceptual model, based on field observations and assumed physics of a perennial firn aquifer near Helheim Glacier (southeast Greenland), is evaluated via steady-state 2-D simulation of liquid water flow and energy transport with phase change. The simulation approach allows natural representation of flow and energy advection and conduction that occur in vertical meltwater recharge through the unsaturated zone and in lateral flow within the saturated aquifer. Agreement between measured and simulated aquifer geometry, temperature, and recharge and discharge rates confirms that the conceptual field-data-based description of the aquifer is consistent with the primary physical processes of groundwater flow, energy transport and phase change. Factors that are found to control simulated aquifer configuration include surface temperature, meltwater recharge rate, residual total-water saturation and capillary fringe thickness. Simulation analyses indicate that the size of perennial firn aquifers depends primarily on recharge rates from surface snowmelt. Results also imply that the recent aquifer expansion, likely due to a warming climate, may eventually produce lakes on the ice-sheet surface that would affect the surface energy balance.

Journal of Glaciology↗

Feeding ecology and energetic relationships with habitat of blue catfish, Ictalurus furcatus, and flathead catfish, Pylodictis olivaris, in the lower Mississippi River, U.S.A.

We examined feeding of blue catfish, Ictalurus furcatus, and flathead catfish, Pylodictis olivaris, collected from floodplain lake, secondary (side) river channel, and main river channel habitats in the lower Mississippi River (LMR), U.S.A. We described the feeding ecology of two large river catfish species within the context of whether off-channel habitats in the LMR (i.e., floodplain lakes and secondary channels) potentially provided energetic benefits to these fishes as purported in contemporary theory on the ecology of large rivers. We used diet composition and associated caloric densities of prey consumed as indicators of energetic benefit to catfishes. Differences in diet among habitats were strong for blue catfish, but weak for flathead catfish; consumed foods generally differed among habitats in caloric (energy) content. Caloric densities of consumed foods were generally greatest in floodplain lakes, least in the main river channel, and intermediate in secondary river channels. Strong between-year variation in diet was observed, but only for blue catfish. Blue catfish fed disproportionately on lower-energy zebra mussels in the main river channel during 1997, and higher-energy chironomids and oligochaetes in floodplain lakes during 1998. Results suggested that although off-channel habitats potentially provided greater energetic return to catfishes in terms of foods consumed, patterns of feeding and subsequent energy intake may vary annually. Energetic benefits associated with off-channel habitats as purported under contemporary theory (e.g., the 'flood-pulse concept') may not be accrued by catfishes every year in the LMR.

Environmental Biology of Fishes↗

Measurements of storm and nonstorm circulation in the northern Adriatic: October 2002 Through April 2003

Fifteen bottom-mounted Acoustic Doppler Current Profilers were deployed from October 2002 through April 2003 in the northern Adriatic Sea. Average transport from the portion of the Western Adriatic Current (WAC) along the Italian slope was 0.1470 ?? 0.0043 Sv, punctuated by bursts of more than twice that amount during storm events. Monthly means were calculated with times of strong wind-driven circulation excluded. These suggest a 2002/2003 seasonal separation consisting of October, December through February, and March through April. An extreme Po River flood influenced November conditions making seasonal categorization difficult. October generally had more kinetic energy and more vertical structure than other months, and near-inertial waves were more frequent in April and October. The Eastern Adriatic Current (EAC)/WAC (i.e. inflow/outflow) system was clearly present in the means for all months. The cyclonic gyre north of the Po River was present October through February. Generally, in the WAC, over 50% of kinetic energy came from vertically uniform monthly mean flows. Elsewhere, eddy kinetic energy was stronger than mean kinetic energy with 10-40% contributions for vertically uniform monthly mean flows, 40-60% for vertically uniform monthly varying flows, and 10-30% for vertically varying monthly varying flows. Mean currents for bora storms indicate enhancement of the EAC/WAC and the cyclonic northern gyre, a shift toward Kvarner Bay in EAC direction, a circulation null point south of the Po, and double-gyre bifurcation of flow at Istria. Strengthening of both the EAC and WAC also occurs during sirocco storms. Copyright 2007 by the American Geophysical Union.

Journal of Geophysical Research C: Oceans↗

The 25 October 2010 Mentawai tsunami earthquake, from real-time discriminants, finite-fault rupture, and tsunami excitation

The moment magnitude 7.8 earthquake that struck offshore the Mentawai islands in western Indonesia on 25 October 2010 created a locally large tsunami that caused more than 400 human causalities. We identify this earthquake as a rare slow‐source tsunami earthquake based on: 1) disproportionately large tsunami waves; 2) excessive rupture duration near 125 s; 3) predominantly shallow, near‐trench slip determined through finite‐fault modeling; and 4) deficiencies in energy‐to‐moment and energy‐to‐duration‐cubed ratios, the latter in near‐real time. We detail the real‐time solutions that identified the slow‐nature of this event, and evaluate how regional reductions in crustal rigidity along the shallow trench as determined by reduced rupture velocity contributed to increased slip, causing the 5–9 m local tsunami runup and observed transoceanic wave heights observed 1600 km to the southeast.

Mentawai Islands↗

Hillslope hydrology in global change research and earth system modeling

Earth System Models (ESMs) are essential tools for understanding and predicting global change, but they cannot explicitly resolve hillslope‐scale terrain structures that fundamentally organize water, energy, and biogeochemical stores and fluxes at subgrid scales. Here we bring together hydrologists, Critical Zone scientists, and ESM developers, to explore how hillslope structures may modulate ESM grid‐level water, energy, and biogeochemical fluxes. In contrast to the one‐dimensional (1‐D), 2‐ to 3‐m deep, and free‐draining soil hydrology in most ESM land models, we hypothesize that 3‐D, lateral ridge‐to‐valley flow through shallow and deep paths and insolation contrasts between sunny and shady slopes are the top two globally quantifiable organizers of water and energy (and vegetation) within an ESM grid cell. We hypothesize that these two processes are likely to impact ESM predictions where (and when) water and/or energy are limiting. We further hypothesize that, if implemented in ESM land models, these processes will increase simulated continental water storage and residence time, buffering terrestrial ecosystems against seasonal and interannual droughts. We explore efficient ways to capture these mechanisms in ESMs and identify critical knowledge gaps preventing us from scaling up hillslope to global processes. One such gap is our extremely limited knowledge of the subsurface, where water is stored (supporting vegetation) and released to stream baseflow (supporting aquatic ecosystems). We conclude with a set of organizing hypotheses and a call for global syntheses activities and model experiments to assess the impact of hillslope hydrology on global change predictions.

Water Resources Research↗

The high-pressure electronic structure of magnesiowustite (Mg, Fe)O: applications to the physics and chemistry of the lower mantle

The electronic structure of magnesiowustite is investigated using self-consistent field X α scattered wave (SCF- X α-SW) molecular orbital calculations on (FeO 6 ) 10− and (FeMg 12 O 14 ) 2− clusters. Calculated one-electron transition energies are used to interpret the optical spectrum of (Mg, Fe)O. The results are applied to the electrical and thermal conductivity of the lower mantle. The spin pairing of Fe 2+ and the effect of pressure on bonding in magnesiowustite, with some inferences regarding the incorporation of oxygen in the outer core, is also addressed. The approach used here appears to give a reliable description of the energy and pressure dependence of the spin-allowed 5 T 2 g → 5 E g ligand field transition and the spin-pairing transition of Fe 2+ in (Mg, Fe)O. However, the oxygen to metal charge transfer transitions in (Mg, Fe)O are not as reliably determined insofar as the p - d band gap varies with cluster size and the energies of the charge transfer states cannot be found without including configurational interaction. Nevertheless, it is argued that the charge transfer transitions that are intrinsic to (Fe, Mg)O are of a sufficiently high energy to be irrelevant to the electrical and thermal conductivity of the lower mantle. This is especially true if Fe 2+ adopts the low-spin configuration. The geophysically significant properties of (Fe, Mg)O probably result from defect Fe 3+ .

Journal of Geophysical Research↗

Source characteristics of the Loma Prieta, California, Earthquake of October 18, 1989 from global digital seismic data

Displacement, velocity and acceleration records of P and SH body waves recorded at teleseismic distances are analysed to determine the static and dynamic source parameters of the Loma Prieta, California earthquake of October 18, 1989 ( m b 6.6, M s 7.1). Three distinct bursts of energy corresponding to three subevents can be recognized in most records. The displacement waveforms indicate that the first subevent contributes negligible moment while the largest releases of moment and energy are controlled by the second and third subevents. The second and third subevents are located north and south of the initial nucleation. A fourth small subevent needed to model later features of the P waveforms suggests that slow slip continued after the major releases of energy occurred. The waveforms are fit with a fault plane solution having strike 130°, dip 65° and slip 140° for all the subevents. The focal depths of the two major subevents are 16 and 12 km, and their asperity radii are 4.0 and 6.0 km, respectively. The seismic moment, M 0 , is 2.2×10 26 dyne-cm. From spectral analysis of teleseismic velocity, the radiated energy, E s , is estimated to be 1.1×10 22 dyne-cm, implying an apparent stress of 15 bars. From the high-frequency level of the teleseismic acceleration spectrum and a rupture area of 440 km 2 , we derive a dynamic stress drop of 51 bars.

California↗