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Geologic and hydrogeologic characteristics of the Ogallala Formation and White River Group, Belvoir Ranch near Cheyenne, Laramie County, Wyoming

The geologic and hydrogeologic characteristics of Tertiary lithostratigraphic units (Ogallala Formation and White River Group) that typically compose or underlie the High Plains aquifer system in southeastern Wyoming were described physically and chemically, and evaluated at a location on the Belvoir Ranch in Laramie County, Wyoming. On the basis of this characterization and evaluation, three Tertiary lithostratigraphic units were identified using physical and chemical characteristics determined during this study and previous studies, and these three units were determined to be correlative with three identified hydrogeologic units composing the groundwater system at the study site—a high-yielding aquifer composed of the entire saturated thickness of the heterogeneous and coarse-grained fluvial sediments assigned to the Ogallala Formation (Ogallala aquifer); an underlying confining unit composed primarily of very fine-grained volcaniclastic sediments and mudrocks assigned to the Brule Formation of the White River Group and some additional underlying sediments that belong to either the Brule or Chadron Formation, or both (Brule confining unit); and an underlying low-yielding aquifer composed primarily of poorly sorted fluvial sediments assigned to the Chadron Formation of the White River Group (Chadron aquifer). Despite widely varying sediment heterogeneity and consolidation, some limited hydraulic connection throughout the full vertical extent of the Ogallala aquifer was indicated but not conclusively proven by interpretation of similar chemical and isotopic characteristics, modern apparent groundwater ages, and similar hydraulic-head responses measured continuously in two Ogallala aquifer monitoring wells installed for this study at two different widely separated (83 feet) depth intervals. Additional work beyond the scope of this study, such as aquifer tests, would be required to conclusively determine hydraulic connection within the Ogallala aquifer. Groundwater levels (hydraulic heads) measured continuously using water-level recorders in both monitoring wells completed in the Ogallala aquifer showed a consistent strong upward vertical gradient in the Ogallala aquifer, indicating the potential for water to move from deeper to shallower parts of the aquifer, regardless of the time of year and the presumed effects of pumping of public-supply and industrial wells in the area. Continuous measurement of groundwater levels in the shallowest monitoring well, installed near the water table, and examination of subsequently constructed water-level hydrographs indicated substantial groundwater recharge is likely during the spring of 2009 and 2010 from the ephemeral stream (Lone Tree Creek) located adjacent to the study site that flows primarily in response to spring snowmelt from the adjacent Laramie Mountains and surface runoff from precipitation events. Using the water-table fluctuation method, groundwater recharge was estimated to be about 13 inches for the period beginning in early October 2009 and ending in late June 2010, and about 4 inches for the period beginning in March 2011 and ending in early July 2011. Comparison of previously measured groundwater levels (hydraulic heads) and groundwater-quality characteristics in nearby monitoring wells completed in the Chadron aquifer with those measured in the two monitoring wells installed for this study in the Ogallala aquifer, combined with detailed lithologic characterization, strongly indicated the Brule confining unit hydraulically confines and isolates the Chadron aquifer from the overlying Ogallala aquifer, thus likely limiting hydraulic connection between the two units. Consequently, because of the impermeable nature of the Brule confining unit and resulting hydraulic separation of the Ogallala and Chadron aquifers, and compared with local and regional hydrostratigraphic definitions of the High Plains aquifer system, the groundwater system in Tertiary lithostratigraphic units overlying the Upper Cretaceous Lance Formation at the location studied on the Belvoir Ranch was defined as being composed of, from shallowest to deepest, the High Plains aquifer system (high-yielding Ogallala aquifer only, composed of the saturated Ogallala Formation); the Brule confining unit composed of the Brule Formation of the White River Group and an underlying fine-grained depth interval with sediments that belong to either the Brule or Chadron Formation, or both; and the low-yielding Chadron aquifer (composed of poorly sorted coarse-grained sediments with substantial fine-grained matrix material assigned to the Chadron Formation of the White River Group).

Wyoming↗

An experiment in representative ground-water sampling for water- quality analysis

Obtaining a sample of groundwater that accurately represents the concentration of a chemical constituent in an aquifer is an important aspect of groundwater-quality studies. Varying aquifer and constituent properties may cause chemical constituents to move within selectively separate parts of the aquifer. An experiment was conducted in an agricultural region in south-central Kansas to address questions related to representative sample collection. Concentrations of selected constituents in samples taken from observation wells completed in the upper part of the aquifer were compared to concentrations in samples taken from irrigation wells to determine if there was a significant difference. Water in all wells sampled was a calcium bicarbonate type with more than 200 mg/L hardness and about 200 mg/L alkalinity. Sodium concentrations were also quite large (about 40 mg/L). There was a significant difference in the nitrite-plus-nitrate concentrations between samples from observation and irrigation wells. The median concentration of nitrite plus nitrate in water from observation wells was 5.7 mg/L compared to 3.4 mg/L in water from irrigation wells. The differences in concentrations of calcium, magnesium, and sodium (larger in water from irrigation wells) were significant at the 78% confidence level but not at the 97% confidence level. Concentrations of the herbicide, atrazine, were less than the detection limit of 0.1 micrograms/L in all but one well. (USGS)

Water-Resources Investigations Report↗

Preliminary analysis of the shallow ground-water system in the vicinity of the Grand Calumet River/Indiana Harbor Canal, northwestern Indiana

The shallow groundwater system in the vicinity of the Grand Calumet River-Indiana Harbor Canal, Indiana was analyzed from June 1985 to May 1986. This analysis was done to obtain detailed information about the physical characteristics of the Calumet aquifer and the shallow groundwater flow system. 36 shallow wells were installed and sediment samples were collected at 26 sites. Water level measurements were made in 45 wells. Data indicate that the aquifer consists of fine-grained to medium-grained sand, locally overlain by slag fill. Aquifer thickness is 0 to 65 ft. This aquifer is underlain by about 100 ft of glacial till and lacustrine clay that overlies carbonate bedrock of Silurian age. Broad, low-relief water table mounds occur between the major surface water drains. The crests of these mounds form major east-west-trending water table divides. Northwest of the Indiana Harbor Canal (IHC), a narrow water table ridge parallels the Lake Michigan shoreline and connects to a somewhat circular, low mound northwest of the IHC. Shallow groundwater generally flows from these water table mounds to the major streams or to Lake Michigan. Groundwater also flows to small ditches, wetlands, and sewer lines. Stream/aquifer relations along the Grand Calumet River/IHC were quite complex. Digital model simulations of a conceptual north-south section near the middle of the study area indicate that discharge of groundwater to small ditches and leaky sewer lines has lowered the water table by several ft from predevelopment levels. Simulations also indicate that downward leakage to the bedrock may have contributed to the decline in the water table.

Indiana↗

Budgets and chemical characterization of groundwater for the Diamond Valley flow system, central Nevada, 2011–12

The Diamond Valley flow system consists of six hydraulically connected hydrographic areas in central Nevada. The general down-gradient order of the areas are southern and northern Monitor Valleys, Antelope Valley, Kobeh Valley, Stevens Basin, and Diamond Valley. Groundwater flow in the Diamond Valley flow system terminates at a large playa in the northern part of Diamond Valley. Concerns relating to continued water-resources development of the flow system resulted in a phased hydrologic investigation that began in 2005 by the U.S. Geological Survey in cooperation with Eureka County. This report presents the culmination of the phased investigation to increase understanding of the groundwater resources of the basin-fill aquifers in the Diamond Valley flow system through evaluations of groundwater chemistry and budgets. Groundwater chemistry was characterized using major ions and stable isotopes from groundwater and precipitation samples. Groundwater budgets accounted for all inflows, outflows, and changes in storage, and were developed for pre-development (pre-1950) and recent (average annual 2011–12) conditions. Major budget components include groundwater discharge by evapotranspiration and groundwater withdrawals; groundwater recharge by precipitation, and interbasin flow; and storage change. Groundwater in the basin-fill aquifer of the Diamond Valley flow system was mostly a calcium or sodium bicarbonate water type and generally within acceptable drinking-water standards. The general water type was similar among the individual hydrographic areas. Stable isotopes of oxygen-18 and deuterium from precipitation varied seasonally, such that enrichment from evaporation was greater during warmer months than cooler months. The isotopic signature of shallow groundwater was similar to cool season precipitation, indicating recharge was relatively recent (similar to recent climatic conditions) and was derived from cool season precipitation. Site-scale groundwater evapotranspiration was estimated from eddy-covariance and micrometeorological measurements collected at four sites and ranged from 0.15 feet per year in sparse, undisturbed shrubland to 1.13 feet per year in a grassland meadow. Vegetation indices calculated from satellite imagery and field mapping were used to define three evapotranspiration units (shrubland, grassland, and playa) and to extrapolate site-scale groundwater evapotranspiration rates to basin-scale estimates. Annual pre-development groundwater evapotranspiration for individual hydrographic areas ranged from 2,900 acre-feet per year (acre-ft/yr) in northern Monitor Valley to 35,000 acre-ft/yr in Diamond Valley. Total groundwater evapotranspiration from the Diamond Valley flow system under pre-development conditions was about 70,000 acre-ft/yr. Areas of irrigated land in the Diamond Valley flow system increased from less than 5,000 acres in the early 1960s to more than 25,000 acres in 2012 and are mostly for growing alfalfa in southern Diamond Valley. Annual (2011–12) net groundwater withdrawals for irrigation, assumed to be the volume of groundwater consumed by crops and pastureland, ranged from about 420 acre-ft/yr in Antelope Valley to 67,000 acre-ft/yr in Diamond Valley. Total net groundwater withdrawals for irrigation in the Diamond Valley flow system were about 69,000 acre-ft/yr (2011–12). Groundwater recharge, the largest inflow component to the Diamond Valley flow system, was determined as the sum of groundwater evapotranspiration and net subsurface outflow (subsurface outflow minus subsurface inflow). Annual groundwater recharge estimates ranged from 200 acre-ft/yr in Stevens Basin to 35,000 acre-ft/yr in Diamond Valley. Subsurface flow between hydrographic basins was evaluated using estimated transmissivity, groundwater-flow sections derived from remotely sensed imagery, and hydraulic gradients determined from 2012 water-level data. Subsurface outflow ranged from 0 acre-ft/yr for Diamond Valley to 3,400 acre-ft/yr for northern Monitor Valley into western Kobeh Valley. Subsurface inflow ranged from 0 acre-ft/yr for southern Monitor Valley to 4,200 acre-ft/yr for Kobeh Valley from northern Monitor and Antelope Valleys. The pre-development, steady state, groundwater budget for the Diamond Valley flow system was estimated at about 70,000 acre-ft/yr of inflow and outflow. During years 2011–12, inflow components of groundwater recharge from precipitation and subsurface inflow from adjacent basins totaled 70,000 acre-ft/yr for the DVFS, whereas outflow components included 64,000 acre-ft/yr of groundwater evapotranspiration and 69,000 acre-ft/yr of net groundwater withdrawals, or net pumpage. Spring discharge in northern Diamond Valley declined about 6,000 acre-ft/yr between pre-development time and years 2011–12. Assuming net groundwater withdrawals minus spring flow decline is equivalent to the storage change, the 2011–12 summation of inflow and storage change was balanced with outflow at about 133,000 acre-ft/yr.

Nevada↗

Simulations of potential future conditions in the cache critical groundwater area, Arkansas

A three-dimensional finite-difference model for part of the Mississippi River Valley alluvial aquifer in the Cache Critical Groundwater Area of eastern Arkansas was constructed to simulate potential future conditions of groundwater flow. The objectives of this study were to test different pilot point distributions to find reasonable estimates of aquifer properties for the alluvial aquifer, to simulate flux from rivers, and to demonstrate how changes in pumping rates for different scenarios affect areas of long-term water-level declines over time. The model was calibrated using the parameter estimation code. Additional calibration was achieved using pilot points with regularization and singular value decomposition. Pilot point parameter values were estimated at a number of discrete locations in the study area to obtain reasonable estimates of aquifer properties. Nine pumping scenarios for the years 2011 to 2020 were tested and compared to the simulated water-level heads from 2010. Hydraulic conductivity values from pilot point calibration ranged between 42 and 173 m/d. Specific yield values ranged between 0.19 and 0.337. Recharge rates ranged between 0.00009 and 0.0006 m/d. The model was calibrated using 2,322 hydraulic head measurements for the years 2000 to 2010 from 150 observation wells located in the study area. For all scenarios, the volume of water depleted ranged between 5.7 and 23.3 percent, except in Scenario 2 (minimum pumping rates), in which the volume increased by 2.5 percent.

Arkansas↗

Yield and quality of ground water from stratified-drift aquifers, Taunton River basin, Massachusetts : executive summary

Water shortages are a chronic problem in parts of the Taunton River basin and are caused by a combination of factors. Water use in this part of the Boston metropolitan area is likely to increase during the next decade. The Massachusetts Division of Water Resources projects that about 50% of the cities and towns within and on the perimeter of the basin may have water supply deficits by 1990 if water management projects are not pursued throughout the 1980s. Estimates of the long-term yield of the 26 regional aquifers indicate that the yields of the two most productive aquifers equal or exceed 11.9 and 11.3 cu ft/sec, 90% of the time, respectively, if minimum stream discharge is maintained at 99.5% flow duration. Eighteen of the 26 aquifers were pumped for public water supply during 1983. Further analysis of the yield characteristics of these 18 aquifers indicates that the 1983 pumping rate of each of these 18 aquifers can be sustained at least 70% of the time. Selected physical properties and concentrations of major chemical constituents in groundwater from the stratified-drift aquifers at 80 sampling sites were used to characterize general water quality in aquifers throughout the basin. The pH of the groundwater ranged from 5.4 to 7.0. Natural elevated concentrations of Fe and Mn in water in the stratified-drift aquifers are present locally in the basin. Natural concentrations of these two metals commonly exceed the limits of 0.3 mg/L for Fe and 0.05 mg/L for Mn recommended for drinking water. Fifty-one analyses of selected trace metals in groundwater samples from stratified-drift aquifers throughout the basin were used to characterize trace metal concentrations in the groundwater. Of the 10 constituents sampled that have US EPA limits recommended for drinking water, only the Pb concentration in water at one site (60 micrograms/L) exceeded the recommended limit of 50 micrograms/L. Analyses of selected organic compounds in water in the stratified-drift aquifers at 74 locations revealed that 13 of the sample contained one or more of the following compounds: chloroform; carbon tetrachloride; dichloroethane; dichloroethylene; tetrachloroethylene; and, toluene. (Lantz-PTT)

Water-Resources Investigations Report↗

Hydrogeology, numerical simulation of groundwater flow, and effects of future water use and drought for reach 1 of the Washita River alluvial aquifer, Roger Mills and Custer Counties, western Oklahoma, 1980–2015

The Washita River alluvial aquifer is a valley-fill and terrace alluvial aquifer along the valley of the Washita River in western Oklahoma that provides a productive source of groundwater for agricultural irrigation and water supply. The Oklahoma Water Resources Board (OWRB) has designated the westernmost section of the aquifer in Roger Mills and Custer Counties, Okla., as reach 1 of the Washita River alluvial aquifer; reach 1 is the focus of this report. The OWRB issued an order on November 13, 1990, that established the maximum annual yield (MAY; 120,320 acre-feet per year [acre-ft/yr]) and equal-proportionate-share (EPS) pumping rate (2.0 acre-feet per acre per year [(acre-ft/acre)/yr]) for reach 1 of the Washita River alluvial aquifer. The MAY and EPS were based on hydrologic investigations that evaluated the effects of potential groundwater withdrawals on groundwater availability in the Washita River alluvial aquifer. Every 20 years, the OWRB is statutorily required to update the hydrologic investigation on which the MAY and EPS were based. Because 30 years have elapsed since the last order was issued, the U.S. Geological Survey, in cooperation with the OWRB, conducted a new hydrologic investigation and evaluated the effects of potential groundwater withdrawals on groundwater flow and availability in the Washita River alluvial aquifer. The Washita River is the primary source of inflow to Foss Reservoir, a Bureau of Reclamation reservoir constructed in 1961 for flood control, water supply, and recreation. Foss Reservoir provides water for Bessie, Clinton, New Cordell, and Hobart, Okla. Nearly 98 percent of the total groundwater use from the Washita River alluvial aquifer during 1967 to 2015 was for irrigation; other uses of groundwater in the study area include public supply, mining, and agriculture. A hydrogeologic framework was developed for the Washita River alluvial aquifer and included the physical characteristics of the aquifer, the geologic setting, the hydraulic properties of hydrogeologic units, the potentiometric surface (water table), and groundwater-flow directions at a scale that captures the regional controls on groundwater flow. The Washita River alluvial aquifer consists of alluvium and terrace deposits that were transported primarily by water and range from clay to gravel in size. The terrace includes windblown deposits of silt size and, in some cases, contains gravel laid down at several levels along former courses of present-day rivers. A conceptual flow model is a simplified description of the aquifer system that includes hydrologic boundaries, major inflow and outflow sources of the groundwater-flow system, and a conceptual water budget with the estimated mean flows between those hydrologic boundaries. During the study period 1980–2015, mean annual groundwater withdrawals, predominantly used for agricultural irrigation, totaled 5,502 acre-ft/yr, or 14 percent of aquifer outflows. When applied across the 132-square-mile aquifer area used for modeling purposes (84,366 acres), mean annual recharge of 3.15 inches per year corresponds to a mean annual recharge volume of 22,169 acre-ft/yr, or 56 percent of aquifer inflows. The annual saturated-zone evapotranspiration outflow was 11,828 acre-ft/yr for the Washita River alluvial aquifer, or about 30 percent of aquifer outflows. For the Washita River alluvial aquifer, lateral flow was 17,157 acre-ft/yr, or 44 percent of the aquifer inflows. The conceptual flow model and hydrogeologic framework were used to conceptualize, design, and build the numerical groundwater-flow model. A numerical groundwater-flow model of the Washita River alluvial aquifer was constructed by using MODFLOW-2005. The Washita River alluvial aquifer groundwater-model grid was spatially discretized into 350-foot (ft) cells and two layers. Layer 1 represented the undifferentiated alluvium and terrace deposits of Quaternary age, and layer 2 represented the bedrock of Permian age, which was given a uniform nominal thickness of 100 ft. The groundwater-simulation period was temporally discretized into 433 monthly transient stress periods, representing January 1980 to December 2015. An initial 365-day steady-state stress period was configured to represent mean annual inflows and outflows from the Washita River alluvial aquifer for the study period. The groundwater-flow model was calibrated manually and by automated adjustment of model inputs by using PEST++. Calibration targets for the Washita River alluvial aquifer model included groundwater-level observations and reservoir-stage observations, as well as base-flow and stream-seepage estimates. Three groundwater-availability scenarios were used in the calibrated groundwater model to (1) estimate the EPS pumping rate that retains the saturated thickness that meets the minimum 20-year life of the aquifer, (2) quantify the effects of projected pumping rates on groundwater storage over a 50-year period, and (3) evaluate how projected pumping rates extended 50 years into the future and sustained hypothetical drought conditions over a 10-year period affect base flow and groundwater in storage. The results of the groundwater-availability scenarios could be used by the OWRB to reevaluate the established MAY of groundwater from the Washita River alluvial aquifer. EPS scenarios for the Washita River alluvial aquifer were run for periods of 20, 40, and 50 years. The 20-, 40-, and 50-year EPS pumping rates under normal recharge conditions were 1.7, 1.6, and 1.6 (acre-ft/acre)/yr, respectively. Given the aquifer area used for modeling purposes (84,366 acres), these rates correspond to annual yields of 142,579, 134,986, and 134,986 acre-ft/yr, respectively. Groundwater storage at the end of the 20-year EPS scenario was about 281,000 acre-feet (acre-ft), or about 306,000 acre-ft (52 percent) less than the starting storage. Considering the land-surface area of the Washita River alluvial aquifer and using a specific yield of 0.12, this decrease in storage was equivalent to a mean groundwater-level decline of about 30 ft. The Washita River downstream from Foss Reservoir and most of the streams in the study area were dry at the end of the 20-year EPS scenario. Foss Reservoir stage was below the dead-pool stage of 1,597 ft after about 7 years of pumping in the 20-year EPS scenario. Four projected 50-year groundwater-use scenarios were used to simulate the effects of selected well withdrawal rates on groundwater storage in the Washita River alluvial aquifer. These four scenarios used (1) no groundwater use, (2) groundwater use at the 2015 pumping rate, (3) mean groundwater use for the simulation period, and (4) increasing groundwater use. Groundwater storage after 50 years with no groundwater use was 545,249 acre-ft, or 693 acre-ft (0.1 percent) greater than the initial groundwater storage; this groundwater storage increase is equivalent to a mean groundwater-level increase of 0.1 ft. Groundwater storage at the end of the 50-year period with 2015 pumping rates was 543,831 acre-ft, or 723 acre-ft (0.1 percent) less than the initial storage; this groundwater storage decrease is equivalent to a mean groundwater-level decrease of 0.1 ft. Groundwater storage after 50 years with the mean pumping rate for the study period was 543,202 acre-ft, or 1,349 acre-ft (0.2 percent) less than the initial groundwater storage; this groundwater storage decrease is equivalent to a mean groundwater-level decrease of 0.1 ft. Groundwater storage at the end of the 50-year period with an increasing demand groundwater-pumping rate, which was 38 percent greater than the 2015 groundwater-pumping rate, was 542,584 acre-ft, or 1,967 acre-ft (0.4 percent) less than the initial storage; this groundwater storage decrease is equivalent to a mean groundwater-level decrease of 0.2 ft. A hypothetical 10-year-drought scenario was used to simulate the effects of a prolonged period of reduced recharge on groundwater storage in the Washita River alluvial aquifer and Foss Reservoir stage and storage. To simulate the hypothetical drought, recharge in the calibrated model was reduced by 50 percent during the simulated drought period (1983–1992). Groundwater storage at the end of the drought period in December 1992 was 562,000 acre-ft, or 36,000 acre-ft (6 percent) less than the groundwater storage of the calibrated groundwater model (598,000 acre-ft). At the end of the hypothetical drought, the largest changes in saturated thickness (as great as 43.5 ft) were in the area upgradient from Foss Reservoir, particularly in the terrace at the model boundary. Substantial decreases in the Foss Reservoir stage began during the fall of 1985 in conjunction with base-flow decreases of up to 100 percent at U.S. Geological Survey streamgage 07324200 Washita River near Hammon, Okla. These lake-stage declines outpaced groundwater-level declines in the surrounding aquifer. The minimum Foss Reservoir storage simulated during the drought period was 77,954 acre-ft, which was a decrease of 46 percent from the nondrought storage.

Oklahoma↗

Simulated effects of allocated and projected 2025 withdrawals from the Potomac-Raritan-Magothy aquifer system, Gloucester and Northeastern Salem Counties, New Jersey

Withdrawals from the Potomac-Raritan-Magothy aquifer system in New Jersey, which includes the Upper, Middle, and Lower Potomac-Raritan-Magothy aquifers, are the principal source of groundwater supply in northern Gloucester and northeastern Salem Counties in the New Jersey Coastal Plain. Water levels in these aquifers have declined in response to pumping. With increased population growth and development expected in Gloucester County and parts of Salem County over the next 2 decades (2005-2025), withdrawals from these aquifers also are expected to increase. A steady-state groundwater-flow model, developed to simulate flow in the Potomac-Raritan-Magothy aquifer system in northern Gloucester and northeastern Salem Counties, was calibrated to withdrawal conditions in 1998, when groundwater withdrawals from the Potomac-Raritan-Magothy aquifer system in the model area were more than 10,100 Mgal/yr (million gallons per year). Withdrawals from water-purveyor wells accounted for about 63 percent of these withdrawals, and withdrawals from industrial self-supply wells accounted for about 32 percent. Withdrawals from agricultural-irrigation, commercial self-supply, and domestic self-supply wells accounted for the remaining 5 percent. Results of the 2000 baseline groundwater-flow simulation, incorporating average annual 1999-2001 groundwater withdrawals, indicate that the average simulated water levels in the Upper, Middle, and Lower Potomac-Raritan-Magothy aquifers are 31, 27, and 30 feet below the National Geodetic Vertical Datum of 1929 (NGVD 29), respectively, and the lowest simulated water levels are 77, 65, and 59 feet below NGVD 29, respectively. In the full-allocation scenario, the maximum State-permitted (allocated) groundwater withdrawals totaled 16,567 Mgal/yr, an increase of 72 percent from the 2000 baseline simulation. Results of the full-allocation simulation indicate that the average simulated water levels in the Upper, Middle, and Lower Potomac-Raritan-Magothy aquifers are 49, 43, and 48 feet below NGVD 29, respectively, which are 18, 16, and 18 feet lower, respectively, than in the 2000 baseline simulation. The lowest simulated water levels are 156, 95, and 69 feet below NGVD 29, respectively, which are 79, 30, and 10 feet lower, respectively, than in the 2000 baseline simulation. Simulated net flow from the Potomac-Raritan-Magothy aquifer system to streams is 8,441 Mgal/yr in the 2000 baseline simulation but is 6,018 Mgal/yr in the full-allocation scenario, a decrease of 29 percent from the 2000 baseline simulation. Simulated net flow in the 2000 baseline simulation is 1,183 Mgal/yr from the aquifer system to the Delaware River but in the full-allocation scenario is 1,816 Mgal/yr from the river to the aquifer system. Four other simulations were conducted that incorporated full-allocation conditions at water-purveyor wells in Critical Area 2 but increased or decreased withdrawals at selected water-purveyor wells outside Critical Area 2 and agricultural-irrigation and industrial-self-supply wells in the study area. The results of the four simulations also indicate net flow from the Delaware River to the Potomac-Raritan-Magothy aquifer system. A growth scenario was developed to simulate future withdrawals in 2025 estimated from population projections for municipalities in the Salem-Gloucester study area. Simulated withdrawals for this scenario totaled 10,261 Mgal/yr, an increase of 6 percent from the 2000 baseline simulation. This total includes about 25 Mgal/yr withdrawn from the Englishtown aquifer system for domestic self-supply. This scenario incorporated full-allocation withdrawals at water-purveyor wells in Critical Area 2, and increased withdrawals at water-purveyor wells outside Critical Area 2. Results of this simulation indicate that the average simulated water levels in the Upper, Middle, and Lower Potomac-Raritan-Magothy aquifers are 32, 29, and 32 feet below NGVD 29, respectively, which are 1, 2, and

Scientific Investigations Report↗

Assessment of water chemistry of the Coconino aquifer in northeastern Arizona

The Coconino aquifer was investigated as a potential groundwater resource for the Hopi Tribe and Navajo Nation in northeastern Arizona. Basic groundwater chemistry, including major ions, total dissolved solids, and selected trace metal concentrations, are presented and analyzed to characterize the Coconino aquifer. The geochemical compositions of groundwater are associated with changes in geology and groundwater movement and are compared to drinking-water standards to determine suitable areas for potential groundwater resource development. Dissolved-solids concentrations in much of the Coconino aquifer water were higher than the U.S. Environmental Protection Agency’s secondary drinking-water standard of 500 milligrams per liter (mg/L) due to a buried halite body in the southeastern part of the study area. However, trace metal concentrations were generally low. Groundwater may need to be treated for high dissolved-solids concentrations before it is suitable for use as a resource for the Hopi Tribe and Navajo Nation.

Arizona↗

Control on groundwater flow in a semiarid folded and faulted intermountain basin

The major processes controlling groundwater flow in intermountain basins are poorly understood, particularly in basins underlain by folded and faulted bedrock and under regionally realistic hydrogeologic heterogeneity. To explore the role of hydrogeologic heterogeneity and poorly constrained mountain hydrologic conditions on regional groundwater flow in contracted intermountain basins, a series of 3-D numerical groundwater flow models were developed using the South Park basin, Colorado, USA as a proxy. The models were used to identify the relative importance of different recharge processes to major aquifers, to estimate typical groundwater circulation depths, and to explore hydrogeologic communication between mountain and valley hydrogeologic landscapes. Modeling results show that mountain landscapes develop topographically controlled and predominantly local-scale to intermediate-scale flow systems. Permeability heterogeneity of the fold and fault belt and decreased topographic roughness led to permeability controlled flow systems in the valley. The structural position of major aquifers in the valley fold and fault belt was found to control the relative importance of different recharge mechanisms. Alternative mountain recharge model scenarios showed that higher mountain recharge rates led to higher mountain water table elevations and increasingly prominent local flow systems, primarily resulting in increased seepage within the mountain landscape and nonlinear increases in mountain block recharge to the valley. Valley aquifers were found to be relatively insensitive to changing mountain water tables, particularly in structurally isolated aquifers inside the fold and fault belt.

Colorado↗

Comparison of age distributions estimated from environmental tracers by using binary-dilution and numerical models of fractured and folded karst: Shenandoah Valley of Virginia and West Virginia, USA

Measured concentrations of environmental tracers in spring discharge from a karst aquifer in the Shenandoah Valley, USA, were used to refine a numerical groundwater flow model. The karst aquifer is folded and faulted carbonate bedrock dominated by diffuse flow along fractures. The numerical model represented bedrock structure and discrete features (fault zones and springs). Concentrations of 3 H, 3 He, 4 He, and CFC-113 in spring discharge were interpreted as binary dilutions of young (0–8 years) water and old (tracer-free) water. Simulated mixtures of groundwater are derived from young water flowing along shallow paths, with the addition of old water flowing along deeper paths through the model domain that discharge to springs along fault zones. The simulated median age of young water discharged from springs (5.7 years) is slightly older than the median age estimated from 3 H/ 3 He data (4.4 years). The numerical model predicted a fraction of old water in spring discharge (0.07) that was half that determined by the binary-dilution model using the 3 H/ 3 He apparent age and 3 H and CFC-113 data (0.14). This difference suggests that faults and lineaments are more numerous or extensive than those mapped and included in the numerical model.

Virginia;West Virginia↗

Hydrogeology of the Canal Creek area, Aberdeen Proving Ground, Maryland

Geologic and borehole geophysical logs made at 77 sites show that the hydrogeologic framework of the study area consists of a sequence of unconsolidated sediments typical of the Coastal Plain of Maryland. Three aquifers and two confining units were delineated within the study area. From the surface down, they are: (1) the surficial aquifer; (2) the upper confining unit; (3) the Canal Creek aquifer; (4) the lower confining unit; and (5) the lower confined aquifer. The aquifer materials range from fine sand to coarse sand and gravel. Clay lenses were commonly found interfingered with the sand, isolating parts of the aquifers. All the units are continuous throughout the study area except for the upper confining unit, which crops out within the study area but is absent in updip outcrops. The unit also is absent within a Pleistocene paleochannel, where it has been eroded. The surficial and Canal Creek aquifers are hydraulically connected where the upper confining unit is absent, and a substantial amount of groundwater may flow between the two aquifers. Currently, no pumping stresses are known to affect the aquifers within the study area. Under current conditions, downward vertical hydraulic gradients prevail at topographic highs, and upward gradients typically prevail near surface-water bodies. Regionally, the direction of groundwater flow in the confined aquifers is to the east and southeast. Significant water level fluctuations correspond with seasonal variations in rainfall, and minor daily fluctuations reflect tidal cycles. (USGS)

Water-Resources Investigations Report↗

Helium isotope studies in the Mojave Desert, California: Implications for groundwater chronology and regional seismicity

We report helium isotope and concentration results for groundwaters from the western Mojave River Basin (MRB), 130 km east of Los Angeles, CA. The basin lies adjacent to the NW-SE trending San Andreas Fault (SAF) system. Samples were collected along two groundwater flowpaths that originate in the San Gabriel Mountains and discharge to the Mojave River located ???32 km to the northeast. Additional groundwater samples were collected from Mojave River Deposits underlying the Mojave River. The primary objective of this study is to identify and quantify crustal and mantle helium contributions to the regional groundwater system. A total of 27 groundwaters, sampled previously for chemistry and isotope systematics (including 14C activity) have measured helium concentrations that increase along flowpaths from 9.9??10-8 to 1.0??10-4 cm3 STP g-1 H2O. Concomitantly, 3He/4He ratios decrease from 0.84RA to 0.11RA (RA equals the 3He/4He ratio in air=1.4??10-6). We did not record 3He/4He ratios equivalent to crustal-production values (???0.02RA) in any sample. Dissolved helium concentrations were resolved into components associated with solubility equilibration, air entrainment, mantle-derivation, in-situ production within the aquifer, and extraneous crustal fluxes. All samples contained the first four components, but only older samples had the superimposed effects of helium derived from a crustal flux. The radiogenic He component has chronological significance, and good concordance between 4He and 14C ages for younger groundwaters (<25,000 year) demonstrates the integrity of the 4 He-chronometer in this setting. Helium-rich waters could also be dated with the 4He technique, but only by first isolating the whole crustal flux (3-10??10-6 cm3 STP cm-2 year-1). Mantle-derived 3He (3Hem) is present in all MRB samples irrespective of distance from the SAF. However, regional-aquifer groundwaters near the terminus of the flowpath have a significantly greater content of mantle-derived 3He in comparison with more modern samples. We propose that faults in the basin other than the SAF may be an additional source of mantle-derived helium. The large range in 3He m concentrations may be related to fault activity; however, groundwaters with lower and more constant 3Hem contents may indicate that seismic activity along the SAF has been relatively constant for the past 30,000 years, demonstrating that ancient groundwaters may serve as an archive for paleo-seismic events. ?? 2003 Elsevier B.V. All rights reserved. All rights reserved.

Chemical Geology↗

Machine-learning predictions of high arsenic and high manganese at drinking water depths of the glacial aquifer system, northern continental United States

Globally, over 200 million people are chronically exposed to arsenic (As) and/or manganese (Mn) from drinking water. We used machine-learning (ML) boosted regression tree (BRT) models to predict high As (>10 μg/L) and Mn (>300 μg/L) in groundwater from the glacial aquifer system (GLAC), which spans 25 states in the northern United States and provides drinking water to 30 million people. Our BRT models’ predictor variables (PVs) included recently developed three-dimensional estimates of a suite of groundwater age metrics, redox condition, and pH. We also demonstrated a successful approach to significantly improve ML prediction sensitivity for imbalanced data sets (small percentage of high values). We present predictions of the probability of high As and high Mn concentrations in groundwater, and uncertainty, at two nonuniform depth surfaces that represent moving median depths of GLAC domestic and public supply wells within the three-dimensional model domain. Predicted high likelihood of anoxic condition (high iron or low dissolved oxygen), predicted pH, relative well depth, several modeled groundwater age metrics, and hydrologic position were all PVs retained in both models; however, PV importance and influence differed between the models. High-As and high-Mn groundwater was predicted with high likelihood over large portions of the central part of the GLAC.

Environmental Science & Technology↗

Sustainability of natural attenuation of nitrate in agricultural aquifers

Increased concentrations of nitrate in groundwater in agricultural areas, coinciding with increased use of chemical and organic fertilizers, have raised concern because of risks to environmental and human health. At some sites, these problems are mitigated by natural attenuation of nitrate as a result of microbially mediated reactions. Results from U.S. Geological Survey (USGS) research under the National Water-Quality Assessment (NAWQA) program show that reactions of dissolved nitrate with solid aquifer minerals and organic carbon help lower nitrate concentrations in groundwater beneath agricultural fields. However, increased fluxes of nitrate cause ongoing depletion of the finite pool of solid reactants. Consumption of the solid reactants diminishes the capacity of the aquifer to remove nitrate, calling into question the long-term sustainability of these natural attenuation processes.

Fact Sheet↗

Numerical model simulations of nitrate concentrations in groundwater using various nitrogen input scenarios, mid-Snake region, south-central Idaho

As part of the U.S. Geological Survey’s National Water Quality Assessment (NAWQA) program nitrate transport in groundwater was modeled in the mid-Snake River region in south-central Idaho to project future concentrations of nitrate. Model simulation results indicated that nitrate concentrations would continue to increase over time, eventually exceeding the U.S. Environmental Protection Agency maximum contaminant level for drinking water of 10 milligrams per liter in some areas. A subregional groundwater model simulated the change of nitrate concentrations in groundwater over time in response to three nitrogen input scenarios: (1) nitrogen input fixed at 2008 levels; (2) nitrogen input increased from 2008 to 2028 using the same rate of increase as the average rate of increase during the previous 10 years (1998 through 2008); after 2028, nitrogen input is fixed at 2028 levels; and (3) nitrogen input related to agriculture completely halted, with only nitrogen input from precipitation remaining. Scenarios 1 and 2 project that nitrate concentrations in groundwater continue to increase from 10 to 50 years beyond the year nitrogen input is fixed, depending on the location in the model area. Projected nitrate concentrations in groundwater increase by as much as 2–4 milligrams per liter in many areas, with nitrate concentrations in some areas reaching 10 milligrams per liter. Scenario 3, although unrealistic, estimates how long (20–50 years) it would take nitrate in groundwater to return to background concentrations—the “flushing time” of the system. The amount of nitrate concentration increase cannot be explained solely by differences in nitrogen input; in fact, some areas with the highest amount of nitrogen input have the lowest increase in nitrate concentration. The geometry of the aquifer and the pattern of regional groundwater flow through the aquifer greatly influence nitrate concentrations. The aquifer thins toward discharge areas along the Snake River which forces upward convergence of good-quality regional groundwater that mixes with the nitrate-laden groundwater in the uppermost parts of the aquifer, which results in lowered nitrate concentrations. A new method of inputting nitrogen to the subregional groundwater model was used that prorates nitrogen input by the probability of detecting nitrate concentrations greater than 2 mg/L. The probability map is based on correlations with physical factors, and prorates an existing nitrogen input dataset providing an estimate of nitrogen flux to the water table that accounts for new factors such as soil properties. The effectiveness of this updated nitrogen input method was evaluated using the software UCODE_2005.

Idaho↗

Simulation of groundwater flow and pumping scenarios for 1900–2050 near Mount Pleasant, South Carolina

Groundwater withdrawals from the Upper Cretaceous-age Middendorf aquifer in South Carolina have created a large, regional cone of depression in the potentiometric surface of the Middendorf aquifer in Charleston and Berkeley Counties, South Carolina. Groundwater-level declines of as much as 249 feet have been observed in wells over the past 125 years and are a result of groundwater use for public water supply, irrigation, and private industry. To address the concerns of users of the Middendorf aquifer, the U.S. Geological Survey, in cooperation with Mount Pleasant Waterworks (MPW), recalibrated an existing groundwater-flow model to incorporate additional groundwater-use and water-level data since 2008. This recalibration process consisted of a technique of parameter estimation that uses regularized inversion and employs “pilot points” for spatial hydraulic property characterization. The groundwater-flow system of the Coastal Plain physiographic province of South Carolina and parts of Georgia and North Carolina was simulated using the U.S. Geological Survey finite-difference computer code MODFLOW-2000. After the model recalibration, the following six predictive water-management scenarios were created to simulate potential changes in groundwater flow and groundwater-level conditions in the Mount Pleasant, South Carolina, area: Scenario 1—maximize MPW reverse-osmosis plant capacity by increasing groundwater withdrawals from the Middendorf aquifer from 3.9 million gallons per day (Mgal/d), which was the amount withdrawn in 2015, to 8.58 Mgal/d; Scenario 2—same as Scenario 1, but with the addition of a 0.5 Mgal/d supply well in the Middendorf aquifer near Moncks Corner, South Carolina; Scenario 3—same as Scenario 1, but with the addition of a 1.5 Mgal/d supply well in the Middendorf aquifer near Moncks Corner, South Carolina; Scenario 4—maximize MPW well capacity by increasing withdrawals from the Middendorf aquifer from 3.9 Mgal/d (in 2015) to 10.16 Mgal/d; Scenario 5—minimize MPW surface-water purchase from the Charleston Water System by adding supply wells and increasing withdrawals from the Middendorf aquifer from 3.9 Mgal/d (in 2015) to 12.16 Mgal/d; and Scenario 6—same as Scenario 1, but with he addition of quarterly model stress periods to simulate seasonal variations in the groundwater withdrawals. Results from the simulations indicated further decline of groundwater levels creating cones of depressions near pumping wells in the Middendorf aquifer in the Mount Pleasant, South Carolina, area between 2015 and 2050 for all six scenarios. Simulation results from Scenario 1 showed an average decline of about 150 feet in the groundwater levels of the MPW production wells. Simulated hydrographs for two area observation wells illustrate the gradual decline in groundwater levels with overall changes in water-level altitudes of –92 and –33 feet, respectively. Simulated groundwater altitudes at a hypothetical observation well located in the MPW well field declined 121 feet between 2015 and 2050. Scenarios 2 and 3 have the same pumping rates as Scenario 1 for the MPW production wells; however, a single hypothetical pumping well was added in the Middendorf aquifer near the town of Moncks Corner, South Carolina. This hypothetical pumping well has a withdrawal rate of 0.5 Mgal/d for Scenario 2 and 1.5 Mgal/d for Scenario 3. A comparison to the 2050 Scenario 1 simulation indicates groundwater altitudes for Scenarios 2 and Scenario 3 are 3 feet and 8 feet lower, respectively, at the MPW production wells. Scenario 4 simulates the maximum pumping capacity of 10.16 Mgal/d for the MPW network of production wells. Simulated 2050 groundwater altitudes for this simulation declined to –359 feet. Simulated hydrographs for two observation wells show groundwater-level declines of 116 and 41 feet, respectively. Simulated differences in groundwater altitudes at a hypothetical observation well located in the MPW well field indicate a water-level decline of 164 feet between 2015 and 2050. Scenario 5 is a modification of Scenario 4 with the addition of two new MPW production wells. For this scenario, the MPW network of production wells were simulated the same as in Scenario 4, but withdrawals from the two new production wells were added in 2020. Simulated 2050 groundwater altitudes for this simulation declined to – 405 feet. Simulated hydrographs for two observation wells show groundwater-level declines of 143 and 51 feet, respectively. Simulated groundwater altitudes at a hypothetical observation well located in the MPW well field declined 199 feet between 2015 and 2050. Scenario 6 is a modification of Scenario 1, in which 140 additional quarterly stress periods were added to simulate MPW seasonal demands. Simulated groundwater altitudes for Scenario 6 declined to –353 feet during 2050. For Scenario 6, simulated hydrographs for two observation wells and the hypothetical observation well show similar groundwater-level declines as seen in Scenario 1, but with seasonal fluctuations of as much as 56 feet in the hypothetical observation well. Water budgets for the model area immediately surrounding Mount Pleasant, South Carolina, were calculated for 2015 and for 2050. The water budget for 2015 is equal for all of the scenarios because it represents the year prior to the hypothetical pumping beginning in 2016. The largest flow component in the 2015 water budget for the Mount Pleasant area is discharge to wells at a rate of 4.17 Mgal/d. Additionally, 0.23 Mgal/d flows laterally out of the Middendorf aquifer in this area of the model due to the regional horizontal hydraulic gradient. Flow into this zone consists predominantly of lateral flow within the Middendorf aquifer at 4.08 Mgal/d. Additionally, 0.02 Mgal/d is released into this zone from aquifer storage. Vertically, 0.06 Mgal/d flows down from the Middendorf confining unit located above the Middendorf aquifer, and 0.25 Mgal/d flows up from the Cape Fear confining unit below. The largest flow component in the 2050 water budget for all six scenarios is discharge to wells in the Mount Pleasant area at rates between 8.89 and 12.47 Mgal/d. Flow into this zone consists mostly of lateral flow between 8.47 and 11.77 Mgal/d within the Middendorf aquifer. Between 0.003 and 0.46 Mgal/d is released into this zone from aquifer storage. Between 0.004 and 0.15 Mgal/d flows laterally out of this zone into adjacent areas of the Middendorf aquifer due to the regional horizontal hydraulic gradient. Finally, between 0.15 and 0.22 Mgal/d flows vertically into this zone from confining units above and below the Middendorf aquifer.

South Carolina↗

Relations of groundwater quality to long-term surface disposal of produced water near the Midway-Sunset and Buena Vista Oil Fields, California, USA

Contamination of groundwater by oil-field fluids in proximity to oil and gas development has been an issue of concern to water users and regulators given long histories of development and legacy disposal practices. A robust set of geochemical tracers including petroleum hydrocarbon compounds, thermogenic gases, inorganic ion concentrations, stable isotopes, radioactive isotopes, and noble gases were used to assess if oil-field fluids mixed with groundwater near the Midway-Sunset and Buena Vista Oil Fields in California, USA. Results show evidence of mixing of oil-field fluids with groundwater within the study area from either anthropogenic or natural processes. Produced water plumes associated with modern surface disposal facilities, used since the late 1950s, extend up to 1.5 km and currently remain within the boundaries of the oil fields. Plumes associated with earlier routing of produced water down natural drainages and in large retention structures (Midway Basin and Sunset Basin) near the Buena Vista Lake Bed are present in groundwater east of the oil fields. Based on geochemical tracer evidence, aerial imagery, and aerial electromagnetic surveys, these legacy plumes reach the western portion of the Central Valley aquifer system, an important groundwater resource for agricultural and domestic supply. The legacy plume associated with Sunset Basin may further be detected downgradient in deeper groundwater beneath the southern extent of the Buena Vista Lake Bed based on the presence of thermogenic gases and petroleum hydrocarbon compounds.

California↗