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USGS2016

Depth calibration of the Experimental Advanced Airborne Research Lidar, EAARL-B

Introduction The original National Aeronautics and Space Administration (NASA) Experimental Advanced Airborne Research Lidar (EAARL) was extensively modified to increase the spatial sampling density and to improve performance in water ranging from 3 to 44 meters (m). The new (EAARL-B) sensor features a higher spatial density that was achieved by optically splitting each laser pulse into three pulses spatially separated by 1.6 m along the flight track and 2.0 m across the flight track, on the water surface when flown at a nominal altitude of 300 m (984 feet). The sample spacing can be optionally increased to 1.0 m across the flight track. Improved depth capability was achieved by increasing the total peak laser power by a factor of 10 and by designing a new “deep-water” receiver, which is optimized to exclusively receive refracted and scattered light from deeper water (15–44 m). Two different clear-water flight missions were conducted over the U.S. Navy's South Florida Testing Facility (SFTF) to determine the EAARL-B calibration coefficients. The SFTF is an established lidar calibration range located in the coastal waters southeast of Fort Lauderdale, Florida. We used 23 selected polygons at 23 distinct depths to compare a reference dataset from this site to determine EAARL-B calibration constants over the depth range of 6.5 to 34 m. We also conducted a near-simultaneous single-beam jet-ski-based sonar survey of selected transects ranging from 1 to 33 m depth in the same area. The near-concurrent jet ski data were used to evaluate the EAARL-B performance over the depth range from 0.9 to 10 m. The more timely jet ski data were necessary because the primary reference dataset was 9 years old, and areas shallower than 6.5 m are dominated by shifting sand. We determined the jet ski data were not useful as a calibration reference in water deeper than 10 m due to large uncertainty in the vertical measurement introduced by the lack of any sensor orientation data, that is, for pitch, roll, and heading to correct the measured slant range to a vertical measurement. The resulting calibrated EAARL-B data were then analyzed and compared with the original reference dataset, the jet-ski-based dataset from the same Fort Lauderdale site, as well as the depth-accuracy requirements of the International Hydrographic Organization (IHO). We do not claim to meet all of the IHO requirements and standards. The IHO minimum depth-accuracy requirements were used as a reference only and we do not address the other IHO requirements such as “ Full Seafloor Search”. Our results show good agreement between the calibrated EAARL-B data and all reference datasets, with results that are within the 95 percent depth accuracy of the IHO Order 1 (a and b) depth-accuracy requirements.

Open-File Report↗

USGS2024

Trace silicon determination in biological samples by inductively coupled plasma mass spectrometry (ICP-MS): Insight into volatility of silicon species in hydrofluoric acid digests for optimal sample preparation and introduction to ICP-MS

A method for the determination of trace levels of silicon from biological materials by inductively coupled plasma mass spectrometry (ICP-MS) has been developed. The volatility of water-soluble silicon species, hexafluorosilicic acid (H 2 SiF 6 ), and sodium metasilicate (Na 2 SiO 3 ) was investigated by evaporating respective solutions (50 µg/mL silicon) in nitric acid (HNO 3 ), nitric acid + hydrochloric acid (HNO 3 + HCl), and nitric acid + hydrochloric acid + hydrofluoric acid (HNO 3 + HCl + HF) at 120 °C on a hot-block to near dryness. The loss of silicon from H 2 SiF 6 solutions was substantial (>99%) regardless of the digestion medium. Losses were also substantial (>98%) for metasilicate solutions heated in HNO 3 + HCl + HF, while no significant loss occurred in HNO 3 or HNO 3 + HCl. These results show that H 2 SiF 6 species were highly volatile and potential losses could confound accuracy at trace level determinations by ICP-MS if digestates prepared in HF are heated to eliminate HF. Among the various matrices comprising major elements, sodium appeared to be effective in reducing silicon loss from H 2 SiF 6 solutions. Excess sodium chloride (NaCl) matrix provided better stability, improving silicon recoveries by up to about 80% in evaporated HF digestates of soil and mine waste samples, but losses could not be fully prevented. To safely remove excess acids and circumvent the adverse effects of excess HF (e.g., risk of high Si background signals), a two-step digestion scheme was adopted for the preparation of biological samples containing trace silicon levels. A closed-vessel digestion was performed either in 4 mL of concentrated HNO 3 and 1 mL of concentrated HCl or 4 mL of concentrated HNO 3 , 1 mL of concentrated HCl and 1 mL of concentrated HClO 4 on a hot plate at 140 °C. Digestates were then evaporated to incipient dryness at 120 °C to remove the acids. A second closed-vessel digestion was carried out to dissolve silicates in 0.5 mL of concentrated HNO 3 and 0.5 mL of concentrated HF at 130 °C. After digestion, digestates were diluted to 10 mL. The solution containing about 5% HNO 3 and 5% HF was directly analyzed by ICP-MS equipped with an HF-inert sample introduction system. The limit of detection was about 110 µg/L for 28 Si when using the Kinetic Energy Discrimination (KED) mode. The method was used to determine silicon in various plant and tissue certified reference materials. Data were acquired for 28 Si using KED and standard (STD) modes, and 74 Ge and 103 Rh as internal standard elements. There was not any significant difference between the accuracy and precision of the results obtained with 74 Ge and 103 Rh within the same measurement mode. Precision, calculated as relative standard deviation for four replicate analyses, varied from 5.3 (tomato leaves) to 21% (peach leaves) for plant and from 2.2 (oyster tissue) to 33% (bovine liver) for tissue SRM/CRMs. Poor precision was attributed to material heterogeneity and the large particle size distribution. An analysis of lung tissue samples from those with occupational exposure to silica dust revealed that tissues possessed substantial levels of water-soluble silicates, but the most silicon was present in the particulate matter fraction.

Minerals↗

USGS2018

A comparison of the chemical sensitivities between in vitro and in vivo propagated juvenile freshwater mussels: Implications for standard toxicity testing

Unionid mussels are ecologically important and are globally imperiled. Toxicants contribute to mussel declines, and toxicity tests using juvenile mussels—a sensitive life stage—are valuable in determining thresholds used to set water quality criteria. In vitro culture methods provide an efficient way to propagate juveniles for toxicity testing, but their relative chemical sensitivity compared with in vivo propagated juveniles is unknown. Current testing guidelines caution against using in vitro cultured juveniles until this sensitivity is described. Our objective was to evaluate the relative sensitivity of juvenile mussels produced from both in vitro and in vivo propagation methods to selected chemicals. We conducted 96-h acute toxicity tests according to ASTM International guidelines with 3 mussel species and 6 toxicants: chloride, nickel, ammonia, and 3 copper-based compounds. Statistically significant differences between in vitro and in vivo juvenile 96-h median effect concentrations were observed in 8 of 17 tests, and in vitro juveniles were more sensitive in 6 of the 8 significant differences. At 96 h, 4 of the 8 statistically different tests for a given chemical were within a factor of 2, which is the intralaboratory variation demonstrated in a recent evaluation of mussel toxicity tests. We found that although differences in chemical sensitivity exist between in vitro and in vivo propagated juvenile mussels, they are within normal toxicity test variation. Therefore, in vitro propagated juvenile mussels may be appropriate for use in ASTM International-based toxicity testing.

Environmental Toxicology and Chemistry↗

USGS1986

Environmental regulation and influence of the eyes and pineal gland on the gonadal cycle and spawning in channel catfish (Ictalurus punctatus)

Blinded, pinealectomized, or blinded and pinealectomized female channel catfish ( Ictalurus punctatus ) were placed with normal (unoperated on) control fish in outdoor tanks at constant temperature (21 ± 2 C) or earthen ponds (ambient conditions) in February or August, when they were 21 or 27 mo old. Fish were sampled through the following reproductive season. The gonadosomatic index (GSI) and plasma estrogen concentration changed seasonally in 3-yr-old fish, but the changes were less marked or lacking in 2-yr-olds. The GSI levels of sexually mature (≥3 years old) fish peaked about a month earlier in the tanks than in the ponds; the estrogen peak for fish in the tanks was lower than that for pond fish. All experimental fish (both ages) in ponds delayed ovarian resorption for about 1 mo, compared with normal control fish. Exposure to constant 21 C water allowed earlier gonadal recrudescence. All groups of sexually mature fish that were surgically altered in August spawned during the following spring. Fish with eyes spawned earlier and had higher spawning percentages (control 68%, pinealectomized 75%) than did fish without eyes (blinded 50%, blinded and pinealectomized 56%). Neither the eyes nor the pineal is essential for spring gonadal maturation or for spawning in channel catfish, but one or both may have a role in timing these events. An annual internal oscillator that may be modified by environmental temperature is suggested as the primary control of reproductive cycling in the species. Light information obtained through the pineal, eyes, or both appears to affect the time of gonadal resorption.

Ecological and Evolutionary Physiology↗

USGS2001

Monthly fractional green vegetation cover associated with land cover classes of the conterminous USA

The land cover classes developed under the coordination of the International Geosphere-Biosphere Programme Data and Information System (IGBP-DIS) have been analyzed for a study area that includes the Conterminous United States and portions of Mexico and Canada. The 1-km resolution data have been analyzed to produce a gridded data set that includes within each 20-km grid cell: 1) the three most dominant land cover classes, 2) the fractional area associated with each of the three dominant classes, and 3) the fractional area covered by water. Additionally, the monthly fraction of green vegetation cover (fgreen) associated with each of the three dominant land cover classes per grid cell was derived from a 5-year climatology of 1-km resolution NOAA-AVHRR data. The variables derived in this study provide a potential improvement over the use of monthly fgreen linked to a single land cover class per model grid cell.

Geophysical Research Letters↗

USGS1982

Geotechnical properties of ash deposits near Hilo, Hawaii

Two holes were hand augered and sampled in ash deposits near Hilo, Hawaii. Color, water content and sensitivity of the ash were measured in the field. The ash alternated between reddish brown and dark reddish brown in color and had water contents as high as 392%. A downhole vane shear device measured sensitivities as high as 6.9. A series of laboratory tests including grain size distribution, Atterberg limits, X-ray diffraction analysis, total carbon determination, vane shear, direct shear and triaxial tests were performed to determine the composition and geotechnical properties of the ash. The ash is very fine grained, highly plastic and composed mostly of gibbsite and amorphous material presumably allophane. The ash has a high angle of internal friction ranging from 40-43? and is classified as medium to very sensitive. A series of different ash layers was distinguished on the basis of plasticity and other geotechnical properties. Sensitivity may be due to a metastable fabric, cementation, leaching, high organic content, and thixotropy. The sensitivity of the volcanic ash deposits near Hilo is consistent with documented slope instability during earthquakes in Hawaii. The high angles of internal friction and cementation permit very steep slopes under static conditions. However, because of high sensitivity of the ash, these slopes are particularly susceptible to seismically-induced landsliding.

Open-File Report↗

USGS2013

Maintaining and restoring sustainable ecosystems in southern Nevada

Managers in southern Nevada are challenge with determining appropriate goals and objectives and developing viable approaches for maintaining and restoring sustainable ecosystems in a time of rapid socio-ecological and environmental change. Sustainable or "healthy" ecosystems supply clean air, water and habitat for a diverse array of plants and animals. As described in Chapter 1, sustainable ecosystems retain characteristic processes like hydrological flux and storage, geomorphic processes, biogeochemical cycling and storage, biological activity and productivity, and population regeneration and reproduction over the normal cycle of disturbance events (modified from Chapin and others 1996 and Christensen and others 1996). Ecological restoration of stressed or disturbed ecosystems in an integral part of managing for sustainable ecosystems. The Society of Ecological Restoration International (SERI) defines ecological restoration as the process of assisting the recovery of an ecosystem that has been degraded, damaged, or destroyed (SERI 2004). Many of the southern Nevada's ecosystems are being subjected to anthropogenic stressors that span global, regional, and local scales (Chapter 2)., and are crossing ecological thresholds to new alternative states (Chapter 4 and Chapter 5). These alternative states often represent novel communities with disturbance regimes that differ significantly from historic conditions. Past management and restoration goals often focused on returning ecosystems to pre-disturbance conditions (Harris and others 2006). This approach assumes stable or equilibrium conditions and ignores changes in ecosystems processes due to land uses, increases in CO 2 concentrations, and climate change. A more realistic approach is to base management and restoration goals on the current potential of an ecosystem to support a given set of ecological conditions, and on the likelihood of future change due to warming climate (Harris and others 2006). This approach requires understanding ecosystem resilience to anthropogenic disturbance and climate change, the alternative states that exist for ecosystems, and the factors that result in threshold crossing (Bestelmeyer and others 2009; Hobbs and Harris 2001; Stingham and others 2003; Whisemnant 1999). It also requires the ability to predict how climate is likely to influence ecosystems in the future (Harris and others 2006). This chapter addresses the restoration aspects of Sub-goal 1.3 in the SNAP Science Research Strategy which is to restore and sustain proper function of southern Nevada's watersheds and landscapes (able 1.3; Turner and others 2009). The effects of global, regional and local stresses on southern Nevada ecosystems are presented in Chapter 2. Here, we discuss appropriate objectives and develop guidelines for maintaining and restoring southern Nevada ecosystems. We then discuss the differences in ecological resilience to stress and disturbance and resistance to invasive species in southern Nevada ecosystems and describe restoration and management approaches for the different ecosystem types. We conclude with knowledge gaps and management implications.

Nevada↗

USGS2009

Relationship of fluviodeltaic facies to coal deposition in the lower Fort Union formation (Palaeocene), south-western North Dakota

Facies analysis of the Ludlow and Tongue River Members of the Palaeocene Fort Union Formation provides an understanding of the relationship between fluviodeltaic environments and associated coal deposition in the south-western Williston Basin. The Ludlow Member consists of high-constructive delta facies that interfinger with brackish-water tongues of the Cannonball Member of the Fort Union Formation. The lower part of the Ludlow Member was deposited on a lower delta plain that consisted of interdistributary crevasse and subdelta lobes. The upper part of the Ludlow Member was deposited in meander belts of the upper delta plain. The delta plain facies of the Ludlow Member is overlain by alluvial plain facies consisting of swamp, crevasse-lobe, lacustrine, and trunk meander belt deposits of the Tongue River Member. The Ludlow delta is believed to have been fed by fluvial systems that probably flowed from the Powder River Basin to the Williston Basin undeterred by the Cedar Creek Anticline. However, the evidence indicates that the Cedar Creek Anticline was prominent enough, during early Tongue River Member deposition, to cause the obstruction of the regional fluvial system flowing from the SW, and the formation of local drainage. The Ludlow Member contains 18 coal beds in the area studied, of which the T-Cross and Yule coals are as thick as 4 m (12 ft). Abandoned delta lobes served as platforms where coals formed, which in turn, were drowned by mainly fresh water and subordinate brackish water. Repetition of deltaic sedimentation, abandonment, and occupation by swamp led to preservation of the T-Cross and Oyster coals in areas as extensive as 260 km 2 (< 100 miles 2 ).

North Dakota↗

USGS2010

Inter-comparison of hydro-climatic regimes across northern catchments: Synchronicity, resistance and resilience

The higher mid-latitudes of the Northern Hemisphere are particularly sensitive to climate change as small differences in temperature determine frozen ground status, precipitation phase, and the magnitude and timing of snow accumulation and melt. An international inter-catchment comparison program, North-Watch, seeks to improve our understanding of the sensitivity of northern catchments to climate change by examining their hydrological and biogeochemical responses. The catchments are located in Sweden (Krycklan), Scotland (Mharcaidh, Girnock and Strontian), the United States (Sleepers River, Hubbard Brook and HJ Andrews) and Canada (Catamaran, Dorset and Wolf Creek). This briefing presents the initial stage of the North-Watch program, which focuses on how these catchments collect, store and release water and identify 'types' of hydro-climatic catchment response. At most sites, a 10-year data of daily precipitation, discharge and temperature were compiled and evaporation and storage were calculated. Inter-annual and seasonal patterns of hydrological processes were assessed via normalized fluxes and standard flow metrics. At the annual-scale, relations between temperature, precipitation and discharge were compared, highlighting the role of seasonality, wetness and snow/frozen ground. The seasonal pattern and synchronicity of fluxes at the monthly scale provided insight into system memory and the role of storage. We identified types of catchments that rapidly translate precipitation into runoff and others that more readily store water for delayed release. Synchronicity and variance of rainfall-runoff patterns were characterized by the coefficient of variation (cv) of monthly fluxes and correlation coefficients. Principal component analysis (PCA) revealed clustering among like catchments in terms of functioning, largely controlled by two components that (i) reflect temperature and precipitation gradients and the correlation of monthly precipitation and discharge and (ii) the seasonality of precipitation and storage. By advancing the ecological concepts of resistance and resilience for catchment functioning, results provided a conceptual framework for understanding susceptibility to hydrological change across northern catchments. ?? 2010 John Wiley & Sons, Ltd.

Hydrological Processes↗

USGS2008

GSTARS computer models and their applications, part I: theoretical development

GSTARS is a series of computer models developed by the U.S. Bureau of Reclamation for alluvial river and reservoir sedimentation studies while the authors were employed by that agency. The first version of GSTARS was released in 1986 using Fortran IV for mainframe computers. GSTARS 2.0 was released in 1998 for personal computer application with most of the code in the original GSTARS revised, improved, and expanded using Fortran IV/77. GSTARS 2.1 is an improved and revised GSTARS 2.0 with graphical user interface. The unique features of all GSTARS models are the conjunctive use of the stream tube concept and of the minimum stream power theory. The application of minimum stream power theory allows the determination of optimum channel geometry with variable channel width and cross-sectional shape. The use of the stream tube concept enables the simulation of river hydraulics using one-dimensional numerical solutions to obtain a semi-two- dimensional presentation of the hydraulic conditions along and across an alluvial channel. According to the stream tube concept, no water or sediment particles can cross the walls of stream tubes, which is valid for many natural rivers. At and near sharp bends, however, sediment particles may cross the boundaries of stream tubes. GSTARS3, based on FORTRAN 90/95, addresses this phenomenon and further expands the capabilities of GSTARS 2.1 for cohesive and non-cohesive sediment transport in rivers and reservoirs. This paper presents the concepts, methods, and techniques used to develop the GSTARS series of computer models, especially GSTARS3. ?? 2008 International Research and Training Centre on Erosion and Sedimentation and the World Association for Sedimentation and Erosion Research.

International Journal of Sediment Research↗

USGS2008

Aquatic toxicity of airfield-pavement deicer materials and implications for airport runoff

Concentrations of airfield-pavement deicer materials (PDM) in a study of airport runoff often exceeded levels of concern regarding aquatic toxicity. Toxicity tests on Vibrio fischeri, Pimephales promelas, Ceriodaphnia dubia, and Pseudokirchneriella subcapitata (commonly known as Selenastrum capricornutum) were performed with potassium acetate (K-Ac) PDM, sodium formate (Na-For) PDM, and with freezing- point depressants (K-Ac and Na-For). Results indicate that toxicity in PDM is driven by the freezing-point depressants in all tests except the Vibrio fisheri test for Na-For PDM which is influenced by an additive. Acute toxicity end points for different organisms ranged from 298 to 6560 mg/L (as acetate) for K-Ac PDM and from 1780 to 4130 mg/L (as formate) for Na- For PDM. Chronic toxicity end points ranged from 19.9 to 336 mg/L (as acetate) for K-Ac PDM and from 584 to 1670 mg/L (as formate) for Na-For PDM. Sample results from outfalls at General Mitchell International Airport in Milwaukee, Wl (GMIA) indicated that 40% of samples had concentrations greater than the aquatic-life benchmark for K-Ac PDM. K-Ac has replaced urea during the 1990s as the most widely used PDM at GMIA and in the United States. Results of ammonia samples from airport outfalls during periods when urea-based PDM was used at GMIA indicated that41% of samples had concentrations exceeding the U.S. Environmental Protection Agency (USEPA) 1 -h water-quality criterion. The USEPA 1-h water-quality criterion for chloride was exceeded in 68% of samples collected in the receiving stream, a result of road-salt runoff from urban influence near the airport. Results demonstrate that PDM must be considered to comprehensively evaluate the impact of chemical deicers on aquatic toxicity in water containing airport runoff. ?? 2009 American Chemical Society.

Environmental Science & Technology↗

USGS2020

Subsea permafrost carbon stocks and climate change sensitivity estimated by expert assessment

The continental shelves of the Arctic Ocean and surrounding seas contain large stocks of organic matter (OM) and methane (CH 4 ), representing a potential ecosystem feedback to climate change not included in international climate agreements. We performed a structured expert assessment with 25 permafrost researchers to combine quantitative estimates of the stocks and sensitivity of organic carbon in the subsea permafrost domain (i.e. unglaciated portions of the continental shelves exposed during the last glacial period). Experts estimated that the subsea permafrost domain contains ~560 gigatons carbon (GtC; 170–740, 90% confidence interval) in OM and 45 GtC (10–110) in CH 4 . Current fluxes of CH 4 and carbon dioxide (CO 2 ) to the water column were estimated at 18 (2–34) and 38 (13–110) megatons C yr −1 , respectively. Under Representative Concentration Pathway (RCP) RCP8.5, the subsea permafrost domain could release 43 Gt CO 2 -equivalent (CO 2 e) by 2100 (14–110) and 190 Gt CO 2 e by 2300 (45–590), with ~30% fewer emissions under RCP2.6. The range of uncertainty demonstrates a serious knowledge gap but provides initial estimates of the magnitude and timing of the subsea permafrost climate feedback.

Environmental Research Letters↗

USGS2026

Rare earth element potential in coal and coal ash in the U.S. Gulf Coast

United States heavy reliance on imports of critical minerals (CMs), including rare earth elements (REEs), underscores the importance of development of domestic sources. The study objective was to quantify CM and REE concentrations in coal and coal ash in the US Gulf Coast region. CM and REE concentrations were measured for 118 samples from outcrops and 14 mines in the Gulf Coast. Results show that total REE + Yttrium (REY) concentrations (dry coal basis) are comparable to those of the upper continental crust (UCC) with localized hot spots, such as the Texas Gibbons Creek mine (REY ≤ ~ 2860 ppm). When normalized to UCC REY concentration (169 ppm, dry coal basis), REY to UCC ratios for Gulf Coast coal samples range from 0.1 to 17 (median ratio 0.6). REE extractability from lignites is high (median: 63%–93%) using environmentally benign weak acid. In addition to raw coal, coal ash from power plants could also serve as an REE source with a median ratio of REY in ash relative to coal of 4; however, extractability from coal ash is generally much lower (≤ 5% using the same weak acid as in coal). The median basket price for extracted REY as oxides from coal, assuming 70% extractability, is $3.2 per tonne of coal and $186 billion based on 58 billion metric tonnes of dry coal in the Gulf Coast. REEs important for magnets (Pr + Nd + Tb + Dy) account for ~ 80% of the total value. The corresponding median basket price for extracted REY as oxides from coal ash, assuming ~ 30% extractability, is ~$4.4 per tonne of ash and $1.2 billion based on 258 million tonnes of ash. REE production from coal would likely require co-products, such as activated carbon or humic acids, to attain economic viability. Production of REEs from coal ash could offset remediation costs related to potential water contamination. This reconnaissance study shows the potential for REE production from coal and coal ash in the Gulf Coast; however, carbon coproducts and/or societal benefits would likely be required for socioeconomic viability.

Alabama, Florida, Louisiana, Mississippi, Texas↗

USGS2007

Holocene sea level and climate change in the Black Sea: Multiple marine incursions related to freshwater discharge events

Repeated marine invasions of the Black Sea during the Holocene have been inferred by many eastern scientists as resulting from episodes of marine inflow from the Mediterranean beneath a brackish outflow from the Black Sea. We support this scenario but a fundamental question remains: What caused the repeated marine invasions? We offer an hypothesis for the repeated marine invasions of the Black Sea based on: (1) the overall similarity of sea-level curves from both tectonically quiescent and active margins of the Black Sea and their similarity to a sequence stratigraphic record from the US mid-Atlantic coast. The similarity of the records from two widely-separated regions suggests their common response to documented Holocene climate ocean-atmosphere reorganizations (coolings); (2) the fact that in the modern Black Sea, freshwater runoff from surrounding rivers dominates over evaporation, so that excess runoff might have temporarily raised Black Sea level (although the Black Sea would have remained brackish). Following the initial invasion of the Black Sea by marine Mediterranean waters (through the Marmara Sea) in the early Holocene, repeated marine incursions were modulated, or perhaps even caused, by freshwater discharge to the Black Sea. Climatic amelioration (warming) following each documented ocean-atmosphere reorganization during the Holocene likely shifted precipitation patterns in the surrounding region and caused mountain glaciers to retreat, increasing freshwater runoff above modern values and temporarily contributing to an increase of Black Sea level. Freshwater-to-brackish water discharges into the Black Sea initially slowed marine inflow but upon mixing of runoff with more marine waters beneath them and their eventual exit through the Bosphorus, marine inflow increased again, accounting for the repeated marine invasions. The magnitude of the hydrologic and sea-level fluctuations became increasingly attenuated through the Holocene, as reflected by Black Sea level curves. ?? 2006 Elsevier Ltd and INQUA.

Quaternary International↗

USGS2021

Developing species-age cohorts from forest inventory and analysis data to parameterize a forest landscape model

Simulating long-term, landscape level changes in forest composition requires estimates of stand age to initialize succession models. Detailed stand ages are rarely available, and even general information on stand history often is lacking. We used data from USDA Forest Service Forest Inventory and Analysis (FIA) database to estimate broad age classes for a forested landscape to simulate changes in landscape composition and structure relative to climate change at Fort Drum, a 43,000 ha U.S. Army installation in northwestern New York. Using simple linear regression, we developed relationships between tree diameter and age for FIA site trees from the host and adjacent ecoregions and applied those relationships to forest stands at Fort Drum. We observed that approximately half of the variation in age was explained by diameter breast height (DBH) across all species studied ( r 2 = 0.42 for sugar maple Acer saccharum to 0.63 for white ash Fraxinus americana ). We then used age-diameter relationships from published research on northern hardwood species to calibrate results from the FIA-based analysis. With predicted stand age, we used tree species life histories and environmental conditions represented by ecological site types to parameterize a stochastic forest landscape model (LANDIS-II) to spatially and temporally model successional changes in forest communities at Fort Drum. Forest stands modeled over 100 years without significant disturbance appeared to reflect expected patterns of increasing dominance by shade-tolerant mesophytic tree species such as sugar maple, red maple ( Acer rubrum ), and eastern hemlock ( Tsuga canadensis ) where soil moisture was sufficient. On drier sandy soils, eastern white pine ( Pinus strobus ), red pine ( P. resinosa ), northern red oak ( Quercus rubra ), and white oak ( Q. alba ) continued to be important components throughout the modeling period with no net loss at the landscape scale. Our results suggest that despite abundant precipitation and relatively low evapotranspiration rates for the region, low soil water holding capacity and fertility may be limiting factors for the spread of mesophytic species on excessively drained soils in the region. Increasing atmospheric temperatures projected for the region could alter moisture regimes for many coarse-textured soils providing a possible mechanism for expansion of xerophytic tree species.

New York↗

USGS1991

Facies development in the Lower Freeport coal bed, west-central Pennsylvania, U.S.A.

The Lower Freeport coal bed in west-central Pennsylvania is interpreted to have formed within a lacustrine-mire environment. Conditions of peat formation, caused by the changing chemical and physical environments, produced five coal facies and two mineral-rich parting facies within the coal bed. The coal bed facies are compositionally unique, having developed under varying conditions, and are manifested by megascopic, petrographic, palynologic and quality characteristics. The initial environment of the Lower Freeport peat resulted in a coal facies that is relatively high in ash yield and contains large amounts of lycopod miospores and moderate abundances of cryptotelinite, crypto-gelocollinite, inertinite and tree fern miospores. This initial Lower Freeport peat is interpreted to have been a topogenous body that was low lying, relatively nutrient rich (mesotrophic to eutrophic), and susceptible to ground water and to sediment influx from surface water. The next facies to form was a ubiquitous, clay-rich durain parting which is attributed to a general rise in the water table accompanied by widespread flooding. Following formation of the parting, peat accumulation resumed within an environment that inhibited clastic input. Development of doming in this facies restricted deposition of the upper shale parting to the margins of the mire and allowed low-ash peat to form in the interior of the mire. Because this environment was conducive to preservation of cellular tissue, this coal facies also contains large amounts of crypto-telinite. This facies development is interpreted to have been a transitional phase from topogenous, planar peat formation to slightly domed, oligotrophic (nutrient-poor) peat formation. As domed peat formation continued, fluctuations in the water table enabled oxidation of the peat surface and produced high inertinite concentrations toward the top of the coal bed. Tree ferns became an increasingly important peat contributor in the e upper facies, based on the palynoflora. This floral change is interpreted to have resulted from the peat surface becoming less wet or better drained, a condition that inhibited proliferation of lycopod trees. Accumulation of the peat continued until rising water levels formed a freshwater lake within which clays and silts were deposited. The development of the Lower Freeport peat from a planar mire through transitional phases toward domed peat formation may be an example of the type of peat formation of other upper Middle and Upper Pennsylvanian coal beds.

International Journal of Coal Geology↗

USGS2013

Bactericidal efficacy of elevated pH on fish pathogenic and environmental bacteria

Ship ballast water is a recognized medium for transfer and introductions of nonindigenous species. There is a need for new ballast water treatment methods that effectively and safely eliminate or greatly minimize movements of these species. The present study employed laboratory methods to evaluate the bactericidal efficacy of increased pH (pH 10.0–12.0) for exposure durations of up to 72 h to kill a variety of Gram-negative and Gram-positive bacteria including fish pathogens (Aeromonas spp., Yersinia ruckeri, Edwardsiella ictaluri, Serratia liquefaciens, Carnobacterium sp.), other common aquatic-inhabitant bacteria (Serratia marcescens, Pseudomonas fluorescens, Staphylococcus sp., Bacillus sp.) and indicators listed in International Maritime Organization D2 Standards; namely, Vibrio cholera (an environmental isolate from fish), Escherichia coli and Enterococcus faecalis. Volumes of 5 N NaOH were added to tryptic soy broth to obtain desired pH adjustments. Viable cells were determined after 0, 4, 12, 24, 48, and 72 h. Initial (0 h) cell numbers ranged from 3.40 × 10 4 cfu/mL for Bacillus sp. to 2.44 × 10 7 cfu/mL for E. faecalis. The effective endpoints of pH and treatment duration necessary to realize 100% bactericidal effect varied; however, all bacteria tested were killed within 72 h at pH 12.0 or lower. The lowest parameters examined, 4 h at pH 10.0, were bactericidal to V. cholera, E. ictaluri, three of four isolates of E. coli, and (three of four) Aeromonas salmonicida subsp. salmonicida. Bactericidal effect was attained at pH 10.0 within 12 h for the other A. salmonicida subsp. salmonicida, and within 24 h for P. fluorescens, and the remaining E. coli.

Journal of Advanced Research↗

USGS2018

Benthic foraminifera from the Carnarvon Ramp reveal variability in Leeuwin Current activity (Western Australia) since the Pliocene

Benthic foraminiferal assemblages from a ~300 m deep core from an outer carbonate-ramp site off Western Australia (International Ocean Discovery Program Core U1460A) were examined to reconstruct the paleoceanographic evolution of the Carnarvon Ramp and the warm surficial Leeuwin Current (LC) for the last 3.54 Ma. Of the identified 179 benthic foraminiferal species, occurrences of the 15 most abundant taxa were assessed using Q-mode Cluster Analysis and Non-Metric Dimensional Scaling. Diversity, equitability, planktonic/benthic index, microhabitat preference, and sedimentary parameters such as lithology and sponge spicule content were analyzed to gather information about past intermediate- and surface-water circulation. Relative abundances of infaunal and epifaunal species were applied to indicate changes in organic-matter supply and oxygenation at the sea floor. Influence of upwelling was recognized by a high infaunal species ratio, with dominance by Uvigerina peregrina , Lagena annellatrachia and Trifarina bradyi . Epifaunal species such as Hanzawaia nipponica and Hyalinea florenceae gradually became more abundant around 1.14 Ma, indicating increased ventilation and establishment of the paleo-LC. A more substantial change was initiated by 0.91 Ma as marked by key species Spirorutilus carinatus and Rotorbinella sp. , together with increased faunal diversity, benthic foraminiferal accumulation rates, and evidence for suspension feeding sponges. With the LC flow suppressing upwelling, and better ventilated waters entering the shelf, the environment favored epifaunal agglutinates, rotalids, and miliolids, while buliminids decreased. Under high-flow conditions of the LC, sponge spicules and skeletal carbonate production reached an optimum at ~0.6 Ma before returning to modern conditions. Supported by these observations, we propose the following paleoceanographic evolution of the Carnarvon Ramp: During the late Pliocene to mid Pleistocene (3.54–0.91 Ma) conditions of deep-water upwelling from the Western Australian Current and Indian Ocean Gyre indicate the absence of the capping LC on the outer carbonate ramp. A transitional phase started in the mid Pleistocene (1.14–0.61 Ma). The paleo-LC triggered gradual oxygenation at the sediment-water interface, which coincided with an increase in carbonate sedimentation rates, and waning sea-surface productivity. During a third phase, mid Pleistocene to present (0.91–0 Ma), the LC’s intensity and flow rates peaked at ~0.6 Ma. Benthic foraminiferal accumulation rates reached a high, then decreased to present-day rates. For short periods, sea-surface productivity was moderately enhanced, likely due to fluctuating LC persistence or landward shift during glacial maxima.

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