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At least 901 records · Page 50Linked to original sources
USGS1985

Geochemistry of ground-water in two sandstone aquifer systems in the Northern Great Plains in parts of Montana and Wyoming, North Dakota, and South Dakota

The Kootenai Formation in the Judith Basin, Montana, and the Lance Formation and Fox Hills Sandstone in the Powder River Basin, Wyoming, constitute two important sandstone aquifer systems in the Northern Great Plains region. Ground waters in each of these systems evolve from low dissolved-solids concentration, near-neutral pH, predominantly calcium and magnesium bicarbonate types in their recharge areas, to high dissolved-solids concentration, high pH, predominantly sodium-bicarbonate types in the basins. Oxidation potentials decrease as the waters flow downgradient under confined conditions. Calculation of the saturation states of aquifer minerals suggests several groups of mineral phases that could control ground- water chemistry. Mass transfer modeling indicates, however, that the observed behavior of major and minor dissolved species in both systems can satisfactorily be explained only by equilibration with cal cite, dolomite, or calcite and dolomite. The geochemistry of these systems is probably controlled by the incongruent dissolution of dolo mite to form calcite. This reaction appears to be driven by cation ex change and the dissolution of carbon dioxide. Plausible carbon diox ide sources include organic carbon oxidation and lignite coalification. Aluminosilicates influence major element chemistry primarily as sub trates for cation exchange, which, in combination with carbonate equilibria, buffer ground water pH at values of 8.5 to 8.9. Dissolved- iron concentrations are controlled by equilibration with amorphous ferric oxyhydroxides in oxidizing waters, with amorphous ferric oxyhydroxides and siderite in moderately reducing waters, and with siderite and amorphous ferrous sulfide in strongly reducing waters. Measured variations in dissolved carbonate isotopic composition compare favorably with carbon isotopic evolution, calculated by assuming dedolomitization. Recharge areas of the two systems are characterized by ground waters with high tritium and carbon-14 activities and relatively low dissolved-solids concentrations, with calcium and magnesium as the predominant cations. Recharge temperatures, calculated from dissolved-argon concentrations and 5 18 0 and SD isotopic measure ments, indicate that recharge is derived primarily from spring snow- melt rather than late spring and summer storms. Ground-water flow directions are generally parallel to trends of increasing dissolved solids concentrations and decreasing divalent to monovalent cation concentration ratios. However, these trends are sometimes obscured in areas of leakage or mixing. Further indication of leakage between aquifers is provided by abrupt changes in major element and isotopic chemistry, which are not characteristic of normally observed geo chemical evolution. Ground-water flow rates, calculated by adjusting measured carbon-14 activities for carbonate mass transfer, are com parable to values calculated from aquifer tests and potentiometric data. These carbon-14 flow rates average 1.6 meters per year for the Second Cat Creek sandstone of the Kootenai Formation, and 1.3 meters per year for the Lance-Fox Hills aquifer.

Montana, North Dakota, South Dakota, Wyoming↗
USGS1986

Geohydrology of bedrock aquifers in the Northern Great Plains in parts of Montana, North Dakota, South Dakota, and Wyoming

Rocks of Paleozoic and Mesozoic age underlie the entire northern Great Plains of the United States. These rocks form 5 artesian aquifer systems that are recharged in the mountainous areas of Montana, South Dakota, and Wyoming and extend more than 600 miles to discharge areas in the northeastern part of North Dakota and in the Canadian Province of Manitoba. Generally, the principal direction of flow in each aquifer is deflected to the north and south around the Williston basin. Flow through the Williston basin is restricted because of geologic structure, and decreased permeability of rocks in the deeper parts of the basin. Major fracture systems or lineaments traverse the geologic section and are either vertical or horizontal conduits, or barriers to, groundwater flow. Vertical leakage from the aquifers is restricted by shale of minimal permeability, halite beds, and stratigraphic traps or minimal-permeability zones associated with petroleum accumulations. Interaquifer leakage appears to occur through and along some of the major lineaments. During the Pleistocene Epoch, thick ice sheets completely covered the discharge areas of the bedrock aquifers. This effectively blocked flow northeastward from the system and, at some locations, it may have caused a reversal of flow. The existing flow, system therefore, may not have reached hydrologic equilibrium with the stress of the last glacial period. (USGS)

Professional Paper↗
USGS1988

Summary of the hydrology of the Floridan aquifer system in Florida and in parts of Georgia, South Carolina, and Alabama

The Floridan aquifer system is one of the major sources of ground-water supplies in the United States. This highly productive aquifer system underlies all of Florida, southern Georgia, and small parts of adjoining Alabama and South Carolina, for a total area of about 100,000 square miles. About 3 billion gallons of water per day is withdrawn from the aquifer for all uses, and, in many areas, the Floridan is the sole source of freshwater. The aquifer system is a sequence of hydraulically connected carbonate rocks (principally limestone and some dolomite) that generally range in age from Late Paleocene to Early Miocene. The rocks vary in thickness from a featheredge where they crop out to more than 3,500 ft where the aquifer is deeply buried. The aquifer system generally consists of an upper aquifer and a lower aquifer, separated by a less permeable confining unit of highly variable properties. In parts of north Florida and southwest Georgia, there is little permeability contrast within the aquifer system. Thus in these areas the Floridan is effectively one continuous aquifer. The upper and lower aquifers are defined on the basis of permeability, and their boundaries locally do not coincide with those for either time-stratigraphic or rock-stratigraphic units. Low-permeability clastic rocks overlie much of the Floridan aquifer system. The lithology, thickness, and integrity of these low-permeability rocks have a controlling effect on the development of permeability and ground-water flow in the Floridan locally. The Floridan aquifer system derives its permeability from openings that vary from fossil hashes and networks of many solution-widened joints to large cavernous openings in karst areas. Diffuse flow pre-dominates where the small openings occur, whereas conduit flow may occur where there are large cavernous openings. For the Upper Floridan aquifer, transmissivities are highest (greater than 1,000,000 ft squared per day) in the unconfined karst areas of central and northern Florida. Lowest transmissivities (less than 50,000 ft squared per day) occur in the Florida panhandle and southernmost Florida, where the Upper Floridan aquifer is confined by thick clay sections. The hydraulic properties of the Lower Floridan aquifer are not well known; however, this unit also contains intervals of very high transmissivity that have been attributed to paleokarst development. The dominant feature of the Floridan flow system, both before and after ground-water development, is Upper Floridan aquifer springs, nearly all of which occur in unconfined and semiconfined parts of the aquifer in Florida. Before ground-water development, spring flow and point discharge to surface-water bodies was about 88 percent of the estimated 21,500 cubic ft per second total discharge. Current discharge (early 1980's) is about 24,100 cubic ft per second, 75 percent of which is spring flow and discharge to surface-water bodies, 17 percent is withdrawal from wells, and 8 percent is diffuse upward leakage. Pumpage has been and continues to be supplied primarily by the diversion of natural outflow from the aquifer system and by induced recharge rather than by loss of water from aquifer storage. The approximately 3 billion gallons per day pumped from the Floridan aquifer system has resulted in long-term regional water-level declines of more than 10 ft in three broad areas of the flow system: (1) coastal Georgia and adjacent South Carolina and northeast Florida, (2) west-central Florida, and (3) the Florida panhandle. Saltwater has encroached as a result of pumping in a few coastal areas. In general, the water chemistry in the Upper Floridan is related to flow and proximity to the freshwater-saltwater interface. In the unconfined or semiconfined areas where flow is vigorous, dissolved-solids concentrations are low (less than 250 milligrams per liter). Where the system is more tightly confined, flow is more sluggish and concentrations are higher (grea

Alabama, Florida, Georgia, South Carolina↗
USGS1986

Hydrogeologic framework of the Floridan aquifer system in Florida and in parts of Georgia, Alabama, and South Carolina

The Floridan aquifer system of the Southeastern United States is comprised of a thick sequence of carbonate rocks that are mostly of Paleocene to early Miocene age and that are hydraulically connected in varying degrees. The aquifer system consists of a single vertically continuous permeable unit updip and of two major permeable zones (the Upper and Lower Floridan aquifers) separated by one of seven middle confining units downdip. Neither the boundaries of the aquifer system or of its component high- and low-permeability zones necessarily conform to either formation boundaries or time-stratigraphic breaks. The rocks that make up the Floridan aquifer system, its upper and lower confining units, and a surficial aquifer have been separated into several chronostratigraphic units. The external and internal geometry of these stratigraphic units is presented on a series of structure contour and isopach maps and by a series of geohydrologic cross sections and a fence diagram. Paleocene through middle Eocene units consist of an updip clastic facies and a downdip carbonate bank facies, that extends progressively farther north and east in progressively younger units. Upper Eocene and Oligocene strata are predominantly carbonate rocks throughout the study area. Miocene and younger strata are mostly clastic rocks. Subsurface data show that some modifications in current stratigraphic nomenclature are necessary. First, the middle Eocene Lake City Limestone cannot be distinguished lithologically or faunally from the overlying middle Eocene Avon Park 'Limestone.' Accordingly, it is proposed that the term Lake City be abandoned and the term Avon Park Formation be applied to the entire middle Eocene carbonate section of peninsular Florida and southeastern Georgia. A reference well section in Levy County, Fla., is proposed for the expanded Avon Park Formation. The Avon Park is called a 'formation' more properly than a 'limestone' because the unit contains rock types other than limestone. Second, like the Avon Park, the lower Eocene Oldsmar and Paleocene Cedar Keys 'Limestones' of peninsular Florida practically everywhere contain rock types other than limestone. It is therefore proposed that these units be referred to more accurately as Oldsmar Formation and Cedar Keys Formation. The uppermost hydrologic unit in the study area is a surficial aquifer that can be divided into (1) a fluvial sand-and-gravel aquifer in southwestern Alabama and westernmost panhandle Florida, (2) limestone and sandy limestone of the Biscayne aquifer in southeastern peninsular Florida, and (3) a thin blanket of terrace and fluvial sands elsewhere. The surficial aquifer is underlain by a thick sequence of fine clastic rocks and low-permeability carbonate rocks, most of which are part of the middle Miocene Hawthorn Formation and all of which form the upper confining unit of the Floridan aquifer system. In places, the upper confining unit has been removed by erosion or is breached by sinkholes. Water in the Floridan aquifer system thus occurs under unconfined, semiconfined, or fully confined conditions, depending upon the presence, thickness, and integrity of the upper confining unit. Within the Floridan aquifer system, seven low permeability zones of subregional extent split the aquifer system in most places into an Upper and Lower Floridan aquifer. The Upper Floridan aquifer, which consists of all or parts of rocks of Oligocene age, late Eocene age, and the upper half of rocks of middle Eocene age, is highly permeable. The middle confining units that underlie the Upper Floridan are mostly of middle Eocene age but may be as young as Oligocene or as old as early Eocene. Where no middle confining unit exists, the entire aquifer system is comprised of permeable rocks and for hydrologic discussions is treated as the Upper Floridan aquifer.

Alabama, Florida, Georgia, South Carolina↗
USGS1988

Ground-water hydraulics, regional flow, and ground-water development of the Floridan aquifer system in Florida and in parts of Georgia, South Carolina, and Alabama

The Floridan aquifer system is one of the major sources of groundwater supplies in the United States. This productive aquifer system underlies all of Florida, southeast Georgia, and small parts of adjoining Alabama and South Carolina, for a total area of about 100,000 square miles. About 3 billion gallons of water per day were withdrawn from the aquifer system in 1980, and in many areas the Floridan is the sole source of freshwater. The Floridan aquifer system is a sequence of hydraulically connected carbonate rocks (principally limestone with some dolomite) ranging in age generally from late Paleocene to early Miocene. The rocks vary in thickness from a featheredge where they crop out to more than 3,500 feet where the aquifer is deeply buried. The aquifer system generally consists of an upper aquifer and a lower aquifer separated by a lesspermeable confining unit of highly variable properties. In parts of north Florida and southwest Georgia, where little permeability contrast exists among the units, the Floridan is effectively one continuous aquifer. The upper and lower aquifers, named the Upper Floridan aquifer and the Lower Floridan aquifer, are defined on the basis of permeability and their boundaries locally do not coincide with those for either time-stratigraphic or rock-stratigraphic units. Overlying much of the Floridan aquifer system are low-permeability clastic rocks. The lithology, thickness, and integrity of these rocks determine the degree of confinement and influence the distribution of natural recharge, discharge, and ground-water flow in the Floridan. The permeability of the Floridan aquifer system is derived from small openings including fossil hashes and solution-widened joints as well as large cavernous openings in karst areas. Diffuse flow predominates where the small openings occur, whereas conduit flow may occur where large cavernous openings are. Transmissivities are highest (greater than 1,000,000 feet squared per day) in the unconfined karst areas of central and northern Florida. Lowest transmissivities (less than 50,000 feet squared per day) occur in panhandle Florida and southernmost Florida where the Upper Floridan aquifer is confined by thick clay sections. The hydraulic properties of the Lower Floridan aquifer are not well known; however, intervals of high transmissivity occur that have been attributed to paleokarst development. Springs, nearly all of which occur in unconfined and semiconfined parts of the Upper Floridan aquifer in Florida are the dominant feature of the Floridan flow system. Before ground-water development, spring flow and point discharge to surface-water bodies were about 88 percent of the estimated 21,500 cubic feet per second total discharge, or about 19,000 cubic feet per second. Diffuse upward leakage, which occurs primarily in confined areas, accounted for the remaining 12 percent or about 2,500 cubic feet per second. Most of the recharge necessary to sustain springflow and aquifer discharge to streams and lakes occurs relatively close to springs and areas of point discharge to surface-water bodies. Recharge to the Upper Floridan is highest, averaging 10-20 inches per year, in unconfined or semiconfined spring areas. The proximity of high recharge to high discharge implies a vigorous and well-developed shallow flow system in the unconfined and semiconfined parts of the Upper Floridan aquifer. Ground-water flow is very sluggish in the parts of the aquifer system that are deeply buried and tightly confined, primarily southeast Georgia and northeast Florida, south Florida, and far-west panhandle Florida. Discharge to springs, streams, and lakes is practically nonexistent in the tightly confined areas and natural discharge occurs almost exclusively by diffuse upward leakage through thick overburden. The regional flow system has not been appreciably altered by groundwater development. However, increasing pumpage that reached 3 billion gallons per day by 1980 has resulted in long-term regional water level decline of more than 10 feet in three broad areas: coastal Georgia, adjacent South Carolina, and northeast Florida; west-central Florida; and panhandle Florida. Saltwater encroachment as a result of pumping has occurred locally in coastal areas. Pumpage from the Upper Floridan aquifer is supplied primarily by reduction of natural discharge and by increased recharge rather than by depletion of aquifer storage. About 20 percent is from reduced discharge to springs, streams, and lakes, about 20 percent is from reduced upward leakage, and about 60 percent is from increased recharge. Compared to predevelopment conditions, discharge to springs, streams, and lakes is reduced by less than 5 percent, upward leakage is reduced by about 30 percent, and recharge is increased by about 12 percent. Total recharge and, therefore, discharge increased from a predevelopment rate of 21,500 cubic feet per second to about 24,100 cubic feet per second by 1980. A considerable area remains of the Floridan aquifer system where large ground-water supplies may be developed. This area is largely inland from the coasts and characterized by high transmissivity and minimal development prior to the early 1980's. The major constraint on future development probably is degradation of water quality rather than water-quantity limitations.

Alabama, Florida, Georgia, South Carolina↗
USGS1989

Hydrogeology, ground-water movement, and subsurface storage in the Floridan aquifer system in southern Florida

The Floridan aquifer system of southern Florida is composed chiefly of carbonate rocks that range in age from early Miocene to Paleocene. The top of the aquifer system in southern Florida generally is at depths ranging from 500 to 1,000 feet, and the average thickness is about 3,000 feet. It is divided into three general hydrogeologic units: (1) the Upper Floridan aquifer, (2) the middle confining unit, and (3) the Lower Floridan aquifer. The Upper Floridan aquifer contains brackish ground water, and the Lower Floridan aquifer contains salty ground water that compares chemically to modern seawater. Zones of high permeability are present in the Upper and Lower Floridan aquifers. A thick, cavernous dolostone in the Lower Floridan aquifer, called the Boulder Zone, is one of the most permeable carbonate units in the world (transmissivity of about 2.5 x 107 feet squared per day). Ground-water movement in the Upper Floridan aquifer is generally southward from the area of highest head in central Florida, eastward to the Straits of Florida, and westward to the Gulf of Mexico. Distributions of natural isotopes of carbon and uranium generally confirm hydraulic gradients in the Lower Floridan aquifer. Groundwater movement in the Lower Floridan aquifer is inland from the Straits of Florida. The concentration gradients of the carbon and uranium isotopes indicate that the source of cold saltwater in the Lower Floridan aquifer is seawater that has entered through the karat features on the submarine Miami Terrace near Fort Lauderdale. The relative ages of the saltwater suggest that the rate of inland movement is related in part to rising sea level during the Holocene transgression. Isotope, temperature, and salinity anomalies in waters from the Upper Floridan aquifer of southern Florida suggest upwelling of saltwater from the Lower Floridan aquifer. The results of the study support the hypothesis of circulating relatively modern seawater and cast doubt on the theory that the saltwater in the Floridan aquifer system probably is connate or unflushed seawater from high stands of sea level. The principal use of the Floridan aquifer system in southern Florida is for subsurface storage of liquid waste. The Boulder Zone of the Lower Floridan aquifer is extensively used as a receptacle for injected treated municipal wastewater, oil field brine, and, to a lesser extent, industrial wastewater. Pilot studies indicate a potential for cyclic storage of freshwater in the Upper Floridan aquifer in southern Florida.

Florida↗
USGS1989

Geochemistry of the Floridan aquifer system in Florida and in parts of Georgia, South Carolina, and Alabama

The chemical quality of the ground water in the Floridan aquifer system is determined primarily by mineral-water interaction. However, some changes in water quality have been imposed by development, particularly near coastal pumping centers. A total of 601 chemical analyses, all from different wells, most completed in the upper part of the aquifer system, were used to describe the variations in water chemistry and to study the processes responsible for observed changes. The Floridan aquifer system is a vertically continuous sequence of Tertiary carbonate rocks that are of generally high permeability and are hydraulically connected in varying degrees. The rocks are principally limestone and dolomite, but they grade into limy sands and clays near the aquifer system's updip limits. Major minerals in the aquifer system are calcite, dolomite, and, locally, gypsum or quartz; minor minerals include apatite, glauconite, and clay minerals such as kaolinite and montmorillonite. Trace amounts of metallic oxides or sulfides are present in some areas. The aquifer system consists of the Upper and Lower Floridan aquifers, separated in most places by a less permeable confining unit that has highly variable hydraulic properties. Only the Upper Floridan aquifer is present throughout the study area. Freshwater enters the aquifer system in outcrop areas located primarily in central Georgia and north-central Florida. Discharge occurs chiefly to streams and springs and, to a lesser extent, directly into the sea. Most of the flow into and out of the system takes place where it is unconfined or where the upper confining unit is thin. Secondary permeability developed by dissolution of aquifer material is most prominent in these areas of dynamic flow. Dissolved-solids concentrations in water from the Upper Floridan aquifer generally range from less than 25 milligrams per liter near outcrops to more than 25,000 milligrams per liter along the coasts. The dominant cations in the ground water are Ca2+, Mg2+, and Na+; the dominant anions are HCO3-, Cl-, and SO42-, The concentration of Ca2+ is controlled primarily by calcite saturation. Concentrations of Mg2+, NA+, and Cl- are highest where mixing of freshwater and saltwater occurs. Concentrations of HCO3- reflect the control of calcite solubility. The concentration of SO42- is highest where gypsiferous rock units are present in the aquifer system. The major geochemical processes that occur in the Upper Floridan aquifer, based on water-quality maps and computations using a geochemical model, are (1) dissolution of aquifer minerals toward equilibrium, (2) mixing of ground water with recharge, leakage, or seawater, (3) sulfate reduction, and (4) cation exchange between water and aquifer minerals. Similar processes apparently control minor dissolved constituents, although quantification is difficult with the available data. Statistical tests of available nutrient data indicate that concentrations of N (nitrogen) species in unconfined recharge areas may be increasing over time; more detailed studies of all N species are needed to test this hypothesis, however. Data on trace metals, radionuclides, and man-made organic contaminants are limited. Available data indicate that most freshwater within the Upper Floridan is potable, but detection of pesticides in a few samples indicates that the system is susceptible to contamination from the land surface in some areas, particularly where its upper confining unit is thin or absent. Geochemical models were used to examine changes in major chemical elements along selected ground-water paths within the Upper Floridan aquifer. Water in the Upper Floridan aquifer can be categorized into four hydrochemical facies, whose exact distribution is determined by confined or unconfined conditions of the aquifer and by chloride concentrations. The reaction models are considered plausible based on available chemical, isotopic, and hydrologic information, and they

Alabama, Florida, Georgia, South Carolina↗
USGS1989

Hydrogeologic framework of the New Jersey Coastal Plain

This report presents the results of a water-resources, oriented subsurface mapping program within the Coastal Plain of New Jersey. The occurrence and configuration of 15 regional hydrogeologic units have been defined, primarily on the basis of an interpretation of borehole geophysical data. The nine aquifers and six confining beds are composed of unconsolidated clay, silt, sand, and gravel and range in age from Cretaceous to Quaternary. Electric and gamma-ray logs from more than 1,000 Coastal Plain wells were examined. Of these, interpretive data for 302 sites were selected, on the basis of logged depth, quality of data, and data distribution, to prepare structure contour and thickness maps for each aquifer and a thickness map for each confining bed. These maps, together with 14 hydrogeologic sections, show the geometry, lateral extent, and vertical and horizontal relationships among the 15 hydrogeologic units. The hydrogeologic maps and sections show that distinct lower, middle, and upper aquifers are present within the Potomac, Raritan-Magothy aquifer system near the Delaware River from Burlington County to Salem County. Although the lower aquifer is recognized only in this area, the middle aquifer extends into the northeastern Coastal Plain of New Jersey, where it is stratigraphically equivalent to the Farrington aquifer. The upper aquifer extends throughout most of the New Jersey Coastal Plain and is stratigraphically equivalent to the Old Bridge aquifer in the northeastern Coastal Plain. The overlying Merchantville-Woodbury confining bed is the most regionally extensive confining bed within the New Jersey Coastal Plain. Its thickness ranges from less than 100 feet near the outcrop to more than 450 feet along the coast. The Englishtown aquifer system acts as a single aquifer throughout most of its subsurface extent, but it contains two water-bearing sands in pars of Monmouth and Ocean Counties. The overlying Marshalltown-Wenonah confining bed is a thin, leaky unit ranging in thickness from approximately 20 to 80 feet. The Wenonah-Mount Laurel aquifer is identified in the subsurface throughout the New Jersey Coastal Plain southeast of its outcrop area. Sediments that overlie the Wenonah-Mount Lauren aquifer and that are subjacent to the major aquifers within the Kirkwood Formation and the Cohansey Sand are described hydrologically as a composite confining bed. These include the Navesink Formation, Red Bank Sand, Tinton Sand, Hornerstown Sand, Vincentown Formation, Manasquan Formation, Shark River Formation, and Piney Point Formation and the basal clay of the Kirkwood Formation.. The Vincentown Formation functions as n aquifer within 3 to 10 miles downdip of its outcrop area. In areas farther downdip the Vincentown Formation functions as a confining bed. The Piney Point aquifer is laterally persistent from the southern New Jersey Coastal Plain northward into parts of Burlington and Ocean Counties. The Atlantic City 800-foot sand of the Kirkwood Formation can be recognized in the subsurface along coastal areas of Cape May, Atlantic, and southern Ocean Counties, but inland only as far west as the extent of the overlying confining bed. In areas west of the extent of the overlying confining bed, the Kirkwood Formation is in hydraulic connection with the overlying Cohansey Sand and younger surficial deposits and functions as an unconfined aquifer.

New Jersey Coastal Plain↗