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USGS2023

Potentiometric surfaces (2013, 2015), groundwater quality (2010–15), and water-level changes (2011–13, 2013–15) in the Sparta-Memphis aquifer in Arkansas

The Sparta-Memphis aquifer, present across much of eastern Arkansas, is the second most used groundwater resource in the State, with the Mississippi River Valley alluvial aquifer being the primary groundwater resource. The U.S. Geological Survey, in cooperation with Arkansas Department of Agriculture-Natural Resources Division, Arkansas Geological Survey, Natural Resources Conservation Service, Union County Water Conservation Board, and the Union County Conservation District, collects groundwater data across the Sparta-Memphis aquifer extent in Arkansas. This report presents water-level data for measurements conducted during two time periods, January–May 2013 and January–June 2015, and discusses water-level altitude changes for the 2011–13 and 2013–15 periods in the Sparta-Memphis aquifer. Accompanying water-level data in this report include groundwater-quality data for the period 2010–15 in the Sparta-Memphis aquifer. Groundwater data can guide ongoing and future groundwater-monitoring efforts and inform management of the aquifers in Arkansas. Water levels measured at 306 wells from January to May 2013 and 273 wells from January to June 2015 are graphically presented as potentiometric-surface maps. Measurements from 2011, 2013, and 2015 were used in the construction of 2011–13 and 2013–15 water-level change maps. Select long-term hydrographs are included in the report to illustrate water-level changes at the local scale. Water-level data show the influence of climate, pumping, and conservation and management efforts on groundwater levels. With respect to climate, the study area experienced extreme drought conditions between January 2011 and December 2012. The proximate effects of drought—increased evapotranspiration, decreased recharge, and increased irrigation needs—resulted in water-level declines that were particularly notable in the northern and central portions of the study area. Groundwater sampled in 2010–15 from 148 wells completed in the Sparta-Memphis aquifer was analyzed for specific conductance, pH, chloride (Cl) concentration, and bromide (Br) concentration. In 2015, groundwater-quality data from 103 wells completed in the Sparta-Memphis aquifer had a median specific conductance of 356 microsiemens per centimeter at 25 degrees Celsius and a median Cl concentration of 9.5 milligrams per liter (mg/L). The data show two areas of higher Cl (greater than 10 mg/L) and higher Br (greater than 0.5 mg/L) concentrations in Union, Calhoun, and Bradley Counties in southern Arkansas and Monroe and Phillips Counties in eastern-central Arkansas. A Cl and Br mixing model indicates the two regions of wells may have different sources of higher salinity. In the greater Union County area, water in most wells may be a mixture of recharge or precipitation and higher salinity groundwater from the Nacatoch aquifer. Water in wells in eastern-central Arkansas may be sourced from aquifers having a higher Cl concentration (and thus, also a higher Cl-to-Br ratio).

Arkansas↗

USGS2010

Status and understanding of groundwater quality in the North San Francisco Bay groundwater basins, 2004: California GAMA Priority Basin Project

Groundwater quality in the approximately 1,000-square-mile (2,590-square-kilometer) North San Francisco Bay study unit was investigated as part of the Priority Basin Project of the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The study unit is located in northern California in Marin, Napa, and Sonoma Counties. The GAMA Priority Basin Project is being conducted by the California State Water Resources Control Board in collaboration with the U.S. Geological Survey (USGS) and the Lawrence Livermore National Laboratory. The GAMA North San Francisco Bay study was designed to provide a spatially unbiased assessment of untreated groundwater quality in the primary aquifer systems. The assessment is based on water-quality and ancillary data collected by the USGS from 89 wells in 2004 and water-quality data from the California Department of Public Health (CDPH) database. The primary aquifer systems (hereinafter referred to as primary aquifers) were defined by the depth interval of the wells listed in the CDPH database for the North San Francisco Bay study unit. The quality of groundwater in shallower or deeper water-bearing zones may differ from that in the primary aquifers; shallower groundwater may be more vulnerable to surficial contamination. The first component of this study, the status of the current quality of the groundwater resource, was assessed by using data from samples analyzed for volatile organic compounds (VOC), pesticides, and naturally occurring inorganic constituents, such as major ions and trace elements. This status assessment is intended to characterize the quality of groundwater resources within the primary aquifers of the North San Francisco Bay study unit, not the treated drinking water delivered to consumers by water purveyors. Relative-concentrations (sample concentration divided by the health- or aesthetic-based benchmark concentration) were used for evaluating groundwater quality for those constituents that have Federal and (or) California benchmarks. A relative-concentration greater than (>) 1.0 indicates a concentration above a benchmark, and less than or equal to (≤) 1.0 indicates a concentration equal to or below a benchmark. Relative-concentrations of organic and special interest constituents were classified as “high” (relative-concentration > 1.0), “moderate” (0.1 < relative-concentration ≤ 1.0), or “low” (relative-concentration ≤ 0.1). Inorganic constituent relative-concentrations were classified as “high” (relative-concentration > 1.0), “moderate” (0.5 < relative-concentration ≤ 1.0), or “low” (relative-concentration ≤ 0.5). Aquifer-scale proportion was used as a metric for evaluating regional-scale groundwater quality. High aquifer-scale proportion is defined as the percentage of the primary aquifers that have a relative-concentration greater than 1.0; proportion is calculated on an areal rather than a volumetric basis. Moderate and low aquifer-scale proportions were defined as the percentage of the primary aquifers that have moderate and low relative-concentrations, respectively. Two statistical approaches—grid-based and spatially-weighted—were used to evaluate aquifer-scale proportion for individual constituents and classes of constituents. Grid-based and spatially-weighted estimates were comparable in the North San Francisco Bay study unit (90-percent confidence intervals). For inorganic constituents with human-health benchmarks, relative-concentrations were high in 14.0 percent of the primary aquifers, moderate in 35.8 percent, and low in 50.2 percent. The high aquifer-scale proportion of inorganic constituents primarily reflected high aquifer-scale proportions of arsenic (10.0 percent), boron (4.1 percent), and lead (1.6 percent). In contrast, relative-concentrations of organic constituents (one or more) were high in 1.4 percent, moderate in 4.9 percent, and low in 93.7 percent (not detected in 64.8 percent) of the primary aquifers. The high aquifer-scale proportion of organic constituents primarily reflected high aquifer-scale proportions of PCE (1.3 percent), TCE (0.1 percent), and 1,1-dichloroethene (0.1 percent). The inorganic constituents with secondary maximum contaminant levels (SMCL), manganese and iron, had relative-concentrations that were high in 40.8 percent and 24.4 percent of the primary aquifers, respectively. Of the 255 organic and special-interest constituents analyzed for, 26 constituents were detected. Two organic constituents were frequently detected (in 10 percent or more of samples), the trihalomethane chloroform and the herbicide simazine, but both were detected at low relative-concentrations. The second component of this study, the understanding assessment, identified the natural and human factors that affect groundwater quality by evaluating land use, physical characteristics of the wells, geochemical conditions of the aquifer, and water temperature. Results from these evaluations were used to explain the occurrence and distribution of constituents in the study unit. The understanding assessment indicated that a majority of the wells that contained nitrate also had an urban or agricultural land-use classification, had a modern or mixed age classification, and had depths to their top perforations <100 ft (30 m). Geochemical data are consistent with partial denitrification of nitrate in some reducing groundwaters in the terminal and deeper parts of the flow system. High and moderate relative-concentrations of arsenic may be attributed to reductive dissolution of manganese or iron oxides, or to desorption or inhibition of arsenic sorption under alkaline conditions. Arsenic concentrations increased with increasing depth and groundwater age in the North San Francisco Bay study unit. High to moderate relative-concentrations of boron were primarily associated with hydrothermal activity or high-salinity waters in the Napa Sonoma lowlands. Simazine was detected in groundwater classified as modern and mixed age more often than in groundwater classified as pre-modern age, while chloroform was detected most often in groundwater classified as mixed age. Simazine and chloroform also were observed in wells that had surrounding land use classified as agricultural or land use classified as urban, and top of perforation depths less than 100 ft (30 m). Together, the occurrence of chloroform and simazine in shallow wells with modern or mixed groundwater located in urban or agricultural areas suggests that these constituents result from anthropogenic activities during the last 50 years. Tritium, helium-isotope, and carbon-14 data were used to classify the predominant age of groundwater samples into three categories: modern (water that has entered the aquifer in the last 50 years), pre-modern (water that entered the aquifer more than 50 years to tens of thousands of years ago), and mixed (mixtures of modern- and pre-modern-age waters). Arsenic, iron, and total dissolved solids (TDS) concentrations were significantly greater in groundwater having pre-modern-age classification than modern, suggesting that these constituents accumulate with groundwater residence time.

California↗

USGS2010

Hydrogeology and water quality in the Snake River alluvial aquifer at Jackson Hole Airport, Jackson, Wyoming, September 2008–June 2009

The hydrogeology and water quality of the Snake River alluvial aquifer, at the Jackson Hole Airport in northwest Wyoming, was studied by the U.S. Geological Survey in cooperation with the Jackson Hole Airport Board and the Teton Conservation District during September 2008-June 2009. Hydrogeologic conditions were characterized using data collected from 14 Jackson Hole Airport wells. Groundwater levels are summarized in this report and the direction of groundwater flow, hydraulic gradients, and estimated groundwater velocity rates in the Snake River alluvial aquifer underlying the study area are presented. Analytical results of chemical, dissolved gas, and stable isotopes are presented and summarized. Seasonally, the water table at Jackson Hole Airport was lowest in early spring and reached its peak in July, with an increase of 12 to 14 feet between April and July 2009. Groundwater flow was predominantly horizontal but had the hydraulic potential for downward flow. The direction of groundwater flow was from the northeast to the west-southwest. Horizontal groundwater velocities within the Snake River alluvial aquifer at the airport were estimated to be about 26 to 66 feet per day. This indicates that the traveltime from the farthest upgradient well to the farthest downgradient well was approximately 53 to 138 days. This estimate only describes the movement of groundwater because some solutes may move at a rate much slower than groundwater flow through the aquifer. The quality of the water in the alluvial aquifer generally was considered good. The alluvial aquifer was a fresh, hard to very hard, calcium carbonate type water. No constituents were detected at concentrations exceeding U.S. Environmental Protection Agency Maximum Contaminant Levels, and no anthropogenic compounds were detected at concentrations greater than laboratory reporting levels. The quality of groundwater in the alluvial aquifer generally was suitable for domestic and other uses; however, dissolved iron and manganese were detected at concentrations exceeding the U.S. Environmental Protection Agency Secondary Maximum Contaminant Levels for drinking water in two monitoring wells. These secondary standards are esthetic guidelines only and are nonenforceable. Iron and manganese are likely both natural components of the geologic materials in the area and may have become mobilized in the aquifer due to reduction/oxidation (redox) processes. Additionally, measurements of dissolved-oxygen concentrations and analyses of major ions and nutrients indicate reducing conditions exist at two of the seven wells sampled. Reducing conditions in an otherwise oxic aquifer system are indicative of an upgradient or in-situ source of organic carbon. The nature of the source of organic carbon at the airport could not be determined. View report for unabridged abstract.

Wyoming↗

USGS2016

Hydrogeology and groundwater quality at monitoring wells installed for the Tunnel and Reservoir Plan System and nearby water-supply wells, Cook County, Illinois, 1995–2013

Groundwater-quality data collected from 1995 through 2013 from 106 monitoring wells open to the base of the Silurian aquifer surrounding the Tunnel and Reservoir Plan (TARP) System in Cook County, Illinois, were analyzed by the U.S. Geological Survey, in cooperation with the Metropolitan Water Reclamation District of Greater Chicago, to assess the efficacy of the monitoring network and the effects of water movement from the tunnel system to the surrounding aquifer. Groundwater from the Silurian aquifer typically drains to the tunnel system so that analyte concentrations in most of the samples from most of the monitoring wells primarily reflect the concentration of the analyte in the nearby Silurian aquifer. Water quality in the Silurian aquifer is spatially variable because of a variety of natural and non-TARP anthropogenic processes. Therefore, the trends in analyte values at a given well from 1995 through 2013 are primarily a reflection of the spatial variation in the value of the analyte in groundwater within that part of the Silurian aquifer draining to the tunnels. Intermittent drainage of combined sewer flow from the tunnel system to the Silurian aquifer when flow in the tunnel systemis greater than 80 million gallons per day may affect water quality in some nearby monitoring wells. Intermittent drainage of combined sewer flow from the tunnel system to the Silurian aquifer appears to affect the values of electrical conductivity, hardness, sulfate, chloride, dissolved organic carbon, ammonia, and fecal coliform in samples from many wells but typically during less than 5 percent of the sampling events. Drainage of combined sewer flow into the aquifer is most prevalent in the downstream parts of the tunnel systems because of the hydraulic pressures elevated above background values and long residence time of combined sewer flow in those areas. Elevated values of the analytes emplaced during intermittent migration of combined sewer flow into the Silurian aquifer decrease through time as water from the aquifer drains back into the tunnels in response to typical hydraulic conditions. Of the analytes sampled, fecal coliform provides the clearest indication of the location and timing of combined sewer flow into the Silurian aquifer surrounding the tunnel system.

Illinois↗

USGS2015

The source, discharge, and chemical characteristics of selected springs, and the abundance and health of associated endemic anuran species in the Mojave network parks

Hydrological and biological investigations were done during 2005 and 2006 in cooperation with the U.S. National Park Service to investigate the source, discharge, and chemical characteristics of selected springs and the abundance and health of endemic anuran (frog and toad) species at Darwin Falls in Death Valley National Park, Piute Spring in Mojave National Preserve, and Fortynine Palms Oasis in Joshua Tree National Park. Discharge from the springs at these sites sustains isolated riparian habitats in the normally dry Mojave Desert. Data were collected on water quantity (discharge) and quality, air and water temperature, and abundance and health of endemic anuran species. In addition, a single survey of the abundance and health of endemic anuran species was completed at Rattlesnake Canyon in Joshua Tree National Park. Results from this study were compared to limited historical data, where they exist, and can provide a baseline for future hydrological and biological investigations to evaluate the health and sustainability of the resource and its response to changing climate and increasing human use. Radiocarbon dating of the water yielded estimated ages of about 7,000 years at Piute Spring and about 3,000 years at Darwin Spring, and tritium-helium-3 dating indicated an age of less than 2 years at Fortynine Palms Oasis. Stable hydrogen-isotope ratios were used to interpret an average altitude of recharge of 2,348 meters for Darwin Spring (about 1,415 meters higher than the altitude of Darwin Spring), 1,668 meters for Piute Spring (about 766 meters higher than the altitude of Piute Spring), and 1,400 meters for the Upper Pool at Fortynine Palms Oasis (about 543 meters higher than the altitude of the Upper Pool). Water-quality data collected for this study did not appear to be sensitive to trends in precipitation or seasonality in the Darwin Falls and Piute Spring study areas; however, it was sensitive to trends in Fortynine Palms Oasis where salinity increased by more than 10 percent during the 2 years of this study. Such a rapid response is consistent with the comparatively short travel time of less than 2 years from recharge to discharge at Fortynine Palms Oasis. Of the 14 trace elements analyzed, only concentrations of uranium at Fortynine Palms Oasis and arsenic at Darwin Spring were above drinking water standards; both constituents are derived from natural sources in the drainage basin and, therefore, are likely to have accumulated as a result of natural processes. Endemic anuran species were surveyed at Darwin Falls for the western toad ( Anaxyrus boreas ) and the red-spotted toad ( Anaxyrus punctatus ), at Piute Spring for the red-spotted toad, and at Fortynine Palms Oasis for the red-spotted toad and California treefrog ( Pseudacris cadaverina ). Historically, red-spotted toads were at the edge of their range at Darwin Falls, but they were not detected during this study and have not been detected since the early 1980s. The 2006 western toad population at Darwin Falls was estimated at 381 adults (95-percent confidence interval [CI] of 314–482). The population of red-spotted toads at Piute Spring was estimated at 1,153 adults (95-percent CI of 935–1,503). However, an elevated rate of abnormalities (approximately 5 percent) was recorded in red-spotted toads as well as the presence of the chytrid fungus, Bactrochochytrium dendrobatidis , at Piute Spring. In Joshua Tree National Park, the California treefrog now occupies only three of the seven historically occupied drainages. Populations of California treefrogs at Fortynine Palms Oasis have declined more than 50 percent from 288 in 1969–71 to 109 in 2006. A similar decline was observed in the populations of red-spotted toads at Fortynine Palms Oasis from 300 adults in 1969–71 to 155 adults (95-percent CI of 90–139) in 2006. The red-spotted toads at Fortynine Palms Oasis also exhibited the presence of Bactrochochytrium dendrobatidis .

California↗

USGS2021

Hydraulic modeling at selected dam-removal and culvert-retrofit sites in the northeastern United States

Aquatic connectivity projects, such as removing dams and modifying culverts, have substantial benefits. The restoration of natural flow conditions improves water quality, sediment transport, aquatic and riparian habitat, and fish passage. These projects can also decrease hazards faced by communities by lowering water-surface elevations of flood waters and by removing the risk of dam breaches associated with aging or inadequate infrastructure. This report documents and provides results of one- and two-dimensional hydraulic models developed for selected rivers and streams in the northeastern United States where a dam was removed or a culvert was retrofitted. The models were developed for conditions before and after the dam removal or culvert modification. The discharges applied in the models included monthly discharges and flood discharges for the annual exceedance probabilities of 50, 20, 10, 4, 2, 1, 0.5, and 0.2 percent. This study, by the U.S. Geological Survey in cooperation with the U.S. Fish and Wildlife Service, demonstrates the benefits resulting from dam removal and retrofitting undersized culverts in terms of decreased water-surface elevations during flooding and improved fish passage. The U.S. Army Corps of Engineers Hydrologic Engineering Center’s River Analysis System was used to model the sites in one- and two-dimensional hydraulics, and decreases in the 1-percent annual exceedance probability discharge water-surface elevation were found at all sites studied. The decreases in water-surface elevation at sites in which the impoundment was removed ranged from 1.3 to 10.4 feet. One site, Bradford Dam in Westerly, Rhode Island, had only a 0.2-foot decrease, but at that site the dam was replaced by a series of weirs to retain the upstream impoundment and allow fish passage. Minimal differences were found between the water-surface elevations computed by the one- and two-dimensional models. The two-dimensional models, however, provide the additional benefit of detailed velocity and depth data throughout the channel at a resolution not possible with a one-dimensional model. These velocity and depth data allowed for assessment of the suitability for fish passage at the sites. Fish passage was improved at all the sites by removing the dams and retrofitting the culvert. Prolonged swim velocity criteria for selected fish species were maintained throughout three of the nine study sites, and burst swim velocity criteria were met at all study sites.

Connecticut, Massachusetts, New Jersey, Rhode Isla↗

USGS2026

Methods for estimating selected low-flow frequency and mean annual flow statistics at gaged and ungaged locations on streams in Georgia, North Carolina, and South Carolina

The U.S. Geological Survey, in cooperation with the Georgia Department of Natural Resources (Environmental Protection Division), North Carolina Department of Environmental Quality (Division of Water Resources), North Carolina Department of Public Safety (Office of Recovery and Resiliency), and South Carolina Department of Environmental Services, updated low-flow frequency, mean annual flow, and flow-duration statistics at 843 streamgages in and near Georgia, North Carolina, and South Carolina. The low-flow frequency statistics are annual minimum 1-day average flow with a 10-year recurrence interval (1Q10), annual minimum 7-day average flow for 2- and 10-year recurrence intervals (7Q2 and 7Q10, respectively), and annual minimum 30-day average flow with 2- and 3-year recurrence intervals (30Q2 and 30Q3, respectively). Monthly 1Q10 and 7Q10, and W7Q10 flow statistics for the winter period (November–March) also are presented. By using data from 604 of the streamgages on streams with streamflows that are not substantially affected by regulation or diversion and are not tidally influenced, regional regression equations were developed to predict flow statistics with prediction intervals at ungaged locations on streams with those same criteria. The regional regression analysis included data from 132 streamgages from adjacent States Alabama, Florida, Tennessee, and Virginia. The final regional regression equations include variables such as drainage area, streamflow variability, precipitation, percentage of impervious area, and percentage of the basin in various ecoregions. The low-flow statistics for the streamgages analyzed and the regional regression equations will be integrated into the U.S. Geological Survey StreamStats application ( https://www.usgs.gov/streamstats ) for Georgia, North Carolina, and South Carolina. StreamStats generates basin characteristics needed to compute low-flow frequency statistics for ungaged locations. A trend analysis of annual minimum 7-day average flows was done for 78 streamgages with at least 30 years of continuous record. Trends were evaluated for 30-, 50‑, 70-, and 90-year periods, ending in climate year 2021, and independence and short- and long-term persistence assumptions were considered. For all trend analysis assumptions, most streamgages did not exhibit significant trends in annual minimum 7-day average flows. Trends in annual precipitation and air temperature were similarly evaluated for the period 1895–2021 to assess the variability of climate for Georgia, North Carolina, and South Carolina.

Georgia, North Carolina, South Carolina↗

USGS2015

Hydrogeologic framework, hydrology, and refined conceptual model of groundwater flow for Coastal Plain aquifers at the Standard Chlorine of Delaware, Inc. Superfund Site, New Castle County, Delaware, 2005-12

From 1966 to 2002, activities at the Standard Chlorine of Delaware chemical facility in New Castle County, Delaware resulted in the contamination of groundwater, soils, and wetland sediment. In 2005, the U.S. Geological Survey (USGS), in partnership with the U.S. Environmental Protection Agency, Region 3, and the Delaware Department of Natural Resources and Environmental Control began a multi-year investigation of the hydrogeologic framework and hydrology of the confined aquifer system. The goals of the ongoing study at the site (the Potomac Aquifer Study) are to determine the hydraulic connection between the Columbia and Potomac aquifers, determine the direction of groundwater flow in the Potomac aquifer, and identify factors affecting the fate of contaminated groundwater. This report describes progress made towards these goals based on available data collected through September 2012. The regional hydrogeologic framework indicates that the site is underlain by Coastal Plain sediments of the Columbia, Merchantville, and Potomac Formations. Two primary aquifers underlying the site, the Columbia and the upper Potomac, are separated by the Merchantville Formation confining unit. Local groundwater flow in the surficial (Columbia) aquifer is controlled by topography and generally flows northward and discharges to nearby surface water. Regional flow within the Potomac aquifer is towards the southeast, and is strongly influenced by major water withdrawals locally. Previous investigations at the site indicated that contaminants, primarily benzene and chlorinated benzene compounds, were present in the Columbia aquifer in most locations; however, there were only limited detections in the upper Potomac aquifer as of 2004. From 2005 through 2012, the USGS designed a monitoring network, assisted with exploratory drilling, collected data at monitoring wells, conducted geophysical surveys, evaluated water-level responses in wells during pumping of a production well, and evaluated major aquifer withdrawals. Data collected through these efforts were used to refine the local conceptual flow system. The refined conceptual flow system for the site includes: (a) identification of gaps in confining units in the study area, (b) identification and correlation of multiple water-bearing sand intervals within the upper Potomac Formation, (c) connections between groundwater and surface water, (d) connections between shallow and deeper groundwater, (e) new water-level (or potentiometric surface) maps and inferred flow directions, and (f) identification of major local pumping well influences. The implications of the revised conceptual flow system on the occurrence and movement of site contaminants are that the resulting detection of contaminants in the upper Potomac aquifer at specific well locations can be attributed primarily to either advective lateral transport, direct vertical contaminant transport, or a combination of vertical and lateral movement resulting from changes in water withdrawal rates over time.

Delaware↗

USGS2015

Hydrogeology of the Owego-Apalachin Elementary School geothermal fields, Tioga County, New York

The hydrogeology of the Owego-Apalachin Elementary School geothermal fields, which penetrate saline water and methane in fractured upper Devonian age bedrock in the Owego Creek valley, south-central New York, was characterized through the analysis of drilling and geophysical logs, water-level monitoring data, and specific-depth water samples. Hydrogeologic insights gained during the study proved beneficial for the design of the geothermal drilling program and protection of the overlying aquifer during construction, and may be useful for the development of future geothermal fields and other energy-related activities, such as drilling for oil and natural gas in similar fractured-bedrock settings. The southwest geothermal field consists of 204 closed-loop wells that penetrate a major saline water-bearing zone associated with bedding-plane fractures near the middle of an interbedded sandstone and shale interval at depths of 238 to 263 feet below land surface (ft bls). The northeast geothermal field consists of 80 closed-loop wells that penetrate a major saline water-bearing zone associated with bedding-plane fractures near the base of the interbedded sandstone and shale interval at depths of 303 to 323 ft bls. Transmissivity estimates for the major saline water-bearing fractured zones range from 735 to 3,400 feet squared per day. The saline water-bearing zone in the southwest field is hydraulically connected over a horizontal distance of at least 350 feet. The hydraulic connection between subhorizontal, stacked bedding-plane fractures is limited by the number and transmissivity of interspersed higher angle fractures; locally, greater stratigraphic separation results in reduced connectivity to a greater degree than does horizontal distance. The specific conductance of the saline water from the shallower fractured zone in the southwest field was about 16,000 microsiemens per centimeter at 25 degrees Celsius (μS/cm at 25°C), and that from the fractured zone in the northeast field was about 65,000 μS/cm at 25°C. The saline waters were characterized by a chemical composition similar to that of deep formation brines collected from oil and gas wells in the Appalachian Basin. About 40 percent of the geothermal wells discharged methane gas to land surface during and (or) following drilling. Sandstone beds at depths of 348 to 378 ft bls are the likely source of the methane gas, which was determined to be early thermogenic in origin.

New York↗

USGS2007

Hydrogeology and Simulated Ground-Water Flow in the Salt Pond Region of Southern Rhode Island

The Salt Pond region of southern Rhode Island extends from Westerly to Narragansett Bay and forms the natural boundary between the Atlantic Ocean and the shallow, highly permeable freshwater aquifer of the South Coastal Basin. Large inputs of fresh ground water coupled with the low flushing rates to the open ocean make the salt ponds particularly susceptible to eutrophication and bacterial contamination. Ground-water discharge to the salt ponds is an important though poorly quantified source of contaminants, such as dissolved nutrients. A ground-water-flow model was developed and used to delineate the watersheds to the salt ponds, including the areas that contribute ground water directly to the ponds and the areas that contribute ground water to streams that flow into ponds. The model also was used to calculate ground-water fluxes to these coastal areas for long-term average conditions. As part of the modeling analysis, adjustments were made to model input parameters to assess potential uncertainties in model-calculated watershed delineations and in ground-water discharge to the salt ponds. The results of the simulations indicate that flow to the salt ponds is affected primarily by the ease with which water is transmitted through a glacial moraine deposit near the regional ground-water divide, and by the specified recharge rate used in the model simulations. The distribution of the total freshwater flow between direct ground-water discharge and ground-water-derived surface-water (streamflow) discharge to the salt ponds is affected primarily by simulated stream characteristics, including the streambed-aquifer connection and the stream stage. The simulated position of the ground-water divide and, therefore, the model-calculated watershed delineations for the salt ponds, were affected only by changes in the transmissivity of the glacial moraine. Selected changes in other simulated hydraulic parameters had substantial effects on total freshwater discharge and the distribution of direct ground-water discharge and ground-water-derived surface-water (streamflow) discharge to the salt ponds, but still provided a reasonable match to the hydrologic data available for model calibration. To reduce the uncertainty in predictions of watershed areas and ground-water discharge to the salt ponds, additional hydrogeologic data would be required to constrain the model input parameters that have the greatest effect on the simulation results.

Scientific Investigations Report↗

USGS2010

StreamStats in Oklahoma– Drainage-basin characteristics and peak-flow frequency statistics for ungaged streams

The USGS Streamflow Statistics (StreamStats) Program was created to make geographic information systems-based estimation of streamflow statistics easier, faster, and more consistent than previously used manual techniques. The StreamStats user interface is a map-based internet application that allows users to easily obtain streamflow statistics, basin characteristics, and other information for user-selected U.S. Geological Survey data-collection stations and ungaged sites of interest. The application relies on the data collected at U.S. Geological Survey streamflow-gaging stations, computer aided computations of drainage-basin characteristics, and published regression equations for several geographic regions comprising the United States. The StreamStats application interface allows the user to (1) obtain information on features in selected map layers, (2) delineate drainage basins for ungaged sites, (3) download drainage-basin polygons to a shapefile, (4) compute selected basin characteristics for delineated drainage basins, (5) estimate selected streamflow statistics for ungaged points on a stream, (6) print map views, (7) retrieve information for U.S. Geological Survey streamflow-gaging stations, and (8) get help on using StreamStats. StreamStats was designed for national application, with each state, territory, or group of states responsible for creating unique geospatial datasets and regression equations to compute selected streamflow statistics. With the cooperation of the Oklahoma Department of Transportation, StreamStats has been implemented for Oklahoma and is available at http://water.usgs.gov/osw/streamstats/. The Oklahoma StreamStats application covers 69 processed hydrologic units and most of the state of Oklahoma. Basin characteristics available for computation include contributing drainage area, contributing drainage area that is unregulated by Natural Resources Conservation Service floodwater retarding structures, mean-annual precipitation at the drainage-basin outlet for the period 1961-1990, 10-85 channel slope (slope between points located at 10 percent and 85 percent of the longest flow-path length upstream from the outlet), and percent impervious area. The Oklahoma StreamStats application interacts with the National Streamflow Statistics database, which contains the peak-flow regression equations in a previously published report. Fourteen peak-flow (flood) frequency statistics are available for computation in the Oklahoma StreamStats application. These statistics include the peak flow at 2-, 5-, 10-, 25-, 50-, 100-, and 500-year recurrence intervals for rural, unregulated streams; and the peak flow at 2-, 5-, 10-, 25-, 50-, 100-, and 500-year recurrence intervals for rural streams that are regulated by Natural Resources Conservation Service floodwater retarding structures. Basin characteristics and streamflow statistics cannot be computed for locations in playa basins (mostly in the Oklahoma Panhandle) and along main stems of the largest river systems in the state, namely the Arkansas, Canadian, Cimarron, Neosho, Red, and Verdigris Rivers, because parts of the drainage areas extend outside of the processed hydrologic units.

Oklahoma↗

USGS2004

Chloroform in the hydrologic system--sources, transport, fate, occurrence, and effects on human health and aquatic organisms

Chloroform is one of the volatile organic compounds (VOCs) detected most frequently in both ground and surface water. Because it is also one of the four trihalomethanes (THMs) produced in the highest concentrations during the chlorination of drinking water and wastewater, the frequent detection of this compound in ground and surface water of the United States is presumed to be caused primarily by the input of chlorinated water to the hydrologic system. Although anthropogenic sources of the compound are substantial, they are currently estimated to constitute only 10 percent of the total global input to the hydrologic system. Natural sources of the compound include volcanic gases, biomass burning, marine algae, and soil microorganisms. Under most conditions (except in the presence of unusually high bromide concentrations), chloroform is the THM produced in the highest concentrations during chlorination. Furthermore, in most cases where more than one THM is produced from chlorination, the relative concentrations among the different compounds usually decrease with increasing bromination (chloroform > dichlorobromomethane > chlorodibromomethane > bromoform). This phenomenon is presumed to be responsible for the common observation that when more than one THM is detected during investigations of the occurrence of these compounds in the hydrologic system, this same trend is typically observed among their relative concentrations or, for a uniform reporting limit, their relative frequencies of detection. This pattern could provide a valuable means for distinguishing between chlorinated water and other potential sources of chloroform in the environment. Chloroform has been widely detected in national, regional, and local studies of VOCs in ground, surface, source, and drinking waters. Total THM (TTHM) concentrations of the compound, however, were typically less than the Maximum Contaminant Level (MCL) of 80 ?g/L (micrograms per liter) established by the U.S. Environmental Protection Agency (USEPA) for TTHMs. In the studies that compared land-use settings, frequencies of detection of chloroform were higher beneath urban and residential areas than beneath agricultural or undeveloped areas. Because chloroform is a suspected human carcinogen, its presence in drinking water is a potential human health concern. Liver damage, however, is known to occur at chloroform exposures lower than those required to cause cancer, an observation that has been considered by the USEPA as the basis for setting a new, non-zero Maximum Contaminant Level Goal of 70 ?g/L for the compound. As part of its National Water-Quality Assessment Program, the U.S. Geological Survey has been assembling and analyzing data on the occurrence of VOCs (including chloroform) in ground and surface water on a national scale from studies conducted between 1991 and the present. This report presents a summary of current (2004) information on the uses, sources, formation, transport, fate, and occurrence of chloroform, as well as its effects on human health and aquatic organisms.

Scientific Investigations Report↗

USGS2013

Nutrient concentrations in surface water and groundwater, and nitrate source identification using stable isotope analysis, in the Barnegat Bay-Little Egg Harbor watershed, New Jersey, 2010–11

Five streams in the Barnegat Bay-Little Egg Harbor (BB-LEH) watershed in southern New Jersey were sampled for nutrient concentrations and stable isotope composition under base-flow and stormflow conditions, and during the growing and nongrowing seasons, to help quantify and identify sources of nutrient loading. Samples were analyzed for concentrations of total nitrogen, ammonia, nitrate plus nitrite, organic nitrogen, total phosphorus, and orthophosphate, and for nitrogen and oxygen stable isotope ratios. Concentrations of total nitrogen in the five streams appear to be related to land use, such that streams in subbasins characterized by extensive urban development (and historical agricultural land use)—North Branch Metedeconk and Toms Rivers—exhibited the highest total nitrogen concentrations (0.84–1.36 milligrams per liter (mg/L) in base flow). Base-flow total nitrogen concentrations in these two streams were dominated by nitrate; nitrate concentrations decreased during storm events as a result of dilution by storm runoff. The two streams in subbasins with the least development—Cedar Creek and Westecunk Creek—exhibited the lowest total nitrogen concentrations (0.16–0.26 mg/L in base flow), with organic nitrogen as the dominant species in both base flow and stormflow. A large proportion of these subbasins lies within forested parts of the Pinelands Area, indicating the likelihood of natural inputs of organic nitrogen to the streams that increase during periods of storm runoff. Base-flow total nitrogen concentrations in Mill Creek, in a moderately developed basin, were 0.43 to 0.62 mg/L and were dominated by ammonia, likely associated with leachate from a landfill located upstream. Total phosphorus and orthophosphate were not found at detectable concentrations in most of the surface-water samples, with the exception of samples collected from the North Branch Metedeconk River, where concentrations ranged from 0.02 to 0.09 mg/L for total phosphorus and 0.008 to 0.011 mg/L for orthophosphate. Measurements of nitrogen and oxygen stable isotope ratios of nitrate in surface-water samples revealed that a mixture of multiple subsurface sources, which may include some combination of animal and septic waste, soil nitrogen, and commercial fertilizers, likely contribute to the base-flow nitrogen load. The results also indicate that atmospheric deposition is not a predominant source of nitrogen transported to the BB-LEH estuary from the watershed, although the contribution of nitrate from the atmosphere increases during stormflow. Atmospheric deposition of nitrate has a greater influence in the less developed subbasins within the BB-LEH watershed, likely because few other major sources of nitrogen (animal and septic waste, fertilizers) are present in the less developed subbasins. Atmospheric sources appear to contribute proportionally less of the overall nitrate as development increases within the BB-LEH watershed. Groundwater samples collected from five wells located within the BB-LEH watershed and screened in the unconfined Kirkwood-Cohansey aquifer system were analyzed for nutrient and stable isotope composition. Concentrations of nitrate ranged from not detected to 3.63 mg/L, with the higher concentrations occurring in the highly developed northern portion of the watershed, indicating the likelihood of anthropogenic sources of nitrogen. Isotope data for the two wells with the highest nitrate concentrations are more consistent with fertilizer sources than with animal or septic waste. Total phosphorus was not detected in any of the wells sampled, and orthophosphate was either not detected or measured at very low concentrations (0.005–0.009 mg/L) in each of the wells sampled.

New Jersey↗

USGS2009

Methods for Estimating Water Withdrawals for Mining in the United States, 2005

The mining water-use category includes groundwater and surface water that is withdrawn and used for nonfuels and fuels mining. Nonfuels mining includes the extraction of ores, stone, sand, and gravel. Fuels mining includes the extraction of coal, petroleum, and natural gas. Water is used for mineral extraction, quarrying, milling, and other operations directly associated with mining activities. For petroleum and natural gas extraction, water often is injected for secondary oil or gas recovery. Estimates of water withdrawals for mining are needed for water planning and management. This report documents methods used to estimate withdrawals of fresh and saline groundwater and surface water for mining during 2005 for each county and county equivalent in the United States, Puerto Rico, and the U.S. Virgin Islands. Fresh and saline groundwater and surface-water withdrawals during 2005 for nonfuels- and coal-mining operations in each county or county equivalent in the United States, Puerto Rico, and the U.S. Virgin Islands were estimated. Fresh and saline groundwater withdrawals for oil and gas operations in counties of six states also were estimated. Water withdrawals for nonfuels and coal mining were estimated by using mine-production data and water-use coefficients. Production data for nonfuels mining included the mine location and weight (in metric tons) of crude ore, rock, or mineral produced at each mine in the United States, Puerto Rico, and the U.S. Virgin Islands during 2004. Production data for coal mining included the weight, in metric tons, of coal produced in each county or county equivalent during 2004. Water-use coefficients for mined commodities were compiled from various sources including published reports and written communications from U.S. Geological Survey National Water-use Information Program (NWUIP) personnel in several states. Water withdrawals for oil and gas extraction were estimated for six States including California, Colorado, Louisiana, New Mexico, Texas, and Wyoming, by using data from State agencies that regulate oil and gas extraction. Total water withdrawals for mining in a county were estimated by summing estimated water withdrawals for nonfuels mining, coal mining, and oil and gas extraction. The results of this study were distributed to NWUIP personnel in each State during 2007. NWUIP personnel were required to submit estimated withdrawals for numerous categories of use in their States to a national compilation team for inclusion in a national report describing water use in the United States during 2005. NWUIP personnel had the option of submitting the estimates determined by using the methods described in this report, a modified version of these estimates, or their own set of estimates or reported data. Estimated withdrawals resulting from the methods described in this report may not be included in the national report; therefore the estimates are not presented herein in order to avoid potential inconsistencies with the national report. Water-use coefficients for specific minerals also are not presented to avoid potential disclosure of confidential production data provided by mining operations to the U.S. Geological Survey.

Scientific Investigations Report↗

USGS2022

Hydrogeology and simulation of groundwater flow in the Lucerne Valley groundwater basin, California

The Lucerne Valley is in the southwestern part of the Mojave Desert and is about 75 miles northeast of Los Angeles, California. The Lucerne Valley groundwater basin encompasses about 230 square miles and is separated from the Upper Mojave Valley groundwater basin by splays of the Helendale Fault. Since its settlement, groundwater has been the primary source of water for agricultural, industrial, municipal, and domestic uses. Groundwater withdrawal from pumping has exceeded the amount of water recharged to the basin, causing groundwater declines of more than 100 feet between 1917 and 2016 in the center of the basin. The continued withdrawal has resulted in an increase in pumping costs, reduced well efficiency, and land subsidence near Lucerne Lake. Although the volume of pumping has declined in recent years, there is concern that new agricultural growth and limits on imported water will continue to strain the sustainability of the groundwater system. To address these concerns, the U.S. Geological Survey entered into a cooperative agreement with the Mojave Water Agency to develop a better understanding of the Lucerne Valley hydrogeologic system and provide tools to help evaluate and manage the effects of future development in the Lucerne Valley. The objectives of this study were to (1) improve the understanding of the aquifer system, (2) improve the understanding of subsidence in the basin, and (3) incorporate the understanding into a groundwater-flow model that can be used to help manage the groundwater resources in the Lucerne Valley. The model developed for this study covers the period of 1942–2016 and can help evaluate various proposed water-management scenarios during different climatic and hydrologic conditions. The aquifer system consists of a shallow aquifer, a confining unit, and middle and lower aquifers. These layered water-bearing units were identified based on geologic units of the mostly unconsolidated sediments and hydrologic properties. These alluvial deposits consist of clay, silt, sand, and gravel; some places also contain clay and silty clay lacustrine deposits. Several faults act, at least in part, as barriers to groundwater flow on the eastern, southern, and western edges of the basin. Present-day natural recharge is primarily from the infiltration of runoff from the San Bernardino Mountains to the south; however, stable and radioactive isotopes show that groundwater from the middle of the Lucerne Valley was older than about 10,000 years and probably was recharged as infiltration from streams draining the mountains in the Mojave Desert to the north, which probably does not occur under present-day climatic conditions. The annual average natural recharge for 1942–2016, estimated by a Basin Characterization Model, was about 635 acre-feet per year; the average amount of treated wastewater effluent transferred to the Lucerne Valley for artificial recharge annually ranged from about 1,500 to 4,000 acre-feet per year during 1980–2016. Pumpage estimates for 1942–2016 ranged from about 3,000 acre-feet in 1942 to about 18,300 acre-feet in 1984. The total cumulative amount of groundwater removed from the basin by pumping between 1942 and 2016 was estimated to be about 700,000 acre-feet, which was about 10 times greater than the cumulative amount of recharge to the entire Lucerne Valley groundwater basin. Before groundwater development, the direction of groundwater flow was from the southern part of the basin northward to discharge areas near Lucerne Lake, where it discharged through springs along the Helendale Fault and by evapotranspiration. Since the early 1900s, groundwater-level declines have mostly eliminated the areas where natural discharge occurred and exceeded 100 feet in the middle of the basin between the early 1950s and mid-1990s, and as much as 25 feet near the margins from about the mid-1950s to 2000s. A decrease in the rate of pumping after the mid-1990s lessened the hydraulic stress on the middle and lower aquifers and enabled hydraulic heads in the middle of the basin to recover slightly as groundwater near the margins of the basin moved toward the pumping depression. Although trends in groundwater levels in the center of the basin have reversed since the mid-1990s, levels at the basin margins continue to decline as the movement of groundwater from the margins fills the pumping depression and gradually flattens the groundwater table throughout the basin. The long-term extraction of groundwater and associated dewatering of the fine-grained sediments present within the aquifer system has resulted in aquifer compaction and consequently land subsidence, primarily near Lucerne Lake. Analysis of interferometric synthetic aperture radar data shows that almost 11 inches of land subsidence has occurred south of Lucerne Lake between April 1992 and November 2009; less subsidence occurred elsewhere in the basin during this period. This differential land subsidence has caused fissures and cracks in the ground surface, which have buckled the pavement and undercut roads in several locations. The Lucerne Valley Hydrologic Model was developed using the finite-difference groundwater modeling software One Water Hydrologic Model to represent the hydrologic conditions and stresses during 1942–2016. The model has a uniform grid of approximately 92 acres per cell (2,000 feet by 2,000 feet) and has four layers representing the water-bearing units. The results from the calibrated model simulations indicated that groundwater pumpage exceeded recharge, resulting in an estimated net cumulative depletion of groundwater storage (discharge minus recharge) of about 465,000 acre-feet from 1942 to 2016. The model simulated as much as 7.5 feet (90 inches; 2,286 millimeters) of aquifer compaction, which indicates the extensive fine-grained deposits and measured subsidence near Lucerne Lake.

California↗

USGS2024

Correlation analysis of groundwater and hydrologic data, Kaloko-Honokōhau National Historical Park, Hawai‘i

Designated in 1978, Kaloko-Honokōhau National Historical Park is located on the west coast of the Island of Hawaiʻi. The Kaloko-Honokōhau National Historical Park encompasses about 1,200 acres of coastal land and nearshore ecosystems, which include wetlands, anchialine pools (landlocked bodies of brackish water with hydrologic connections to the ocean), fishponds, a fishtrap, and coral reefs. These nearshore ecosystems are dependent on groundwater discharge with a freshwater component and provide habitat for threatened and endangered, endemic species, such as the orangeblack Hawaiian damselfly ( Megalagrion xanthomelas ) and the Hawaiian coot (ʻAlae keʻokeʻo, Fulica alai ). The populations of these native species, however, are threatened because of habitat loss related to urban development and environmental changes. Kaloko-Honokōhau National Historical Park is within the Keauhou aquifer system and the North Kona District, which experienced a 52 percent resident-population increase between 2000 and 2020 and a 41 percent visitor increase between 2008 and 2019. To support the current water demand associated with this growing population, groundwater is the primary source of freshwater used in the North Kona District, with about 15 million gallons of groundwater withdrawn from the Keauhou aquifer system per day since 2009. With anticipated development, future (2015–35) groundwater withdrawal from the Keauhou aquifer system is projected to be about 55 percent greater than recent (2012–14) withdrawal. Because Kaloko-Honokōhau National Historical Park is located within a coastal aquifer, natural and human-induced changes can affect the quality and quantity of groundwater, which can threaten groundwater-dependent ecosystems. To improve understanding of recent groundwater conditions, the U.S. Geological Survey, in cooperation with the National Park Service, undertook this study to document correlations between hydrologic time-series datasets from sites in and near Kaloko-Honokōhau National Historical Park using the nonparametric (distribution-free) Kendall’s tau statistical test. For the statistical analyses, dependent variables representing the groundwater system include groundwater level, the groundwater-level difference between pairs of sites, and specific conductance, and independent variables include datasets of sea level, rainfall, and groundwater withdrawal. About 34 percent of the 140 non-time-lagged Kendall’s tau statistical tests evaluated in this report are statistically significant ( p -value ≤ 0.050) with generally weak (0.1 ≤ tau ≤ 0.2) to moderate (0.2 ≤ tau ≤ 0.3) correlations. Groundwater levels measured at monitoring sites have the strongest correlation with the multivariate El Niño–Southern Oscillation index and withdrawal from production wells at the nearby Kohanaiki Private Club Community. Specific conductance is not consistently and significantly correlated with the independent hydrologic variables investigated in this report. Because the relations between hydrologic variables are commonly not instantaneous, a second set of correlations was evaluated after applying a range of time lags to the independent variable datasets. Relative to the non-time-lagged case (the set of correlations that did not use time-lagged independent variables), some of the time-lagged independent variables improved correlations with some of the dependent variables. For a particular independent variable, similar time lags were expected between the independent variable and dependent variable at all four monitoring sites. However, different time lags among the four sites sometimes produced the strongest correlations. This study identified several correlations that are statistically significant and hydrologically plausible, but the correlations could indicate that multiple concurrent factors are controlling the observed groundwater-system response, which might be better addressed using multivariate analyses. This study only investigates bivariate correlations, which may not explain all the variance in the data. The correlations analyzed in this report are limited by the quantity of available hydrologic data in the area near Kaloko-Honokōhau National Historical Park and are based on 14 years of time-series data, which were aggregated to a relatively coarse monthly temporal resolution that represents the minimum resolution common to all datasets.

Hawaii↗

USGS2026

Analyses of meteorological and hydrological records support Tribal members’ accounts of changing climate on the Fort Apache Reservation, east–central Arizona

The Fort Apache Reservation in east–central Arizona, home to the White Mountain Apache Tribe of the Fort Apache Reservation, Arizona, contains several climate zones because of the large variation in surface elevation within the reservation. This study was carried out in cooperation with the White Mountain Apache Tribe of the Fort Apache Reservation, Arizona, to raise awareness of how the changing climate affects the Fort Apache Reservation. This report documents the evaluation of existing multidecadal meteorological and hydrological datasets for the Fort Apache Reservation, used to evaluate the effects of a changing climate on the reservation. In this evaluation, near-surface air temperature, snow depth, snow water equivalent, precipitation, and streamflow datasets were analyzed for monotonic trends indicative of changing climatic conditions during specified periods of time. The results of these trend analyses were then compared with the Tribal community's memories of the changing climate. Trend analysis of near-surface air temperatures from a U.S. Historical Climatological Network station on the Fort Apache Reservation at Whiteriver, Arizona, indicated that mean annual air temperatures have increased by an average of 2.48 degrees Fahrenheit from 1980 to 2023. Records from the same station also indicated that average monthly maximum temperatures recorded for March increased by 5.39 degrees Fahrenheit for the same time period. Annual precipitation at the five precipitation stations used in this study decreased greatly from the 1980s to 2023. The largest total decrease was 10.07 inches, or 34.7 percent. However, only one of the two precipitation stations with longer term data available prior to 1980 had a significant negative trend when data from the entire period of record, from 1901 to 2023, were analyzed. Trend analyses show a decrease in the annual maximum snow water equivalent and an earlier disappearance of the snowpack at two Natural Resources Conservation Service snow telemetry stations in the mountainous region just east of the Fort Apache Reservation from 1981 to 2023. Based on the trend analyses, the average annual maximum snow water equivalent has decreased by more than 40 percent at both stations, and the average date when the snowpack was fully melted at the stations in the spring has moved earlier in time from late April to early April or late March. However, a statistically significant trend was not determined for the early April snow water equivalent measured at a nearby Natural Resources Conservation Service snow course across its period of record, indicating that the history of mountain snowpack in this area is not fully understood. Analysis of snowfall data from a National Oceanic and Atmospheric Administration Cooperative Observer Program network station on the Fort Apache Reservation at McNary 2N, AZ (station 025412) indicated that, on average, the measured total annual snowfall at the station decreased 42.4 percent from 1935 to 2023. Streamflow data from six U.S. Geological Survey streamgages on the Fort Apache Reservation were analyzed for trends. For most streamflow gages, statistically significant trends were not determined for tested parameters when the entire streamflow period of record was used for stations with records going back to at least the 1960s. However, when the data from 1980 to 2023 was tested, most of the streamflow parameters had statistically significant negative trends. All six streamgages showed a decrease in average annual runoff of at least 50 percent from 1980 to 2023; one streamgage showed an 81.8 percent decrease. A similar statistical finding was observed in the analysis of the annual spring snowmelt peak from one of the six streamgages used in the study and located in an area receiving measurable amounts of snowmelt runoff. When data from the entire period of record (1958–2023) was used, no trend in streamflow was determined; however, a significant negative trend was determined from 1980 to 2023, indicating a decrease in average annual springtime runoff of 62.6 percent. Statistical analysis on the timing of the annual spring snowmelt peak at the same streamgage indicated the snowmelt peak is happening on average about 12 days earlier now (2023) than it did in the past. The trend results for the timing of the annual spring snowmelt peak were the same and statistically significant for both periods tested (1958–2023 and 1980–2023). Two of the streamflow records from the Fort Apache Reservation were compared to the Palmer Hydrological Drought Index computed for Arizona Climate Division 4 (East Central) by the National Centers for Environmental Information. The comparison showed that the streamflow records generally tracked the Palmer Hydrological Drought Index. In interviews, Tribal community members living on the Fort Apache Reservation described the changes in climate that they observed during their lifetimes. Common themes reported were that air temperatures have become warmer, and the weather is less predictable with changes in seasonal patterns. Drier conditions, lower snowfall, shorter winters, and lower river levels were also reported. These community member observations align with the results of this study.

Arizona↗

USGS2008

Hydrochemical Regions of the Glacial Aquifer System, Northern United States, and Their Environmental and Water-Quality Characteristics

The glacial aquifer system in the United States is a large (953,000 square miles) regional aquifer system of heterogeneous composition. As described in this report, the glacial aquifer system includes all unconsolidated geologic material above bedrock that lies on or north of the line of maximum glacial advance within the United States. Examining ground-water quality on a regional scale indicates that variations in the concentrations of major and minor ions and some trace elements most likely are the result of natural variations in the geologic and physical environment. Study of the glacial aquifer system was designed around a regional framework based on the assumption that two primary characteristics of the aquifer system can affect water quality: intrinsic susceptibility (hydraulic properties) and vulnerability (geochemical properties). The hydrochemical regions described in this report were developed to identify and explain regional spatial variations in ground-water quality in the glacial aquifer system within the hypothetical framework context. Data analyzed for this study were collected from 1991 to 2003 at 1,716 wells open to the glacial aquifer system. Cluster analysis was used to group wells with similar ground-water concentrations of calcium, chloride, fluoride, magnesium, potassium, sodium, sulfate, and bicarbonate into five unique groups. Maximum Likelihood Classification was used to make the extrapolation from clustered groups of wells, defined by points, to areas of similar water quality (hydrochemical regions) defined in a geospatial model. Spatial data that represented average annual precipitation, average annual temperature, land use, land-surface slope, vertical soil permeability, average soil clay content, texture of surficial deposits, type of surficial deposit, and potential for ground-water recharge were used in the Maximum Likelihood Classification to classify the areas so the characteristics of the hydrochemical regions would resemble the characteristics of the clusters. The result of the Maximum Likelihood Classification is a map showing five hydrochemical regions of the glacial aquifer system. Statistical analysis of ion concentrations (calcium, chloride, fluoride, magnesium, sodium, potassium, sulfate, and bicarbonate) in samples collected from wells completed in the glacial aquifer system illustrates that variations in water quality can be explained, in part, by related environmental characteristics that control the movement of ground water through the aquifer system. A comparison of median concentrations of chemical constituents in ground water among the five hydrochemical regions indicates that ground water in the Midwestern Agricultural Region, the Urban-Influenced Region, and the Western Agriculture and Grassland Region has the highest concentrations of major and minor ions, whereas ground water in the Northern and Great Lakes Forested Region and the Mountain and Coastal Forested Region has the lowest concentrations of these ions. Median concentrations of barium, arsenic, lithium, boron, strontium, and nitrite plus nitrate as nitrogen also are significantly different among the hydrochemical regions.

Scientific Investigations Report↗